JP2006297354A - Coating tool for uniformly coating coating liquid on coating surface of automobile body - Google Patents

Coating tool for uniformly coating coating liquid on coating surface of automobile body Download PDF

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JP2006297354A
JP2006297354A JP2005127204A JP2005127204A JP2006297354A JP 2006297354 A JP2006297354 A JP 2006297354A JP 2005127204 A JP2005127204 A JP 2005127204A JP 2005127204 A JP2005127204 A JP 2005127204A JP 2006297354 A JP2006297354 A JP 2006297354A
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coating liquid
cloth
coating
applicator
film
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JP4575227B2 (en
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Yasuo Kitani
安生 木谷
Hironobu Kinoshita
浩伸 木下
Kuniyasu Toda
州泰 戸田
Yohei Nishiyama
洋平 西山
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KOBE GOSEI KK
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KOBE GOSEI KK
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a coating tool uniformly coating a film-forming substance for protecting the coated surface of an automobile body, and a coating liquid dissolving or dispersing the substance, having a volatile solvent as a principal component, to form a thin film. <P>SOLUTION: This coating tool 17 uniformly coating the coating liquid on the coated surface of an automobile body, is formed by inserting a sponge core body 1 having a shape of an acute angle of a tip 15 side into a bag body 16 consisting of cloth impregnated with a coating liquid having a film forming substance and a volatile solvent as principal components, the solvent being capable of dissolving or dispersing the film forming substance. The bag body 16 is formed of cloth with a sliding angle of 35° or less from a horizontal face when a load of 490 Pa is applied to the cloth impregnated with the coating liquid, laminated to a thickness of 1 mm, and capable of impregnating 0.01-0.4 cc of coating liquid per 1 cm<SP>2</SP>. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

この発明は、自動車ボディーの塗装面、特に新車のボディーの塗装面に皮膜形成性物質とそれを溶解または分散しうる揮発性溶媒を主成分とするコーティング液の薄膜を均一に塗布して乾燥硬化してボディーの塗装面を保護するために使用する皮膜形成性物質とそれを溶解または分散しうる揮発性溶媒を主成分とするコーティング液の塗布具に関する。   The present invention uniformly applies a thin film of a coating liquid mainly composed of a film-forming substance and a volatile solvent capable of dissolving or dispersing it on a painted surface of an automobile body, in particular, a painted surface of a new vehicle body, followed by drying and curing. The present invention also relates to an applicator for a coating liquid mainly composed of a film-forming substance used for protecting a painted surface of a body and a volatile solvent capable of dissolving or dispersing the substance.

一般に、自動車のボディーの外表面の塗装面や、樹脂部分や、ガラス部分や、あるいは車内の塗装面、特に乗用車などの新車のボディーの塗装面は、自動車の出荷に先立ち皮膜形成性物質とそれを溶解または分散しうる揮発性溶媒を主成分とするコーティング液を塗布、乾燥して塗装面上に薄膜を形成させて塗装面を保護するとともに美しく仕上げることにより付加価値を一層向上させることがしばしば行われている。また、このような皮膜形成性物質とそれを溶解または分散しうる揮発性溶媒を主成分とするコーティング液を塗布していても耐久期間が経過して保護機能が失われた場合に、再びこれらのコーティング液を塗布して仕上げ直すことも行われている。そこで皮膜形成性物質とそれを溶解または分散しうる揮発性溶媒を主成分とするコーティング液をクロスに含浸させ、この含浸させたクロスを手のひらなどで保持して塗装面を拭くことによりコーティング液の薄膜を形成する。この場合、コーティング液がクロスから枯渇してくると、再びコーティング液をクロスに浸潤させたり、あるいは塗装面に垂らして、再びクロスで拭いてコーティング液の塗膜を塗装面上に形成していく。   In general, the painted surface of the outer surface of an automobile body, the resin portion, the glass portion, or the painted surface of the interior of a vehicle, particularly the painted surface of a new vehicle body such as a passenger car, is a film-forming substance and it prior to vehicle shipment. Applying a coating solution mainly composed of a volatile solvent that can dissolve or disperse the material, and drying it to form a thin film on the painted surface to protect the painted surface and often improve the added value further. Has been done. In addition, even when such a film-forming substance and a coating liquid mainly composed of a volatile solvent capable of dissolving or dispersing the same are applied, the protective function is lost again after the endurance period has passed. It is also practiced to apply the coating liquid and finish it again. Therefore, the coating liquid mainly composed of a film-forming substance and a volatile solvent capable of dissolving or dispersing it is impregnated in the cloth, and the coated liquid is wiped by holding the impregnated cloth with a palm or the like and wiping the coated surface. A thin film is formed. In this case, when the coating liquid is depleted from the cloth, the coating liquid is infiltrated into the cloth again, or it is dropped on the painted surface and wiped with the cloth again to form a coating film of the coating liquid on the painted surface. .

ところで、実際の自動車においては曲面や凹凸の部分が多く存在する。そのためにコーティング液をこれらの塗装面に均一に十分に拡げることが困難であり、仕上げの膜厚にムラが生じ易く、また、このために修正などの余分な作業を必要とした。したがって、このような事態が生じないようにするために、コーティング液を塗装面に均一に薄く十分に拡げる必要がある。このためには皮膜形成性物質とそれを溶解または分散しうる揮発性溶媒を主成分とするコーティング液が湿潤状態にある間に、可能な限り短時間で塗装面に拡げなければならなかった。さらにそのための適切な塗布具を必要とした。しかし、均一な薄い膜厚からなる仕上げ面を得ることは、実際には容易なことではでなかった。このために熟練した手作業を必要とした。   By the way, in an actual automobile, there are many curved surfaces and uneven portions. For this reason, it is difficult to spread the coating solution uniformly and sufficiently on these painted surfaces, and the film thickness of the finished film tends to be uneven, and this requires extra work such as correction. Therefore, in order to prevent such a situation from occurring, it is necessary to spread the coating liquid uniformly and sufficiently on the painted surface. For this purpose, the coating liquid containing a film-forming substance and a volatile solvent capable of dissolving or dispersing it as a main component must be spread on the painted surface in as short a time as possible. Furthermore, an appropriate applicator for that purpose was required. However, it is not easy in practice to obtain a finished surface having a uniform thin film thickness. This required skilled manual work.

一方、コーティング液を均一な膜厚の薄膜に塗布することができる塗布具として、被塗布面に線接触してコーティング液を塗布する塗布具および塗布方法が開発されている(例えば、特許文献1参照。)。ところで、この塗布具および塗布方法は上記のように線接触が絶対条件であり、このためには格別の柄つきの用具を必要とし、このために細かい凹凸の部分にコーティング液を塗布しにくく、広い面積の平らな部分にしか塗膜を形成することはできない問題があった。さらに、この塗布具を使用する塗布方法は、平滑な透明ガラスに対する干渉膜を生成しない塗布方法に関するものであった。   On the other hand, as an applicator that can apply the coating liquid to a thin film having a uniform film thickness, an applicator and an application method for applying the coating liquid in line contact with the surface to be applied have been developed (for example, Patent Document 1). reference.). By the way, in this applicator and application method, line contact is an absolute condition as described above, and for this purpose, a tool with a special handle is required, and for this reason, it is difficult to apply the coating liquid to a fine uneven portion, and it is wide. There was a problem that a coating film could be formed only on a flat area. Furthermore, the coating method using this applicator relates to a coating method that does not generate an interference film on smooth transparent glass.

一方、ローラー体に超極細繊維で編んだ繊維からなるブラシ面構成布を貼着した塗装用ブラシが提案されている(例えば、特許文献2参照)。また、超極細繊維の管状布体をローラー体の表面に被覆した塗装ブラシが提案されている(例えば、特許文献3参照)。しかし、これらのものは、ローラー回転のブラッシ形状をしており、比較的高い粘度のコーティング液を塗布するもので塗膜の厚さが1μm以上の厚いものしか適用できない問題があった。   On the other hand, a brush for painting has been proposed in which a brush surface-constituting fabric made of fibers knitted with ultrafine fibers is attached to a roller body (see, for example, Patent Document 2). Further, a painting brush in which a surface of a roller body is coated with a tubular cloth body of ultrafine fibers has been proposed (for example, see Patent Document 3). However, these have a brush-rotating brush shape, and have a problem that only a thick coating film having a thickness of 1 μm or more can be applied by applying a coating liquid having a relatively high viscosity.

特開2003−164793号公報JP 2003-164793 A 実開平5−74679号公報Japanese Utility Model Publication No. 5-74679 特開平11−19573号公報JP-A-11-19573

本発明が解決しようとする課題は、自動車のボディーの塗装面を保護するために、皮膜形成性物質とそれを溶解または分散しうる揮発性溶媒を主成分とするコーティング液を均一に塗布して薄膜を形成するための塗布具、平面状の塗装面のみならず細かい曲面にも適用可能な塗布具を提供することである。   The problem to be solved by the present invention is to uniformly apply a coating liquid composed mainly of a film-forming substance and a volatile solvent capable of dissolving or dispersing it in order to protect the painted surface of the body of an automobile. An object of the present invention is to provide an applicator for forming a thin film and an applicator applicable not only to a flat painted surface but also to a fine curved surface.

上記の課題を解決する本発明の手段は、請求項1の発明では、自動車ボディーの塗装面にコーティング液を薄くかつ均一に塗布するための塗布具であって、この塗布具は皮膜形成性物質とそれを溶解または分散しうる揮発性溶媒を主成分とするコーティング液を含浸し得るクロスからなり、手で把持しうる大きさの袋体に、少なくとも一方の先端を鋭角とした形状のスポンジからなる芯体を挿着して有する自動車ボディーの塗装面にコーティング液を薄くかつ均一に塗布するための塗布具である。   The means of the present invention for solving the above-mentioned problems is an applicator for thinly and uniformly applying a coating liquid to a painted surface of an automobile body according to the invention of claim 1, wherein the applicator is a film-forming substance. And a cloth that can be impregnated with a coating liquid mainly composed of a volatile solvent that can dissolve or disperse it, and from a sponge having a shape with at least one tip at a sharp angle to a bag that can be grasped by hand. An applicator for applying a coating liquid thinly and uniformly onto a painted surface of an automobile body having a core body inserted therein.

請求項2の発明では、上記の請求項1の自動車ボディーの塗装面にコーティング液を均一に塗布するための塗布具であって、皮膜形成性物質とそれを溶解または分散しうる揮発性溶媒を主成分とするコーティング液を含浸し得るクロスの基材がポリエステルからなる袋体に少なくとも一方の先端を鋭角とした形状のスポンジからなる芯体を挿着して有する自動車ボディーの塗装面にコーティング液を薄くかつ均一に塗布するための塗布具である。   According to a second aspect of the present invention, there is provided an applicator for uniformly applying a coating liquid onto the painted surface of the automobile body according to the first aspect, wherein a film-forming substance and a volatile solvent capable of dissolving or dispersing the film-forming substance are provided. The coating liquid is applied to the painted surface of an automobile body having a cloth base material which is impregnated with a main component and a core body made of a sponge having a sharp shape with at least one tip at a bag body made of polyester. Is an applicator for applying a thin and uniform coating.

請求項3の発明では、上記の請求項1または2の手段における自動車ボディーの塗装面にコーティング液を均一に塗布するための塗布具であって、皮膜形成性物質とそれを溶解または分散しうる揮発性溶媒を主成分とするコーティング液を含浸し得るクロスからなる袋体は、コーティング液を含浸したクロスに490Pa(=5gf/cm2)の荷重を加えた場合の自動車塗装と同等面に対する滑走角度が水平面から35°以下であり、かつ、厚さ1mmに重層したもので面積1cm2当たりに0.01〜0.4ccのコーティング液を含浸し得るクロスから形成されている袋体を有する塗布具である。 According to a third aspect of the present invention, there is provided an applicator for uniformly applying a coating liquid onto a painted surface of an automobile body according to the means of the first or second aspect, wherein the film-forming substance and the coating liquid can be dissolved or dispersed. A bag made of a cloth that can be impregnated with a coating liquid containing a volatile solvent as a main component slides on the same surface as an automobile when a load of 490 Pa (= 5 gf / cm 2 ) is applied to the cloth impregnated with the coating liquid. Application having a bag formed of a cloth having an angle of 35 ° or less from a horizontal plane and layered with a thickness of 1 mm and capable of impregnating 0.01 to 0.4 cc of coating liquid per 1 cm 2 area. It is a tool.

請求項4の発明では、上記の請求項1〜3のいずれか1項の手段におけるクロスからなる袋体は、2〜4枚を重ねて複数枚としたクロスからなり、袋体の収容部分の厚さが10〜30mmで、幅が40〜100mm、長さが50〜300mmである大きさの袋体からなり、この袋体の大きさは長さ方向の先端が20〜45°の鋭角に形成されている鋭角を持つ形状のスポンジの板体からなる芯体を挿着し得る大きさであり、これらの袋体と挿着したスポンジからなる自動車ボディーの塗装面にコーティング液を均一に塗布するための塗布具である。   In the invention of claim 4, the bag body made of cloth in the means of any one of claims 1 to 3 is made of a cloth made up of a plurality of 2 to 4 sheets, It consists of a bag body with a thickness of 10 to 30 mm, a width of 40 to 100 mm, and a length of 50 to 300 mm. The size of this bag body is an acute angle with a tip in the length direction of 20 to 45 °. The core that consists of sponge plates with a sharp angle formed can be inserted, and the coating solution is evenly applied to the painted surface of the automobile body consisting of these bags and sponges. It is an applicator for doing.

請求項5の発明では、上記の請求項1〜4のいずれか1項の手段における自動車ボディーの塗装面にコーティング液を均一に塗布するための塗布具において、少なくとも一方を鋭角に持つ形状のスポンジからなる芯体はスポンジが連続気泡または独立気泡から形成されていることを特徴とする塗布具である。   According to a fifth aspect of the present invention, in the applicator for uniformly applying the coating liquid to the painted surface of the automobile body according to any one of the first to fourth aspects, a sponge having a shape having at least one acute angle. The core body is an applicator characterized in that a sponge is formed from open cells or closed cells.

クロスからなる袋体の上記の条件を満たすクロスは、コーティング液の含浸性や吐出性、滑り性、耐久性などの点から基材としてポリエステル(以下「PET」という。)を主たる基材とするものが好ましく、なかでもPET100%製のものが好ましい。市販のクロスとしては、繊維径11μのPET100%の長繊維からなるニット製の布(商品名:MEワイパー)、繊維径15μのPET100%の繊維からなるニット製の布(商品名:生機品番80370)、繊維径60μmのPET繊維からなるニット製の布(商品名:クリーンニット04026w)、ポリエステル100%の不織布(商品名:GC120)からなるクロス類が例示できる。   The cloth satisfying the above conditions of the bag body made of cloth has polyester (hereinafter referred to as “PET”) as a main base material from the viewpoints of impregnation property, ejection property, slipperiness, durability and the like of the coating liquid. Of these, those made of 100% PET are preferred. As a commercially available cloth, a knit cloth (trade name: ME wiper) made of 100% PET 100% long fiber having a fiber diameter of 11 μm, and a knit cloth made of 100% PET fiber having a fiber diameter of 15 μ (trade name: raw machine product number 80370). ), Knitted cloth (trade name: Clean Knit 04026w) made of PET fibers having a fiber diameter of 60 μm, and cloths made of 100% polyester non-woven fabric (trade name: GC120).

本発明は、請求項1の発明の塗布具は、少なくとも一方を鋭角に持つ形状のスポンジからなる芯体を挿着して有するので、先端側は曲がりやすく、したがって先端側を適度の角度に曲げて塗布することで塗装面にかける力の配分が容易であり、したがって、曲線部においてもスムーズに作業することができる。さらに、この塗布後に袋体から挿着している芯体を抜き取り、袋体と芯体をそれぞれ個別に洗浄して、再び利用をすることができる。さらに請求項2の発明の塗布具の素材であるクロスの基材がポリエステルからからなるので、コーティング液の含浸性や吐出性、滑り性、耐久性などの点で極めてすぐれており、請求項3の発明の塗布具は、その袋体がコーティング液を含浸させた場合に、滑走開始角度が35°以内の角度の素材からなるものとするので、非常に滑りやすく自動車ボディーの広範囲の面積を一度含浸させた塗布具で均一に薄膜で塗布することができる。さらに請求項4の発明の塗布具は、手で把持しうる大きさであり、平らな塗装面のみならずドアノブの内側などの狭い曲面などにも手で直接把持して塗布するので効率よく作業をすることができる。   In the present invention, since the applicator of the invention of claim 1 has a core body made of a sponge having an acute angle at least one of which is inserted, the distal end side is easily bent, and therefore the distal end side is bent at an appropriate angle. When applied, it is easy to distribute the force applied to the painted surface, and therefore it is possible to work smoothly even in a curved portion. Furthermore, the core body inserted from the bag body after this application can be removed, and the bag body and the core body can be separately washed and reused. Furthermore, since the cloth base material of the applicator of the invention of claim 2 is made of polyester, it is extremely excellent in terms of impregnation property, discharge property, slipping property, durability, etc. of the coating solution. When the bag body is impregnated with the coating liquid, the applicator of the invention is made of a material having a sliding start angle of 35 ° or less. A thin film can be applied uniformly with an impregnated applicator. Furthermore, the applicator of the invention of claim 4 is of a size that can be gripped by hand, and can be applied efficiently by directly gripping and coating not only a flat painted surface but also a narrow curved surface such as the inside of a door knob. Can do.

さらに請求項5の発明の塗布具は、連続気泡又は独立気泡からなるスポンジの芯体を有し、連続気泡からなるスポンジの芯体を有する場合には、スポンジの芯体にコーティング液が含浸されることとなり、塗布の途中でコーティング液が含浸している芯体から滲みだしてくるので、コーティング液が枯渇するような事態は減少されることとなる。連続気泡からなるスポンジの芯体は手に馴染みやすい利点を有する。さらにスポンジの芯体が独立気泡からなっている場合には、塗布に必要な量以上のコーティング液がポリウレタンの芯体に吸い込まれることが実質的にないので、コーティング液はクロスに含浸させているのみであり、仮に塗布する手の力を掛けすぎたとしても余分のコーティング液が芯体から出てくることが少ないので、袋体から滲みだすコーティング液は比較的に均一であり、薄く延ばして均一に塗布しやすく、さらに使用後の袋体と芯体の洗浄も容易となる。以上のように本発明は従来にない優れた効果を奏するものである。   Furthermore, the applicator of the invention of claim 5 has a sponge core made of open cells or closed cells, and when having a sponge core made of open cells, the sponge core is impregnated with a coating liquid. As a result, the coating liquid oozes out from the core impregnated with the coating liquid in the middle of application, so that the situation where the coating liquid is exhausted is reduced. The sponge core made of open cells has the advantage of being familiar with the hand. Further, when the sponge core is composed of closed cells, the coating liquid is not substantially sucked into the polyurethane core more than necessary for the coating, so the cloth is impregnated in the cloth. Even if too much hand force is applied, the excess coating liquid is unlikely to come out of the core, so the coating liquid that oozes out from the bag is relatively uniform and thinly extended. It is easy to apply uniformly, and the bag and core after use can be easily cleaned. As described above, the present invention has an excellent effect that has not been achieved in the past.

本発明を実施するための最良の形態について説明する。本発明の塗布具17に使用する芯体1は、弾性を有する材料から形成した。すなわち、このような芯体1の弾性材料として、ポリウレタン・ポリエチレン・ゴム製のスポンジが使用可能であるが、耐久性や作業性の面で特に好ましいポリウレタンスポンジから形成した。この芯体1は60mm厚のポリウレタンスポンジを例えば190℃の温度で熱プレスして20mm厚に圧縮して形成した。例えば、この芯体1を図1により示すと、芯体1は台形からなり、その形状は長さ方向の後端が台形の下底2および上底3に垂直な面の後端4に形成されており、下底2の長さは120mm、上底3の長さは90mm、幅5は80mm、後端4の高さは厚さの20mmからなり、長さ方向の先端6は鋭角、例えば30°の鋭角に形成されている。この芯体の弾性材料は、請求項4の発明では、連続気泡からなるポリウレタンスポンジから形成し、一方では、上記の連続気泡に替えて吸液しにくい材料である独立気泡からなるポリウレタンスポンジから形成した。さらに、これらの芯体1は、皮膜形成性物質とそれを溶解または分散しうる揮発性溶媒を主成分とするコーティング液を含浸し得るクロスから形成した袋体16に挿着されている。皮膜形成性物質とそれを溶解または分散しうる揮発性溶媒を主成分とするコーティング液としては、特開2003−327908号公報、特許第3367953号、特許第3374368号、特許第3202930号の各特許公報に記載のコーティング液が例示されている。   The best mode for carrying out the present invention will be described. The core body 1 used for the applicator 17 of the present invention was formed from an elastic material. That is, as the elastic material of the core 1, a polyurethane / polyethylene / rubber sponge can be used, but a polyurethane sponge particularly preferable in terms of durability and workability is used. The core 1 was formed by hot pressing a 60 mm thick polyurethane sponge at a temperature of, for example, 190 ° C. and compressing it to a thickness of 20 mm. For example, when the core body 1 is shown in FIG. 1, the core body 1 has a trapezoidal shape, and the shape thereof is formed at the rear end 4 of the surface perpendicular to the trapezoidal lower and upper bases 2 and 3. The length of the lower base 2 is 120 mm, the length of the upper base 3 is 90 mm, the width 5 is 80 mm, the height of the rear end 4 is 20 mm in thickness, and the tip 6 in the length direction is an acute angle, For example, it is formed at an acute angle of 30 °. In the invention of claim 4, the elastic material of the core is formed from a polyurethane sponge composed of open cells, and on the other hand, formed from a polyurethane sponge composed of closed cells which is a material that hardly absorbs liquid instead of the open cells. did. Further, these cores 1 are inserted into a bag 16 formed of a cloth that can be impregnated with a coating liquid mainly composed of a film-forming substance and a volatile solvent that can dissolve or disperse the film-forming substance. As a coating liquid mainly composed of a film-forming substance and a volatile solvent capable of dissolving or dispersing the same, Japanese Patent Application Laid-Open No. 2003-327908, Japanese Patent No. 3367953, Japanese Patent No. 3374368, Japanese Patent No. 3302930 The coating liquid described in the publication is exemplified.

さらに、これらのクロスとして表1に示す商品名の市販の各種の布地について、特許第3367953号の特許公報に記載の剥き塗料液からなるコーティング液を用いて作業性、塗布面の外観などにより総合評価した。その総合評価した総合評価レベルを1〜6の数字で示し、この総合評価レベル1は劣るもの、6は最も優れたものとして表1に示した。なお、表1の市販の商品名には、図2でグラフとして示す際の便宜のために、a〜wの符号を付した。また、表1の総合評価は、作業時にクロスからの抜け毛の有無、塗装面の凹凸への対応性、クロスと塗布液との相性などの作業性Aと、乾燥時の白斑の発生、塗布時の塗布液の着きすぎによる黒斑の発生などの外観B、親水性能の強弱による親水斑の有無Cと、塗布液の継ぎ足し性、上下方向・左右方向の滑走性能の有無などの作業性Dについて評価して総合評価レベルで示した。なお、表1のコメントにおける「親水斑に問題」は、親水斑の生じない場合と生じる場合があり、再現性が不安定であることを示している。しかし、この場合でも、クロスがナイロンのものは耐久性の点で優れているので、親水性に問題が多少あってもそれを補って、符号a、b、eのクロスはPETに準ずるクロスとして塗布具に十分に使用できる。   Furthermore, for various kinds of commercial cloths having the trade names shown in Table 1 as these cloths, the workability, the appearance of the coated surface, etc. are comprehensively determined using the coating liquid composed of the peeling paint liquid described in the patent publication No. 3367953. evaluated. The overall evaluation level of the overall evaluation is shown by numbers 1 to 6. Table 1 shows that the overall evaluation level 1 is inferior and 6 is the most excellent. In addition, the code | symbol of aw was attached | subjected to the commercial product name of Table 1 for the convenience at the time of showing as a graph in FIG. In addition, the overall evaluation in Table 1 is based on the workability A such as the presence or absence of hair loss from the cloth at the time of work, compatibility with the unevenness of the coated surface, compatibility between the cloth and the coating liquid, the occurrence of white spots during drying, and the time of application. Appearance B such as the occurrence of black spots due to excessive application of coating liquid, presence or absence C of hydrophilic spots due to the strength of hydrophilic performance, and workability D such as the addition of coating liquid and the presence or absence of sliding performance in the vertical and horizontal directions It was evaluated and shown at the overall evaluation level. The “problem with hydrophilic spots” in the comments in Table 1 may or may not occur with hydrophilic spots, indicating that reproducibility is unstable. However, even in this case, the nylon cloth is excellent in terms of durability, so even if there is a problem with hydrophilicity, the cloth with the signs a, b and e is a cloth that conforms to PET. Can be used sufficiently for applicators.

Figure 2006297354
Figure 2006297354

表1において、総合評価レベル6となった市販のクロスを列挙すると、符号kの繊維径11μのPET100%の長繊維からなるニット製のクロス(商品名:MEワイパー)、符号nの繊維径15μのPET100%の繊維からなるニット製のクロス(商品名:生機品番80370)、符号qの繊維径60μmのPET繊維からなるニット製のクロス(商品名:クリーンニット04026w)、若しくは符号wのポリエステル繊維からなる不織布(商品名:GC120)などからなるクロスであった。   In Table 1, a list of commercially available cloths having an overall evaluation level of 6 is a knit cloth (trade name: ME wiper) made of 100% PET 100% long fibers having a fiber diameter of 11 μm, and a fiber diameter of 15 μm of a symbol n. Knitted cloth made of 100% PET fiber (trade name: raw machine product number 80370), knitted cloth made of PET fiber having a fiber diameter of q of 60 μm (trade name: clean knit 04026w), or polyester fiber of code w It was the cloth which consists of the nonwoven fabric which consists of (brand name: GC120) etc.

さらに、表1に示す商品名のクロスの、処理する塗装面に対するすべり性能を調査する滑走性能試験を実施した。この試験は、先ず、親水性ポリマーからなるコーティング液を含浸しない乾燥状態でのクロスを用意し、それぞれのクロスの上に490Paの荷重を加え、水平に配置した自動車塗装面と同等の塗装鋼板の塗装面上に載置した。次いで、この塗装鋼板の塗装面を徐々に傾斜し、荷重を加えたクロスが滑走し始める水平面からの傾斜角度を求めて滑走開始角度とした。この場合、クロスとして市販の表1に示す商品名の布地を使用した。上記試験に用いたクロスは袋体に模して合計厚みが0.5〜5.0mmになるように重ねた複数枚のクロスから形成した。次に、これらの乾燥状態時の滑走性能試験の結果を総合評価レベルとともに図2に符号で示した。   Furthermore, the sliding performance test which investigates the sliding performance with respect to the coating surface to process of the cloth of the brand name shown in Table 1 was implemented. In this test, first, a cloth in a dry state not impregnated with a coating solution composed of a hydrophilic polymer was prepared, a load of 490 Pa was applied on each cloth, and a coated steel sheet equivalent to a horizontally disposed automobile painted surface was used. Placed on the painted surface. Next, the coated surface of the coated steel sheet was gradually inclined, and the angle of inclination from the horizontal plane where the cloth to which the load was applied started to slide was determined to be the sliding start angle. In this case, the cloth of the brand name shown in Table 1 marketed as cloth was used. The cloth used in the above test was formed from a plurality of cloths that were overlapped so that the total thickness was 0.5 to 5.0 mm, imitating a bag. Next, the results of the sliding performance test in the dry state are shown by reference numerals in FIG. 2 together with the overall evaluation level.

これらの総合評価レベル6のクロスからなる袋体16に、芯体1を挿着した塗布具17は、袋体16を形成する布地の厚さ1mmで面積1cm2当たり0.01〜0.4ccのコーティング液を含浸したクロスから形成した袋体16であり、この袋体16に芯体1を鋭角の先端15側から挿入したものである。図2に見られるように、表1で総合評価レベル6の上記したクロスはその滑走開始速度は水平面から35°以下であった。 The applicator 17 in which the core body 1 is inserted into the bag body 16 made of the cloth of these comprehensive evaluation levels 6 has a thickness of 1 mm of the cloth forming the bag body 16 and 0.01 to 0.4 cc per 1 cm 2 area. The bag body 16 is formed from a cloth impregnated with the coating liquid, and the core body 1 is inserted into the bag body 16 from the acute end 15 side. As can be seen in FIG. 2, the above-mentioned cloth having the overall evaluation level 6 in Table 1 has a sliding start speed of 35 ° or less from the horizontal plane.

この袋体16は、例えば3枚のクロスを重ねたものを、幅40〜100mm、長さ50〜300mmの大きさからなる大きさに縫製により形成した。これらの大きさは、手で握ってする作業のし易さと、コーティング液の含浸量から求めたものである。この袋体16には、長さ方向の先端15を20〜45°の鋭角に形成した少なくとも一方に鋭角を持つ形状のスポンジ、例えば、上記した図1のポリウレタンスポンジからなる芯体1を挿着した。この先端15の角度が20°未満では台形の底部の長さを大きくする必要があり、この結果、塗布具17自体が大きくなり過ぎ扱いにくくなり、45°より大きいと、塗布具17の先端部を曲げて塗布する際の曲げ具合すなわち把持する手の力の入れ具合を困難とする。この袋体16の縫製方法を図2により説明すると、先ず、例えば、上記の商品名MEの繊維径11μのPET100%の長繊維からなるニット製のクロスを、図3の(a)に示すように、長さ19.5cmで幅11cmの最大幅布地8と、長さ19.5cmで幅9.5cmの中間幅布地9と、長さ19.5cmで幅8.5cmの最少幅布地10の3枚の布地に切断する。次いでこれらの3枚の布地を重ねて、(b)に示すように、中央の重ね部の端側の本縫い11と長手方向の両端部の本縫い12とを縫製した。   This bag body 16 was formed by sewing, for example, a stack of three cloths into a size having a width of 40 to 100 mm and a length of 50 to 300 mm. These sizes are obtained from the ease of the work of grasping by hand and the amount of coating liquid impregnated. The bag body 16 is inserted with a core body 1 made of a sponge having an acute angle on at least one of its longitudinal ends 15 formed at an acute angle of 20 to 45 °, for example, the polyurethane sponge shown in FIG. did. If the angle of the tip 15 is less than 20 °, it is necessary to increase the length of the bottom of the trapezoid. As a result, the applicator 17 itself becomes too large and difficult to handle. It is difficult to apply the bending force when bending and applying the force of the hand to be gripped. The sewing method of the bag body 16 will be described with reference to FIG. 2. First, for example, a knit cloth made of 100% PET 100% long fiber having a fiber diameter of 11 .mu. A maximum width fabric 8 having a length of 19.5 cm and a width of 11 cm, an intermediate width fabric 9 having a length of 19.5 cm and a width of 9.5 cm, and a minimum width fabric 10 having a length of 19.5 cm and a width of 8.5 cm. Cut into three pieces of fabric. Next, these three fabrics were overlapped, and as shown in (b), a main stitch 11 on the end side of the central overlap portion and a main stitch 12 on both end portions in the longitudinal direction were sewn.

この場合、ニット編み目の細かい部分を布地の表面とし、この目の細かい表面が完成した時に最外層になるように注意して配置して上記の本縫い11、12を縫製した。さらに、完成品で外側となる最大幅布地8の部分を内側になるように中央で山折りして(c)とした。さらに(c)の山折りのうち最も側辺部である最大幅布地8の編地の側辺の部分を本縫い13に縫製して袋体とした。この袋体の口の部分の周囲に縁取りして(d)に示すようにバイアステープ縁取り14を縫製により形成して口の端部をほつれなくした後、得られた袋体の表裏を返して最大幅布地8の表地が外側になるようにして本発明に使用する袋体16に完成した。この袋体16に図1の少なくとも一方に鋭角を持つ形状のスポンジからなる芯体1を挿入し、図4に示す本縫い13の部分を側部に有し、バイアステープ縁取り14を後端に有し、かつ、先端15を鋭角とする袋体16と、袋体16に挿着した芯体1からなる塗布具17とした。   In this case, the fine stitches of the knit stitches were used as the surface of the fabric, and the above-described main stitches 11 and 12 were sewn with careful arrangement so as to be the outermost layer when this fine surface was completed. Further, the portion of the maximum width fabric 8 on the outer side in the finished product was folded in the center so as to be on the inner side to obtain (c). Further, the side portion of the knitted fabric of the maximum width fabric 8 which is the most side portion of the mountain folds of (c) was sewn to the main stitch 13 to form a bag. The periphery of the mouth portion of the bag body is trimmed, and a bias tape border 14 is formed by sewing as shown in (d) to prevent the mouth end from fraying, and the obtained bag body is turned upside down. The bag 16 used in the present invention was completed with the outermost surface of the maximum width fabric 8 facing outward. The core body 1 made of a sponge having an acute angle shape is inserted into at least one of the bag body 16 shown in FIG. 1, the side portion of the main stitch 13 shown in FIG. 4 is provided, and the bias tape edge 14 is provided at the rear end. The applicator 17 includes a bag body 16 having an acute angle at the tip 15 and a core body 1 inserted into the bag body 16.

ところで、ポリウレタンスポンジからなる芯体1が、請求項4の手段における連続気泡のポリウレタンスポンジからなると、塗布に用いるコーティング液は、この芯体1の中に含浸されることとなる。したがって、含浸量を1回の含浸により長時間にわたる塗布作業を行うことができる。しかし、一方で、これらのポリマーが架橋しない、できるだけ短時間のうちに、広い面積を均一な薄さに延ばして塗布する必要がある。このため、連続気泡のポリウレタンスポンジからなる芯体1を使用するに当たっては含浸量が多い場合には熟練を要することとなる。さらに、芯体1が連続気泡のポリウレタンスポンジである場合には、芯体1に含浸させたコーティング液を使い切ってしまうか、あるいは使用後に素早く芯体1を洗浄して残ったコーティング液を除かなければ、残ったコーティング液が芯体1中で架橋して硬化してしまうこととなり、二度とこのスポンジの芯体1は使用できないこととなる。   By the way, when the core body 1 made of polyurethane sponge is made of open-cell polyurethane sponge in the means of claim 4, the coating liquid used for coating is impregnated in the core body 1. Therefore, it is possible to perform a coating operation for a long time by impregnating the impregnation amount once. However, on the other hand, it is necessary to extend and apply a large area to a uniform thin film in a short time as long as these polymers do not crosslink. For this reason, when using the core 1 made of open-cell polyurethane sponge, skill is required when the amount of impregnation is large. Furthermore, when the core body 1 is an open-cell polyurethane sponge, the coating liquid impregnated in the core body 1 is used up or the core body 1 is quickly washed after use to remove the remaining coating liquid. Otherwise, the remaining coating solution will be crosslinked and hardened in the core body 1, and the sponge core body 1 can no longer be used.

そこで、このようなことが生じないようにするため、コーティング液を塗布具17に含浸させるときは、予め、クロスの厚さ1mmで面積1cm2当たりコーティング液0.01〜0.4ccが含浸される量のコーティング液を量り取り、これを平底容器に移してから、塗布具17の塗布面に含浸させるか、あるいは直接袋体16の布地の塗布面に振りかけることにより芯体1の部分への含浸が殆どない状態で塗布ができた。所定面積を塗布した後、さらに同様の方法でコーティング液を補充することで、次の部分の塗布を行った。この結果、約0.1μmの厚さの塗布層を均一に広範な部位に形成することができた。この時、クロスの厚さ1mmで面積1cm2当たりに含浸させるコーティング液の量が0.01ccよりも少ない場合、液量不十分により塗布面に対して十分な皮膜が形成されず性能に斑が生じ、またクロスの厚さ1mmで面積1cm2当たりに含浸させるコーティング液の量が0.4ccを超える場合には、液量のつき過ぎにより塗布斑などの問題を引き起こした。 In order to prevent this from happening, when impregnating the applicator 17 with the coating liquid, the coating liquid is impregnated with 0.01 to 0.4 cc per 1 cm 2 of the cloth with a thickness of 1 mm in advance. The coating liquid is weighed out and transferred to a flat bottom container, and then impregnated on the application surface of the applicator 17 or directly sprinkled on the application surface of the fabric of the bag body 16 to the core body 1 portion. Application was possible with almost no impregnation. After the predetermined area was applied, the next portion was applied by replenishing the coating solution in the same manner. As a result, a coating layer having a thickness of about 0.1 μm could be uniformly formed over a wide area. At this time, if the amount of the coating liquid to be impregnated per 1 cm 2 of the cloth with a thickness of 1 mm is less than 0.01 cc, a sufficient film is not formed on the coated surface due to insufficient liquid amount and the performance is uneven. In addition, when the amount of the coating liquid impregnated per 1 cm 2 of the cloth with a thickness of 1 mm exceeded 0.4 cc, problems such as coating unevenness were caused by the excessive amount of the liquid.

本発明の塗布具17の使用状態を図5により説明する。コーティング液をクロスの袋体1に浸漬した塗布具17を先端15の鋭角の部分を、処理する自動車ボディーの塗装面18の側として載置し、この載置した塗布具17を図示しない手で把持して芯体1の後端4の側を持ち上げ、先端15の側を自動車ボディーの塗装面18に押しつけて適宜曲状にしながら速やかに移動して塗布する。この場合、上記のように塗布具17を適宜曲状にすることで、自動車ボディーの塗装面18への塗布圧力を調節するものとした。   The use state of the applicator 17 of the present invention will be described with reference to FIG. The applicator 17 in which the coating liquid is immersed in the cloth bag 1 is placed with the acute angle portion of the tip 15 as the side of the painted surface 18 of the automobile body to be processed. Grip and lift the rear end 4 side of the core body 1 and press the end 15 side against the painted surface 18 of the automobile body to move quickly and apply it in an appropriate curved shape. In this case, the application pressure on the painted surface 18 of the automobile body is adjusted by appropriately bending the applicator 17 as described above.

このようにクロスの袋体16のみにコーティング液を含浸したことで、手で塗布具17を把持して塗布する際に、塗布具17に加える把持した手の圧力が多少変動したとしても、余分なコーティング液が芯体1から滲みだすようなことがなかった。このために自動車ボディーの塗装面18にコーティング液をムラなく均一に薄く塗布することが容易に実施できた。この場合、袋体16に含浸した1回分のコーティング液を塗布するのみであるので、コーティング液を短時間内で十分に伸展でき、塗布した部分に伸展しきれずにムラを生じて残ることがなかった。この場合、袋体16に含浸させたコーティング液を使用し尽くすと、使いきった袋体16に再びコーティング液を含浸させるか、あるいは自動車ボディーの塗装面18にコーティング液を垂らして引き続いて残余の自動車ボディーの塗装面18を塗布具17により塗布することができた。   As described above, only the cloth bag 16 is impregnated with the coating liquid, so that when the applicator 17 is gripped and applied by hand, even if the gripped hand pressure applied to the applicator 17 slightly varies, an extra The coating liquid did not ooze out from the core body 1. For this reason, it was possible to easily apply the coating liquid uniformly and thinly onto the painted surface 18 of the automobile body. In this case, since only one coating liquid impregnated into the bag body 16 is applied, the coating liquid can be sufficiently extended within a short period of time, and the applied portion does not extend completely and does not remain uneven. It was. In this case, when the coating liquid impregnated in the bag body 16 is used up, the used bag body 16 is impregnated with the coating liquid again, or the coating liquid is dropped on the painted surface 18 of the automobile body and the remaining liquid is continuously applied. The painted surface 18 of the automobile body could be applied with the applicator 17.

一方、これらの芯体1として、上記の連続気泡のポリウレタンスポンジに替えて、吸液性を有しにくい独立気泡のポリウレタンスポンジから形成し、塗布するコーティング液をポリウレタンスポンジに吸収し難いものとした。このようにコーティング液を吸収し難い独立気泡のポリウレタンスポンジから芯体1を形成したことにより、自動車ボディーの塗装面18にコーティング液を塗布する際に、コーティング液が芯体1に含浸されることが無いので、芯体1の外周を被覆する袋体16のクロスにのみにコーティング液を含浸させることができ、手で把持して塗布する際にコーティング液が出すぎて塗りムラを生じるようなことがなかった。   On the other hand, instead of the above-mentioned open cell polyurethane sponge, these cores 1 are formed from closed cell polyurethane sponges that are difficult to absorb, and the coating liquid to be applied is difficult to be absorbed by the polyurethane sponges. . By forming the core body 1 from the closed cell polyurethane sponge which hardly absorbs the coating liquid, the core body 1 is impregnated with the coating liquid when the coating liquid is applied to the painted surface 18 of the automobile body. Therefore, only the cloth of the bag body 16 covering the outer periphery of the core body 1 can be impregnated with the coating liquid. It never happened.

なお、上記のように3枚のクロス地を重ねて合計厚み0.5〜5.0mmの袋体16とすることなく、袋体16を同一基材で厚みが0.2mmのウエス1枚のみを袋体16に形成したものでは、袋体16へのコーティング液の含浸量は十分でなく、塗布面積が狭くなり、何度もコーティング液の継ぎ足しが必要であった。このため均一に塗布できなく、塗りムラが生じた。また、合計厚みが5mm以上になるようにクロス地を単独または重ねて袋体16にすると含浸されるコーティング液の量が多くなり過ぎ、使用量のロスを多くすることや、凹凸の部分に対応しきれなくなるなどの問題が生じた。これらの実験により、本発明では合計厚みが0.5〜5mmとなるように単独または複数枚の市販のクロス地の繊維径11μのPET100%の長繊維からなるニット製のクロス(商品名:MEワイパー)、繊維径15μのPET100%の繊維からなるニット製のクロス(商品名:生機品番80370)、繊維径60μmのPET繊維からなるニット製のクロス(商品名:クリーンニット04026w)、若しくはポリエステル繊維からなる不織布(商品名:GC120)などからなるクロスを重ねて形成した袋体16が、それぞれ請求項2に記載の条件を満足し得るものであった。   In addition, the cloth body 16 is made of the same base material and only one waste cloth having a thickness of 0.2 mm without overlapping the three cloth cloths as described above to form the bag body 16 having a total thickness of 0.5 to 5.0 mm. In the case where the bag body 16 is formed, the amount of impregnation of the coating liquid into the bag body 16 is not sufficient, the application area is reduced, and the coating liquid needs to be added many times. For this reason, it was not possible to apply uniformly and uneven coating occurred. In addition, if the cloth body 16 is made of cloth cloth so that the total thickness is 5 mm or more, the amount of the coating liquid impregnated becomes too large, resulting in a large loss of use amount and corresponding to uneven parts. Problems such as being unable to fill up occurred. According to these experiments, in the present invention, a knit cloth (trade name: ME) made of 100% PET 100% long fiber having a fiber diameter of 11 μm, which is a single or a plurality of commercially available cloths, so that the total thickness is 0.5 to 5 mm. Wiper), knitted cloth made of 100% PET fiber having a fiber diameter of 15 μ (trade name: raw machine product number 80370), knitted cloth made of PET fiber having a fiber diameter of 60 μm (trade name: clean knit 04026w), or polyester fiber Each of the bag bodies 16 formed by overlapping cloths made of non-woven fabric (trade name: GC120) or the like can satisfy the conditions described in claim 2.

本発明の塗布具に挿着する芯体の外観例を示す斜視図である。It is a perspective view which shows the external appearance example of the core body inserted in the applicator of this invention. クロスの乾燥状態時の滑走性能を示すグラフである。It is a graph which shows the sliding performance at the time of the dry state of cloth. 本発明の塗布具の袋体の製造工程を示す図である。It is a figure which shows the manufacturing process of the bag body of the applicator of this invention. 本発明の塗布具の1実施の形態の斜視図である。It is a perspective view of one embodiment of the applicator of the present invention. 本発明の塗布具の使用状態を模式的に示す斜視図である。It is a perspective view which shows the use condition of the applicator of this invention typically.

符号の説明Explanation of symbols

1 芯体
2 下底
3 上底
4 後端
5 幅
6 先端
7 鋭角
8 最大幅布地
9 中間幅布地
10 最少幅布地
11 本縫い
12 本縫い
13 本縫い
14 バイアステープ縁取り
15 先端
16 袋体
17 塗布具
18 自動車ボディーの塗装面
DESCRIPTION OF SYMBOLS 1 Core body 2 Lower base 3 Upper base 4 Rear end 5 Width 6 Front end 7 Acute angle 8 Maximum width cloth 9 Intermediate width cloth 10 Minimum width cloth 11 Main sewing 12 Main sewing 13 Main sewing 14 Bias tape edge 15 Front end 16 Bag body 17 Application Tool 18 Painted surface of automobile body

Claims (5)

皮膜形成性物質とそれを溶解または分散しうる揮発性溶媒を主成分とするコーティング液を含浸し得るクロスからなり手で把持しうる大きさの袋体に少なくとも一方の先端を鋭角とした形状のスポンジからなる芯体を挿着して有することを特徴とする自動車ボディーの塗装面にコーティング液を均一に塗布するための塗布具。   It consists of a cloth that can be impregnated with a coating liquid composed mainly of a film-forming substance and a volatile solvent that can dissolve or disperse it, and has a shape with at least one tip at an acute angle in a bag that can be gripped by hand. An applicator for uniformly applying a coating liquid to a painted surface of an automobile body, wherein a core made of a sponge is inserted. 皮膜形成性物質とそれを溶解または分散しうる揮発性溶媒を主成分とするコーティング液を含浸しうるクロスの基材がポリエステルであることを特徴とする請求項1に記載の自動車ボディーの塗装面にコーティング液を均一に塗布するための塗布具。   2. The painted surface of an automobile body according to claim 1, wherein the cloth base material which can be impregnated with a coating liquid mainly composed of a film-forming substance and a volatile solvent capable of dissolving or dispersing it is polyester. An applicator for uniformly applying the coating liquid to the skin. 皮膜形成性物質とそれを溶解または分散しうる揮発性溶媒を主成分とするコーティング液を含浸しうるクロスからなる袋体は、皮膜形成性物質とそれを溶解または分散しうる揮発性溶媒を主成分とするコーティング液を含浸したクロスに490Paの荷重を加えた場合の滑走角度が水平面から35°以下で、かつ、厚さ1mmで面積1cm2当たり0.01〜0.4ccのコーティング液を含浸し得るクロスから形成されていることを特徴とする請求項1または2に記載の自動車ボディーの塗装面にコーティング液を均一に塗布するための塗布具。 A bag body made of cloth that can be impregnated with a coating liquid mainly composed of a film-forming substance and a volatile solvent that can dissolve or disperse the film-forming substance contains a film-forming substance and a volatile solvent that can dissolve or disperse the film-forming substance. When a load of 490 Pa is applied to the cloth impregnated with the coating liquid as a component, the sliding angle is 35 ° or less from the horizontal plane, and the coating liquid is impregnated with 0.01 to 0.4 cc per 1 cm 2 in thickness of 1 mm. 3. An applicator for uniformly applying a coating liquid to a painted surface of an automobile body according to claim 1 or 2, wherein the applicator is formed from a cloth that can be used. クロスからなる袋体は、単独又は複数枚のクロスを重ね合わせた合計厚みが0.5〜5.0mmのクロスから形成の、厚さ10〜30mmで、幅40〜100mm、長さ50〜300mmの大きさの袋体からなり、長さ方向の少なくとも一方の先端が20〜45°の鋭角に形成されているスポンジからなる芯体を挿着し得る大きさであることを特徴とする請求項1〜3のいずれか1項に記載の自動車ボディーの塗装面にコーティング液を均一に塗布するための塗布具。   A bag made of cloth is formed from a cloth having a total thickness of 0.5 to 5.0 mm obtained by superimposing a single cloth or a plurality of cloths, having a thickness of 10 to 30 mm, a width of 40 to 100 mm, and a length of 50 to 300 mm. A core body made of a sponge made of a sponge having a length of at least one end in the length direction and having an acute angle of 20 to 45 ° can be inserted. The applicator for apply | coating a coating liquid uniformly to the coating surface of the motor vehicle body of any one of 1-3. 少なくとも一方の先端を鋭角とした形状のスポンジからなる芯体は、スポンジが連続気泡または独立気泡から形成されていることを特徴とする請求項1〜4のいずれか1項に記載の自動車ボディーの塗装面にコーティング液を均一に塗布するための塗布具。   5. The automobile body according to claim 1, wherein the core made of a sponge having an acute angle at at least one tip is formed of open cells or closed cells. An applicator for evenly applying the coating liquid to the painted surface.
JP2005127204A 2005-04-25 2005-04-25 Applicator for uniformly applying the coating liquid to the painted surface of the automobile body Active JP4575227B2 (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010131530A (en) * 2008-12-04 2010-06-17 Soft99 Corporation Applicator and auxiliary application gadget
JP2012511494A (en) * 2008-12-12 2012-05-24 ピルキントン グループ リミテッド Glass with improved contamination resistance
WO2024025043A1 (en) * 2022-07-26 2024-02-01 주식회사 엠에스포유 Sponge block having outer cover replacement function

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JPS6161075U (en) * 1984-09-25 1986-04-24
JP2001089706A (en) * 1999-09-21 2001-04-03 Toto Ltd Photocatalytic hydrophilic coating agent
JP2001121049A (en) * 1999-10-26 2001-05-08 Nagase & Co Ltd Sheet coating apparatus and method for manufacturing sheet having thin resin layer by using the same
JP2003164793A (en) * 2001-09-18 2003-06-10 Matsushita Electric Works Ltd Coating tool and coating method
JP2003327908A (en) * 2002-05-16 2003-11-19 Clariant (Japan) Kk Hydrophilicity promoter and hydrophilicity retaining agent for polysilazane-containing coating film

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JPS6161075U (en) * 1984-09-25 1986-04-24
JP2001089706A (en) * 1999-09-21 2001-04-03 Toto Ltd Photocatalytic hydrophilic coating agent
JP2001121049A (en) * 1999-10-26 2001-05-08 Nagase & Co Ltd Sheet coating apparatus and method for manufacturing sheet having thin resin layer by using the same
JP2003164793A (en) * 2001-09-18 2003-06-10 Matsushita Electric Works Ltd Coating tool and coating method
JP2003327908A (en) * 2002-05-16 2003-11-19 Clariant (Japan) Kk Hydrophilicity promoter and hydrophilicity retaining agent for polysilazane-containing coating film

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010131530A (en) * 2008-12-04 2010-06-17 Soft99 Corporation Applicator and auxiliary application gadget
JP4654290B2 (en) * 2008-12-04 2011-03-16 株式会社ソフト99コーポレーション Application tool and application aid
JP2012511494A (en) * 2008-12-12 2012-05-24 ピルキントン グループ リミテッド Glass with improved contamination resistance
WO2024025043A1 (en) * 2022-07-26 2024-02-01 주식회사 엠에스포유 Sponge block having outer cover replacement function

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