JP2007146060A - Thermoplastic polyester resin molded article - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To obtain a thermoplastic polyester resin molded article composed of a thermoplastic polyester resin composition capable of developing stabilized processability in injection molding, calendering, film molding, extrusion molding, blow molding, compression molding, transfer molding, thermoforming, flow forming, laminate molding, etc., by efficiently improving melting viscosity of a thermoplastic polyester resin. <P>SOLUTION: The thermoplastic polyester resin molded article comprises (A) 100 pts.wt. thermoplastic polyester resin and (B) 0.1-50 pts.wt. thickener obtained by polymerizing a mixture composed of (a) 70-95 wt.% aromatic vinyl monomer, (b) 5-30 wt.% alkyl acrylate in which carbon number of alkyl group is 1-8 and (c) 0-10 wt.% other vinyl monomer copolymerizable with those. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

  The present invention includes thermoplastic polyester resin injection molding, calender molding, film molding, extrusion molding, blow molding, compression molding, transfer molding, thermoforming, fluid molding, laminate molding, foam molding, especially atypical shapes, boards, pipes, etc. The present invention relates to a thermoplastic polyester resin molded article obtained by molding a thermoplastic polyester resin composition having excellent molding processability in extrusion molding.

  Thermoplastic polyester resin is a polymer with excellent transparency, mechanical properties, gas barrier properties, physical properties such as heat resistance, chemical properties such as solvent resistance, acid resistance, and alkali resistance, economy, and reusability. Yes, it is widely used in various fields mainly for packaging materials such as bottles. In particular, recently, studies have been made on extrusion applications such as sheet, film, and profile extrusion, taking advantage of surface properties.

  On the other hand, since thermoplastic polyester resins such as polyethylene terephthalate and polybutylene terephthalate generally have a large temperature dependence of melt viscosity, injection molding, calender molding, film molding, extrusion molding, blow molding performed in a temperature range above the melting point. In melt processing such as compression molding, transfer molding, thermoforming, fluid molding, lamination molding and foam molding, and particularly in melt processing such as extrusion molding, the melt viscosity is low and disadvantageous.

  For the purpose of improving the molding processability of thermoplastic polyester resins, studies have been conventionally made on blending a copolymer having compatibility with these resins as a melt viscosity modifier (thickener).

  For example, a method of blending a copolymer made of a specific methacrylic acid ester having a weight average molecular weight of 500,000 or more with respect to a thermoplastic resin (see Patent Document 1), a weight average with respect to a thermoplastic polyester resin A method of blending a copolymer comprising styrene, glycidyl methacrylate and (meth) acrylic acid ester having a molecular weight of 1,000,000 to 4,000,000 (see Patent Document 2), and 5% by weight or more of glycidyl methacrylate with respect to polyethylene terephthalate A method of blending a vinyl-based copolymer containing a polymer (see Patent Document 3) and a method of adding a polyglycidyl methacrylate having a weight average molecular weight of 900 or more (see Patent Document 4) are disclosed.

  However, both the increase in the melt viscosity of the thermoplastic polyester resin composition and the maintenance of the high transparency and gloss of the molded article are sufficient to ensure stable moldability in extrusion molding such as boards, profiles, and pipes. It was difficult.

  For example, when a copolymer obtained by copolymerizing a monomer having reactivity with a thermoplastic polyester resin typified by glycidyl methacrylate is blended as a thickener, the melt viscosity of the thermoplastic polyester resin increases. On the other hand, the surface of the obtained molded body may be whitened, and an undesired tendency that transparency and gloss are lowered may be observed.

For this reason, in extrusion molding, injection molding, blow molding, calendar molding, and the like, there has been a strong demand for a technique that achieves both stable molding processability, high transparency of molded products, and maintenance of gloss.
JP-A-1-268761 JP-A-6-41376 JP 62-187756 A Japanese Patent Laid-Open No. 62-149746

  The present invention dramatically increases the melt viscosity of the thermoplastic polyester resin, such as injection molding, calender molding, film molding, extrusion molding, blow molding, compression molding, transfer molding, thermoforming, fluid molding, laminate molding, foam molding, etc. A thermoplastic polyester resin obtained by molding and processing a thermoplastic polyester resin composition containing a thickening agent to obtain a molded article having a good surface property and excellent impact resistance An object is to obtain a molded product.

  Based on the actual situation as described above, the present inventors have conducted intensive studies, and as a result, a thermoplastic polyester obtained by blending a monomer mixture of a specific type and amount as a thickener for a thermoplastic polyester resin. By using a resin composition, it has been found that a molded article having a dramatic thickening effect and excellent transparency and gloss can be obtained, and the above-mentioned problems can be solved, and the present invention has been completed.

  That is, the present invention relates to (a) 70 to 95% by weight of an aromatic vinyl monomer and (b) an alkyl acrylate having 1 to 8 carbon atoms in the alkyl group, based on 100 parts by weight of the thermoplastic polyester resin (A). ~ 30% by weight, and (c) 0 to 10% by weight of other vinyl monomers copolymerizable with them [100% by weight of (a), (b) and (c) combined]] The present invention relates to a molded product of a thermoplastic polyester resin characterized by containing 0.1 to 50 parts by weight of a sticking agent (B).

  In a preferred embodiment, the monomer constituting the thickener (B) does not contain an epoxy group, an isocyanate group, an oxazoline group, a hydroxy group, a carboxy group, an alkoxy group, an acid anhydride group, and an acid chloride group. The present invention relates to a molded article of the thermoplastic polyester resin, which is a monomer.

  In a preferred embodiment, the thermoplastic polyester resin molding process, wherein the alkyl acrylate (b) constituting the thickener (B) is an alkyl acrylate having an alkyl group having 1 to 4 carbon atoms. Related to goods.

  In a preferred embodiment, the thermoplastic polyester resin molding process is characterized in that the alkyl acrylate (b) constituting the thickener (B) is an alkyl acrylate having 1 to 2 carbon atoms in the alkyl group. Related to goods.

  A preferred embodiment relates to the thermoplastic polyester resin molded article, wherein the thickener (B) has a weight average molecular weight of 10,000 to 4,000,000.

  A preferred embodiment relates to the thermoplastic polyester resin molded product, wherein the thickener (B) has a weight average molecular weight of 10,000 to 400,000.

  A preferred embodiment relates to the thermoplastic polyester resin molded product, wherein the thickener (B) has a refractive index of 1.55 to 1.58.

  In a preferred embodiment, a thermoplastic polyester resin molded article is obtained by injection molding, calender molding, film molding, extrusion molding, blow molding, compression molding, transfer molding, thermoforming, fluid molding, laminate molding, or foam molding. The present invention relates to a molded article of the thermoplastic polyester resin.

  A preferred embodiment relates to the above-mentioned thermoplastic polyester resin molded article, wherein the thermoplastic polyester resin molded article is a fibrous molded article.

  A preferred embodiment relates to the above-mentioned thermoplastic polyester resin molded processed product, wherein the thermoplastic polyester resin molded processed product is a sheet-shaped molded processed product.

  A preferred embodiment relates to the above-mentioned thermoplastic polyester resin molded article, wherein the thermoplastic polyester resin molded article is a film-like molded article.

  A preferred embodiment relates to the above-mentioned thermoplastic polyester resin molded product, wherein the thermoplastic polyester resin molded product is a pipe-shaped molded product.

  A preferred embodiment relates to the above-described thermoplastic polyester resin molded processed product, wherein the thermoplastic polyester resin molded processed product is an odd-shaped molded processed product.

  A preferred embodiment relates to the above-mentioned thermoplastic polyester resin molded product, wherein the thermoplastic polyester resin molded product is a card-shaped molded product.

  A preferred embodiment relates to the above-mentioned thermoplastic polyester resin molded article, wherein the thermoplastic polyester resin molded article is a building member.

  A preferred embodiment relates to the above-mentioned thermoplastic polyester resin molded article, wherein the thermoplastic polyester resin molded article is an agricultural member.

  A preferred embodiment relates to the above-mentioned thermoplastic polyester resin molded article, wherein the thermoplastic polyester resin molded article is a mechanical member.

  A preferable embodiment relates to the above-mentioned thermoplastic polyester resin molded article, wherein the thermoplastic polyester resin molded article is an optical member.

  A preferred embodiment relates to the above-mentioned thermoplastic polyester resin molded article, wherein the thermoplastic polyester resin molded article is a daily necessities member.

  A preferred embodiment relates to the above-mentioned thermoplastic polyester resin molded article, wherein the thermoplastic polyester resin molded article is an electrical device.

  A preferred embodiment relates to the above-mentioned thermoplastic polyester resin molded article, wherein the thermoplastic polyester resin molded article is an electronic device.

  A preferred embodiment relates to the above-mentioned thermoplastic polyester resin molded article, wherein the thermoplastic polyester resin molded article is an OA device.

  A preferred embodiment relates to the above-mentioned thermoplastic polyester resin molded processed product, wherein the thermoplastic polyester resin molded processed product is an automobile member.

  A preferred embodiment relates to the above-mentioned thermoplastic polyester resin molded article, wherein the thermoplastic polyester resin molded article is a packaging material.

  The thermoplastic polyester resin composition for obtaining the thermoplastic polyester resin molded product of the present invention has a dramatically increased melt viscosity, and is injection molding, calender molding, film molding, extrusion molding, blow molding, compression molding. In addition, stable processing is possible in transfer molding, thermoforming, fluid molding, laminate molding, foam molding, and the like, and the surface properties of the resulting molded article are also improved.

  In the present invention, (a) 70 to 95% by weight of aromatic vinyl monomer, (b) 5 to 30% by weight of alkyl acrylate having 1 to 8 carbon atoms in the alkyl group, and (c) copolymerizable with these. Another vinyl monomer is characterized by using a thickener (B) obtained by polymerizing 0 to 10% by weight [100% by weight of (a), (b) and (c) together].

  The thickener (B) used for obtaining the molded product of the thermoplastic polyester resin of the present invention is, for example, by blending 0.1 to 50 parts by weight with respect to 100 parts by weight of the thermoplastic polyester resin (A). Injection molding, calender molding, film molding, extrusion molding, blow molding, compression molding, transfer molding, thermoforming, fluid molding without impairing the excellent physical and chemical properties inherent in thermoplastic polyester resin compositions In addition, the melt viscosity at the time of melt processing in laminate molding, foam molding and the like can be drastically improved, and the effect expected by the addition of the thickener for thermoplastic polyester resin can be remarkably exhibited.

  Although there is no restriction | limiting in particular as said (a) aromatic vinyl monomer used for preparation of the thickener (B) in this invention, For example, styrene, (alpha) -methylstyrene, chlorostyrene etc. can be illustrated preferably. These may be used alone or in combination of two or more. These are contained in the thickener (B) in an amount of 70 to 95% by weight, preferably 70 to 90% by weight, and more preferably 75 to 90% by weight. Stable injection molding, calender molding, film molding, extrusion molding, blow molding, compression molding, transfer molding, thermoforming, fluid molding, laminate molding, foam molding, and the like are preferred because they can be improved to a possible level.

  Examples of the (b) alkyl acrylate having 1 to 8 carbon atoms in the alkyl group include methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, and 2-ethylhexyl acrylate, and further methyl acrylate and ethyl acrylate. Alkyl acrylates having 1 to 4 carbon atoms, such as propyl acrylate, butyl acrylate, etc. are preferred, particularly methyl acrylate or ethyl acrylate having 1 to 2 carbon atoms is more preferred, and methyl acrylate is most preferred. Can be exemplified. These may be used independently and may be used in combination of 2 or more type as needed. These are included in the thickener (B) in the range of 5 to 30% by weight, preferably 10 to 30% by weight, and more preferably 10 to 25% by weight. The viscosity is preferable from the viewpoint that stable injection molding, calender molding, film molding, extrusion molding, blow molding, compression molding, transfer molding, thermoforming, fluid molding, laminate molding, foam molding and the like can be improved.

  In the present invention, (c) other vinyl monomers copolymerizable therewith can be copolymerized with an aromatic vinyl monomer and an alkyl acrylate having an alkyl group having 1 to 8 carbon atoms (a) and (b). Although it will not be restrict | limited especially if it is vinyl monomers other than, For example, an alkylmethacrylate, a vinyl cyanide monomer, etc. may be illustrated. Preferred examples of the alkyl methacrylate include alkyl methacrylates having 1 to 8 carbon atoms in the alkyl group such as methyl methacrylate, ethyl methacrylate, propyl methacrylate, butyl methacrylate, and 2-ethylhexyl methacrylate. Examples of the vinyl cyanide monomer include acrylonitrile and methacrylonitrile. These may be used alone or in combination of two or more. It is thermoplastic that these are contained in the thickener (B) in an amount of 0 to 10% by weight, preferably 0 to 8% by weight, more preferably 0 to 5% by weight, and particularly preferably 0 to 4% by weight. Improve the melt viscosity of polyester resin composition to a level where stable injection molding, calender molding, film molding, extrusion molding, blow molding, compression molding, transfer molding, thermoforming, fluid molding, laminate molding, foam molding, etc. are possible. It is preferable because it can be performed.

  As the monomer used in the production of the thickener (B) of the present invention, it is preferable to use a monomer that does not contain a functional group having reactivity with the thermoplastic polyester resin (A), specifically, an epoxy group or an isocyanate. It is preferable to use a monomer that does not contain a reactive group such as a group, an oxazoline group, a hydroxy group, a carboxy group, an alkoxy group, an acid anhydride group, and an acid chloride group. When a thickener is produced using a monomer having the above-mentioned reactive group, the effect of thickening the melt viscosity of the thermoplastic polyester resin composition is excellent, but the surface of the resulting molded body is whitened, transparency, There may be a tendency for the gloss to decrease.

  The weight average molecular weight of the thickener (B) used in the thermoplastic polyester resin composition of the present invention can be appropriately set as necessary, but the melt viscosity of the thermoplastic polyester resin composition can be stably injection-molded and calender-molded. It is preferably 10,000 to 4,000,000 from the viewpoint that film molding, extrusion molding, blow molding, compression molding, transfer molding, thermoforming, fluid molding, laminate molding, foam molding and the like can be improved. More preferably, it is 10,000-2,500,000, More preferably, it is 10,000-400,000, Especially preferably, it is 10,000-300,000. The weight average molecular weight is obtained by, for example, dissolving a sample in tetrahydrofuran (THF) and using gel permeation chromatography (manufactured by WATERS, 510 type pump 410RI486UV) based on polystyrene as a soluble component. (Sample solution: sample 20 mg / THF 10 mL, measurement temperature: 25 ° C., detector: differential refraction system, injection amount: 1 mL).

  Although there is no limitation in particular about the refractive index of the thickener (B) in this invention, in order to maintain the outstanding transparency of a thermoplastic polyester resin, it adjusts to the range of 1.55-1.58. Is preferred. When the thermoplastic polyester resin is polyethylene terephthalate, it is more preferable to adjust the refractive index to 1.57, and when it is PETG, the refractive index is adjusted to about 1.56. In addition, although the refractive index in this invention is a value measured with the Abbe refractometer at 20 degreeC, it can also calculate and obtain | require based on literature values (Polymer Handbook 4th edition, JOHN WILEY & SONS, etc.).

  The manufacturing method of the thickener (B) of this invention is not specifically limited, For example, it can manufacture by methods, such as suspension polymerization method, emulsion polymerization method, and solution polymerization method.

  For example, when the thickener (B) is produced by an emulsion polymerization method, the monomer mixture may be subjected to emulsion polymerization in the presence of a suitable medium, an emulsifier, a chain transfer agent, a polymerization initiator and the like. The medium used in the emulsion polymerization method is usually water.

  Known emulsifiers can be used as the emulsifier. For example, anionic surfactants such as fatty acid salts, alkyl sulfate ester salts, alkylbenzene sulfonate salts, alkyl phosphate ester salts, sulfosuccinic acid diester salts, and nonionic surfactants such as polyoxyethylene alkyl ethers and polyoxyethylene fatty acid esters Surfactant etc. are mention | raise | lifted.

  The polymerization initiator is not particularly limited, and a water-soluble or oil-soluble polymerization initiator can be used. For example, usual inorganic polymerization initiators such as persulfates, or organic peroxides, azo compounds and the like may be used alone, but these polymerization initiator compounds and sulfites, thiosulfates, first metal salts, A combination of sodium formaldehyde sulfoxylate and the like may be used in a redox system. Preferred persulfates include, for example, sodium persulfate, potassium persulfate, and ammonium persulfate. Preferred organic peroxides include, for example, t-butyl hydroperoxide, cumene hydroperoxide, benzoyl peroxide, Examples include lauroyl peroxide.

  The chain transfer agent is not particularly limited, and examples thereof include alkyl mercaptans such as t-dodecyl mercaptan, n-dodecyl mercaptan, t-decyl mercaptan, n-decyl mercaptan, n-octyl mercaptan, and 2-ethylhexyl thioglycolate. Alkyl ester mercaptans and the like can be used.

  There are no particular limitations on the temperature and time during the polymerization reaction, and the temperature and time may be adjusted as appropriate according to the purpose of use.

  The thickener (B) used in the thermoplastic polyester resin composition of the present invention may be a one-stage polymer or a multistage polymer such as a two-stage or three-stage polymer. For example, when the thickener (B) is produced by two-stage polymerization, the addition of the monomer after the second stage of polymerization is performed after confirming that the polymerization of the first stage monomer is completed. Thus, the second stage polymerization can be performed without mixing with the first stage monomer.

  Thus, the particles in the polymer latex obtained by emulsion polymerization usually have a volume average particle diameter of about 100 to 3,000 mm, and are subjected to salting out, coagulation, or hot air by adding an electrolyte to the normal latex. The latex can be removed from the latex by spraying and drying. If necessary, the polymer particles of the thickener (B) are washed, dehydrated and dried by a usual method.

  The thermoplastic polyester resin (A) used in the present invention is not particularly limited, and for example, polyalkylene terephthalate, polyalkylene naphthalene dicarboxylate, or at least one of aliphatic diol or cycloaliphatic diol, or these Examples include combinations and thermoplastic polyester resins containing units derived from at least one dibasic acid. The thermoplastic polyester resin (A) may be used alone or in combination of two or more.

  Examples of the polyalkylene terephthalate include polybutylene terephthalate, polyethylene terephthalate, polypentylene terephthalate, etc., or two types of glycols (for example, ethylene glycol and cyclohexanedimethanol) or two types of dibasic acids (for example, terephthalic acid and isophthalic acid). Aromatic copolyesters containing derived units are exemplified, and polyethylene terephthalate, or copolyesters containing units derived from ethylene glycol or cyclohexanedimethanol and isophthalic acid can be preferably exemplified.

  Examples of the polyalkylene naphthalene dicarboxylate include poly naphthalene dicarboxylate.

  The blending ratio of the thermoplastic polyester resin (A) and the thickener (B) in the thermoplastic polyester resin composition of the present invention can be widely adopted as required, but preferably 100 parts by weight of the thermoplastic polyester resin (A). The thickener (B) is 0.1 to 50 parts by weight, preferably 0.1 to 20 parts by weight, more preferably 0.5 to 10 parts by weight, still more preferably the thickener (B). 0.5 to 7 parts by weight. If the blending amount of the thickener (B) is less than 0.1 parts by weight, the melt viscosity cannot be increased sufficiently, and stable molding processability may not be realized, while the blending amount of the thickener (B). In the range exceeding 50 parts by weight, the gloss and transparency of the resulting molded product may be lost.

  In the present invention, a core-shell type graft copolymer (C) can be used in addition to the thermoplastic polyester resin (A) and the thickener (B). The core-shell type graft copolymer (C) is made of a polymer obtained by polymerizing a specific monomer mixture, and is used in combination with the thickening agent for thermoplastic polyester resin. During melt processing such as injection molding, calender molding, film molding, extrusion molding, blow molding, compression molding, transfer molding, thermoforming, fluid molding, laminate molding, foam molding, etc. without reducing the physical and chemical properties of The melt viscosity and the impact resistance of the molded product can be improved.

  There is no limitation in particular as a method of manufacturing the thermoplastic polyester resin composition for obtaining the thermoplastic polyester resin molding processed product of this invention, A well-known method is employable. For example, thermoplastic polyester resin (A) and thickener (B) are mixed in advance using a Henschel mixer, tumbler, etc., and then melted using a single screw extruder, twin screw extruder, Banbury mixer, heating roll, etc. A method of obtaining a resin composition by kneading can be employed.

  Furthermore, for example, a high-concentration master batch in which the thickener (B) is mixed in a range exceeding 50 parts by weight with respect to 100 parts by weight of the thermoplastic polyester resin (A) is manufactured in advance, and the actual molding is performed. At the time of processing, the masterbatch is mixed with the thermoplastic polyester resin (A) and diluted so that the blending amount of the thickener (B) is within a range of 0.1 to 50 parts by weight. May be.

  In the thermoplastic polyester resin composition of the present invention, other additives such as a spreading agent, a lubricant, a plasticizer, a colorant, a filler, an impact resistance enhancer, an antibacterial / antifungal agent and the like are used alone as necessary. Or two or more kinds may be added in combination.

  The method for obtaining a molded body from the thermoplastic polyester resin composition of the present invention is not particularly limited and can be applied to commonly used molding methods, such as extrusion molding, calendar molding, blow molding, It can be preferably applied to an injection molding method. According to the present invention, at the time of melt processing, injection molding, calender molding, film molding, extrusion molding, blow molding, compression molding, transfer molding, thermoforming, fluid molding, lamination molding, or higher molding viscosity is required. In foam molding, it is possible to obtain a molded product that exhibits stable processability, has good surface properties, and excellent impact resistance.

  In the thermoplastic polyester resin composition used to obtain the molded article of the thermoplastic polyester resin of the present invention, a foaming thermoplastic polyester is obtained by further adding a foaming agent to the thermoplastic polyester resin and the thickener. A resin composition can be obtained.

  The blowing agent that can be used in the present invention is not particularly limited, and is an inert gas such as nitrogen gas, carbon dioxide gas, and helium, saturated hydrocarbons such as propane, butane, pentane, and hexane, tetrafluoromethane, and chlorofluorocarbon. Physical foaming agents such as halogenated hydrocarbons, thermal decomposition inorganic foaming agents such as sodium bicarbonate, potassium bicarbonate, ammonium bicarbonate, sodium carbonate, ammonium carbonate, N, N′-dinitrosopentamethylenetetramine, Nitroso compounds such as N, N′-dimethyl-N, N′-dinitrosotephthalamide, azo compounds such as azodicarbonamide, azobisisobutyronitrile, barium azodicarboxylate, benzenesulfonyl hydrazide, toluenesulfonyl hydrazide, etc. Sulfonyl hydrazide compounds such as Pyrolytic foaming agents such as pyrolytic organic foaming agents can be used. These can be used individually or in mixture of 2 or more types. Among them, it is preferable to use a pyrolytic foaming agent from the point that it is not necessary to use a foaming equipment having a foaming efficiency and an explosion-proof structure. Particularly preferred from the viewpoint. As the pyrolytic organic foaming agent, azodicarbonamide is particularly preferable from the viewpoint of foaming efficiency and cost.

  The amount of the foaming agent added is not particularly limited depending on the purpose, but is usually preferably 0.1 to 20 parts by weight, more preferably 0 to 100 parts by weight of the thermoplastic polyester resin. .2 to 10 parts by weight, more preferably 0.3 to 5 parts by weight. When the amount of the foaming agent added is less than 0.1 parts by weight, it is difficult to obtain a molded product having a sufficient expansion ratio. On the other hand, when the amount exceeds 20 parts by weight, the foamed cells are often torn and the foamed molded product shrinks. As a result, the surface property tends to deteriorate.

  The production method of the foamable thermoplastic polyester resin composition for obtaining the foamed thermoplastic polyester resin molded article of the present invention is not particularly limited. For example, the thermoplastic polyester resin, the thickener, the foaming agent, and other additives are mixed and then melted in a melt kneader such as a single screw or twin screw extruder at a temperature suitable for the resin composition. It can be produced by a kneading method or the like.

  The molding method for obtaining the foamed thermoplastic polyester resin molded product of the present invention is not particularly limited, and a commonly used foam molding method such as an extrusion foam molding method can be applied.

  The thermoplastic polyester resin molded product of the present invention includes a fibrous molded product, a sheet-shaped molded product, a film-shaped molded product, a pipe-shaped molded product, an odd-shaped molded product, a card-shaped molded product, and an architectural product. Examples include, but are not limited to, members, agricultural members, mechanical members, optical members, daily necessities members, electrical equipment, electronic equipment, OA equipment, automobile members, packaging materials, and the like.

  Examples of the fibrous molded product include, but are not limited to, undrawn yarn, drawn yarn, and super drawn yarn.

  Examples of the sheet-shaped molded product include, but are not limited to, a compression-molded tray, a siding material, and a molded plate.

  Examples of the film-shaped molded product include, but are not limited to, unstretched films, uniaxially stretched films, biaxially stretched films, wet laminates, hot melt laminates, laminate films such as dry laminates, and multi-films. .

  Examples of the pipe-shaped molded product include, but are not limited to, various pipes such as water and sewage pipes and electric pipes, and various pipes.

  Examples of the modified molded product include, but are not limited to, interior / exterior furniture and window frames.

  Examples of the card-shaped molded product include, but are not limited to, an ID card and a cash card.

  Examples of the building member include, but are not limited to, a cushioning material, a heat insulating material, a soundproofing material, a cushioning material, a wall material, a ceiling material, and a flooring material.

  Examples of the agricultural member include, but are not limited to, an agricultural cover sheet, a planting pot, a plant net, a lawn pile, a fertilizer bag, a fish net, a water retaining sheet, and a sandbag.

  Examples of mechanical members include, but are not limited to, various types of bearings such as cleaning jigs, oilless bearings, stern bearings, and underwater bearings, motor parts, lighters, typewriters, and pump parts.

  Examples of the optical member include, but are not limited to, a microscope, binoculars, a telescope, a camera, a watch, an optical pickup, and an illumination component.

  Daily commodities include, but are not limited to, shopping bags, strapping bands, garbage bags, compost bags, lunch boxes, tableware, beverage containers, cups, cosmetic containers, detergent containers, bleach containers, and cold containers. It is not something.

  Electrical equipment / electronic equipment / OA equipment includes housings, sensors, LED lamps, connectors, sockets, resistors, relay cases, switches, coil bobbins, capacitors, variable capacitor cases, oscillators, various terminal boards, modifiers, breakers, plugs. , Printed wiring board, tuner, speaker, microphone, headphones, motor, magnetic head base, power module, semiconductor, FDD carriage, FDD chassis, motor brush holder, parabolic antenna, CD tray, DVD tray, cartridge, cassette, sorter, AC Adapter, charging stand, switchboard, outlet cover, VTR part, TV part, radio part, iron, hair dryer, rice cooker part, microwave oven part, refrigerator part, acoustic part, audio, laser Discs, compact discs, air conditioner parts, typewriter parts, word processor parts, telephone-related parts, mobile phone parts, facsimile-related parts, copier-related parts, computer housings such as personal computers, PC dummy cards, IR masks, compact audio Examples include, but are not limited to, product casings and packaging materials.

  Automobile parts include spare tire covers, floor mats, alternator terminals, alternator connectors, precision machinery-related parts, IC regulators, various valves such as exhaust gas valves, fuel-related, exhaust system, various intake system pipes, air intake snorkel , Intake manifold, fuel pump, engine coolant joint, carburetor, exhaust gas sensor, coolant sensor, oil temperature sensor, brake pad wear sensor, throttle position sensor, air flow meter, thermostat base for air conditioner, heating hot air flow control valve , Brush holders for radiator motors, water pump impellers, turbine vanes, wiper motor related parts, distributors, starter switches, Tarta relay, transmission wire harness, window washer nozzle, air conditioner panel switch base, fuel-related electromagnetic valve coil, fuse connector, horn terminal, electrical component insulation plate, step motor rotor, lamp socket, lamp reflector, lamp housing, brake piston Examples include, but are not limited to, solenoid bobbins, engine oil filters, ignition device cases, ceiling materials, and the like.

  Examples of the packaging material include, but are not limited to, blister packs, PTP containers, various covers, various cases, food containers and trays.

Claims (24)

  With respect to 100 parts by weight of the thermoplastic polyester resin (A), (a) 70 to 95% by weight of an aromatic vinyl monomer, and (b) 5 to 30% by weight of an alkyl acrylate having 1 to 8 carbon atoms in the alkyl group; , (C) Thickener (B) obtained by polymerizing 0 to 10% by weight of other vinyl monomers copolymerizable therewith [100% by weight in combination of (a), (b) and (c)] A thermoplastic polyester resin molded processed product comprising 0.1 to 50 parts by weight.   The monomer constituting the thickener (B) is a monomer that does not contain an epoxy group, an isocyanate group, an oxazoline group, a hydroxy group, a carboxy group, an alkoxy group, an acid anhydride group, and an acid chloride group. The thermoplastic polyester resin molded article according to claim 1, characterized in that it is characterized by the following.   The thermoplastic polyester resin molding according to claim 1 or 2, wherein the alkyl acrylate (b) constituting the thickener (B) is an alkyl acrylate having 1 to 4 carbon atoms in the alkyl group. Processed goods.   The thermoplastic polyester resin molding according to claim 1 or 2, wherein the alkyl acrylate (b) constituting the thickener (B) is an alkyl acrylate having 1 to 2 carbon atoms in the alkyl group. Processed goods.   The thermoplastic polyester resin molded product according to any one of claims 1 to 4, wherein the thickener (B) has a weight average molecular weight of 10,000 to 4,000,000.   The thermoplastic polyester resin molded article according to any one of claims 1 to 4, wherein the thickener (B) has a weight average molecular weight of 10,000 to 400,000.   The thermoplastic polyester resin molded article according to any one of claims 1 to 6, wherein the thickener (B) has a refractive index of 1.55 to 1.58.   A thermoplastic polyester resin molded article is obtained by injection molding, calendar molding, film molding, extrusion molding, blow molding, compression molding, transfer molding, thermoforming, fluid molding, laminate molding, or foam molding. The thermoplastic polyester resin molded product according to any one of claims 1 to 7.   The thermoplastic polyester resin molded article according to any one of claims 1 to 8, wherein the thermoplastic polyester resin molded article is a fibrous molded article.   The thermoplastic polyester resin molded processed product according to any one of claims 1 to 8, wherein the thermoplastic polyester resin molded processed product is a sheet-shaped molded processed product.   The thermoplastic polyester resin molded processed product according to any one of claims 1 to 8, wherein the thermoplastic polyester resin molded processed product is a film-shaped molded processed product.   The thermoplastic polyester resin molded product according to any one of claims 1 to 8, wherein the thermoplastic polyester resin molded product is a pipe-shaped molded product.   The thermoplastic polyester resin molded processed product according to any one of claims 1 to 8, wherein the thermoplastic polyester resin molded processed product is an odd-shaped molded processed product.   The thermoplastic polyester resin molded processed product according to any one of claims 1 to 8, wherein the thermoplastic polyester resin molded processed product is a card-shaped molded processed product.   The thermoplastic polyester resin molded article according to any one of claims 1 to 8, wherein the thermoplastic polyester resin molded article is a building member.   The thermoplastic polyester resin molded processed product according to any one of claims 1 to 8, wherein the thermoplastic polyester resin molded processed product is an agricultural member.   The thermoplastic polyester resin molded article according to any one of claims 1 to 8, wherein the thermoplastic polyester resin molded article is a mechanical member.   The thermoplastic polyester resin molded article according to any one of claims 1 to 8, wherein the thermoplastic polyester resin molded article is an optical member.   The thermoplastic polyester resin molded processed article according to any one of claims 1 to 8, wherein the thermoplastic polyester resin molded processed article is a daily necessities member.   The thermoplastic polyester resin molded processed product according to any one of claims 1 to 8, wherein the thermoplastic polyester resin molded processed product is an electrical device.   The thermoplastic polyester resin molded article according to any one of claims 1 to 8, wherein the thermoplastic polyester resin molded article is an electronic device.   The thermoplastic polyester resin molded article according to any one of claims 1 to 8, wherein the thermoplastic polyester resin molded article is an OA device.   The thermoplastic polyester resin molded article according to any one of claims 1 to 8, wherein the thermoplastic polyester resin molded article is a member for an automobile.   The thermoplastic polyester resin molded article according to any one of claims 1 to 8, wherein the thermoplastic polyester resin molded article is a packaging material.