JP2006284681A - Thermosensitive adhesive label - Google Patents

Thermosensitive adhesive label Download PDF

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JP2006284681A
JP2006284681A JP2005101332A JP2005101332A JP2006284681A JP 2006284681 A JP2006284681 A JP 2006284681A JP 2005101332 A JP2005101332 A JP 2005101332A JP 2005101332 A JP2005101332 A JP 2005101332A JP 2006284681 A JP2006284681 A JP 2006284681A
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label
sensitive adhesive
heat
layer
thermosensitive adhesive
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JP4713196B2 (en
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Tetsuro Suenaga
哲朗 末長
Taketaka Hamada
剛孝 浜田
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Dai Nippon Printing Co Ltd
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Dai Nippon Printing Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a thermosensitive adhesive label that can be easily stripped from a glass bottle or the like, to which the label has been adhered, by only immersing it in water in a short period of time, that can be stably adhered to the glass bottle or the like, without producing wrinkles on the label surface in the adhered state. <P>SOLUTION: In the thermosensitive adhesive label, on the inner surface of the label substrate that is a rectangular label substrate, having a resin layer and a paper layer successively layered from the outer surface, belt-like thermosensitive adhesive coating portions with a specified width are formed along two facing side lines, and spot-like thermosensitive adhesive coating portions are formed in a staggered arrangement, in the region between the belt-like thermosensitive adhesive coating portions. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、短時間水に浸けるだけで接着されたラベルを瓶等の被着体から簡単に剥がすことができるとともに、瓶等に安定して接着でき、且つ貼った状態でラベルの表面に貼りしわが発生しないガラス瓶等に使用できる感熱接着ラベルに関する。   The present invention can be easily peeled off an adherend such as a bottle by simply immersing it in water for a short time, can be stably adhered to a bottle, etc., and can be attached to the surface of the label in a pasted state. The present invention relates to a heat-sensitive adhesive label that can be used for glass bottles and the like that do not generate wrinkles.

従来、感熱性接着剤を部分的に塗布した構成の感熱接着ラベルとしては、感熱性接着剤を塗布してなる接着面を有する医療容器用感熱性ラベルにおいて、接着面には感熱性接着剤の塗布された部分と感熱性接着剤の塗布されていない部分とが一定の割合で設けてあり、かつ接着面のラベル周縁部に位置する部分には、感熱性接着剤が隙間なく塗布されている構成の医療容器用感熱性ラベル(例えば、特許文献1参照)等が知られている。
実公平5─943号公報
Conventionally, as a heat-sensitive adhesive label having a configuration in which a heat-sensitive adhesive is partially applied, in a heat-sensitive label for a medical container having an adhesive surface formed by applying a heat-sensitive adhesive, the adhesive surface is made of a heat-sensitive adhesive. The applied part and the part where the heat-sensitive adhesive is not applied are provided at a certain ratio, and the heat-sensitive adhesive is applied without any gap to the part located on the peripheral edge of the label on the adhesive surface. A heat-sensitive label for a medical container having a configuration (for example, see Patent Document 1) is known.
No. 5-943

しかしながら、上記の医療容器用感熱性ラベルでは、ラベル周縁部に位置する部分には感熱性接着剤が隙間なく塗布されているので、ガラス瓶等の被着材に貼られたラベルを水に浸してラベルを剥離しようとしても、水が瓶とラベルの間に浸透しにくいため、水に溶けやすい感熱性接着剤を使用した場合でも、瓶等に貼られたラベルが水によって剥離しにくいという欠点がある。また、感熱性接着剤の塗布パターンにおいても外部と連通する通路がないためラベルが貼られた瓶を水に浸してもラベルの中央部まで水が浸透しにくいという欠点を有している。   However, in the above-mentioned thermosensitive label for medical containers, since the thermosensitive adhesive is applied to the portion located at the periphery of the label without any gap, the label attached to the adherend such as a glass bottle is immersed in water. Even if you try to peel off the label, water hardly penetrates between the bottle and the label, so even if you use a heat-sensitive adhesive that easily dissolves in water, the label stuck on the bottle etc. is difficult to peel off with water is there. Further, even in the application pattern of the heat-sensitive adhesive, since there is no passage communicating with the outside, there is a disadvantage that even if the bottle with the label attached is immersed in water, the water hardly penetrates to the center of the label.

本発明の目的は、ガラス瓶等に貼り付けたラベルを短時間水の中に浸けるだけで簡単に瓶から剥がすことができるとともに、ラベルの貼り始めと貼り終わりに対応する両側端部にて被着体に安定して接着し、且つ被着体に貼り付けた状態でラベルの縦及び横方向に連通する感熱接着剤の非塗布部がないために、線状の貼りしわが出ることのないガラス瓶等に使用できる感熱接着ラベルを提供することである。   The object of the present invention is that the label attached to a glass bottle or the like can be easily peeled off from the bottle simply by immersing it in water for a short time. Since there is no non-applied part of the heat-sensitive adhesive that adheres stably to the body and is attached to the adherend in the vertical and horizontal directions, the glass bottle does not cause linear sticking wrinkles It is to provide a heat-sensitive adhesive label that can be used for the like.

長方形状のラベル基材の内面に感熱接着剤が塗布されたラベルであって、対向する2辺に沿って所定幅の帯状感熱接着剤層が形成されるとともに、帯状感熱接着剤層間の領域にスポット状感熱接着剤層が千鳥状に形成されている構成の感熱接着ラベルである。   A label in which a heat-sensitive adhesive is applied to the inner surface of a rectangular label base material, and a band-shaped heat-sensitive adhesive layer having a predetermined width is formed along two opposing sides, and is formed in a region between the belt-shaped heat-sensitive adhesive layers. It is a heat-sensitive adhesive label having a configuration in which spot-like heat-sensitive adhesive layers are formed in a staggered pattern.

上記の感熱接着ラベルにおいて、前記スポット状感熱接着剤層が、4角形状であり4角形の対角線が帯状感熱接着剤層の長手方向と平行方向ないしは直角方向に配列されている構成である。   In the heat-sensitive adhesive label, the spot-like heat-sensitive adhesive layer has a quadrangular shape, and a diagonal line of the quadrangular shape is arranged in a direction parallel to or perpendicular to the longitudinal direction of the belt-like heat-sensitive adhesive layer.

上記の感熱接着ラベルにおいて、前記感熱接着剤が水に対する接触角が103度以下である構成である。   In the heat-sensitive adhesive label, the heat-sensitive adhesive has a contact angle with water of 103 degrees or less.

上記の感熱接着ラベルにおいて、前記ラベル基材が、外面から順に樹脂層と紙層と目止層との積層体からなる構成である。   In the above heat-sensitive adhesive label, the label base material is configured by a laminate of a resin layer, a paper layer, and a sealing layer in order from the outer surface.

本発明の感熱接着ラベルの場合、ガラス瓶等に貼り付けたラベルを短時間水に浸けるだけで簡単にラベルを瓶から剥がすことができるとともに、ラベルの貼り始めと貼り終わりに対応する両側端部にて瓶等の被着体に安定して接着し、且つ被着体に貼り付けた状態でラベルの表面に貼りしわが出ることのないガラス瓶等に使用できる感熱接着ラベルとすることができる。   In the case of the heat-sensitive adhesive label of the present invention, the label attached to a glass bottle or the like can be easily peeled off from the bottle simply by immersing the label in water for a short time, and at both end portions corresponding to the start and end of label application. Thus, a heat-sensitive adhesive label that can be used for a glass bottle or the like that adheres stably to an adherend such as a bottle and does not cause wrinkles on the surface of the label when attached to the adherend.

請求項2に係る発明では、ラベルをガラス瓶等に貼りつけた際に、ラベルの縦及び横方向に連通する感熱接着剤の非塗布部がないため、ラベルの表面に縦及び横方向に線状の貼りしわが出ない。   In the invention according to claim 2, when the label is attached to a glass bottle or the like, since there is no non-applied portion of the heat-sensitive adhesive that communicates in the vertical and horizontal directions of the label, the surface of the label is linear in the vertical and horizontal directions. No sticking wrinkles.

請求項3に係る発明では、ラベルを貼り付けたガラス瓶等を水に浸けることにより、ガラス瓶等に貼り付けられたラベルを水により簡単に剥離させることができる。   In the invention which concerns on Claim 3, the label stuck on the glass bottle etc. can be easily peeled with water by immersing the glass bottle etc. which stuck the label in water.

請求項4に係る発明では、ラベル基材の内面となる目止層面に感熱接着剤が塗布されるので、感熱接着剤の紙層への浸透を抑えることができるとともに、水に浸した際に紙が吸湿してふやけたりぼこついたりするのを防止できる。   In the invention according to claim 4, since the heat-sensitive adhesive is applied to the sealing layer surface that is the inner surface of the label base material, the heat-sensitive adhesive can be prevented from penetrating into the paper layer, and when immersed in water. It can prevent the paper from absorbing moisture and becoming dull or voluminous.

以下、図面を引用して本発明の実施の形態を説明する。
図1は本発明の感熱接着ラベルの実施形態の内面側を示す平面図、図2は図1のI−I線断面図、図3はラベル基材の積層構成を示す図であって、2は帯状感熱接着剤塗布部、3はスポット状感熱接着剤塗布部、4は感熱接着剤非塗布部、10はラベル基材、11は樹脂層、12は紙層、13は目止層をそれぞれ表す。
Hereinafter, embodiments of the present invention will be described with reference to the drawings.
1 is a plan view showing an inner surface side of an embodiment of the heat-sensitive adhesive label of the present invention, FIG. 2 is a cross-sectional view taken along line II of FIG. 1, and FIG. Is a belt-like heat-sensitive adhesive application part, 3 is a spot-like heat-sensitive adhesive application part, 4 is a heat-sensitive adhesive non-application part, 10 is a label substrate, 11 is a resin layer, 12 is a paper layer, and 13 is a sealing layer. To express.

本発明の実施形態の感熱接着ラベルは図1、図2に示すとおりである。実施形態の感熱接着ラベルの内面側の形状は、図1に示すように、ガラス瓶等の被着体への貼付け方向の貼り始め端縁部と貼り終り端縁部となるラベルの対向する両側端部には、所定幅を有するベタ状に感熱接着剤が塗布された帯状感熱接着剤塗布部2が形成され、対向する両側端部に形成された帯状感熱接着剤塗布部2に挟まれた領域にはスポット状感熱接着剤塗布部3が千鳥状に配列されて形成され、個々のスポット状感熱接着剤塗布部3間が所定間隔を有する感熱接着剤非塗布部4とされている形状である。   The heat-sensitive adhesive label of the embodiment of the present invention is as shown in FIGS. As shown in FIG. 1, the shape of the inner surface side of the heat-sensitive adhesive label of the embodiment is such that both the opposite ends of the label which are the start edge and the end edge of the sticking in the attaching direction to the adherend such as a glass bottle The area is formed with a band-like heat-sensitive adhesive application part 2 in which a heat-sensitive adhesive is applied in a solid shape having a predetermined width, and is sandwiched between the belt-like heat-sensitive adhesive application parts 2 formed on opposite side ends. The spot-like heat-sensitive adhesive application portions 3 are formed in a zigzag pattern, and each spot-like heat-sensitive adhesive application portion 3 is a heat-sensitive adhesive non-application portion 4 having a predetermined interval. .

実施形態の感熱接着ラベルのラベル基材10の積層構成は、図3に示すとおりであり、外面側から順に樹脂層11と紙層12と目止層13とが積層された構成からなり、内面側の目止層13面に感熱接着剤が所定の形状に塗布されているものである。上記の構成のラベル基材10の内面となる目止層13面に感熱接着剤が塗布されるので、感熱接着剤のラベル基材10への浸透を抑えることができるとともに、水に浸した際にラベル基材10が吸湿してふやけたりぼこついたりするのを防止できる。   The laminated structure of the label base material 10 of the heat-sensitive adhesive label of the embodiment is as shown in FIG. 3, and is composed of a structure in which a resin layer 11, a paper layer 12, and a sealing layer 13 are laminated in order from the outer surface side. A heat-sensitive adhesive is applied in a predetermined shape to the side sealing layer 13 surface. Since the heat-sensitive adhesive is applied to the surface of the sealing layer 13 which is the inner surface of the label base material 10 having the above configuration, the heat-sensitive adhesive can be prevented from penetrating into the label base material 10 and when immersed in water. In addition, it is possible to prevent the label base material 10 from absorbing moisture and becoming dull or voluminous.

実施形態の感熱接着ラベルの構成とすることにより、ガラス瓶等に貼り付けたラベルを短時間水に浸けるだけで、ラベルの端縁に連通している感熱接着剤非塗布部4を通って水がラベルの中央部まで浸透しやすくなり、浸透してきた水によりラベルを簡単に瓶等の被着体から剥離させることができる。また、貼り始めと貼り終わりに対応する対向する両側端部は帯状感熱接着剤塗布部2とされているので瓶等の被着体に安定して接着するとともに、スポット状感熱接着剤塗布部3が千鳥状に配置されており、ラベルの縦及び横方向に連通する感熱接着剤の非塗布部が形成されないため、ラベルの表面に縦又は横方向に線状の貼りしわが出ることがない。   With the configuration of the heat-sensitive adhesive label of the embodiment, water can be passed through the heat-sensitive adhesive non-applied portion 4 communicating with the edge of the label only by immersing the label attached to a glass bottle or the like in water for a short time. It becomes easy to permeate to the center of the label, and the label can be easily peeled off from the adherend such as a bottle by the permeated water. Further, the opposite side end portions corresponding to the start and end of the application are the band-like heat-sensitive adhesive application part 2, so that it adheres stably to an adherend such as a bottle and the spot-like heat-sensitive adhesive application part 3 Are arranged in a zigzag pattern, and no non-application portion of the heat-sensitive adhesive that communicates in the vertical and horizontal directions of the label is formed, so that no linear wrinkles appear in the vertical or horizontal direction on the surface of the label.

ラベル基材10を構成する樹脂層11としては、2軸延伸ポリエチレンテレフタレート、2軸延伸ポリプロピレン等の2軸延伸フィルム、合成樹脂からなるコーティング層が使用できる。目止層13としては、ポリエチレン等の押出樹脂層、合成樹脂ないしは天然樹脂の溶液ないしは水系分散体をコーティングすることにより形成される。紙層12としては厚さが60〜100g/m2 の上質紙、クラフト紙等が使用される。樹脂層11と紙層12の積層はドライラミネーションないしはポリエチレンによる押出ラミネーションにより行われる。感熱接着ラベルの絵柄は紙層の外面に印刷により形成される。 As the resin layer 11 constituting the label substrate 10, a biaxially stretched film such as biaxially stretched polyethylene terephthalate or biaxially stretched polypropylene, or a coating layer made of a synthetic resin can be used. The sealing layer 13 is formed by coating an extruded resin layer such as polyethylene, a synthetic resin or a natural resin solution, or an aqueous dispersion. As the paper layer 12, high-quality paper having a thickness of 60 to 100 g / m 2 , kraft paper or the like is used. Lamination of the resin layer 11 and the paper layer 12 is performed by dry lamination or extrusion lamination with polyethylene. The pattern of the heat-sensitive adhesive label is formed on the outer surface of the paper layer by printing.

本発明の感熱接着ラベルに使用する感熱接着剤としては、例えば、特開2000−137438号公報に記載されているような、ポリエチレン、エチレン−酢酸ビニル共重合体、エチレン−メタクリル酸エステル共重合体、エチレン−アクリル酸エステル共重合体、スチレン−ブタジエン−スチレンブロックポリマー等のポリマー10〜80重量部とタッキファィヤー10〜60重量部とカルナバワックス、キャンデリアワックス、モンタンワックス、ポリエチレンワックス、マイクロクリスタリンワックス等のワックス10〜70重量部とHLB値が15以下である非イオン界面活性剤0.001〜60重量部を含み、水に対する接触角が103度であるホットメルト接着剤、特開2002−40950号公報に記載されているような、ブタジエン共重合体系、酢酸ビニル共重合体系及びアクリル共重合体系から選ばれる1種以上の室温以下では粘着性のない熱可塑性樹脂を含む水性分散体を有するディレードタック型粘着剤組成物を使用することができる。上記構成の感熱接着剤を使用することより、被着体に接着された感熱接着ラベルを水に浸けることにより簡単にラベルを被着体から剥離させることができる。   Examples of the heat-sensitive adhesive used in the heat-sensitive adhesive label of the present invention include polyethylene, ethylene-vinyl acetate copolymer, and ethylene-methacrylic acid ester copolymer as described in JP-A No. 2000-137438. , Ethylene-acrylic acid ester copolymer, styrene-butadiene-styrene block polymer 10-80 parts by weight, tackifier 10-60 parts by weight, carnauba wax, canderia wax, montan wax, polyethylene wax, microcrystalline wax, etc. A hot melt adhesive containing 10 to 70 parts by weight of a wax and 0.001 to 60 parts by weight of a nonionic surfactant having an HLB value of 15 or less and having a contact angle with water of 103 degrees, Japanese Patent Application Laid-Open No. 2002-40950 As described in the publication, Use a delayed tack-type pressure-sensitive adhesive composition having an aqueous dispersion containing a thermoplastic resin that is not sticky at least at one room temperature selected from a diene copolymer system, a vinyl acetate copolymer system, and an acrylic copolymer system Can do. By using the heat-sensitive adhesive having the above structure, the label can be easily peeled off from the adherend by immersing the heat-sensitive adhesive label adhered to the adherend in water.

実施形態の感熱接着ラベルを製造する際に、樹脂層と紙層と目止層を積層したラベル基材の目止層面に感熱接着剤を塗布するには、所定のパターンにてエッチングされたグラビア印刷版を使用して、感熱接着剤組成物をラベル基材の目止層面に印刷することにより塗布することができる。グラビア印刷版として、スクリーン線数が150〜175線、版深60〜80μmのものを使用して印刷することにより、10〜30g/m2 の塗布量で感熱接着剤層を形成することができる。 When manufacturing the heat-sensitive adhesive label of the embodiment, the gravure etched in a predetermined pattern is used to apply the heat-sensitive adhesive to the sealing layer surface of the label base material in which the resin layer, the paper layer, and the sealing layer are laminated. Using a printing plate, the heat-sensitive adhesive composition can be applied by printing on the sealing layer surface of the label substrate. By using a gravure printing plate with a screen line number of 150 to 175 lines and a plate depth of 60 to 80 μm, a heat-sensitive adhesive layer can be formed with a coating amount of 10 to 30 g / m 2. .

本発明の感熱接着ラベルの実施形態の内面側を示す平面図。The top view which shows the inner surface side of embodiment of the thermosensitive adhesive label of this invention. 図1のI−I線断面図。II sectional view taken on the line of FIG. ラベル基材の積層構成を示す図The figure which shows the lamination constitution of the label base material

符号の説明Explanation of symbols

2 帯状感熱接着剤塗布部
3 スポット状感熱接着剤塗布部
4 感熱接着剤非塗布部
10 ラベル基材
11 樹脂層
12 紙層
13 目止層
2 Band-like heat-sensitive adhesive application part 3 Spot-like heat-sensitive adhesive application part 4 Heat-sensitive adhesive non-application part
10 Label substrate
11 Resin layer
12 paper layers
13 Eye stop layer

Claims (4)

長方形状のラベル基材の内面に感熱接着剤が塗布されたラベルであって、対向する2辺に沿って所定幅の帯状感熱接着剤層が形成されるとともに、帯状感熱接着剤層間の領域にスポット状感熱接着剤層が千鳥状に形成されている構成からなることを特徴とする感熱接着ラベル。 A label in which a heat-sensitive adhesive is applied to the inner surface of a rectangular label base material, and a band-shaped heat-sensitive adhesive layer having a predetermined width is formed along two opposing sides, and is formed in a region between the belt-shaped heat-sensitive adhesive layers. A heat-sensitive adhesive label comprising a spot-shaped heat-sensitive adhesive layer formed in a zigzag pattern. 前記スポット状感熱接着剤層が、4角形状であり4角形の対角線が帯状感熱接着剤層の長手方向と平行方向ないしは直角方向に配列されている構成からなることを特徴とする請求項1記載の感熱接着ラベル。 2. The spot-like heat-sensitive adhesive layer has a quadrangular shape, and a diagonal line of the square is arranged in a direction parallel to or perpendicular to the longitudinal direction of the belt-like heat-sensitive adhesive layer. Heat-sensitive adhesive label. 前記感熱接着剤が水に対する接触角が103度以下であることを特徴とする請求項1または2記載の感熱接着ラベル。 The heat-sensitive adhesive label according to claim 1 or 2, wherein the heat-sensitive adhesive has a contact angle with water of 103 degrees or less. 前記ラベル基材が、外面から順に樹脂層と紙層と目止層との積層体からなることを特徴とする請求項1〜3のいずれかに記載の感熱接着ラベル。
The thermosensitive adhesive label according to any one of claims 1 to 3, wherein the label base material is composed of a laminate of a resin layer, a paper layer, and a sealing layer in order from the outer surface.
JP2005101332A 2005-03-31 2005-03-31 Thermal adhesive label Expired - Fee Related JP4713196B2 (en)

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JP4713196B2 JP4713196B2 (en) 2011-06-29

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Cited By (4)

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JP2010085636A (en) * 2008-09-30 2010-04-15 Dainippon Printing Co Ltd Thermo-sensitive adhesive label and roll material equipped with the same
CN102083625A (en) * 2010-05-27 2011-06-01 东洋摩顿株式会社 Dry-type laminating method and laminate obtained therefrom
JP4895456B2 (en) * 2000-04-04 2012-03-14 寿精版印刷株式会社 label
JP2015014630A (en) * 2013-07-03 2015-01-22 凸版印刷株式会社 Thermosensitive label

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JP4895456B2 (en) * 2000-04-04 2012-03-14 寿精版印刷株式会社 label
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