JP2007046126A - Surface treated steel strip - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a surface treated steel strip capable of exhibiting industrially stable plastic working performance by the formation of a lubricating film having excellent resistance such as corrosion resistance and oil resistance upon long term storage under a practical environment that the surface treated steel strip is used. <P>SOLUTION: In the surface treated steel strip in which a film comprising: (A) an alkali silicate metal salt in which the molar ratio of SiO<SB>2</SB>/M<SB>2</SB>O (M denotes an alkali metal) is 2 to 5; (B) synthetic hectorite; and (C) the alkali metal salt of saturated or unsaturated fatty acid, and comprising no wax, or a film comprising: (A) the above alkali silicate metal salt; (B) synthetic hectorite; (C) an alkali metal salt; and (D) high polymer wax as an auxiliary lubricating component is formed on the surface of the steel strip. Based on the total solid component mass of the film, the solid component contents of (A), (B), and (C) are 45 to 94 mass%, 1 to 10 mass%, and 5 to 20 mass%, respectively, and, in the case (D) is comprised, the solid component content thereof is 1 to 15 mass%. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

  The present invention relates to a surface-treated steel strip having lubricity that can be used in the field of cold plastic working of a steel strip such as plate forging, press forming, roll forming and the like. More specifically, there is no lubrication film on the surface of the steel strip that can exhibit stable plastic processing performance in a practical environment without rusting during long-term storage or contact deterioration with rust preventive oil or processing oil. The present invention relates to a surface-treated steel strip.

Among the plastic working fields in which steel strips are used, in particular in the cold forging field such as plate forging, where strong processing under high surface pressure is required, phosphate crystals are deposited on the steel sheet surface, and then the upper layer is coated with a soap film. Phosphate soap treatment that forms a composite film of phosphate and soap by coating has long been performed. The phosphate film has good adhesion to the material and has excellent seizure resistance to follow the area expansion during processing by cleaving the crystal, and the upper layer is formed by reaction with phosphate. As the metal soap film and alkali soap film are formed, excellent plastic workability is imparted to the surface of the steel sheet to realize advanced forging.
Furthermore, the steel plate surface coated with phosphate soap film is suitable for long-term storage due to the anticorrosive action of phosphate, and there is no contact with oil or change in performance over time for stable practical use. Is also excellent.

  However, a chemical conversion treatment method such as phosphate soap treatment involves complicated steps including pre- and post-treatments, and requires a long chemical conversion reaction time. Therefore, continuous treatment in the form of a steel strip is substantially difficult. Therefore, in plate forging using a steel strip, after the blanking step of cutting the steel strip into a pre-working shape, chemical conversion treatment must be performed for each of the cut workpieces, and the equipment burden or outsourcing treatment costs associated therewith, It takes a lot of effort and cost. Furthermore, in phosphate soap treatment, it is inevitable that sludge generated by chemical reaction and waste soap deteriorated due to acid contamination from the previous process become a large amount of industrial waste. As a result, wastewater containing heavy metal ions, phosphate ions, nitrate ions, hydrofluoric acid ions, etc. is generated, which requires much labor and cost for wastewater treatment. Therefore, phosphate soap treatment is being regarded as a problem in recent trends aimed at environmental conservation.

  On the other hand, in recent years, for the purpose of improving productivity and environmental conservation, a lubrication system that is going to replace the phosphate soap treatment is being developed. This technology provides a high level of lubricity by a simple process of attaching a liquid non-reactive coating agent to the surface of the metal material to be processed and then drying it. It is also suitable for continuous processing in the form of steel strips, which was difficult to achieve in the industry. Furthermore, compared to chemical conversion processing, the generation of waste such as reaction by-products is overwhelmingly small, and the working environment is also good. The above utility value is highly evaluated.

  As such a technique, Patent Document 1 discloses an aqueous composition for forming a protective film containing an aqueous inorganic salt and a smectite clay mineral. As the aqueous inorganic salt, at least one selected from sulfates, borates, silicates, molybdates, vanadine sun salts, and tungstates is used. At least one selected from light, nontronite, saponite, iron saponite and stevensite is used. The composition contains at least one lubricating component selected from oil, soap, metal soap, wax and polytetrafluoroethylene as a lubricating component, based on the total of aqueous inorganic salt, smectite clay mineral and lubricating component, 1 By containing ~ 70% by mass, the formed lubricating film can have both good seizure resistance and excellent lubricating performance, so that the film is an excellent lubricating film comparable to a phosphate soap film. It is described as.

  This composition contains an aqueous inorganic salt, a smectite-based clay mineral, and water. The smectite-based clay mineral particles are colloidally dispersed in the aqueous inorganic salt aqueous solution, so that appropriate thixotropy is expressed. Thus, the liquid film adhering to the surface of the material to be coated causes rapid gelation until the drying step, thereby realizing a uniform coverage with less adhesion amount gradient and adhesion spots due to dripping. In addition, the viscosity improvement rate for liquid film concentration is very high, and the physical uniformity of the film composition is dramatically improved to physically suppress aggregation and segregation due to heat concentration of lubricating components contained in the liquid film. Has been. As a result, these are responsible for improving the seizure resistance and lubrication stability of the surface of the workpiece, and regardless of the coating type, the film has excellent processability and seizure resistance equivalent to or better than the chemical conversion treatment method. Is formed.

However, in the above invention, resistance to a practical environment in which the surface-treated steel strip is handled, such as rusting during long-term storage and film deterioration due to contact with antirust oil or processing oil, is not sufficiently assumed. The appearance of a surface-treated steel strip that can exhibit stable plastic working performance in a practical environment has been awaited.
International Publication WO02 / 014458

  The present invention solves the above-described problems of the prior art. In other words, resistance to the practical environment in which the surface-treated steel strip is handled, such as rusting during long-term storage, and film degradation due to contact with rust-preventing oil or processing oil, etc., can exhibit stable plastic processing performance The purpose is to provide a surface-treated steel strip. In the present invention, “plastic processing performance” refers to a low coefficient of friction for reducing the load during plastic processing, film adhesion for preventing the seizure by the film following the surface area expansion, and seizure resistance. Means dynamic performance.

  As a result of intensive studies to solve the above problems, the inventors of the present invention contain a specific alkali metal silicate, synthetic hectorite and alkali metal salt of a saturated or unsaturated fatty acid on the surface of the steel strip. Produces a surface-treated steel strip that can exhibit practically stable plastic working performance by forming a film without causing rusting during long-term storage or contact with rust preventive oil or processing oil. The present inventors have found that the lubricating performance can be further improved without lowering the oil resistance by blending a specific amount of the polymer wax.

That is, the present invention relates to alkali metal silicate (A), synthetic hectorite (B), and saturated or unsaturated fatty acid alkali having a SiO ₂ / M ₂ O (M represents alkali metal) molar ratio of 2 to 5. Film containing metal salt (C) but no wax, or alkali metal silicate (A), synthetic hectorite (B) and alkali metal salt (C) as described above and polymer wax as auxiliary lubricating component ( D) is a surface-treated steel strip formed on the surface of the steel strip, and the solid content of (A), (B) and (C) based on the total solid mass of the coating Are 45-94 mass%, 1-10 mass%, and 5-20 mass%, respectively, and it is related with this surface treatment steel strip whose solid content of (D) is 1-15 mass%. The polymer wax is preferably at least one selected from polyethylene wax, polypropylene wax and polytetrafluoroethylene wax. Moreover, it is preferable that the adhesion amount of a lubricating film is 1-15 g / m < ² >. In addition, the solid content of (A), (B), (C) and (D) in the above-mentioned film is (A) based on the total solid content in the aqueous treatment liquid used to form the film. , (B), (C), and (D), which are equal to the solid content, and are represented by their respective solid content.

  The lubricating film formed on the surface of the steel strip of the present invention exhibits excellent seizure resistance and rust resistance due to the film made of alkali metal silicate (A), and is water-soluble so that it is hardly affected by oil. Alternatively, by containing an alkali metal salt (C) of an unsaturated fatty acid, stable lubricity is exhibited even in a contact environment with oil. In the formation process of the lubricating film, the liquid film viscosity in the film formation process is controlled by the synthetic hectorite (B) dispersed colloidally in the alkali metal silicate aqueous solution, and the film is uniformly applied. In addition, since the uniformity of the alkali metal salt of a saturated or unsaturated fatty acid distributed in the film and the distribution of other dispersed components in the film is ensured, a smooth lubricating film can be formed. Further, by blending the polymer wax (D) that does not easily swell into oil in a specific amount range, it is possible to impart further excellent plastic processing performance to the formed film.

  The surface-treated steel strip of the present invention is excellent in resistance in a practical environment where the surface-treated steel strip is handled, for example, corrosion resistance and oil resistance during long-term storage, and can exhibit industrially stable plastic working performance. Further, the surface-treated steel strip of the present invention is a simple method of drying after attaching an aqueous treatment liquid to the surface of the steel strip, and has less waste than the phosphate soap treatment method, and has a working environment. Can be manufactured by a good method, and the performance is comparable to that of a surface-treated steel strip having a phosphate soap-treated film. Therefore, the industrial utility value of the present invention is extremely large.

The present invention is described in detail below.
The “steel” in the “surface-treated steel strip” of the present invention includes not only carbon steel but also alloy steel and special steel. The steel strip includes not only a hot-rolled steel strip and a cold-rolled steel strip, but also a plated steel strip whose surface is galvanized. The surface-treated steel strip of the present invention is mainly used for plate forging applications, but is not limited thereto and can be used for a wide range of applications. In addition, as a steel strip used for a plate forging use, it is common to use a hot-rolled steel strip having a relatively thick plate thickness such as a plate thickness of 2.3 mm or more.

The alkali metal silicate (A), which is the coating base (main component) of the lubricating coating formed on the surface of the surface-treated steel strip of the present invention, forms a strong continuous coating with excellent heat resistance on the steel strip surface. In addition to exhibiting a seizure resistance function that prevents direct metal contact between the workpiece and the tool and a rust resistance function due to the barrier properties of a dense alkaline film, alkali metal salts of saturated or unsaturated fatty acids. In addition, it has a function of retaining other dispersed components in the film. The alkali metal silicate (A) is usually used in the form of an aqueous solution. It is considered that the alkali metal silicate salt can exist stably in the liquid because the hydrated M ⁺ impedes the condensation of silicate ions with OH, and the more the M ₂ O content, the more it dissolves in water. It is easy and stable as an aqueous solution. However, in the present invention, in order to form a glassy film with an alkali metal silicate salt, it is necessary that the SiO ₂ / M ₂ O molar ratio is in the range of 2 to 5, and if it is outside this range The film strength is not sufficiently obtained, and the plastic working performance is extremely deteriorated. In addition, when it is larger than 5, the stability as an aqueous solution is deteriorated, so that the practicality becomes poor. Specifically, lithium silicate, sodium silicate, potassium silicate and the like having a molar ratio of SiO ₂ / M ₂ O of ₂ to 5 can be used, but considering the stability of the aqueous solution, film forming property, etc. Sodium silicate is particularly preferable, and the molar ratio of SiO ₂ / M ₂ O is preferably 3-4.

  The content of the alkali metal silicate (A) in the lubricating film formed on the surface of the surface-treated steel strip of the present invention is 45 to 94% by mass as a solid content based on the total solid mass of the film. It is necessary to be 50 to 90% by mass. If the content of (A) is less than 45% by mass, the continuity of the glassy film formed by the alkali metal silicate is poor, so that the film strength that can withstand plastic working cannot be obtained. When the content of (A) exceeds 94% by mass, the amount of the synthetic hectorite (B) and saturated or unsaturated fatty acid alkali metal salt (C) that can be blended is insufficient. It becomes impossible to express.

Synthetic hectorite (B), which ensures uniform coating properties when forming a lubricating film on the surface-treated steel strip of the present invention and the uniformity of the distribution of lubricating components in the film, has the general formula [Si ₈ (Mg _a Li _b ) O ₂₀ (OH) _c F4 _−c ] ^−x Na ^{+ x} (0 <a ≦ 6, 0 <b ≦ 6, 4 <a + b <8, 0 ≦ c ≦ 4, x = 12-2 a−b) Is a synthetic clay mineral. The particles of the synthetic hectorite have a three-layer structure, and each layer of the crystal structure in the layered structure is a two-dimensional platelet having a thickness of about 1 nm. Then, some of the magnesium atoms present in the middle layer of the platelet unit are isomorphously substituted with low-valent lithium atoms, and as a result, the platelet unit is negatively charged. In the dry state, this negative charge is balanced with displaceable cations outside the lattice structure of the plate surface, and in the solid phase these particles are bonded together by van der Waals forces to form a flat plate bundle.

  When such synthetic hectorite (B) is dispersed in the aqueous phase, the replaceable cation is hydrated, causing the particles to swell. When dispersed using a normal disperser such as a high-speed dissolver, a stable sol is obtained. Obtainable. In such a state dispersed in the aqueous phase, the platelets have negative charges on the surface, electrostatically repel each other, and become stable sols subdivided into platelet-like primary particles. However, when the particle concentration is increased or the ion concentration is increased, the repulsive force due to the surface negative charge is reduced, and the other plate edge that is positively charged is electrically connected to the negatively charged platelet surface. It becomes possible to orientate and form a so-called card house structure, exhibiting thickening and thixotropy. Since the card house structure is bonded due to electrical attraction, the dispersion exhibits structural viscosity in the low shear region and bond separation occurs in the high shear region, resulting in a sol state, indicating excellent thixotropy. Conceivable. The aqueous phase dispersion of synthetic hectorite is considered to be a two-dimensional platelet or disk-like plate having a thickness of about 1 nm and a plate surface diameter of 20 to 40 nm.

  Synthetic hectorite (B) is essential for forming a uniform film on the steel strip and also ensuring the uniformity of the distribution of the lubricating component in the film. Since the synthetic hectorite (B) contained in the colloidal dispersion state in the aqueous solution of the alkali metal silicate (A) has a very small diameter, the aqueous solution efficiently has a strong structural viscosity at low shear. To express. The liquid film adhering to the surface of the material to be coated due to this structural viscosity causes rapid gelation until the drying process, and can realize uniform coverage with less adhesion amount gradient and adhesion spots due to dripping. Furthermore, since the viscosity improvement rate for liquid film concentration is very high, aggregation and segregation due to heat concentration of lubricating components contained in the liquid film can be physically suppressed, and the composition uniformity of the film is dramatically improved. To do. As a result, these are responsible for the stable improvement in seizure resistance and lubricity of the surface-treated steel strip of the present invention.

  The content of the synthetic hectorite (B) in the lubricating film of the surface-treated steel strip of the present invention needs to be 1 to 10% by mass as a solid content based on the total solid content mass of the film, It is preferable that it is 2-8 mass%. If the content of the synthetic hectorite (B) is less than 1% by mass, sufficient structural viscosity is difficult to be exhibited, and the uniform coating property of the coating and the uniformity of the distribution of the lubricating component are likely to be adversely affected. In addition, when the content exceeds 10% by mass, the effect is saturated, and the viscosity of the treatment liquid is extremely increased, resulting in poor handling in the coating process.

  Since the alkali metal salt (C) of the saturated or unsaturated fatty acid in the lubricating film of the surface-treated steel strip of the present invention has lubricity, it is water-soluble and hardly compatible with oil. It is an essential component for imparting lubricity and oil resistance to the film formed on the surface. Specific examples of the saturated or unsaturated fatty acid alkali metal salt (C) include octanoic acid, decanoic acid, lauric acid, myristic acid, palmitic acid, icosanoic acid, oleic acid, linoleic acid, linolenic acid, stearic acid, and a portion. Examples thereof include lithium salts, sodium salts and potassium salts of saturated or unsaturated fatty acids such as isostearic acid having a branched structure. Moreover, it is preferable that carbon number which comprises this fatty acid is 8-22, and it is more preferable that it is 12-18. If it is 7 or less, the lubricity is insufficient, and if it is 23 or more, the hydrophobicity becomes strong and the oil resistance tends to be inferior. These alkali metal salts of saturated or unsaturated fatty acids can be used alone or in combination of two or more.

  The content of the alkali metal salt (C) of the saturated or unsaturated fatty acid in the lubricating film of the surface-treated steel strip of the present invention is 5 to 20% by mass as a solid content based on the total solid content mass of the film. It is necessary. If the content of (C) is less than 5% by mass, the desired plastic working performance cannot be obtained because the lubricity is insufficient. On the other hand, if it exceeds 20% by mass, the effects relating to lubricity and oil resistance are saturated and economically wasteful, and the plastic working performance deteriorates due to a decrease in the continuity of the film.

  In the lubricating film formed on the surface-treated steel strip of the present invention, for the purpose of further improving the plastic processing performance of the film, a polymer wax (D) having a feature that hardly swells in oil may be contained. it can. The polymer wax (D) is preferably polyethylene wax, polypropylene wax, or polytetrafluoroethylene wax, and these can be used alone or in combination of two or more.

  The content of the polymer wax (D) in the lubricating film of the surface-treated steel strip of the present invention is preferably 1 to 15% by mass as a solid content based on the total solid mass of the film. More preferably, it is 10 mass%. If the content of (D) is less than 1% by mass, it tends to be difficult to achieve further improvement in the plastic working performance, and if it exceeds 15% by mass, oil diffusion from the wax interface into the film becomes significant. Oil resistance deteriorates, and the desired plastic working performance tends to be difficult to obtain in an environment where the oil comes into contact.

  When forming the lubricating film covering the surface-treated steel strip of the present invention, a viscosity modifier can be contained within a range that does not affect the film strength in order to adjust the viscosity of the aqueous treatment liquid. As the viscosity modifier, those commonly used can be used, and examples thereof include organic polymer thickeners such as hydroxyethyl cellulose, carboxymethyl cellulose, polyacrylic amide, sodium polyacrylate, polyvinyl pyrrolidone, and polyvinyl alcohol. It is done. When using a viscosity modifier, it is preferable that the content is less than 10 mass% as solid content on the basis of the total solid content mass of this membrane | film | coat.

In order to form a lubricating film covering the surface of the surface-treated steel strip of the present invention, an aqueous treatment solution containing a predetermined amount of each of the above components in water is prepared and applied to the surface of the steel strip that is the material to be coated. And then drying.
Although there is no restriction | limiting in particular about the minimum of solid content concentration of an aqueous processing liquid, It is preferable that it is 5 mass% or more, and it is further more preferable that it is 10 mass% or more. Although there is no restriction | limiting in particular also about the upper limit of this solid content concentration, It is preferable that it is 40 mass% or less. When the solid content concentration is less than 5% by mass, it tends to be difficult to form a uniform film. When the solid content concentration exceeds 40% by mass, the viscosity of the aqueous treatment liquid is remarkably increased, and uniform application tends to be difficult in handling. .

  Prior to applying the aqueous treatment liquid used to form the lubricating film of the surface-treated steel strip of the present invention to the coated material, a pretreatment for cleaning the coated surface of the coated material is performed. Is appropriate. Such pretreatment is usually performed by alkali degreasing → water washing → acid washing → water washing → drying, alkali degreasing → water washing → drying and the like.

  As a method for applying the aqueous treatment liquid, conventional methods such as dipping, shower ringer, roll coating, etc. can be employed. Of these, the roll coating method is common. In addition, application | coating should just fully coat | cover the to-be-coated material surface with an aqueous processing liquid, and there is no restriction | limiting in particular in aqueous processing liquid temperature and application | coating time. Further, the treatment liquid film after application needs to be dried. Drying may be performed by standing at normal temperature, but it is usually preferable to perform the hot strip drying so that the steel strip surface temperature reaches 50 to 150 ° C.

If the amount of the lubricating coating on the surface-treated steel strip of the present invention is too large, the amount of residue generated during forging will increase, and there will be a tendency to contaminate around the tool and processing oil. It tends to cause seizure. From this point of view, the coating amount is preferably 1 to 15 g / m ² .

The present invention will be described more specifically with its effects by giving examples of the present invention together with comparative examples. In addition, this invention is not restrict | limited by these Examples.
(1) Preparation of aqueous treatment liquid Examples 1 to 8 and Comparative Examples 1 to 6 used for forming a lubricating film on the surface of a steel strip using the components shown below in combinations and proportions shown in Table 1. An aqueous processing solution was prepared. The solid content concentration of these aqueous treatment liquids was 10% by mass.

<Alkali metal silicate (A) or alkali metal salt to be compared with it>
a-1 Sodium silicate (SiO ₂ / M ₂ O molar ratio = 2)
a-2 Sodium silicate (SiO ₂ / M ₂ O molar ratio = 4)
a-3 Potassium silicate (SiO ₂ / M ₂ O molar ratio = 5)
a-4 Sodium silicate (SiO ₂ / M ₂ O molar ratio = 1)
a-5 lithium silicate _{(SiO 2} / _M 2 O molar ratio = 8)
a-6 potassium tetraborate * a-1 to a-3 are alkali metal silicates within the scope of the present invention, and a-4 to a-6 are alkali metal silicates and silicic acids outside the scope of the present invention. An alkali metal salt of an inorganic acid other than an acid.

<Synthetic hectorite (B)>
A commercially available synthetic hectorite (Na ^+0.7 [Si ₈ (Mg _5.5 Li _0.3 ) O ₂₀ (OH) ₄ ] ^−0.7 ) was used.
<Alkali metal salt (C) of saturated or unsaturated fatty acid or fatty acid salt to be compared with it>
c-1 potassium laurate c-2 sodium palmitate c-3 sodium stearate c-4 lithium isostearate c-5 potassium oleate c-6 calcium stearate * c-1 to c-5 are within the scope of the present invention C-6 is a fatty acid salt outside the scope of the present invention.

<Polymer wax (D) or wax to be compared with it>
d-1 Polyethylene wax d-2 Polytetrafluoroethylene wax d-3 Microcrystalline wax * d-1 and d-2 are high molecular waxes, and d-3 is a low molecular wax.

(2) Pretreatment and film treatment (2-1) Film treatment for uniform adhesion, rust prevention, oil resistance test Examples 1 to 8 and Comparative Examples 1 to 9 were treated by the following treatment procedure.
(A) Test piece for evaluation: Cold rolled steel sheet (SPCC-SB) 150 mm × 70 mm × 0.8 mmt (t is thickness)
(B) Degreasing: Degreasing agent (registered trademark Fine Cleaner D5410, manufactured by Nihon Parkerizing Co., Ltd.) diluted with water to a concentration of 45 g / L, temperature 60 ° C., immersion 5 minutes (c) Washing water: tap water, room temperature, spray Treatment 30 seconds (d) Lubricant film treatment: Each aqueous treatment solution prepared above, 60 ° C., immersion 10 seconds (e) Drying: Hot air drying so that the maximum temperature reached 100 ° C. (f) Dry film mass: 5g / m ²

(2-2) Film processing for plastic workability test Examples 1 to 8 and Comparative Examples 1 to 9 were processed according to the following processing procedure.
(A) Test piece for evaluation: S45C spheroidized annealing material 25 mmφ × 30 mm
(B) Degreasing: Degreasing agent (registered trademark Fine Cleaner D5410, manufactured by Nihon Parkerizing Co., Ltd.), concentration 45 g / L, temperature 60 ° C., immersion 5 minutes (c) water washing: tap water, room temperature, immersion 30 seconds (d) lubrication Film treatment: Each aqueous treatment liquid prepared above, 60 ° C., immersion 30 seconds (e) Drying: 10 minutes by hot air drying at 100 ° C. (f) Dry film mass: 10 g / m ²

(3) Evaluation test (3-1) Uniform adhesion After forming the lubricating film under the following processing conditions, the amount of film adhesion at each part when the test piece was cut into two equal parts was measured. The uniform adhesion property was evaluated by calculating the adhesion amount gradient rate (%) from the adhesion amount of each and the average adhesion amount of both portions by the following formula.
Adhesion amount gradient rate = (each partial adhesion amount−average adhesion amount) / average adhesion amount × 100
Processing conditions:
Subsequent to the above-described lubricating film treatment process (application of aqueous treatment liquid), a liquid draining holding process for 10 seconds was introduced at an angle of 45 degrees, followed by a drying process.
Measurement of adhesion amount:
The difference between the mass of the cut piece when the lubricant film was adhered and the mass of the cut piece after the lubricant film was peeled off was used as the adhesion amount, and the film was peeled by ultrasonic cleaning for 10 minutes after immersion in an alkaline degreasing solution.
Evaluation criteria:
○ Gradient rate is less than ± 5% △ 〃 is ± 5% or more and less than ± 15% × 〃 is ± 15% or more

(3-2) Rust prevention property Each coating plate for a rust prevention test prepared in the above-described lubricating coating treatment step was exposed indoors for 6 months, and the rust generation area was visually evaluated. The test plate was left horizontally with respect to the ground with the upper surface as the evaluation surface, and the rust generation area ratio (%) was calculated by the following equation.
Rust generation area ratio = rust generation area / total area of test plate evaluation surface × 100
Evaluation criteria:
○ Rust generation area ratio is less than 5% △ Rust generation area ratio is 5% or more and less than 15% × Rust generation area ratio is 15% or more

(3-3) Oil resistance A frictional wear test is performed by comparing each film-treated plate for oil resistance test prepared in the above-described lubricating film treatment step with a treated plate immersed in rust-proof oil for 2 days. The oil resistance was evaluated from the difference in seizure sliding distance (decrease in lubricity). A ball-on-disk friction and wear tester was used as a tester, and the lubricity reduction rate (%) was calculated by the following equation from the obtained results.
Rate of decrease in lubricity = (seizure sliding distance before immersion in rust prevention oil-seizure sliding distance after immersion in rust prevention oil) / seizure sliding distance before immersion in rust prevention oil x 100
Anti-rust oil:
NOX-RUST550S (manufactured by Parker Kosan Co., Ltd.)
Test conditions:
SUJ2 steel ball of 6 mmφ is used as the indenter. Vertical load = 10 N, turning radius = 10 mm, rotating speed = 50 rpm, temperature = normal temperature evaluation criteria:
○ Lubricity decrease rate is less than 20% △ Lubricity decrease rate is 20% or more and less than 40% × Lubricity decrease rate is 40% or more

(3-4) Plastic workability Plastic workability is obtained by performing spike test processing according to the invention of Japanese Patent No. 3227721 using the plastic workability evaluation test piece prepared in the lubricating film treatment step described above, and after processing. The film following degree to the protrusion part of the test piece and the presence or absence of the seized part were visually evaluated. Those having good followability have sufficient seizure resistance against the surface area expansion during cold plastic working, and seizure is likely to occur if the film does not follow.
Evaluation criteria:
○ The film is following up to the protrusion and there is no seizure. △ The film does not follow up to the protrusion, but there is no seizure. × The film does not follow up to the protrusion and there is a seizure.

The test results are shown in Table 2. As is apparent from Table 2, the lubricant film formed on the surface of the surface-treated steel strip of Examples 1 to 8 of the present invention has a uniform adhesion necessary to ensure the performance without the surface as a surface-treated steel strip. In addition to being excellent in rust prevention and oil resistance to maintain industrially stable lubricating film performance without causing film deterioration in practical and practical environments, it has sufficiently satisfactory plastic processing performance. It was. On the other hand, the content of the alkali metal salt of the saturated or unsaturated fatty acid is too small, or the lubricant film of Comparative Examples 1 and 2 not containing, the polymer wax in an amount exceeding the allowable range of the present invention, or the polymer Therefore, the lubricating film of Comparative Examples 3 and 4 containing a wax that easily swells in oil, the lubricating film of Comparative Example 6 containing a calcium salt of a saturated fatty acid instead of an alkali metal salt of a saturated or unsaturated fatty acid, The oil resistance was remarkably inferior, and the lubricating film of Comparative Example 5 containing no synthetic hectorite was extremely inferior in uniform adhesion. In addition, the lubricating films of Comparative Examples 7 and 8 in which the SiO ₂ / M ₂ O molar ratio of the alkali metal silicate that is the film base is out of the scope of the present invention are extremely inferior in plastic workability. The lubricating film of Comparative Example 9 whose base was not an alkali metal silicate salt was extremely inferior in rust prevention.

Claims (3)

Silica alkali metal salt (A), synthetic hectorite (B), and alkali metal salt of saturated or unsaturated fatty acid (C) having a molar ratio of SiO ₂ / M ₂ O (M represents an alkali metal) of 2 to 5 Or a film containing no wax, or the above-described alkali metal silicate (A), synthetic hectorite (B) and alkali metal salt (C), and polymer wax (D) as an auxiliary lubricating component A surface-treated steel strip in which a coating is formed on the surface of the steel strip, and the solid content of (A), (B) and (C) is 45 to 94, respectively, based on the total solid mass of the coating The surface-treated steel strip, having a mass content of 1 to 10 mass% and 5 to 20 mass%, and the solid content of (D) when contained is 1 to 15 mass%. The surface-treated steel strip according to claim 1, wherein the polymer wax (D) is at least one selected from polyethylene wax, polypropylene wax and polytetrafluoroethylene wax. Surface treated steel strip according to claim 1 or 2 wherein the amount of deposition of said coating is 1 to 15 g / ^{m 2.}