JP2006239667A - Apparatus for purification of contaminated water - Google Patents
Apparatus for purification of contaminated water Download PDFInfo
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- JP2006239667A JP2006239667A JP2005092726A JP2005092726A JP2006239667A JP 2006239667 A JP2006239667 A JP 2006239667A JP 2005092726 A JP2005092726 A JP 2005092726A JP 2005092726 A JP2005092726 A JP 2005092726A JP 2006239667 A JP2006239667 A JP 2006239667A
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Abstract
Description
本発明は、凝縮触媒浄化剤、酸素触媒浄化剤を汚濁水中吊り下げることにより汚濁水中の汚濁物質を吸着分解し、汚濁物質と水を分離分解させる汚濁水浄化装置である。 The present invention is a polluted water purifier that adsorbs and decomposes pollutants in polluted water by suspending a condensation catalyst purifier and oxygen catalyst purifier to separate and decompose pollutants and water.
従来の汚濁水浄化構造は、河川、湖沼、池などの浄化として浚渫機を使い水底の汚泥を浚渫することが主体として行われてきた。水底の汚泥浚渫だけでは水質の改善には至らず、水底を深く掘削することは水底の生態系を破壊することにもつながり水質改善にはならない。近年は経済発展に伴い、都市化と産業発展により排水中の不純物が多種類化しており末端処理場では対応が追い着かないのが現状である。また、従来の浄化システムは、微生物の繁殖と濾過による自然浄化システムが多く、現況の水質悪化状況には自然浄化システムでは対応が困難である。以下従来の微生物の繁殖による浄化システムと微生物と濾過による浄化については、下記公開特許広報に公開されている。
大規模な水質浄化機械設置により水質浄化工法もあるが、これらの浄化工法は莫大な費用がかかり、その莫大な費用を投資した割合には成果が上がっていない。 There are also water purification methods by installing large-scale water purification machines, but these purification methods are enormously expensive and have not been successful in the proportion of investment.
他に自然菌を培養繁殖させ、その菌による水質浄化工法もあるが、菌の地域特性と温度差による培養繁殖は画一的ではなく地域差と温度差により浄化効果が異なる。冬期と低気温の場合、培養繁殖が沈滞し活動が休止する欠点があり、水質浄化は成果が上がらず期待出来ない。自然菌と濾過剤を併用した水中浄化方法もあるが、そして、上記のとおり菌の地域特性、温度差があり菌の培養繁殖による大量水域での水質浄化を期待することは、難しい結果となっているのが現状である。 There is also a water quality purification method that allows natural bacteria to be cultivated and propagated, but the culture and propagation due to the regional characteristics and temperature differences of the bacteria is not uniform, and the purification effect differs depending on the regional differences and temperature differences. In winter and at low temperatures, there is a drawback that culture breeding stagnates and the activity stops, and water quality purification cannot be expected because it does not produce results. There is also an underwater purification method that uses both natural bacteria and a filter. However, as mentioned above, it is difficult to expect water purification in a large amount of water by cultivating and breeding bacteria due to differences in local characteristics and temperature. This is the current situation.
以上述べた従来の最終処理場以外の水質浄化装置は、大型浚渫工事は莫大な経費がかかり、なお、大型機械導入により移動が容易ではなく不動設置の傾向があり、地域が限定され水質改善の為の簡易移動の活動が困難である。また、その浄化設備を増加するには投下資金も莫大となり広域での浄化活動が限定される。 As for the water purification equipment other than the conventional final treatment plants described above, large dredging works cost a lot of money, and it is not easy to move due to the introduction of large machinery, and there is a tendency to immovably install it. It is difficult to carry out simple movement activities. Also, in order to increase the purification facilities, investment funds become enormous and purification activities in a wide area are limited.
大規模なポンプ循環による濾過工法は、瞬時での浄化工法には適するが、設備の増加には設備費用が莫大にかかり、大量な水質浄化を必要とする現状では処理能率に限界があり、資金投下の割には成果が期待出来ない。 The filtration method using large-scale pump circulation is suitable for the instantaneous purification method, but the increase in equipment costs a huge amount of equipment, and there is a limit to the treatment efficiency under the current situation where a large amount of water purification is required. No results can be expected for the investment.
また、自然菌の培養繁殖と濾過剤使用による水質改善は、自然菌の地域特性と温度の高低差による活動が不確定なこともあり、持続的な水質浄化には期待が不透明である。 In addition, there are uncertain expectations regarding the improvement of water quality by cultivating and propagating natural bacteria and the use of filter media due to the uncertain activity due to differences in local characteristics and temperature of natural bacteria.
本発明は、上記のような従来からの構成により水質浄化が遅滞し、水質悪化が進んでいる問題を解決しようとすることであり、河川、湖沼、池の汚濁水の水質改善し、自然再生の実現と環境保全へ向けての足がかりとなることを目的とする。 The present invention is intended to solve the problem that water purification is delayed and the water quality is worsening due to the conventional configuration as described above, and improves the water quality of polluted water in rivers, lakes, ponds, and regenerates nature. The purpose is to become a foothold for the realization of environmental protection.
本発明は、上記目的を達成するために既存の水質浄化方法を見直し、確実に水質浄化が可能となる凝縮浄化剤、酸素触媒浄化剤を水中に装置することにより水酸化ラジカルの働きにより水質浄化が可能な装置である。 In order to achieve the above-mentioned object, the present invention reviews existing water purification methods, and provides water purification by the action of hydroxyl radicals by installing a condensation purification agent and an oxygen catalyst purification agent in water that can reliably perform water purification. It is a device that can.
第1の課題解決手段による作用は次の通りである。莫大な資金を必要としないで確実に水質浄化ができることである。そして、水質浄化の成果を第一と考え、急速な水質浄化も必要であり可能であるが、持続的に水質浄化が計ることができる。 The operation of the first problem solving means is as follows. The water quality can be reliably purified without the need for huge funds. And, considering the result of water purification as the first, rapid water purification is necessary, but it is possible to measure water quality continuously.
また、第2の課題解決手段による作用は、自然資源で水生態系に悪影響を及ばさない中性無機質で水生態系に影響を及ぼさない凝集縮触媒浄化剤が水中にて汚濁水と接触し浄化する。この凝縮触媒剤の特性は、水和反応、ポゾラン反応を有する。水和反応は、物理的吸水作用があり、その繊維素多孔性親水基が汚泥濁水中の汚濁物質、悪臭物質、重金属などを吸着吸収する。 In addition, the action of the second problem solving means is that the agglomerated catalyst purification agent that does not affect the aquatic ecosystem with natural resources and does not affect the aquatic ecosystem comes into contact with polluted water in the water. Purify. The characteristics of the condensation catalyst agent include a hydration reaction and a pozzolanic reaction. The hydration reaction has a physical water absorption action, and its fibrous porous hydrophilic group absorbs and absorbs pollutants, malodorous substances, heavy metals and the like in sludge turbid water.
以上に述べた通り、水中に装置された凝縮触媒浄化剤は、水中の上記不純物を緩やかに吸着されてくる。急速に水質浄化を期待するのであれば、汚濁水中にこの凝縮触媒剤の粉状で直接散をすれば、急速に水質が浄化される。その場合、一時的であり広範囲の水質浄化は、使用凝縮浄化剤が多量に必要となり非経済的である。本発明は、その凝縮触媒浄化剤を水中に保置することにより、少ない資金投下で持続的な水質浄化をすることが目的である。 As described above, the condensed catalyst purifier installed in water slowly adsorbs the impurities in water. If water purification is expected rapidly, the water quality is rapidly purified by directly dispersing the condensed catalyst in powder form in the polluted water. In that case, a temporary and wide-range water purification is uneconomical because a large amount of condensing purification agent is required. An object of the present invention is to perform continuous water purification with a small investment of funds by retaining the condensed catalyst purifier in water.
また、汚濁水中に装置された酸素触媒は、触媒作用を併用した浄化装置である。水酸化ラジカルが効率よく汚濁水中の不純物を分解、吸収し汚濁水を浄化する。 Moreover, the oxygen catalyst installed in the polluted water is a purification device that also uses a catalytic action. Hydroxyl radicals efficiently decompose and absorb impurities in polluted water to purify polluted water.
上述したように本発明の汚濁水浄化装置は、河川、湖水、池の水質の汚濁水を浄化ができる。大都市地域の河川は、上流の下水道の普及により水質悪は改善されつつあるが、しかし、水質悪化は進んでいる。本発明を活用することにより、広範囲に水質の浄化が期待できる。 As described above, the polluted water purification apparatus of the present invention can purify polluted water of river, lake water, and pond water quality. Rivers in large urban areas are being improved in water quality due to the spread of upstream sewers, but water quality deterioration is progressing. By utilizing the present invention, purification of water quality can be expected in a wide range.
地方都市の下水道の普及率は、完全とは言えず家庭雑排水、未処理の工場排水、化学肥料を含む農業排水が直接に河川、湖沼、池に流されている。それが水質悪化の原因となり、水質悪化の方向に進んでいる結果となっている。それらの汚染された汚濁水を本発明の汚濁水浄化装置を活用することで解決ができると考える。 The dissemination rate of sewage in local cities is not perfect. Domestic wastewater, untreated factory wastewater, and agricultural wastewater including chemical fertilizers are directly discharged into rivers, lakes and ponds. It causes water quality deterioration and results in progress in the direction of water quality deterioration. It is considered that such contaminated polluted water can be solved by utilizing the polluted water purification apparatus of the present invention.
以下、本発明の実施の形態を図1〜図3に基づいて説明する。 Hereinafter, embodiments of the present invention will be described with reference to FIGS.
図1においては、粉状の凝縮触媒剤に水を加え練り込みモルタル状にする。モルタル状にした凝縮触媒浄化剤を舛目状のプラスチック板に塗布する。その凝縮触媒浄化剤の使用量は、汚濁水の汚濁度と水量により使用量を計算する。使用する凝縮触媒浄化剤の使用数量は、汚濁水量に対して0.1%程度が平均使用数量である。大規模な汚濁水の浄化には凝縮触媒剤を塗布した網板の数量を増加し、装置することにより汚濁水の浄化が可能となる。 In FIG. 1, water is added to a powdery condensation catalyst agent and kneaded to form a mortar. Apply the mortar-shaped condensed catalyst purifier to a square plastic plate. The usage amount of the condensed catalyst purifier is calculated based on the turbidity of the polluted water and the amount of water. About 0.1% of the amount of the condensed catalyst purifier used is about 0.1% of the amount of polluted water. In order to purify large-scale polluted water, the number of mesh plates coated with a condensing catalyst agent can be increased and the apparatus can be used to purify polluted water.
図2においては、液体の酸素触媒浄化剤を発砲ウレタンフォームに沁み込ませ脱剤する。乾燥後、再度この作業を繰り返し完全乾燥後に網に挿入する。網に挿入した酸素触媒浄化剤は、汚濁水中にはえなわ式に吊り下げ装置する。 In FIG. 2, a liquid oxygen catalyst purifier is swallowed into a foamed urethane foam and removed. After drying, this operation is repeated again and inserted into the net after complete drying. The oxygen catalyst purifier inserted in the net is suspended in a polluted water.
図3においては、汚濁水中に浄化装置を設置した状態です。凝縮触媒浄化剤は、材料その物に重量がありますので沈みますが、逆に酸素触媒剤は浮力があり浮き上がりますので、吊り下げ用重石を必要とします。そして、凝縮触媒浄化、酸素触媒浄化のいずれの装置にしても汚濁水中に吊り下げ、延縄のように連続して綱に接続します。水深がある場合は、縦に何連も連結します。また、汚濁水の浄化が広範囲な場合、触媒浄化剤の吊り下げる接続ロープを増加することにより浄化目的が達成できる。 In Fig. 3, the purification device is installed in the polluted water. Condensed catalyst purifiers sink due to the weight of the material itself, but conversely, oxygen catalyst agents are buoyant and lift up, requiring heavy stones for suspension. And it can be suspended in the polluted water and connected to the rope continuously like a long line regardless of whether it is a condensing catalyst purification or oxygen catalyst purification device. If there is water depth, connect several lines vertically. In the case of extensive purification of polluted water, the purpose of purification can be achieved by increasing the number of connecting ropes that suspend the catalyst purification agent.
本発明の装置は、汚濁水の浄化をすることが目的であるが、流速の急な河川では浄化の効果が遅滞することが考えられる。閉塞的か暖流的な湖沼、池、河川に装備することにて汚濁水の浄化は、約一ヶ月程度で浄化効果が発揮されて浄化された状態が確認される。この浄化装置は、持続的に水質浄化が実現できる汚濁水浄化装置である。 The apparatus of the present invention is intended to purify polluted water, but it is conceivable that the purifying effect is delayed in rivers with a rapid flow rate. Equipped with obstructive or warm current lakes, ponds, and rivers, the purification of polluted water can be confirmed in about one month. This purification apparatus is a polluted water purification apparatus that can achieve continuous water purification.
図3は、本発明装置での凝縮触媒剤使用しての装置をした池浄化の1実施例の断面図である。水量は約2000トンであり浄化触媒剤を縦3連につなぎ、50セットを装置した。装置を汚濁水中に吊り下げた後、約一週間経過の状態は、汚濁水と浄化触媒剤が融合して池の水が薄乳白色に変化してきたが、その後約二週間程経過した時点でその薄乳白色が消え、次第に池の水が浄化され始め、一ヶ月後には透明度が増してきた。凝縮触媒浄化剤を引き続き吊り下げることにより、なお一層の水質浄化ができる。 FIG. 3 is a cross-sectional view of an embodiment of pond purification using an apparatus using a condensation catalyst in the apparatus of the present invention. The amount of water was about 2000 tons, and the purification catalyst agent was connected in three vertical columns, and 50 sets were installed. After suspending the device in the polluted water, about one week has passed, the polluted water and the purification catalyst have merged, and the water in the pond has turned light milky white. The light milky white color disappeared, and the water in the pond gradually began to be purified. After a month, the transparency increased. Further water quality purification can be achieved by continuously suspending the condensed catalyst purification agent.
本発明の凝縮触媒浄化装置、酸素触媒浄化装置を汚濁されている河川、湖沼、池に吊り下げ装置することにより、汚濁水が持続的に浄化される。 The suspended water is continuously purified by suspending the condensation catalyst purification device and the oxygen catalyst purification device of the present invention in a polluted river, lake, or pond.
1 触媒浄化剤保持延長ロープ
2 浮き球
3 浄化触媒剤接続ロープ
4 凝縮触媒剤練り込み確保舛目板
5 凝縮触媒浄化剤
6 空気触媒浄化剤保持円筒網篭
7 空気触媒浄化剤
8 円筒網篭吊り下げ安定重石
9 触媒浄化剤吊り下げロープのアンカー
10 ロープ接続リング
11 凝縮触媒浄化剤
12 酸素触媒浄化剤
T 水底
W 水面1 Catalyst purifier
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JP2011050878A (en) * | 2009-09-02 | 2011-03-17 | Ishii Shoji Kk | Water-bloom suppressing material, method of using the same and water-bloom suppressing device |
CN102897867A (en) * | 2012-11-09 | 2013-01-30 | 哈尔滨工业大学 | Connecting rod fluctuation type adsorption device applied to sudden water contamination emergency treatment |
CN103496759A (en) * | 2013-09-23 | 2014-01-08 | 青岛科技大学 | Movable adsorption device of toxic and harmful substances in natural waters |
JP2015152456A (en) * | 2014-02-14 | 2015-08-24 | 東洋紡株式会社 | Cesium adsorption apparatus and cesium adsorption method |
JP2018180000A (en) * | 2018-07-02 | 2018-11-15 | 東洋紡株式会社 | Cesium adsorption apparatus and adsorption method |
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JP2020052057A (en) * | 2019-12-09 | 2020-04-02 | 東洋紡株式会社 | Cesium adsorption apparatus and adsorption method |
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JP2011050878A (en) * | 2009-09-02 | 2011-03-17 | Ishii Shoji Kk | Water-bloom suppressing material, method of using the same and water-bloom suppressing device |
CN102897867A (en) * | 2012-11-09 | 2013-01-30 | 哈尔滨工业大学 | Connecting rod fluctuation type adsorption device applied to sudden water contamination emergency treatment |
CN103496759A (en) * | 2013-09-23 | 2014-01-08 | 青岛科技大学 | Movable adsorption device of toxic and harmful substances in natural waters |
JP2015152456A (en) * | 2014-02-14 | 2015-08-24 | 東洋紡株式会社 | Cesium adsorption apparatus and cesium adsorption method |
JP2018180000A (en) * | 2018-07-02 | 2018-11-15 | 東洋紡株式会社 | Cesium adsorption apparatus and adsorption method |
CN109095540A (en) * | 2018-07-10 | 2018-12-28 | 孔军旭 | A kind of municipal administration ornamental plantation pond water deodorization apparatus |
JP2020052057A (en) * | 2019-12-09 | 2020-04-02 | 東洋紡株式会社 | Cesium adsorption apparatus and adsorption method |
CN112900529A (en) * | 2020-12-23 | 2021-06-04 | 中国建筑第八工程局有限公司 | River dredging anti-pollution diffusion device |
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