JP2006183003A - Lubricant - Google Patents

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JP2006183003A
JP2006183003A JP2004381049A JP2004381049A JP2006183003A JP 2006183003 A JP2006183003 A JP 2006183003A JP 2004381049 A JP2004381049 A JP 2004381049A JP 2004381049 A JP2004381049 A JP 2004381049A JP 2006183003 A JP2006183003 A JP 2006183003A
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lubricant
solid lubricant
paste
graphite
solid
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JP4730885B2 (en
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Kiyotaka Takimoto
清隆 瀧本
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a lubricant spread on a running body traveling on a rail such as a traveling crane to prevent abrasion of the rail side and a wheel flange surface of the running body, and reduce a contact resistance of sliding surface so as to give smooth traveling of the running body, more particularly, a pasty lubricant added to a solid lubricant filled in a container for a solid lubricant. <P>SOLUTION: The inlet of the solid lubricant in the container is equipped with a very thin sealing agent. The lubricant in which the pasty lubricant is filled in the solid lubricant composed of molybdenum disulfide or tungsten disulfide, graphite and a synthetic wax or a thermoplastic synthetic resin, and the pasty lubricant is composed of a base oil, a thickening agent, molybdenum disulfide and graphite, and the ratio of the contact areas with the solid lubricant and with the pasty lubricant is about 5:3. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、走行クレーン等のレール上を走行する走行体に装着されて該走行体の走行と共にレールの側面と走行体の車輪フランジ面の磨耗を防止し、その摺動面の接触抵抗を軽減して円滑に走行体の走行をさせるための走行体に使用する潤滑剤、更に詳細には、固形潤滑剤の容器に充填されたペースト状潤滑剤に関するものである。   The present invention is mounted on a traveling body that travels on a rail such as a traveling crane, prevents the wear of the side surface of the rail and the wheel flange surface of the traveling body, and reduces the contact resistance of the sliding surface. The present invention relates to a lubricant used for a traveling body for smoothly traveling the traveling body, and more particularly to a paste-like lubricant filled in a solid lubricant container.

セメント工場、製鉄工場、石炭貯蔵場、スクラップ工場等のダストやミストを発生する場所で使用される走行クレーンや台車その他のレール上を走行する走行体を使用する現場では、ダストやミストがレール上面に付着したり堆積したりするため、その付着物や堆積物によって走行体の車輪がスリップする場合がある。特に、車輪の片方のみがスリップすると、走行体に蛇行するような力が作用するため、レールや車輪に損傷を生じる場合がある。   Dust and mist are on the top surface of the rail when using traveling cranes, trolleys and other traveling bodies that run on rails used in places where dust and mist are generated, such as cement factories, steel factories, coal storages, and scrap factories. In some cases, the wheels of the traveling body slip due to the deposits or deposits. In particular, if only one of the wheels slips, a meandering force acts on the traveling body, which may cause damage to the rails and wheels.

従って、常時レールの清掃とレールの側面と走行体の車輪フランジ面の磨耗を防止し、その摺動面の接触抵抗を軽減して円滑に走行体の走行をさせることが必要となり、そこで走行体に潤滑剤の塗布装置を装着し、走行体の走行時にレールの側面と走行体の車輪フランジ面潤滑剤の塗布を行う方式が種々提案されている。   Therefore, it is necessary to always clean the rail and prevent wear of the side surface of the rail and the wheel flange surface of the traveling body, reduce the contact resistance of the sliding surface, and smoothly travel the traveling body. Various types of systems have been proposed in which a lubricant application device is attached to the rail, and the side surface of the rail and the wheel flange surface lubricant of the traveling body are applied during traveling of the traveling body.

例えば、実公昭47−22304号公報、実公昭48−13814号公報には、シンセティックワックス、熱可塑性合成樹脂をバインダーとして、グラファイト、二硫化モリブデン等の固形潤滑剤を混練した成形物が記載されている。
また、実公昭49−3912号公報には、外層に二硫化モリブデン等の硬質潤滑剤を内層に軟質の潤滑剤を成形した固形潤滑剤が記載されている。
実公昭47−22304号公報 実公昭48−13814号公報 実公昭49−3912号公報
For example, Japanese Utility Model Publication Nos. 47-22304 and 48-13814 describe molded products obtained by kneading a solid lubricant such as graphite and molybdenum disulfide using a synthetic wax and a thermoplastic synthetic resin as a binder. Yes.
Japanese Utility Model Publication No. 49-3912 discloses a solid lubricant in which a hard lubricant such as molybdenum disulfide is formed in the outer layer and a soft lubricant is formed in the inner layer.
Japanese Utility Model Publication No. 47-22304 Japanese Utility Model Publication No. 48-13814 Japanese Utility Model Publication No. 49-3912

これらの固形潤滑剤は、グラファイト、二硫化モリブデン、二硫化タングステン等を、溶融されたシンセティックワックス、熱可塑性合成樹脂等を結合材として、乾燥したドライ被膜が形成されるのみであって、レールの側面と走行体の車輪フランジ面への密着性がなく、金属に対しての付着性がよくないという欠点があり、金属製レールや車輪のフランジ等の摺動面に擦り付けても十分な潤滑被膜が形成されないため、現在は全く使用されていない。   These solid lubricants only form a dry dry film using graphite, molybdenum disulfide, tungsten disulfide, etc., as a binder, with molten synthetic wax, thermoplastic synthetic resin, etc. There is a drawback that the side surface and the wheel flange surface of the traveling body are not closely attached, and the adhesion to the metal is not good, and a sufficient lubrication film even when rubbing against a sliding surface such as a metal rail or wheel flange Is not used at all because it is not formed.

一方、パラフィン製外筒の中にグリース等の潤滑剤を封入した構造物は実開昭51−137084号公報、実公昭54−41905号公報に記載されている。
実開昭51−137084公報 実公昭54−41905号公報
On the other hand, a structure in which a lubricant such as grease is sealed in a paraffin outer cylinder is described in Japanese Utility Model Laid-Open Nos. 51-137084 and 54-41905.
Japanese Utility Model Publication No. 51-137084 Japanese Utility Model Publication No. 54-41905

しかしながら、特許文献4の潤滑剤は、潤滑棒の折損防止、硬質の潤滑剤からのグリースの流失及び強度を得るための隔壁を設け、各隔壁に油分を含む流動性のあるグリース等を充填した固形潤滑剤であるから、隔壁を製作することが困難であり、各隔壁へのグリース等の挿入、封止も甚だ困難であるばありでなく、その注入後の最終工程の封止作業に必要な部材があり、その技術を含むコストがかかる欠点がある。
また、特許文献5の潤滑剤は、黒鉛製の容器の各部屋の内面にパラフィン製壁を被着し、その中にグリースを充填する技術が困難であり、高コストになる問題点がある。
However, the lubricant of Patent Document 4 is provided with partition walls for preventing breakage of the lubricating rod, flow of grease from the hard lubricant and obtaining strength, and filling each partition wall with fluid grease containing oil. Because it is a solid lubricant, it is difficult to manufacture partition walls, and it is not always difficult to insert and seal grease etc. into each partition wall, and it is necessary for the sealing process in the final process after injection. There is a disadvantage that it is costly to include the technology.
In addition, the lubricant disclosed in Patent Document 5 has a problem in that it is difficult to apply a technique in which a paraffin wall is attached to the inner surface of each chamber of a graphite container and grease is filled therein, resulting in high costs.

また、外筒のシンセティックワックスに熱可塑性合成樹脂をバインダーとしてグラファイト、二硫化モリブデン等の固形潤滑剤を混練した基体に、潤滑油又はグリースにグラファイト、二硫化モリブデン等の固形潤滑剤を混練したペーストを内包したカプセルを分散させた固形潤滑剤が実公昭55−9622号公報に記載されている。
実公昭55−9622号公報
Also, a paste in which a solid lubricant such as graphite or molybdenum disulfide is kneaded in a synthetic wax in the outer cylinder and a solid lubricant such as graphite or molybdenum disulfide is kneaded in a base, and a solid lubricant such as graphite or molybdenum disulfide is kneaded in lubricating oil or grease. Japanese Utility Model Publication No. 55-9622 discloses a solid lubricant in which capsules containing bismuth are dispersed.
Japanese Utility Model Publication No. 55-9622

しかしながら、この固形潤滑剤の製造工程において、密着性のある十分な油分を含有するカプセルを、あらかじめ溶解された硬質の固形潤滑剤(溶融温度75℃)へ、実際の成形用鋳型に注入するときの110〜130℃の高温の中に油分を含有するカプセルを均一に撹拌しながら分散させ注入させることは、カプセルの外表面の被膜が薄く、また温度的に、撹拌中に成形用鋳型の注入温度によりその被膜は柔らかくなって破れ、油分がカプセルの外に逸散して、その油分が潤滑剤中に溶け込み、固形潤滑剤としての目的とする性状を保持することができない欠点がある。   However, in the manufacturing process of this solid lubricant, when a capsule containing a sufficient oil content with adhesiveness is poured into a hard solid lubricant (melting temperature 75 ° C.) dissolved in advance into an actual mold. Disperse capsules containing oil in a high temperature of 110 to 130 ° C. while uniformly stirring them, so that the coating on the outer surface of the capsules is thin, and the molding mold is injected while stirring in terms of temperature. The film softens and breaks due to temperature, and the oil component is dissipated out of the capsule, so that the oil component dissolves in the lubricant and the desired properties as a solid lubricant cannot be maintained.

更に、中空の容器の内面にパラフィンの塗布層を形成して内部に粘度の強いグリースを封入したものが記載されている。
実公昭58−22854号公報
Furthermore, there is a description in which a paraffin coating layer is formed on the inner surface of a hollow container and grease having a high viscosity is sealed inside.
Japanese Utility Model Publication No. 58-22854

特許文献5の潤滑剤と同様に、特許文献7の容器の各部屋の内面にパラフィン製壁を被着する充填する技術が困難であり、高コストになる問題点がある。   Similar to the lubricant of Patent Document 5, it is difficult to fill the inner surface of each chamber of the container of Patent Document 7 with a paraffin wall, which results in a high cost.

そして、特許文献8には、マイクロカプセルパウダーとワックス原料からなり、マイクロカプセルパウダーの壁材が二硫化モリブデン等の固体潤滑剤を含有し、マイクロカプセルパウダーが固体潤滑剤とおいる又はグリースとの分散体を内包しており、マイクロカプセルパウダーがワックス中に均一に分散しているワックスが記載されている。
特開平6−158071号公報
Patent Document 8 includes a microcapsule powder and a wax raw material, the wall material of the microcapsule powder contains a solid lubricant such as molybdenum disulfide, and the microcapsule powder is dispersed with a solid lubricant or grease. It describes a wax that contains the body and in which the microcapsule powder is uniformly dispersed in the wax.
Japanese Patent Laid-Open No. 6-158071

この特許文献8も、特許文献6と同様に、あらかじめ溶解された潤滑剤の中にマイクロカプセルを混入し、均一に分散させることは、カプセルの外皮の素材がゼラチン質等であるため、温度的に不安定であり、かつ被膜が薄いため、撹拌中に溶解温度によって必然的にそのカプセルが破れ、その中に含有された油分が潤滑剤中に溶け込み、かつ破れたカプセル膜の素材だけが撹拌中に寄せ集まり、だんご状態になって、均一な分散状態での固形潤滑剤を製造することができず、目標とする当初の硬度の固形潤滑剤を作り出すことが困難である。   Similarly to Patent Document 6, this Patent Document 8 also mixes microcapsules in a pre-dissolved lubricant and uniformly disperses them because the capsule shell material is gelatinous or the like. The capsule is ruptured due to the melting temperature during stirring, and the oil contained therein dissolves in the lubricant, and only the material of the broken capsule film is stirred. It is difficult to produce a solid lubricant having a desired initial hardness because it is difficult to produce a solid lubricant in a uniformly dispersed state due to gathering inside and becoming a bun.

上記特許文献4ないし特許文献8に記載された潤滑剤は、固形潤滑剤の中に潤滑油、鉱油、シリコン油等の高粘度の金属石鹸、ペントナイト等を混和したグリースを充填しているため、常温では潤滑油が滲出しないが、時間の経過とともに潤滑油が滲出してきて、走行クレーン等のレールの側面と走行体の車輪フランジ面の塗布面に潤滑油が付着し、周囲の塵埃が潤滑油の塗布面の周囲に付着し、塗布面の周囲にまで拡散し、塗布面が濡れたりよごれたりして汚染され、却ってレールの側面と走行体の車輪フランジ面の摺動面の接触抵抗が大きくなり、円滑に走行体の走行をさせることができなくなるという問題点があった。   The lubricants described in Patent Document 4 to Patent Document 8 are filled with grease in which solid lubricant is mixed with high-viscosity metal soap such as lubricating oil, mineral oil, and silicon oil, pentonite, and the like. The lubricant does not exude at room temperature, but the lubricant exudes over time, and the lubricant adheres to the rail side of the traveling crane and the application surface of the wheel flange surface of the traveling body, and the surrounding dust is lubricated. It adheres to the periphery of the oil application surface, diffuses to the periphery of the application surface, and the application surface is contaminated by getting wet or dirty, and on the contrary, the contact resistance between the rail side and the sliding surface of the wheel flange surface of the traveling body There is a problem that the size of the vehicle becomes large and the traveling body cannot smoothly run.

本発明は、係る従来技術の問題点に鑑み、走行クレーン等のレール上を走行する走行体に装着されて該走行体の走行と共にレールの側面と走行体の車輪フランジ面の磨耗を防止し、その摺動面の接触抵抗を軽減して円滑に走行体の走行をさせるための走行体に使用する潤滑剤、更に詳細には、固形潤滑剤の容器に充填されたペースト状潤滑剤にペースト状潤滑剤を提供することを目的とするものである。   In view of the problems of the related art, the present invention is attached to a traveling body that travels on a rail such as a traveling crane and prevents wear of the side surface of the rail and the wheel flange surface of the traveling body together with traveling of the traveling body, Lubricant used in a traveling body for reducing the contact resistance of the sliding surface and causing the traveling body to travel smoothly, more specifically, a paste-like lubricant filled in a solid lubricant container The object is to provide a lubricant.

本発明は、係る観点のもとになされたものであって、容器状の固形潤滑剤の挿入口には極めて薄い封止用シール剤を有し、前記固形潤滑剤の中に十分な油分を含むペースト状潤滑剤が充填されてなる潤滑剤を特徴とする。   The present invention has been made based on such a viewpoint, and has an extremely thin sealing agent at the insertion port of the container-like solid lubricant, and a sufficient oil content is contained in the solid lubricant. It is characterized by a lubricant filled with a pasty lubricant.

固形潤滑剤は、二硫化モリブデン又は二硫化タングステンとグラファイトとシンセチックワックス又は熱可塑性合成樹脂とからなり、ペースト状潤滑剤は、基油と増稠剤と二硫化モリブデンとグラファイトとからなり、固形潤滑剤とペースト状潤滑剤の当接面積が略5:3からなることを特徴とする。   Solid lubricant is composed of molybdenum disulfide or tungsten disulfide and graphite and synthetic wax or thermoplastic synthetic resin. Paste lubricant is composed of base oil, thickener, molybdenum disulfide and graphite, The contact area between the lubricant and the paste lubricant is approximately 5: 3.

本発明の潤滑剤は、容器状の固形潤滑剤の挿入口には極めて薄い封止用シール材を有し、前記固形潤滑剤の中にペースト状潤滑剤が充填されてなるため、強力で半ドライ状の強靱な潤滑被膜が走行クレーン等のレールの側面と走行体の車輪フランジ面の潤滑剤塗布面に形成され、特に、夏場の雰囲気温度が40℃以上になっても、潤滑剤が流出しない。したがって、周囲の塵埃が潤滑油の塗布面に付着し、塗布面がよごれることがないので、油分の拡散等もなく、耐湿気、耐雨に撚る腐食等がみられないため、レールの側面と走行体の車輪フランジ面の摺動面の接触抵抗が軽減され、円滑に走行体の走行をさせることができる。   The lubricant of the present invention has a very thin sealing seal material at the container-shaped solid lubricant insertion port, and is filled with the paste-like lubricant in the solid lubricant. A dry, tough lubricant film is formed on the side of the rail of a traveling crane or the like and on the surface of the wheel flange of the traveling body where the lubricant is applied. do not do. Therefore, since the surrounding dust does not adhere to the lubricating oil application surface and the application surface does not get dirty, there is no diffusion of oil, etc., and there is no moisture resistance, rain resistance corrosion, etc. The contact resistance of the sliding surface of the wheel flange surface of the traveling body is reduced, and the traveling body can travel smoothly.

本発明の潤滑剤は、固形潤滑剤とペースト状潤滑剤の当接面積が略5:3からなるので、固形潤滑剤の強度が十分保持されながら半乾燥状態の潤滑被膜がレールの側面と走行体の車輪フランジ面の摺動面に形成されるので、レールの側面と走行体の車輪フランジ面の摺動面の接触抵抗が軽減され、円滑に走行体の走行をさせることができ、被膜の耐用期間が延長される。 In the lubricant of the present invention, the contact area between the solid lubricant and the paste-like lubricant is approximately 5: 3, so that the semi-dried lubricant film runs on the side of the rail while the strength of the solid lubricant is sufficiently maintained. Since it is formed on the sliding surface of the wheel flange surface of the body, the contact resistance between the side surface of the rail and the sliding surface of the wheel flange surface of the traveling body is reduced, and the traveling body can run smoothly, The service life is extended.

以下に本発明に係る潤滑剤の構成を、図面に基づいて説明する。先ず図1は、本発明に係る湾曲型潤滑剤の代表例を示す斜視図であり、図2は、長方形型潤滑剤の斜視図、図3は、図1のA−A断面図である。
これらの図面において、潤滑剤は、中空の固形容器からなる固形潤滑剤1とペースト状潤滑剤2とからなる。
Hereinafter, the configuration of the lubricant according to the present invention will be described with reference to the drawings. First, FIG. 1 is a perspective view showing a representative example of a curved lubricant according to the present invention, FIG. 2 is a perspective view of a rectangular lubricant, and FIG. 3 is a cross-sectional view taken along line AA of FIG.
In these drawings, the lubricant is composed of a solid lubricant 1 and a paste-like lubricant 2 made of a hollow solid container.

固形潤滑剤1は、二硫化モリブデン、二硫化タングステン、グラファイト等を、加熱溶融された液状化されたシンセティックワックス、熱可塑性合成樹脂等の中に混入し、撹拌、均一化させた潤滑剤を図1、図2に示すような形状の金型に注入し、冷却、固形化したものである。   The solid lubricant 1 is a lubricant in which molybdenum disulfide, tungsten disulfide, graphite, or the like is mixed in a heated and liquefied synthetic wax, thermoplastic synthetic resin, etc., and stirred and homogenized. 1. Injected into a mold having a shape as shown in FIG. 2, cooled and solidified.

一方、中空の固形容器からなる固形潤滑剤1の内蔵室3には、挿入口4よりペースト充填機により、鉱物油、エステル系合成油、炭化水素系合成油等の普通に使用されている潤滑油、増稠材、二硫化モリブデン又は二硫化タングステン、グラファイト等を含有するペースト状潤滑剤を充填し、その後、封止用シール材5によって封止される。   On the other hand, in the built-in chamber 3 of the solid lubricant 1 composed of a hollow solid container, a commonly used lubrication such as mineral oil, ester-based synthetic oil, hydrocarbon-based synthetic oil or the like is performed by a paste filling machine from the insertion port 4. A pasty lubricant containing oil, thickening material, molybdenum disulfide or tungsten disulfide, graphite or the like is filled, and then sealed with a sealing material 5 for sealing.

封止用シール材5は、固形潤滑剤と同系のものをホットガンを用いて溶融された固形潤滑剤を挿入口4に溶着した後、冷却し、ペースト状潤滑剤を完全に封止される。   As the sealing material 5 for sealing, a solid lubricant melted using a hot gun is welded to the insertion port 4 and then cooled, and the pasty lubricant is completely sealed.

走行クレーン等のレールの側面と走行体の車輪フランジ面の潤滑剤塗布面には、図1、図2に示すように、潤滑剤に固形潤滑剤1からなる塗布壁6が形成される。塗布壁6は使用時に、固形潤滑剤1とペースト状潤滑剤が直ちに潤滑剤塗布面に均一に塗布されるように塗布壁6の厚みは0.3〜1.0mm程度の厚みに形成される。   As shown in FIGS. 1 and 2, an application wall 6 made of a solid lubricant 1 is formed on the side surface of a rail such as a traveling crane and the lubricant application surface of the wheel flange surface of the traveling body. The application wall 6 is formed to have a thickness of about 0.3 to 1.0 mm so that the solid lubricant 1 and the paste-like lubricant are immediately and uniformly applied to the lubricant application surface during use. .

本発明に使用する成分の基油としては、鉱物油、エステル系合成油、エーテル系合成油、炭化水素系合成油等の普通に使用される潤滑油又はこれらの混合油が挙げられる。   Examples of the base oil used in the present invention include commonly used lubricating oils such as mineral oils, ester-based synthetic oils, ether-based synthetic oils, hydrocarbon-based synthetic oils, and mixed oils thereof.

本発明に使用される増稠剤としては、各種金属石鹸、例えば、リチウム石鹸、石油系ワセリン等が挙げられる。その他、脂肪族アミン、脂環式アミン、芳香族アミン等と各種イソシアネート化合物の反応によってえれらるウレア化合物を用いたものであってもよい。ウレア系増稠剤としては、脂肪族ジウレア化合物、芳香族ジウレア化合物、脂肪族ポリウレア化合物、芳香族ポリウレア化合物が挙げられる。   Examples of the thickener used in the present invention include various metal soaps such as lithium soap and petroleum-based petroleum jelly. In addition, urea compounds obtained by reaction of aliphatic amines, alicyclic amines, aromatic amines and the like with various isocyanate compounds may be used. Examples of urea thickeners include aliphatic diurea compounds, aromatic diurea compounds, aliphatic polyurea compounds, and aromatic polyurea compounds.

二硫化モリブデンは、その潤滑機構として層状格子構造を有し、すべり運動下で薄層状に容易に剪断し、摩擦を低減させる。なお、二硫化モリブデンに換えて、二硫化タングステンを使用してもよい。   Molybdenum disulfide has a layered lattice structure as its lubrication mechanism and easily shears into a thin layer under a sliding motion to reduce friction. Note that tungsten disulfide may be used instead of molybdenum disulfide.

グラファイト(黒鉛)は、炭素の同素体の一つで、磨耗防止性能や焼き付け防止性能を発揮するものであり、摺動面に被膜を形成する。平均粒度はそ0.25〜10μmを有するものが適している。   Graphite (graphite) is one of the allotropes of carbon and exhibits wear prevention performance and seizure prevention performance, and forms a film on the sliding surface. An average particle size of 0.25 to 10 μm is suitable.

なお、本発明のペースト状潤滑剤には、上記成分のほかに酸化防止剤、防錆剤、防食剤、耐加重添加剤等を含有させてもよい。   In addition to the above components, the paste-like lubricant of the present invention may contain an antioxidant, a rust inhibitor, a corrosion inhibitor, a load-resistant additive, and the like.

本発明のペースト状潤滑剤は、ペースト状潤滑剤の全重量に対して、ペースト状潤滑剤の全重量に対して、基油は65〜75重量%、増稠剤は5〜10重量%、二硫化モリブデンは10〜20重量%、グラファイトは2〜5重量%、その他の添加剤は1〜5重量%を含有している。基油の含有量が65重量%未満、増稠剤の含有量が5重量%未満、二硫化モリブデンの含有量が10重量%未満、グラファイトの含有量が2重量%未満では、所期の効果を得ることが困難であり、また、基油の含有量が75重量%以上、増稠剤の含有量が15重量%以上、二硫化モリブデンの含有量が25重量%以上、グラファイトの含有量が10重量%以上である場合でも、潤滑は逆効果を生じる。また、滴点が200℃以下、ちょう度(60W/25℃)が250以上では、潤滑剤の雰囲気温度が40℃以上になると潤滑剤が流出する。   The paste lubricant of the present invention is based on the total weight of the paste lubricant, the base oil is 65 to 75% by weight, the thickener is 5 to 10% by weight, Molybdenum disulfide contains 10 to 20% by weight, graphite 2 to 5% by weight, and other additives 1 to 5% by weight. Expected effects when the base oil content is less than 65% by weight, the thickener content is less than 5% by weight, the molybdenum disulfide content is less than 10% by weight, and the graphite content is less than 2% by weight. The base oil content is 75% by weight or more, the thickener content is 15% by weight or more, the molybdenum disulfide content is 25% by weight or more, and the graphite content is Even in the case of 10% by weight or more, lubrication has an adverse effect. When the dropping point is 200 ° C. or lower and the consistency (60 W / 25 ° C.) is 250 or higher, the lubricant flows out when the lubricant ambient temperature is 40 ° C. or higher.

固体潤滑剤とペースト状潤滑剤とのレール、車輪等の塗布面に当接させる時の面積比率については、固体潤滑剤の当接面積が、ペースト状潤滑剤の当接面積より小さい場合は、塗布面に対する潤滑剤の密着率は多くなり、固体潤滑剤の当接面積が、ペースト状潤滑剤の当接面積より大きい場合は、塗布面に対する潤滑剤の密着率は少なくなる。
このとき、ペースト状潤滑剤がドライでもウエットでもなく、半ドライ、即ち、滴点が200℃〜250℃、ちょう度が230以下ものであれば、潤滑被膜が形成されるので、潤滑被膜の剥離現象がなく、より強力で密着性の強力な半ドライ状の強靱な潤滑被膜が形成される。
For the area ratio when the solid lubricant and the paste lubricant are brought into contact with the application surface of the rail, wheel, etc., when the contact area of the solid lubricant is smaller than the contact area of the paste lubricant, The adhesion ratio of the lubricant to the application surface increases, and when the contact area of the solid lubricant is larger than the contact area of the paste lubricant, the adhesion ratio of the lubricant to the application surface decreases.
At this time, if the pasty lubricant is neither dry nor wet, but semi-dry, that is, if the dropping point is 200 ° C. to 250 ° C. and the consistency is 230 or less, a lubricating coating is formed. There is no phenomenon, and a stronger, semi-dry, tough lubricating coating with stronger adhesion is formed.

このことを、図3によって示すと、固体潤滑剤1の面積CはA×B−Dであり、ペースト状潤滑剤4の面積Dはa×bである。
そこで、C≦Dであるときは、固体潤滑剤としての機械的強度が得られず、切損が生じやすいので潤滑剤として使用できない。
また、C≧DであってCがDよりかなり多いときは、固体潤滑剤としての機械的強度が大きすぎてなかなか消耗しないで、ペースト状潤滑剤の塗布面への密着ができず、半ドライ潤滑被膜を形成させることができないことが判明した。
If this is shown by FIG. 3, the area C of the solid lubricant 1 is A × BD, and the area D of the paste lubricant 4 is a × b.
Therefore, when C ≦ D, the mechanical strength as a solid lubricant cannot be obtained, and cutting is likely to occur, so that it cannot be used as a lubricant.
Further, when C ≧ D and C is much larger than D, the mechanical strength as a solid lubricant is too high and does not easily wear out, and the adhesion of the paste-like lubricant to the application surface cannot be achieved. It has been found that a lubricating coating cannot be formed.

そこで、種々の実験を行った結果、固体潤滑剤の当接面積とペースト状潤滑剤の当接面積との比率が、5:3であるときが、もっとも良好な半ドライ潤滑被膜を形成させることができた。   Therefore, as a result of various experiments, when the ratio of the contact area of the solid lubricant and the contact area of the paste lubricant is 5: 3, the best semi-dry lubricant film can be formed. I was able to.

以下、本発明を実施例及び比較例に基づいて説明する。
実施例1〜4、比較例1〜4
実施例1は、固形潤滑剤として、二硫化モリブデン150gとグラファイト50gとを、ポリエチレンワックス(融点105℃)900gとを150℃で混練し、保温した金型に流し込み、成形した容器状固定潤滑剤を得た。
また、基油として鉱物油を700g、リチウム石鹸110gを添加し撹拌し、70〜100℃まで加熱した。更に、鉱物油を200gを添加し、200℃まで加熱後、100℃以下まで冷却し、ベースペーストを得た。
次いで、得られたベースペーストに、表1及び表2に示す二硫化モリブデンとグラファイト等を添加し、適宜鉱物油を添加しながらロールミルによって滴点が200℃に調製し、ペースト状潤滑油を得た。
また、容器状の固形潤滑剤の中に、ペースト状潤滑油を流し込んで充填し、容器状の固形潤滑剤の挿入口には、固形潤滑剤と同系のものをホットガンを用いて溶融された固形潤滑剤を挿入口4に溶着した後、冷却し、ペースト状潤滑剤を完全に封止した。
実施例2,3,4は鉱物油、増稠剤、二硫化モリブデン、グラファイトをそれぞれ表1に示す重量%比で混合した。
固体潤滑剤の当接面積とペースト状潤滑剤の当接面積との比率は5:3であるとき最適の効果を奏した。
比較例1〜4はそれぞれ市販のモリペースト(500)、モリペースト(300)、スミテック(403)、マルテンプ(SRL)を試用した。
Hereinafter, the present invention will be described based on examples and comparative examples.
Examples 1-4, Comparative Examples 1-4
In Example 1, as a solid lubricant, 150 g of molybdenum disulfide and 50 g of graphite, 900 g of polyethylene wax (melting point: 105 ° C.) at 150 ° C. were kneaded and poured into a mold that was kept warm, and molded into a container-like fixed lubricant. Got.
Moreover, 700 g of mineral oil and 110 g of lithium soap were added and stirred as the base oil and heated to 70 to 100 ° C. Furthermore, 200 g of mineral oil was added, heated to 200 ° C., and then cooled to 100 ° C. or lower to obtain a base paste.
Next, molybdenum disulfide and graphite as shown in Tables 1 and 2 are added to the obtained base paste, and a drop point is adjusted to 200 ° C. by a roll mill while appropriately adding mineral oil to obtain a pasty lubricating oil. It was.
Also, paste-like lubricating oil is poured into a container-like solid lubricant and filled, and a solid lubricant similar to the solid lubricant is melted into a container-like solid lubricant insertion port using a hot gun. After the lubricant was welded to the insertion port 4, it was cooled and the pasty lubricant was completely sealed.
In Examples 2, 3, and 4, mineral oil, thickener, molybdenum disulfide, and graphite were mixed at a weight percent ratio shown in Table 1, respectively.
When the ratio of the contact area of the solid lubricant and the contact area of the paste lubricant was 5: 3, the optimum effect was achieved.
In Comparative Examples 1 to 4, commercially available Moly paste (500), Moly paste (300), Sumitec (403), and Maltemp (SRL) were used as trials.

ここで、滴点は、JIS K 2220 8、ちょう度は、JIS K 2220 7によった。また、試験結果は実施例1を100として相対的な寿命比を示した。   Here, the dropping point was according to JIS K 22208 8, and the consistency was according to JIS K 22207. Moreover, the test result showed the relative life ratio by setting Example 1 to 100.

上記の実施例及び比較例から、本発明の潤滑剤は、油分の拡散等もなく、耐湿気、耐雨による腐食等がみられないため、レールの側面と走行体の車輪フランジ面の摺動面の接触抵抗が軽減され、円滑に走行体の走行をさせることができる。
また、固形潤滑剤とペースト状潤滑剤の当接面積が略5:3からなるので、固形潤滑剤の強度が十分保持されながら半乾燥状態の潤滑被膜がレールの側面と走行体の車輪フランジ面の摺動面に形成されるので、レールの側面と走行体の車輪フランジ面の摺動面の接触抵抗が軽減され、円滑に走行体の走行をさせることができ、被膜の耐用期間が延長される。

Figure 2006183003


Figure 2006183003


From the above examples and comparative examples, the lubricant of the present invention has no oil diffusion or the like, and does not show corrosion due to moisture resistance or rain resistance. The contact resistance is reduced, and the traveling body can run smoothly.
Further, since the contact area between the solid lubricant and the paste lubricant is approximately 5: 3, the semi-dried lubricant film is formed on the side surfaces of the rail and the wheel flange surface of the traveling body while the solid lubricant is sufficiently maintained in strength. Therefore, the contact resistance between the rail side surface and the sliding surface of the wheel flange surface of the traveling body is reduced, the traveling body can run smoothly, and the life of the coating is extended. The
Figure 2006183003


Figure 2006183003


本発明に係る潤滑剤の一例を示す斜視図である。It is a perspective view which shows an example of the lubricant which concerns on this invention. 図1に示した潤滑剤の他の例を示す斜視図である。It is a perspective view which shows the other example of the lubricant shown in FIG. 図AのA−A断面図である。It is AA sectional drawing of FIG.

符号の説明Explanation of symbols

1 容器状固形潤滑剤
2 ペースト状潤滑剤
3 内蔵室
4 挿入口
5 封止用シール剤
6 塗布壁
C 固形潤滑剤の当接面積
D ペースト状潤滑剤の当接面積
DESCRIPTION OF SYMBOLS 1 Container-form solid lubricant 2 Paste-form lubricant 3 Built-in chamber 4 Insertion slot 5 Sealing agent 6 Sealing wall C Solid lubricant contact area D Paste-type lubricant contact area

Claims (3)

容器状の固形潤滑剤の挿入口には極めて薄い封止用シール剤を有し、前記固形潤滑剤の中にペースト状潤滑剤が充填されてなる潤滑剤において、固形潤滑剤は、二硫化モリブデン又は二硫化タングステンとグラファイトとシンセチックワックス又は熱可塑性合成樹脂とからなり、ペースト状潤滑剤は、基油と増稠剤と二硫化モリブデンとグラファイトとからなり、固形潤滑剤とペースト状潤滑剤の当接面積が略5:3からなることを特徴とする潤滑剤 The container-shaped solid lubricant insertion port has a very thin sealing agent, and the solid lubricant is filled with a paste-like lubricant. The solid lubricant is molybdenum disulfide. Or, it consists of tungsten disulfide and graphite and synthetic wax or thermoplastic synthetic resin, and the paste lubricant consists of base oil, thickener, molybdenum disulfide and graphite, and solid lubricant and paste lubricant. Lubricant having a contact area of approximately 5: 3 ペースト状潤滑剤は、滴点が200℃以上、ちょう度が230以下のものである請求項1に記載の潤滑剤 2. The lubricant according to claim 1, wherein the pasty lubricant has a dropping point of 200 ° C. or higher and a consistency of 230 or lower. ペースト状潤滑剤は、ペースト状潤滑剤の全重量に対して、基油は65〜75重量%、増稠剤は5〜10重量%、二硫化モリブデンは10〜20重量%、グラファイトは2〜5重量%、その他の添加剤は1〜5重量%を含有している請求項1又は請求項2に記載の潤滑剤 The paste lubricant is 65 to 75% by weight of the base oil, 5 to 10% by weight of the thickener, 10 to 20% by weight of molybdenum disulfide, 2 to 2% of the graphite, based on the total weight of the paste lubricant. The lubricant according to claim 1 or 2, wherein 5 wt% and other additives contain 1 to 5 wt%.
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Publication number Priority date Publication date Assignee Title
JP2009138055A (en) * 2007-12-04 2009-06-25 Ntn Corp Lubricating grease
JP2010065770A (en) * 2008-09-11 2010-03-25 Sii Micro Precision Kk Rolling bearing manufacturing method, rolling bearing, and pivot bearing
CN111979021A (en) * 2020-07-29 2020-11-24 黄山明杰新材料有限公司 Polyester resin solid lubricating block and preparation method thereof

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JPS52137282A (en) * 1976-05-12 1977-11-16 Hamasawa Kogyo:Kk Solar cell for clock
JPS559622Y2 (en) * 1976-10-12 1980-03-03
JPS5822854Y2 (en) * 1980-02-15 1983-05-16 水谷 勝行 wheel flange wear protector
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009138055A (en) * 2007-12-04 2009-06-25 Ntn Corp Lubricating grease
JP2010065770A (en) * 2008-09-11 2010-03-25 Sii Micro Precision Kk Rolling bearing manufacturing method, rolling bearing, and pivot bearing
CN111979021A (en) * 2020-07-29 2020-11-24 黄山明杰新材料有限公司 Polyester resin solid lubricating block and preparation method thereof

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