JP2007207624A - Lead storage battery - Google Patents

Lead storage battery Download PDF

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Publication number
JP2007207624A
JP2007207624A JP2006026278A JP2006026278A JP2007207624A JP 2007207624 A JP2007207624 A JP 2007207624A JP 2006026278 A JP2006026278 A JP 2006026278A JP 2006026278 A JP2006026278 A JP 2006026278A JP 2007207624 A JP2007207624 A JP 2007207624A
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water
cell chamber
lead
opening
lead storage
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Japanese (ja)
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Ikumi Motoi
郁美 元井
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GS Yuasa Corp
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GS Yuasa Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Abstract

<P>PROBLEM TO BE SOLVED: To control progression of deterioration of a lead storage battery used in a harsh condition. <P>SOLUTION: A group of electrodes 3 are placed in a plurality of cell chambers 2 divided by partitions 1. On the top of the group of electrodes 3, a water tank 4 having a water filling pipe 41 and a water refilling opening 42 is prepared to store water for supplying to the cell chamber 2. An aperture 41a is formed an end of the water filling pipe 41 so that it responds to the liquid level in each cell chamber 2 and refills water automatically to the cell chamber 2 when the liquid level falls. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は簡素な補水機能を備えた鉛蓄電池に関するものである。   The present invention relates to a lead storage battery having a simple water replenishment function.

鉛蓄電池、特に自動車のボンネット内に収容される自動車用鉛蓄電池は、エンジンの出力向上、排気ガス対策、盗難防止等の機能の拡充によって、その設置スペースが小さくなってきており、前述した機能によって、その設置環境も過酷なものになってきている。また、このような鉛蓄電池は、定電圧充電に近い状態で使用されるため、前述した環境下においては、充電過電圧が低下して充電電流が増加しやすく、電池が満充電近くになると水の電気分解が加速されて電解液中の水分が失われやすく、さらに、このような環境下では、蒸発によっても水分が失われる。   Lead storage batteries, especially lead storage batteries for automobiles housed in the hood of automobiles, have become smaller in installation space due to expansion of functions such as engine output improvement, exhaust gas countermeasures, and anti-theft. The installation environment is becoming harsh. In addition, since such a lead storage battery is used in a state close to constant voltage charging, in the environment described above, the charge overvoltage is reduced and the charging current is likely to increase. Electrolysis is accelerated and moisture in the electrolyte is easily lost. Furthermore, in such an environment, moisture is lost even by evaporation.

電解液中の水分が失われると、硫酸濃度が高くなるため、正極活物質中の二酸化鉛粒子が微細化して結合力を低下させ、電池寿命を短縮させる原因となる。また、電解液面が低下するため、ストラップが露出した状態になってストラップと極板耳部との境界で耳部が腐食して、エンジンの始動といった大電流による放電が難しくなる。   When the water in the electrolyte is lost, the sulfuric acid concentration increases, so that the lead dioxide particles in the positive electrode active material are refined to reduce the bonding force and shorten the battery life. In addition, since the electrolyte level is lowered, the strap is exposed, the ear is corroded at the boundary between the strap and the electrode plate ear, and it becomes difficult to discharge by a large current such as starting the engine.

そのため、定期的な補水、特に設置環境が最も過酷になる夏期においては、頻繁な補水が不可欠となるが、ユーザー自身が定期的な補水を行っていないという状況下において、このような定期的な補水を行うことは煩雑な作業であった。   Therefore, regular water replenishment, especially in the summer when the installation environment is the harshest, frequent replenishment is indispensable, but in the situation where users themselves do not perform regular water replenishment, Replenishing water was a cumbersome task.

このような補水作業の軽減を図るものとして、特許文献1、2のような提案がなされている。
実開昭56−122267号公報 特開平10―188949号公報 上記した特許文献1には、複数のセル室を有するバッテリ本体の上部にバッテリ補充液を貯溜するための密閉可能な補助タンクを設け、この補助タンクの底面にはバッテリ本体の各セル室に連通する連通管を突設し、その連通管の下端を各セル室のバッテリ液の適正レベルまで到達させ、バッテリ液の液面がその連通管の下端より下がり連通管内に空気が流入したときに開弁するフロート弁を連通管内に設けたバッテリ液補充装置が開示されている。また、上記した特許文献2には、開口部にシートで栓をした突起を有した水容器の前記シートを、濃硫酸によって分解する物質を含むものとして該突起を電解液中に浸漬しておき、液面が低下して該シートが破壊されると、容器内に水が電解液中に加えられるようにした自動補水装置が開示されている。
Proposals such as Patent Documents 1 and 2 have been made to reduce such water replenishment work.
Japanese Utility Model Publication No. 56-122267 JP, 10-188949, A In the above-mentioned patent documents 1, the auxiliary tank which can be sealed for storing battery replenisher is provided in the upper part of the battery main part which has a plurality of cell chambers, and a battery is put on the bottom of this auxiliary tank. A communication pipe that communicates with each cell chamber of the main body is protruded, the lower end of the communication pipe reaches the appropriate level of the battery liquid in each cell chamber, the liquid level of the battery liquid falls from the lower end of the communication pipe, and it enters the communication pipe A battery liquid replenishing device is disclosed in which a float valve that opens when air flows in is provided in a communication pipe. Further, in Patent Document 2 described above, the sheet of a water container having a protrusion plugged with a sheet at the opening is immersed in an electrolytic solution, assuming that the sheet contains a substance that is decomposed by concentrated sulfuric acid. An automatic water replenishing device is disclosed in which water is added to an electrolytic solution in a container when the liquid level is lowered and the sheet is destroyed.

上記した特許文献1のものは、バッテリの上部に補助タンクが突出するため、バッテリの占有スペースが増大するという問題があった。また、上記した特許文献2のものは、シートの材質を特殊な素材にしなければならないため、コストの点で好ましくないという問題があった。   The above-mentioned Patent Document 1 has a problem that the space occupied by the battery increases because the auxiliary tank protrudes above the battery. Moreover, since the material of the above-mentioned patent document 2 must make the material of a sheet into a special material, there existed a problem that it was not preferable at the point of cost.

本発明は上記した問題に鑑みてなされたものである。すなわち、本発明は、隔壁によって区画された複数のセル室に極板群を収納し、該極板群の上部に前記セル室に供給するための水を貯蔵した水タンクを配した鉛蓄電池であって、前記水タンクには注水管と補水口とが設けられ、前記注水管は一端に形成した開口部が各セル室の液面位に対応するように設けられ、前記補水口は前記セル室を閉じる液口栓によって閉じられるように設けられていることを特徴(請求項1)とし、また、前記鉛蓄電池において、注水管には糸状体を挿通させるとともに、前記糸状体は一端を開口部から延出させて該開口部を閉塞するための栓体に取り付けられ、他端を液口栓の下面に取り付けられていることを特徴(請求項2)とする。   The present invention has been made in view of the above problems. That is, the present invention is a lead storage battery in which a group of electrode plates is housed in a plurality of cell chambers partitioned by a partition wall, and a water tank storing water for supplying the cell chamber is disposed above the electrode plate group. The water tank is provided with a water injection pipe and a water replenishment port, the water injection pipe is provided so that an opening formed at one end thereof corresponds to the liquid level of each cell chamber, and The lead-acid storage battery is provided with a thread-like body inserted into the water injection pipe, and one end of the thread-like body is opened at one end. The other end is attached to the lower surface of the liquid port plug, and the other end is attached to the stopper for extending the opening and closing the opening.

本発明は、前述した如く、極板群の上部に前記セル室に供給するための水を貯蔵した水タンクを配し、また、水タンクも特殊な材質のものではないから、鉛蓄電池の上部に水タンクが突出して、その占有スペースを増大させたり、コストが上昇したり、といった問題が生じることがない。   In the present invention, as described above, a water tank that stores water to be supplied to the cell chamber is disposed above the electrode plate group, and the water tank is not made of a special material. Therefore, there is no problem that the water tank protrudes to increase the occupied space or increase the cost.

以下、本発明を、その実施の形態に基づいて説明する。   Hereinafter, the present invention will be described based on the embodiments.

図1は、本発明の実施の形態に係る鉛蓄電池の要部切欠き断面図である。   FIG. 1 is a cutaway cross-sectional view of a main part of a lead storage battery according to an embodiment of the present invention.

図1に示したように、本発明係る鉛蓄電池は、隔壁1によって区画された6つのセル室2からなり、各セル室2に極板群3を収納し、各極板群3の上部に、その極板群3が収納されたセル室2に供給するための水を貯蔵し、注水管41と補水口42とを設けた水タンク4を配してなるものである。この水タンク4の材質としては、耐酸性にすぐれたポリエチレン系あるいはポリプロピレン系のものがよい。   As shown in FIG. 1, the lead storage battery according to the present invention includes six cell chambers 2 partitioned by a partition wall 1. Each cell chamber 2 stores an electrode plate group 3. The water to be supplied to the cell chamber 2 in which the electrode plate group 3 is stored is stored, and a water tank 4 provided with a water injection pipe 41 and a water replenishing port 42 is disposed. The material of the water tank 4 is preferably a polyethylene or polypropylene material with excellent acid resistance.

前記水タンク4には、注水管41と補水口42とが設けられ、前記注水管41は一端に形成した開口部41aが各セル室2の液面位に対応するように設けられている。このように水タンク4を設ける方法としては、セル室2に極板群3を収納した後、正極または負極のストラップ上に載置するようにしてもよいが、前記注水管41の開口部41aが各セル室2の所定液面位(たとえば、最高液面位と最低液面位の中間位置)になる位置の電槽の内壁に突起を形成しておき、この突起によって保持するようにしてもよい。   The water tank 4 is provided with a water injection pipe 41 and a water replenishing port 42, and the water injection pipe 41 is provided so that an opening 41 a formed at one end corresponds to the liquid level of each cell chamber 2. As a method of providing the water tank 4 in this way, the electrode plate group 3 may be accommodated in the cell chamber 2 and then placed on the positive or negative strap, but the opening 41a of the water injection pipe 41 may be provided. A protrusion is formed on the inner wall of the battery case at a position where each cell chamber 2 is at a predetermined liquid level (for example, an intermediate position between the highest liquid level and the lowest liquid level). Also good.

前記補水口42は前記セル室2を閉じる液口栓5によって鉛蓄電池の注液口6とともに閉じられる位置に設けられている。このような構成とするために、液口栓5には、図示した如く、水タンク4の補水口42を閉じるための下部螺着部51と注液口6を閉じるための上部螺着部52とが形成されており、好ましくは、水タンク4と注液口6との間隔に応じて柔軟であるように、下部螺着部51と上部螺着部52との間をベローズ構造のように弾力性を持たせたものにしておくのがよい。   The water replenishing port 42 is provided at a position to be closed together with the liquid injection port 6 of the lead storage battery by a liquid port plug 5 that closes the cell chamber 2. In order to achieve such a configuration, the liquid spout 5 has a lower threaded portion 51 for closing the water replenishing port 42 of the water tank 4 and an upper threaded portion 52 for closing the liquid injection port 6 as shown in the figure. Preferably, the space between the lower screwing portion 51 and the upper screwing portion 52 is like a bellows structure so as to be flexible according to the interval between the water tank 4 and the liquid injection port 6. It should be kept elastic.

また、前記液口栓5には、図示した如く、下端に耐酸性の糸状体5aが取り付けられるとともに、その先端に耐酸性の球体5bが取り付けられており、この糸状体5aは前記注液口6、補水口42、注水管41を挿通させておいて、液口栓5を開いた際には糸状体5aによって先端の球体5bが引っ張られて開口部41aが閉鎖されるようにしている。なお、糸状体5aとしては、前記水タンク4と同様に、耐酸性のもの、特に強度の点でもすぐれているポリプロピレン系のものがよく、前記球体5bも、糸状体5aと同様に、耐酸性のもので、強度の点でもすぐれているポリプロピレン系のものがよい。   Further, as shown in the drawing, an acid-resistant thread-like body 5a is attached to the lower end of the liquid spout 5 and an acid-resistant sphere 5b is attached to the tip thereof. 6, the water replenishing port 42 and the water injection pipe 41 are inserted, and when the liquid spout 5 is opened, the sphere 5b at the tip is pulled by the filament 5a to close the opening 41a. In addition, as the filament 5a, like the water tank 4, an acid-resistant one, particularly a polypropylene-based one excellent in strength, may be used. The sphere 5b is also acid-resistant like the filament 5a. Polypropylene type that is excellent in strength is also preferable.

次に、このような構成からなる鉛蓄電池の動作について説明する。   Next, the operation of the lead storage battery having such a configuration will be described.

前述した如き過酷な環境下で鉛蓄電池が使用されると、電解液中の水分が失われて液面が低下し、液面と開口部41aとの間に隙間ができることになる。このような隙間ができると、通常の使用状態においては、液口栓5が閉じられていることによって球体5bによって開口部41aが開放されているため、前述した隙間によって、水タンク4からの水が開口部41aを通って電解液に加えられて、液面を適正レベルにまで戻すことができる。   When the lead storage battery is used under the harsh environment as described above, the water in the electrolytic solution is lost, the liquid level is lowered, and a gap is formed between the liquid level and the opening 41a. If such a gap is formed, the opening 41a is opened by the sphere 5b when the liquid spout 5 is closed in a normal use state, so that the water from the water tank 4 is opened by the gap described above. Is added to the electrolytic solution through the opening 41a, and the liquid level can be returned to an appropriate level.

そして、一旦、水タンク4からの水が電解液に加えられると、水タンク4内はほぼ空になる。前述の特許文献2のものでは、水タンク4に対応するゴム製容器が設けられているが、このゴム製容器では水がなくなると、補充することはできないのに対し、本発明のものは、液口栓5を開くと、球体5bが糸状体5aによって引っ張られて開口部41aを閉鎖するので、注液口6と補水口42を介して水タンク4内に水を補充することができる。また、水を補充する際、補水口42から溢れ出ることも考えられるが、溢れ出ても電解液中に加わるだけであるため、このことによる問題はない。なお、水が補水口42から溢れ出るのが好ましくないときには、スポイトなどを用いるのがよい。   Once the water from the water tank 4 is added to the electrolyte, the water tank 4 is almost empty. In the thing of the above-mentioned patent document 2, although the rubber container corresponding to the water tank 4 is provided, when water runs out in this rubber container, it cannot replenish, whereas the thing of the present invention is When the liquid spout 5 is opened, the sphere 5b is pulled by the filament 5a and closes the opening 41a, so that the water tank 4 can be replenished with water through the liquid injection port 6 and the water replenishment port 42. Moreover, when water is replenished, it is conceivable that the water will overflow from the water replenishing port 42. However, even if the water overflows, it is only added to the electrolyte solution, so that there is no problem due to this. In addition, when it is not preferable that water overflows from the water replenishing port 42, it is preferable to use a dropper or the like.

本発明によれば、過酷な環境下で使用されることによって液面が低下した鉛蓄電池に、簡素な構成からなる自動補水機能を設けたものであるから、前述した環境下での使用時においても、劣化の進行を抑えることができ、その産業上の利用可能性が大である。   According to the present invention, the lead rechargeable battery whose liquid level is lowered by being used in a severe environment is provided with an automatic water replenishment function having a simple configuration. However, the progress of deterioration can be suppressed, and its industrial applicability is great.

本発明の実施形態に係る鉛蓄電池の一部切欠き断面図。1 is a partially cutaway cross-sectional view of a lead storage battery according to an embodiment of the present invention.

符号の説明Explanation of symbols

1 隔壁
2 セル室
3 極板群
4 水タンク
41 注水管
41a 開口部
42 補水口
5 液口栓
51 下部螺着部
52 上部螺着部
5a 糸状体
5b 球体
6 注液口
DESCRIPTION OF SYMBOLS 1 Partition 2 Cell chamber 3 Electrode plate group 4 Water tank 41 Water injection pipe 41a Opening part 42 Water replenishment port 5 Liquid port stopper 51 Lower screwing part 52 Upper screwing part 5a Filamentous body 5b Sphere 6 Injection hole

Claims (2)

隔壁によって区画された複数のセル室に極板群を収納し、該極板群の上部に前記セル室に供給するための水を貯蔵した水タンクを配した鉛蓄電池であって、前記水タンクには注水管と補水口とが設けられ、前記注水管は一端に形成した開口部が各セル室の液面位に対応するように設けられ、前記補水口は前記セル室を閉じる液口栓によって閉じられるように設けられていることを特徴とする鉛蓄電池。 A lead acid battery in which a group of electrode plates is stored in a plurality of cell chambers partitioned by a partition wall, and a water tank storing water for supplying to the cell chamber is disposed above the electrode plate group. Are provided with a water injection pipe and a water replenishment opening, the water injection pipe is provided with an opening formed at one end corresponding to the liquid level of each cell chamber, and the water replenishment opening closes the cell chamber. A lead-acid battery, wherein the lead-acid battery is provided so as to be closed. 請求項1記載の鉛蓄電池において、注水管には糸状体を挿通させるとともに、前記糸状体は一端を開口部から延出させて該開口部を閉塞するための栓体に取り付けられ、他端を液口栓の下面に取り付けられていることを特徴とする鉛蓄電池。 2. The lead-acid battery according to claim 1, wherein a thread-like body is inserted into the water injection pipe, and the thread-like body is attached to a plug for extending one end from the opening and closing the opening, and the other end is attached. A lead-acid battery, characterized in that it is attached to the lower surface of the liquid spigot.
JP2006026278A 2006-02-02 2006-02-02 Lead storage battery Pending JP2007207624A (en)

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JP2006026278A JP2007207624A (en) 2006-02-02 2006-02-02 Lead storage battery

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