JP2007189926A - Meat quality improver, and method for producing meat processed product - Google Patents

Meat quality improver, and method for producing meat processed product Download PDF

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JP2007189926A
JP2007189926A JP2006009621A JP2006009621A JP2007189926A JP 2007189926 A JP2007189926 A JP 2007189926A JP 2006009621 A JP2006009621 A JP 2006009621A JP 2006009621 A JP2006009621 A JP 2006009621A JP 2007189926 A JP2007189926 A JP 2007189926A
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meat
quality improver
transglutaminase
producing
vinegar
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Miyuki Kako
美由紀 加古
Tatsuya Kubota
達也 窪田
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Ajinomoto Co Inc
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Ajinomoto Co Inc
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a meat quality improver for obtaining a meat processed product having good palate feeling and a higher product yield: and to provide a method for producing a meat processed product having good palate feeling and a higher product yield. <P>SOLUTION: The meat quality improver comprises transglutaminase and vinegar (1). The meat quality improver comprises calcium hydrate and/or calcium oxide, and trisodium citrate (2). The meat quality improver, wherein the vinegar is malic acid (3). The method for producing a meat processed product comprises using the meat quality improver (4). <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は食感が良好で製品歩留まりの高い食肉加工品を得るための食肉改質剤及び食感が良好で製品歩留まりの高い食肉加工品の製造法に関する。   The present invention relates to a meat modifier for obtaining a processed meat product having a good texture and a high product yield, and a method for producing a processed meat product having a good texture and a high product yield.

ハム・ソーセージ等の食肉加工品の製造において、加熱歩留まり等加工時の製品歩留まりを向上させる目的で、ピロリン酸塩、重合リン酸塩等のリン酸塩が一般に添加されているが、リン酸塩過剰摂取を懸念する消費者のニーズに応じ、リン酸塩不使用の食肉加工品も上市されている。リン酸塩不使用の食肉加工品の製造法として、特許文献1には、水酸化カルシウム・酸化カルシウムと、クエン酸3ナトリウム・クエン酸3カリウムとトランスグルタミナーゼとを含む食肉単味品用製剤、ピックルが開示されている。特許文献2には、トランスグルタミナーゼを用いたリン酸塩無添加の食肉製品の製造法が開示されている。
特開2004−248661号公報 特開平2−135071号公報
In the manufacture of processed meat products such as ham and sausage, phosphates such as pyrophosphate and polymerized phosphate are generally added to improve the product yield during processing such as heating yield. According to the needs of consumers concerned about overdose, processed meat products that do not use phosphates are also on the market. As a method for producing a phosphate-free processed meat product, Patent Document 1 discloses a preparation for a simple meat product containing calcium hydroxide / calcium oxide, trisodium citrate / tripotassium citrate and transglutaminase, A pickle is disclosed. Patent Document 2 discloses a method for producing a meat product without transphosphate using transglutaminase.
JP 2004-248661 A Japanese Patent Laid-Open No. 2-135071

本発明は、食感が良好で製品歩留まりの高い食肉加工品を得るための食肉改質剤及び食感が良好で製品歩留まりの高い食肉加工品の製造法を提供することを目的とする。   An object of the present invention is to provide a meat modifier for obtaining a processed meat product having a good texture and a high product yield, and a method for producing a processed meat product having a good texture and a high product yield.

本発明者らは、前記課題を解決する為、鋭意検討を重ねた結果、トランスグルタミナーゼ及び食酢を含むことを特徴とする食肉改質剤、或いは、さらに水酸化カルシウム及び/又は酸化カルシウムと、クエン酸三ナトリウムを含むことを特徴とする食肉改質剤を用いることにより、食感がパサつくことなく良好で、加熱等加工時の製品歩留まりの高い食肉加工品を製造できることを見出した。即ち、本発明は以下の通りである。   As a result of intensive studies to solve the above problems, the present inventors have found that a meat modifier characterized by containing transglutaminase and vinegar, or further calcium hydroxide and / or calcium oxide, It has been found that by using a meat modifier characterized by containing trisodium acid, it is possible to produce a processed meat product that has a good texture without being prickly and has a high product yield during processing such as heating. That is, the present invention is as follows.

(1)トランスグルタミナーゼ及び食酢を含むことを特徴とする食肉改質剤。
(2)さらに水酸化カルシウム及び/又は酸化カルシウムと、クエン酸三ナトリウムを含むことを特徴とする(1)記載の食肉改質剤。
(3)食酢がリンゴ酢である(1)又は(2)記載の食肉改質剤。
(4)(1)乃至(3)記載の食肉改質剤を用いることを特徴とする食肉加工品の製造法。
(1) A meat modifier comprising transglutaminase and vinegar.
(2) The meat modifier according to (1), further comprising calcium hydroxide and / or calcium oxide and trisodium citrate.
(3) The meat modifier according to (1) or (2), wherein the vinegar is apple vinegar.
(4) A method for producing a processed meat product, wherein the meat modifier according to (1) to (3) is used.

本発明の効果として、リン酸塩を使用せずとも、食感が良好で製品歩留まりの高い食肉加工品を製造することができる。   As an effect of the present invention, a processed meat product having a good texture and a high product yield can be produced without using a phosphate.

本発明の食肉改質剤は、トランスグルタミナーゼ及びリンゴ酢等の食酢が成分として含まれていればよく、さらに水酸化カルシウム及び/又は酸化カルシウムと、クエン酸三ナトリウムが含まれていればより好ましい。その他、食塩、グルタミン酸ナトリウム、砂糖、醤油等の調味料、香辛料、パイナップル、リンゴ等の果汁、大豆蛋白、乳蛋白等が含まれていてもよい。   The meat modifier of the present invention only needs to contain vinegars such as transglutaminase and apple vinegar as components, and more preferably calcium hydroxide and / or calcium oxide and trisodium citrate are contained. . In addition, seasonings such as salt, sodium glutamate, sugar and soy sauce, spices, fruit juices such as pineapple and apple, soy protein, milk protein and the like may be included.

食肉改質剤を用いる方法は、水に混合した上で、ピックル液として、食肉を浸漬させてもよいし、食肉に注入してもよい。   The method using the meat modifier may be mixed with water and then dipped into the meat as a pickle solution or injected into the meat.

本発明で使用するトランスグルタミナーゼは、トランスグルタミナーゼ活性を有する限り、その起源を特に問わず、例えばストレプトベルチシリウム属(Streptoverticillium属)などに属する微生物由来のもの(特開昭64−27471参照)、モルモットなどの哺乳動物由来のもの(特公平1ー50382号参照)、タラなどの魚類由来のもの(関信夫ら、昭和63年度日本水産学会秋期大会講演要旨集167頁参照)、バイオテクノロジーを利用して遺伝子組換法によって得られるもの(特開平1ー300889号、特開平6ー225775号参照)などを用いることができる。この内、カルシウムが無くても作用する事及び大量に入手できる事等の理由から微生物由来のトランスグルタミナーゼを用いるのが好ましい。   The transglutaminase used in the present invention is not particularly limited as long as it has transglutaminase activity. Derived from mammals such as guinea pigs (see Japanese Patent Publication No. 1-50382), derived from fish such as cod (see Nobuo Seki et al. And the like obtained by gene recombination (see JP-A-1-3000889 and JP-A-6-225775). Among these, it is preferable to use a microorganism-derived transglutaminase because it works without calcium and is available in large quantities.

なお、本発明でいうトランスグルタミナーゼの活性単位は、次のように測定され、かつ、定義される。すなわち、温度37℃、pH6.0のトリス緩衝液中、ベンジルオキシカルボニル−L−グルタミルグリシン及びヒドロキシルアミンを基質とする反応系で、トランスグルタミナーゼを作用せしめ、生成したヒドロキサム酸をトリクロロ酢酸存在下で鉄錯体を形成させた後、525nmにおける吸光度を測定し、ヒドロキサム酸量を検量線により求め、1分間に1μモルのヒドロキサム酸を生成せしめた酵素を1ユニット(1U)とする(特開昭64−27471号明細書記載参照)。   The activity unit of transglutaminase referred to in the present invention is measured and defined as follows. That is, in a reaction system using benzyloxycarbonyl-L-glutamylglycine and hydroxylamine as substrates in a Tris buffer solution at a temperature of 37 ° C. and pH 6.0, transglutaminase was allowed to act, and the resulting hydroxamic acid was added in the presence of trichloroacetic acid. After the iron complex was formed, the absorbance at 525 nm was measured, the amount of hydroxamic acid was determined by a calibration curve, and the enzyme that produced 1 μmol of hydroxamic acid per minute was defined as 1 unit (1 U) (JP-A-64). -27471 description).

トランスグルタミナーゼの食肉への添加量は、食肉100g当り、0.1〜1000ユニットが好ましく、1〜100ユニットがより好ましい。食酢の添加量は、食肉100g当り、0.02〜4gが好ましく、0.1〜2gがより好ましい。クエン酸三ナトリウムの添加量は食肉100g当り、0.1〜10gが好ましく、0.2〜5gがより好ましい。水酸化カルシウム、酸化カルシウムの添加量は、食肉100g当り、水酸化カルシウム、酸化カルシウムの合計が0.01〜1gが好ましく、0.02〜0.2gがより好ましい。   The amount of transglutaminase added to the meat is preferably 0.1 to 1000 units, more preferably 1 to 100 units per 100 g of meat. The amount of vinegar added is preferably 0.02 to 4 g and more preferably 0.1 to 2 g per 100 g of meat. The amount of trisodium citrate added is preferably 0.1 to 10 g, more preferably 0.2 to 5 g per 100 g of meat. The added amount of calcium hydroxide and calcium oxide is preferably 0.01 to 1 g, more preferably 0.02 to 0.2 g, per 100 g of meat.

本発明の食肉改質剤に含まれる食酢の量は特に限定されないが、トランスグルタミナーゼ1ユニット当り、0.01〜0.5gが好ましい。本発明の食肉改質剤に含まれるクエン酸三ナトリウム、水酸化カルシウム、酸化カルシウムの量も特に限定されないが、クエン酸三ナトリウムの量はトランスグルタミナーゼ1ユニット当り、0.01〜0.5gが好ましい。水酸化カルシウム、酸化カルシウムの添加量は、トランスグルタミナーゼ1ユニット当り、水酸化カルシウム、酸化カルシウムの合計が0.001〜0.1gが好ましい。   The amount of vinegar contained in the meat modifier of the present invention is not particularly limited, but is preferably 0.01 to 0.5 g per unit of transglutaminase. The amount of trisodium citrate, calcium hydroxide, and calcium oxide contained in the meat modifier of the present invention is not particularly limited, but the amount of trisodium citrate is 0.01 to 0.5 g per unit of transglutaminase. preferable. The added amount of calcium hydroxide and calcium oxide is preferably 0.001 to 0.1 g in total for calcium hydroxide and calcium oxide per unit of transglutaminase.

以下に実施例を挙げ、本発明をさらに詳しく説明する。本発明は、この実施例により何ら限定されない。   The following examples further illustrate the present invention. The present invention is not limited in any way by this example.

豪州産冷凍牛肉(2.5cm角、ブリスケットナーベル)300gを半解凍状態で表1に示した配合のピックル液60gに浸漬し、冷蔵庫内に一晩置いた。得られた浸漬肉に450gの市水を加え2時間煮熟した。得られた煮熟肉の重量を測定し歩留まりを算出するとともに、官能評価を行なった。結果を表2に示す。表2に示したように、トランスグルタミナーゼ、食酢(リンゴ酢)を含んだ食肉改質剤を用いることにより、或いはトランスグルタミナーゼ、食酢(リンゴ酢)、クエン酸ナトリウム、酸化カルシウムを含んだ食肉改質剤を用いることにより、食感が良好で製品歩留まりの高い食肉加工品を製造することができた。尚、トランスグルタミナーゼ製剤として用いた味の素社製「アクティバ」TG−HPは、製剤100g当り、トランスグルタミナーゼ10ユニット、クエン酸三ナトリウム92.4g、貝殻焼成カルシウム=酸化カルシウム6.2gを含有している。   300 g of Australian frozen beef (2.5 cm square, brisket navel) was immersed in 60 g of pickle solution having the composition shown in Table 1 in a half-thawed state and placed in a refrigerator overnight. 450 g of city water was added to the obtained soaked meat and boiled for 2 hours. The weight of the resulting boiled meat was measured to calculate the yield, and sensory evaluation was performed. The results are shown in Table 2. As shown in Table 2, by using a meat modifier containing transglutaminase and vinegar (apple vinegar), or meat modification containing transglutaminase, vinegar (apple vinegar), sodium citrate and calcium oxide By using the agent, it was possible to produce a processed meat product having a good texture and a high product yield. “Activa” TG-HP manufactured by Ajinomoto Co., Inc. used as a transglutaminase preparation contains 10 units of transglutaminase, 92.4 g of trisodium citrate, and calcined shell calcium = 6.2 g of calcium oxide per 100 g of the preparation. .

Figure 2007189926
Figure 2007189926

Figure 2007189926
Figure 2007189926

本発明によれば、リン酸塩を使用せずとも、食感が良好で製品歩留まりの高い食肉加工品を製造することができるので、本発明は食品分野において極めて有用である。   According to the present invention, a processed meat product having a good texture and a high product yield can be produced without using a phosphate, so that the present invention is extremely useful in the food field.

Claims (4)

トランスグルタミナーゼ及び食酢を含むことを特徴とする食肉改質剤。   A meat modifier comprising transglutaminase and vinegar. さらに水酸化カルシウム及び/又は酸化カルシウムと、クエン酸三ナトリウムを含むことを特徴とする請求項1記載の食肉改質剤。   The meat modifier according to claim 1, further comprising calcium hydroxide and / or calcium oxide and trisodium citrate. 食酢がリンゴ酢である請求項1又は2記載の食肉改質剤。   The meat modifier according to claim 1 or 2, wherein the vinegar is apple vinegar. 請求項1乃至3記載の食肉改質剤を用いることを特徴とする食肉加工品の製造法。   A method for producing a processed meat product, wherein the meat modifier according to claim 1 is used.
JP2006009621A 2006-01-18 2006-01-18 Meat quality improver, and method for producing meat processed product Pending JP2007189926A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012254022A (en) * 2011-06-07 2012-12-27 Yoichi Tezuka Method for injecting pickle liquid
KR20220159980A (en) 2020-03-30 2022-12-05 제이-오일 밀스, 인코포레이티드 Manufacturing method of processed meat products

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012254022A (en) * 2011-06-07 2012-12-27 Yoichi Tezuka Method for injecting pickle liquid
KR20220159980A (en) 2020-03-30 2022-12-05 제이-오일 밀스, 인코포레이티드 Manufacturing method of processed meat products

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