JP2007270249A - Special steel for sinter cake supporting stand - Google Patents

Special steel for sinter cake supporting stand Download PDF

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JP2007270249A
JP2007270249A JP2006097114A JP2006097114A JP2007270249A JP 2007270249 A JP2007270249 A JP 2007270249A JP 2006097114 A JP2006097114 A JP 2006097114A JP 2006097114 A JP2006097114 A JP 2006097114A JP 2007270249 A JP2007270249 A JP 2007270249A
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sintering
sinter cake
stand
special steel
raw material
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JP4512564B2 (en
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Susumu Matsuno
松野  進
Yasunari Mitsui
康徳 三井
Atsushi Takagi
敦 高木
Daisuke Shimose
大輔 下瀬
Yohei Ito
洋平 伊藤
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Nippon Steel Corp
Kurimoto Mec Ltd
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Nippon Steel Corp
Kurimoto Mec Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To elongate the service life of a sinter cake supporting stand installed at a sintering pellet in a lower suction type sintering machine. <P>SOLUTION: The special steel used as the material for a sinter cake supporting stand 1 has a composition comprising, by weight, 0.4 to 0.8% C, 0.2 to 2.0% Si, 0.1 to 1.5% Mn, 25 to 29% Cr and 0.2 to 2.0% Ni, and the balance Fe with inevitable impurities. Namely, by making the contents of C and Cr higher than those in the conventional steel, its hardness and corrosion resistance are increased, and its wear resistance is improved, thus the progression of wear is suppressed. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、下方吸引式焼結機の焼結パレットに設置されるシンターケーキ支持スタンドの材料として用いるのに適した特殊鋼に関する。   The present invention relates to a special steel suitable for use as a material for a sinter cake support stand installed on a sintering pallet of a downward suction type sintering machine.

高炉等の製鉄プロセスでは、粉鉄鉱石を焼結機で塊状に焼き固めた焼結鉱を原料として使用することが多い。図3は一般的な焼結機による焼結鉱製造工程を示す。この焼結鉱製造工程では、まず、主原料の粉鉄鉱石、副原料の石灰石および燃料のコークスを、それぞれホッパー11、12、13から切り出し、返鉱ホッパー14から切り出した返鉱とともにミキサー15で調湿、造粒して焼結原料とする。この焼結原料をサージホッパー16に搬送して一旦貯蔵した後、ドラムフィーダー17から切り出し、シュート18を介して焼結パレット19の供給部に供給することにより、焼結パレット19上に焼結原料層20を形成する。そして、焼結パレット19により搬送される焼結原料層20の表層のコークスに点火炉21で点火して、焼結原料層20の下方に空気を吸引しながらコークスを燃焼させ、この燃焼熱で焼結原料層20を上層から下層へ順次焼結していく。この焼結方法を「下方吸引式」という。このようにして焼結が完了した原料は、焼結鉱として焼結パレット19の排出部から排出される。   In iron making processes such as blast furnaces, sintered ore obtained by sintering powder iron ore into a lump with a sintering machine is often used as a raw material. FIG. 3 shows a sinter production process by a general sintering machine. In this sintered ore production process, firstly, the main raw material powdered iron ore, the auxiliary raw material limestone, and the fuel coke are cut out from the hoppers 11, 12, and 13, respectively, and the returned ore cut out from the return hopper 14 together with the mixer 15. Condition and granulate to make a sintered raw material. The sintered raw material is transported to the surge hopper 16 and temporarily stored, then cut out from the drum feeder 17 and supplied to the supply portion of the sintered pallet 19 via the chute 18 so that the sintered raw material is placed on the sintered pallet 19. Layer 20 is formed. Then, the coke on the surface layer of the sintering raw material layer 20 conveyed by the sintering pallet 19 is ignited by an ignition furnace 21, and the coke is burned while sucking air below the sintering raw material layer 20. The sintering raw material layer 20 is sequentially sintered from the upper layer to the lower layer. This sintering method is called “downward suction type”. The raw material thus sintered is discharged from the discharge part of the sintering pallet 19 as sintered ore.

上記のような下方吸引式の焼結方法をとる焼結機では、焼結原料層の上層部が下層部よりも先に焼結されて焼結塊(以下、「シンターケーキ」と記す。)となるため、焼結が進むにつれて原料層の下層部がシンターケーキの重みを受けて圧縮され、高密度になっていく。焼結原料層が高密度化すると、通気性が低下して、コークスの燃焼速度の低下や燃焼むらが生じる。その結果、焼結速度が遅くなるし、焼結パレットから排出される焼結鉱の品質のばらつきも大きくなり、生産性が低下しやすい。そこで、通常は、焼結パレットに、シンターケーキの重みを受ける支持部材(以下、「シンターケーキ支持スタンド」、または単に「スタンド」と記す。)を、焼結原料層に埋没するように設置して、原料層の下層部の高密度化による通気性の低下を防止し、焼結鉱の生産性の向上を図っている。   In a sintering machine that employs the downward suction type sintering method as described above, the upper layer portion of the sintering raw material layer is sintered before the lower layer portion, and is sintered (hereinafter referred to as “sinter cake”). Therefore, as the sintering progresses, the lower layer portion of the raw material layer receives the weight of the sinter cake and is compressed to become high density. When the sintered raw material layer is densified, the air permeability is lowered, resulting in a reduction in the combustion rate of coke and uneven combustion. As a result, the sintering speed is slowed, the quality of the sintered ore discharged from the sintering pallet is highly varied, and the productivity tends to be lowered. Therefore, a support member (hereinafter referred to as “sinter cake support stand” or simply “stand”) that receives the weight of the sinter cake is usually installed on the sintering pallet so as to be buried in the sintering material layer. Therefore, the lowering of the air permeability due to the higher density of the lower layer of the raw material layer is prevented, and the productivity of the sintered ore is improved.

ところで、上記シンターケーキ支持スタンドは、焼結パレットの供給部から排出部へ向かう途中で高さ方向に大きな温度差が生じ、焼結パレットの排出部から供給部へ戻るときには全体が冷却されることにより、繰り返し熱応力を受ける。また、その使用環境は、高温の腐食雰囲気となる。従って、このスタンドを形成する材料は、十分な耐熱疲労性と高温強度を有し、耐食性にも優れたものが望ましい。このような特性を備えた材料として、Cを0.2wt%程度、Crを13wt%程度含む特殊鋼を用いることが提案されている(例えば、特許文献1参照。)。
特許第3151653号公報
By the way, the sinter cake support stand has a large temperature difference in the height direction on the way from the supply part of the sintering pallet to the discharge part, and the whole is cooled when returning from the discharge part of the sintering pallet to the supply part. Due to repeated thermal stress. Moreover, the use environment becomes a hot corrosive atmosphere. Therefore, it is desirable that the material for forming the stand has sufficient heat fatigue resistance and high temperature strength and is excellent in corrosion resistance. As a material having such characteristics, it has been proposed to use a special steel containing about 0.2 wt% C and about 13 wt% Cr (for example, see Patent Document 1).
Japanese Patent No. 3151653

しかしながら、シンターケーキ支持スタンドの材料には、上記の特性に加えて、耐摩耗性も要求される。すなわち、このスタンドは、焼結パレットの供給部に焼結原料が供給されるときや、パレット排出部で焼結完了後の原料が焼結鉱として排出されるときに原料と擦れ合って摩耗する。そして、減肉によりシンターケーキの重みを支えきれなくなって、焼結原料層の通気性低下を防止できなくなると交換が必要となるので、耐摩耗性が寿命の長さを決定する要因の1つとなっている。これに対して、上記特許文献1に記載の特殊鋼で形成したスタンドは、必ずしも耐摩耗性が十分とは言えず、早期摩耗によって短寿命となる場合があった。   However, in addition to the above properties, the material for the sinter cake support stand is also required to have wear resistance. That is, this stand wears by rubbing against the raw material when the sintering raw material is supplied to the supply part of the sintering pallet or when the raw material after completion of sintering is discharged as sintered ore at the pallet discharging part. . And since it is not possible to support the weight of the sinter cake due to thinning and it is not possible to prevent a decrease in air permeability of the sintered raw material layer, it is necessary to replace it. Therefore, wear resistance is one of the factors determining the length of life. It has become. On the other hand, the stand formed of the special steel described in Patent Document 1 cannot always be said to have sufficient wear resistance, and may have a short life due to early wear.

本発明の課題は、下方吸引式焼結機の焼結パレットに設置されるシンターケーキ支持スタンドの長寿命化を図ることである。   An object of the present invention is to extend the life of a sinter cake support stand installed on a sintering pallet of a downward suction type sintering machine.

上記の課題を解決するために、本発明は、シンターケーキ支持スタンドの材料として用いられる特殊鋼の組成を、C:0.4〜0.8wt%、Si:0.2〜2.0wt%、Mn:0.1〜1.5wt%、Cr:25〜29wt%、Ni:0.2〜2.0wt%を含有し、残部がFeおよび不可避的不純物からなるものとした。   In order to solve the above-mentioned problems, the present invention has a composition of a special steel used as a material for a sinter cake support stand, C: 0.4 to 0.8 wt%, Si: 0.2 to 2.0 wt%, It contained Mn: 0.1 to 1.5 wt%, Cr: 25 to 29 wt%, Ni: 0.2 to 2.0 wt%, and the balance was made of Fe and inevitable impurities.

すなわち、この用途では延性不足による割れが比較的生じにくいことに着目し、前述した特許文献1に記載の特殊鋼(従来鋼)に比べて、割れが生じない範囲で、C含有量を増加させて硬度を高めるとともに、Cr含有量を増加させて耐食性をさらに高めることにより、耐摩耗性を向上させてスタンド交換周期を延長できるようにしたのである。   That is, focusing on the fact that cracks due to insufficient ductility are relatively unlikely to occur in this application, the C content is increased in a range where cracks do not occur compared to the special steel described in Patent Document 1 described above (conventional steel). Thus, the hardness is increased, and the Cr content is increased to further enhance the corrosion resistance, thereby improving the wear resistance and extending the stand replacement cycle.

次に、各合金元素の含有量を上記の範囲に限定した理由について説明する。
(1)Cは、一部が母材に固溶して母材を強化するほか、炭化物を形成して、高温強度および硬度を高めるために有効な元素である。必要な高温強度を確保するだけでなく、耐摩耗性を向上させるために、少なくとも0.4wt%含むようにする。含有量が多いほど、高温強度および硬度は高くなるが、高温使用時の時効による2次炭化物の析出量が過剰になって延性の低下を招くようになるので、この用途で延性不足による割れが生じないように、含有量の上限を0.8wt%とした。
Next, the reason why the content of each alloy element is limited to the above range will be described.
(1) C is an element effective for increasing the high-temperature strength and hardness by forming a carbide in addition to strengthening the base material by partly dissolving in the base material. In addition to ensuring the necessary high temperature strength, at least 0.4 wt% is included in order to improve wear resistance. The higher the content, the higher the high-temperature strength and hardness. However, the precipitation amount of secondary carbide due to aging at the time of high-temperature use becomes excessive, leading to a decrease in ductility. The upper limit of the content was set to 0.8 wt% so as not to occur.

(2)Siは、合金溶解時の脱酸元素であり、鋳造工程における溶湯の流動性を高める効果を有する。また、高温における耐食性も向上させる。これらの効果は含有量に比例して向上するが、過剰に含有すると延性低下を招くので、含有量は2.0wt%以下とする。一方、含有量が極端に少ないと、熱サイクルを受けた後に焼きが入りやすくなって延性低下を招くので、0.2wt%以上含有する必要がある。 (2) Si is a deoxidizing element when the alloy is melted, and has the effect of increasing the fluidity of the molten metal in the casting process. It also improves the corrosion resistance at high temperatures. These effects are improved in proportion to the content, but if contained excessively, the ductility is lowered, so the content is set to 2.0 wt% or less. On the other hand, if the content is extremely small, baking is likely to occur after being subjected to a thermal cycle, leading to a reduction in ductility. Therefore, it is necessary to contain 0.2 wt% or more.

(3)Mnは、脱酸作用を有し、またSを固定して無害化する元素であり、0.1wt%以上含有する必要がある。一方、1.5wt%以上に増量しても効果の増加は少ないので、含有量の上限を1.5wt%とした。 (3) Mn is an element having a deoxidizing action and detoxifying by fixing S, and it is necessary to contain 0.1 wt% or more. On the other hand, even if the amount is increased to 1.5 wt% or more, the increase in the effect is small, so the upper limit of the content was set to 1.5 wt%.

(4)Crは、高温強度および耐食性を高める元素である。耐摩耗性の向上に寄与するように耐食性を高めるために、含有量の下限を25wt%とした。しかし、過剰に含有すると延性低下を招くので、この用途で割れが生じないように、上限を29wt%とした。 (4) Cr is an element that improves high-temperature strength and corrosion resistance. In order to improve the corrosion resistance so as to contribute to the improvement of the wear resistance, the lower limit of the content was set to 25 wt%. However, if contained excessively, the ductility is lowered, so the upper limit was made 29 wt% so that cracking would not occur in this application.

(5)Niは、高温強度を高めるために0.2wt%以上含有するようにした。ただし、過剰に含有すると、オーステナイト相が増加し、線膨張係数が大きくなって熱変形が大きくなるので、上限を2.0wt%とした。 (5) Ni is contained in an amount of 0.2 wt% or more in order to increase the high temperature strength. However, since an austenite phase will increase and a linear expansion coefficient will become large and thermal deformation will become large if it contains excessively, the upper limit was 2.0 wt%.

本発明のシンターケーキ支持スタンド用特殊鋼は、上述したように、従来鋼に比べて、この用途で割れが生じない範囲でCおよびCrの含有量を増やすことにより、硬度と耐食性を高めて耐摩耗性を向上させたものである。従って、この特殊鋼をスタンドの材料として用いれば、従来よりもスタンド交換周期が長くなり、新品スタンドの製作費やスタンド交換作業の労務費の減少によりメンテナンスコストの削減が図れる。また、スタンド交換作業のために焼結機全体を休止させる時間が短縮されるので、焼結鉱の生産性を向上させることもできる。   As described above, the special steel for the sinter cake support stand of the present invention increases hardness and corrosion resistance by increasing the content of C and Cr in a range where cracking does not occur in this application compared to conventional steel. Abrasion is improved. Therefore, if this special steel is used as the material of the stand, the stand replacement cycle becomes longer than before, and the maintenance cost can be reduced by reducing the production cost of the new stand and the labor cost of the stand replacement work. Further, since the time for stopping the entire sintering machine for the stand replacement operation is shortened, the productivity of the sintered ore can be improved.

以下、本発明の実施形態を説明する。表1は、実施形態の特殊鋼(実施例1〜3)および従来鋼相当材(比較例)の組成と常温での硬度測定結果(5点平均値)を併せて示す。表1からわかるように、各実施例の硬度はC含有量にほぼ比例して増加し、実施例のうちで最もC含有量が少ないもの(実施例1)でも、比較例に比べて15%以上高い硬度が得られている。   Embodiments of the present invention will be described below. Table 1 shows the composition of the special steel of the embodiment (Examples 1 to 3) and the conventional steel equivalent (comparative example) and the hardness measurement result at room temperature (5-point average value). As can be seen from Table 1, the hardness of each example increased almost in proportion to the C content, and even in the examples (Example 1) having the smallest C content, the hardness was 15% compared to the comparative example. High hardness is obtained.

Figure 2007270249
Figure 2007270249

次に、表1中の実施例の特殊鋼を用いて図1に示すシンターケーキ支持スタンド1を形成した。このスタンド1は、台形板状の本体部2とその下部に連続する取付部3とからなり、図2に示すように、一般的な焼結鉱製造工程(図3参照)の焼結機の焼結パレット19上に2〜4列配置される(図2は2列配置の例)。本体部2の高さは300mmであり、この本体部2が焼結パレット19上に形成されて600mm程度の高さとなる焼結原料層20に埋没し、焼結原料層20の上層部の焼結により生成したシンターケーキを支持するようになっている。   Next, the sinter cake support stand 1 shown in FIG. 1 was formed using the special steels of the examples in Table 1. The stand 1 includes a trapezoidal plate-like main body 2 and a mounting portion 3 continuous therebelow, and as shown in FIG. 2, a stand for a sintering machine in a general sintered ore manufacturing process (see FIG. 3). Two to four rows are arranged on the sintering pallet 19 (FIG. 2 shows an example of two rows). The height of the main body 2 is 300 mm, and the main body 2 is formed on the sintering pallet 19 and buried in the sintering raw material layer 20 having a height of about 600 mm. It is designed to support the sinter cake produced by ligation.

このスタンド1を図2に示した設置状態で連続使用する実験を行った結果、従来鋼で形成したスタンドに比べて摩耗の進行が遅く、交換周期が大幅に延長できた。また、交換時に、割れの発生がないことも確認された。   As a result of conducting an experiment in which the stand 1 is continuously used in the installation state shown in FIG. 2, the progress of wear is slower than that of a stand made of conventional steel, and the replacement cycle can be extended significantly. It was also confirmed that there were no cracks during the replacement.

実施形態の特殊鋼で形成したスタンドの斜視図The perspective view of the stand formed with the special steel of the embodiment 図1のスタンドの設置状態を示す斜視図The perspective view which shows the installation state of the stand of FIG. 一般的な焼結鉱製造工程の説明図Illustration of general sinter manufacturing process

符号の説明Explanation of symbols

1 スタンド
2 本体部
3 取付部
11、12、13、14 ホッパー
15 ミキサー
16 サージホッパー
17 ドラムフィーダー
18 シュート
19 焼結パレット
20 焼結原料層
21 点火炉
DESCRIPTION OF SYMBOLS 1 Stand 2 Main-body part 3 Attachment part 11, 12, 13, 14 Hopper 15 Mixer 16 Surge hopper 17 Drum feeder 18 Chute 19 Sintering pallet 20 Sintering raw material layer 21 Ignition furnace

Claims (1)

下方吸引式焼結機の焼結パレットに設置されるシンターケーキ支持スタンドの材料として用いられ、C:0.4〜0.8wt%、Si:0.2〜2.0wt%、Mn:0.1〜1.5wt%、Cr:25〜29wt%、Ni:0.2〜2.0wt%を含有し、残部がFeおよび不可避的不純物からなるシンターケーキ支持スタンド用特殊鋼。   Used as a material for a sinter cake support stand installed on a sintering pallet of a lower suction type sintering machine, C: 0.4 to 0.8 wt%, Si: 0.2 to 2.0 wt%, Mn: 0. A special steel for a sinter cake support stand containing 1 to 1.5 wt%, Cr: 25 to 29 wt%, Ni: 0.2 to 2.0 wt%, the balance being Fe and inevitable impurities.
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5641354A (en) * 1979-09-11 1981-04-18 Daido Steel Co Ltd Heat resistant steel for precombustion chamber
JPS59123744A (en) * 1982-12-29 1984-07-17 Taiheiyo Kinzoku Kk Roll for galvanization
JPS62501860A (en) * 1985-02-19 1987-07-23 アセア スタ−ル アクテイエボラ−グ Manufacturing method for iron alloy molded products
JPH08291343A (en) * 1995-04-19 1996-11-05 Nippon Steel Corp Sintering operation method and stand inclination correcting device
JPH0941098A (en) * 1995-07-31 1997-02-10 Nippon Steel Corp Special cast steel for sinter cake supporting stand

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5641354A (en) * 1979-09-11 1981-04-18 Daido Steel Co Ltd Heat resistant steel for precombustion chamber
JPS59123744A (en) * 1982-12-29 1984-07-17 Taiheiyo Kinzoku Kk Roll for galvanization
JPS62501860A (en) * 1985-02-19 1987-07-23 アセア スタ−ル アクテイエボラ−グ Manufacturing method for iron alloy molded products
JPH08291343A (en) * 1995-04-19 1996-11-05 Nippon Steel Corp Sintering operation method and stand inclination correcting device
JPH0941098A (en) * 1995-07-31 1997-02-10 Nippon Steel Corp Special cast steel for sinter cake supporting stand

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