JP2006275090A - Fire prevention division penetrating part structure - Google Patents
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Abstract
Description
本発明は、建築物の防火区画を形成している床面または壁面などをガス配管が貫通する際の貫通部の構造に関する。 The present invention relates to a structure of a penetrating portion when a gas pipe penetrates a floor surface or a wall surface forming a fire prevention section of a building.
通常ガス配管などに使用される配管材料としては、強度および防食性に優れており、さらに塩ビなどの環境負荷の大きい材料を含んでいないという点でポリエチレン被覆鋼管が使用される例が少なくないが、従来は屋内での使用に関しては、防火区画貫通部の耐火性などの点で使用は制限されていた。不燃材料である金属管を防火区画貫通部に用いることは可能であるが、防食性等の点で問題がある。
一方、ポリエチレン管等の可燃性材料からなる配管材料を防火区画貫通部位に適用するための防火措置工法として種々のものが提案されている。例えば、熱膨張性断熱材を床もしくは壁を構成するコンクリートと配管材料であるパイプとの間に充填し、一旦火災が起きた際にはこれが膨張し、床もしくは壁に火災が通るような隙間が発生する事を防ぐというもの(特許文献1)、また、防火区画を貫通する配管材がグラスウール保温材で被覆され、グラスウール保温材で被覆された配管材のグラスウール保温材側に加熱によって耐火断熱層を形成する熱膨張性材料が配設されたもの(特許文献2)などが主なものであった。
There are many cases where polyethylene-coated steel pipes are used as pipe materials that are usually used for gas pipes because they are excellent in strength and corrosion resistance and do not contain materials with high environmental impact such as PVC. Conventionally, for indoor use, use has been limited in terms of fire resistance of the penetration part of the fire prevention compartment. Although it is possible to use a metal tube, which is a non-combustible material, in the fireproof compartment penetrating portion, there are problems in terms of corrosion resistance and the like.
On the other hand, various types of fire protection methods have been proposed for applying a piping material made of a combustible material such as a polyethylene pipe to a fire protection compartment penetration site. For example, a thermal expansive insulation material is filled between the concrete that makes up the floor or wall and the pipe pipe material, and once a fire breaks out, it expands and a gap passes through the floor or wall. (Patent Document 1), and the piping material penetrating through the fire prevention compartment is covered with glass wool heat insulating material, and the heat resistance and heat insulation by heating the glass wool heat insulating material side of the piping material covered with glass wool heat insulating material The main ones (Patent Document 2) provided with a heat-expandable material for forming a layer.
しかしながら、これら従来の方法は現場での施工が多くなるうえ、実際の現場での作業スペースは狭いことも多々あり、必ずしも作業効率の良いものでなく、施工時の労力や施工コストが大きくなるという欠点があった。 However, these conventional methods require a lot of construction at the site, and the work space at the actual site is often narrow, which is not necessarily efficient and increases the labor and construction cost during construction. There were drawbacks.
本発明は、環境負荷の大きい材料を使用せず防食性に優れた樹脂被覆鋼管を防火区画貫通部に適用するための、現場での施工の簡便な防火区画貫通部の構造についてのものである。 The present invention relates to a structure of a fireproof compartment penetration portion that is easy to construct on site for applying a resin-coated steel pipe excellent in corrosion resistance without using a material having a large environmental load to the fireproof compartment penetration portion. .
本発明者らは、区画貫通部の防火性能と、樹脂被覆鋼管の構造及び材質に関して鋭意検討した結果、以下の方法により上記課題を解決できることが判明した。つまり、建築物の防火区画を形成する床、または壁などを配管が貫通する際の貫通部の構造において、床もしくは壁などの区画を仕切っている仕切り部材に貫通しようとする管よりも大きめの孔をあけ、ポリエチレン被覆鋼管を貫通し、空隙をモルタルで埋め戻した構造であり、さらに、最低でも区画貫通部、およびその両側30mmの範囲にわたって用いるポリエチレン被覆鋼管が、厚みが5.9mm以下で外径が116mm以下の鋼管の外側にメルトフローレイトが0.6以下のポリエチレンからなる層がある構造とすれば、この防火区画貫通部は建築基準法施行令でいうところの1時間遮炎性能相当、および財団法人日本消防設備安全センターの1時間耐火性能相当の耐火性を有し、建築基準法施行令でいうところの防火区画、および消防法施行令でいうところの共住区画等の防火区画の配管の貫通に充分適用できるレベルであることが判明した。 As a result of intensive studies on the fireproof performance of the partition through portion and the structure and material of the resin-coated steel pipe, the present inventors have found that the above problem can be solved by the following method. In other words, in the structure of the penetration part when the pipe penetrates the floor or wall that forms the fire prevention compartment of the building, it is larger than the pipe that tries to penetrate the partition member that partitions the compartment such as the floor or wall. The structure is a structure in which a hole is made, the polyethylene-coated steel pipe is penetrated, and the gap is backfilled with mortar. Further, the polyethylene-coated steel pipe used at least in the section through portion and the range of 30 mm on both sides has a thickness of 5.9 mm or less. If the outer diameter of the steel pipe is 116 mm or less and the outer layer has a polyethylene layer with a melt flow rate of 0.6 or less, this fire-blocking section penetration is one-hour flame-shielding performance as stated in the Building Standards Law Enforcement Ordinance. Equivalent to the fire prevention area equivalent to the one-hour fire resistance performance of the Japan Fire Fighting Equipment Safety Center It proved to be a level capable of sufficiently applicable to penetrate the pipe firestop co housing compartment such as referred in Boho Enforcement Order.
本発明の構造の防火区画貫通部にすれば、区画貫通部の片側が火災で昇温しても被覆樹脂は昇温によって完全に流下することなく区画貫通部の鋼管とモルタルとの間に適度に燃え殻を形成するため、火災が通るような隙間は発生せず、さらに、本発明によれば鋼管は火災が起きない限り常にポリエチレンによって被覆されており、非常に防食性の優れたものになっている。 If the fireproof compartment penetrating portion of the structure of the present invention is used, even if one side of the compartment penetrating portion is heated due to a fire, the coating resin does not flow down completely due to the temperature rise, and it is appropriate between the steel pipe and the mortar of the compartment penetrating portion. In order to form a burning husk, there is no gap through which a fire can pass.Furthermore, according to the present invention, the steel pipe is always covered with polyethylene unless a fire occurs, so that it has excellent corrosion resistance. ing.
本発明の防火区画貫通構造は、塩ビなどの環境負荷の大きい材料を含んでおらず強度および防食性に優れている被覆鋼管を用い、かつ現場での施工も簡便であり作業効率がよく、施行時の労力や施工コストも低く抑えられ充分な防火性を備えるものである。 The fireproof compartment penetrating structure of the present invention uses a coated steel pipe that does not contain a material with high environmental impact such as polyvinyl chloride, and has excellent strength and corrosion resistance. The labor and construction cost at the time are kept low, and it has sufficient fire resistance.
以下に本発明の種々の好ましい実施の形態について説明する。 Various preferred embodiments of the present invention will be described below.
(区画貫通部構造)
建築基準法施行令でいうところの防火区画、および消防法施行令でいうところの共住区画等の防火区画を形成する建築物の床、または壁などを配管が貫通する防火区画貫通部の構造において、床もしくは壁などの区画を仕切っている仕切り部材に貫通しようとする管の外径よりも40mmから80mm大きめの円形の孔をあけ、以下に述べるポリエチレン被覆鋼管を貫通し、空隙をモルタルで埋め戻した構造である。また、防火性能、もしくは施工のしやすさ、施工精度確保の上で、最低でも区画貫通部、およびその両側30mmの範囲にわたって以下に述べるポリエチレン被覆鋼管を適用する必要がある。もちろん、施工の簡便性や配管の防食性等を考慮してこれ以上の長さの該ポリエチレン被覆鋼管を用いてもいっこうに構わない。
(Partition penetration structure)
Structure of the fire-blocking section through which piping penetrates the floor or wall of the building that forms the fire-blocking area such as the fire-resisting section as defined in the Building Standard Law Enforcement Ordinance and the Fire Fighting Law Enforcement Ordinance In the above, a circular hole 40 to 80 mm larger than the outer diameter of the pipe to be passed through the partition member partitioning the floor or the wall or the like is drilled, and the polyethylene-coated steel pipe described below is penetrated, and the gap is formed with mortar. It is a backfilled structure. Moreover, in order to ensure fireproof performance, ease of construction, and construction accuracy, it is necessary to apply the polyethylene-coated steel pipe described below over at least the section through portion and the range of 30 mm on both sides. Of course, the polyethylene-coated steel pipe having a length longer than this may be used in consideration of the ease of construction and the corrosion resistance of the pipe.
ここでの仕切り部材は、通常、防火区画や共住区画を構成している鉄筋コンクリート・ALC板(軽量気泡コンクリート板)などでよく、厚さは通常100mm以上のものである。また、管と仕切り部材との間にできる空隙を埋め戻すモルタルは通常用いられている既知の物でよく、普通ポルトランドセメントと川砂または山砂からなる細骨材と水を、セメント:砂の重量比が1:2〜1:3で調合したもの等を使うことができる。また、開口部の面積に対するポリエチレン被覆鋼管の断面積の比は46%以下、好ましくは41%以下が望ましい。 The partition member here may be a reinforced concrete / ALC plate (lightweight cellular concrete plate) or the like that usually constitutes a fire prevention compartment or a cohabitation compartment, and the thickness is usually 100 mm or more. Also, the mortar that fills the gap formed between the pipe and the partition member may be a known one that is usually used, and is usually composed of fine aggregate and water composed of Portland cement and river sand or mountain sand, and the weight of cement: sand. Those prepared in a ratio of 1: 2 to 1: 3 can be used. The ratio of the cross-sectional area of the polyethylene-coated steel pipe to the area of the opening is 46% or less, preferably 41% or less.
上記のポリエチレン被覆鋼管の適用が短すぎる場合や、開口部の面積に対するポリエチレン被覆鋼管の断面積の比が大きすぎる場合には、貫通部の防火特性が発現できず、期待した効果を得られなくなる。 When the application of the above polyethylene-coated steel pipe is too short, or when the ratio of the cross-sectional area of the polyethylene-coated steel pipe to the area of the opening is too large, the fire prevention characteristics of the through portion cannot be expressed, and the expected effect cannot be obtained. .
また、配管を貫通するために区画に設ける孔相互の隔離距離は200mm以上であることが望ましい。 Moreover, it is desirable that the separation distance between the holes provided in the partition for penetrating the pipe is 200 mm or more.
(鋼管)
本発明で用いられる鋼管は、外径が116mm以下で肉厚が5.9mm以下の鋼管であれば良く、特に好ましくは外径が20mm以上90mm以下、肉厚が2.4mm以上5.5mm以下が望ましい。鋼管外面にブラスト処理、酸洗処理、化成処理、メッキ処理、もしくは厚さ200μm以下の熱硬化性プライマー塗装処理を行なっても良く、また、鋼管内面には、ブラスト処理、酸洗処理、化成処理、メッキ処理、熱硬化性プライマー塗装処理などをしてもよい。鋼管の外径が116mmを超える場合、もしくは肉厚が5.9mmを超える場合には、区画の片側より加熱されたときに鋼管を通しての反対面への伝熱量が多くなりすぎ裏面温度が高くなり過ぎてしまう。
(Steel pipe)
The steel pipe used in the present invention may be a steel pipe having an outer diameter of 116 mm or less and a wall thickness of 5.9 mm or less, particularly preferably an outer diameter of 20 mm or more and 90 mm or less and a wall thickness of 2.4 mm or more and 5.5 mm or less. Is desirable. Blasting, pickling, chemical conversion, plating, or thermosetting primer coating with a thickness of 200 μm or less may be applied to the outer surface of the steel pipe, and blasting, pickling, chemical conversion on the inner surface of the steel pipe. , Plating treatment, thermosetting primer coating treatment, etc. If the outer diameter of the steel pipe exceeds 116 mm, or if the wall thickness exceeds 5.9 mm, the amount of heat transferred to the opposite surface through the steel pipe increases when heated from one side of the compartment, and the back surface temperature becomes high. It will pass.
(ポリエチレン被覆)
被覆層に用いられるポリエチレンは、既知の汎用樹脂であり、エチレンを主成分として重合したものであるが、被覆層としての性能を向上させるために共重合モノマーとして、プロピレン、ブテン、ヘキセン、もしくはオクテンなどの俗に言うα−オレフィンを用いた共重合体であっても良い。ただし、メルトフローレイトが0.6以下のものであること、より好ましくは0.3以下のものであることが区画貫通部の防火性上よい。メルトフローレイトの下限は特に制限されないが実用上0.05程度までである。メルトフローレイトはポリエチレンのメルトマスフローレイトを測定する通常の方法で求めることができ、JIS K6922−1(測定温度190℃、荷重2.16kg)で規定されている方法で測ることができる。単位はg/10分である。
(Polyethylene coating)
Polyethylene used for the coating layer is a known general-purpose resin that is polymerized with ethylene as a main component, but propylene, butene, hexene, or octene is used as a copolymerization monomer to improve the performance as a coating layer. A copolymer using a commonly called α-olefin may be used. However, the melt flow rate is 0.6 or less, more preferably 0.3 or less, in terms of fire resistance of the partition through portion. The lower limit of the melt flow rate is not particularly limited, but is practically about 0.05. The melt flow rate can be determined by an ordinary method for measuring the melt mass flow rate of polyethylene, and can be measured by the method defined in JIS K6922-1 (measurement temperature 190 ° C., load 2.16 kg). The unit is g / 10 minutes.
また、上記樹脂組成物には本発明の性能を損なわない範囲で、他の樹脂を混ぜ合わせても良く、必要に応じて酸化防止剤、紫外線吸収材、耐光安定化材、難燃剤、顔料、着色料、充填剤、滑材、帯電防止剤、粘着付与剤等の添加剤を加えることができる。 In addition, the resin composition may be mixed with other resins as long as the performance of the present invention is not impaired. If necessary, an antioxidant, an ultraviolet absorber, a light-resistant stabilizer, a flame retardant, a pigment, Additives such as colorants, fillers, lubricants, antistatic agents, tackifiers and the like can be added.
ポリエチレン層の厚みは0.6〜2.4mm程度、好ましくは1.4〜2.0mm程度とする。
鋼管とポリエチレン層とを強固に接着させるために鋼管もしくはプライマー塗装などがなされた鋼管とポリエチレン層の間に接着剤からなる層を介在させてもよく、接着剤層の材料としては無水マレイン酸変性ポリエチレンなどを使用することができるが、接着剤層の厚みは0.3mm以下にすることが望ましい。接着剤層の厚みがこれを超えると、貫通部の防火特性が充分に発現できず、期待した効果を得られにくくなる。一方、接着機能を発揮させるためと、均一に層を形成させるために、厚みは最低でも0.1mm以上とすることが好ましい。
The thickness of the polyethylene layer is about 0.6 to 2.4 mm, preferably about 1.4 to 2.0 mm.
In order to firmly bond the steel pipe and the polyethylene layer, an adhesive layer may be interposed between the steel pipe or the steel pipe coated with a primer and the polyethylene layer, and the adhesive layer is modified with maleic anhydride. Polyethylene or the like can be used, but the thickness of the adhesive layer is desirably 0.3 mm or less. If the thickness of the adhesive layer exceeds this, the fireproof property of the penetrating portion cannot be sufficiently exhibited, and it becomes difficult to obtain the expected effect. On the other hand, it is preferable that the thickness is at least 0.1 mm or more in order to exhibit an adhesive function and to form a uniform layer.
また、鋼管の外側に形成される被覆層の厚みは、ポリエチレン層と接着剤層とを合わせた合計で2.5mm以下であればよい。2.5mmを超えると、貫通部の防火特性が充分に発現できず、期待した効果が得られにくくなる場合がある。 Moreover, the thickness of the coating layer formed in the outer side of a steel pipe should just be 2.5 mm or less in total which put the polyethylene layer and the adhesive bond layer together. If it exceeds 2.5 mm, the fireproof properties of the penetrating part cannot be sufficiently exhibited, and the expected effect may be difficult to obtain.
(被覆方法)
これら樹脂の鋼管への被覆は通常行なわれている方法でよく、鋼管の外側に酸変性ポリエチレンとポリエチレンとを順次押出し被覆してもよく、一度に共押出ししてもよい。また、それぞれを粉体塗装して被覆層を形成しても良い。
(Coating method)
The coating of the resin on the steel pipe may be performed by a conventional method. The acid-modified polyethylene and polyethylene may be sequentially extruded and coated on the outside of the steel pipe, or may be co-extruded at a time. Alternatively, each may be powder-coated to form a coating layer.
以下に、本発明の区画貫通構造について、実施例を用いて説明するが、本発明は以下の実施例のみに限定されるものではない。 Hereinafter, the compartment penetrating structure of the present invention will be described using examples, but the present invention is not limited to the following examples.
(実施例1〜11)
あらかじめ、表1に示す鋼管の外面をブラスト処理し、その外側に熱硬化性エポキシプライマーを10〜20μmの厚さで塗布した。この鋼管を誘導加熱で190℃に昇温してプライマーを硬化した。表1に示すポリエチレンと融点125℃、密度0.936g/cm3の無水マレイン酸変性ポリエチレンを押出し機にて溶融し、酸変性ポリエチレンが内側になるようにクロスヘッド金型より筒状に共押出しして、鋼管の外表面に表1に示す厚さの被覆層を形成した。こうして、ポリエチレン被覆鋼管を製造した。得られたポリエチレン被覆鋼管を長さが1400mmになるように切断した。
(Examples 1 to 11)
In advance, the outer surface of the steel pipe shown in Table 1 was blasted, and a thermosetting epoxy primer was applied to the outside thereof in a thickness of 10 to 20 μm. The steel pipe was heated to 190 ° C. by induction heating to cure the primer. The polyethylene shown in Table 1 and maleic anhydride-modified polyethylene having a melting point of 125 ° C. and a density of 0.936 g /
長さ800mm、巾1600mm、厚さ100mmの鉄筋コンクリート板を作製した。この際、鉄筋コンクリート板の中央付近に表3の寸法の孔を互いに200mm以上離れるように2箇所できるように作製した。110日間養生した後、孔の中央にポリエチレン被覆鋼管を通しコンクリート板との間隙をモルタルで埋め戻して仕切り部材を作製した。モルタルは普通ポルトランドセメントと砂を重量比で1:3で調合した。その後110日間養生し区画貫通部の試験体とした。 A reinforced concrete plate having a length of 800 mm, a width of 1600 mm, and a thickness of 100 mm was produced. At this time, the holes having the dimensions shown in Table 3 were prepared in the vicinity of the center of the reinforced concrete plate so as to be separated from each other by 200 mm or more. After curing for 110 days, a polyethylene-coated steel pipe was passed through the center of the hole, and the gap with the concrete plate was backfilled with mortar to produce a partition member. For mortar, ordinary Portland cement and sand were mixed at a weight ratio of 1: 3. Thereafter, the specimen was cured for 110 days to obtain a test piece for the section penetration portion.
また、被覆鋼管は片側がコンクリート板面よりも1000mmの長さ、反対の側が板面よりも300mmの長さになる用にセッティングし、板面よりも300mm突出ている側の被覆鋼管の端を塞いだ。 In addition, the coated steel pipe is set so that one side is 1000 mm longer than the concrete plate surface and the opposite side is 300 mm longer than the plate surface, and the end of the coated steel tube on the side protruding 300 mm from the plate surface is set. It was blocked.
(比較例1〜4)
表2に示すポリエチレンを使用し、表2に示した厚さの被覆層をもつポリエチレン被覆鋼管を実施例1〜11と同様の方法で製造し、これを用いて実施例1〜11と同様の方法で区画貫通部の試験体を製造した。ただし、鉄筋コンクリート板に開ける孔は表3に示した大きさとした。また、比較例1、2については2箇所の孔がお互いに300mm以上離れるようにした。
(Comparative Examples 1-4)
Using the polyethylene shown in Table 2, a polyethylene-coated steel pipe having a coating layer having the thickness shown in Table 2 was produced in the same manner as in Examples 1 to 11, and using this, the same as in Examples 1 to 11 was used. The test body of the division penetration part was manufactured by the method. However, the holes opened in the reinforced concrete plate were the sizes shown in Table 3. In Comparative Examples 1 and 2, the two holes were separated from each other by 300 mm or more.
こうして得られた実施例1〜11及び比較例1〜4の区画貫通部試験体につき、防火性を調べて評価を行なった。 About the compartment penetration part test body of Examples 1-11 and Comparative Examples 1-4 which were obtained in this way, fireproof property was investigated and evaluated.
<防火性>
製造した区画貫通部試験体の鋼管の長さが300mmの側を加熱側とし、加熱側のモルタル埋め戻し部よりも160mm以上離れた部分を爆裂防止のため厚さ25mmのセラミック板で覆った。この区画貫通部試験体につき財団法人日本消防設備安全センター規定の「防火区画貫通配管等の耐火試験方法」に準じた1時間耐火試験およびその評価を行った。評価結果を表4に示す。ここで初期裏面温度は、仕切り部材の非加熱側面の被覆鋼管貫通部より10mm離れたモルタル埋め戻し部分の温度であり、円周方向に90度間隔で4ヶ所測り、その最高温度とした。また、最高裏面温度は、初期裏面温度と同じ位置を試験中および試験後30分後まで測定しその中で最高となった温度を示した。
<Fireproof>
The side where the length of the steel pipe of the manufactured section penetration part test piece was 300 mm was set as the heating side, and a part separated by 160 mm or more from the mortar backfill part on the heating side was covered with a 25 mm thick ceramic plate to prevent explosion. This zone penetration part test specimen was subjected to a 1 hour fire resistance test and its evaluation in accordance with the “Fireproof Test Method for Fire Protection Zone Through Piping” provided by the Japan Fire Department Safety Center Foundation. The evaluation results are shown in Table 4. Here, the initial back surface temperature is the temperature of a mortar backfill portion that is 10 mm away from the coated steel pipe penetrating portion on the non-heated side surface of the partition member, and is measured at four points at intervals of 90 degrees in the circumferential direction, which is the maximum temperature. Moreover, the maximum back surface temperature measured the same position as the initial back surface temperature during the test and 30 minutes after the test, and showed the highest temperature among them.
<評価>
評価は、表4内の(a)、(b)、(c)が「なし」であり、(d)が100mm未満であり、さらに最高裏面温度が210℃を超えず、かつ初期裏面温度に180℃を加えた温度を超えない場合を良好とし、それ以外を不良「×」とした。良好の場合でも、表4内の(d)が、80mm未満の場合を「◎」、80mm以上95mm未満の場合を「○」、95mm以上100mm未満の場合を「△」とした。
<Evaluation>
In the evaluation, (a), (b) and (c) in Table 4 are “none”, (d) is less than 100 mm, the maximum back surface temperature does not exceed 210 ° C., and the initial back surface temperature is reached. The case where the temperature which added 180 degreeC was not exceeded was made favorable, and other than that was made into defect "x". Even in the case of good, the case where (d) in Table 4 is less than 80 mm is “◎”, the case of 80 mm or more and less than 95 mm is “◯”, and the case of 95 mm or more and less than 100 mm is “Δ”.
表4の結果より実施例1から11までは良好であるのに対し、比較例1から4は不良であった。 From the results of Table 4, Examples 1 to 11 were good, while Comparative Examples 1 to 4 were bad.
本発明は、建築物の防火区画を形成している床面または壁面などをガス配管が貫通する際の貫通部の構造に好適である。 INDUSTRIAL APPLICABILITY The present invention is suitable for a structure of a penetration portion when a gas pipe penetrates a floor surface or a wall surface forming a fire prevention section of a building.
1…区画仕切り部材
2…孔
3…モルタル、モルタル埋め戻し部
4…ポリエチレン被覆鋼管
5…鋼管
6…プライマー層
7…接着剤層
8…ポリエチレン層
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JP2005091753A JP2006275090A (en) | 2005-03-28 | 2005-03-28 | Fire prevention division penetrating part structure |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0353936U (en) * | 1989-09-30 | 1991-05-24 | ||
JPH0972464A (en) * | 1995-09-04 | 1997-03-18 | Nippon Petrochem Co Ltd | Repairing pipe for existing piping |
JPH09125032A (en) * | 1995-10-27 | 1997-05-13 | Nkk Corp | Resin-coated steel pipe |
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2005
- 2005-03-28 JP JP2005091753A patent/JP2006275090A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0353936U (en) * | 1989-09-30 | 1991-05-24 | ||
JPH0972464A (en) * | 1995-09-04 | 1997-03-18 | Nippon Petrochem Co Ltd | Repairing pipe for existing piping |
JPH09125032A (en) * | 1995-10-27 | 1997-05-13 | Nkk Corp | Resin-coated steel pipe |
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