JP2007091917A5 - - Google Patents

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JP2007091917A5
JP2007091917A5 JP2005284096A JP2005284096A JP2007091917A5 JP 2007091917 A5 JP2007091917 A5 JP 2007091917A5 JP 2005284096 A JP2005284096 A JP 2005284096A JP 2005284096 A JP2005284096 A JP 2005284096A JP 2007091917 A5 JP2007091917 A5 JP 2007091917A5
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Japan
Prior art keywords
paper processing
resin emulsion
alkyl ether
polyoxyethylene alkyl
producing
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JP2005284096A
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JP4766311B2 (en
JP2007091917A (en
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Priority claimed from JP2005284096A external-priority patent/JP4766311B2/en
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Publication of JP2007091917A5 publication Critical patent/JP2007091917A5/ja
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即ち、本発明は、一分子中にオキシエチレン単位を平均５０個以上有するポリオキシエチレンアルキルエーテル（Ａ）の存在下で、メチルアクリレート及び／又はエチルアクリレート（Ｂ）を必須成分として含有するエチレン性不飽和単量体類を乳化重合する紙加工用樹脂エマルジョンの製造方法であって、前記紙加工用樹脂エマルジョンに用いるコポリマーが、−２０〜２０℃の範囲の計算ガラス転移温度（計算Ｔｇ）を有することを特徴とする紙加工用樹脂エマルジョンの製造方法、を提供するものである。 That is, the present invention is an ethylenic compound containing methyl acrylate and / or ethyl acrylate (B) as an essential component in the presence of polyoxyethylene alkyl ether (A) having an average of 50 or more oxyethylene units in one molecule. A method for producing a paper processing resin emulsion for emulsion polymerization of unsaturated monomers , wherein the copolymer used for the paper processing resin emulsion has a calculated glass transition temperature (calculated Tg) in the range of -20 to 20 ° C. The present invention provides a method for producing a paper processing resin emulsion.

前記紙加工用樹脂エマルジョンに用いるコポリマーは、−２０〜２０℃の範囲の計算ガラス転移温度（計算Ｔｇ）を有する。


Copolymers used in the paper processing resin emulsion has a calculated glass transition temperature in the range of -20 to 20 ° C. (calculated Tg).


Claims (6)

一分子中にオキシエチレン単位を平均５０個以上有するポリオキシエチレンアルキルエーテル（Ａ）の存在下で、メチルアクリレート及び／又はエチルアクリレート（Ｂ）を必須成分として含有するエチレン性不飽和単量体類を乳化重合する紙加工用樹脂エマルジョンの製造方法であって、前記紙加工用樹脂エマルジョンに用いるコポリマーが、−２０〜２０℃の範囲の計算ガラス転移温度を有することを特徴とする紙加工用樹脂エマルジョンの製造方法。 Ethylenically unsaturated monomers containing methyl acrylate and / or ethyl acrylate (B) as an essential component in the presence of polyoxyethylene alkyl ether (A) having an average of 50 or more oxyethylene units in one molecule A method for producing a paper processing resin emulsion for emulsion polymerization, wherein the copolymer used in the paper processing resin emulsion has a calculated glass transition temperature in the range of -20 to 20 ° C. Method for producing emulsion. 前記エチレン性不飽和単量体類中のメチルアクリレート及び／又はエチルアクリレート（Ｂ）の含有率が３０〜９０重量％、炭素原子数８〜１５のアルキル基を有するアルキル（メタ）アクリレート（Ｃ）の含有率が１〜１０重量％、及びその他のエチレン性不飽和単量体の含有率が０〜６９重量％である請求項１に記載の紙加工用樹脂エマルジョンの製造方法。 Alkyl (meth) acrylate (C) having a methyl acrylate and / or ethyl acrylate (B) content of 30 to 90% by weight and an alkyl group having 8 to 15 carbon atoms in the ethylenically unsaturated monomers 2. The method for producing a resin emulsion for paper processing according to claim 1, wherein the content of 1 to 10% by weight and the content of other ethylenically unsaturated monomers is 0 to 69% by weight. 前記エチレン性不飽和単量体類が、更にブチル（メタ）アクリレート（Ｄ）を含有するものである請求項１に記載の紙加工用樹脂エマルジョンの製造方法。 The method for producing a resin emulsion for paper processing according to claim 1, wherein the ethylenically unsaturated monomers further contain butyl (meth) acrylate (D). 前記ポリオキシエチレンアルキルエーテル（Ａ）が、一分子中にオキシエチレン単位を平均５０〜１５０個有するポリオキシエチレンアルキルエーテルである請求項１〜３の何れか一項に記載の紙加工用樹脂エマルジョンの製造方法。 The resin emulsion for paper processing according to any one of claims 1 to 3, wherein the polyoxyethylene alkyl ether (A) is a polyoxyethylene alkyl ether having an average of 50 to 150 oxyethylene units in one molecule. Manufacturing method. 前記ポリオキシエチレンアルキルエーテル（Ａ）が、一分子中にオキシエチレン単位を平均８０〜１１０個有するポリオキシエチレンアルキルエーテルである請求項１〜３の何れか一項に記載の紙加工用樹脂エマルジョンの製造方法。 The resin emulsion for paper processing according to any one of claims 1 to 3, wherein the polyoxyethylene alkyl ether (A) is a polyoxyethylene alkyl ether having an average of 80 to 110 oxyethylene units in one molecule. Manufacturing method. 前記ポリオキシエチレンアルキルエーテル（Ａ）を、前記エチレン性不飽和単量体の合計１００重量部に対して、３〜１０重量部の範囲で存在させる請求項１〜３の何れか一項に記載の紙加工用樹脂エマルジョンの製造方法。 The said polyoxyethylene alkyl ether (A) is made to exist in the range of 3-10 weight part with respect to a total of 100 weight part of the said ethylenically unsaturated monomer. Of producing a resin emulsion for paper processing.
JP2005284096A 2005-09-29 2005-09-29 Method for producing resin emulsion for paper processing Expired - Fee Related JP4766311B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2005284096A JP4766311B2 (en) 2005-09-29 2005-09-29 Method for producing resin emulsion for paper processing

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Application Number Priority Date Filing Date Title
JP2005284096A JP4766311B2 (en) 2005-09-29 2005-09-29 Method for producing resin emulsion for paper processing

Publications (3)

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JP2007091917A JP2007091917A (en) 2007-04-12
JP2007091917A5 true JP2007091917A5 (en) 2008-09-25
JP4766311B2 JP4766311B2 (en) 2011-09-07

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Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4803425B2 (en) * 2005-11-24 2011-10-26 Ｄｉｃ株式会社 Method for producing resin emulsion for paper processing
CN102533176A (en) * 2011-12-26 2012-07-04 北京高盟新材料股份有限公司 Waterborne gravure paper-plastic composite adhesive and preparation method thereof
JP6415132B2 (en) * 2014-06-25 2018-10-31 ジャパンコーティングレジン株式会社 Method for producing polymer emulsion and polymer emulsion obtained thereby, and method for producing hollow particle and hollow particle obtained thereby

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JP2688705B2 (en) * 1988-05-11 1997-12-10 中央理化工業株式会社 Acrylic emulsion composition
JPH10298210A (en) * 1997-04-25 1998-11-10 Kao Corp Activator for emulsion polymerization and production of aqueous polymer by using it
JP3429705B2 (en) * 1999-06-23 2003-07-22 花王株式会社 Surfactant composition for emulsion polymerization
JP2001354709A (en) * 2000-06-15 2001-12-25 Kao Corp Surface active agent composition for emulsion polymerization
JP2002173871A (en) * 2000-12-06 2002-06-21 Nippon Carbide Ind Co Inc Aqueous dispersion of crosslinked resin for textile finishing
JP3901500B2 (en) * 2001-11-30 2007-04-04 日本カーバイド工業株式会社 Cross-linked resin aqueous composition for fiber processing
JP4349858B2 (en) * 2002-07-18 2009-10-21 日本乳化剤株式会社 Higher aliphatic alcohol alkylene oxide addition surfactants

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