JP2007308764A - Dissolve oxygen water-producing apparatus - Google Patents

Dissolve oxygen water-producing apparatus Download PDF

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JP2007308764A
JP2007308764A JP2006139214A JP2006139214A JP2007308764A JP 2007308764 A JP2007308764 A JP 2007308764A JP 2006139214 A JP2006139214 A JP 2006139214A JP 2006139214 A JP2006139214 A JP 2006139214A JP 2007308764 A JP2007308764 A JP 2007308764A
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water
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dissolved oxygen
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JP4182119B2 (en
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Toshihiko Chibana
敏彦 知花
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SADAHIRO TEKKOSHO KK
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a dissolved oxygen water-producing apparatus for producing neutral fresh water having enriched dissolved oxygen. <P>SOLUTION: The dissolved oxygen water-producing apparatus is provided with: a water storage vessel 10 for storing raw material water; an electrode member 30 arranged on the bottom 10b of the water storage vessel 10 and provided with a pair of electrodes comprising a cathode electrode 31 and an anode electrode 32 in a center member 33; and a controller 40 for carrying out various control related to the supply of DC voltage to the electrode member 30. The controller 40 is provided with: a voltage converting means 42 for converting AC voltage supplied from an outside power source 50 to DC voltage; a timing means 43 for timing a preset switching time for switching the polarity of the DC voltage supplied to each electrode 31, 32 of the electrode member 30 and outputting switching information corresponding to the timing when the switching time is timed: and a polarity switching means 44 for switching the voltage supplied to each electrode 31, 32 of the electrode member 30 based on the switching information output from the timing means 43 to reverse the polarity of each electrode 31, 32. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、原料水を改水処理し、中性で溶存酸素が豊富な溶存酸素水を生成する溶存酸素水生成装置に関するものである。   The present invention relates to a dissolved oxygen water generating device that reforms raw water to generate a dissolved oxygen water that is neutral and rich in dissolved oxygen.

従来より、電解槽内に陰極および陽極からなる電極と、両極間を区画するとともに水中のイオンを自由に通過させるイオン透過分離膜とを設け、この電解槽内に、水道水等の原料水を供給して両極間に直流電圧を印加することにより、水を電気分解する過程で水溶液中の陽イオンが陰極側に移動し、陰イオンが陽極側に移動することを利用して、イオン透過分離膜の陰極側にマグネシウムイオン、カリウムイオン、ナトリウムイオン等の陽イオンを多く含むアルカリイオン水を生成させ、陽極側に塩素イオン、硫酸イオン等の陰イオンを多く含む酸性イオン水を生成させるようにした電解水生成装置がある(例えば特許文献1を参照)。   Conventionally, an electrode composed of a cathode and an anode and an ion permeable separation membrane for partitioning both electrodes and allowing ions in water to pass freely are provided in the electrolytic cell, and raw water such as tap water is provided in the electrolytic cell. By supplying and applying a DC voltage between both electrodes, ion permeation separation is performed by utilizing the fact that cations in aqueous solution move to the cathode side and anions move to the anode side in the process of electrolyzing water. Alkaline ion water containing a large amount of cations such as magnesium ion, potassium ion and sodium ion is generated on the cathode side of the membrane, and acidic ion water containing a large amount of anions such as chloride ion and sulfate ion is generated on the anode side. There is an electrolyzed water generating apparatus (see, for example, Patent Document 1).

この種の電解水生成装置では、陰極(アルカリ電極)と陽極(酸性電極)に直流電圧を印加すると、原料水の中に存在するカルシウム、マグネシウム、ナトリウム、カリウムなどのミネラル栄養分であるプラスイオンは陰極に引寄せられる。また、塩素、硫酸、硫黄などのマイナスイオンは陽極に引寄せられる。これと同時に、陰極では水素イオンH+ が陰極から電子を奪って、水素分子H2 となり、空気中に逃げていくので、水酸イオンOH- が増加して、水はアルカリ性になる。一方、陽極では水酸イオンOH- が陽極に電子を与えて、酸素分子O2 となり空気中に逃げていくので、水素イオンH+ が増加して、水は酸性になる。そして、この陰極と陽極における電気分解反応を化学方程式で表すと以下のようになる。
陰極:4H+ +4e→2H2
陽極:4OH- →O2 +2H2 O+4e
特開2003−390068号公報
In this type of electrolyzed water generator, when a DC voltage is applied to the cathode (alkaline electrode) and anode (acidic electrode), the positive ions that are mineral nutrients such as calcium, magnesium, sodium, and potassium present in the raw water are Attracted to the cathode. Also, negative ions such as chlorine, sulfuric acid, and sulfur are attracted to the anode. At the same time, at the cathode, hydrogen ions H + take electrons from the cathode and become hydrogen molecules H 2 , which escape into the air, so that hydroxide ions OH increase and water becomes alkaline. On the other hand, at the anode, the hydroxide ions OH give electrons to the anode and become oxygen molecules O 2 and escape into the air, so that the hydrogen ions H + increase and the water becomes acidic. The electrolysis reaction between the cathode and the anode is represented by the following chemical equation.
Cathode: 4H + + 4e → 2H 2
Anode: 4OH → O 2 + 2H 2 O + 4e
JP 2003-390068 A

このような電解水生成装置を用いた場合、陰極側で生成されたアルカリイオン水はミネラル栄養分を種々含んでいるため飲用水など様々な用途で使用されるが、陽極側で生成された酸性水はほとんどが捨てられてしまうため、経済的ではない。   When such an electrolyzed water generator is used, the alkaline ion water generated on the cathode side is used for various purposes such as drinking water because it contains various mineral nutrients, but the acidic water generated on the anode side Is not economical because most are thrown away.

そして、水は水分子(H2 O)同士が互いに水素結合やファンデルワーカスなどの弱い力で結合して水分子集団(クラスター)となり存在している(一般的な水道水や湧水などの水は、通常平均で15〜20個程度の水分子のクラスターを形成してなる)。そして、上述したような電解水生成装置を用いて原料水をアルカリイオン水と酸性水とを分離生成する場合、このクラスターが大きいことにより容易に分離できず、電離槽に大きな負担がかかり電解水生成装置の寿命の短命化を招いている。さらに、原料水をアルカリ水と酸性水とに生成分離する際に、電気分解によって電離槽の電極にカルシウム、マグネシウム等のミネラル成分が付着してしまい、これにより電極の機能が低下するという問題も起こっている。 And water exists as a water molecule group (cluster) by combining water molecules (H 2 O) with each other with a weak force such as hydrogen bond or van der Waus (such as general tap water or spring water). Water usually forms a cluster of about 15 to 20 water molecules on average). When the raw material water is separated and produced from the alkaline ionized water and the acidic water using the electrolyzed water generating apparatus as described above, it cannot be easily separated due to the large size of the cluster, and the ionization tank is subjected to a heavy burden. The life of the generator is shortened. Furthermore, when the raw material water is generated and separated into alkaline water and acidic water, mineral components such as calcium and magnesium adhere to the electrode of the ionization tank due to electrolysis, thereby reducing the function of the electrode. is happening.

また、近年、水分子集団(クラスター)が小さい、いわゆるクラスター水が人体の代謝機能を改善することが知られてきており、水分子集団(クラスター)を小さくする手段が各種開発されてきている。また、美容健康、ダイエット効果、成人病予防など健康な体づくりや体質改善を目的として溶存酸素が豊富な水が注目されている。   In recent years, it has been known that so-called cluster water having a small water molecule group (cluster) improves the metabolic function of the human body, and various means for reducing the water molecule group (cluster) have been developed. In addition, water rich in dissolved oxygen is attracting attention for the purpose of creating a healthy body such as beauty and health, diet effects, and adult disease prevention, and improving the constitution.

しかしながら、水分子集団(クラスター)を小さくする装置や溶存酸素が豊富な水を生成する装置は、イオン交換膜やフィルタ槽などの他様々な部品を備えて構成されているため装置本体の構造が複雑である。そして、この装置の複雑さにより、装置本体や該装置を用いて生成した水の価格が高くなってしまい、広く普及させることが困難であった。   However, devices that reduce water molecule clusters (clusters) and devices that generate water rich in dissolved oxygen are composed of various other components such as ion exchange membranes and filter tanks. It is complicated. Due to the complexity of the device, the price of the device main body and the water produced using the device has increased, making it difficult to spread widely.

そこで、本発明は上記問題点に鑑みてなされたものであり、原料水を効率的に使用するとともに、簡易的な構成で原料水の水分子集団(クラスター)を分断し、且つ、高濃度の溶存酸素量を有する新規の水を生成する溶存酸素水生成装置を提供することを目的とするものである。   Therefore, the present invention has been made in view of the above problems, and efficiently uses raw water, divides a water molecule group (cluster) of raw water with a simple configuration, and has a high concentration. It aims at providing the dissolved oxygen water production | generation apparatus which produces | generates the novel water which has dissolved oxygen amount.

上記した目的を達成するために、請求項1記載の溶存酸素水生成装置は、原料水を貯水する貯水容器と、該貯水容器の底部に配設され、中心部材に陰極電極、陽極電極からなる一対の電極を備えた電極部材と、該電極部材に供給する電圧に関する各種制御をする制御装置とを備え、前記電極部材に電圧を印加して前記貯水容器内に貯水された原料水を改水する溶存酸素水生成装置であって、
前記制御装置は、
外部電源から供給された交流電圧を直流電圧に変換する電圧変換手段と、
予め設定された前記電極部材の各電極に供給する前記直流電圧の極性を切り替えるための切替時間を計時し、該切替時間を計時すると、この計時に応じた切替情報を出力する計時手段と、
該計時手段から出力された切替情報に基づき前記電極部材の各電極に供給する電圧を切り替えて前記各電極の極性を逆転させる極性切替手段と、
を備えて構成されることを特徴とする。
In order to achieve the above object, a dissolved oxygen water generating device according to claim 1 is provided with a water storage container for storing raw water, a bottom electrode of the water storage container, a central member comprising a cathode electrode and an anode electrode. An electrode member having a pair of electrodes, and a control device that performs various controls relating to the voltage supplied to the electrode member, and reforming raw water stored in the water storage container by applying a voltage to the electrode member A dissolved oxygen water generator,
The controller is
Voltage conversion means for converting an AC voltage supplied from an external power source into a DC voltage;
Measuring a switching time for switching the polarity of the DC voltage to be supplied to each electrode of the electrode member set in advance, and measuring the switching time, a timing means for outputting switching information according to the timing;
Polarity switching means for switching the voltage supplied to each electrode of the electrode member based on the switching information output from the time measuring means to reverse the polarity of each electrode;
It is characterized by comprising.

請求項2記載の溶存酸素水生成装置は、前記電極部材は、請求項1記載の溶存酸素水生成装置において、前記各電極が前記中心部材を中心として一方が時計方向に、他方が半時計方向に、それぞれ所定径を有しながら螺旋状に巻回するような形状で形成され、且つ、前記各電極は互いに接触しないよう前記中心部材の鉛直方向に対して前記各電極の位置が上下になるよう配設されていることを特徴とする。   The dissolved oxygen water generating apparatus according to claim 2, wherein the electrode member is the dissolved oxygen water generating apparatus according to claim 1, wherein each of the electrodes is centered on the central member, one is clockwise, and the other is counterclockwise. In addition, each electrode has a shape that is spirally wound while having a predetermined diameter, and the electrodes are vertically positioned with respect to the vertical direction of the central member so that the electrodes do not contact each other. It is arranged so that it may be arranged.

請求項3記載の溶存酸素水生成装置は、請求項1または2記載の溶存酸素水生成装置において、前記貯水容器は着脱可能な容器蓋を備え、該容器蓋には前記電極部材によって前記貯水容器内の原料水が改水された際に発生する水素ガスを外部に放出するための通気孔が形成されていることを特徴とする。   The dissolved oxygen water generating device according to claim 3 is the dissolved oxygen water generating device according to claim 1 or 2, wherein the water storage container is provided with a detachable container lid, and the container lid is provided with the electrode member on the container lid. A vent hole is formed to discharge hydrogen gas generated when the raw material water is reformed to the outside.

請求項4記載の溶存酸素水生成装置は、請求項1〜3の何れかに記載の溶存酸素水生成装置において、前記計時手段が計時する切替時間を少なくとも10分以内にすることを特徴とする。   The dissolved oxygen water generating device according to claim 4 is characterized in that, in the dissolved oxygen water generating device according to any one of claims 1 to 3, the switching time measured by the time measuring means is set to at least 10 minutes. .

請求項5記載の溶存酸素水生成装置は、請求項1〜4に何れかに記載の溶存酸素水生成装置において、さらに、前記貯水容器内を照明する照明手段を所要位置に配設したことを特徴とする。   The dissolved oxygen water generation device according to claim 5 is the dissolved oxygen water generation device according to any one of claims 1 to 4, further comprising an illumination means for illuminating the inside of the water storage container at a required position. Features.

本発明の溶存酸素水生成装置によれば、貯水された原料水を無駄なく使用し、簡易的な構成で溶存酸素量が豊富で、且つ、水分子集団(クラスター)が分解された中性の溶存酸素水を提供することができる。   According to the dissolved oxygen water generating apparatus of the present invention, the stored raw water is used without waste, the dissolved oxygen amount is abundant with a simple configuration, and the water molecule group (cluster) is decomposed. Dissolved oxygen water can be provided.

また、改水時に使用する電極部材は、各電極が中心部材を中心として時計方向と半時計方向にそれぞれ所定径を有しながら螺旋状に巻回するような形状で形成され、且つ、各電極は互いに接触しないよう中心部材の鉛直方向に対して電極の位置が上下になるよう配設されているため、原料水を効率的良く改水することができる。   Further, the electrode member used at the time of water reforming is formed in such a shape that each electrode is spirally wound with a predetermined diameter in the clockwise direction and the counterclockwise direction around the center member, and each electrode Since the electrodes are arranged so that the positions of the electrodes are up and down with respect to the vertical direction of the central member so that they do not contact each other, the raw water can be efficiently reformed.

さらに、電極部材に印加する電圧の極性を少なくとも10分以内に逆転させているため、各電極に原料水中のミネラル成分が電極に付着するのを防止し、電極をメンテナンスする手間を省くことができる。   Furthermore, since the polarity of the voltage applied to the electrode member is reversed within at least 10 minutes, it is possible to prevent the mineral component in the raw material water from adhering to the electrode and to save the trouble of maintaining the electrode. .

以下、本発明における最良の形態について、添付した図面を参照しながらそれぞれ詳細に説明する。図1は本発明に係る溶存酸素水生成装置を説明するための概略斜視図であり、図2は同装置の概略を説明するための断面図であり、図3は同装置における電極部材を説明するための概略斜視図であり、図4は同装置における制御装置の構成を説明するための概略ブロック図である。   Hereinafter, the best mode of the present invention will be described in detail with reference to the accompanying drawings. FIG. 1 is a schematic perspective view for explaining a dissolved oxygen water generating apparatus according to the present invention, FIG. 2 is a cross-sectional view for explaining the outline of the apparatus, and FIG. 3 explains an electrode member in the apparatus. FIG. 4 is a schematic block diagram for explaining a configuration of a control device in the apparatus.

まず、本例の溶存酸素水生成装置の構成について、図1〜図4を参照しながら説明する。図1または図2に示すように、溶存酸素水生成装置1は、貯水容器10と、出水用コック20と、電極部材30と、制御装置40とを備えて概略構成される。なお、以下の説明で使用する原料水とは、例えば水道水、自然の湧水(ミネラルウォータ)、井戸水などの一般的な水を指す。   First, the structure of the dissolved oxygen water production | generation apparatus of this example is demonstrated, referring FIGS. 1-4. As shown in FIG. 1 or FIG. 2, the dissolved oxygen water generation device 1 is schematically configured to include a water storage container 10, a water discharge cock 20, an electrode member 30, and a control device 40. In addition, the raw material water used by the following description points out common waters, such as a tap water, natural spring water (mineral water), well water, for example.

貯水容器10は、例えばガラスなどの貯水した水が外部から見えるように透明で、且つ、原料水の改水時に行われる電気分解によって貯水容器10本体の組成成分が溶存酸素水中に溶解しない材質で形成されていることが好適である。また、貯水容器10の上部には、原料水を注ぎ入れるための開口部10aが設けられており、原料水の補充を行う際に使用する。また、この開口部を塞ぐための着脱可能な容器蓋11が具備されている。この容器蓋11の上部には、貯水容器10内の原料水を改水する際に発生する水素ガスを容器外に放出するための通気孔11aが形成されている。   The water storage container 10 is made of a material that is transparent so that the stored water such as glass can be seen from the outside, and the composition components of the main body of the water storage container 10 are not dissolved in the dissolved oxygen water by electrolysis performed when the raw water is reformed. It is suitable that it is formed. Moreover, the upper part of the water storage container 10 is provided with an opening 10a for pouring raw water, and is used when replenishing raw water. In addition, a detachable container lid 11 for closing the opening is provided. A vent hole 11a for releasing hydrogen gas generated when the raw water in the water storage container 10 is reformed is formed in the upper part of the container lid 11.

出水用コック20は、例えばプラスチックやステンレス鋼などの耐食性に優れた材質で構成されている。出水用コック20は、貯水容器10の所定箇所に配設され、具備されたレバー21を操作して貯水容器10内の溶存酸素水を出水する際に使用される。   The water discharge cock 20 is made of a material having excellent corrosion resistance such as plastic and stainless steel. The water discharge cock 20 is disposed at a predetermined location of the water storage container 10 and is used when the dissolved oxygen water in the water storage container 10 is discharged by operating the provided lever 21.

電極部材30は、チタン製の電極に白金で表面をコーティングした陰極電極31、陽極電極32からなる一対の電極が中心部材33の所定位置に配設されている。陰極電極31、陽極電極32は、図3に示すように、原料水を電気分解して改水する際に電極全体で電気分解を効率的に行うため、各電極31、32が中心部材33を中心として一方が時計方向に、他方が半時計方向に、それぞれ所定径を有しながら螺旋状に巻回するような形状で形成され、且つ、各電極31、32は互いに接触しないよう中心部材33の鉛直方向に対して電極の位置が上下になるよう配設されている。また、電極部材30の下方には、各電極31、32に電圧を供給するための電極用プラグ34が各電極31、32に対応して設けられており、制御装置40と接続されている。   In the electrode member 30, a pair of electrodes including a cathode electrode 31 and an anode electrode 32 whose surfaces are coated with platinum on a titanium electrode is disposed at a predetermined position of the central member 33. As shown in FIG. 3, the cathode electrode 31 and the anode electrode 32, when electrolyzing raw material water and reforming the water, efficiently perform electrolysis on the entire electrode. The center member 33 is formed in such a shape that one side is clockwise and the other is counterclockwise as the center and is spirally wound with a predetermined diameter, and the electrodes 31 and 32 are not in contact with each other. The electrode is disposed so that the position of the electrode is up and down with respect to the vertical direction. Further, below the electrode member 30, electrode plugs 34 for supplying a voltage to the electrodes 31 and 32 are provided corresponding to the electrodes 31 and 32, and are connected to the control device 40.

制御装置40は、溶存酸素水生成装置1を構成する各部を駆動制御を行う装置である。制御装置40は、図1に示すように電極部材30への電源供給ON/OFFや後述する照明手段45への電源供給ON/OFFを切り替えるための切替スイッチ41a、41bが設けられており、必要に応じて所定操作して電源ON/OFFの切替を行う。そして、図4に示すように、制御装置40は、電圧変換手段42と、計時手段43と、極性切替手段44と、照明手段45とを備えて概略構成されている。
なお、本例では電極部材30への電源供給ON/OFFは切替スイッチ41aで、照明手段45への電源供給ON/OFFは切替スイッチ41bで行う構成であるが、配置位置などは特に限定されない。
The control device 40 is a device that performs drive control of each part constituting the dissolved oxygen water generation device 1. As shown in FIG. 1, the control device 40 is provided with changeover switches 41a and 41b for switching power supply ON / OFF to the electrode member 30 and power supply ON / OFF to the illumination means 45 described later. The power is turned on / off by a predetermined operation according to the above. As shown in FIG. 4, the control device 40 includes a voltage conversion unit 42, a time measuring unit 43, a polarity switching unit 44, and an illumination unit 45.
In this example, the power supply ON / OFF to the electrode member 30 is configured by the changeover switch 41a and the power supply ON / OFF to the illumination unit 45 is performed by the changeover switch 41b. However, the arrangement position is not particularly limited.

電圧変換手段42は、例えば商用電源などの外部電源50から供給された交流(AC)電圧を直流(DC)電圧に変換するAC/DC変換器で構成され、外部電源50をAC/DC変換した後、各部に電源供給している。   The voltage conversion means 42 is composed of an AC / DC converter that converts an alternating current (AC) voltage supplied from an external power source 50 such as a commercial power source into a direct current (DC) voltage, and the external power source 50 is AC / DC converted. After that, power is supplied to each part.

計時手段43は、例えばタイマーで構成され、陰極電極31、陽極電極32に供給される+電圧と−電圧を切り替えて各電極31、32の極性を逆転させる際の切替時間を計時しており、予め設定された切替時間を計時すると、この計時に応じた切替情報を極性切替手段44に出力している。なお、この切替時間は、装置の大きさや使用環境に応じて任意に設定することができるが、改水時の電気分解により原料水に含有されたカルシウムやマグネシウムなどのミネラル成分が各電極31、32の表面部分に付着しないようにするため、少なくとも10分以内に設定することが好適である。   The time measuring means 43 is constituted by, for example, a timer, and measures the switching time when the polarity of each electrode 31, 32 is reversed by switching the + voltage and the − voltage supplied to the cathode electrode 31 and the anode electrode 32. When the preset switching time is counted, switching information corresponding to the timing is output to the polarity switching means 44. This switching time can be arbitrarily set according to the size of the device and the use environment, but mineral components such as calcium and magnesium contained in the raw water by electrolysis at the time of water reforming are each electrode 31, In order not to adhere to the surface portion of 32, it is preferable to set within at least 10 minutes.

極性切替手段44は、例えばスイッチなどで構成され、電極部材30の電源プラグ34と接続されている。極性切替手段44は、計時手段43から出力された切替情報に基づき電極部材30の各電極31、32に供給している電圧を切り替えて、各電極31、32の極性を逆転させている。   The polarity switching means 44 is composed of a switch or the like, for example, and is connected to the power plug 34 of the electrode member 30. The polarity switching unit 44 switches the voltage supplied to the electrodes 31 and 32 of the electrode member 30 based on the switching information output from the time measuring unit 43 to reverse the polarity of the electrodes 31 and 32.

照明手段45は、例えばLEDなどの照明機器で構成され、貯水容器10内に照明光を照射するため貯水容器10の底部10b近傍に配設されている。照明手段45は、鑑賞用ディスプレイとして使用する際の照明として使用され、切替スイッチ41bを所定操作することで点灯/消灯を行う。   The illuminating means 45 is constituted by, for example, an illumination device such as an LED, and is disposed in the vicinity of the bottom 10 b of the water storage container 10 in order to irradiate the water storage container 10 with illumination light. The illumination means 45 is used as illumination when used as a viewing display, and is turned on / off by a predetermined operation of the changeover switch 41b.

そして、上述した構成の溶存酸素水生成装置1では、まず貯水容器10に原料水を貯水した後、切替スイッチ41aを操作して電源をONにし、電極部材30に電源を供給する。そして、外部電源50から変換した直流電圧を所定間隔で極性を切り替えながら電極部材30の各電極31、32にそれぞれ供給して貯水された原料水を改水し、所定時間経過後に出水用コック20を操作して改水された溶存酸素水を出水する。また、必要に応じて照明手段45用の切替スイッチ41bを操作して照明のON/OFFを行う。   In the dissolved oxygen water generator 1 having the above-described configuration, first, raw water is stored in the water storage container 10, and then the power is turned on by operating the changeover switch 41 a to supply power to the electrode member 30. Then, the raw water stored by supplying the direct current voltage converted from the external power supply 50 to each of the electrodes 31 and 32 of the electrode member 30 while switching the polarity at predetermined intervals is renewed, and the water discharge cock 20 is passed after a predetermined time has elapsed. Operate to discharge the modified dissolved oxygen water. Further, if necessary, the illumination switch 45 for the illumination means 45 is operated to turn on / off the illumination.

次に、上述した溶存酸素水生成装置1を用いて生成した溶存酸素水と改水前の原料水との比較実験について説明する。   Next, a comparative experiment between the dissolved oxygen water generated using the above-described dissolved oxygen water generator 1 and the raw water before the water reform will be described.

実験内容としては、原料水として水道水を使用し、電極部材30に外部電源50(AC100V)からDC24Vに変換した直流電圧を20分間印加して原料水の改水を行い、溶存酸素水を生成した。そして、生成した溶存酸素水との比較して、溶存酸素水生成に使用したものと同様式の貯水容器10に溶存酸素水と同量の原料水を入れたものを比較対象として使用した。また、溶存酸素を計測するための溶存酸素計は「飯島電子工業(株)製のHI98129(コンボ)」を、pH測定器は「ハンナインスルメンツ・ジャパン株式会社製のF−102」を用いて、各容器内に貯水さえた水の溶存酸素量とpHを測定した。
(原料水)
・pH:7.26
・溶存酸素量:7.3ppm
(溶存酸素水)
・pH:7.57
・溶存酸素量:14.7ppm
The contents of the experiment are: tap water is used as raw material water, and the direct current voltage converted from the external power source 50 (AC100V) to DC24V is applied to the electrode member 30 for 20 minutes to reform the raw material water to produce dissolved oxygen water. did. And compared with the produced | generated dissolved oxygen water, what put raw material water of the same quantity as dissolved oxygen water into the water storage container 10 of the same formula as what was used for the dissolved oxygen water production | generation was used as a comparison object. Moreover, the dissolved oxygen meter for measuring dissolved oxygen uses “HI98129 (combo) manufactured by Iijima Electronics Co., Ltd.”, and the pH meter uses “F-102 manufactured by Hanna Instruments Japan Co., Ltd.”. Then, the dissolved oxygen content and pH of the water stored in each container were measured.
(Raw material water)
-PH: 7.26
・ Amount of dissolved oxygen: 7.3 ppm
(Dissolved oxygen water)
-PH: 7.57
・ Amount of dissolved oxygen: 14.7ppm

上記実験結果から、原料水と本例の溶存酸素水のpHは互いに中性の範囲を示しているのに対し、溶存酸素水の溶存酸素量は原料水に比べ約2倍になった。これは、溶存酸素水生成装置1によって原料水の水分子集団(クラスター)が分解されイオン化したことにより(1クラスターあたり平均で5〜7個程度で形成される)、原料水中の溶存酸素量が増大したと考えられる。   From the above experimental results, the pH of the raw water and the dissolved oxygen water of this example showed a neutral range, whereas the dissolved oxygen amount of the dissolved oxygen water was about twice that of the raw water. This is because the dissolved oxygen water generating device 1 decomposes and ionizes the water molecule group (cluster) of the raw water (formed with an average of about 5 to 7 per cluster), so that the amount of dissolved oxygen in the raw water is reduced. It is thought that it increased.

このように、上述した溶存酸素水生成装置1は、貯水容器10に原料水を貯水し、貯水容器10の底部10bには、各電極31、32が中心部材33を中心として一方が時計方向に、他方が半時計方向に、それぞれ所定径を有しながら螺旋状に巻回するような形状で形成され、且つ、各電極31、32は互いに接触しないよう中心部材33の鉛直方向に対して電極の位置が上下になるよう配設された電極部材30に直流電圧を印加して貯水された原料水を電気分解して改水する。
これにより、貯水容器10内に貯水された原料水が各電極31、32によって同時に改水されるため、溶存酸素量が豊富で水分子集団(クラスター)が分解された中性の溶存酸素水を生成することができる。
Thus, the above-described dissolved oxygen water generating apparatus 1 stores the raw water in the water storage container 10, and each electrode 31, 32 is centered on the central member 33 on the bottom 10 b of the water storage container 10, one of which is clockwise. The other is formed in a shape that is spirally wound with a predetermined diameter in the counterclockwise direction, and the electrodes 31 and 32 are electrodes with respect to the vertical direction of the central member 33 so as not to contact each other. The raw material water stored by applying a direct current voltage to the electrode member 30 arranged so that the position of the upper and lower portions of the electrode member 30 is arranged is electrolyzed and reformed.
As a result, the raw water stored in the water storage container 10 is reformed simultaneously by the electrodes 31 and 32, so that the neutral dissolved oxygen water with abundant dissolved oxygen amount and decomposed water molecule group (cluster) can be obtained. Can be generated.

また、電極部材30は、各電極31、32が中心部材33を中心として一方が時計方向に、他方が半時計方向に、それぞれ所定径を有しながら螺旋状に巻回するような形状で形成され、且つ、各電極31、32は互いに接触しないよう中心部材33の鉛直方向に対して電極の位置が上下になるよう配設されているため、各電極31、32全体から均等に、且つ、効率的に改水処理を行うことができる。   In addition, the electrode member 30 is formed in such a shape that each electrode 31 and 32 is spirally wound with a predetermined diameter, one in the clockwise direction and the other in the counterclockwise direction with the center member 33 as the center. In addition, since the electrodes 31 and 32 are arranged so that the positions of the electrodes are up and down with respect to the vertical direction of the central member 33 so that they do not contact each other, Water reforming can be performed efficiently.

さらに、電極部材30の各電極31、32に印加する電圧の極性を少なくとも10分以内に逆転させているため、各電極31、32に原料水中のミネラル成分が電極に付着するのを防止する効果を奏する。   Furthermore, since the polarity of the voltage applied to the electrodes 31 and 32 of the electrode member 30 is reversed within at least 10 minutes, the effect of preventing the mineral components in the raw material water from adhering to the electrodes on the electrodes 31 and 32 is achieved. Play.

ところで、上述した溶存酸素水生成装置1において、貯水容器10の形状を六角柱形状の貯水容器10を例に挙げたが、これに形状限定されることはなく、使用する場所や用途に応じて例えば立方体、直方体、多面体、球体など装置全体の大きさや外観バランスに応じて種々の形状のものを使用することができる。   By the way, in the dissolved oxygen water production | generation apparatus 1 mentioned above, although the shape of the water storage container 10 gave the example of the water storage container 10 of hexagonal column shape, it is not limited to this shape, According to the place and use to be used. For example, various shapes such as a cube, a rectangular parallelepiped, a polyhedron, and a sphere can be used according to the overall size and appearance balance of the apparatus.

また、電極部材30は、上述したような各電極31、32が略同等の所定径を有する形状に限定されることはなく、原料水を介する際に均等に、且つ、各電極31、32の全体面で電気分解が効率的に行われるような形状であれば電極の径の大きさや形状(例えば板状や棒状)など、貯水容器10の大きさや形状に応じて適宜選択することができる。さらに、陰極電極31、陽極電極32の配設位置は、所定間隔で供給される電圧が逆転するため配設位置が逆であってもよい。   In addition, the electrode member 30 is not limited to the shape in which the electrodes 31 and 32 have substantially the same predetermined diameter as described above. The shape can be appropriately selected according to the size and shape of the water storage container 10 such as the size and shape of the electrode (for example, a plate shape or a rod shape) as long as the shape allows efficient electrolysis on the entire surface. Furthermore, the arrangement positions of the cathode electrode 31 and the anode electrode 32 may be reversed because the voltages supplied at predetermined intervals are reversed.

また、上述した溶存酸素水生成装置1は、照明手段45を点灯/点滅させることにより照明光が貯水容器10内の溶存酸素水や電気分解で発生した気泡に反射し、視覚的に鑑賞効果を備えた鑑賞用ディスプレイとしても使用することができる。この場合、電極部材30は、上側に配置する電極を下側に配置する電極よりも小さい径の電極を使用することにより、下側の電極から発生した気泡と上側の電極から発生した気泡とが略環状に混在して液面に向かって上昇するため、鑑賞用ディスプレイとしての視覚的効果がさらに向上する。なお、上述した形態では、照明手段45は貯水容器10の底部10bに配設された例で説明したが、照明手段45から照射された照明光が貯水容器10内に照射される箇所に配設されていれば、照明手段45の配置場所は特に限定されない。   Moreover, the dissolved oxygen water production | generation apparatus 1 mentioned above reflects illumination light in the bubble which generate | occur | produced by dissolved oxygen water and the electrolysis in the water storage container 10 by lighting / flashing the illumination means 45, and has a visual appreciation effect. It can also be used as a display for viewing. In this case, the electrode member 30 uses an electrode having a diameter smaller than that of the electrode disposed on the lower side, so that bubbles generated from the lower electrode and bubbles generated from the upper electrode are removed. Since it is mixed in a substantially annular shape and rises toward the liquid surface, the visual effect as a viewing display is further improved. In the above-described embodiment, the illumination unit 45 is described as being disposed on the bottom 10b of the water storage container 10. However, the illumination unit 45 is disposed at a location where the illumination light emitted from the illumination unit 45 is irradiated into the water storage container 10. If it is, the arrangement place of the illumination means 45 is not particularly limited.

さらに、上述した形態では、照明手段45が制御装置40内に設けられた構成で説明したが、これに限定されることはなく、例えば制御装置40と照明手段45を別体構成とすることもできる。この場合、制御装置40、照明手段45の何れかに不具合が生じた場合に、別体であるので故障した部分のみを修理することができ、メンテナンスが容易となり利便性が向上する。   Further, in the above-described embodiment, the configuration in which the illumination unit 45 is provided in the control device 40 has been described. However, the present invention is not limited to this. For example, the control device 40 and the illumination unit 45 may be configured separately. it can. In this case, when a malfunction occurs in either the control device 40 or the illumination unit 45, since it is a separate body, only the failed part can be repaired, and maintenance is facilitated and convenience is improved.

以上述べたことから明らかなように、本発明によって生成された溶存酸素水は、飲用水としての用途に限らず非常に広範囲にわたる様々な水に対して適用することが可能であり、水分子集団(クラスター)がイオン化して細分化した水分子の働きにより、例えば水道水の塩素臭、排水路やトイレのアンモニア臭などを効果的に抑制することができる。
さらに、溶存酸素量が豊富であるため、例えば農業、漁業または工業のような産業で、またはビルや一般の住宅で種々の目的で水を蓄えられる水槽や貯水槽、例えば金魚や熱帯魚等の水棲動物を鑑賞や販売の目的で飼育するための水槽、魚介類や藻類等を養殖するための水槽や貯水池、水泳用または消火用のプール、或いは天然の池や湖沼もしくは人工的な池やダム等の場所で利用した場合に、水が腐敗したりアオコなどの発生を防止することができる。
As is apparent from the above description, the dissolved oxygen water produced by the present invention is not limited to use as potable water, and can be applied to a wide variety of water. For example, the chlorine odor of tap water and the ammonia odor of drainage channels and toilets can be effectively suppressed by the action of water molecules that are ionized into (clusters) and subdivided.
In addition, the abundance of dissolved oxygen makes it possible to store water for various purposes in industries such as agriculture, fishery or industry, or in buildings and general houses, such as aquariums such as goldfish and tropical fish. Aquarium for breeding animals for the purpose of appreciation and sales, aquarium and reservoir for aquaculture of seafood and algae, swimming or fire fighting pool, natural pond, lake, artificial pond, dam, etc. When it is used in this place, it is possible to prevent the water from rotting and the occurrence of water bullies.

以上、本願発明における最良の形態について説明したが、この形態による記述及び図面により本発明が限定されることはない。すなわち、この形態に基づいて当業者等によりなされる他の形態、実施例及び運用技術等はすべて本発明の範疇に含まれることは勿論である。   As mentioned above, although the best form in this invention was demonstrated, this invention is not limited with the description and drawing by this form. That is, it is a matter of course that all other forms, examples, operation techniques, and the like made by those skilled in the art based on this form are included in the scope of the present invention.

本発明に係る溶存酸素水生成装置を説明するための概略斜視図である。It is a schematic perspective view for demonstrating the dissolved oxygen water production | generation apparatus which concerns on this invention. 同装置の概略を説明するための断面図である。It is sectional drawing for demonstrating the outline of the apparatus. 同装置における電極部材を説明するための概略斜視図である。It is a schematic perspective view for demonstrating the electrode member in the same apparatus. 同装置における制御装置の構成を説明するための概略ブロック図である。It is a schematic block diagram for demonstrating the structure of the control apparatus in the same apparatus.

符号の説明Explanation of symbols

1 溶存酸素水生成装置
10 貯水容器
20 出水用コック
30 電極部材
40 制御装置
41a、41b 切替スイッチ
42 電圧変換手段
43 計時手段
44 極性切替手段
45 照明手段
50 外部電源
DESCRIPTION OF SYMBOLS 1 Dissolved oxygen water production | generation apparatus 10 Water storage container 20 Cock for discharge 30 Electrode member 40 Control apparatus 41a, 41b Changeover switch 42 Voltage conversion means 43 Time measuring means 44 Polarity switching means 45 Illumination means 50 External power supply

Claims (5)

原料水を貯水する貯水容器と、該貯水容器の底部に配設され、中心部材に陰極電極、陽極電極からなる一対の電極を備えた電極部材と、該電極部材に供給する電圧に関する各種制御をする制御装置とを備え、前記電極部材に電圧を印加して前記貯水容器内に貯水された原料水を改水する溶存酸素水生成装置であって、
前記制御装置は、
外部電源から供給された交流電圧を直流電圧に変換する電圧変換手段と、
予め設定された前記電極部材の各電極に供給する前記直流電圧の極性を切り替えるための切替時間を計時し、該切替時間を計時すると、この計時に応じた切替情報を出力する計時手段と、
該計時手段から出力された切替情報に基づき前記電極部材の各電極に供給する電圧を切り替えて前記各電極の極性を逆転させる極性切替手段と、
を備えて構成されることを特徴とする溶存酸素水生成装置。
A water storage container that stores raw water, an electrode member that is disposed at the bottom of the water storage container and includes a pair of electrodes that are a cathode electrode and an anode electrode as a central member, and various controls relating to the voltage supplied to the electrode member A dissolved oxygen water generator that applies a voltage to the electrode member to reform the raw water stored in the water storage container,
The controller is
Voltage conversion means for converting an AC voltage supplied from an external power source into a DC voltage;
Measuring a switching time for switching the polarity of the DC voltage to be supplied to each electrode of the electrode member set in advance, and measuring the switching time, a timing means for outputting switching information according to the timing;
Polarity switching means for switching the voltage supplied to each electrode of the electrode member based on the switching information output from the time measuring means to reverse the polarity of each electrode;
A device for generating dissolved oxygen water, comprising:
前記電極部材は、前記各電極が前記中心部材を中心として一方が時計方向に、他方が半時計方向に、それぞれ所定径を有しながら螺旋状に巻回するような形状で形成され、且つ、前記各電極は互いに接触しないよう前記中心部材の鉛直方向に対して前記各電極の位置が上下になるよう配設されていることを特徴とする請求項1記載の溶存酸素水生成装置。 The electrode member is formed in such a shape that each electrode is spirally wound with a predetermined diameter, one in the clockwise direction and the other in the counterclockwise direction around the central member, and The dissolved oxygen water generating apparatus according to claim 1, wherein the electrodes are arranged so that the positions of the electrodes are up and down with respect to the vertical direction of the central member so as not to contact each other. 前記貯水容器は着脱可能な容器蓋を備え、該容器蓋には前記電極部材によって前記貯水容器内の原料水が改水された際に発生する水素ガスを外部に放出するための通気孔が形成されていることを特徴とする請求項1または2記載の溶存酸素水生成装置。 The water storage container includes a detachable container lid, and the container lid is formed with a vent hole for releasing hydrogen gas generated when the raw water in the water storage container is reformed by the electrode member. The dissolved oxygen water generator according to claim 1 or 2, wherein the dissolved oxygen water generator is provided. 前記計時手段が計時する切替時間を少なくとも10分以内にすることを特徴とする請求項1〜3の何れかに記載の溶存酸素水生成装置。 The dissolved oxygen water generating apparatus according to any one of claims 1 to 3, wherein a switching time measured by the time measuring means is set to at least 10 minutes. さらに、前記貯水容器内を照明する照明手段を所要位置に配設したことを特徴とする請求項1〜4の何れかに記載の溶存酸素水生成装置。 Furthermore, the dissolved oxygen water production | generation apparatus in any one of Claims 1-4 which has arrange | positioned the illumination means which illuminates the inside of the said water storage container in a required position.
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JP2012525504A (en) * 2009-04-28 2012-10-22 エレクトロリティック オゾン インコーポレイテッド Disposable cartridge for electrolyzer
WO2014125521A1 (en) * 2013-02-18 2014-08-21 株式会社フラックス Hydrogen water generation device
JP2014226575A (en) * 2013-05-18 2014-12-08 株式会社健康支援センター Hydrogen water generator
JP2014240049A (en) * 2013-06-12 2014-12-25 株式会社健康支援センター Portable hydrogen water generation implement

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