JP2007272064A - Image receiving sheet for electrostatic charge liquid development, and image receiving label for electrostatic charge liquid development - Google Patents

Image receiving sheet for electrostatic charge liquid development, and image receiving label for electrostatic charge liquid development Download PDF

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JP2007272064A
JP2007272064A JP2006099500A JP2006099500A JP2007272064A JP 2007272064 A JP2007272064 A JP 2007272064A JP 2006099500 A JP2006099500 A JP 2006099500A JP 2006099500 A JP2006099500 A JP 2006099500A JP 2007272064 A JP2007272064 A JP 2007272064A
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electrostatic charge
image receiving
image
charge liquid
receiving sheet
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JP4860326B2 (en
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Soichiro Fujinaga
壮一郎 藤永
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Lintec Corp
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Lintec Corp
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Priority to PCT/JP2007/054583 priority patent/WO2007113982A1/en
Priority to TW96109971A priority patent/TW200807190A/en
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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00Developers
    • G03G9/08Developers with toner particles
    • G03G9/12Developers with toner particles in liquid developer mixtures
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G7/00Selection of materials for use in image-receiving members, i.e. for reversal by physical contact; Manufacture thereof
    • G03G7/0006Cover layers for image-receiving members; Strippable coversheets
    • G03G7/002Organic components thereof
    • G03G7/0026Organic components thereof being macromolecular
    • G03G7/0046Organic components thereof being macromolecular obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Liquid Developers In Electrophotography (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide an image receiving sheet for electrostatic charge liquid development in which an image receiving layer excellent in adhesiveness to a toner image by electrostatic charge liquid development and also in adhesiveness to a substrate is provided, and to provide an image receiving label for electrostatic charge liquid development. <P>SOLUTION: The image receiving sheet for electrostatic charge liquid development is characterized in that the image receiving layer is formed by applying and drying a coating liquid, which contains an ethylene-(meth)acrylic acid copolymer and a tetramethylxylylene diisocyanate-blocked isocyanate crosslinking agent, on at least one surface of a substrate. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、静電荷液体現像によるトナー画像との密着性に優れた静電荷液体現像用受像シート及び静電荷液体現像用受像ラベルに関する。   The present invention relates to an image receiving sheet for developing an electrostatic charge liquid and an image receiving label for developing an electrostatic charge liquid, which are excellent in adhesion to a toner image by electrostatic charge liquid development.

消費者のニーズが多様化している今日、印刷物の製造についても少量かつ多品種の製造が要求される傾向が顕著になってきている。そこで、このような要求に対応するための方法として、費用と時間がかかる製版工程を必要としない電子写真法が着目されている。中でも、液体トナーを用いた湿式電子写真法である静電荷液体現像法は、粉体トナーを用いた乾式電子写真法と比較して、トナーを構成する粒子の平均粒径が小さいことから、グラビア印刷方式やオフセット印刷方式等と同程度の高精細性を達成することができる。この静電荷液体現像法は、まず、帯電したドラムにレーザーを照射して電荷を消散させることで静電潜像を形成し、この潜像に電荷を有する液体トナーを接触させて、画像を現像する。次に、この画像を静電気によってドラムから中間転写体に飛ばし、中間転写体上で画像を熱溶融して熱及び圧力によって受像シートに転写して画像を定着する。   Today, as consumers' needs are diversifying, the tendency to demand a small quantity and a wide variety of production is also becoming more prominent. Thus, attention has been paid to an electrophotographic method that does not require a costly and time-consuming plate making process as a method for meeting such requirements. In particular, the electrostatic charge liquid developing method, which is a wet electrophotographic method using liquid toner, has a smaller average particle diameter of the particles constituting the toner than the dry electrophotographic method using powder toner. The same high definition as the printing method or offset printing method can be achieved. In this electrostatic charge liquid development method, first, an electrostatic latent image is formed by irradiating a charged drum with a laser to dissipate the charge, and then the latent image is brought into contact with liquid toner having a charge to develop the image. To do. Next, the image is transferred from the drum to the intermediate transfer member by static electricity, the image is melted on the intermediate transfer member, and transferred to the image receiving sheet by heat and pressure to fix the image.

この受像シートの基材がプラスチックフィルムやプラスチックシート等であると、トナー画像と受像シートとの密着性が低く、トナー画像が受像シートから剥がれやすいという問題があることはよく知られている事実である。そこで、トナー画像と受像シートとの密着性を改善するための方法として、例えば、特許文献1には、基材の表面に受像層となるポリエチレンを主成分とする樹脂を塗布したシートが記載されている。また、特許文献2には、プラスチックフィルム等の被印刷体上に、受像層となるエチレン・アクリル酸系樹脂又はポリブタジエン系樹脂からなるプライマー層を形成したものが記載されている。
特開平9−281738号公報 特開平10−76744号公報
It is a well-known fact that when the substrate of this image receiving sheet is a plastic film, a plastic sheet or the like, the adhesion between the toner image and the image receiving sheet is low, and the toner image is easily peeled off from the image receiving sheet. is there. Thus, as a method for improving the adhesion between the toner image and the image receiving sheet, for example, Patent Document 1 describes a sheet in which a resin mainly composed of polyethylene serving as an image receiving layer is applied to the surface of a base material. ing. Japanese Patent Application Laid-Open No. H10-228667 describes a primer layer made of an ethylene / acrylic acid resin or polybutadiene resin serving as an image receiving layer on a printed material such as a plastic film.
JP-A-9-281738 JP-A-10-76744

しかしながら、特許文献1や特許文献2に記載されている受像シートは、受像層とトナー画像との密着が不十分であり、また、基材と受像層との密着も不十分であった。
そこで、本発明は、静電荷液体現像によるトナー画像との密着性とともに基材との密着性に優れた受像層を設けた静電荷液体現像用受像シート及び静電荷液体現像用受像ラベルを提供することを目的とする。
However, the image-receiving sheets described in Patent Document 1 and Patent Document 2 have insufficient adhesion between the image-receiving layer and the toner image, and also insufficient adhesion between the substrate and the image-receiving layer.
Accordingly, the present invention provides an image receiving sheet for developing an electrostatic charge liquid and an image receiving label for developing an electrostatic charge liquid provided with an image receiving layer having excellent adhesion to a toner image as well as adhesion to a toner image by electrostatic charge liquid development. For the purpose.

本発明者は、上記の点に鑑み鋭意研究を重ねた結果、基材の表面にエチレン・(メタ)アクリル酸共重合体及びテトラメチルキシリレンジイソシアナートをブロック化したイソシアナート架橋剤(以下「TMXDIブロックイソシアナート架橋剤」と略称する)を含む塗工液を塗布し乾燥させて形成した受像層は、静電荷液体現像によるトナー画像との間で優れた密着性を発揮するとともに、基材との密着性にも優れることを見出した。   As a result of intensive studies in view of the above points, the present inventor has found that an isocyanate cross-linking agent (hereinafter referred to as “an ethylene / (meth) acrylic acid copolymer and tetramethylxylylene diisocyanate) blocked on the surface of the substrate. The image-receiving layer formed by applying and drying a coating solution containing a TMXDI block isocyanate cross-linking agent) exhibits excellent adhesion with a toner image by electrostatic charge liquid development, It has been found that the adhesiveness is excellent.

上記の知見に基づいてなされた本発明の静電荷液体現像用受像シートは、請求項1記載の通り、基材の少なくとも片面に、エチレン・(メタ)アクリル酸共重合体及びTMXDIブロックイソシアナート架橋剤を含む塗工液を塗布し乾燥させて受像層を形成してなることを特徴とする。
また、請求項2記載の静電荷液体現像用受像シートは、請求項1記載の静電荷液体現像用受像シートにおいて、静電荷液体現像に使用する液体トナーの定着樹脂がエチレン・(メタ)アクリル酸共重合体を含むことを特徴とする。
また、請求項3記載の静電荷液体現像用受像シートは、請求項1又は2記載の静電荷液体現像用受像シートにおいて、受像層の厚さが0.1〜5.0μmであることを特徴とする。
また、請求項4記載の静電荷液体現像用受像シートは、請求項1乃至3のいずれかに記載の静電荷液体現像用受像シートにおいて、基材に塗布した塗工液の乾燥温度を60〜80℃とすることを特徴とする。
また、本発明の静電荷液体現像用受像ラベルは、請求項5記載の通り、請求項1乃至4のいずれかに記載の静電荷液体現像用受像シートの受像層を形成した基材の面の反対面に、粘着剤層及び剥離材をこの順に積層してなることを特徴とする。
The electrostatic charge liquid developing image-receiving sheet of the present invention made on the basis of the above knowledge is, as described in claim 1, an ethylene / (meth) acrylic acid copolymer and a TMXDI block isocyanate crosslinked on at least one side of the substrate. An image receiving layer is formed by applying a coating liquid containing an agent and drying.
The electrostatic charge liquid developing image receiving sheet according to claim 2 is the electrostatic charge liquid developing image receiving sheet according to claim 1, wherein the fixing resin of the liquid toner used for electrostatic charge liquid development is ethylene / (meth) acrylic acid. It is characterized by including a copolymer.
The image receiving sheet for developing electrostatic charge according to claim 3 is the image receiving sheet for developing electrostatic charge according to claim 1 or 2, wherein the thickness of the image receiving layer is from 0.1 to 5.0 μm. And
The electrostatic charge liquid developing image-receiving sheet according to claim 4 is the electrostatic charge liquid developing image-receiving sheet according to any one of claims 1 to 3, wherein the drying temperature of the coating liquid applied to the substrate is from 60 to 60. It is characterized by being 80 ° C.
The image receiving label for developing an electrostatic charge liquid according to the present invention has a surface of a substrate on which the image receiving layer of the image receiving sheet for developing an electrostatic charge according to any one of claims 1 to 4 is formed. A pressure-sensitive adhesive layer and a release material are laminated in this order on the opposite surface.

本発明の静電荷液体現像用受像シートにおける、基材の少なくとも片面に、エチレン・(メタ)アクリル酸共重合体及びTMXDIブロックイソシアナート架橋剤を含む塗工液を塗布し乾燥させることで設けた受像層は、静電荷液体現像によるトナー画像との間で優れた密着性を発揮するとともに、基材との密着性にも優れる。従って、本発明の静電荷液体現像用受像シートを用いれば、転写した画像を良好に定着させることができ、少量かつ多品種な印刷物の高精細な製造に対する要求を満たす静電荷液体現像が可能となる。   In the image-receiving sheet for electrostatic charge liquid development of the present invention, the coating liquid containing an ethylene / (meth) acrylic acid copolymer and a TMXDI block isocyanate crosslinking agent was applied to at least one surface of the base material and dried. The image receiving layer exhibits excellent adhesion to a toner image obtained by electrostatic charge liquid development, and also excellent adhesion to a substrate. Therefore, if the image-receiving sheet for developing electrostatic charge liquid of the present invention is used, the transferred image can be fixed satisfactorily, and electrostatic charge liquid development satisfying the demand for high-definition production of a small quantity and various kinds of printed materials becomes possible. Become.

本発明の静電荷液体現像用受像シートは、基材の少なくとも片面に、エチレン・(メタ)アクリル酸共重合体及びTMXDIブロックイソシアナート架橋剤を含む塗工液を塗布し乾燥させて受像層を形成してなることを特徴とするものである。   The image-receiving sheet for developing an electrostatic charge liquid of the present invention has an image-receiving layer formed by applying a coating liquid containing an ethylene / (meth) acrylic acid copolymer and a TMXDI block isocyanate cross-linking agent on at least one side of a substrate and drying it. It is characterized by being formed.

本発明の静電荷液体現像用受像シートにおける受像層を形成するための塗工液の構成成分とするエチレン・(メタ)アクリル酸共重合体は、水溶液タイプや分散液タイプの種々の市販品や公知のものを用いることができる。例えば、水溶液タイプのエチレン・アクリル酸共重合体としては、東邦化学工業社のハイテックS−3121(商品名)や住友精化社のザイクセンA(商品名)の他、マイケルマン社のDP1000(商品名)等が挙げられ、分散液タイプのエチレン・アクリル酸共重合体としては、中央理化工業社のリカボンドET−8(商品名)等が挙げられる。また、水溶液タイプのエチレン・メタクリル酸共重合体としては、東邦化学工業社のハイテックSC−100(商品名)等が挙げられ、分散液タイプのエチレン・メタクリル酸共重合体としては、中央理化工業社のアクアテックスAC−3100(商品名)等が挙げられる。なお、塗工液の構成成分として、エチレン・(メタ)アクリル酸共重合体に、エチレン・(メタ)アクリル酸メチル共重合体、エチレン・(メタ)アクリル酸エチル共重合体、エチレン・(メタ)アクリル酸プロピル共重合体、エチレン・(メタ)アクリル酸ブチル共重合体、エチレン・(メタ)アクリル酸2−エチルヘキシル共重合体等のエチレン・(メタ)アクリル酸エステル共重合体を混合してもよい。   The ethylene / (meth) acrylic acid copolymer as a constituent component of the coating liquid for forming the image receiving layer in the image receiving sheet for electrostatic charge liquid development of the present invention includes various commercially available products of aqueous solution type and dispersion type, A well-known thing can be used. For example, as an aqueous solution type ethylene / acrylic acid copolymer, high-tech S-3121 (trade name) of Toho Chemical Industry Co., Ltd., Seixen A (trade name) of Sumitomo Seika Co., Ltd. Examples of the dispersion type ethylene / acrylic acid copolymer include Rikabond ET-8 (trade name) manufactured by Chuo Rika Kogyo Co., Ltd. Examples of the aqueous solution type ethylene / methacrylic acid copolymer include Hitech SC-100 (trade name) manufactured by Toho Chemical Industry Co., Ltd., and examples of the dispersion type ethylene / methacrylic acid copolymer include Chuo Rika Kogyo. The company's Aquatex AC-3100 (trade name) and the like. In addition, as a component of the coating liquid, ethylene / (meth) acrylic acid copolymer, ethylene / (meth) methyl acrylate copolymer, ethylene / (meth) ethyl acrylate copolymer, ethylene / (meta ) Propyl acrylate copolymer, ethylene / (meth) acrylic acid butyl copolymer, ethylene / (meth) acrylic acid 2-ethylhexyl copolymer etc. Also good.

TMXDIブロックイソシアナート架橋剤におけるTMXDIは、飽和蒸気圧が高いことからビューレット体、イソシアヌレート体、アダクト体として用いることが望ましい。TMXDIのブロック化に使用されるブロック剤としては、メチルエチルケトオキシムやアセトオキシムが例示されるオキシム類、ノニルフェノールやオクチルフェノールが例示されるアルキルフェノール類、アセト酢酸エチルやマロン酸エチルが例示される活性メチレン類、ε−カプロラクタムが例示されるラクタム類等が挙げられるが、中でも解離温度が比較的低温のオキシム類が好適に挙げられる。ブロック剤が塗工液の乾燥時又は印刷時の高温により解離することでTMXDIのイソシアナート基が活性化される。ブロック剤としてオキシム類を使用したTMXDIブロックイソシアナート架橋剤としては、第一工業製薬社のエラストロンBN−08(商品名)や武田薬品工業社のタケネートXB−77−M9(商品名)等が挙げられる。   Since TMXDI in the TMXDI block isocyanate cross-linking agent has a high saturated vapor pressure, it is desirable to use it as a burette body, isocyanurate body, or adduct body. As blocking agents used for blocking TMXDI, oximes exemplified by methyl ethyl ketoxime and acetooxime, alkylphenols exemplified by nonylphenol and octylphenol, active methylenes exemplified by ethyl acetoacetate and ethyl malonate, Examples include lactams exemplified by ε-caprolactam, among which oximes having a relatively low dissociation temperature are preferable. The isocyanate group of TMXDI is activated by the dissociation of the blocking agent due to the high temperature during drying or printing of the coating solution. Examples of TMXDI block isocyanate cross-linking agents using oximes as blocking agents include Elastolon BN-08 (trade name) from Daiichi Kogyo Seiyaku Co., Ltd. and Takenate XB-77-M9 (trade name) from Takeda Pharmaceutical Company Limited. It is done.

塗工液中へのエチレン・(メタ)アクリル酸共重合体及びTMXDIブロックイソシアナート架橋剤の配合量は、エチレン・(メタ)アクリル酸共重合体100重量部に対してTMXDIブロックイソシアナート架橋剤1〜50重量部が望ましく、5〜40重量部がより望ましい(固形分比)。TMXDIブロックイソシアナート架橋剤の配合量がエチレン・(メタ)アクリル酸共重合体100重量部に対して1重量部未満であると基材と受像層との密着が不十分になる恐れがある一方、50重量部を越えるとトナー画像と受像層との密着が不十分になる恐れがある。また、エチレン・(メタ)アクリル酸共重合体及びTMXDIブロックイソシアナート架橋剤を含む塗工液の固形分は、0.5〜30重量%であることが望ましく、1〜25重量%であることがより望ましい。固形分が0.5重量%未満であると基材の表面に受像層を形成するための必要な塗布厚が得られない恐れがある一方、30重量%を越えると塗工液の粘度が高くなりすぎて平滑な塗工面が得られない恐れがある。   The blending amount of the ethylene / (meth) acrylic acid copolymer and the TMXDI block isocyanate cross-linking agent in the coating liquid is the TMXDI block isocyanate cross-linking agent with respect to 100 parts by weight of the ethylene / (meth) acrylic acid copolymer. 1 to 50 parts by weight is desirable, and 5 to 40 parts by weight is more desirable (solid content ratio). While the amount of the TMXDI block isocyanate cross-linking agent is less than 1 part by weight based on 100 parts by weight of the ethylene / (meth) acrylic acid copolymer, the adhesion between the substrate and the image receiving layer may be insufficient. If the amount exceeds 50 parts by weight, the toner image and the image receiving layer may be insufficiently adhered. The solid content of the coating solution containing the ethylene / (meth) acrylic acid copolymer and the TMXDI block isocyanate crosslinking agent is preferably 0.5 to 30% by weight, and preferably 1 to 25% by weight. Is more desirable. If the solid content is less than 0.5% by weight, the coating thickness required for forming the image receiving layer on the surface of the substrate may not be obtained, whereas if it exceeds 30% by weight, the viscosity of the coating solution is high. There is a possibility that a smooth coated surface may not be obtained due to too much.

塗工液の調製は水とメチルアルコールとの混合溶媒を用いて行うことが望ましい。水とメチルアルコールとの混合溶媒を用いて調製された塗工液を基材の表面に塗布することで、発泡や白濁がない透明性に優れた受像層を形成することができる。水とメチルアルコールとの混合割合は、水100重量部に対してメチルアルコール10〜60重量部が望ましい。メチルアルコールの混合量が水100重量部に対して10重量部未満であると塗工液が基材からはじかれやすく、また、乾燥時間が長くなり実用的でなくなる恐れがある一方、60重量部を越えると塗工液がゲル状化しやすく、安定な塗工を行えない恐れがある。   The coating liquid is preferably prepared using a mixed solvent of water and methyl alcohol. By applying a coating solution prepared using a mixed solvent of water and methyl alcohol to the surface of the substrate, an image-receiving layer having excellent transparency without foaming or clouding can be formed. The mixing ratio of water and methyl alcohol is preferably 10 to 60 parts by weight of methyl alcohol with respect to 100 parts by weight of water. When the mixing amount of methyl alcohol is less than 10 parts by weight with respect to 100 parts by weight of water, the coating liquid is likely to be repelled from the base material, and the drying time may become longer and impractical. If it exceeds 1, the coating solution tends to gel, and stable coating may not be possible.

なお、塗工液には、ブロッキング防止のために、無機顔料や有機顔料を適宜配合してもよいし、消泡剤、紫外線吸収剤、酸化防止剤、レベリング剤、粘性調整剤等を適宜配合してもよい。   In addition, in the coating liquid, an inorganic pigment or an organic pigment may be appropriately blended to prevent blocking, and an antifoaming agent, an ultraviolet absorber, an antioxidant, a leveling agent, a viscosity modifier, etc. are blended as appropriate. May be.

本発明の静電荷液体現像用受像シートにおける基材は、特段限定されるものではないが、ポリエチレンテレフタレートフィルムが例示されるポリエステルフィルムの他、ポリエチレンフィルム、ポリプロピレンフィルム、塩化ビニルフィルム等の合成樹脂製フィルムを好適に用いることができる。基材の厚さは10〜300μmが望ましく、20〜200μmがより望ましい。なお、基材と受像層との密着性を向上させるために、基材にコロナ処理や火炎処理等の処理を行ってもよい。また、基材にポリエステル系樹脂やアクリル系樹脂等からなるアンカーコート層を設け、このアンカーコート層上に受像層を形成してもよい。   The substrate in the image receiving sheet for developing an electrostatic charge liquid of the present invention is not particularly limited, but is made of a synthetic resin such as a polyethylene film, a polypropylene film, a vinyl chloride film, in addition to a polyester film exemplified by a polyethylene terephthalate film. A film can be suitably used. The thickness of the substrate is preferably 10 to 300 μm, more preferably 20 to 200 μm. In addition, in order to improve the adhesiveness of a base material and an image receiving layer, you may perform processes, such as a corona treatment and a flame treatment, to a base material. Further, an anchor coat layer made of a polyester resin, an acrylic resin, or the like may be provided on the base material, and an image receiving layer may be formed on the anchor coat layer.

基材の表面への塗工液の塗布は、例えば、エアーナイフコーター、ブレードコーター、リバースロールコーター、グラビアコーター、バーコーター等を用いて行えばよい。中でもグラビアコーターを好適に用いることができる。基材の表面に塗布された塗工液を乾燥する方法としては、例えば、熱風乾燥を用いることができる。塗工液の乾燥温度は60〜80℃が望ましい。乾燥温度が60℃未満であると基材と受像層との間で安定した密着性が得られにくくなる恐れがある一方、80℃を超えるとトナー画像と受像層との間で安定した密着性が得られにくくなる恐れがある。   Application of the coating liquid to the surface of the substrate may be performed using, for example, an air knife coater, a blade coater, a reverse roll coater, a gravure coater, a bar coater, or the like. Of these, a gravure coater can be preferably used. As a method for drying the coating liquid applied to the surface of the substrate, for example, hot air drying can be used. The drying temperature of the coating liquid is preferably 60 to 80 ° C. If the drying temperature is less than 60 ° C., stable adhesion between the substrate and the image receiving layer may be difficult to obtain, whereas if it exceeds 80 ° C., stable adhesion between the toner image and the image receiving layer. May be difficult to obtain.

以上のようにして基材の表面に形成される受像層の厚さは0.1〜5.0μmが望ましく、0.5〜3.0μmがより望ましい。受像層の厚さが0.1μm未満であると基材と受像層との間で安定した密着性が得られにくくなる恐れがある一方、5.0μmを超えると基材を巻き取った後にブロッキングが生じやすくなる恐れがある。   The thickness of the image receiving layer formed on the surface of the substrate as described above is preferably 0.1 to 5.0 μm, and more preferably 0.5 to 3.0 μm. If the thickness of the image receiving layer is less than 0.1 μm, stable adhesion between the substrate and the image receiving layer may be difficult to obtain, whereas if it exceeds 5.0 μm, blocking after winding the substrate. May be more likely to occur.

以上のようにして製造される本発明の静電荷液体現像用受像シートは、その受像層を設けた基材の面の反対面に粘着剤層及び剥離材をこの順に積層することによって静電荷液体現像用受像ラベルとすることができる。   The electrostatic charge liquid developing image-receiving sheet of the present invention produced as described above is obtained by laminating an adhesive layer and a release material in this order on the surface opposite to the surface of the substrate provided with the image-receiving layer. An image receiving label for development can be obtained.

粘着剤層を構成する粘着剤としては、エマルジョン型、溶剤型、無溶剤型のいずれの粘着剤を用いてもよく、例えば、アクリル系粘着剤の他、ゴム系、ポリエステル系、ポリウレタン系粘着剤等を用いることができる。また、耐熱性が要求される場合は、耐熱性に優れるシリコーン系粘着剤を用いてもよい。粘着剤層の厚さは5〜60μmが望ましく、15〜40μmがより望ましい。粘着剤層の厚さが5μm未満であると粘着力が不十分となる恐れがある一方、60μmを超えると粘着剤のはみ出しが発生する恐れがある。粘着剤層の形成は、例えば、ナイフコーター、ロールコーター、ダイコーター等を用いて粘着剤を基材の表面に塗布した後、乾燥することで行えばよい。こうして形成した粘着剤層に剥離材を積層すれば、静電荷液体現像用受像ラベルを製造することができる。また、静電荷液体現像用受像ラベルは、剥離材の表面に粘着剤をナイフコーターやロールコーター等を用いて塗布した後、乾燥して粘着剤層を形成し、こうして形成した粘着剤層を受像層を設けた基材の面の反対面に積層することで製造してもよい。このような製造方法は、粘着剤層を形成するための乾燥過程における加熱が受像層に対してダメージを与えないので望ましい。   As the pressure-sensitive adhesive constituting the pressure-sensitive adhesive layer, any of emulsion-type, solvent-type and solventless-type pressure-sensitive adhesives may be used. For example, in addition to acrylic pressure-sensitive adhesives, rubber-based, polyester-based, polyurethane-based pressure-sensitive adhesives Etc. can be used. Moreover, when heat resistance is required, a silicone-based pressure-sensitive adhesive having excellent heat resistance may be used. The thickness of the pressure-sensitive adhesive layer is preferably 5 to 60 μm, and more preferably 15 to 40 μm. If the thickness of the pressure-sensitive adhesive layer is less than 5 μm, the adhesive force may be insufficient. On the other hand, if it exceeds 60 μm, the pressure-sensitive adhesive may protrude. The pressure-sensitive adhesive layer may be formed, for example, by applying the pressure-sensitive adhesive to the surface of the substrate using a knife coater, roll coater, die coater or the like and then drying it. By laminating a release material on the pressure-sensitive adhesive layer thus formed, an image receiving label for developing an electrostatic charge liquid can be produced. In addition, the image receiving label for developing an electrostatic charge liquid is coated with an adhesive on the surface of a release material using a knife coater or a roll coater, and then dried to form an adhesive layer. You may manufacture by laminating | stacking on the opposite surface of the surface of the base material which provided the layer. Such a production method is desirable because heating in the drying process for forming the pressure-sensitive adhesive layer does not damage the image receiving layer.

剥離材としては、ポリエチレンテレフタレートフィルム、発泡ポリエチレンテレフタレートフィルム、ポリプロピレンフィルム等のプラスチックフィルムや、コート紙、グラシン紙、その他ポリエチレンラミネート紙等の紙に、シリコーン系、フッ素系、長鎖アルキル系等からなる剥離剤を塗布したものを用いることができる。剥離材の厚さは、特に制限されないが、通常20〜200μm程度であればよい。   The release material consists of plastic film such as polyethylene terephthalate film, foamed polyethylene terephthalate film, polypropylene film, paper such as coated paper, glassine paper, and other polyethylene laminated paper, silicone, fluorine, long chain alkyl, etc. What apply | coated the release agent can be used. The thickness of the release material is not particularly limited, but may be usually about 20 to 200 μm.

本発明の静電荷液体現像用受像シートに対して適用される画像層を形成するための静電荷現像用の液体トナーとしては、可視化するための着色剤と、着色剤を受像シートに固定するための定着樹脂と、電気的特性を調整するための電荷調整剤等をキャリア液体に分散させた一般的なものを用いることができる。   The liquid toner for electrostatic charge development for forming an image layer applied to the image receiving sheet for developing electrostatic charge liquid of the present invention includes a colorant for visualization and a colorant for fixing the colorant to the image receiving sheet. A general resin in which a fixing resin and a charge adjusting agent for adjusting electrical characteristics are dispersed in a carrier liquid can be used.

着色剤としては、従来から静電荷現像用の液体トナーの着色剤として用いられている公知の顔料や染料、例えば、ハンザイエロー、ベンジジンイエロー、ベンジジンオレンジ、ファーストレッド、ブリリアントカーミン3B、銅フタロシアニンブルー、フタロシアニングリーン、スピリットブラック、オイルブルー、アルカリブルー、ローダミン6B、ニグロシン、カーボンブラック、ジクロロキナクリドン、イソインドリン、酸化チタン等を用いることができる。   As the colorant, known pigments and dyes conventionally used as colorants for liquid toners for electrostatic charge development, such as Hansa Yellow, Benzidine Yellow, Benzidine Orange, First Red, Brilliant Carmine 3B, Copper Phthalocyanine Blue, Phthalocyanine green, spirit black, oil blue, alkali blue, rhodamine 6B, nigrosine, carbon black, dichloroquinacridone, isoindoline, titanium oxide, and the like can be used.

定着樹脂としては、従来から静電荷現像用の液体トナーの定着樹脂として用いられている公知の樹脂、例えば、ポリスチレン、スチレン・アクリル酸共重合体、ポリアクリル酸、ポリエチレン、エチレン・(メタ)アクリル酸共重合体、エチレン・(メタ)アクリル酸エステル共重合体、ポリプロピレン、ポリエステル、ポリウレタン、ポリアミド等の熱可塑性樹脂を単体で又は混合して用いることができる。本発明の静電荷液体現像用受像シートに対して好適な定着樹脂としてはエチレン・(メタ)アクリル酸共重合体を含むものが挙げられる。   As fixing resins, known resins conventionally used as fixing resins for liquid toners for electrostatic charge development, such as polystyrene, styrene / acrylic acid copolymers, polyacrylic acid, polyethylene, ethylene / (meth) acrylic. Thermoplastic resins such as acid copolymers, ethylene / (meth) acrylic acid ester copolymers, polypropylene, polyester, polyurethane, and polyamide can be used alone or in combination. Suitable fixing resins for the electrostatic charge liquid developing image-receiving sheet of the present invention include those containing an ethylene / (meth) acrylic acid copolymer.

電荷調整剤としては、従来から静電荷現像用の液体トナーの電荷調整剤として用いられている、ナフテン酸、オクテン酸、オレイン酸、ステアリン酸等の樹脂酸の金属塩、スルホコハク酸エステルの金属塩、ポリオキシエチル化アルキルアミンのような非イオン性界面活性剤、レシチン、アマニ油等の油脂類、ポリビニルピロリドン、多価アルコールの有機酸エステル等を用いることができる。   As the charge control agent, metal salts of resin acids such as naphthenic acid, octenoic acid, oleic acid and stearic acid, and metal salts of sulfosuccinic acid esters, which are conventionally used as charge control agents for liquid toners for electrostatic charge development. Nonionic surfactants such as polyoxyethylated alkylamines, fats and oils such as lecithin and linseed oil, polyvinylpyrrolidone, organic acid esters of polyhydric alcohols, and the like can be used.

キャリア液体としては、高絶縁性・低誘電率の炭化水素系溶剤が用いられる。好ましくは分岐鎖状脂肪族炭化水素であり、具体的にはアイソパーG、アイソパーL、アイソパーM(エクソン化学社の商品名)等が挙げられる。   As the carrier liquid, a hydrocarbon solvent having a high insulating property and a low dielectric constant is used. Preferred are branched aliphatic hydrocarbons, and specific examples include Isopar G, Isopar L, Isopar M (a trade name of Exxon Chemical).

次に、本発明の静電荷液体現像用受像シート及び静電荷液体現像用受像ラベルの実施例を比較例とともに説明するが、本発明は以下の例に限定されるものではない。   Next, examples of the image receiving sheet for electrostatic charge liquid development and the image receiving label for electrostatic charge liquid development of the present invention will be described together with comparative examples, but the present invention is not limited to the following examples.

実施例1:
水溶液タイプのエチレン・アクリル酸共重合体(住友精化社製、商品名:ザイクセンA、固形分:25.0重量%)100重量部に対してTMXDIブロックイソシアナート架橋剤(第一工業製薬社製、商品名:エラストロンBN−08、固形分:34.5重量%、ブロック剤の種類はオキシム類でその解離温度は120℃)8重量部を添加し(固形分比)、さらに水/メチルアルコールが100重量部/25重量部の割合からなる混合溶剤を添加して希釈し、固形分が9.5重量%の塗工液を調製した。この塗工液を、コロナ処理を施した厚さ50μmのポリエチレンテレフタレートフィルム(東レ社製、商品名:ルミラー♯50 T−60)を基材としてそのコロナ処理面にグラビアコーターを用いて塗布し、70℃で乾燥させて、厚さ0.8μmの受像層を形成することで静電荷液体現像用受像シートを製造した。この受像層は、表面状態が平滑であり、乾燥後の透明性が優れていた。
次に、グラシン紙の表面にシリコーンを塗布した剥離材(リンテック社製、商品名:SP−8Kアオ、厚さ90μm)の剥離層の表面に、アクリル系粘着剤(東洋インキ製造社製、商品名:オリバインBPS−1109)100重量部に架橋剤(日本ポリウレタン工業社製、商品名:コロネートL)3重量部を添加した粘着剤を乾燥後の厚さが30μmとなるようにロールコーターを用いて塗布し、90℃で1分間乾燥させて粘着剤層を形成した。この剥離材上の粘着剤層を、上記の静電荷液体現像用受像シートの受像層を設けた基材の面の反対面に積層して静電荷液体現像用受像ラベルを製造した。
Example 1:
TMXDI block isocyanate cross-linking agent (Daiichi Kogyo Seiyaku Co., Ltd.) with respect to 100 parts by weight of an aqueous solution type ethylene / acrylic acid copolymer (manufactured by Sumitomo Seika Co., Ltd., trade name: Syxen A, solid content: 25.0% by weight) Product name: Elastron BN-08, solid content: 34.5% by weight, block agent type is oxime, dissociation temperature is 120 ° C, 8 parts by weight (solid content ratio), water / methyl A mixed solvent consisting of 100 parts by weight / 25 parts by weight of alcohol was added and diluted to prepare a coating liquid having a solid content of 9.5% by weight. This coating solution was applied using a gravure coater on the corona-treated surface of a corona-treated polyethylene terephthalate film (trade name: Lumirror # 50 T-60, manufactured by Toray Industries, Inc.) having a thickness of 50 μm, An image receiving sheet for developing an electrostatic charge liquid was manufactured by drying at 70 ° C. to form an image receiving layer having a thickness of 0.8 μm. The image receiving layer had a smooth surface state and excellent transparency after drying.
Next, on the surface of the release layer of a release material (product name: SP-8K Ao, thickness 90 μm) made by applying silicone to the surface of glassine paper, an acrylic adhesive (product made by Toyo Ink Manufacturing Co., Ltd., product) Name: Olivevine BPS-1109) A roll coater was used so that the pressure-sensitive adhesive obtained by adding 3 parts by weight of a crosslinking agent (manufactured by Nippon Polyurethane Industry Co., Ltd., trade name: Coronate L) to 100 parts by weight was 30 μm after drying. And then dried at 90 ° C. for 1 minute to form an adhesive layer. The pressure-sensitive adhesive layer on the release material was laminated on the surface opposite to the surface of the substrate on which the image receiving layer of the image receiving sheet for electrostatic charge liquid development was provided, thereby producing an image receiving label for electrostatic charge liquid development.

実施例2:
水溶液タイプのエチレン・アクリル酸共重合体(マイケルマン社製、商品名:DP1000、固形分:34.0重量%)100重量部に対して実施例1で用いたTMXDIブロックイソシアナート架橋剤6重量部を添加した(固形分比)こと以外は、実施例1と同様にして静電荷液体現像用受像シートと静電荷液体現像用受像ラベルを製造した。
Example 2:
6 parts by weight of the TMXDI block isocyanate cross-linking agent used in Example 1 with respect to 100 parts by weight of an aqueous solution type ethylene / acrylic acid copolymer (manufactured by Michael Mann Co., Ltd., trade name: DP1000, solid content: 34.0% by weight) An electrostatic charge liquid developing image-receiving sheet and an electrostatic charge liquid developing image-receiving label were produced in the same manner as in Example 1 except that the parts were added (solid content ratio).

実施例3:
実施例1で用いた水溶液タイプのエチレン・アクリル酸共重合体100重量部に対して実施例1で用いたTMXDIブロックイソシアナート架橋剤28重量部を添加した(固形分比)こと以外は、実施例1と同様にして静電荷液体現像用受像シートと静電荷液体現像用受像ラベルを製造した。
Example 3:
Except that 28 parts by weight of the TMXDI block isocyanate cross-linking agent used in Example 1 was added (solid content ratio) to 100 parts by weight of the aqueous solution type ethylene / acrylic acid copolymer used in Example 1. In the same manner as in Example 1, an image receiving sheet for developing electrostatic charge liquid and an image receiving label for developing electrostatic charge liquid were produced.

実施例4:
分散液タイプのエチレン・メタクリル酸共重合体(中央理化工業社製、商品名:アクアテックスAC−3100、固形分45.0重量%)100重量部に対して実施例1で用いたTMXDIブロックイソシアナート架橋剤10重量部を添加した(固形分比)こと以外は、実施例1と同様にして静電荷液体現像用受像シートと静電荷液体現像用受像ラベルを製造した。
Example 4:
TMXDI block isocyanate used in Example 1 with respect to 100 parts by weight of a dispersion type ethylene / methacrylic acid copolymer (manufactured by Chuo Rika Kogyo Co., Ltd., trade name: Aquatex AC-3100, solid content 45.0% by weight) An electrostatic charge liquid developing image-receiving sheet and an electrostatic charge liquid developing image-receiving label were produced in the same manner as in Example 1 except that 10 parts by weight of a nart crosslinking agent was added (solid content ratio).

比較例1:
TMXDIブロックイソシアナート架橋剤を添加しなかったこと以外は、実施例1と同様にして静電荷液体現像用受像シートと静電荷液体現像用受像ラベルを製造した。
Comparative Example 1:
An electrostatic charge liquid developing image-receiving sheet and an electrostatic charge liquid developing image-receiving label were produced in the same manner as in Example 1 except that the TMXDI block isocyanate crosslinking agent was not added.

比較例2:
TMXDIブロックイソシアナート架橋剤8重量部のかわりにTDIブロックイソシアナート架橋剤(トリレンジイソシアナート系ブロックイソシアナート架橋剤、第一工業製薬社製、商品名:エラストロンBN−44、固形分:42.0重量%、ブロック剤の種類はオキシム類でその解離温度は120℃)10重量部を添加したこと以外は、実施例1と同様にして静電荷液体現像用受像シートと静電荷液体現像用受像ラベルを製造した。
Comparative Example 2:
Instead of 8 parts by weight of TMXDI block isocyanate crosslinking agent, TDI block isocyanate crosslinking agent (tolylene diisocyanate block isocyanate crosslinking agent, manufactured by Daiichi Kogyo Seiyaku Co., Ltd., trade name: Elastron BN-44, solid content: 42. 0% by weight, the type of blocking agent is an oxime, and its dissociation temperature is 120 ° C.) Except that 10 parts by weight was added, the electrostatic charge liquid developing image-receiving sheet and the electrostatic charge liquid developing image-receiving sheet were the same as in Example 1. A label was manufactured.

比較例3:
TMXDIブロックイソシアナート架橋剤8重量部のかわりにMDIブロックイソシアナート架橋剤(ジフェニルメタンジイソシアナート系ブロックイソシアナート架橋剤、第一工業製薬社製、商品名:エラストロンBN−04、固形分:33.5重量%、ブロック剤の種類はアルキルフェノール類でその解離温度は120℃)8重量部を添加したこと以外は、実施例1と同様にして静電荷液体現像用受像シートと静電荷液体現像用受像ラベルを製造した。
Comparative Example 3:
Instead of 8 parts by weight of TMXDI block isocyanate crosslinker, MDI block isocyanate crosslinker (diphenylmethane diisocyanate block isocyanate crosslinker, manufactured by Daiichi Kogyo Seiyaku Co., Ltd., trade name: Elastron BN-04, solid content: 33. 5% by weight, the type of blocking agent is an alkylphenol and its dissociation temperature is 120 ° C.) Except for the addition of 8 parts by weight, the electrostatic charge liquid developing image-receiving sheet and the electrostatic charge liquid developing image-receiving sheet are the same as in Example 1. A label was manufactured.

(基材と受像層との密着性の評価)
受像層に対してJIS K 5400(1990)に準じたXカットテープ法による評価を行い、Xカット部に剥がれがない場合を10点、Xカット部よりも大きく剥がれた場合を0点とした。結果を表1に示す。
(Evaluation of adhesion between substrate and image-receiving layer)
The image-receiving layer was evaluated by the X-cut tape method according to JIS K 5400 (1990). The case where the X-cut portion did not peel was 10 points, and the case where the X-cut portion was peeled larger than the X-cut portion was defined as 0 point. The results are shown in Table 1.

(トナー画像と受像層との密着性の評価)
実施例及び比較例で得た静電荷液体現像用受像シートのそれぞれについて、定着樹脂がエチレン・(メタ)アクリル酸共重合体を含む静電荷現像用の黒色の液体トナー(ヒューレットパッカード社製の「ElectroInk Mark4.0−Black」)を用いて、静電荷液体現像印刷方式の印刷機(ヒューレットパッカード社製のデジタル印刷機「Press WS 4000」)でベタ印刷を行った(設定転写温度:100℃)。
印刷面にニチバン社製のセロハンテープを20N荷重で貼付後、テープを人手で剥離し、テープを貼付した部分の貼付前と剥離後の反射濃度を分光色差計(日本電色工業社製のハンディ型分光色差計「NF 777CE」)で測定し、この測定値からトナー画像と受像層との密着性を下記式に示す濃度残存率で評価した。結果を表1に示す。
濃度残存率(%)=(剥離後の反射濃度/貼付前の反射濃度)×100
(Evaluation of adhesion between toner image and image receiving layer)
For each of the electrostatic charge liquid developing image-receiving sheets obtained in the examples and comparative examples, a black liquid toner for electrostatic charge development in which the fixing resin contains an ethylene / (meth) acrylic acid copolymer (manufactured by “Hewlett Packard” Electroink Mark 4.0-Black ") was used to perform solid printing on a printer using an electrostatic charge liquid development printing method (digital press" Press WS 4000 "manufactured by Hewlett Packard) (set transfer temperature: 100 ° C) .
After applying the Nichiban cellophane tape to the printed surface with a load of 20 N, the tape is peeled off manually, and the reflection density before and after the tape is applied is measured with a spectral color difference meter (Nippon Denshoku Handy Type spectral color difference meter “NF 777CE”), and the adhesion between the toner image and the image receiving layer was evaluated from the measured value by the residual density ratio shown in the following formula. The results are shown in Table 1.
Concentration residual ratio (%) = (reflection density after peeling / reflection density before application) × 100

Figure 2007272064
Figure 2007272064

表1から明らかなように、静電荷液体現像用受像シートにおける受像層を形成するための塗工液の構成成分としてTMXDIブロックイソシアナート架橋剤を用いた場合に限り、基材と受像層との密着性とトナー画像と受像層との密着性の双方が良好であった(実施例1〜4)。塗工液に架橋剤を添加しない場合、トナー画像と受像層との密着性は良好であったが、基材と受像層との密着性は不良であった(比較例1)。架橋剤としてTDIブロックイソシアナート架橋剤やMDIブロックイソシアナート架橋剤を用いた場合、これらの架橋剤は、TMXDIブロックイソシアナート架橋剤とブロック剤の解離温度が同じであるにもかかわらず、基材と受像層との密着性とトナー画像と受像層との密着性の双方が不良であった(比較例2、3)。
以上のような結果が得られた理由は、次のように考えられる。即ち、イソシアナート基のα位に2つのメチル基を有するTMXDIブロックイソシアナート架橋剤は、ブロック剤の解離温度よりも低い温度でもブロック剤の解離が部分的に起こり、受像層を形成するために採用した70℃という塗工液の乾燥温度でもブロック剤の解離が部分的に起こって活性化したイソシアナート基が基材と受像層との密着性の確保に寄与する一方、この段階では全てのブロック剤が解離せず、その後の100℃という印刷時の転写温度により解離せずに残っていたブロック剤が解離してトナー画像と受像層との密着性の確保に寄与し、結果として基材と受像層との密着性とトナー画像と受像層との密着性の双方を良好にするものと考えられる。これに対し、TDIブロックイソシアナート架橋剤やMDIブロックイソシアナート架橋剤は、70℃というような低温ではブロック剤の解離が起こらず、よって基材と受像層との密着性を確保することができない一方、100℃という印刷時の転写温度でブロック剤の解離が起こり、トナー画像と受像層との密着性の確保に寄与したことから、トナー画像と受像層との密着性の評価を行った場合、基材と受像層との界面で剥がれが起こったものと考えられる。
As apparent from Table 1, only when the TMXDI block isocyanate cross-linking agent is used as a component of the coating liquid for forming the image receiving layer in the image receiving sheet for developing an electrostatic charge liquid, the substrate and the image receiving layer Both the adhesion and the adhesion between the toner image and the image receiving layer were good (Examples 1 to 4). When no crosslinking agent was added to the coating solution, the adhesion between the toner image and the image receiving layer was good, but the adhesion between the substrate and the image receiving layer was poor (Comparative Example 1). When a TDI block isocyanate crosslinker or an MDI block isocyanate crosslinker is used as a crosslinker, these crosslinkers are formed on the base material even though the dissociation temperatures of the TMXDI block isocyanate crosslinker and the block agent are the same. Both the adhesion between the toner image and the image receiving layer and the adhesion between the toner image and the image receiving layer were poor (Comparative Examples 2 and 3).
The reason why the above results are obtained is considered as follows. That is, the TMXDI block isocyanate cross-linking agent having two methyl groups at the α-position of the isocyanate group partially dissociates the blocking agent even at a temperature lower than the dissociation temperature of the blocking agent, and forms an image receiving layer. The isocyanate group activated by partial dissociation of the blocking agent at the drying temperature of the employed coating solution of 70 ° C. contributes to securing the adhesion between the substrate and the image receiving layer. The blocking agent does not dissociate, and the remaining blocking agent does not dissociate due to the transfer temperature at the time of printing of 100 ° C., thereby contributing to ensuring the adhesion between the toner image and the image receiving layer. It is considered that both the adhesion between the toner image and the image receiving layer and the adhesion between the toner image and the image receiving layer are improved. On the other hand, the TDI block isocyanate cross-linking agent and the MDI block isocyanate cross-linking agent do not dissociate the block agent at a low temperature such as 70 ° C., and thus cannot secure the adhesion between the substrate and the image receiving layer. On the other hand, the dissociation of the blocking agent occurred at a printing temperature of 100 ° C., which contributed to ensuring the adhesion between the toner image and the image receiving layer. Therefore, when the adhesion between the toner image and the image receiving layer was evaluated. It is considered that peeling occurred at the interface between the base material and the image receiving layer.

本発明は、静電荷液体現像によるトナー画像との密着性とともに基材との密着性に優れた受像層を設けた静電荷液体現像用受像シート及び静電荷液体現像用受像ラベルを提供することができる点において産業上の利用可能性を有する。   The present invention provides an image receiving sheet for developing an electrostatic charge liquid and an image receiving label for developing an electrostatic charge liquid provided with an image receiving layer having excellent adhesion to a toner image as well as adhesion to a toner image by electrostatic charge liquid development. It has industrial applicability in terms of what it can do.

Claims (5)

基材の少なくとも片面に、エチレン・(メタ)アクリル酸共重合体及びテトラメチルキシリレンジイソシアナートをブロック化したイソシアナート架橋剤を含む塗工液を塗布し乾燥させて受像層を形成してなることを特徴とする静電荷液体現像用受像シート。   An image receiving layer is formed by applying a coating liquid containing an isocyanate cross-linking agent obtained by blocking ethylene / (meth) acrylic acid copolymer and tetramethylxylylene diisocyanate on at least one surface of a base material and drying it. An image receiving sheet for developing an electrostatic charge liquid. 静電荷液体現像に使用する液体トナーの定着樹脂がエチレン・(メタ)アクリル酸共重合体を含むことを特徴とする請求項1記載の静電荷液体現像用受像シート。   2. The image receiving sheet for electrostatic charge liquid development according to claim 1, wherein the fixing resin of the liquid toner used for electrostatic charge liquid development contains an ethylene / (meth) acrylic acid copolymer. 受像層の厚さが0.1〜5.0μmであることを特徴とする請求項1又は2記載の静電荷液体現像用受像シート。   3. The image receiving sheet for electrostatic charge liquid development according to claim 1, wherein the image receiving layer has a thickness of 0.1 to 5.0 [mu] m. 基材に塗布した塗工液の乾燥温度を60〜80℃とすることを特徴とする請求項1乃至3のいずれかに記載の静電荷液体現像用受像シート。   The image receiving sheet for developing an electrostatic charge liquid according to any one of claims 1 to 3, wherein the drying temperature of the coating solution applied to the substrate is 60 to 80 ° C. 請求項1乃至4のいずれかに記載の静電荷液体現像用受像シートの受像層を形成した基材の面の反対面に、粘着剤層及び剥離材をこの順に積層してなることを特徴とする静電荷液体現像用受像ラベル。   A pressure-sensitive adhesive layer and a release material are laminated in this order on the surface opposite to the surface of the substrate on which the image-receiving layer of the image-receiving sheet for electrostatic charge liquid development according to any one of claims 1 to 4 is formed. An image receiving label for developing an electrostatic charge liquid.
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JP2012208150A (en) * 2011-03-29 2012-10-25 Lintec Corp Image-receiving sheet for electrostatic charge liquid development and image receiving adhesive sheet for electrostatic charge liquid development
CN102968004A (en) * 2011-03-29 2013-03-13 琳得科株式会社 Image-receiving sheet for electrostatic charge liquid development and image receiving adhesive sheet for electrostatic charge liquid development
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