JP2007240951A5 - - Google Patents

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JP2007240951A5
JP2007240951A5 JP2006064237A JP2006064237A JP2007240951A5 JP 2007240951 A5 JP2007240951 A5 JP 2007240951A5 JP 2006064237 A JP2006064237 A JP 2006064237A JP 2006064237 A JP2006064237 A JP 2006064237A JP 2007240951 A5 JP2007240951 A5 JP 2007240951A5
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photosensitive member
electrophotographic photosensitive
general formula
member according
substituent
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JP2006064237A
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JP4717665B2 (en
JP2007240951A (en
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Claims (13)

導電性支持体上に、該導電性支持体側から、電荷発生物質を有する電荷発生層と、電荷輸送物質および結着樹脂を有する電荷輸送層と、連鎖重合性官能基を有する化合物を電子線照射によって硬化させることによって得られた樹脂を含有する保護層とを、この順に形成することによって、電子写真感光体を製造する方法において、
膜厚が10μmのときの加速電圧80kVおよび線量4Mradの電子線照射線量に対する電子線遮蔽率が43%以上である樹脂を該電荷輸送層の結着樹脂として用いることを特徴とする電子写真感光体の製造方法
Electron beam irradiation on the conductive support from the conductive support side with a charge generation layer having a charge generation material, a charge transport layer having a charge transport material and a binder resin, and a compound having a chain polymerizable functional group In the method for producing an electrophotographic photosensitive member , by forming a protective layer containing a resin obtained by curing with, in this order ,
Film thickness resin electron beam shielding factor with respect to the electron beam irradiation dose of accelerating voltage 80kV and dose 4Mrad when the 10μm is 4 3% or more, and the Rukoto used as the binder resin of the charge transport layer A method for producing an electrophotographic photoreceptor.
前記電子線遮蔽率が47%以上である請求項1に記載の電子写真感光体の製造方法The method for producing an electrophotographic photosensitive member according to claim 1, wherein the electron beam shielding rate is 47% or more. 前記電荷輸送層の前記結着樹脂が、下記一般式(1)で示される構成単位を有するポリカーボネート重合体又は下記一般式(1)で示される構成単位を有するポリカーボネート共重合体である請求項1又は2に記載の電子写真感光体の製造方法

(式(1)中、R〜Rそれぞれ独立に、水素原子、置換基を有してもよい炭素数1〜3のアルキル基又は置換基を有してもよいアリール基を示す。ただし、R〜Rの少なくとも1つは置換基を有してもよいアリール基を示す。)
The binder resin of the charge transport layer, a polycarbonate polymer having the structural unit represented by the following general formula (1), or, Ru polycarbonate copolymer der having a structural unit represented by the following general formula (1) The method for producing an electrophotographic photosensitive member according to claim 1.

(In the formula (1), R 1 ~R 4 each independently represent a hydrogen atom, an aryl group which may have an alkyl group or a substituent having carbon atoms of 1 to 3 may have a substituent (However, at least one of R 1 to R 4 represents an aryl group which may have a substituent.)
前記一般式(1)中の 置換基を有してもよいアリール基であり、R〜R それぞれ独立に水素原子もしくは置換基を有してもよい炭素数1〜3のアルキル基である請求項3に記載の電子写真感光体の製造方法Wherein R 1 in the general formula (1) is an aryl group which may have a substituent, R 2 to R 4 are each independently a water atom or substituted carbon atoms that may have a group 1 to 3 method for producing an electrophotographic photosensitive member according to an alkyl group der Ru claim 3. 前記一般式(1)中の 置換基を有してもよいビフェニル基である請求項4に記載の電子写真感光体の製造方法 Production method of the above general formula (1) electrophotographic photosensitive member according to claim 4 R 1 is also a good biphenyl Li Le group substituted in. 前記一般式(1)で示される構成単位が、下記一般式(1−1)で示される構成単位である請求項5に記載の電子写真感光体の製造方法
The method for producing an electrophotographic photosensitive member according to claim 5, wherein the structural unit represented by the general formula (1) is a structural unit represented by the following general formula (1-1).
前記一般式(1)中の 置換基を有してもよい炭素数1〜3のアルキル基であり、R 置換基を有してもよい炭素数1〜3のアルキル基又は置換基を有してもよいアリール基であり、R及びR 置換基を有してもよいアリール基である請求項3に記載の電子写真感光体の製造方法R 1 in the general formula (1) is an optionally substituted alkyl group having 1 to 3 carbon atoms, and R 2 is an optionally substituted alkyl group having 1 to 3 carbon atoms, or substituent is an aryl group which may have a, R 3 and R 4 are provided methods for producing the electrophotographic photosensitive member according to claim 3 Ru aryl group der may have a substituent. 前記一般式(1)で示される構成単位が、下記一般式(1−2)で示される構成単位である請求項7に記載の電子写真感光体の製造方法
The method for producing an electrophotographic photosensitive member according to claim 7, wherein the structural unit represented by the general formula (1) is a structural unit represented by the following general formula (1-2).
前記電荷輸送層膜厚13μmのときの加速電圧80kVおよび線量4Mradの電子線照射線量に対する電子線遮蔽率が、47%以上である請求項1に記載の電子写真感光体の製造方法Accelerating voltage 80kV and electron beam shielding factor with respect to the electron beam irradiation dose dose 4Mrad method of manufacturing an electrophotographic photosensitive member according to claim 1 is 4 7% or more when the charge transport layer, the film thickness 13 .mu.m. 前記電荷輸送層の前記電荷輸送物質が下記一般式(2)で示される化合物である請求項に記載の電子写真感光体の製造方法

(式(2)中、R及びRそれぞれ独立に、水素原子、置換基を有してもよいアルキル基、置換基を有してもよいアリール基を示す、あるいは、とRが結合して形成される環状の2価の基を示し、R〜R10それぞれ独立に、置換基を有してもよいアリール基を示す。)
The charge transport material of the charge transport layer, the manufacturing method of the electrophotographic photosensitive member according to claim 9, which is a compound represented by the following general formula (2).

(In the formula (2), R 5 and R 6 are each independently a hydrogen atom, an optionally substituted alkyl group, an aryl group which may have a substituent, or an R 5 represents a divalent group annular R 6 is formed by bonding, R 7 to R 10 each independently represent an aryl group which may have a substituent.)
請求項1〜10のいずれかに記載の製造方法により製造された電子写真感光体。An electrophotographic photosensitive member produced by the production method according to claim 1. 請求項11に記載の電子写真感光体と、該電子写真感光体を帯電させる帯電手段、該電子写真感光体に形成された静電潜像をトナーで現像する現像手段及び電子写真感光体上の転写残りトナーを除去するクリーニング手段からなる群より選ばれる少なくとも1つの手段とを共に一体に支持し、電子写真装置本体に着脱自在であるプロセスカートリッジ。 An electrophotographic photosensitive member according to claim 11, electrophotography charging means for charging the photosensitive member, developing means for developing the electrostatic latent image formed on the electrophotographic photosensitive member with toner and the electrophotographic photoreceptor onto At least one and means both integrally supported, freely der pulp b Seth cartridge detachably attached to an electrophotographic apparatus main body selected from the group consisting of cleaning means for removing transfer residual toner. 請求項11に記載の電子写真感光体、該電子写真感光体を帯電させる帯電手段、帯電した電子写真感光体に対し露光を行って該電子写真感光体に静電潜像を形成する露光手段、該電子写真感光体に形成された静電潜像トナーで現像する現像手段及び電子写真感光体上のトナー像を転写材上に転写する転写手段を備える電子写真装置。 The electrophotographic photosensitive member according to claim 11, charging means for charging the electrophotographic photoreceptor to form an electrostatic latent image on the electrophotographic photosensitive member I rows exposure to charged the electrophotographic photosensitive member exposure means, the electrophotographic photosensitive member formed electrostatic latent image developing to a developing means and an electrophotographic photosensitive member onto a transfer means Ru electronic photographic apparatus comprising a transferred onto a transfer material the toner image on the toner.
JP2006064237A 2006-03-09 2006-03-09 Electrophotographic photosensitive member manufacturing method, electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus Expired - Fee Related JP4717665B2 (en)

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JP2006064237A JP4717665B2 (en) 2006-03-09 2006-03-09 Electrophotographic photosensitive member manufacturing method, electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus

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JP2006064237A JP4717665B2 (en) 2006-03-09 2006-03-09 Electrophotographic photosensitive member manufacturing method, electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus

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JP2007240951A JP2007240951A (en) 2007-09-20
JP2007240951A5 true JP2007240951A5 (en) 2009-04-16
JP4717665B2 JP4717665B2 (en) 2011-07-06

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Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009122185A (en) * 2007-11-12 2009-06-04 Mitsubishi Chemicals Corp Electrophotographic photoreceptor, photoreceptor cartridge provided with the electrophotographic photoreceptor and image forming apparatus
JP5123736B2 (en) * 2008-05-20 2013-01-23 株式会社リコー Electrophotographic photoreceptor, image forming method, image forming apparatus, and process cartridge
JP6015264B2 (en) * 2012-09-12 2016-10-26 富士ゼロックス株式会社 Electrophotographic photosensitive member, process cartridge, and image forming apparatus
JP6003669B2 (en) 2013-01-21 2016-10-05 富士ゼロックス株式会社 Electrophotographic photosensitive member, process cartridge, and image forming apparatus

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3730349B2 (en) * 1997-02-20 2006-01-05 出光興産株式会社 Electrophotographic photoreceptor
JP3981461B2 (en) * 1998-03-30 2007-09-26 三菱化学株式会社 Electrophotographic photoreceptor
JP2001166502A (en) * 1999-12-13 2001-06-22 Canon Inc Electrophotographic photoreceptor, electrophotographic device and process cartridge for electrophotographic device
JP2005345782A (en) * 2004-06-03 2005-12-15 Canon Inc Electrophotographic photoreceptor, process cartridge and electrophotographic apparatus

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