JP2007306840A - Functional releasing oil composition, method for producing the composition, and use of the composition - Google Patents

Functional releasing oil composition, method for producing the composition, and use of the composition Download PDF

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JP2007306840A
JP2007306840A JP2006138328A JP2006138328A JP2007306840A JP 2007306840 A JP2007306840 A JP 2007306840A JP 2006138328 A JP2006138328 A JP 2006138328A JP 2006138328 A JP2006138328 A JP 2006138328A JP 2007306840 A JP2007306840 A JP 2007306840A
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oil composition
food
release oil
oil
lecithin
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JP4571925B2 (en
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Tomoe Kato
智絵 加藤
Namiko Takahashi
菜見子 高橋
Akihito Hayashi
彰人 林
Nobutoshi Hamaguchi
展年 濱口
行植 ▲高▼
Yukitane Ko
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TSUJI SEIYU KK
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a releasing oil composition slightly emitting smoke when burned at high temperature, continuously producible, excellent in releasing property, having low permeability to dough and thereby usable for a mold for a steamed product. <P>SOLUTION: The functional releasing oil composition contains the following: (1) edible oil and fat where the content of ≤14C fatty acid as constituent fatty acid accounts for 82 wt.% or more based on the total amount of the constituent fatty acid in the oil and fat; and (2) lecithin having ≥50 wt.% of phosphatidylcholine based on the content of phospholipid, wherein the amount of the lecithin (in terms of phospholipid) accounts for 0.1-10 mass% based on the whole of the releasing oil composition. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、食品生地を、油脂を含有する離型油組成物を塗布した面と接触させ、この面上の食品生地を焼成または蒸成する時に、焼成または蒸成食品への浸透性が低い離型油組成物、それを用いる食品の製造方法、およびその製造方法で製造された食品に関する。   In the present invention, when a food dough is brought into contact with a surface to which a release oil composition containing fats and oils is applied, and the food dough on this surface is baked or steamed, the permeability to the baked or steamed food is low. The present invention relates to a release oil composition, a method for producing a food using the same, and a food produced by the method.

どら焼きやみたらし団子などのような焼き菓子は、食品生地に澱粉類や蛋白質、糖分などが含まれているので、食品生地を加熱焼成することによって製造する時に、例えば製造される焼き菓子などの焼成食品が部分的に天板や型ないしは容器に付着して天板や型ないしは容器から離れ難くなり、焼き菓子が型崩れして商品価値の低下を招く。このため、天板や型ないしは容器に離型油を塗布することが行われている。しかし、通常の離型油では焼き菓子などの焼成食品への油脂の浸透性が強いため、加工した食品が油っぽくなり、食品本来の風味以外の異味が伴うという問題があった。特にでんぷん系の焼成食品では、油の浸透が大きく焼成食品が油っぽくなり、その油っぽさが消費者に嫌われる。そのため高温で短時間で食品生地を焼成することが試みられている。高温で使用し得る離型油として、従来固形状の固形乳化脂が使用されてきた。しかし、固形乳化脂を焼成天板や型ないしは容器の表面にこすりつけながら焼成食品を連続的に製造すると、作業工程が(1)煩雑になる、(2)固形乳化脂の性能が不十分なため連続生産がとぎれ不良品が多く生じるなどの問題点が指摘されていた。   Baked confectionery such as dorayaki and mitarashi dumplings contain starches, proteins, sugars, etc. in food dough, so when producing food dough by heating and baking, for example, baked confectionery produced The baked food partially adheres to the top plate, mold, or container, making it difficult to separate from the top plate, mold, or container, and the baked confectionery loses its shape, causing a reduction in commercial value. For this reason, a release oil is applied to a top plate, a mold or a container. However, ordinary release oil has a problem that fats and oils permeate into baked foods such as baked confectionery, so that processed foods become oily and have a different taste other than the original flavor of the food. In particular, starch-based baked foods have a large oil penetration and the baked foods become oily, and the oiliness is disliked by consumers. For this reason, attempts have been made to bake food dough at a high temperature in a short time. Conventionally, solid solid emulsified fat has been used as a release oil that can be used at high temperatures. However, continuous production of baked foods while rubbing the solid emulsified fat on the baking table, mold or container surface makes the work process (1) complicated, and (2) insufficient performance of the solid emulsified fat. Problems such as continuous production being interrupted and many defective products were pointed out.

これを解決する方法として、液状の離型油を焼成天板や型ないしは容器に噴霧しながら作業を行う方法もとられているが、天板や型ないしは容器に離型油が残りそれが天板や型ないしは容器に、油ダレを生じさせたり、残った油脂が天板や型ないしは容器に粘着するなどの問題がある。この問題を解決するため、種々の液状の離型油が提案されている。例えば、構成脂肪酸組成がモノエン酸に富む油脂および中鎖飽和トリグリセライド(中鎖飽和トリアシルグリセロール)と、添加剤としてHLB7以下のポリグリセリン脂肪酸エステル、HLB7以下の蔗糖脂肪酸エステル並びにレシチン若しくはリゾレシチンを混合溶解してなる離型油組成物が知られている(特許文献1参照)。しかし、この離型油組成物では、モノエン酸に富む油脂と中鎖飽和トリアシルグリセロールに添加剤を3種類配合しなければ、離型性、発煙性が解決されないため、実用的でない。   As a method for solving this problem, there is a method in which liquid release oil is sprayed onto a baking top plate, mold or container, but the release oil remains on the top plate, mold or container, which is the top. There are problems such as causing oil sagging on the plate, mold or container, and the remaining oil or fat sticking to the top board, mold or container. In order to solve this problem, various liquid release oils have been proposed. For example, fats and oils rich in monoenoic acid and medium-chain saturated triglycerides (mixed-chain saturated triacylglycerol), polyglycerin fatty acid esters of HLB7 or less, sucrose fatty acid esters of HLB7 or less, and lecithin or lysolecithin are mixed and dissolved as additives. A release oil composition is known (see Patent Document 1). However, this release oil composition is impractical because release properties and fuming properties cannot be solved unless three types of additives are added to the fat and oil rich in monoenoic acid and medium-chain saturated triacylglycerol.

また、常温で液状の油脂に、該油脂100重量部あたりレシチンまたはレシチンと油溶性乳化剤との混合物を0.1〜30重量部加えて溶解させた離型油を、静電塗油装置のノズルから噴霧して離型油微粒子をマイナスに帯電させ、その微粒子を塗布体表面に噴出塗布することを特徴とする焼き洋菓子用離型膜の形成方法が知られている(特許文献2参照)。しかし、本特許文献に記載の方法は、静電塗油装置という特別の装置で離型油をマイナスに帯電させなければ離型性は不良となり、また風味も悪いものとなる(特許文献2の比較例3参照)。   In addition, a release oil obtained by adding 0.1 to 30 parts by weight of lecithin or a mixture of lecithin and an oil-soluble emulsifier to 100 parts by weight of the oil and fat in a liquid oil at room temperature is dissolved in a nozzle of an electrostatic oil coating apparatus. A method for forming a release film for baked confectionery is known, in which the release oil fine particles are negatively charged by spraying and spraying the fine particles onto the surface of the coated body (see Patent Document 2). However, in the method described in this patent document, if the release oil is not negatively charged by a special device called an electrostatic oiling device, the releasability is poor and the flavor is poor (see Patent Document 2). See Comparative Example 3).

一方、C6-10の脂肪酸からなる中鎖脂肪酸トリアシルグリセロールは熱安定性やスプレー性に非常に優れているが、焼成時の離型油として使用した場合、発煙を起こし使用しづらく、また加熱により揮散してしまい離型効果が継続しないという問題がある。このことから、食用油脂90〜96重量%と中鎖トリアシルグリセロール4〜10重量%との混合油脂をエステル交換した油脂にレシチンなどの分散剤を配合した離型油が知られている(例えば、特許文献3参照。)しかし、該離型油も安定性や離型性の点から離型油としては不十分である。 On the other hand, medium-chain fatty acid triacylglycerols composed of fatty acids of C 6-10 are very excellent in thermal stability and sprayability, but when used as release oils during firing, they produce smoke and are difficult to use. There is a problem that the release effect does not continue due to evaporation by heating. From this, a release oil in which a dispersant such as lecithin is blended with a fat obtained by transesterifying a mixed fat comprising 90 to 96% by weight of edible fat and 4 to 10% by weight of medium chain triacylglycerol is known (for example, However, the release oil is also insufficient as a release oil in terms of stability and releasability.

また、水分が多くても比容積が大きく、沈みのない弾力性に富み、ソフトで口溶けが良く、食味、食感の優れた蒸しケーキの製造方法では、蒸しケーキの生地についての改良がなされているものが多い(特許文献4参照)が、蒸しケーキの型に使われる離型油については殆ど検討されておらず、これは蒸しケーキの製造で解決すべき課題の1つであった。
特開平6−253738号公報 特開2000−184849号公報 特公平1−18701号公報 特開平6−133695号公報
In addition, the steamed cake dough has been improved in the method for producing a steamed cake, which has a large specific volume even with a lot of moisture, is rich in elasticity without sinking, is soft and melts well, and has a good taste and texture. There are many things (refer patent document 4), However, The mold release oil used for the type | mold of a steamed cake is hardly examined, and this was one of the problems which should be solved by manufacture of a steamed cake.
JP-A-6-2553738 JP 2000-184849 A Japanese Patent Publication No. 1-18701 JP-A-6-133695

本発明は、170℃以上の高温焼成時に発煙が少なく、特別の塗油装置を使用しなくても離型性の優れた焼成食品の連続生産を可能とする離型油組成物を提供することを目的とする。さらに食品生地の蒸成時に蒸成食品への油脂の浸透性が低く、蒸成食品の比容積、弾力性、食味、食感を優れたものにする蒸成器の型ないしは容器に使われる離型油組成物を提供することを目的とする。   The present invention provides a mold release oil composition that enables continuous production of a baked food product that emits less smoke when fired at a high temperature of 170 ° C. or higher and does not use a special oil coating device. With the goal. Furthermore, when the food dough is steamed, the fat and oil penetration into the steamed food is low, and the mold used for the steamer mold or container that makes the steamed food excellent in specific volume, elasticity, taste and texture. An object is to provide a mold oil composition.

本発明者らは、上記目的を達成すべく鋭意検討した結果、油脂の構成脂肪酸としての炭素数14以下の脂肪酸含量が、油脂中の構成脂肪酸全量に対して82%以上である食用油脂と、リン脂質含量に対するホスファチジルコリンの割合が50%以上であるレシチンとを混合して得られる離型油組成物が、上記課題を解決することを見出した。更に前記離型油組成物に食用ワックス、植物ステロール、酢酸モノグリセライドまたはクエン酸モノグリセライドなどを添加することで離型性が更に向上することを見出した。本発明者らは、さらに鋭意研究を重ねて、本発明を完成した。   As a result of intensive studies to achieve the above object, the present inventors have found that edible fats and oils having a fatty acid content of 14 or less carbon atoms as constituent fatty acids of the fats and oils are 82% or more based on the total amount of constituent fatty acids in the fats and oils, It has been found that a release oil composition obtained by mixing with lecithin in which the ratio of phosphatidylcholine to phospholipid content is 50% or more solves the above problems. Furthermore, it has been found that the releasability is further improved by adding edible wax, plant sterol, acetic acid monoglyceride or citric acid monoglyceride to the releasing oil composition. The inventors of the present invention made further studies and completed the present invention.

すなわち、本発明は、
[1](1)油脂の構成脂肪酸としての炭素数14以下の脂肪酸含量が、油脂中の構成脂肪酸全量に対して82%以上である食用油脂と、
(2)リン脂質含量に対するホスファチジルコリンの割合が50%以上であるレシチンとを含有し、
前記レシチンの量(リン脂質換算)が離型油組成物全体に対して0.1〜10質量%であることを特徴とする離型油組成物。
[2]さらに、食用ワックス、植物ステロールおよび有機酸モノグリセライドより成る群より選ばれる少なくとも1種を離型油組成物全体に対して0.01〜5質量%含有する上記[1]に記載の離型油組成物、
[3]離型剤として請求項1または2に記載の離型油組成物を、天板、型または容器と食品生地が接触する天板、型または容器の面に塗布し、離型油組成物が塗布された天板、型または容器を用いて食品生地を焼成または蒸成することを特徴とする食品の製造方法、
[4]上記[3]に記載の製造方法で製造された食品、
[5]食品が焼団子である上記[4]に記載の食品、
[6]食品がどら焼きである上記[4]に記載の食品、および
[7]食品が蒸しケーキである上記[4]に記載の食品、
に関する。
That is, the present invention
[1] (1) Edible oil and fat having a fatty acid content of 14 or less carbon atoms as a constituent fatty acid of the oil and fat is 82% or more with respect to the total amount of the constituent fatty acid in the oil and fat;
(2) containing lecithin in which the ratio of phosphatidylcholine to phospholipid content is 50% or more,
The release oil composition, wherein the amount of lecithin (in terms of phospholipid) is 0.1 to 10% by mass with respect to the entire release oil composition.
[2] The release according to [1] above, further containing 0.01 to 5% by mass of at least one selected from the group consisting of edible wax, plant sterol and organic acid monoglyceride with respect to the entire release oil composition. Mold oil composition,
[3] The release oil composition according to claim 1 or 2 as a release agent is applied to the top plate, mold or container surface where the food dough contacts the top plate, mold or container, and the release oil composition A method for producing a food, characterized in that the food dough is baked or steamed using a top plate, mold or container to which the product is applied,
[4] A food produced by the production method according to [3] above,
[5] The food according to [4] above, wherein the food is a grilled dumpling,
[6] The food according to [4] above, wherein the food is Dorayaki, and [7] the food according to [4] above, wherein the food is a steamed cake,
About.

本発明に係る離型油組成物は、食品生地を約170℃以上の高温で焼成して製造される焼成食品を連続して生産することを可能ならしめる。さらに本発明に係る離型油組成物は、該離型油組成物を使用して焼成して製造された焼成食品において、該焼成食品への油脂の浸透性が少なく、焼成食品の風味を向上させ得る。また、前記焼成食品への油脂の浸透を抑える効果は、比較的低温(約90〜120℃)で食品生地を例えば蒸成などの加熱方法で加熱して製造される例えば蒸しケーキのような食品においても得られるので、本発明に係る離型油組成物は、比較的低温で製造される例えば蒸成食品などにおける型ないしは容器の離型油組成物としても使用することができる。本発明に係る離型油組成物を使用して製造された焼成または蒸成食品は、焼成または蒸成時に生地への油脂の浸透性が低いことから、比容積が大きく、中心部が沈み難く、弾力性に富む。   The release oil composition according to the present invention makes it possible to continuously produce a baked food produced by baking a food dough at a high temperature of about 170 ° C. or higher. Furthermore, the release oil composition according to the present invention is a baked food produced by baking using the release oil composition, which has less oil and fat permeability to the baked food and improves the flavor of the baked food. Can be. In addition, the effect of suppressing the penetration of fats and oils into the baked food is produced by heating the food dough at a relatively low temperature (about 90 to 120 ° C.) by a heating method such as steaming, for example, a food such as steamed cake Therefore, the release oil composition according to the present invention can be used as a release oil composition for molds or containers in, for example, steamed foods produced at a relatively low temperature. The baked or steamed food produced using the release oil composition according to the present invention has a large specific volume and is difficult to sink due to the low permeability of fats and oils to the dough during baking or steaming. , Rich in elasticity.

また、本発明に係る離型油組成物は、油脂の構成脂肪酸としての炭素数14以下の脂肪酸含量が油脂中の構成脂肪酸全量に対して82%以上である食用油脂を主体としている。本発明の離型油組成物は、発煙点が低く、揮発性であるので、天板や型ないしは容器に油が残り液ダレを起こし難く、また残った油脂が天板や型ないしは容器に粘着しにくい。また、本発明の組成物に、前記主体とする食用油脂にリン脂質含量に対するホスファチジルコリンの割合が50%以上であるレシチンが配合されていると、当該組成物の発煙点が低いにもかかわらず組成物の発煙を抑制できる。
本発明によれば、静電塗油装置などのような特別の塗油装置を使用しなくても、通常の噴霧や刷毛または布などによって本発明の離型油組成物を天板や型ないしは容器へ塗布でき、かつ、該天板や型ないしは容器において上記した液ダレや油脂の粘着あるいは発煙が抑制され、天板や型ないしは容器からの分離のよい焼成または蒸成食品が連続的に製造され得る。
The release oil composition according to the present invention is mainly composed of edible fats and oils having a fatty acid content of 14 or less carbon atoms as constituent fatty acids of the fats and oils of 82% or more based on the total amount of constituent fatty acids in the fats and oils. Since the release oil composition of the present invention has a low smoke point and is volatile, oil remains on the top plate, mold or container, and it is difficult for liquid to drip, and the remaining oil or fat adheres to the top plate, mold or container. Hard to do. In addition, when the composition of the present invention contains lecithin in which the ratio of phosphatidylcholine to phospholipid content is 50% or more in the edible fat or oil as the main component, the composition has a low smoke point. Smoke of things can be suppressed.
According to the present invention, the release oil composition of the present invention can be applied to the top plate, mold, or the like by ordinary spraying, brushing, cloth, or the like without using a special oiling device such as an electrostatic oiling device. A baking or steamed food that can be applied to a container and that prevents sticking or fuming of the above-mentioned sag or oil or fat in the top plate, mold or container, and is well separated from the top plate, mold or container is continuously produced. Can be done.

本発明に係る離型油組成物は、少なくとも(1)油脂の構成脂肪酸としての炭素数14以下の脂肪酸(以下、炭素数14以下の脂肪酸と略記することもある。)含量が油脂中の構成脂肪酸全量に対して約82%以上である食用油脂(以下、炭素数14以下の脂肪酸が約82%以上である食用油脂と略記する。)と(2)リン脂質含量に対するホスファチジルコリンの割合が約50%以上であるレシチンとを含有する。   In the release oil composition according to the present invention, the content of at least (1) a fatty acid having 14 or less carbon atoms (hereinafter sometimes abbreviated as a fatty acid having 14 or less carbon atoms) as a constituent fatty acid of the fat or oil. Edible fats and oils that are about 82% or more with respect to the total amount of fatty acids (hereinafter abbreviated as edible fats and oils with fatty acids having 14 or less carbon atoms are about 82% or more) and (2) the ratio of phosphatidylcholine to phospholipid content is about 50 % Of lecithin.

油脂を構成する炭素数14以下の脂肪酸としては、炭素数が14以下の脂肪酸であれば、特に限定はされず、例えば直鎖飽和脂肪酸、直鎖不飽和脂肪酸、分枝鎖飽和脂肪酸または分枝鎖不飽和脂肪酸が挙げられ、具体的には、例えば酪酸、カプロン酸(n−ヘキサン酸)、カプリル酸(n−オクタン酸)、ラウリン酸、ミリスチン酸、イソ酪酸又はミリストレイン酸などが挙げられるが、直鎖飽和脂肪酸が好ましい。油脂を構成するこれら脂肪酸は、1種単独であってもよく、2種以上の混合物であってもよい。   The fatty acid having 14 or less carbon atoms constituting the fat is not particularly limited as long as the fatty acid has 14 or less carbon atoms, and for example, a straight chain saturated fatty acid, a straight chain unsaturated fatty acid, a branched chain saturated fatty acid, or a branched chain. Examples include chain unsaturated fatty acids, and specific examples include butyric acid, caproic acid (n-hexanoic acid), caprylic acid (n-octanoic acid), lauric acid, myristic acid, isobutyric acid, and myristoleic acid. However, linear saturated fatty acids are preferred. These fatty acids constituting the fats and oils may be used alone or in a mixture of two or more.

炭素数14以下の脂肪酸が約82%以上である食用油脂としては、食用に適する油脂であって、該油脂中の構成脂肪酸全量に対して炭素数14以下の脂肪酸を約82%以上含むものであれば特に限定されず、単一の食用に適する油脂であってもよく、2種類以上の食用に適する油脂を組み合わせて混合して炭素数14以下の脂肪酸が約82%以上である食用油脂としたものであってもよい。前記2種類以上の食用に適する油脂を組み合わせた食用油脂としては、例えば、炭素数14以下の脂肪酸が約82%以上である食用に適する油脂を2種類以上組み合わせて調製された食用油脂、または炭素数14以下の脂肪酸含量が油脂中の構成脂肪酸全量に対して約82%未満の食用に適する油脂と、炭素数14以下の脂肪酸含量が油脂中の構成脂肪酸全量に対して高い(約82%以上、好ましくは約90%以上)食用に適する油脂(例えば、中鎖トリアシルグリセロールなど)とを組み合わせて調製された、炭素数14以下の脂肪酸が約82%以上である食用油脂などが挙げられる。2種類以上の組み合わせに使用し得る食用に適する油脂としては、例えばオリーブ油、キャノーラ油、米油、米ぬか油、ゴマ油、サフラワー油、大豆油、大豆白紋油、コーン油、パーム油、パーム核油、米糠油、菜種油、菜種白絞油、ひまわり油、綿実油、やし油、落花生油、グレープシード油またはしそ油などの植物性油脂;牛脂、豚脂、魚油、乳脂またはラードなどの動物性油脂;中鎖トリアシルグリセロール;あるいはそれらを分別処理したもの、水素添加処理したもの、さらに前記食用油脂はエステル結合した脂肪酸を同一油脂,あるいは2種類以上を任意に組み合わせて混和した油脂とエステル交換処理した加工油脂などが挙げられる。これら食用に適する油脂の中でも、中鎖トリアシルグリセロールと、ヤシ油またはパーム核油との組み合わせが特に好ましい。炭素数14以下の脂肪酸が約82%以上である食用油脂を離型油組成物に使用すると、塗布された天板や型ないしは容器に該食用油脂が残らず、繰り返し焼成食品を製造しても天板や型ないしは容器が黒化せず、良好な離型性を維持できる。   Edible fats and oils having about 14% or more fatty acids having 14 or less carbon atoms are edible oils and fats and contain about 82% or more fatty acids having 14 or less carbon atoms with respect to the total amount of constituent fatty acids in the fats and oils. If it is not specifically limited, it may be a single edible fat and oil, and a combination of two or more edible fats and oils and a mixture of edible fats and fatty acids having 14 or less carbon atoms with about 82% or more It may be what you did. Examples of edible fats and oils combining two or more types of edible fats and oils include, for example, edible fats and oils prepared by combining two or more types of edible fats and oils having about 14% or more of fatty acids having 14 or less carbon atoms, or carbon Fats and oils suitable for food having a fatty acid content of several 14 or less and less than about 82% with respect to the total amount of constituent fatty acids in the fat and oil, and fatty acids with 14 or less carbon atoms being higher than the total amount of constituent fatty acids in the fat and oil (about 82% or more (Preferably about 90% or more) edible fats and oils prepared by combining edible fats and oils (for example, medium chain triacylglycerol and the like) and having about 14% or more fatty acids having 14 or less carbon atoms. Examples of edible oils and fats that can be used in two or more combinations include olive oil, canola oil, rice oil, rice bran oil, sesame oil, safflower oil, soybean oil, soybean white coat oil, corn oil, palm oil, and palm kernel. Vegetable oils such as oil, rice bran oil, rapeseed oil, rapeseed white squeezed oil, sunflower oil, cottonseed oil, palm oil, peanut oil, grape seed oil or perilla oil; animal properties such as beef fat, pork fat, fish oil, milk fat or lard Fats and oils; Medium chain triacylglycerols; or those subjected to fractionation treatment, hydrogenation treatment, and the above edible fats and oils are the same fats and fats mixed with any combination of two or more types of ester-bonded fatty acids. Processed fats and oils etc. processed are mentioned. Among these edible fats and oils, a combination of medium chain triacylglycerol and coconut oil or palm kernel oil is particularly preferable. When edible fats and oils having about 14% or less fatty acids having 14 or less carbon atoms are used in the release oil composition, the edible fats and oils do not remain on the coated top plate, mold or container, and repeatedly baked foods can be produced. The top plate, mold or container is not blackened and good releasability can be maintained.

前記中鎖トリアシルグリセロールとしては、1分子のグリセロールに、3分子の炭素数約4〜12、好ましくは約6〜12の脂肪酸(例えば、カプロン酸、カプリル酸、カプリン酸、ラウリン酸など)がエステル結合したものが挙げられる。   As the medium chain triacylglycerol, one molecule of glycerol includes three molecules of fatty acid having about 4 to 12 carbon atoms, preferably about 6 to 12 carbon atoms (for example, caproic acid, caprylic acid, capric acid, lauric acid, etc.). Examples include ester-bonded ones.

また、炭素数14以下の脂肪酸が約82%以上である食用油脂には長鎖トリアシルグリセロールが含有されていてもよい。長鎖トリアシルグリセロールとしては、1分子のグリセロールに、3分子の炭素数約16〜18の脂肪酸(例えば、パルミチン酸、ステアリン酸、オレイン酸、リノール酸など)がエステル結合したものが挙げられる。   Moreover, long-chain triacylglycerols may be contained in edible fats and oils whose fatty acid having 14 or less carbon atoms is about 82% or more. Examples of the long-chain triacylglycerol include those in which one molecule of glycerol is ester-bonded with three molecules of a fatty acid having about 16 to 18 carbon atoms (for example, palmitic acid, stearic acid, oleic acid, linoleic acid, etc.).

本発明に使用される食用油脂の構成脂肪酸は、基準油脂分析試験法 2.4.1.2-1996 メチルエステル化法(三フッ化ホウ素メタノール法)の記載に従いガスクロマトグラフ法により分析できる。本発明における炭素数14以下の脂肪酸の%は、前記基準油脂分析試験法 2.4.1.2-1996に従い得られたクロマトグラム上の脂肪酸の総ピーク面積に対する炭素数14以下の脂肪酸のピーク面積百分率である。 The constituent fatty acids of edible fats and oils used in the present invention can be analyzed by gas chromatography according to the description in the standard fat analysis method 2.4.1.2 -1996 methyl esterification method (boron trifluoride methanol method). In the present invention, the percentage of fatty acids having 14 or less carbon atoms is the peak of fatty acids having 14 or less carbon atoms with respect to the total peak area of fatty acids on the chromatogram obtained according to the above standard fat analysis method 2.4.1.2 -1996. Area percentage.

本発明に係る離型油組成物に使用されるレシチンは、リン脂質(例えばホスファチジルコリン、ホスファチジルエタノールアミン、ホスファチジルイノシトール、ホスファチジン酸など)含量のうちホスファチジルコリンの割合が約50%以上、好ましくは約60〜100%であるレシチンである。本発明で使用されるレシチンは、好ましくはリン脂質としてアセトン不溶物を60質量%以上含む。前記レシチンとしては、例えば、ナタネレシチンや大豆レシチンなどの植物性レシチン、あるいは卵黄由来の卵黄レシチンなどが挙げられる。また前記レシチンを、例えば溶媒分画などによりリン脂質含量に対するホスファチジルコリンの割合を約50%以上に、好ましくは約60〜100%となるよう調製されたものも本発明に使用されるレシチンに含まれる。溶媒分画における溶媒としては、例えば、エタノール、プロパノールまたはイソプロパノールなどが挙げられる。溶媒分画は、公知の方法で行うことができる、例えばエタノール分画の場合、レシチンと約2〜10倍量のエタノールとを接触させエタノール可溶部を遠心分離などで分離し、エタノール不溶部にエタノールを加え同様に両者を接触させ、遠心分離する工程を約2〜5回繰り返した後、エタノール可溶部を合わせてエタノールを留去する方法などが挙げられる。この方法によってレシチンにおけるリン脂質の含量に対するホスファチジルコリンの割合を増加させることができる。接触方法としては、攪拌、振とうなどが挙げられる。卵黄レシチンは、除蛋白が行われたものが好ましい。卵黄レシチンを除蛋白することにより、焼成または蒸成時に離型油による悪臭を抑制することができる。除蛋白は、公知の方法に従いまたは公知の方法に準じて行うことができる。レシチンにおけるリン脂質含量に対するホスファチジルコリンの割合が約50%以上の場合に、本発明に係る離型油組成物の発煙が抑制され得る。   The lecithin used in the release oil composition according to the present invention has a phosphatidylcholine content of about 50% or more, preferably about 60 to more than phospholipid (eg, phosphatidylcholine, phosphatidylethanolamine, phosphatidylinositol, phosphatidic acid). It is lecithin which is 100%. The lecithin used in the present invention preferably contains 60% by mass or more of acetone-insoluble matter as a phospholipid. Examples of the lecithin include plant lecithins such as rapeseed lecithin and soybean lecithin, or egg yolk lecithin derived from egg yolk. In addition, the lecithin prepared by using the lecithin so that the ratio of the phosphatidylcholine to the phospholipid content is about 50% or more, preferably about 60 to 100%, for example, by solvent fractionation is also included in the lecithin used in the present invention. . Examples of the solvent in the solvent fraction include ethanol, propanol, and isopropanol. Solvent fractionation can be performed by a known method. For example, in the case of ethanol fractionation, lecithin and about 2 to 10 times the amount of ethanol are brought into contact with each other, and the ethanol soluble part is separated by centrifugation or the like, and the ethanol insoluble part is separated. There is a method of adding ethanol to the same and contacting them in the same manner and centrifuging them about 2 to 5 times, and then combining the ethanol soluble portions to distill off the ethanol. By this method, the ratio of phosphatidylcholine to phospholipid content in lecithin can be increased. Examples of the contact method include stirring and shaking. Egg yolk lecithin is preferably subjected to deproteinization. By deproteinizing egg yolk lecithin, malodor caused by release oil during firing or steaming can be suppressed. Deproteinization can be performed according to a known method or according to a known method. When the ratio of the phosphatidylcholine to the phospholipid content in lecithin is about 50% or more, the smoke generation of the release oil composition according to the present invention can be suppressed.

本発明に係る離型油組成物は、ホスファチジルコリンを約50%以上含むレシチンを離型油組成物全体に対して約0.1〜10質量%含有せしめることが好ましく、約0.2〜6質量%含有せしめることがより好ましく、約0.3〜4質量%がさらに好ましい。該レシチンの含量が0.1質量%未満では離型性が悪く、また焼成または蒸成時における離型油組成物からの発煙量を抑えることができない。また、10質量%を超える量のレシチンを配合すると、焼成または蒸成に用いる天板上や型ないしは容器に残る油脂量がふえ、風味に悪影響を及ぼす。
なお、本発明において前記レシチン量はアセトン不溶物であるリン脂質換算の量を指し、該リン脂質量は日本油脂化学会編「基準油脂分析試験法 5.3.3.1−86 リン脂質リン組成」に記載の方法により測定することができる。また、本発明において、ホスファチジルコリンの割合は、基準油脂分析試験法 4.3.3.1-1996 リン脂質組成(薄層クロマトグラフ法)に従い分離定量したレシチンに含まれる各リン脂質に由来するリンの総リンに対するホスファチジルコリンに由来するリンの百分率をいう。
The release oil composition according to the present invention preferably contains about 0.1 to 10% by mass of lecithin containing about 50% or more of phosphatidylcholine with respect to the entire release oil composition, and about 0.2 to 6% by mass. % Is more preferable, and about 0.3 to 4% by mass is more preferable. When the lecithin content is less than 0.1% by mass, the releasability is poor, and the amount of smoke emitted from the release oil composition during firing or steaming cannot be suppressed. In addition, when lecithin in an amount exceeding 10% by mass is blended, the amount of fats and oils remaining on the top plate, mold or container used for baking or steaming increases, which adversely affects the flavor.
In the present invention, the amount of lecithin refers to an amount in terms of phospholipid, which is an acetone insoluble matter, and the amount of phospholipid is “standard oil analysis test method 5.3.3.1-86 phospholipid phospholipid edited by Japan Oil and Fat Chemical Society”. It can be measured by the method described in “Composition”. Further, the phosphorus in the present invention, the proportion of phosphatidylcholine is derived from the phospholipids contained in the separation and determination lecithins accordance with the standards fats analyzing test method 4.3.3.1 -1996 phospholipid composition (thin layer chromatography) The percentage of phosphorus derived from phosphatidylcholine relative to total phosphorus.

本発明に係る離型油組成物には、さらに食用ワックス、植物ステロールまたは有機酸モノグリセライドなど(以下、これらを食用ワックスなどということもある。)が配合されることが好ましい。前記食用ワックスなどが配合されることにより、離型性を更に高めることができる。これら食用ワックスなどは、焼成または蒸成される食品の物性、風味に合わせて適宜選択されるのが好ましい。食用ワックスなどの添加量は本発明に係る離型油組成物に対して約0.01〜5質量%とするのが好ましい。約0.01質量%未満では離型性の向上に役立たず、約5質量%を超える量では焼成または蒸成される食品の風味が悪くなるなどの悪影響を及ぼす。これら食用ワックスなどは、1種単独でも2種以上を混合して配合してもよい。   The release oil composition according to the present invention preferably further contains edible wax, plant sterol or organic acid monoglyceride (hereinafter sometimes referred to as edible wax). By incorporating the edible wax and the like, the releasability can be further enhanced. These edible waxes are preferably selected as appropriate in accordance with the physical properties and flavor of the baked or steamed food. The amount of edible wax added is preferably about 0.01 to 5% by mass relative to the release oil composition according to the present invention. If it is less than about 0.01% by mass, it does not help to improve the releasability, and if it exceeds about 5% by mass, there is an adverse effect such that the flavor of the baked or steamed food becomes worse. These edible waxes may be used alone or in admixture of two or more.

前記食用ワックスとしては、特に限定されず、動物性ワックスまたは植物性ワックスあるいはそれらの混合ワックスのいずれであってもよく、例えばカルナウバロウ、ライスワックス、キャンデリラロウ、木ロウまたは蜜蝋などが好ましく挙げられ、ライスワックスがより好ましい。
前記植物ステロールとしては、特に限定されず、例えばスチグマステロール、シトステロールまたはカンペステロールなどが好ましく挙げられる。
前記有機酸モノグリセライドとしては、例えば酢酸モノグリセライドまたはクエン酸モノグリセライドが好ましく挙げられる。
The edible wax is not particularly limited, and may be any of animal wax, vegetable wax, or mixed wax thereof. For example, carnauba wax, rice wax, candelilla wax, wood wax, beeswax and the like are preferable. Rice wax is more preferable.
It does not specifically limit as said plant sterol, For example, stigmasterol, sitosterol, campesterol etc. are mentioned preferably.
Preferred examples of the organic acid monoglyceride include acetic acid monoglyceride and citric acid monoglyceride.

本発明に係る離型油組成物は、自体公知の方法で製造することができる。具体的には、上記した食用油脂およびレシチン、さらに所望により食用ワックス、植物ステロール、または有機酸モノグリセライドなどを、例えば攪拌機などで均一に攪拌することにより製造できる。   The release oil composition according to the present invention can be produced by a method known per se. Specifically, the above-described edible oil and fat and lecithin, and further, if desired, edible wax, plant sterol, or organic acid monoglyceride can be produced by uniformly stirring, for example, with a stirrer.

本発明の離型油組成物を、天板、型または容器と食品生地が接触する天板、型または容器の面に塗布し、離型油組成物が塗布された天板、型または容器を用いて食品生地を焼成または蒸成することにより、焼成または蒸成された食品を製造することができる。離型油組成物の塗布の方法としては、特に限定されず噴霧または刷毛や布などによる離型油組成物の上記面への塗布などが挙げられる。前記食品としては、澱粉や蛋白質などを含み焼成または蒸成された食品であれば特に限定されないが、例えば小麦粉や米粉などの穀物粉あるいはもち米などの穀物に卵、砂糖および水などを配合し、混和して、これを焼成または蒸成することによって製造される食品、例えば焼き団子、どら焼き、ホットケーキ、カステラまたはパンなどの焼成食品または蒸しケーキ、蒸しパンなどの蒸成食品などが好ましく挙げられる。
本発明に係る離型油組成物を食品の焼成に用いる場合、特に約170℃以上の高温で焼成する食品に好ましく使用することでき、焼成食品の連続生産が可能になる。
The release oil composition of the present invention is applied to the top plate, mold or container surface where the top plate, mold or container and food dough contact, and the top plate, mold or container coated with the release oil composition is applied. The baked or steamed food can be manufactured by baking or steaming the food dough. The method for applying the release oil composition is not particularly limited, and examples thereof include application to the surface of the release oil composition by spraying or brush or cloth. The food is not particularly limited as long as it is a baked or steamed food containing starch, protein, etc. For example, grains such as wheat flour and rice flour, or grains such as glutinous rice are mixed with eggs, sugar and water. Foods produced by mixing and baking or steaming, such as grilled dumplings, dorayaki, baked foods such as hot cakes, castella or bread, steamed cakes, steamed foods such as steamed bread, etc. are preferred Can be mentioned.
When the release oil composition according to the present invention is used for baking foods, it can be preferably used particularly for foods baked at a high temperature of about 170 ° C. or higher, and continuous production of baked foods becomes possible.

以下に本発明のいくつかの実施例を示し、本発明を更に詳細に説明するが、本発明はそのような実施例の記載によって何らの制限を受けるものではない。また、本発明には以下の実施例の他にも、更には上記の具体的記述以外にも、本発明の主旨を逸脱しない限りにおいて、当業者の知識に基づいて種々の変更、修正、改良を加え得るものを含む。   Hereinafter, the present invention will be described in more detail with reference to some examples of the present invention. However, the present invention is not limited by the description of such examples. In addition to the following examples, in addition to the above specific description, the present invention includes various changes, modifications, and improvements based on the knowledge of those skilled in the art without departing from the spirit of the present invention. Including those that can be added.

試験例1 油脂およびレシチン含有油脂の加熱試験
銅板(厚さ10mm)を185〜195℃になるまで加熱し、下記の油脂およびレシチンを表1の割合で混合して調製した離型油組成物を3分に1回の間隔で塗布し、この操作を30分続け、30分後の銅板の状態や発煙性を確認した。
Test Example 1 Heating test of fats and oils containing lecithin A release oil composition prepared by heating a copper plate (thickness 10 mm) until it reaches 185 to 195 ° C. and mixing the following fats and fats and lecithins in the ratios shown in Table 1. The coating was applied at intervals of once every 3 minutes, and this operation was continued for 30 minutes. The state of the copper plate and smoke generation after 30 minutes were confirmed.

油脂(*は炭素数14以下の脂肪酸含量を示す):
ナタネ油(0%):なたね白絞油、辻製油株式会社製
パーム油(1.4%):PWLNS(N)、不二製油株式会社製
パーム核油(68.3%):精製パーム核油、不二製油株式会社製
ヤシ油(79.4%):精製ヤシ油、不二製油株式会社製
中鎖トリアシルグリセロール(MCT)(100%):スコレー64HG、日清オイリオグループ株式会社製
Fats and oils (* indicates a fatty acid content of 14 or less carbon atoms):
Rapeseed oil (0% * ): rapeseed white oil, Palm oil (1.4% * ) manufactured by Sakai Seisaku Co., Ltd .: PWLNS (N), palm kernel oil (68.3% * ) manufactured by Fuji Oil Co., Ltd. : Refined palm kernel oil, Fuji Oil Co., Ltd. palm oil (79.4% * ): Refined palm oil, Fuji Oil Co., Ltd. medium chain triacylglycerol (MCT) (100% * ): Scoley 64HG, Japan Made by Kiyo Oilio Group

レシチン:
大豆レシチン:SLP−ペースト、辻製油株式会社製[アセトン不溶物(リン脂質含量)62質量%(リン脂質に対するホスファチジルコリンの割合:28%)]
大豆分画レシチンPC35:SLP−PC35、辻製油株式会社製[アセトン不溶物(リン脂質含量):65質量%(リン脂質に対するホスファチジルコリンの割合:70%)]
結果を表1に記す。
lecithin:
Soy lecithin: SLP-paste, manufactured by Sakai Oil Co., Ltd. [acetone insoluble matter (phospholipid content) 62% by mass (ratio of phosphatidylcholine to phospholipid: 28%)]
Soy fraction lecithin PC35: SLP-PC35, manufactured by Sakai Oil Co., Ltd. [acetone insoluble matter (phospholipid content): 65% by mass (ratio of phosphatidylcholine to phospholipid: 70%)]
The results are shown in Table 1.

炭素数14以下の脂肪酸が約82%以上である食用油脂とリン脂質含量に対するホスファチジルコリンの割合が50%以上である大豆分画レシチンPC35(SLP−PC35)を含有する離型油組成物では、高温での焼成後も銅板は黒化せず、油を塗付しないものと変わらなかった(実施例1、2)。また、加熱による油脂からの発煙もほとんど認められなかった(実施例1、2)。一方大豆分画レシチンPC35(SLP−PC35)を含まない油脂では銅板の状態は良好であるが、MCT単独より少ないが発煙性が認められた(比較例1、2)。一方、MCTを等量混合したナタネ油またはパーム油を含み、炭素数14以下の脂肪酸含量は50%前後である油脂を含み、大豆分画レシチンPC35(SLP−PC35)を含まない離型油組成物では、銅板に黒茶色の膜が生じ黒化した(比較例3、4)。表1には示していないが、ナタネ油またはパーム油単独では黒化がさらに著しかった。いずれにしろこれらの油脂では高温での焼成食品の連続生産が不可である。また、焼成後の銅板の状態が良好な実施例1、2の大豆分画レシチンPC35(SLP−PC35)の代わりに通常の大豆レシチンを加えたものでは黒化は起こらないが銅板上に炭化した離型油組成物の粕が残り、連続生産に不適であった(比較例5,6)。なお発煙性もMCT単独の場合よりも低いが、実施例1または2より発煙性は高かった。
炭素数14以下の脂肪酸含量が79.4%のヤシ油に分画レシチンPC35(SLP−PC35)を添加した離型油組成物(比較例7)では、離型油組成物の発煙性は抑えられたが、銅板が黒化し、焼成食品の高温での連続生産が困難となった。
In a release oil composition containing edible fats and oils whose fatty acid having 14 or less carbon atoms is about 82% or more and soybean fraction lecithin PC35 (SLP-PC35) whose ratio of phosphatidylcholine to phospholipid content is 50% or more, The copper plate was not blackened even after baking at the same temperature as that in which no oil was applied (Examples 1 and 2). Moreover, almost no fuming from the fats and oils by heating was recognized (Examples 1 and 2). On the other hand, although the state of the copper plate was good in the fats and oils not containing soybean fraction lecithin PC35 (SLP-PC35), although it was less than MCT alone, smoke generation was observed (Comparative Examples 1 and 2). On the other hand, a release oil composition containing rapeseed oil or palm oil mixed with an equal amount of MCT, containing fats and oils having a carbon number of 14 or less and a fat content of around 50%, and not containing soybean fraction lecithin PC35 (SLP-PC35) In the product, a black brown film was formed on the copper plate and blackened (Comparative Examples 3 and 4). Although not shown in Table 1, blackening was even more marked with rapeseed oil or palm oil alone. In any case, continuous production of baked foods at high temperatures is not possible with these fats and oils. In addition, when the soy fraction lecithin PC35 (SLP-PC35) of Examples 1 and 2 in which the state of the copper plate after firing was good, blackening did not occur but carbonized on the copper plate. The mold release oil composition remained so that it was unsuitable for continuous production (Comparative Examples 5 and 6). In addition, although the fuming property was lower than that of MCT alone, the fuming property was higher than that of Example 1 or 2.
In the release oil composition (Comparative Example 7) in which fractionated lecithin PC35 (SLP-PC35) is added to coconut oil having a fatty acid content of 14 or less carbon atoms and 79.4%, the smoke release property of the release oil composition is suppressed. However, the copper plate turned black, making it difficult to continuously produce baked foods at high temperatures.

試験例2 離型油組成物の離型性、風味試験
試験例1と同じく、銅板を185〜195℃になるまで加熱し、離型油組成物を銅板に塗付後、該銅板に団子をのせて10秒間焼いた。この操作を10分間繰り返し行い、団子の臭い、風味、離型性を調べた。本発明の実施例1の離型油組成物に以下の添加物:
ライスワックス:SC−7001、セラリカ野田株式会社製
植物ステロール(スチグマステロール、シトステロール及びカンベステロールの混合物):辻製油株式会社製
酢酸モノグリセライド:ポエムG002、理研ビタミン株式会社製(酢酸モノグリセライドラウリン系)
クエン酸モノグリセライド:ポエムK−37V、理研ビタミン株式会社製(クエン酸モノグリセライドオレイン系)
を表2の配合量で加えた離型油組成物(実施例3〜6)を使用して、同様に前記操作を行った。
また、比較例として、上記比較例1の離型油組成物、およびヤシ油(脂肪酸含量:79.4%)99質量部と大豆分画レシチンPC35(SLP−PC35)1質量部の割合で混合した離型油組成物(比較例7)を使用した。
評価は以下の基準:
◎:最も良好、
○:良好、
△:普通、
×:劣る
の4段階で示した。
結果を表2に記す。
Test Example 2 Releasability and Flavor Test of Mold Release Oil Composition As in Test Example 1, the copper plate was heated to 185 to 195 ° C., the release oil composition was applied to the copper plate, and dumpling was applied to the copper plate. Baked for 10 seconds. This operation was repeated for 10 minutes, and the odor, flavor and releasability of the dumpling were examined. The following additives are added to the release oil composition of Example 1 of the present invention:
Rice wax: SC-7001, Celerica Noda Co., Ltd. plant sterol (mixture of stigmasterol, sitosterol and canvesterol): Sakai Oil Co., Ltd. Acetic acid monoglyceride: Poem G002, Riken Vitamin Co., Ltd. (monoglyceride lauric acetate system)
Citric acid monoglyceride: Poem K-37V, manufactured by Riken Vitamin Co., Ltd. (citric acid monoglyceride olein type)
Using the release oil composition (Examples 3 to 6) to which was added in the amounts shown in Table 2, the same operation was performed.
In addition, as a comparative example, the release oil composition of Comparative Example 1 was mixed with 99 parts by mass of coconut oil (fatty acid content: 79.4%) and 1 part by mass of soybean fraction lecithin PC35 (SLP-PC35). The release oil composition (Comparative Example 7) was used.
Evaluation is based on the following criteria:
A: Best,
○: Good,
Δ: Normal,
X: Shown in four stages of inferiority.
The results are shown in Table 2.

ヤシ油とMCTの等量混合油に大豆分画レシチンPC35(SLP−PC35)を配合した実施例1の離型油組成物はくり返し団子を焼成しても銅板の色などが変化せず、焼成品(団子)に適度の焼きめがつき、また団子の風味、臭いが良く良好であった。しかし、団子の連続焼成をくり返すと、団子が銅板からはずれ難くなった。しかし、ライスワックス、植物ステロール、酢酸モノグリセライドまたはクエン酸モノグリセライドを添加した離型油組成物は、最後まで離型性が実施例1より優れていた(実施例3〜6)。一方、大豆分画レシチンPC35(SLP−PC35)を添加していない離型油組成物では発煙性で問題があるばかりでなく、団子材料が銅板に付着し、時間と共にその頻度は大きく離型性で大きな問題があった。また、比較例1の離型油組成物を塗布して生産された団子は、実施例1、3〜6の離型油組成物で生産された団子と比較して臭い、風味の点においても劣った。炭素数14以下の脂肪酸を78.6%含むヤシ油と分画レシチンPC35(SLP−PC35)とを含む離型油組成物を用いる場合(比較例7)であっても離型性に問題があり、臭い、風味の点でも優れたものでなかった。   The release oil composition of Example 1 in which soybean fraction lecithin PC35 (SLP-PC35) was blended with an equal mixture of coconut oil and MCT, the color of the copper plate did not change even when the dumpling was fired. The product (dumpling) was moderately baked and the dumpling flavor and smell were good and good. However, when the dumpling was repeatedly fired, it became difficult for the dumpling to come off the copper plate. However, the release oil composition to which rice wax, plant sterol, acetic acid monoglyceride or citric acid monoglyceride was added was superior to Example 1 in releasability to the end (Examples 3 to 6). On the other hand, the release oil composition to which soybean fraction lecithin PC35 (SLP-PC35) is not added has not only a problem with smoke generation, but also the dumpling material adheres to the copper plate, and the frequency increases with time. There was a big problem. In addition, the dumpling produced by applying the release oil composition of Comparative Example 1 is more odor and flavor than the dumpling produced by the release oil compositions of Examples 1 and 3-6. inferior. Even in the case of using a release oil composition containing coconut oil containing 78.6% of a fatty acid having 14 or less carbon atoms and fractionated lecithin PC35 (SLP-PC35) (Comparative Example 7), there is a problem in release properties. Yes, it was not excellent in smell and flavor.

試験例3 蒸しケーキ試験
混合した卵2個と砂糖50gの中に、溶かしたバター40gを加えて混ぜた。これにホットケーキミックス(森永製菓(株)社製)200gおよび牛乳100mLを順に加えてよく混ぜ、クリーム状にした。ケーキの型(底面積19.6cm、上面積43.0cmの円錐型プラスチック製)の内壁面に離型油組成物1.0gを塗付し、上記の生地50gを入れて、強火で15分間蒸しあげた。
Test Example 3 Steamed cake test 40 g of melted butter was added to and mixed with two mixed eggs and 50 g of sugar. To this, 200 g of hot cake mix (manufactured by Morinaga & Co., Ltd.) and 100 mL of milk were added in order and mixed well to form a cream. The type of cake given coating a release oil composition 1.0g on the inner wall surface of the (bottom area 19.6 cm 2, upper made conical plastic area 43.0cm 2), put the dough 50 g, with high heat Steamed for 15 minutes.

ケーキの物性[ケーキ生地の型の壁面へのくっつきに基づく変形、ケーキ生地に起泡が入ったすだち、ケーキ全体のボリューム(ケーキ全体がふっくらともりあがった状態)]を以下の基準:
◎優れている、
○良好、
△普通、
×劣る
の4段階で評価した。結果を表3に記す。
The physical properties of the cake [deformation based on the sticking of the cake dough mold to the wall surface, the cake dough is immediately foamed, and the volume of the entire cake (the whole cake is full) is as follows:
◎ Excellent,
○ Good,
△ Normal,
× Evaluated in four stages of inferiority. The results are shown in Table 3.

本発明の実施例1の離型油組成物およびこれにライスワックスを添加した離型油組成物(実施例3)ではケーキの物性が優れていた。しかし、比較例1や、比較例1に大豆分画レシチンPC35(SLP−PC35)を加えたものは、ケーキにすだちが入り、ボリュームも小さかった。即ち本発明の離型油組成物は、蒸しケーキの離型油にも使用し得ることが分かった。   The release oil composition of Example 1 of the present invention and the release oil composition (Example 3) in which rice wax was added thereto had excellent cake properties. However, in Comparative Example 1 and Comparative Example 1 in which soybean fraction lecithin PC35 (SLP-PC35) was added, sushi entered the cake and the volume was small. That is, it was found that the release oil composition of the present invention can also be used as a release oil for steamed cakes.

試験例4 蒸しケーキへの離型油組成物の浸透試験
本発明の離型油組成物が蒸しケーキに及ぼす効果を知るため、試験例3と同様の方法で蒸しケーキを作製した。離型油組成物の生地への浸透性を知るため、離型油組成物にβ-カロチン(色素)を添加した。その結果を図1に記す。
Test Example 4 Penetration Test of Release Oil Composition into Steamed Cake In order to know the effect of the release oil composition of the present invention on the steamed cake, a steamed cake was prepared in the same manner as in Test Example 3. In order to know the permeability of the release oil composition to the dough, β-carotene (pigment) was added to the release oil composition. The results are shown in FIG.

図1から明らかなように、本発明の実施例1および3の離型油組成物を塗布して蒸成した蒸しケーキは膨らみ方も均一に大きく、かつ離型油組成物の浸透は蒸しケーキの表面にとどまり、蒸しケーキの中への浸透はほとんど認められなかった(図1の1,2)。一方、炭素数14以下の脂肪酸を含まない比較例3に大豆分画レシチンPC35(SLP−PC35)を添加した離型油組成物を塗布して蒸成した蒸しケーキにおいては、実施例1または3の離型油組成物を塗布して蒸成した蒸しケーキより膨らみ方が少なかった。また、比較例3の離型油組成物は蒸しケーキの表面にとどまらず、蒸しケーキの中まで浸透した(図1の3)。本結果から、炭素数14以下の脂肪酸を含む油脂とリン脂質含量に対するホスファチジルコリンの割合が50%以上であるレシチンとを組み合わせることにより焼成または蒸成食品への油脂の浸透を抑制させることが判明した。   As is clear from FIG. 1, the steamed cake obtained by applying and steaming the release oil compositions of Examples 1 and 3 of the present invention has a uniformly large swell and the penetration of the release oil composition is steamed cake. The penetration into the steamed cake was hardly observed (1, 2 in FIG. 1). On the other hand, in a steamed cake obtained by applying a release oil composition to which soybean fraction lecithin PC35 (SLP-PC35) was added to Comparative Example 3 containing no fatty acid having 14 or less carbon atoms and steaming, Example 1 or 3 It was less swelled than the steamed cake coated with the release oil composition and steamed. Further, the release oil composition of Comparative Example 3 penetrated not only to the surface of the steamed cake but also to the steamed cake (3 in FIG. 1). From this result, it was found that by combining fats and oils containing fatty acids having 14 or less carbon atoms and lecithin in which the ratio of phosphatidylcholine to phospholipid content is 50% or more, the penetration of fats and oils into baked or steamed foods is suppressed. .

本発明の離型油組成物は、生地の焼成または蒸成時において焼成または蒸成食品への油脂の浸透性が低く、天板や型ないしは容器と焼成または蒸成食品との分離が良好で、特に170℃以上の高温で生地を焼成する焼成食品の連続生産に有用である。   The release oil composition of the present invention has low permeability of fats and oils to the baked or steamed food during baking or steaming of the dough, and good separation of the baking sheet or steamed food from the top plate or mold or container. In particular, it is useful for continuous production of baked foods in which the dough is baked at a high temperature of 170 ° C. or higher.

図1は、蒸しケーキの写真を示す。図中、1は実施例1の離型油組成物、2は実施例3の離型油組成物、3は比較例3の油に分画レシチンPC35を1.0質量%添加した離型油組成物を型に塗布して蒸成した蒸しケーキを示す。FIG. 1 shows a picture of a steamed cake. In the figure, 1 is a release oil composition of Example 1, 2 is a release oil composition of Example 3, and 3 is a release oil obtained by adding 1.0% by mass of fractionated lecithin PC35 to the oil of Comparative Example 3. The steamed cake which apply | coated the composition to the type | mold and was steamed is shown.

Claims (7)

(1)油脂の構成脂肪酸としての炭素数14以下の脂肪酸含量が、油脂中の構成脂肪酸全量に対して82%以上である食用油脂と、
(2)リン脂質含量に対するホスファチジルコリンの割合が50%以上であるレシチンとを含有し、
前記レシチンの量(リン脂質換算)が離型油組成物全体に対して0.1〜10質量%であることを特徴とする離型油組成物。
(1) Edible oil and fat having a fatty acid content of 14 or less carbon atoms as a constituent fatty acid of the oil and fat is 82% or more with respect to the total amount of the constituent fatty acid in the oil and fat;
(2) containing lecithin in which the ratio of phosphatidylcholine to phospholipid content is 50% or more,
The release oil composition, wherein the amount of lecithin (in terms of phospholipid) is 0.1 to 10% by mass with respect to the entire release oil composition.
さらに、食用ワックス、植物ステロールおよび有機酸モノグリセリドより成る群より選ばれる少なくとも1種を離型油組成物全体に対して0.01〜5質量%含有する請求項1に記載の離型油組成物。   Furthermore, the mold release oil composition of Claim 1 which contains 0.01-5 mass% of at least 1 sort (s) chosen from the group which consists of an edible wax, a plant sterol, and an organic acid monoglyceride with respect to the whole mold release oil composition. . 離型剤として請求項1または2に記載の離型油組成物を、天板、型または容器と食品生地が接触する天板、型または容器の面に塗布し、離型油組成物が塗布された天板、型または容器を用いて食品生地を焼成または蒸成することを特徴とする食品の製造方法。   The release oil composition according to claim 1 or 2 as a release agent is applied to the top plate, mold or container surface where the food dough contacts the top plate, mold or container, and the release oil composition is applied. A method for producing a food, comprising baking or steaming the food dough using the prepared top plate, mold or container. 請求項3に記載の製造方法で製造された食品。   The foodstuff manufactured with the manufacturing method of Claim 3. 食品が焼団子である請求項4に記載の食品。   The food according to claim 4, wherein the food is a grilled dumpling. 食品がどら焼きである請求項4に記載の食品。   The food according to claim 4, wherein the food is dorayaki. 食品が蒸しケーキである請求項4に記載の食品。   The food according to claim 4, wherein the food is a steamed cake.
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013081475A (en) * 2011-08-29 2013-05-09 J-Oil Mills Inc Method of manufacturing fat composition containing lecithin and method of preventing precipitation of lecithin
JP2014018170A (en) * 2012-07-20 2014-02-03 Nisshin Oillio Group Ltd Mold release oil
CN103763932A (en) * 2011-08-29 2014-04-30 J-制油株式会社 Oil composition for sauting and method for producing same
JP2015065871A (en) * 2013-09-27 2015-04-13 日清オイリオグループ株式会社 Steamed cake and manufacturing method thereof
JP2017063684A (en) * 2015-09-29 2017-04-06 理研ビタミン株式会社 Casing releasability improver for processed food
JP2017123882A (en) * 2017-04-27 2017-07-20 日清オイリオグループ株式会社 Mold release oil
JP7479892B2 (en) 2020-03-27 2024-05-09 理研ビタミン株式会社 Release oil
JP7578273B2 (en) 2020-11-27 2024-11-06 株式会社ウエノフードテクノ Food processing aid composition

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0739304A (en) * 1993-07-29 1995-02-10 Riken Vitamin Co Ltd Mold release oil for production of confection
JPH07170910A (en) * 1993-12-17 1995-07-11 Taiyo Kagaku Co Ltd Mold-releasing oil
JPH10248488A (en) * 1997-03-14 1998-09-22 Honen Corp Separate type oil
JP2002209517A (en) * 2001-01-19 2002-07-30 Nisshin Oil Mills Ltd:The Plant sterol-including food oil composition having excellent storage stability and method of producing the same
JP2003238984A (en) * 2002-02-14 2003-08-27 Nisshin Oillio Ltd Fat and oil composition, mold release oil and method for evaluating mold release oil

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0739304A (en) * 1993-07-29 1995-02-10 Riken Vitamin Co Ltd Mold release oil for production of confection
JPH07170910A (en) * 1993-12-17 1995-07-11 Taiyo Kagaku Co Ltd Mold-releasing oil
JPH10248488A (en) * 1997-03-14 1998-09-22 Honen Corp Separate type oil
JP2002209517A (en) * 2001-01-19 2002-07-30 Nisshin Oil Mills Ltd:The Plant sterol-including food oil composition having excellent storage stability and method of producing the same
JP2003238984A (en) * 2002-02-14 2003-08-27 Nisshin Oillio Ltd Fat and oil composition, mold release oil and method for evaluating mold release oil

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013081475A (en) * 2011-08-29 2013-05-09 J-Oil Mills Inc Method of manufacturing fat composition containing lecithin and method of preventing precipitation of lecithin
JP5209148B1 (en) * 2011-08-29 2013-06-12 株式会社J−オイルミルズ Oil and fat composition and method for producing the same
CN103763932A (en) * 2011-08-29 2014-04-30 J-制油株式会社 Oil composition for sauting and method for producing same
JP2014018170A (en) * 2012-07-20 2014-02-03 Nisshin Oillio Group Ltd Mold release oil
JP2015065871A (en) * 2013-09-27 2015-04-13 日清オイリオグループ株式会社 Steamed cake and manufacturing method thereof
JP2017063684A (en) * 2015-09-29 2017-04-06 理研ビタミン株式会社 Casing releasability improver for processed food
JP2017123882A (en) * 2017-04-27 2017-07-20 日清オイリオグループ株式会社 Mold release oil
JP7479892B2 (en) 2020-03-27 2024-05-09 理研ビタミン株式会社 Release oil
JP7578273B2 (en) 2020-11-27 2024-11-06 株式会社ウエノフードテクノ Food processing aid composition

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