JP2006284879A - Liquid crystal display element and manufacturing method therefor - Google Patents

Liquid crystal display element and manufacturing method therefor Download PDF

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JP2006284879A
JP2006284879A JP2005104145A JP2005104145A JP2006284879A JP 2006284879 A JP2006284879 A JP 2006284879A JP 2005104145 A JP2005104145 A JP 2005104145A JP 2005104145 A JP2005104145 A JP 2005104145A JP 2006284879 A JP2006284879 A JP 2006284879A
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liquid crystal
injection port
display element
substrate
crystal display
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JP4755438B2 (en
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Yasuhiro Shigefuji
泰大 重藤
Masanori Arima
政典 有馬
Junichiro Sugimura
潤一郎 杉村
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Citizen Miyota Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To make a liquid crystal remaining surface in a filling port smooth even when liquid crystal remaining nearby the filling port is cleaned by using an ultrasonic wave. <P>SOLUTION: A liquid crystal display element is constituted by sticking a pair of substrates together across a sealant provided with the filling port in a projection shape, and filling liquid crystal from the filling port, and the liquid crystal display element is characterized in that two sides of a projection part of the filling port are slant to the normal of the substrate end surface closest to the filling port and spreads in a chevron shape from the substrate end surface to the center. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、液晶表示素子およびその製造方法に関する   The present invention relates to a liquid crystal display element and a method for manufacturing the same.

従来、液晶表示素子において、一対の基板の周辺部同士をシール剤でシールし、該シール剤に設けた液晶注入口から基板間に液晶を注入した後、該液晶注入口に封止剤を塗布して封止した構成が知られている。液晶注入口から液晶を注入した後は、該液晶注入口の近傍、シール剤の端面および基板の端面は液晶で濡れた状態となる。そこで、前記液晶注入口の近傍の液晶を、不織布で拭き取る、エアブローで吹き飛ばす、あるいは吸引などして取り去る除去作業を行った後、液晶注入口に封止剤を塗布している。   Conventionally, in a liquid crystal display element, the peripheral portions of a pair of substrates are sealed with a sealing agent, and liquid crystal is injected between the substrates from a liquid crystal injection port provided in the sealing agent, and then a sealing agent is applied to the liquid crystal injection port Thus, a sealed configuration is known. After the liquid crystal is injected from the liquid crystal injection port, the vicinity of the liquid crystal injection port, the end surface of the sealing agent, and the end surface of the substrate are wet with the liquid crystal. Therefore, after removing the liquid crystal in the vicinity of the liquid crystal injection port with a nonwoven fabric, blowing it off with air blow, or removing it by suction or the like, a sealing agent is applied to the liquid crystal injection port.

前記従来の構成では、液晶注入口の近傍の液晶を完全に取り去ることは困難であり、シール剤の端面と封止剤との間、あるいは基板の端面と封止剤との間には、わずかではあるが液晶が存在している状態となっている。また、シール剤の端面と基板の端面との間に段差がある場合には、この段差の部分に液晶が溜まることがある。そして、これらの状態では、シール剤と封止剤との間の液晶によりシール剤と封止剤との間の接着力が低下し、外部からの応力などにより封止剤が剥離したり、あるいは、シール剤の端面と封止剤との間、あるいは基板の端面と封止剤との間に溜まった液晶によりいわゆるリークパスが生じ、前記液晶注入口から基板間の内側に空気や汚染物質が侵入し、表示不良の原因となる問題を有している。   In the conventional configuration, it is difficult to completely remove the liquid crystal in the vicinity of the liquid crystal injection port, and there is a slight gap between the end surface of the sealing agent and the sealing agent, or between the end surface of the substrate and the sealing agent. However, the liquid crystal is present. In addition, when there is a step between the end surface of the sealing agent and the end surface of the substrate, liquid crystal may accumulate in the step portion. And in these states, the adhesive force between the sealing agent and the sealing agent decreases due to the liquid crystal between the sealing agent and the sealing agent, and the sealing agent peels off due to external stress or the like, or A so-called leak path is created by the liquid crystal accumulated between the end surface of the sealing agent and the sealing agent, or between the end surface of the substrate and the sealing agent, and air and contaminants enter the inside of the substrate from the liquid crystal inlet. However, there is a problem that causes display defects.

前記問題を解決する技術として、封止前に液晶表示素子の前記液晶注入口近傍を溶剤中に浸漬させ超音波洗浄することにより、前記液晶注入口近傍の液晶を除去し、液晶を除去した部分に封止剤を充填した後に硬化させる液晶表示素子の製造方法が公開されている。
例えば特許文献1参照。
As a technique for solving the above problem, the liquid crystal near the liquid crystal inlet is removed by ultrasonic cleaning by immersing the liquid crystal inlet near the liquid crystal display element in a solvent before sealing, and the portion where the liquid crystal is removed The manufacturing method of the liquid crystal display element made to harden | cure after being filled with sealing agent is disclosed.
For example, see Patent Document 1.

図3は従来技術による液晶表示素子の液晶注入口付近のシール剤形状を示す模式図で上面図であり、図4は超音波洗浄後の上面図である。図3において、1は第1基板、2は第2基板で透明基板であり、第1基板1と第2基板2はシール剤3で接着されている。シール剤3の一部に液晶注入口4となる突出部がシール剤3a、3bにより形成されている。突出部を形成するシール剤3a、3bは第2基板の端面2aに対し垂直に形成されている。第1基板1、第2基板2、シール剤3で形成された空間を真空にし、液晶注入口4付近にあらかじめ滴下しておいた液晶を加熱し液体化させると、液晶は前記空間に充填される。滴下する液晶の量は、前記空間を充填しても少しあまる量が設定され、図3で示すように、液晶注入口4付近に残っている。この液晶を前述のように封止前に液晶表示素子の前記液晶注入口近傍を溶剤中に浸漬させ超音波洗浄することにより、前記液晶注入口近傍の液晶を除去する。
特開2004−258556号
FIG. 3 is a schematic view showing a shape of a sealant in the vicinity of a liquid crystal injection port of a liquid crystal display element according to the prior art, and FIG. 4 is a top view after ultrasonic cleaning. In FIG. 3, reference numeral 1 denotes a first substrate, 2 denotes a second substrate, which is a transparent substrate, and the first substrate 1 and the second substrate 2 are bonded together with a sealant 3. A protruding portion that becomes the liquid crystal injection port 4 is formed in a part of the sealing agent 3 by the sealing agents 3a and 3b. The sealing agents 3a and 3b forming the protruding portions are formed perpendicular to the end surface 2a of the second substrate. When the space formed by the first substrate 1, the second substrate 2, and the sealant 3 is evacuated and the liquid crystal dropped in advance near the liquid crystal injection port 4 is heated and liquefied, the liquid crystal is filled into the space. The The amount of liquid crystal to be dropped is set to be slightly larger even if the space is filled, and remains in the vicinity of the liquid crystal injection port 4 as shown in FIG. As described above, the liquid crystal in the vicinity of the liquid crystal inlet is removed by immersing the liquid crystal inlet in the vicinity of the liquid crystal display element in a solvent and ultrasonically cleaning the liquid crystal before sealing.
JP 2004-258556 A

前記液晶表示素子において、液晶注入後(封止前)に液晶注入口近傍を溶剤に浸漬させ、前記液晶注入口近傍が充分きれいになるまで超音波洗浄をおこなうと、前記液晶素子内部(液晶注入口4の内部)の液晶までけずられてしまいう。図4に示すように、液晶注入口4付近の液晶は除去されるが、液晶の残存表面は5aのごとく、平滑面ではなく、特にシール剤3aの壁面近くがえぐられた状態になることが多い。常温での液晶は流動性が低く、特に強誘電性液晶の場合は流動性が低いがために、洗浄の超音波の伝播により発生すると推測されるが、常温ではこの液晶残存表面5aが平滑面に変わることはない。   In the liquid crystal display element, after the liquid crystal is injected (before sealing), the vicinity of the liquid crystal inlet is immersed in a solvent, and ultrasonic cleaning is performed until the vicinity of the liquid crystal inlet is sufficiently clean. The liquid crystal inside (4) is displaced. As shown in FIG. 4, the liquid crystal in the vicinity of the liquid crystal injection port 4 is removed, but the remaining surface of the liquid crystal is not a smooth surface as in 5a, and in particular, the vicinity of the wall surface of the sealant 3a may be removed. Many. Liquid crystals at room temperature have low fluidity, and in particular, ferroelectric liquid crystals have low fluidity. Therefore, it is assumed that they are generated by the propagation of ultrasonic waves for cleaning. Will not change.

液晶残存表面が5aに示すような形状になると、封止剤が液晶残存表面5aに密着せず、封止剤と液晶残存表面5aの間に空間が発生する。前記空間は、前記液晶表示素子内にて移動する可能性があり、前記空間が表示画素部に移動した場合、表示欠陥となる。   When the liquid crystal remaining surface has a shape as shown in 5a, the sealing agent does not adhere to the liquid crystal remaining surface 5a, and a space is generated between the sealing agent and the liquid crystal remaining surface 5a. The space may move in the liquid crystal display element, and when the space moves to the display pixel portion, a display defect occurs.

一対の基板を、突出形状を有する液晶注入口を設けたシール剤を介して貼り合わせ、前記液晶注入口より液晶を注入してなる、液晶表示素子において、前記液晶注入口の突出部のそれぞれの2辺が、前記液晶注入口に最も近い基板端面の法線に対して傾いていて、かつ前記2辺がハの字形状で、前記基板端面から中央に向かって広がっている液晶表示素子とする。   In the liquid crystal display element, in which a pair of substrates are bonded through a sealant provided with a liquid crystal injection port having a protruding shape, and liquid crystal is injected from the liquid crystal injection port, each of the protrusions of the liquid crystal injection port A liquid crystal display element in which two sides are inclined with respect to the normal line of the substrate end surface closest to the liquid crystal injection port, and the two sides have a square shape and spread from the substrate end surface toward the center. .

本発明の液晶表示素子の製造方法は、前記の課題を解決するために、少なくとも、一対の基板の一方の基板に液晶注入口の突出部のそれぞれの2辺が、前記液晶注入口に最も近い基板端面の法線に対して傾いていて、かつ前記2辺がハの字形状で、前記基板端面から中央に向かって広がっているシール剤を形成する工程と、一対の基板を前記シール剤を介して貼り合わせる工程と、前記液晶注入口より液晶を注入する工程と、液晶注入口近傍を溶剤中に浸漬させ超音波洗浄する工程と、前記注入口を封止する工程を有する液晶表示素子の製造方法とする。   In order to solve the above-described problem, the method for manufacturing a liquid crystal display element of the present invention has at least two sides of the protruding portion of the liquid crystal injection port closest to the liquid crystal injection port on one of the pair of substrates. Forming a sealing agent that is inclined with respect to the normal of the substrate end face and has two sides in the shape of a letter C and extends from the end face of the substrate toward the center; A liquid crystal display element comprising: a step of bonding through a liquid crystal; a step of injecting liquid crystal from the liquid crystal injection port; a step of immersing the vicinity of the liquid crystal injection port in a solvent; and a step of ultrasonically cleaning; Let it be a manufacturing method.

本発明による液晶表示素子及び製造方法によると、液晶注入後に液晶注入口近傍を溶剤中に浸漬させ、液晶注入口近傍の液晶が充分きれいに除去されるまで超音波洗浄を実施しているにもかかわらず、液晶表示素子内部に空間ができずに、封止の品質を向上させることができる。   According to the liquid crystal display element and the manufacturing method of the present invention, the vicinity of the liquid crystal inlet is immersed in a solvent after the liquid is injected, and the ultrasonic cleaning is performed until the liquid crystal in the vicinity of the liquid crystal inlet is sufficiently removed. Therefore, no space is formed inside the liquid crystal display element, and the sealing quality can be improved.

本発明の実施形態の特徴は、前記液晶注入口の突出部のそれぞれの2辺が、前記液晶注入口に最も近い基板端面の法線に対して傾いていて、かつ前記2辺がハの字形状で、前記基板端面から中央に向かって広がっている点にある。   A feature of the embodiment of the present invention is that two sides of each protrusion of the liquid crystal injection port are inclined with respect to the normal line of the substrate end surface closest to the liquid crystal injection port, and the two sides are cross-shaped. It is in a shape that spreads from the substrate end surface toward the center.

以下、本発明による液晶表示素子の説明と合わせて本発明による液晶表示素子の製造方法を説明する。図1は本発明による液晶表示素子の液晶注入口付近のシール剤形状を示す模式図で上面図である。1は第1基板、2は第2基板で透明基板であり、第1基板1と第2基板2は一方の基板に形成されたシール剤6で接着されている。シール剤6の一部に液晶注入口4となる突出部がシール剤6a、6bにより形成されている。突出部を形成するシール剤6a、6bは、液晶注入口4が形成される第2基板2の端面2aの法線Aに対して傾いていて、かつ前記2辺(6a、6b)がハの字形状で、前記端面2aから中央に向かって広がっている形状に形成する。第1基板1、第2基板2、シール剤6で形成された空間を真空にし、液晶注入口4付近に滴下しておいた液晶を加熱して、液晶5を注入するのは従来技術と同様である。   Hereinafter, the manufacturing method of the liquid crystal display element according to the present invention will be described together with the description of the liquid crystal display element according to the present invention. FIG. 1 is a top view schematically showing a sealant shape in the vicinity of a liquid crystal inlet of a liquid crystal display device according to the present invention. Reference numeral 1 denotes a first substrate, 2 denotes a second substrate which is a transparent substrate, and the first substrate 1 and the second substrate 2 are bonded to each other with a sealing agent 6 formed on one substrate. Protrusions that serve as the liquid crystal injection ports 4 are formed in a part of the sealing agent 6 by the sealing agents 6a and 6b. The sealing agents 6a and 6b forming the protrusions are inclined with respect to the normal A of the end surface 2a of the second substrate 2 where the liquid crystal injection port 4 is formed, and the two sides (6a and 6b) are It has a letter shape and is formed in a shape spreading from the end face 2a toward the center. The space formed by the first substrate 1, the second substrate 2, and the sealant 6 is evacuated, the liquid crystal dripped in the vicinity of the liquid crystal injection port 4 is heated, and the liquid crystal 5 is injected as in the prior art. It is.

液晶が注入された液晶表示素子を、液晶注入口4が上方になるように縦向きにして、溶剤に浸し、超音波をかける。その際、前記液晶注入口4が液中に完全に隠れるようにする。   The liquid crystal display element into which the liquid crystal has been injected is vertically oriented so that the liquid crystal injection port 4 faces upward, soaked in a solvent, and subjected to ultrasonic waves. At that time, the liquid crystal injection port 4 is completely hidden in the liquid.

溶剤には、半導体グレードのIPAを使用し、超音波洗浄装置には「SHARP社製 超音波洗浄機 UT−205」を使用する。超音波洗浄の条件は、出力80%で、4分30秒で洗浄した。   As the solvent, semiconductor grade IPA is used, and as the ultrasonic cleaning apparatus, “Ultrasonic Cleaning Machine UT-205 manufactured by SHARP” is used. The ultrasonic cleaning conditions were 80% output and 4 minutes 30 seconds.

図2は、本発明による超音波洗浄実施後の、液晶注入口付近の上面図である。前記液晶注入口4の突出部のそれぞれの2辺が、前記液晶注入口4に最も近い基板端面2aの法線Aに対して傾いていない、従来技術による突出部(液晶注入口)形状の場合と比較すると、液晶残存表面5bは平坦であり、特にシール剤6aの内壁面付近のえぐれが発生していないことがわかる。   FIG. 2 is a top view of the vicinity of the liquid crystal inlet after the ultrasonic cleaning according to the present invention. In the case of a conventional projecting portion (liquid crystal inlet) shape in which the two sides of the projecting portion of the liquid crystal inlet 4 are not inclined with respect to the normal A of the substrate end surface 2a closest to the liquid crystal inlet 4 As compared with the above, it can be seen that the liquid crystal remaining surface 5b is flat, and in particular, no pitting occurs near the inner wall surface of the sealant 6a.

図1ではシール剤6a、6bを傾斜させているが、シール剤6a、6bの内壁が実質的に傾斜(曲線も含む)してハの字形状であれば良いことはいうまでもない。   In FIG. 1, the sealing agents 6 a and 6 b are inclined, but it goes without saying that the inner walls of the sealing agents 6 a and 6 b are substantially inclined (including curved lines) and have a square shape.

本発明による液晶表示素子の液晶注入口付近のシール剤形状を示す模式図で上面図The top view with the schematic diagram which shows the sealing agent shape of the liquid crystal inlet vicinity of the liquid crystal display element by this invention 本発明による超音波洗浄実施後の、液晶注入口付近の上面図Top view near the liquid crystal inlet after ultrasonic cleaning according to the present invention. 従来技術による液晶表示素子の液晶注入口付近のシール剤形状を示す模式図で上面図A top view with a schematic diagram showing the shape of the sealant near the liquid crystal inlet of a liquid crystal display device according to the prior art 超音波洗浄後の上面図Top view after ultrasonic cleaning

符号の説明Explanation of symbols

1 第1基板
2 第2基板
2a 第2基板端面
3 シール剤
3a 突出部シール剤
3b 突出部シール剤
4 液晶注入口
5 液晶
5a 液晶残存表面
5b 液晶残存表面
6 シール剤
6a 突出部シール剤
6b 突出部シール剤
DESCRIPTION OF SYMBOLS 1 1st board | substrate 2 2nd board | substrate 2a 2nd board | substrate end surface 3 Sealing agent 3a Protrusion part sealing agent 3b Protrusion part sealing agent 4 Liquid crystal injection port 5 Liquid crystal 5a Liquid crystal residual surface 5b Liquid crystal residual surface 6 Sealing agent 6a Protrusion part sealing agent 6b Protrusion Sealant

Claims (2)

一対の基板を、突出形状を有する液晶注入口を設けたシール剤を介して貼り合わせ、前記液晶注入口より液晶を注入してなる、液晶表示素子において、前記液晶注入口の突出部のそれぞれの2辺が、前記液晶注入口に最も近い基板端面の法線に対して傾いていて、かつ前記2辺がハの字形状で、前記基板端面から中央に向かって広がっていることを特徴とする液晶表示素子。   In the liquid crystal display element, in which a pair of substrates are bonded through a sealant provided with a liquid crystal injection port having a protruding shape, and liquid crystal is injected from the liquid crystal injection port, each of the protrusions of the liquid crystal injection port Two sides are inclined with respect to a normal line of a substrate end surface closest to the liquid crystal injection port, and the two sides are shaped like a letter C and are spread from the substrate end surface toward the center. Liquid crystal display element. 少なくとも、一対の基板の一方の基板に液晶注入口の突出部のそれぞれの2辺が、前記液晶注入口に最も近い基板端面の法線に対して傾いていて、かつ前記2辺がハの字形状で、前記基板端面から中央に向かって広がっているシール剤を形成する工程と、一対の基板を前記シール剤を介して貼り合わせる工程と、前記液晶注入口より液晶を注入する工程と、液晶注入口近傍を溶剤中に浸漬させ超音波洗浄する工程と、前記注入口を封止する工程を有することを特徴とする液晶表示素子の製造方法。   At least two sides of the protrusion of the liquid crystal injection port on at least one of the pair of substrates are inclined with respect to the normal line of the end surface of the substrate closest to the liquid crystal injection port, and the two sides are cross-shaped. Forming a sealing agent spreading in shape from the substrate end surface toward the center, bonding a pair of substrates through the sealing agent, injecting liquid crystal from the liquid crystal injection port, and liquid crystal A method of manufacturing a liquid crystal display element, comprising: a step of immersing the vicinity of the inlet in a solvent and ultrasonically cleaning; and a step of sealing the inlet.
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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63110418A (en) * 1986-10-29 1988-05-14 Matsushita Electric Ind Co Ltd Manufacture of liquid crystal display panel
JPH06235923A (en) * 1993-02-10 1994-08-23 Rohm Co Ltd Liquid crystal display element
JPH07325311A (en) * 1994-05-31 1995-12-12 Sharp Corp Adhered liquid crystal removing device
JPH08146443A (en) * 1994-11-18 1996-06-07 Mitsubishi Electric Corp Liquid crystal display element and its production
JP2000180873A (en) * 1998-12-10 2000-06-30 Hitachi Ltd Liquid crystal display element
JP2004258556A (en) * 2003-02-27 2004-09-16 Miyota Kk Method for manufacturing ferroelectric liquid crystal display element

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63110418A (en) * 1986-10-29 1988-05-14 Matsushita Electric Ind Co Ltd Manufacture of liquid crystal display panel
JPH06235923A (en) * 1993-02-10 1994-08-23 Rohm Co Ltd Liquid crystal display element
JPH07325311A (en) * 1994-05-31 1995-12-12 Sharp Corp Adhered liquid crystal removing device
JPH08146443A (en) * 1994-11-18 1996-06-07 Mitsubishi Electric Corp Liquid crystal display element and its production
JP2000180873A (en) * 1998-12-10 2000-06-30 Hitachi Ltd Liquid crystal display element
JP2004258556A (en) * 2003-02-27 2004-09-16 Miyota Kk Method for manufacturing ferroelectric liquid crystal display element

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