JP2007084679A - Reactive putty material and method for producing the same - Google Patents

Reactive putty material and method for producing the same Download PDF

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JP2007084679A
JP2007084679A JP2005274821A JP2005274821A JP2007084679A JP 2007084679 A JP2007084679 A JP 2007084679A JP 2005274821 A JP2005274821 A JP 2005274821A JP 2005274821 A JP2005274821 A JP 2005274821A JP 2007084679 A JP2007084679 A JP 2007084679A
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molded body
reactive
curing agent
putty material
resin
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Minoru Tarumi
実 垂水
Hiroki Takagi
博喜 高木
Goro Hasegawa
吾郎 長谷川
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Nitto Kasei Co Ltd
Alteco Inc
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Nitto Kasei Co Ltd
Alteco Inc
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a reactive putty material of type in which the first molded article containing a reactive resin as a main agent and the second molded article containing a curing agent as a main component are arranged in parallel, whose curing reaction hardly proceeds on end faces where the first molded article faces the second molded article, or in their side edge portions or their peripheral portions, and in which an evaporable relatively highly reactive curing agent can also be compounded or used as the agent, and to provide a method for producing the same. <P>SOLUTION: This reactive putty material is characterized by disposing the third bar-like molded article (3) containing a non-reactive resin not reacting with the first bar-like molded article (1) containing the reactive resin as the main agent and the second bar-like molded article (2) containing the curing agent as the main component, between the first bar-like molded article (1) and the second bar-like molded article (2), and then adhering mold release sheets (4), (4) to both the upper and lower sides of the parallel contact-arranged product. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、反応性樹脂を主成分とする主剤からなる棒状の成形体と、硬化剤を主成分とする棒状の成形体との間に、非反応性樹脂を主成分とする棒状の成形体を接触するように配置したタイプの反応性パテ材およびその製造法に関するものである。   The present invention relates to a rod-shaped molded body composed mainly of a non-reactive resin between a rod-shaped molded body composed mainly of a reactive resin as a main component and a rod-shaped molded body composed mainly of a curing agent. It is related with the reactive putty material of the type arrange | positioned so that it may contact, and its manufacturing method.

特開2001−234123号公報JP 2001-234123 A

<第1のタイプの反応性パテ材>
反応性パテ材として、反応性樹脂を主成分とする主剤からなる棒状の第1成形体と、硬化剤を主成分とする棒状の第2成形体とを、別々に包装したものが知られている(第1のタイプの反応性パテ材とする)。各成形体の製造工程における取り扱いを容易にし、かつ包装後の成形体が包材に粘着するのを防止するため、各成形体の両面には離型性シートを貼着しておくのが通常である。
<Reactive putty material of the first type>
As a reactive putty material, a rod-shaped first molded body composed mainly of a reactive resin as a main component and a rod-shaped second molded body composed mainly of a curing agent are separately packaged. (A first type reactive putty material). In order to facilitate the handling of each molded body in the manufacturing process and to prevent the molded body after packaging from sticking to the packaging material, it is usual to attach a release sheet on both surfaces of each molded body. It is.

この第1のタイプの反応性パテ材を使用するときには、第1成形体および第2成形体のそれぞれから必要量を切り取り、両者を指で混練してから、パテ材として用いる。家庭工作用には、両成形体の形状を同一にして、目分量で混合するときに多少の誤差があってもほぼ等量の混合が達成する事が出来るようにすることが多い。   When this first type of reactive putty material is used, a necessary amount is cut from each of the first molded body and the second molded body, and both are kneaded with fingers, and then used as a putty material. For home crafts, the shape of both molded bodies is often the same so that almost equal amounts of mixing can be achieved even when there is some error when mixing in a scale.

<第2のタイプの反応性パテ材>
また、別のタイプの反応性パテ材(第2のタイプの反応性パテ材とする)として、反応性樹脂を主成分とする主剤からなる棒状の第1成形体(101)と、硬化剤を主成分とする棒状の第2成形体(102)とを、若干の距離をあけて並行に配置し、かつそれらの第1成形体および第2成形体の並行配置体(101)(102)の両面に離型性シート(103)(103)を貼着し(図4(A)参照)、さらに全体を包材(104)で包装したものが知られている(図4(B)参照)。ここで、第1成形体(101)と第2成形体(102)とを若干離すようにするのは、両者が接触すると接触界面において硬化が急速に進むからである。
<Second type reactive putty material>
Moreover, as another type of reactive putty material (referred to as a second type of reactive putty material), a rod-shaped first molded body (101) made of a main ingredient mainly composed of reactive resin and a curing agent are used. The rod-shaped second molded body (102) as a main component is arranged in parallel at a slight distance, and the parallel molded bodies (101) (102) of the first molded body and the second molded body are arranged. It is known that the releasable sheets (103) and (103) are attached to both sides (see FIG. 4A), and the whole is wrapped with a packaging material (104) (see FIG. 4B). . Here, the reason why the first molded body (101) and the second molded body (102) are slightly separated from each other is that the curing rapidly proceeds at the contact interface when they come into contact with each other.

この第2のタイプの反応性パテ材は、製造工程における、第1成形体(101)および第2成形体(102)の形成のための押出機からの吐出、吐出後の並行配置体(101)(102)の両面への離型性シート(103)(103)の貼着、さらには包装までの一連の工程を自動化できるので、生産性の点で好ましい。しかもその使用に際してこの並行配置体(101)(102)を巾方向に横断して切り取れば、第1成形体(101)および第2成形体(102)の各ピースが所定の重量割合で得られるので、両ピース(101)(102)を混練するだけで所定の主剤・硬化剤の混合比となり、上記第1タイプの反応性パテに比し使い勝手の点でも好ましい。   This second type of reactive putty material is discharged from an extruder for forming the first molded body (101) and the second molded body (102) in the manufacturing process, and the parallel arrangement body (101 after discharge). ) (102) Since the series of steps up to pasting of the releasable sheets (103) and (103) on both surfaces of (102) and packaging can be automated, it is preferable in terms of productivity. Moreover, when the parallel-arranged bodies (101) and (102) are cut across the width direction in use, the pieces of the first molded body (101) and the second molded body (102) are obtained in a predetermined weight ratio. Therefore, only by kneading both pieces (101) and (102), the mixing ratio of the main agent and the curing agent is obtained, which is preferable in terms of usability as compared with the first type reactive putty.

しかしながら、上記第2のタイプの反応性パテ材にあっては、第2成形体(102)の主成分である硬化剤として適度の硬化速度を有するものを用いると、そのような硬化剤は一般に若干の揮発性を有するので、製品の流通および保管期間中にその揮発ガス(具体的にはアミンガス)が第1成形体(101)の主成分である反応性樹脂に影響を与え、比較的短期間で第1成形体(101)の第2成形体(102)と対向する側の端面ないし側縁部分またはその周辺部分が硬化してしまい、さらに保存期間が長くなると実際の使用に際して支障を生ずるようになることを免れない。   However, in the second type of reactive putty material, when a curing agent that has a proper curing rate is used as a curing agent that is a main component of the second molded body (102), such a curing agent is generally used. Since it has some volatility, the volatile gas (specifically amine gas) affects the reactive resin which is the main component of the first molded body (101) during the distribution and storage period of the product, and it is relatively short-term. In the meantime, the end surface or the side edge portion of the first molded body (101) facing the second molded body (102) or the peripheral portion thereof is hardened, and if the storage period is further extended, troubles occur in actual use. It is inevitable to become.

そこで、第2成形体(102)の硬化剤として揮発性の小さい硬化剤(例えば、第1成形体(101)の主剤がビスフェノールA型エポキシ樹脂であるときはポリアミド系硬化剤)を使用する工夫もなされているが、使用に際して混合後の硬化速度が過度に遅くなる傾向がある上、その硬化剤中に微量に残留する反応性の揮発ガスにより、製品流通および保管期間が長くなると、依然として第1成形体(101)の第2成形体(102)と対向する側の端面ないし側縁部分またはその周辺部分が硬化してくることを有効には防止できない。   Therefore, a device that uses a low-volatile curing agent (for example, a polyamide-based curing agent when the main component of the first molded body (101) is a bisphenol A type epoxy resin) as a curing agent for the second molded body (102). However, the curing rate after mixing tends to be excessively slow at the time of use, and when the product distribution and storage period is prolonged due to the reactive volatile gas remaining in a trace amount in the curing agent, It is not possible to effectively prevent the end surface or side edge portion of the one molded body (101) facing the second molded body (102) or the peripheral portion thereof from hardening.

また、第1成形体(101)および第2成形体(102)からなる第2のタイプの反応性パテ材の全体を包装する包材(104)として孔明き包材を用い、第2成形体(102)から揮散するガス状の硬化剤をできるだけすみやかに外部に逃がすような工夫もなされているが、依然として第1成形体(101)の第2成形体(102)と対向する側の端面ないし側縁部分またはその周辺部分が硬化することを充分には防止できない。   Further, a perforated wrapping material is used as a wrapping material (104) for wrapping the entire second type of reactive putty material composed of the first molded body (101) and the second molded body (102), and the second molded body. Although the device has been devised to allow the gaseous curing agent evaporating from (102) to escape to the outside as quickly as possible, the end surface of the first molded body (101) facing the second molded body (102) or Curing of the side edge portion or its peripheral portion cannot be sufficiently prevented.

<第3のタイプの反応性パテ材>
上記の問題に鑑み、特許文献1に記載の発明に係る反応性パテ材(第3のタイプの反応性パテ材とする)が提案されている。これは、図5(A)に示すように、第1成形体(101)と第2成形体(102)とが、溝状の隙間(105)を介して並行に配置され、かつその並行配置体の上下両面に離型性シート(103)(103)が貼着されている反応性パテ材であって、溝状の隙間(105)において、両離型性シート(103)(103)同士が互いに接触または近接するようにされていると共に、それら両離型性シート(103)(103)が、上記の第1成形体(101)および第2成形体(102)の相対向する対向端面(101a)(102a)をも被覆しているものである。これは、図5(B)に示すように、上記の溝状の隙間(105)において離型性シート(103)(103)を第1および第2成形体(101)(102)の相対向する対向端面(101a)(102a)に密着させるために、ローラー(R)などによる離型性シート(103)(103)の押圧によって形成されたものである。
<Reactive putty material of the third type>
In view of the above problems, a reactive putty material (referred to as a third type reactive putty material) according to the invention described in Patent Document 1 has been proposed. As shown in FIG. 5 (A), the first molded body (101) and the second molded body (102) are arranged in parallel through the groove-like gap (105), and the parallel arrangement thereof is performed. Reactive putty material in which releasable sheets (103) and (103) are adhered to both upper and lower surfaces of the body, and both releasable sheets (103) and (103) are disposed in a groove-like gap (105). Are in contact with each other or in close proximity to each other, and both the releasable sheets (103) and (103) are opposed end faces of the first molded body (101) and the second molded body (102) facing each other. (101a) (102a) is also covered. As shown in FIG. 5B, the release sheet (103) (103) is opposed to the first and second molded bodies (101) (102) in the groove-like gap (105). It is formed by pressing the releasable sheets (103) (103) with a roller (R) or the like so as to be in close contact with the opposing end faces (101a) (102a).

この構成により、第2成形体(102)の硬化剤中に微量に残留する反応性の揮発性ガスの揮散が有効に防止され、その流通過程や保管過程において、第1成形体(101)の第2成形体(102)と対向する側の端面ないし側縁部分またはその周辺部分が硬化しにくい反応性パテ材が提供できたものである。また、硬化剤として揮発性のある比較的反応速度の大きなものを配合したり使用したりすることも可能となるので、硬化剤の選択の巾が拡がり、パテ材使用時の使い勝手も良い反応性パテ材が提供できたものである。   With this configuration, the volatilization of the reactive volatile gas remaining in a trace amount in the curing agent of the second molded body (102) is effectively prevented, and the first molded body (101) can be prevented from flowing out and stored. It is possible to provide a reactive putty material in which the end face or side edge portion on the side facing the second molded body (102) or the peripheral portion thereof is hard to be cured. In addition, it is possible to mix and use a volatile curing agent with a relatively high reaction rate, so the range of choice of curing agent is expanded, and reactivity is also good when using putty materials. Putty materials could be provided.

しかしながら、この第3のタイプの反応性パテ材にあっても、上記反応性の揮発性ガスの揮散が完全に防止されたものではなく、長期にわたる保存中に第1成形体(101)と第2成形体(102)との各々における、隙間(105)に面する部分が硬化してしまうなどの問題を依然有しており、更に優れた反応性パテ材が望まれていた。   However, even in the third type of reactive putty material, the volatilization of the reactive volatile gas is not completely prevented, and the first molded body (101) and the first molded body (101) are stored during long-term storage. There still remains a problem that the portion facing the gap (105) in each of the two molded bodies (102) is cured, and a more excellent reactive putty material has been desired.

本発明は、このような背景下において、上記第2のタイプの反応性パテ材のように第1成形体と第2成形体を若干の距離をあけて並行配置したものの両面に離型性シートを貼着し、さらに全体を包装したものにおいて、製品の流通および保管期間中に第1成形体の第2成形体と対向する側の端面ないし側縁部分またはその周辺部分の硬化反応が進みがたく、また硬化剤として揮発性のある比較的反応速度の大きなものを配合したり使用したりすることも可能であって、かつ、上記第3のタイプの反応性パテ材よりも更に長期にわたる保存性に優れる反応性パテ材を、工業的に有利に製造できる方法を提供することを目的とするものである。   Under such circumstances, the present invention provides a releasable sheet on both sides of a first molded body and a second molded body that are arranged in parallel at a distance from each other like the second type of reactive putty material. In the case where the whole is further packaged, the curing reaction of the end surface or side edge portion of the first molded body facing the second molded body or the peripheral portion thereof proceeds during the distribution and storage period of the product. In addition, it is possible to mix and use a volatile relatively high reaction rate as a curing agent, and it can be stored for a longer period of time than the third type of reactive putty material. It aims at providing the method which can manufacture the reactive putty material excellent in property advantageously industrially.

上記の課題を解決するための手段として、本発明の請求項1に記載の反応性パテ材は、反応性樹脂を主成分とする主剤からなる第1成形体(1)と、硬化剤を主成分とする第2成形体(2)との間に、第1成形体(1)および第2成形体(2)のどちらとも反応しない非反応性樹脂を主成分とする第3成形体(3)を接触するように配置したことを特徴とするものである。   As means for solving the above-mentioned problems, the reactive putty material according to claim 1 of the present invention is mainly composed of a first molded body (1) composed of a main agent mainly composed of a reactive resin and a curing agent. Between the 2nd molded object (2) used as a component, the 3rd molded object (3) which has a non-reactive resin as a main component which does not react with either a 1st molded object (1) or a 2nd molded object (2) ) In contact with each other.

また、本発明の請求項2に記載の反応性パテ材は、上記請求項1に記載の反応性パテ材において、上記の第1成形体(1)と第2成形体(2)と第3成形体(3)とからなる、並行接触配置体の上下両面に離型性シート(4)(4)が貼着されたことを特徴とするものである。   A reactive putty material according to a second aspect of the present invention is the reactive putty material according to the first aspect, wherein the first molded body (1), the second molded body (2), and the third The releasable sheets (4) and (4) are adhered to both the upper and lower surfaces of the parallel contact arrangement formed of the molded body (3).

また、本発明の請求項3に記載の反応性パテ材は、上記請求項2に記載の反応性パテ材において、上記の、離型性シート(4)(4)が貼着された状態にある並行接触配置体の全体が、包材(5)で包装されたことを特徴とするものである。   Moreover, the reactive putty material according to claim 3 of the present invention is the reactive putty material according to claim 2 in a state where the release sheet (4) (4) is adhered. The entire parallel contact arrangement is packaged with the packaging material (5).

また、本発明の請求項4に記載の反応性パテ材は、上記請求項1〜3のいずれかに記載の反応性パテ材において、第1成形体(1)がエポキシ樹脂を主成分とする主剤の成形体であり、第2成形体(2)がポリアミド系硬化剤、ポリアミン系硬化剤およびポリチオール系硬化剤よりなる群から選ばれた少なくとも1種以上を主成分とする硬化剤の成形体であり、第3成形体(3)がキシレン樹脂等の非反応性樹脂を主成分とする成形体であることを特徴とするものである。   Moreover, the reactive putty material according to claim 4 of the present invention is the reactive putty material according to any one of claims 1 to 3, wherein the first molded body (1) has an epoxy resin as a main component. A molded body of a main agent, the second molded body (2) having a main component of at least one selected from the group consisting of a polyamide curing agent, a polyamine curing agent and a polythiol curing agent. The third molded body (3) is a molded body mainly composed of a non-reactive resin such as xylene resin.

また、本発明の請求項5に記載の反応性パテ材の製造法は、反応性樹脂を主成分とする主剤からなる主剤組成物と、硬化剤を主成分とする硬化剤組成物との間に、主剤と硬化剤のどちらとも反応しない非反応性樹脂を主成分とする非反応性組成物が挟まれるように、上記の各組成物をそれぞれ押出機から吐出して、並行に配置された、棒状の第1成形体(1)と棒状の第2成形体(2)との間に第3成形体(3)が配置された、並行接触配置体を形成していく工程を実施することを特徴とするものである。   Moreover, the method for producing a reactive putty material according to claim 5 of the present invention is between a main agent composition composed of a main agent composed mainly of a reactive resin and a curing agent composition composed mainly of a curing agent. Each of the above compositions was discharged from the extruder and arranged in parallel so that a non-reactive composition mainly composed of a non-reactive resin that did not react with either the main agent or the curing agent was sandwiched between them. The step of forming a parallel contact arrangement in which the third molded body (3) is disposed between the rod-shaped first molded body (1) and the rod-shaped second molded body (2) is performed. It is characterized by.

また、本発明の請求項6に記載の反応性パテ材の製造法は、請求項5に記載された工程に際して、または当該工程に続いて、上記の並行接触配置体の上下両面に離型性シート(4)(4)を貼着する工程を実施することを特徴とするものである。   Moreover, the manufacturing method of the reactive putty material according to claim 6 of the present invention is such that the release property is formed on both the upper and lower surfaces of the parallel contact arrangement body in the process described in claim 5 or subsequent to the process. The step of sticking the sheets (4) and (4) is carried out.

また、本発明の請求項7に記載の反応性パテ材の製造法は、請求項6に記載された工程に際して、または当該工程に続いて、上記の離型性シート(4)(4)が貼着された並行接触配置体を巾方向に横断するように、所定の長さにカットする工程を実施することを特徴とするものである。   Moreover, the manufacturing method of the reactive putty material of Claim 7 of this invention is the said release sheet (4) (4) in the process described in Claim 6, or following the said process. It is characterized by carrying out a step of cutting to a predetermined length so as to cross the stuck parallel contact arrangement body in the width direction.

また、本発明の請求項8に記載の反応性パテ材の製造法は、請求項7に記載された工程に際して、または当該工程に続いて、上記のカットされた並行接触配置体を包材(5)で包装する工程を実施することを特徴とするものである。   Moreover, the manufacturing method of the reactive putty material of Claim 8 of this invention is a packaging material (the said parallel contact arrangement | positioning body cut | disconnected at the time of the process described in Claim 7, or the said process. The step of packaging in 5) is performed.

本発明の反応性パテ材は第1成形体(1)および第2成形体(2)の間に第3成形体(3)が並行接触配置され、その上下面は離型性シート(4)(4)で被覆されている。そのため第2成形体(2)の硬化剤中に微量に残留する反応性揮発ガスの揮散が有効に防止され、その流通経路や保管過程において、第1成形体(1)と第2成形体(2)の一部が硬化することがない。   In the reactive putty material of the present invention, the third molded body (3) is arranged in parallel contact between the first molded body (1) and the second molded body (2), and the upper and lower surfaces thereof are the release sheet (4). Covered with (4). Therefore, the volatilization of the reactive volatile gas remaining in a trace amount in the curing agent of the second molded body (2) is effectively prevented, and the first molded body (1) and the second molded body ( Part of 2) is not cured.

加えて、従来のこのタイプの反応性パテ材にあっては、硬化剤として反応速度の高いものを使用したりすることは不可能であったが、本発明によれば、硬化剤として揮発性のある比較的反応速度の大きなものを配合したりすることも可能となるので、硬化剤選択の巾が拡がり、パテ使用時の使い勝手も良くなるという利点もある。   In addition, in the conventional reactive putty material of this type, it was impossible to use a curing agent having a high reaction rate, but according to the present invention, the curing agent is volatile. It is also possible to add a compound having a relatively high reaction rate, which has the advantage of widening the range of selection of the curing agent and improving usability when using putty.

また、本発明の反応性パテ材にあっては、従来の反応性パテ材よりも更に長期にわたる保存性に優れる反応性パテ材を提供できたものである。   In addition, the reactive putty material of the present invention can provide a reactive putty material that is superior in storage stability over a longer period than conventional reactive putty materials.

<反応性パテ材>
本発明の反応性パテ材は、図1及び図2(A)に示すように、棒状の第1成形体(1)と棒状の第2成形体(2)の間に第3成形体(3)を接触するように配置した並行接触配置体の上下両面に、離型性シート(4)(4)が貼着された基本構成を有する。
<Reactive putty material>
As shown in FIG. 1 and FIG. 2 (A), the reactive putty material of the present invention has a third molded body (3) between a rod-shaped first molded body (1) and a rod-shaped second molded body (2). ) Have a basic structure in which the releasable sheets (4) and (4) are attached to the upper and lower surfaces of the parallel contact arrangement body arranged so as to be in contact with each other.

第1成形体(1)は反応性樹脂を主成分とする主剤からなり、第2成形体(2)は上記反応性樹脂を硬化する作用を有する硬化剤を主成分とするものであり、第3成形体(3)は上記反応性樹脂および硬化剤と反応する作用を有さない非反応性樹脂を主成分とする。   The first molded body (1) is composed of a main agent mainly composed of a reactive resin, and the second molded body (2) is composed mainly of a curing agent having a function of curing the reactive resin. 3 Molded body (3) has as a main component the non-reactive resin which does not have the effect | action which reacts with the said reactive resin and a hardening | curing agent.

反応性樹脂と硬化剤と非反応性樹脂との組み合わせに特に限定はないが、エポキシ樹脂とその硬化剤および非反応性樹脂の組み合わせが重要となる。   The combination of the reactive resin, the curing agent, and the non-reactive resin is not particularly limited, but the combination of the epoxy resin, the curing agent, and the non-reactive resin is important.

第1成形体(1)の反応性樹脂がエポキシ樹脂であるときの樹脂としては、例えば、ビスフェノールA型エポキシ樹脂、ビスフェノールF型エポキシ樹脂、脂環式エポキシ樹脂、脂肪族エポキシ樹脂、グリシジルエステル系エポキシ樹脂、グリシジルアミン系エポキシ樹脂、複素環式エポキシ樹脂などが用いられる。これらのエポキシ樹脂に、グリシジルエーテル系希釈剤をはじめとする反応性希釈剤や、非反応性希釈剤を併用することもできる。   As the resin when the reactive resin of the first molded body (1) is an epoxy resin, for example, bisphenol A type epoxy resin, bisphenol F type epoxy resin, alicyclic epoxy resin, aliphatic epoxy resin, glycidyl ester type Epoxy resins, glycidylamine epoxy resins, heterocyclic epoxy resins, and the like are used. Reactive diluents such as glycidyl ether diluents and non-reactive diluents can be used in combination with these epoxy resins.

第2成形体(2)の硬化剤としては、例えば、ポリアノアミド系硬化剤、脂肪族ポリアミン系硬化剤、芳香族ポリアミン系硬化剤、ポリチオール系硬化剤などの硬化剤や、これらの2種以上の混合物からなる各種の硬化剤が用いられる。これらの中では、ポリアミノアミド(ポリアミドと呼ばれる高分子領域の硬化剤や、これと構造的に類似し同じ機能を持つ単量体単位の低分子硬化剤化合物)、ポリチオール硬化剤、またはこれらに硬化速度を調整するための第3級アミンなどを配合することもできる。   Examples of the curing agent for the second molded body (2) include a curing agent such as a polyanamide curing agent, an aliphatic polyamine curing agent, an aromatic polyamine curing agent, and a polythiol curing agent, and two or more of these. Various curing agents made of a mixture are used. Among these, polyaminoamides (polyamide curing agents called polyamides, and low molecular curing compound compounds that are structurally similar and have the same function), polythiol curing agents, or cure to these A tertiary amine or the like for adjusting the speed can also be blended.

第3成形体(3)の非反応性樹脂は、例えば、ポリエステル樹脂、ポリオール、ボリブテン、ポリブタジエン、ポリイソプレン、液状ニトリルゴム、EPDM(エチレンプロピレンゴム)、キシレン樹脂などが用いられる。また、これらにベンジルアルコールや流動パラフィンなどの非反応性希釈剤を併用することもできる。   As the non-reactive resin of the third molded body (3), for example, polyester resin, polyol, boribten, polybutadiene, polyisoprene, liquid nitrile rubber, EPDM (ethylene propylene rubber), xylene resin and the like are used. These can also be used in combination with a non-reactive diluent such as benzyl alcohol or liquid paraffin.

第1成形体(1)、第2成形体(2)、第3成形体(3)のそれぞれには主成分のほかに、多量のフィラーを配合することが多い。その他に必要に応じて、膨形用中空フィラー、着色剤、その他の添加剤を配合することもできる。フィラーとしては、例えば、炭酸カルシウム、炭酸マグネシウム、珪藻土、タルク、クレー、焼成クレー、焼成タルク、カオリン、微粉マイカ、シリカ、水酸化マグネシウム、水酸化アルミニウム、セピオライト、ベントナイト、ゼオライト、酸化亜鉛などがある。膨形用中空フィラーとして、例えば、有機質マイクロバルーン、シリカバルーン、ガラスバルーン、フライアッシュバルーンなどがある。顔料としては、例えば、酸化チタン、カーボンなどがある。添加剤としては、分散剤、消泡剤、タレ防止剤、沈降防止剤、スコーチ防止剤、レベリング剤、発泡剤、酸化防止剤、光安定剤などがある。   In addition to the main component, each of the first molded body (1), the second molded body (2), and the third molded body (3) often contains a large amount of filler. In addition, a hollow filler for expansion, a colorant, and other additives can be blended as necessary. Examples of the filler include calcium carbonate, magnesium carbonate, diatomaceous earth, talc, clay, calcined clay, calcined talc, kaolin, fine powder mica, silica, magnesium hydroxide, aluminum hydroxide, sepiolite, bentonite, zeolite, zinc oxide, and the like. . Examples of the hollow filler for expansion include organic microballoons, silica balloons, glass balloons, fly ash balloons and the like. Examples of the pigment include titanium oxide and carbon. Examples of the additive include a dispersant, an antifoaming agent, an anti-sagging agent, an anti-settling agent, an anti-scorch agent, a leveling agent, a foaming agent, an antioxidant, and a light stabilizer.

第1成形体(1)、第2成形体(2)、第3成形体(3)の断面形状は棒状とする。この場合、図1および図2に示すように、矩形断面の板棒状にすることが多いが、第1成形体、第2成形体の側面は片台形断面とすることもでき、その他長円形断面、円形断面のような断面形状とすることもできる。その他、第1成形体(1)と第2成形体(2)の間に第3成形体(3)を接触配置させることが出来る形状ならば、どの様な形状でも差し支えない。例えば、図3(A)に示したように、円柱状の第2成形体(2)を取り巻くように、円管状の第1成形体(1)と第3成形体(3)とが配置された形状や、図3(B)に示したように、各成形体が平板状に形成されて、各々の広い面同士が接触するようにされた形状や、図3(C)に示したように、図3(B)に示したものの更に周囲を第3成形体(3)で包んだようにした形状などが挙げられる。
従来は、例えば図4や図5に示すように、第1成形体(1)と第2成形体(2)との間に空間を設ける必要があったため、実施可能な形状が限られていたが、本発明では、第1成形体(1)と第2成形体(2)の間が第3成形体(3)によって保持されるものであるため、上記のように種々の形状での実施が可能である。
The cross-sectional shapes of the first molded body (1), the second molded body (2), and the third molded body (3) are rod-shaped. In this case, as shown in FIG. 1 and FIG. 2, it is often a plate bar shape with a rectangular cross section, but the side surfaces of the first molded body and the second molded body can be a single trapezoidal cross section. A cross-sectional shape such as a circular cross-section can also be used. In addition, any shape can be used as long as the third molded body (3) can be placed in contact between the first molded body (1) and the second molded body (2). For example, as shown in FIG. 3 (A), the tubular first molded body (1) and the third molded body (3) are arranged so as to surround the cylindrical second molded body (2). As shown in FIG. 3 (B), as shown in FIG. 3 (B), each molded body is formed in a flat plate shape so that the respective wide surfaces come into contact with each other. In addition, there may be mentioned a shape in which the periphery of what is shown in FIG. 3 (B) is wrapped with the third molded body (3).
Conventionally, for example, as shown in FIG. 4 and FIG. 5, since it is necessary to provide a space between the first molded body (1) and the second molded body (2), the shapes that can be implemented are limited. However, in the present invention, the space between the first molded body (1) and the second molded body (2) is held by the third molded body (3). Is possible.

第1成形体(1)、第2成形体(2)の太さ(断面積)は、これを同一にして、目分量で混合するときに多少の誤差があってもほぼ等量の混合が達成できるようにすることが多い。しかしながら、たとえば、第1成形体(1)の方を太くし、第2成形体(2)の方の太さを細くしても差し支えない。というのは、これらの第1成形体(1)、第2成形体(2)は後述のように並行配置体となっており、その並行配置体の巾方向に横断するようにカットして用いるものであるので、常に一定の混合比率が得られるからである。   The first molded body (1) and the second molded body (2) have the same thickness (cross-sectional area), and even when there is a slight error when mixing with the reference amount, almost equal amount of mixing is possible. Often to be able to achieve. However, for example, the first molded body (1) may be thicker and the second molded body (2) may be thinner. This is because the first molded body (1) and the second molded body (2) are arranged in parallel as will be described later, and are cut and used so as to cross the width direction of the parallel arranged body. This is because a constant mixing ratio is always obtained.

第3成形体(3)は、第1成形体(1)と第2成形体(2)の間に接触するように、並行接触配列される。その巾は適宣に設定できるもので特に限定しないが、薄すぎると製造工程上困難となり、広すぎると物量的に主剤と硬化剤の反応生成物を希釈することになるので、硬化物物性に影響を与えない設定を行う必要がある。   The third compact (3) is arranged in parallel contact so as to be in contact between the first compact (1) and the second compact (2). The width can be set appropriately and is not particularly limited, but if it is too thin, it will be difficult in the production process, and if it is too wide, the reaction product of the main agent and the curing agent will be diluted in terms of quantity. It is necessary to make settings that do not affect it.

ここで、後述の実施例では、第1成形体(1)、第2成形体(2)のそれぞれの巾12mmに対して第3成形体(3)を巾2mmとしている。つまり、並行接触配置体の全巾に対する第3成形体(3)の巾の比率は、(2/(12+12+2)×100)=7.69%となる。この比率は、上記理由により、2%〜20%の範囲内で実施することが望ましい。   Here, in the examples described later, the third molded body (3) has a width of 2 mm with respect to the width of 12 mm of each of the first molded body (1) and the second molded body (2). That is, the ratio of the width of the third molded body (3) to the total width of the parallel contact arrangement body is (2 / (12 + 12 + 2) × 100) = 7.69%. It is desirable to implement this ratio within the range of 2% to 20% for the above reason.

第1成形体(1)と第2成形体(2)と第3成形体(3)とからなる並行接触配置体の上下両面には、離型性シート(4)(4)が貼着される。ここで離型性シート(4)(4)としては、たとえば、ポリオレフィンフィルム、ポリエステルフィルム、紙、ポリエチレンラミネート紙などの薄膜シートをシリコーン形剥離剤などの離型剤で処理したシート、その材質自体が離型性を有するシート、樹脂に剥離剤を内添して製膜したシートなどが用いられる。   The releasable sheets (4) and (4) are attached to the upper and lower surfaces of the parallel contact arrangement composed of the first molded body (1), the second molded body (2), and the third molded body (3). The Here, as the releasable sheet (4) (4), for example, a sheet obtained by treating a thin film sheet such as polyolefin film, polyester film, paper, polyethylene laminated paper or the like with a release agent such as a silicone-type release agent, the material itself A sheet having releasability, a sheet formed by adding a release agent to a resin, and the like are used.

<反応性パテ材の製造法>
本発明の反応性パテ材は、上記の構成を有する限りにおいて任意の方法により製造することができるが、工業的には、
(イ)反応性樹脂を主成分とする主剤からなる主剤組成物と、硬化剤を主成分とする硬化剤組成物との間に、主剤と硬化剤のどちらとも反応しない非反応性樹脂を主成分とする非反応性組成物が挟まれるように、上記の各組成物をそれぞれ押出機から吐出して、並行に配置された、棒状の第1成形体(1)と棒状の第2成形体(2)との間に第3成形体(3)が配置された、並行接触配置体を形成していく工程、
(ロ)前工程に際してまたは前工程に続いて、上記の並行接触配置体の上下両面に離型性シート(4)(4)を貼着する工程、
(ハ)上記の離型性シート(4)(4)で被覆された並行接触配置体を巾方向に横断するように、所定の長さにカットする工程、
(ニ)上記のカットされた並行接触配置体を包材(5)で包装する工程、を実施する方法により製造することが特に好ましい。
<Reactive putty material manufacturing method>
The reactive putty material of the present invention can be manufactured by any method as long as it has the above-described configuration.
(B) A non-reactive resin that does not react with either the main agent or the curing agent is mainly between the main agent composition composed of the main component mainly composed of a reactive resin and the curing agent composition mainly composed of a curing agent. The rod-shaped first molded body (1) and the rod-shaped second molded body, which are arranged in parallel, are each discharged from the extruder so that the non-reactive composition as a component is sandwiched between them. A step of forming a parallel contact arrangement in which the third molded body (3) is arranged between (2) and
(B) A step of sticking the releasable sheets (4) and (4) to the upper and lower surfaces of the parallel contact arrangement in the previous step or following the previous step,
(C) A step of cutting the parallel contact arrangement body covered with the above-described release sheet (4) (4) into a predetermined length so as to cross in the width direction,
(D) It is particularly preferable to manufacture the cut parallel contact arrangement body by a method of packaging the packaged material with the packaging material (5).

上記工程(ニ)における包材(5)としては、たとえば、ヒートシール可能なフィルム、内面となる側にシーラント層を設けた基材フィルム、アルミニウム箔ラミネートフィルム、紙、樹脂コート紙、不織布などを用いることができる。   As the packaging material (5) in the above step (d), for example, a heat-sealable film, a base film provided with a sealant layer on the inner surface side, an aluminum foil laminate film, paper, resin-coated paper, non-woven fabric, etc. Can be used.

また、この包材(5)として孔あき包材を用いることにより、第2成形体(2)から揮散するおそれのあるアミン類などの揮発性ガスを袋外に放出させるようにすることも好ましい。   It is also preferable to use a perforated wrapping material as the wrapping material (5) so that volatile gases such as amines that may be volatilized from the second molded body (2) are released out of the bag. .

<用途>
本発明の反応性パテ材は、ホビー用をはじめとする各種材料の接着のほか、自動車バンパーの補修、木工家具類の凹部補修、浴室のタイル補修、フローリングの補修、陶磁器の補修、コンクリートのひび割れ補修、外装仕上げ材の剥離部の補修など補修目的に有用である。
<Application>
The reactive putty material of the present invention is used for bonding various materials including hobby, repairing automobile bumpers, repairing concave parts of woodworking furniture, repairing bathroom tiles, repairing flooring, repairing ceramics, cracking concrete. It is useful for repair purposes such as repair and repair of peeled parts of exterior finish materials.

<使い方>
本発明の反応性パテ材を使用するにあたっては、包材(5)を開封してから、並行接触配置体を巾方向に横断するようにカットして必要量の第1成形体(1)と第2成形体(2)と第3成形体(3)の並行接触配置体のピースを得る(離型性シート(4)(4)はカット前または後に除去する)。ついで両ピースを指で混練してから、対象物を接着したり、必要箇所の充填に用いたりする。その後は放置するだけで、接着や補修の目的が達成される。
<How to use>
In using the reactive putty material of the present invention, after opening the packaging material (5), the parallel contact arrangement body is cut so as to cross in the width direction, and the necessary amount of the first molded body (1) and A piece of the parallel contact arrangement body of the second molded body (2) and the third molded body (3) is obtained (removable sheets (4) and (4) are removed before or after cutting). Then, after kneading both pieces with fingers, the object is adhered or used for filling a necessary portion. After that, the purpose of adhesion and repair can be achieved simply by leaving it alone.

次に実施例をあげて本発明を詳細に説明する。以下「部」とあるのは重量部である。
図2(A)は本発明の反応性パテ材の一例を示した巾方向の断面図である。
Next, the present invention will be described in detail with reference to examples. Hereinafter, “parts” means parts by weight.
FIG. 2A is a cross-sectional view in the width direction showing an example of the reactive putty material of the present invention.

反応性樹脂を主成分とする主剤からなる主剤組成物として、ビスフェノールA型エポキシ樹脂100部、炭酸カルシウム100部、タルク100部、および少量の中空フィラーと顔料よりなる組成物を準備した。   As a main ingredient composition comprising a main ingredient mainly composed of a reactive resin, a composition comprising 100 parts of a bisphenol A type epoxy resin, 100 parts of calcium carbonate, 100 parts of talc, and a small amount of a hollow filler and a pigment was prepared.

硬化剤を主成分とする硬化剤組成物としてポリアミド樹脂を60部、ポリアミン樹脂40部、炭酸カルシウム100部、タルク100部、その他少量の中空フィラーと顔料よりなる組成物を準備した。   A composition comprising 60 parts of a polyamide resin, 40 parts of a polyamine resin, 100 parts of calcium carbonate, 100 parts of talc, and a small amount of a hollow filler and a pigment was prepared as a curing agent composition containing a curing agent as a main component.

実施例1の非反応性樹脂を主成分とする非反応性組成物としてキシレン樹脂100部、炭酸カルシウム200部、その他少量の中空フィラーと顔料よりなる組成物を準備した。   A composition comprising 100 parts of xylene resin, 200 parts of calcium carbonate, and a small amount of a hollow filler and a pigment was prepared as a non-reactive composition mainly composed of the non-reactive resin of Example 1.

実施例2の非反応性樹脂を主成分とする非反応性組成物としてポリオール(ビスフェノールAエチレンオキシド)100部、炭酸カルシウム200部、その他少量の中空フィラーと顔料よりなる組成物を準備した。   A composition comprising 100 parts of polyol (bisphenol A ethylene oxide), 200 parts of calcium carbonate, and a small amount of a hollow filler and a pigment was prepared as a non-reactive composition mainly composed of the non-reactive resin of Example 2.

離型性シート(4)(4)として片面にシリコーン系離型剤による剥離処理を施した厚み50μmのポリエチレンフィルムを準備した。また包材(5)として、厚み50μmの二軸延伸ポリプロピレンフィルムの片面に厚み30μmのポリエチレンシーラント層を設けたラミネートフィルムに、0.3mmφの孔を5〜6個/cm2の割合で設けた孔あき包材を準備した。 As a releasable sheet (4) (4), a polyethylene film having a thickness of 50 μm, which was subjected to a release treatment with a silicone release agent on one side, was prepared. Further, as a packaging material (5), 0.3 mmφ holes were provided at a rate of 5 to 6 / cm 2 on a laminate film in which a polyethylene sealant layer having a thickness of 30 μm was provided on one side of a biaxially stretched polypropylene film having a thickness of 50 μm. A perforated packaging material was prepared.

上記3種の組成物をそれぞれの押出機に供給し、それぞれのダイから、搬送ベルト上を走行する離型性シート(4)(4)の剥離処理面上に、厚み3.5mm、巾12mmの長尺の第1成形体(1)と厚み3.5mm、巾12mmの長尺の第2成形体(2)との間に、厚み3.5mm、巾2mmの第3成形体(3)が配置された並行接触配置体として吐出すると共に、その上から離型性シート(4)(4)を離型処理面が並行接触配置体側となるように被覆貼着していった。   The above three kinds of compositions are supplied to the respective extruders, and the 3.5 mm thickness and 12 mm width are provided on the release treatment surfaces of the release sheets (4) and (4) running on the conveyor belt from the respective dies. A third molded body (3) having a thickness of 3.5 mm and a width of 2 mm between the long first molded body (1) and a long second molded body (2) having a thickness of 3.5 mm and a width of 12 mm. Was discharged as a parallel contact arrangement body in which was disposed, and the releasable sheets (4) and (4) were coated and adhered from above so that the release treatment surface was on the parallel contact arrangement body side.

続いて、全体を所定の長さに巾方向に横断するようにカットし、上述の包材(5)で包装した。これにより図2(B)に示すような反応性パテ材が得られた。   Then, it cut so that the whole might cross | intersect the width direction to predetermined length, and packaged with the above-mentioned packaging material (5). As a result, a reactive putty material as shown in FIG. 2B was obtained.

この反応性パテ材を、温度40℃の加速試験に供して、第1成形体(1)と第2成形体(2)と第3成形体(3)との接触部分における硬化の有無を見ると共に、何日経過したときに実際の使用に際して支障を生ずるかどうかの、保存性の評価を行った。   This reactive putty material is subjected to an accelerated test at a temperature of 40 ° C., and the presence or absence of curing at the contact portion between the first molded body (1), the second molded body (2), and the third molded body (3) is observed. At the same time, the storage stability was evaluated to determine how many days would elapse during actual use.

次に、比較例1として、次の反応性パテ材を製作した。
上記のうち、主剤組成物と硬化剤組成物をそれぞれの押出機に供給し、それぞれのダイから、搬送ベルト上を走行する離型性シート(103)(103)の剥離処理上に、厚み3.5mm、巾12mmの長尺の第1成形体(101)と厚み3.5mm、巾12mmの長尺の第2成形体(102)を5mmの溝状の間隔をあけて並行に配置されるように吐出すると共に、その上から離型性シート(103)(103)を離型処理面が並行接触配置体側となるように被覆貼着していった(図4(A)参照)。続いて、全体を所定の長さに巾方向に横断するようにカットし、上述の包材(104)で包装した。これにより図4(B)に示すような反応性パテ材(比較例1)が得られた。
Next, as Comparative Example 1, the following reactive putty material was manufactured.
Of the above, the main component composition and the curing agent composition are supplied to the respective extruders, and the thickness 3 on the release treatment of the releasable sheets (103) (103) running on the conveyor belt from the respective dies. A long first molded body (101) having a length of 5 mm and a width of 12 mm and a long second molded body (102) having a thickness of 3.5 mm and a width of 12 mm are arranged in parallel with a gap of a groove of 5 mm. In addition, the releasable sheets (103) and (103) were coated and adhered so that the release treatment surface was on the side of the parallel contact arrangement body (see FIG. 4A). Subsequently, the whole was cut to a predetermined length so as to cross in the width direction and packaged with the above-described packaging material (104). Thereby, a reactive putty material (Comparative Example 1) as shown in FIG. 4B was obtained.

また、特許文献1に記載の、従来における第3のタイプのパテ材についても、比較例2として製作した。これは、図4(A)に示すものの、第1成形体(101)と第2成形体(102)との間における離型性シート(103)(103)を、ローラーによって上方から押圧して得られた、図5(C)に示すような反応性パテ材である。
上記のようにして得られた各比較例の反応性パテ材につき、上記実施例と同様にして保存性の評価を行った。
Further, the third type putty material of the prior art described in Patent Document 1 was also manufactured as Comparative Example 2. As shown in FIG. 4 (A), the release sheet (103) (103) between the first molded body (101) and the second molded body (102) is pressed from above with a roller. The obtained reactive putty material as shown in FIG.
The reactive putty material of each comparative example obtained as described above was evaluated for storage stability in the same manner as in the above examples.

<結果>
各実施例と各比較例との保存性の評価結果を表1に示す。表中で、○は初期状態に比して変化なし、△は端縁部分のタックがなくなりかけた時点、×は実際の使用に際して支障を生ずるようになった時点(端縁部分のタックがなくなると共に固くなるため、折ったときにクラックが入り、第1成形体(1)(101)および第2成形体(2)(102)の混練に際して「ブツ」を生ずるようになった時点)である。
なお、表中の「表面」とは、図2(B)及び図4(B)、図5(C)上における上下側の面であり、同「外側の側面」とは同各図上における左右の外側面である。
また、同「接触部」とは、実施例においては、第1成形体(1)あるいは第2成形体(2)の、第3成形体(3)と接する面であり、比較例2においては、図5(C)で「V」形とされた部分における第1成形体(101)と第2成形体(102)との接触部分である。また、同「間隙部」とは、比較例1における第1成形体(101)と第2成形体(102)との対向面である。
また、同「混練物」とは、第1成形体(1)(101)と第2成形体(2)(102)とを混練した状態を指す。
<Result>
Table 1 shows the evaluation results of the storage stability of each example and each comparative example. In the table, ○ indicates no change compared to the initial state, △ indicates that the edge portion of the tack is about to disappear, and × indicates a point in time when trouble occurs in actual use (the end portion of the tack disappears) Since it hardens together, it cracks when it is folded, and when the first molded body (1) (101) and the second molded body (2) (102) are kneaded, it becomes a “slip”. .
The “surface” in the table is the upper and lower surfaces in FIGS. 2B, 4B, and 5C, and the “outer side surface” is the same in each figure. Left and right outer surfaces.
The “contact portion” is a surface of the first molded body (1) or the second molded body (2) in contact with the third molded body (3) in the embodiment. FIG. 5C is a contact portion between the first molded body (101) and the second molded body (102) in the portion formed as “V” in FIG. In addition, the “gap portion” is an opposing surface of the first molded body (101) and the second molded body (102) in Comparative Example 1.
Further, the “kneaded product” refers to a state in which the first molded body (1) (101) and the second molded body (2) (102) are kneaded.

表1に示すように、比較例1では、60日経過後に支障が生じるようになり、比較例2では、240日経過後に支障が生じるようになった。これに対し、実施例では270日までは何ら支障なく使用でき、従来の反応パテ材よりも長期にわたる保存性に優れることが確認できた。   As shown in Table 1, in Comparative Example 1, trouble occurred after 60 days, and in Comparative Example 2, trouble occurred after 240 days. On the other hand, in the Example, it could be used without any trouble until 270 days, and it was confirmed that the storage stability over a long period of time was superior to the conventional reaction putty material.

Figure 2007084679
Figure 2007084679

本発明の反応性パテ材の構成を示した斜視図である。It is the perspective view which showed the structure of the reactive putty material of this invention. (A)は本発明の反応性パテ材を示した巾方向の断面図であり、(B)は本発明の反応性パテ材を包装した状態を示した巾方向の断面図である。(A) is the cross-sectional view of the width direction which showed the reactive putty material of this invention, (B) is the cross-sectional view of the width direction which showed the state which packaged the reactive putty material of this invention. (A)〜(C)共、本発明の反応性パテ材における、主剤組成物と硬化剤組成物の間に非反応性組成物を接触配置させる例を示した斜視図である。(A)-(C) is the perspective view which showed the example which contacts and arrange | positions a non-reactive composition between the main ingredient composition and the hardening | curing agent composition in the reactive putty material of this invention. (A)は従来タイプの反応性パテ材を示した巾方向の断面図であり、(B)は包装された従来タイプの反応性パテ材を示した巾方向の断面図である。(A) is the cross-sectional view of the width direction which showed the conventional type reactive putty material, (B) is the cross-sectional view of the width direction which showed the packaged conventional type reactive putty material. (A)は他の従来タイプの反応性パテ材を示した巾方向の断面図であり、(B)は(A)の反応性パテ材の製造工程を示す斜視の説明図である。また、(C)は他の従来タイプの反応性パテ材の異なる形態を示した巾方向の断面図である。(A) is sectional drawing of the width direction which showed the reactive putty material of the other conventional type, (B) is explanatory drawing of the perspective which shows the manufacturing process of the reactive putty material of (A). Further, (C) is a cross-sectional view in the width direction showing a different form of another conventional type putty material.

符号の説明Explanation of symbols

(1)…第1成形体
(2)…第2成形体
(3)…第3成形体
(4)…離型性シート
(5)…包材
(1) ... first molded body (2) ... second molded body (3) ... third molded body (4) ... releasable sheet (5) ... packaging material

Claims (8)

反応性樹脂を主成分とする主剤からなる第1成形体(1)と、硬化剤を主成分とする第2成形体(2)との間に、第1成形体(1)および第2成形体(2)のどちらとも反応しない非反応性樹脂を主成分とする第3成形体(3)を接触するように配置したことを特徴とする反応性パテ材。   Between the 1st molded object (1) which consists of a main ingredient which has a reactive resin as a main component, and the 2nd molded object (2) which has a hardening | curing agent as a main component, a 1st molded object (1) and 2nd shaping | molding A reactive putty material comprising a third molded body (3) mainly composed of a non-reactive resin that does not react with either of the bodies (2). 上記の第1成形体(1)と第2成形体(2)と第3成形体(3)とからなる、並行接触配置体の上下両面に離型性シート(4)(4)が貼着されたことを特徴とする、請求項1に記載の反応性パテ材。   The releasable sheets (4) and (4) are attached to the upper and lower surfaces of the parallel contact arrangement comprising the first molded body (1), the second molded body (2) and the third molded body (3). The reactive putty material according to claim 1, wherein 上記の、離型性シート(4)(4)が貼着された状態にある並行接触配置体の全体が、包材(5)で包装されたことを特徴とする、請求項2に記載の反応性パテ材。   The whole parallel contact arrangement body in the state in which the release sheet (4) (4) is adhered is packaged with a packaging material (5) according to claim 2, Reactive putty material. 第1成形体(1)がエポキシ樹脂を主成分とする主剤の成形体であり、
第2成形体(2)がポリアミド系硬化剤、ポリアミン系硬化剤およびポリチオール系硬化剤よりなる群から選ばれた少なくとも1種以上を主成分とする硬化剤の成形体であり、
第3成形体(3)がキシレン樹脂等の非反応性樹脂を主成分とする成形体であることを特徴とする、請求項1〜3のいずれかに記載の反応性パテ材。
The first molded body (1) is a molded body of a main ingredient mainly composed of an epoxy resin,
The second molded body (2) is a molded body of a curing agent mainly composed of at least one selected from the group consisting of a polyamide curing agent, a polyamine curing agent and a polythiol curing agent,
The reactive putty material according to any one of claims 1 to 3, wherein the third molded body (3) is a molded body mainly composed of a non-reactive resin such as xylene resin.
反応性樹脂を主成分とする主剤からなる主剤組成物と、硬化剤を主成分とする硬化剤組成物との間に、主剤と硬化剤のどちらとも反応しない非反応性樹脂を主成分とする非反応性組成物が挟まれるように、上記の各組成物をそれぞれ押出機から吐出して、
並行に配置された、棒状の第1成形体(1)と棒状の第2成形体(2)との間に第3成形体(3)が配置された、並行接触配置体を形成していく工程を実施することを特徴とする反応性パテ材の製造法。
The main component is a non-reactive resin that does not react with either the main agent or the curing agent between the main agent composition composed of the main component mainly composed of a reactive resin and the curing agent composition mainly composed of the curing agent. Each of the above compositions is discharged from the extruder so that the non-reactive composition is sandwiched between them,
A parallel contact arrangement in which the third molded body (3) is disposed between the rod-shaped first molded body (1) and the rod-shaped second molded body (2) arranged in parallel is formed. The manufacturing method of the reactive putty material characterized by implementing a process.
請求項5に記載された工程に際して、または当該工程に続いて、
上記の並行接触配置体の上下両面に離型性シート(4)(4)を貼着する工程を実施することを特徴とする反応性パテ材の製造法。
Upon or following the process recited in claim 5
The manufacturing method of the reactive putty material characterized by implementing the process of sticking a release sheet (4) (4) on the upper and lower surfaces of said parallel contact arrangement body.
請求項6に記載された工程に際して、または当該工程に続いて、
上記の離型性シート(4)(4)が貼着された並行接触配置体を巾方向に横断するように、所定の長さにカットする工程を実施することを特徴とする反応性パテ材の製造法。
During or following the process recited in claim 6,
Reactive putty material characterized by performing a step of cutting to a predetermined length so as to cross the parallel contact arrangement body to which the above-mentioned releasable sheets (4) and (4) are adhered in the width direction Manufacturing method.
請求項7に記載された工程に際して、または当該工程に続いて、
上記のカットされた並行接触配置体を包材(5)で包装する工程を実施することを特徴とする反応性パテ材の製造法。
During or following the process recited in claim 7,
The manufacturing method of the reactive putty material characterized by implementing the process of packaging said cut parallel contact arrangement body with a packaging material (5).
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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4997866A (en) * 1972-11-02 1974-09-17
JP2001234123A (en) * 2000-02-23 2001-08-28 Alteco Inc Reactive putty material and its manufacturing method

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4997866A (en) * 1972-11-02 1974-09-17
JP2001234123A (en) * 2000-02-23 2001-08-28 Alteco Inc Reactive putty material and its manufacturing method

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