JP2006141224A - Liquid seasoning - Google Patents

Liquid seasoning Download PDF

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JP2006141224A
JP2006141224A JP2004332367A JP2004332367A JP2006141224A JP 2006141224 A JP2006141224 A JP 2006141224A JP 2004332367 A JP2004332367 A JP 2004332367A JP 2004332367 A JP2004332367 A JP 2004332367A JP 2006141224 A JP2006141224 A JP 2006141224A
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mass
liquid seasoning
acid
salt
content
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Shigemi Tsuchiya
滋美 土屋
Yoko Seo
陽子 瀬尾
Jun Kobori
純 小堀
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Kao Corp
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Kao Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide liquid seasoning making an eater sufficiently feel salty in spite of its low content of salt. <P>SOLUTION: The liquid seasoning has the following ingredients (A)-(C): (A) ≤9 mass% of salt; (B) 0.5-4.2 mass% of potassium; (C) at least one kind of substance selected from nucleic taste substance, phytic acid, citric acid or its salt, inorganic acid salt, sweetener, protein and milk whey minerals. The content of nitrogen of (D) part of the liquid seasoning excluding the ingredient (C) is ≥1.6 mass% due to substance other than the ingredient (C). <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、食塩含有量が低いにもかかわらず塩味のある液体調味料に関する。   The present invention relates to a liquid seasoning having a salty taste despite a low salt content.

醤油に代表される液体調味料は、日本料理だけでなく、各種の料理になくてはならない調味料として広く使用されている。一方、食塩の過多な摂取は、腎臓病、心臓病、高血圧症に悪影響を及ぼすことから、あらゆる飲食品が低食塩化されており、代表的なものとして減塩醤油が挙げられる。そして、減塩醤油は食塩含有量が9w/w%以下と定められている。   Liquid seasonings represented by soy sauce are widely used as seasonings indispensable for various dishes as well as Japanese dishes. On the other hand, excessive intake of salt has an adverse effect on kidney disease, heart disease, and hypertension, so all foods and drinks are low-salt, and a typical example is low-salt soy sauce. And low salt soy sauce has salt content defined as 9 w / w% or less.

このように食塩の摂取量を制限するには減塩された液体調味料の使用が望ましい。しかし、減塩された液体調味料は、食塩含有量が低いことから、いわゆる塩味が十分感じられず、味がもの足りないと感じる人が多い。そのため食塩の摂取量制限が勧められている割には、減塩された液体調味料は普及しておらず、減塩醤油は使用量が増加していない。   Thus, it is desirable to use a reduced salt seasoning to limit salt intake. However, since the salted liquid seasoning has a low salt content, many people feel that the so-called salty taste is not sufficiently felt and the taste is not sufficient. For this reason, while salt intake restriction is recommended, low-salt liquid seasonings are not widespread, and low-salt soy sauce is not used.

液体調味料の味のもの足りなさを改良する手段としては、様々な取り組みがなされている。例えば、減塩醤油においては、食塩代替物として塩化カリウムを使用する方法があるが(特許文献1及び2)、同時に使用するクエン酸塩の味の影響や、糖アルコールにより塩味もマスキングされてしまうという問題点がある。また、減塩醤油にトレハロースを添加する方法(特許文献3)、カプサイシンを添加する方法(特許文献4)、シソ葉エキスを添加する方法(特許文献5)では、それら添加物の風味を異味として感じてしまうという問題点がある。低塩・淡色・高窒素にする方法(特許文献6)では、コク味の増強がみられるが塩味については言及されていない。更に、減塩醤油の技術ではないが、食塩を低減させた場合に塩味を増強する方法として、特定の有機酸、アミノ酸等を組み合わせて添加するという技術もある(特許文献7)。   Various approaches have been made to improve the lack of taste of liquid seasonings. For example, in low-salt soy sauce, there is a method of using potassium chloride as a salt substitute (Patent Documents 1 and 2), but the influence of the taste of citrate used at the same time and the salty taste are masked by sugar alcohol. There is a problem. Moreover, in the method of adding trehalose to low-salt soy sauce (Patent Document 3), the method of adding capsaicin (Patent Document 4), and the method of adding perilla leaf extract (Patent Document 5) There is a problem of feeling. In the method of making low salt, light color, and high nitrogen (Patent Document 6), the richness is enhanced, but the salty taste is not mentioned. Furthermore, although it is not a technique of reduced salt soy sauce, there is also a technique of adding a specific organic acid, amino acid or the like in combination as a method of enhancing the saltiness when salt is reduced (Patent Document 7).

特許第2675254号公報Japanese Patent No. 2675254 特公平06−97972号公報Japanese Patent Publication No. 06-97972 特開平10−66540号公報Japanese Patent Laid-Open No. 10-66540 特開2001−245627号公報JP 2001-245627 A 特開2002−165577号公報Japanese Patent Laid-Open No. 2002-165577 特公平05−007987号公報Japanese Patent Publication No. 05-007987 特開平11−187841号公報JP-A-11-187841

これら従来の減塩された食品の風味を改良する取り組みは、それぞれ一定の効果を上げているが、未だ十分とはいえない。特に食塩含有量の低下と塩味の両立という点で十分とはいえない。
本発明の目的は、食塩含有量が低いにもかかわらず塩味のある、液体調味料を提供することにある。
Each of these conventional efforts to improve the flavor of low-salt foods has achieved a certain effect, but is still not sufficient. In particular, it is not sufficient in terms of both a decrease in salt content and a salty taste.
An object of the present invention is to provide a liquid seasoning having a salty taste despite a low salt content.

なお、本願における「減塩醤油類」とは、製品100g中のナトリウム量が3550mg(食塩として9g)以下の「しょうゆ」、および「しょうゆ加工品」をいい、栄養改善法の病者用の特別用途食品に限定されるものではない。「しょうゆ」とは、日本農林規格に定めるところの液体調味料であり、「しょうゆ加工品」とは、日本農林規格に適合する「しょうゆ」に調味料、酸味料、香料、だし、エキス類等を添加した、「しょうゆ」と同様の用途で用いられる液体調味料をいう。ここで、本願で記載する「醤油」は、日本農林規格の「しょうゆ」と同一概念である。また、本願で記載する「液体調味料」は、減塩醤油類、及び上記の減塩醤油の規格からは外れるが本願の要件を備えた調味料を含める概念とする。なお、液体調味料の業界においては、配合物質の含有量は、通常w/v%にて表記するが、本願においては、各成分の配合量は液体調味料全体中の質量%で記載した。この場合、例えば醤油の窒素分の場合、「1.6質量%」は、「1.9w/v%」に相当する。   As used herein, “reduced salt soy sauce” refers to “soy sauce” and “soy sauce processed product” in which the amount of sodium in 100 g of product is 3550 mg (9 g as salt) or less, and is special for patients with nutrition improvement methods. It is not limited to food products. “Soy sauce” is a liquid seasoning as defined in the Japanese Agricultural Standards, and “soy sauce processed products” means “soy sauce” that meets Japanese Agricultural Standards, seasonings, sours, flavorings, dashi, extracts, etc. This is a liquid seasoning used for the same purpose as “soy sauce”. Here, “soy sauce” described in the present application has the same concept as “soy sauce” in Japanese agricultural and forestry standards. In addition, the “liquid seasoning” described in the present application is a concept including a low salt soy sauce and a seasoning having a requirement of the present application, which is out of the standard of the low salt soy sauce. In the liquid seasoning industry, the content of the compounding substance is usually expressed in w / v%, but in the present application, the compounding amount of each component is described in mass% in the entire liquid seasoning. In this case, for example, in the case of the nitrogen content of soy sauce, “1.6 mass%” corresponds to “1.9 w / v%”.

本発明者は、食塩含有量を9質量%以下にしても塩味を感じさせる手段について検討してきた結果、食塩含有量を9質量%以下と低くし、かつカリウムを0.5〜4.2質量%、窒素含有量を1.6質量%以上とした系で、特定の風味改良成分を含有させることにより、塩味がより強く感じられ、味の良好な液体調味料が得られることを見出した。   As a result of studying means for giving a salty taste even when the salt content is 9% by mass or less, the present inventor has made the salt content as low as 9% by mass or less and 0.5 to 4.2% by mass of potassium. %, And a nitrogen content of 1.6% by mass or more, it was found that by adding a specific flavor improving component, a salty taste is felt more strongly and a liquid seasoning with good taste can be obtained.

すなわち、本発明は、次の成分(A)〜(C):
(A)食塩9質量%以下、
(B)カリウム0.5〜4.2質量%、
(C)核酸系呈味物質、フィチン酸、クエン酸又はその塩、無機酸塩、甘味料、蛋白質及び乳清ミネラルから選択される1種又は2種以上の物質
を含有する液体調味料であって、成分(C)を除いた液体調味料の部分の(D)窒素含有量が、成分(C)以外の物質により1.6質量%以上としたものである液体調味料を提供するものである。
That is, the present invention includes the following components (A) to (C):
(A) salt 9 mass% or less,
(B) 0.5 to 4.2% by mass of potassium,
(C) A liquid seasoning containing one or more substances selected from nucleic acid-based taste substances, phytic acid, citric acid or salts thereof, inorganic acid salts, sweeteners, proteins and whey minerals. And (D) nitrogen content of the portion of the liquid seasoning excluding the component (C) is 1.6% by mass or more due to substances other than the component (C). is there.

本発明によれば、食塩含有量が9質量%以下であるにもかかわらず、塩味を十分に感じることのできる液体調味料が得られる。   According to the present invention, it is possible to obtain a liquid seasoning that can sufficiently feel a salty taste even though the salt content is 9% by mass or less.

本発明の液体調味料中の(A)食塩の含有量は9質量%以下であるが、更に7〜9質量%、特に8〜9質量%であることが血圧降下作用及び風味(塩味を十分に感じる)の点から好ましい。なお、本発明における「含有量」とは、以下特に記載がない場合は、液体調味料全体中の割合をいう。   The content of (A) sodium chloride in the liquid seasoning of the present invention is 9% by mass or less, but it is 7-9% by mass, particularly 8-9% by mass. It is preferable from the point of feeling. In the present invention, “content” refers to the ratio of the whole liquid seasoning unless otherwise specified.

本発明の液体調味料中の(B)カリウムの含有量は0.5〜4.2質量%であるが、好ましくは1〜3.6質量%、更に1.5〜3.1質量%であることが、食塩含有量が低いにもかかわらず塩味を増強させ、かつ苦味を生じない点から好ましい。また、カリウムは塩味があり、かつ異味が少ない点から塩化カリウムであることが好ましい。塩化カリウムを用いる場合は1〜7質量%、更に2〜6質量%、特に3〜5質量%配合することが好ましい。   The content of (B) potassium in the liquid seasoning of the present invention is 0.5 to 4.2% by mass, preferably 1 to 3.6% by mass, and further 1.5 to 3.1% by mass. It is preferable from the point that saltiness is enhanced and bitterness is not generated despite the low salt content. Further, potassium is preferably potassium chloride from the viewpoint that it has a salty taste and a little off-taste. When potassium chloride is used, it is preferably 1 to 7% by mass, more preferably 2 to 6% by mass, and particularly preferably 3 to 5% by mass.

食塩含有量とカリウム含有量を前記範囲に調整するには、例えば仕込水として食塩と例えば塩化カリウムの混合溶液を用いて醤油を製造する方法;塩化カリウム単独の溶液を仕込水として用いて得た醤油と食塩水を単独で仕込水として用いて得た醤油とを混合する方法;食塩水を仕込水として用いた通常の醤油を電気透析、膜処理等によって食塩を除去した脱塩醤油に塩化カリウムを添加する方法等が挙げられる。   In order to adjust the salt content and potassium content to the above ranges, for example, a method of producing soy sauce using a mixed solution of sodium chloride and potassium chloride, for example, as feed water; obtained using a solution of potassium chloride alone as the feed water A method of mixing soy sauce and soy sauce obtained by using saline alone as the feed water; ordinary soy sauce using saline as the feed water is desalted soy sauce from which salt has been removed by electrodialysis, membrane treatment, etc. And the like.

本発明の液体調味料においては、成分(A)〜(C)を含有する液体調味料であって、更に成分(C)を除いた液体調味料の部分の(D)窒素含有量を、成分(C)以外の物質により1.6質量%以上とする。また、成分(C)を除いた液体調味料の部分の(D)窒素の含有量は、1.6〜2質量%であることがより好ましい。通常、醤油においては窒素含有量を高くするとまろやかな味になり、塩味が低下するといわれているところ、食塩含有量が低く、カリウムが含まれている醤油であって、全窒素含有量を上記範囲とすることにより、塩味が向上することは全く予想外であった。   In the liquid seasoning of this invention, it is a liquid seasoning containing component (A)-(C), Comprising: (D) Nitrogen content of the part of the liquid seasoning except a component (C) is used as a component. It is 1.6 mass% or more with substances other than (C). Moreover, as for the content of (D) nitrogen of the part of a liquid seasoning except a component (C), it is more preferable that it is 1.6-2 mass%. Usually, in soy sauce, it is said that when the nitrogen content is increased, the taste becomes mellow and the salty taste is lowered, soy sauce containing low salt content and potassium is included, and the total nitrogen content is within the above range. It was completely unexpected that the salty taste was improved.

通常の醤油の窒素含有量は1.2〜1.6質量%であるが、窒素含有量を1.6質量%以上とするには、通常の方法で醸造した醤油に、アミノ酸等の窒素を含有する物質を本発明の規定範囲の量となるように添加すること、又は濃縮及び脱塩の工程を施すことにより達成できる。例えば、減塩濃縮法によって食塩を除去するとともに、水を主成分とする揮発成分での希釈率を調整する方法や、電気透析装置によって食塩を除去する際に起こるイオンの水和水の移動を利用して、窒素分も同時に濃縮する方法等がある。また、通常より食塩分の低い減塩醤油をRO膜や減圧濃縮により、窒素含有量を高める方法や、逆に、たまり醤油、再仕込み醤油のような窒素含有量の高い醤油から脱塩することによる方法等がある。   The normal soy sauce has a nitrogen content of 1.2 to 1.6% by mass. To make the nitrogen content 1.6% by mass or more, soy sauce brewed by a normal method is added nitrogen such as amino acids. This can be achieved by adding the substance to be contained in an amount within the specified range of the present invention, or by performing steps of concentration and desalting. For example, while removing salt by reducing salt concentration, adjusting the dilution rate with volatile components containing water as the main component, and transferring ion hydration water that occurs when removing salt by electrodialysis equipment There is a method of concentrating nitrogen content at the same time. In addition, salt-reduced soy sauce, which has a lower salt content than usual, can be desalted from RO membranes or methods of increasing the nitrogen content by concentrating under reduced pressure, or conversely, desalting from soy sauce with a high nitrogen content, such as tamari soy sauce or recharged soy sauce. There is a method.

本発明の液体調味料においては、窒素含有量を高める方法として、成分(C)以外の窒素を含有する物質を添加することが好ましい。窒素含有物質の中でも、アミノ酸、特に酸性アミノ酸、塩基性アミノ酸が塩味の増強、及び持続性の点から好ましい。液体調味料中の含有量は、酸性アミノ酸が2質量%超、及び/又は塩基性アミノ酸が1質量%超であることが好ましい。また、酸性アミノ酸は2質量%超5質量%以下、更に2.4〜4.5質量%、特に2.5〜3.8質量%であることが、塩味の持続性の点から好ましく、塩基性アミノ酸は1質量%超3質量%以下、更に1.2〜2.5質量%、特に1.5〜2質量%であることが、塩味の持続性の点から好ましい。なお、本発明の液体調味料は、醸造調味料をベースとしたものが塩味の持続性、風味等の点から好ましいが、この場合には、アミノ酸は原料醤油由来のものも含み、上記範囲に満たない場合には酸性アミノ酸、又は塩基性アミノ酸塩等を別添することが好ましい。なお、本発明にいう「酸性アミノ酸、塩基性アミノ酸」は、遊離(フリー)のアミノ酸又はアミノ酸塩の状態のものを指すが、本発明に規定する含有量は、遊離のアミノ酸に換算した値をいう。   In the liquid seasoning of this invention, it is preferable to add the substance containing nitrogen other than a component (C) as a method of raising nitrogen content. Among nitrogen-containing substances, amino acids, particularly acidic amino acids and basic amino acids are preferred from the viewpoint of enhancing salty taste and sustainability. The content in the liquid seasoning is preferably such that the acidic amino acid exceeds 2% by mass and / or the basic amino acid exceeds 1% by mass. Further, the acidic amino acid is preferably more than 2% by mass and not more than 5% by mass, more preferably 2.4 to 4.5% by mass, particularly preferably 2.5 to 3.8% by mass from the viewpoint of the persistence of salty taste. It is preferable from the viewpoint of the persistence of salty taste that the amino acid content is more than 1% by mass and 3% by mass or less, further 1.2 to 2.5% by mass, particularly 1.5 to 2% by mass. In addition, the liquid seasoning of the present invention is preferably based on a brewing seasoning from the viewpoint of the sustainability of salty taste, flavor, etc.In this case, the amino acids include those derived from raw material soy sauce, and in the above range When it is less, it is preferable to attach an acidic amino acid or a basic amino acid salt. The “acidic amino acid, basic amino acid” referred to in the present invention refers to a free (free) amino acid or amino acid salt, but the content defined in the present invention is a value converted to a free amino acid. Say.

また、本発明の液体調味料においては、酸性アミノ酸、塩基性アミノ酸の中でも酸性アミノ酸であるアスパラギン酸、グルタミン酸が塩味の持続性の点から好ましく、更に、アスパラギン酸とグルタミン酸を併用することが、塩味の持続性の点から好ましい。この場合、アスパラギン酸の含有量は1〜3質量%が好ましく、更に1.2〜2.5質量%、特に1.2〜2質量%であることが、塩味の持続性の点から好ましい。アスパラギン酸は、醸造調味料をベースとした場合には原料由来のものも含み、上記範囲に満たない場合にはL−アスパラギン酸、L−アスパラギン酸ナトリウム等を別添することが好ましい。また、グルタミン酸の含有量は1〜2質量%が好ましく、更に1.2〜2質量%、特に1.3〜1.8質量%であることが、塩味の持続性の点から好ましい。グルタミン酸は、醸造調味料をベースとした場合には原料由来のものも含み、上記範囲に満たない場合にはL−グルタミン酸、L−グルタミン酸ナトリウム等を別添することが好ましい。   In the liquid seasoning of the present invention, among the acidic amino acids and basic amino acids, aspartic acid and glutamic acid, which are acidic amino acids, are preferable from the standpoint of the persistence of salty taste, and it is further preferable to use aspartic acid and glutamic acid in combination. From the standpoint of sustainability. In this case, the content of aspartic acid is preferably 1 to 3% by mass, more preferably 1.2 to 2.5% by mass, and particularly preferably 1.2 to 2% by mass, from the viewpoint of sustaining salty taste. When aspartic acid is based on a brewing seasoning, it also includes those derived from raw materials. When it is less than the above range, it is preferable to add L-aspartic acid, sodium L-aspartate and the like. In addition, the content of glutamic acid is preferably 1 to 2% by mass, more preferably 1.2 to 2% by mass, and particularly preferably 1.3 to 1.8% by mass from the viewpoint of salty persistence. When glutamic acid is based on a brewing seasoning, it includes those derived from raw materials, and when it is less than the above range, L-glutamic acid, sodium L-glutamate and the like are preferably added.

塩基性アミノ酸は、リジン、アルギニン、ヒスチジン、及びオルニチンが挙げられるが、中でもリジン、ヒスチジンが好ましく、特にヒスチジンが好ましい。リジンの含有量は0.5〜1質量%であることが塩味の刺激感の点で好ましく、ヒスチジンの含有量は0.2〜2質量%、更に0.5〜1質量%であることが、塩味の増強及び持続性の点から好ましい。これらの塩基性アミノ酸も醸造調味料をベースとした場合には原料由来のものも含み、上記範囲に満たない場合には、別添することが好ましい。   Examples of basic amino acids include lysine, arginine, histidine, and ornithine. Among them, lysine and histidine are preferable, and histidine is particularly preferable. The content of lysine is preferably 0.5 to 1% by mass from the viewpoint of salty irritation, and the content of histidine is 0.2 to 2% by mass, more preferably 0.5 to 1% by mass. From the viewpoint of enhancement of salty taste and sustainability. When these basic amino acids are also based on brewing seasonings, they also include those derived from raw materials.

本発明の液体調味料においては、特にアスパラギン酸/(B)カリウムの質量比が0.25以上であることが好ましく、更に0.3以上、特に0.46以上、殊更0.5以上であることが、塩化カリウム由来の苦味を消失させる点から好ましい。   In the liquid seasoning of the present invention, the mass ratio of aspartic acid / (B) potassium is preferably 0.25 or more, more preferably 0.3 or more, particularly 0.46 or more, and particularly 0.5 or more. It is preferable from the point of eliminating the bitter taste derived from potassium chloride.

また、本発明の液体調味料においては、成分(C)を除いた部分の液体調味料中のアスパラギン酸/(D)窒素の含有量の質量比を0.5以上とすることが好ましい。当該質量比は、更に0.6以上、特に0.7以上であることが塩味を強くし、シャープさを向上させる点から好ましい。   Moreover, in the liquid seasoning of this invention, it is preferable to make mass ratio of content of aspartic acid / (D) nitrogen in the liquid seasoning of the part except a component (C) into 0.5 or more. The mass ratio is preferably 0.6 or more, particularly 0.7 or more from the viewpoint of enhancing the saltiness and improving the sharpness.

本発明の液体調味料の(C)風味改良剤としては、核酸系呈味物質、フィチン酸、クエン酸又はその塩、無機酸塩、甘味料、蛋白質及び乳清ミネラルから選択される1種又は2種以上の物質を用いる。   As the (C) flavor improver of the liquid seasoning of the present invention, one or more selected from nucleic acid-based taste substances, phytic acid, citric acid or salts thereof, inorganic acid salts, sweeteners, proteins and whey minerals Use two or more substances.

核酸系呈味物質としては、5'−イノシン酸、グアニル酸、5'−リボヌクレオチド、ウリジル酸、アデニル酸並びにこれらのナトリウム塩等、酵母エキス等が挙げられ、これらの1種又は2種以上を用いることができる。これらは、本発明の液体調味料中に0.005〜0.2質量%、好ましくは0.01〜0.1質量%含有されることが、塩味の増強、また異味、苦味の低減等、醤油の風味を向上させる点から好ましい。   Examples of nucleic acid-based taste substances include 5'-inosinic acid, guanylic acid, 5'-ribonucleotide, uridylic acid, adenylic acid, and sodium salts thereof, yeast extracts, and the like, one or more of these. Can be used. These may be contained in the liquid seasoning of the present invention in an amount of 0.005 to 0.2% by mass, preferably 0.01 to 0.1% by mass, enhancing salty taste, reducing taste, bitterness, etc. It is preferable from the point of improving the flavor of soy sauce.

クエン酸又はその塩としては、クエン酸一ナトリウム、クエン酸二ナトリウム、クエン酸三ナトリウム、クエン一酸カリウム、クエン酸二カリウム、クエン酸三カリウム、クエン酸カルシウム、並びにイソクエン酸又はその塩等が挙げられ、これらの1種又は2種以上を用いることができる。これらは、本発明の液体調味料中にクエン酸として0.5〜2質量%、好ましくは0.7〜1.5質量%含有されることが、塩味の増強、また異味、苦味の低減等、醤油の風味を向上させる点から好ましい。   Citric acid or a salt thereof includes monosodium citrate, disodium citrate, trisodium citrate, potassium citrate, dipotassium citrate, tripotassium citrate, calcium citrate, and isocitric acid or a salt thereof. 1 type or 2 types or more can be used. These are contained in the liquid seasoning of the present invention in an amount of 0.5 to 2% by mass, preferably 0.7 to 1.5% by mass as citric acid. From the point of improving the flavor of soy sauce.

無機酸塩としては、塩化カルシウム、塩化マグネシウム、硫酸ナトリウム、硫酸第一鉄、硫酸マグネシウム、カリウムミョウバン塩等が挙げられ、これらの1種又は2種以上を用いることができる。これらは、本発明の液体調味料中に0.1〜5質量%、好ましくは0.2〜2質量%含有されることが、塩味の増強、また異味、苦味の低減等、醤油の風味を向上させる点から好ましい。   Examples of inorganic acid salts include calcium chloride, magnesium chloride, sodium sulfate, ferrous sulfate, magnesium sulfate, potassium alum salt, and the like, and one or more of these can be used. These are contained in the liquid seasoning of the present invention in an amount of 0.1 to 5% by mass, preferably 0.2 to 2% by mass, to enhance the salty taste and to reduce the taste and bitterness of the soy sauce. It is preferable from the point of improving.

甘味料としては、果糖、ブドウ糖、トレハロース、甘草エキス、糖アルコール(ソルビトール、マンニトール、マルチトール、還元パラチノース、キシリトール等)、グリチルリチン酸ナトリウム、ステビア抽出物等が挙げられ、これらの1種又は2種以上を用いることができる。ステビア抽出物、甘草エキス、グリチルリチン酸ナトリウムは、本発明の液体調味料中に0.0001〜0.1質量%、好ましくは0.0005〜0.01質量%含有されることが、塩味の増強、また異味、苦味の低減等、醤油の風味を向上させる点から好ましい。その他の甘味料は、本発明の液体調味料中に0.1〜2質量%、好ましくは0.2〜1質量%含有されることが、塩味の増強、また異味、苦味の低減等、醤油の風味を向上させる点から好ましい。   Examples of the sweetener include fructose, glucose, trehalose, licorice extract, sugar alcohol (sorbitol, mannitol, maltitol, reduced palatinose, xylitol, etc.), sodium glycyrrhizinate, stevia extract, etc., and one or two of these The above can be used. Stevia extract, licorice extract, and sodium glycyrrhizinate are contained in the liquid seasoning of the present invention in an amount of 0.0001 to 0.1% by mass, preferably 0.0005 to 0.01% by mass to enhance salty taste. Moreover, it is preferable from the point of improving the flavor of soy sauce, such as reduction of off-taste and bitterness. Other sweeteners may be contained in the liquid seasoning of the present invention in an amount of 0.1 to 2% by mass, preferably 0.2 to 1% by mass, soy sauce for enhancing salty taste, reducing off taste and bitterness, etc. It is preferable from the point of improving the flavor.

蛋白質としては、ゼラチン等水溶性のものが挙げられ、1種又は2種以上を用いることができる。これらは、本発明の液体調味料中に0.1〜2質量%、好ましくは0.2〜1質量%含有されることが、塩味の増強、また異味、苦味の低減等、醤油の風味を向上させる点から好ましい。
フィチン酸は、本発明の液体調味料中に0.1〜2質量%、好ましくは0.2〜1質量含有されることが、塩味の増強、また異味、苦味の低減等、醤油の風味を向上させる点から好ましい。
乳清ミネラルは、本発明の液体調味料中に0.1〜5質量%、好ましくは0.2〜2質量%含有されることが、塩味の増強、また異味、苦味の低減等、醤油の風味を向上させる点から好ましい。
Examples of the protein include water-soluble proteins such as gelatin, and one or more can be used. These are contained in the liquid seasoning of the present invention in an amount of 0.1 to 2% by mass, preferably 0.2 to 1% by mass, to enhance the salty taste and to reduce the taste and bitterness of the soy sauce. It is preferable from the point of improving.
When phytic acid is contained in the liquid seasoning of the present invention in an amount of 0.1 to 2% by mass, preferably 0.2 to 1%, the salty taste is enhanced, and the flavor of soy sauce is reduced, such as reduction in taste and bitterness. It is preferable from the point of improving.
The whey mineral is contained in the liquid seasoning of the present invention in an amount of 0.1 to 5% by mass, preferably 0.2 to 2% by mass. It is preferable from the point of improving the flavor.

更に、本発明の液体調味料においては、更に、(E)前記アミノ酸以外のアミノ酸系調味料、フィチン酸、クエン酸及びその塩を除く有機酸塩系調味料及び酸味料等を含有することが塩味の増強、また異味、苦味の低減等、醤油の風味を向上させる点から好ましい。   Furthermore, the liquid seasoning of the present invention may further contain (E) an amino acid seasoning other than the amino acid, an organic acid salt seasoning excluding phytic acid, citric acid and salts thereof, an acidulant and the like. It is preferable from the viewpoint of improving the flavor of soy sauce, such as enhancement of salty taste and reduction of off-taste and bitterness.

アミノ酸系調味料としては酸性アミノ酸、塩基性アミノ酸、及びこれらの塩以外のもの、例えば、グリシン、アラニン、フェニルアラニン、シスチン、スレオニン、チロシン、イソロイシン、あるいはこれらのナトリウム塩又はカリウム塩等が挙げられ、これらを1種又は2種以上配合することができる。配合後のアミノ酸系調味料の本発明の液体調味料中の含有量は、それぞれ遊離のアミノ酸に換算した場合、グリシンは0.3質量%超、アラニンは0.7質量%超、フェニルアラニンは0.5質量%超、シスチンは質量%超、スレオニンは0質量%超、チロシンは0.2質量%超、イソロイシンは0.5質量%超であり、かつそれぞれ上限は1.5質量%以下が好ましい。中でもイソロイシンが塩味の持続性の点で好ましく、含有量は0.5質量%超1質量%以下であることが好ましい。   Examples of amino acid seasonings include acidic amino acids, basic amino acids, and salts other than these salts, such as glycine, alanine, phenylalanine, cystine, threonine, tyrosine, isoleucine, or sodium or potassium salts thereof. One or more of these can be blended. The content of the amino acid seasoning after blending in the liquid seasoning of the present invention, when converted to free amino acids, glycine exceeds 0.3% by mass, alanine exceeds 0.7% by mass, and phenylalanine is 0%. .5% by mass, cystine is more than mass%, threonine is more than 0% by mass, tyrosine is more than 0.2% by mass, isoleucine is more than 0.5% by mass, and each upper limit is 1.5% by mass or less. preferable. Of these, isoleucine is preferable from the viewpoint of salty sustainability, and the content is preferably more than 0.5% by mass and 1% by mass or less.

有機酸塩系調味料としては乳酸、コハク酸、リンゴ酸、酒石酸、グルコン酸等の有機酸のナトリウム塩、カリウム塩等が挙げられる。特にコハク酸二ナトリウム、グルコン酸ナトリウムが好ましい。これらの本発明の液体調味料中の含有量は、遊離のアミノ酸に換算した場合、0.005〜0.2質量%が好ましく、0.01〜0.1質量%が特に好ましい。   Examples of the organic acid salt seasoning include sodium salts and potassium salts of organic acids such as lactic acid, succinic acid, malic acid, tartaric acid and gluconic acid. In particular, disodium succinate and sodium gluconate are preferable. The content in the liquid seasoning of the present invention is preferably 0.005 to 0.2% by mass, particularly preferably 0.01 to 0.1% by mass when converted to a free amino acid.

酸味料としては、乳酸、コハク酸、リンゴ酸、酒石酸等が挙げられる。中でも乳酸、コハク酸、リンゴ酸が好ましく、特に乳酸が好ましい。本発明の液体調味料中の含有量は、それぞれ遊離の酸に換算した場合、乳酸の含有量は0.9〜3質量%、更に1.3〜3質量%、特に1.5〜2.5質量%、コハク酸は0.004〜2質量%、更に0.06〜1.5質量%、特に0.1〜1質量%、リンゴ酸は0.05〜2質量%、更に0.1〜1.5質量%含有することが、塩味の増強、また異味、苦味の低減等、醤油の風味を向上させる点から好ましい。   Examples of the acidulant include lactic acid, succinic acid, malic acid, tartaric acid and the like. Of these, lactic acid, succinic acid, and malic acid are preferable, and lactic acid is particularly preferable. When the content in the liquid seasoning of the present invention is converted into a free acid, the content of lactic acid is 0.9 to 3% by mass, further 1.3 to 3% by mass, particularly 1.5 to 2.%. 5% by mass, succinic acid is 0.004 to 2% by mass, further 0.06 to 1.5% by mass, especially 0.1 to 1% by mass, malic acid is 0.05 to 2% by mass, and further 0.1 It is preferable to contain -1.5 mass% from the point which improves the flavor of soy sauce, such as an increase in salty taste, and a reduction in off-taste and bitterness.

また、本発明の液体調味料においては、pHが3〜6.5、更に4〜6、特に4.5〜5.5であることが、風味が劣化しない点から好ましい。更に、塩素量4〜9質量%、固形分量20〜45質量%の特数値を有することが好ましい。   Moreover, in the liquid seasoning of this invention, it is preferable that pH is 3-6.5, Furthermore, 4-6, especially 4.5-5.5 from the point which a flavor does not deteriorate. Furthermore, it is preferable to have a special value of 4 to 9% by mass of chlorine and 20 to 45% by mass of solid content.

また、本発明の液体調味料には、好み等に応じてエタノール、みりん、醸造酢等を添加することができ、つゆ、たれ等、種々の醤油加工品に応用できる。   In addition, ethanol, mirin, brewed vinegar and the like can be added to the liquid seasoning of the present invention according to taste and the like, and can be applied to various soy sauce processed products such as soy sauce and sauce.

(1)試験品1及び2の調製法
減塩醤油Bをベース醤油として、それぞれ塩化カリウム、L−アスパラギン酸ナトリウム、L−グルタミン酸ナトリウム、各種風味改良剤を添加し、表1及び2に示す配合量とした。
(1) Preparation methods of test products 1 and 2 Using reduced salt soy sauce B as base soy sauce, potassium chloride, sodium L-aspartate, sodium L-glutamate, and various flavor improvers were added, and the formulations shown in Tables 1 and 2 The amount.

(2)食塩含有量の測定法
食塩の含有量はナトリウム含有量を測定し、これを食塩の含有量に換算することにより求めた。ナトリウム含有量は原子吸光光度計(Z−6100形日立偏光ゼーマン原子吸光光度計)により測定した。
(2) Method for measuring salt content The salt content was determined by measuring the sodium content and converting it to the salt content. The sodium content was measured by an atomic absorption photometer (Z-6100 type Hitachi Polarized Zeeman atomic absorption photometer).

(3)カリウム及び塩化カリウム含有量の測定法
カリウムの含有量は上述のナトリウム含有量測定のものと同じもので測定した。
(3) Measuring method of potassium and potassium chloride content Potassium content was measured by the same thing as the above-mentioned sodium content measurement.

(4)窒素含有量の測定法
窒素濃度は全窒素分析装置(三菱化成TN−05型)により測定した。
(4) Measuring method of nitrogen content Nitrogen concentration was measured with a total nitrogen analyzer (Mitsubishi Kasei TN-05 type).

(5)アミノ酸含有量の測定法
全系中のアミノ酸含有量は、アミノ酸分析計(日立L−8800)により測定した。
(5) Measuring method of amino acid content The amino acid content in the whole system was measured with an amino acid analyzer (Hitachi L-8800).

(6)評価方法
得られた液体調味料について、パネラー20名による2点識別試験法で塩味及び苦みを官能評価した。また、醤油としての風味の好ましさを総合評価として行った。なお、対照品はベース醤油Aとした。総合評価は、下記の基準により行った。得られた結果を表1に示す。
(6) Evaluation method The obtained liquid seasoning was subjected to sensory evaluation of saltiness and bitterness by a two-point identification test method by 20 panelists. Moreover, the taste of the flavor as soy sauce was evaluated as a comprehensive evaluation. The control product was base soy sauce A. Comprehensive evaluation was performed according to the following criteria. The obtained results are shown in Table 1.

〔総合評価の判断基準〕
5:非常に好ましい塩味を持ち、かつ、味の調和に優れている。
4:非常に好ましい塩味を持ち、味の調和がとれている。
3:良好な塩味を持ち、味の調和がとれている。
2:味の調和に若干欠ける。
1:味の調和に欠け、苦味や異味を感じる。
[Judgment criteria for comprehensive evaluation]
5: It has a very favorable salty taste and excellent in harmony of taste.
4: Has a very favorable salty taste and harmonious taste.
3: Has a good salty taste and harmonious taste.
2: Slightly lacking in harmony of taste.
1: Lack of harmony in taste, and bitterness and nasty taste.

表1に示すように、減塩醤油Bに風味改良剤である5'−イノシン酸二ナトリウムを0〜2%の範囲で添加した。この場合、塩化カリウムを4質量%となるように配合した。その結果、5'−イノシン酸二ナトリウムの配合量が0.005〜0.2質量%の範囲で良好な塩味が得られ、さらに0.01〜0.1質量%の範囲で良好な塩味が得られた(試験品1−1〜8)。
また、減塩醤油Bに5'−イノシン酸二ナトリウムを添加した系において、塩化カリウム含有量を変化させた。この場合、5'−イノシン酸二ナトリウムは0.05質量%となるように配合した。その結果、液体調味料中に塩化カリウムを1〜7質量%の範囲で添加した場合に良好な塩味が得られ、さらに、2〜6質量%の範囲、特に3〜5質量%の範囲で非常に良好な塩味が得られた(試験品1−9〜17)。
また、減塩醤油Bに5'−イノシン酸二ナトリウム0.05%及び塩化カリウム4質量%を配合し、さらにL−アスパラギン酸ナトリウム1質量%及びL-グルタミン酸ナトリウム0.5質量%を添加した系では、より塩味が強く、好ましい風味となった(試験品1−18)。
As shown in Table 1, 5′-inosinate disodium as a flavor improver was added to the reduced salt soy sauce B in a range of 0 to 2%. In this case, potassium chloride was blended so as to be 4% by mass. As a result, good salty taste is obtained when the blending amount of disodium 5′-inosinate is in the range of 0.005 to 0.2% by mass, and good salty taste is obtained in the range of 0.01 to 0.1% by mass. Obtained (test products 1-1 to 8).
Further, in the system in which 5′-inosinate disodium was added to the reduced salt soy sauce B, the potassium chloride content was changed. In this case, disodium 5'-inosinate was blended so as to be 0.05% by mass. As a result, when potassium chloride is added to the liquid seasoning in the range of 1 to 7% by mass, a good salty taste is obtained, and further in the range of 2 to 6% by mass, particularly in the range of 3 to 5% by mass. In addition, a good salty taste was obtained (test products 1-9 to 17).
Moreover, 5'-inosinic acid disodium 0.05% and potassium chloride 4% by mass were added to the reduced salt soy sauce B, and further 1% by mass of sodium L-aspartate and 0.5% by mass of sodium L-glutamate were added. In the system, the salty taste was stronger and the flavor became preferable (test product 1-18).

表2に示すように、ベース醤油を減塩醤油Bとし、種々の風味改良剤を添加した。この場合、塩化カリウムを4質量%、L−アスパラギン酸ナトリウム1.0質量%、L−グルタミン酸ナトリウム0.5質量%となるように配合した。この結果、種々の風味改良剤の添加により、塩味が増強し、カリウムの苦味が抑制され、好ましい風味となった。   As shown in Table 2, the base soy sauce was reduced salt soy sauce B, and various flavor improvers were added. In this case, potassium chloride was blended so as to be 4% by mass, 1.0% by mass of sodium L-aspartate, and 0.5% by mass of sodium L-glutamate. As a result, by adding various flavor improvers, the salty taste was enhanced, the bitter taste of potassium was suppressed, and a favorable flavor was obtained.

Claims (6)

次の成分(A)〜(C):
(A)食塩9質量%以下、
(B)カリウム0.5〜4.2質量%、
(C)核酸系呈味物質、フィチン酸、クエン酸又はその塩、無機酸塩、甘味料、蛋白質及び乳清ミネラルから選択される1種又は2種以上の物質
を含有する液体調味料であって、成分(C)を除いた液体調味料の部分の(D)窒素の含有量が、成分(C)以外の物質により1.6質量%以上としたものである液体調味料。
The following components (A) to (C):
(A) salt 9 mass% or less,
(B) 0.5 to 4.2% by mass of potassium,
(C) A liquid seasoning containing one or more substances selected from nucleic acid-based taste substances, phytic acid, citric acid or salts thereof, inorganic acid salts, sweeteners, proteins and whey minerals. Then, the liquid seasoning in which the content of (D) nitrogen in the portion of the liquid seasoning excluding the component (C) is 1.6% by mass or more by a substance other than the component (C).
成分(C)を除いた部分の液体調味料中の(D)窒素の含有量を1.6質量%以上とするための、成分(C)以外の物質がアミノ酸を含むものである請求項1記載の液体調味料。   The substance other than the component (C) for making the content of (D) nitrogen in the portion of the liquid seasoning excluding the component (C) 1.6% by mass or more contains an amino acid. Liquid seasoning. 液体調味料中に酸性アミノ酸2質量%超、及び/又は塩基性アミノ酸1質量%超を含有するものである請求項1又は2に記載の液体調味料。   The liquid seasoning according to claim 1 or 2, wherein the liquid seasoning contains more than 2% by mass of acidic amino acids and / or more than 1% by mass of basic amino acids. 液体調味料中にアスパラギン酸を1〜3質量%、グルタミン酸を1〜2質量%含有し、かつアスパラギン酸/(B)カリウム≧0.25(質量比)である請求項1〜3のいずれか1項に記載の液体調味料。   The liquid seasoning contains aspartic acid in an amount of 1 to 3 mass%, glutamic acid in an amount of 1 to 2 mass%, and aspartic acid / (B) potassium ≧ 0.25 (mass ratio). Item 1. A liquid seasoning according to item 1. 成分(C)を除いた液体調味料の部分の、アスパラギン酸/(D)窒素≧0.5(質量%比)である請求項1〜4のいずれか1項に記載の液体調味料。   The liquid seasoning according to any one of claims 1 to 4, wherein aspartic acid / (D) nitrogen> 0.5 (mass% ratio) of the portion of the liquid seasoning excluding the component (C). 液体調味料が減塩醤油類である請求項1〜5のいずれか1項に記載の液体調味料。   The liquid seasoning is a reduced salt soy sauce, The liquid seasoning according to any one of claims 1 to 5.
JP2004332367A 2004-11-16 2004-11-16 Liquid seasoning Pending JP2006141224A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2326302A1 (en) * 2007-10-01 2009-10-06 Douglas Latorre Manrique Product for the salado of foods and device for your dispensation. (Machine-translation by Google Translate, not legally binding)
JP2013544104A (en) * 2010-11-30 2013-12-12 ジボダン エス エー Organic compounds
US9095163B2 (en) 2009-07-15 2015-08-04 Kao Corporation Packed soy sauce-containing liquid seasoning

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2326302A1 (en) * 2007-10-01 2009-10-06 Douglas Latorre Manrique Product for the salado of foods and device for your dispensation. (Machine-translation by Google Translate, not legally binding)
US9095163B2 (en) 2009-07-15 2015-08-04 Kao Corporation Packed soy sauce-containing liquid seasoning
JP2013544104A (en) * 2010-11-30 2013-12-12 ジボダン エス エー Organic compounds

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