JP2006522683A5 - - Google Patents

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Publication number
JP2006522683A5
JP2006522683A5 JP2006509922A JP2006509922A JP2006522683A5 JP 2006522683 A5 JP2006522683 A5 JP 2006522683A5 JP 2006509922 A JP2006509922 A JP 2006509922A JP 2006509922 A JP2006509922 A JP 2006509922A JP 2006522683 A5 JP2006522683 A5 JP 2006522683A5
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Japan
Prior art keywords
ion exchange
exchange medium
ionic species
medium
producing
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Pending
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JP2006509922A
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Japanese (ja)
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JP2006522683A (en
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Priority claimed from US10/411,900 external-priority patent/US7045057B2/en
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Publication of JP2006522683A publication Critical patent/JP2006522683A/en
Publication of JP2006522683A5 publication Critical patent/JP2006522683A5/ja
Pending legal-status Critical Current

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Claims (15)

媒体流又は模擬媒体流を創り出す移動床又は模擬移動床装置内で、実質的に均質なイオン交換媒体を連続的に又は実質的に連続的に作製する方法であって、
(a)前記床を、第1のイオン種を含むイオン交換媒体で充填する工程、
(b)第2のイオン種、又は前記第1のイオン種及び第2のイオン種を含む溶液を、前記媒体を介して、前記媒体流に対して少なくとも部分的に向流で導入することにより、平衡化の際に前記イオン種を所望の水準まで前記媒体に装填する工程、及び
(c)洗浄液を前記媒体流に導入する工程
を有することを特徴とする方法。
In medium flow or transfer to exit create a simulated medium flow fluidized bed or in a simulated moving bed apparatus, a substantially homogeneous ion exchange medium continuously or substantially continuously the method of making,
(A) filling the bed with an ion exchange medium containing a first ionic species;
(B) a second ionic species, or a solution containing the first ionic species and the second ionic species, through the medium, by introducing at least partly counter-current to the medium flow , wherein further comprising the step of introducing step is loaded into the medium the ionic species to a desired level upon equilibration, and (c) washing liquid to the medium flow.
前記移動床装置が複数カラム接触装置である請求項1記載のイオン交換媒体の作製方法。 The method for producing an ion exchange medium according to claim 1 , wherein the moving bed apparatus is a multi-column contact apparatus. 前記イオン交換媒体が、カチオン又はアニオンを交換することのできる部位を含む無機固体である請求項1記載のイオン交換媒体の作製方法。 The method for producing an ion exchange medium according to claim 1 , wherein the ion exchange medium is an inorganic solid including a site capable of exchanging a cation or an anion. 前記無機固体が、ゼオライト又はアルミナ変性シリカである請求項記載のイオン交換媒体の作製方法。 Wherein the inorganic solid is a zeolite or alumina-modified silica, a manufacturing method of the ion exchange medium of claim 3, wherein. 前記第2のイオン種を、前記媒体の重量の少なくとも0.1重量%の濃度水準まで前記媒体に装填する請求項1記載のイオン交換媒体の作製方法。 The method of making an ion exchange medium according to claim 1 , wherein the medium is loaded with the second ionic species to a concentration level of at least 0.1% by weight of the medium. 前記第2のイオン種を平衡容量まで装填する請求項1記載のイオン交換媒体の作製方法。 The method for producing an ion exchange medium according to claim 1 , wherein the second ionic species is charged to an equilibrium capacity. 前記第1と第2のイオン種が、カチオン又はアニオン性の種を含む請求項1記載のイオン交換媒体の作製方法。 The first and second ionic species, including cationic or anionic species, a method for manufacturing the ion exchange medium of claim 1, wherein. 第1のイオン種を含む前記イオン交換媒体が0.02mm〜2mmの大きさである請求項1記載のイオン交換媒体の作製方法。 The method for producing an ion exchange medium according to claim 1 , wherein the ion exchange medium containing the first ion species has a size of 0.02 mm to 2 mm. 前記接触装置、流体導入マルチポート・ロータリー・バルブと共に使用される請求項2記載のイオン交換媒体の作製方法。 The method for producing an ion exchange medium according to claim 2 , wherein the contact device is used together with a fluid introduction multi-port rotary valve. 前記洗浄液低イオン含有量を有する溶媒を含み、前記溶液と相溶性である請求項1記載のイオン交換媒体の作製方法。 The cleaning solution includes a solvent which have a low ion content, the a solution compatible, a method for manufacturing the ion exchange medium of claim 1, wherein. さらに、前記洗浄液第二処理溶液で置き換えられる溶媒変換工程を含む工程(d)を有する請求項1記載のイオン交換媒体の作製方法。 Furthermore, the manufacturing method of the ion exchange medium of Claim 1 which has a process (d) including the solvent conversion process by which the said washing | cleaning liquid is replaced with a 2nd process solution. 前記工程順次に又は同時に行うことができる請求項1記載のイオン交換媒体の作製方法。 Manufacturing method of the process can be carried out sequentially or simultaneously, according to claim 1, wherein the ion exchange medium. さらに、前記洗浄液を流出液として抽出し、前記流出液を前記媒体流中に導入する工程(d)を有する請求項1記載のイオン交換媒体の作製方法。   The method for producing an ion exchange medium according to claim 1, further comprising a step (d) of extracting the cleaning liquid as an effluent and introducing the effluent into the medium stream. 媒体流又は模擬媒体流を創り出す移動床又は模擬移動床装置内で実質的に均質なイオン交換媒体を連続的又は実質的に連続的に作製する方法であって、  A method of continuously or substantially continuously producing a substantially homogeneous ion exchange medium in a moving bed or simulated moving bed apparatus that creates a media stream or simulated media stream comprising:
(a) 前記床を、第1のイオン種を含むイオン交換媒体で充填する工程(a) filling the bed with an ion exchange medium containing a first ionic species
(b) 第2のイオン種、又は前記第1のイオン種及び第2のイオン種を含む溶液を、前記媒体を介して、前記媒体流に対して少なくとも部分的に向流で導入することにより、平衡化の際に前記イオン種を所望の水準まで前記媒体に装填する工程、及び(b) introducing a second ionic species or a solution containing the first ionic species and the second ionic species at least partially countercurrently with respect to the medium stream through the medium; Loading the medium with the ionic species to a desired level during equilibration; and
(c) 洗浄液を、イオン又はカチオンを交換することが出来る部位を含むように機能化されたポリマー・ビーズを含む媒体流に導入する工程(c) introducing a cleaning solution into a media stream comprising polymer beads functionalized to contain sites capable of exchanging ions or cations.
を有することを特徴とする方法。A method characterized by comprising:
前記ポリマー・ビーズが、カチオン又はアニオン形態におけるスルホン化スチレン−ジビニルベンゼン樹脂又はアクリル樹脂である請求項14記載のイオン交換媒体の作製方法。
The method for producing an ion exchange medium according to claim 14 , wherein the polymer beads are a sulfonated styrene-divinylbenzene resin or an acrylic resin in a cation or anion form.
JP2006509922A 2003-04-11 2004-04-12 Production of homogeneously charged ion exchangers Pending JP2006522683A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/411,900 US7045057B2 (en) 2003-04-11 2003-04-11 Preparation of homogeneously loaded ion exchangers
PCT/US2004/011189 WO2004091790A1 (en) 2003-04-11 2004-04-12 Preparation of homogeneously loaded ion exchangers

Publications (2)

Publication Number Publication Date
JP2006522683A JP2006522683A (en) 2006-10-05
JP2006522683A5 true JP2006522683A5 (en) 2010-01-28

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JP2006509922A Pending JP2006522683A (en) 2003-04-11 2004-04-12 Production of homogeneously charged ion exchangers

Country Status (10)

Country Link
US (1) US7045057B2 (en)
EP (1) EP1610898B1 (en)
JP (1) JP2006522683A (en)
KR (1) KR20060015501A (en)
CN (1) CN1771089A (en)
AT (1) ATE395135T1 (en)
AU (1) AU2004231076B9 (en)
DE (1) DE602004013751D1 (en)
IL (1) IL171015A (en)
WO (1) WO2004091790A1 (en)

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AU2011240779B2 (en) * 2010-04-12 2014-12-04 Cyanco Holding Corporation Process for high concentration cation exchange metathesis
EP3131674A1 (en) * 2014-04-15 2017-02-22 Trailblazer Technologies (Pty) Ltd Ion exchange process

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