JP2006137704A - Infrared-reflecting powder and use thereof - Google Patents
Infrared-reflecting powder and use thereof Download PDFInfo
- Publication number
- JP2006137704A JP2006137704A JP2004328857A JP2004328857A JP2006137704A JP 2006137704 A JP2006137704 A JP 2006137704A JP 2004328857 A JP2004328857 A JP 2004328857A JP 2004328857 A JP2004328857 A JP 2004328857A JP 2006137704 A JP2006137704 A JP 2006137704A
- Authority
- JP
- Japan
- Prior art keywords
- powder
- infrared
- metal oxide
- coated
- hollow resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 150000004706 metal oxides Chemical class 0.000 claims abstract description 26
- 229920005989 resin Polymers 0.000 claims abstract description 26
- 239000011347 resin Substances 0.000 claims abstract description 26
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 11
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- 239000002537 cosmetic Substances 0.000 claims description 32
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- 230000000694 effects Effects 0.000 description 11
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Landscapes
- Cosmetics (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
Description
本発明は、赤外線を反射し、赤外線からの防護材料に有用な粉体と、その用途に関する。 The present invention relates to a powder that reflects infrared rays and is useful as a protective material from infrared rays, and uses thereof.
可視光よりも短波長側の可視光近傍の光線である、紫外線は、皮膚にとって悪影響を及ぼすことが既に遍く知られており、その対策も種々考案されている。可視光線近傍の光線であって、紫外線と対極に位置する赤外線は、別名熱線と称されており、物体に良く吸収され物体内部で熱エネルギーへと効率よく変換される。赤外線は太陽光の内の８０％を占めている。赤外線は、紫外線や可視光線に比べて、大気中の微粒子で反射したり、散乱を起こすことが少なく、大気中の酸素や窒素などの分子に邪魔されずに空気中を良く透過し、地上へと到達する。赤外線を分類すると４０００nmを境にして、短波長側を近赤外線と呼び、長波長側を遠赤外線と呼ぶ。近赤外線に比べて、遠赤外線の方が吸収作用が大きく、熱の運搬役として色々な役割を果たす。赤外線の皮膚に対する作用としては、前記の熱エネルギーへの変換により、温感を呈することが知られているが、近年に於いては、紫外線とともに、皮膚の老化、或いは、光による発ガンに関与していることが示唆されている。この様に、赤外線が皮膚に対して悪影響を及ぼす可能性が存することは、つい近年知られるようになったことであるので、その対策については僅かにしか知られていない。例えば、銀被覆粉体やステンレスなどの金属粉末、該金属粉末でタルクなどの粉体を被覆した粉体などが知られている。（例えば、特許文献１、特許文献２、特許文献３、特許文献４を参照）しかしながら、金属粉末は、接触アレルギー、電解質との接触による部分電池の形成とそれによる金属イオンの溶出と言った問題が存し、安全性或いは安定性の面で使用しにくい場合が存した。即ち、金属そのままのように、種々の反応性を有する材料とは異なり、物理化学的に安定な赤外線防護用の材料の開発が望まれていたと言える。 It is already known that ultraviolet rays, which are light rays in the vicinity of visible light shorter than visible light, have an adverse effect on the skin, and various countermeasures have been devised. Light rays in the vicinity of visible light rays and infrared rays positioned opposite to ultraviolet rays are also called heat rays, and are well absorbed by the object and efficiently converted into heat energy inside the object. Infrared radiation accounts for 80% of sunlight. Infrared rays are less likely to be reflected or scattered by fine particles in the atmosphere than ultraviolet rays and visible rays, and penetrate well into the air without being obstructed by molecules such as oxygen and nitrogen in the atmosphere. And reach. When the infrared rays are classified, the short wavelength side is called near infrared ray and the long wavelength side is called far infrared ray with 4000 nm as a boundary. Compared with near infrared rays, far infrared rays have a larger absorbing action and play various roles as heat transporters. As an effect of infrared rays on the skin, it is known to exhibit a warm feeling due to the conversion to the thermal energy described above, but in recent years, it is involved in skin aging or light-induced carcinogenesis with ultraviolet rays. It is suggested that As described above, since the possibility that infrared rays have an adverse effect on the skin exists in recent years, only a few countermeasures are known. For example, a silver-coated powder, a metal powder such as stainless steel, and a powder obtained by coating a powder such as talc with the metal powder are known. (For example, see Patent Document 1, Patent Document 2, Patent Document 3, and Patent Document 4) However, metal powder has problems such as contact allergy, formation of a partial battery by contact with an electrolyte, and elution of metal ions by the contact. There were cases where it was difficult to use in terms of safety or stability. That is, it can be said that development of a material for infrared protection that is physicochemically stable is desired, unlike a material having various reactivity such as a metal as it is.
一方、金属酸化物で被覆されていても良い、中空樹脂球状粉体は既に化粧料用の原料として知られており、市販もされている。（例えば、特許文献５を参照）しかしながら、赤外線を効率よく反射する作用を有することは全く知られていなかったし、赤外線からの防護の目的でかかる粉体を利用することも、かかる粉体を含有した赤外線からの防護用の化粧料も全く知られていなかった。 On the other hand, hollow resin spherical powder, which may be coated with a metal oxide, is already known as a raw material for cosmetics and is also commercially available. However, it has not been known at all to have an effect of efficiently reflecting infrared rays, and such powders can be used for the purpose of protection from infrared rays. The contained infrared protective cosmetics were not known at all.
本発明は、この様な状況下為されたものであり、物理化学的に安定な赤外線防護用の材料を提供することを課題とする。 The present invention has been made under such circumstances, and an object of the present invention is to provide a physicochemically stable material for infrared protection.
本発明者らは、この様な状況に鑑みて、物理化学的に安定な赤外線防護用の材料を求めて、鋭意研究努力を重ねた結果、金属酸化物で被覆されていても良い、中空樹脂球状粉体がその様な特性を有していることを見出し、発明を完成させるに至った。即ち、本発明は以下に示すとおりである。
（１）金属酸化物で被覆されていても良い、中空樹脂球状粉体からなる、赤外線反射用粉体。
（２）前記金属酸化物で被覆されていても良い、中空樹脂球状粉体において、中空樹脂球状粉体の主成分がポリアクリロニトリルであることを特徴とする、（１）に記載の赤外線反射用粉体。
（３）前記金属酸化物で被覆されていても良い、中空樹脂球状粉体において、被覆に金属酸化物として、二酸化チタンを用いることを特徴とする、（１）又は（２）に記載の赤外線反射用粉体。
（４）平均粒径が１０〜３０μｍであることを特徴とする、（１）〜（３）何れか１項に記載の赤外線反射用粉体。
（５）（１）〜（４）何れか１項に記載の赤外線反射用粉体を含有する化粧料。
（６）赤外線からの防護用であることを特徴とする、（６）に記載の化粧料。
（７）金属酸化物で被覆されていても良い、中空樹脂球状粉体を含有することを特徴とする、赤外線からの防護用の化粧料。
（８）前記金属酸化物で被覆されていても良い、中空樹脂球状粉体において、中空樹脂球状粉体の主成分がポリアクリロニトリルであることを特徴とする、（７）に記載の赤外線からの防護用の化粧料。
（９）前記金属酸化物で被覆されていても良い、中空樹脂球状粉体において、被覆に金属酸化物として、二酸化チタンを用いることを特徴とする、（７）又は（８）に記載の赤外線からの防護用の化粧料。
（１０）平均粒径が１０〜３０μｍであることを特徴とする、（７）〜（９）何れか１項に記載の赤外線からの防護用の化粧料。
In view of such circumstances, the present inventors have sought for a physicochemically stable material for infrared protection, and as a result of earnest research efforts, the hollow resin may be coated with a metal oxide. The inventors have found that spherical powder has such characteristics and have completed the invention. That is, the present invention is as follows.
(1) An infrared reflecting powder made of a hollow resin spherical powder which may be coated with a metal oxide.
(2) In the hollow resin spherical powder which may be coated with the metal oxide, the main component of the hollow resin spherical powder is polyacrylonitrile, (1) for infrared reflection powder.
(3) The infrared ray according to (1) or (2), wherein the hollow resin spherical powder which may be coated with the metal oxide uses titanium dioxide as the metal oxide for the coating. Reflective powder.
(4) The infrared reflective powder according to any one of (1) to (3), wherein the average particle size is 10 to 30 μm.
(5) A cosmetic containing the powder for infrared reflection according to any one of (1) to (4).
(6) The cosmetic according to (6), which is used for protection from infrared rays.
(7) A cosmetic material for protection from infrared rays, characterized by containing a hollow resin spherical powder which may be coated with a metal oxide.
(8) In the hollow resin spherical powder, which may be coated with the metal oxide, the main component of the hollow resin spherical powder is polyacrylonitrile. Protective cosmetics.
(9) The infrared ray according to (7) or (8), wherein in the hollow resin spherical powder which may be coated with the metal oxide, titanium dioxide is used as the metal oxide for the coating. Cosmetics for protection from.
(10) The cosmetic for protecting against infrared rays according to any one of (7) to (9), wherein the average particle size is 10 to 30 μm.
本発明のよれば、物理化学的に安定な赤外線防護用の材料を提供することができる。 ADVANTAGE OF THE INVENTION According to this invention, the material for infrared protection which is physicochemically stable can be provided.
（１）本発明の赤外線反射用粉体
本発明の赤外線反射用粉体は、金属酸化物で被覆されていても良い、中空樹脂球状粉体からなることを特徴とする。かかる粉体の基体となる、中空樹脂球状粉体としては、例えば、塩化ビニル，酢酸ビニル，メチルビニルエーテル等のビニル系モノマー、アクリル酸，アクリル酸エステル，メタクリル酸，メタクリル酸エステル，アクリロニトリル，メタクリロニトリル等のアクリル系モノマー、スチレン、塩化ビニリデン、ジビニルベンゼン、エチレングリコールジメタクリレート等から選択される一種以上のモノマーを重合して得られるホモポリマー又はコポリマーが挙げられ、これらより一種又は二種以上用いることができる。これらの中でも、アクリル酸、メタクリル酸あるいはそのエステル類、アクリロニトリル、塩化ビニリデン、メタクリロニトリル等から選ばれるモノマーの一種乃至は二種以上を重合してなるポリマー又はコポリマーであることが好ましい。更に、このような重合体は、ジビニルベンゼン、エチレングリコールジメタクリレート、トリアクリルフォルマール等の架橋剤で架橋されていても良い。かかる基体中に中空を設ける方法としては、コアセルベーション法によるセル構造の構築を利用する方法（例えば、特許文献６を参照）や、例えば、エタン、プロパン、ブタン、イソブタン、イソブテン、イソペンタン、ネオペンタン、ネオヘキサン、アセチレン、ヘキサン、ヘプタン等の炭化水素、トリクロロフルオロメタン、ジクロロジフルオロメタン等のハロゲン化炭化水素、テトラアルキルシラン等の低沸点化合物等の揮発性を有する液体を発泡剤として、熱可塑性ポリマーに内包させて、加熱し、発泡剤を気化させて中空を構築する方法等既に知られている方法に準じて製造することが出来る。（例えば、特許文献７を参照）かくして製造された中空球状樹脂粉体に於ける、中空の形態は、製造条件により異なってくる場合が存するが、本発明の赤外線を反射する効果においては、かかる形態の影響は少ないので形態は限定されない。この様な形態としては、唯１個の中空のみ存在する形態、多数の小泡が多孔質状に存在する形態、これらの中間的形態などが例示できる。かくして得られた、中空球状の樹脂粉体は、所望により、金属酸化物などを被覆することが出来る。かかる金属酸化物としては、例えば、タルク、セリサイト、マイカ、二酸化チタン、酸化亜鉛、酸化鉄、酸化セリウム、酸化ジルコニウム、シリカ等が挙げられる。特に好ましいものはタルク、二酸化チタン、酸化セリウムであり、中でも二酸化チタンが特に好ましい。かかる金属酸化物による被覆は、常法に従って行えばよい。（例えば、特許文献８を参照）この様な被覆において、中空球状樹脂粉体と、無機酸化物の好ましい質量比は、５：９５〜６０：４０であり、より好ましくは１：９〜１：１である。かくして得られた、金属酸化物で被覆されていても良い、中空樹脂球状粉体は、その平均粒径を１０〜３０μｍに揃えることが好ましく、更に好ましくは１５〜２５μｍに揃えることである。これは、平均粒径が小さすぎると赤外線を反射する作用が低下する場合が存し、大きすぎると、光学効果が著しくなりすぎて、化粧効果を損なう場合存するからである。この様な粉体には既に市販されているものが存し、かかる市販品を購入して使用することも出来る。好ましい市販品としては、例えば、エクスパンセル（ＫＥＭＡＮＯＲＤＰＬＡＳＴ ＡＢ社製）、マツモトマイクロスフェアＦシリーズ、マツモトマイクロスフェアＭＦＬシリーズ（いずれも松本油脂製薬社製）等が好適に例示でき、中でもマツモトマイクロスフェアＭＦＬシリーズが好ましく、シリーズ中ではＭＦＬ８０ＧＴＡ（タルク被覆ポリアクリロニトリル中空球状粉体；平均粒径２０μｍ）、ＭＦＬ５０ＳＴＩ（シリカ・二酸化チタン被覆ポリアクリロニトリル中空球状粉体平均粒径２０μｍ）、ＭＦＬ３０ＳＴＩ（二酸化チタン被覆ポリアクリロニトリル中空球状粉体；平均粒径２０μｍ）が特に好ましく例示できる。本発明の赤外線反射用粉体は唯一種を含有することも出来るし、二種以上を組み合わせて含有することも出来る。後記本発明の赤外線防護用の化粧料には、かかる粉体を、総量で、化粧料全量に対し、１〜５０質量％含有させることが好ましく、２〜３０質量％含有させることがより好ましい。
(1) Infrared reflecting powder of the present invention The infrared reflecting powder of the present invention is characterized by comprising a hollow resin spherical powder which may be coated with a metal oxide. Examples of the hollow resin spherical powder used as the base of the powder include vinyl monomers such as vinyl chloride, vinyl acetate, and methyl vinyl ether, acrylic acid, acrylic ester, methacrylic acid, methacrylic ester, acrylonitrile, methacrylo Examples include homopolymers or copolymers obtained by polymerizing one or more monomers selected from acrylic monomers such as nitrile, styrene, vinylidene chloride, divinylbenzene, ethylene glycol dimethacrylate, and the like, and one or more of these are used. be able to. Among these, a polymer or copolymer obtained by polymerizing one or more monomers selected from acrylic acid, methacrylic acid or esters thereof, acrylonitrile, vinylidene chloride, methacrylonitrile and the like is preferable. Further, such a polymer may be cross-linked with a cross-linking agent such as divinylbenzene, ethylene glycol dimethacrylate, or triacryl formal. As a method of providing a hollow in such a substrate, a method utilizing the construction of a cell structure by a coacervation method (see, for example, Patent Document 6), for example, ethane, propane, butane, isobutane, isobutene, isopentane, neopentane, etc. Volatile liquids such as hydrocarbons such as neohexane, acetylene, hexane, heptane, halogenated hydrocarbons such as trichlorofluoromethane and dichlorodifluoromethane, low-boiling compounds such as tetraalkylsilane, etc. It can be produced according to a method already known, such as a method of encapsulating in a polymer, heating, and evaporating a foaming agent to construct a hollow. (See, for example, Patent Document 7) The hollow form of the hollow spherical resin powder produced in this way may vary depending on the production conditions, but the effect of reflecting infrared rays of the present invention is such. Since the influence of the form is small, the form is not limited. Examples of such a form include a form in which only one hollow is present, a form in which a large number of small bubbles are present in a porous state, and an intermediate form thereof. The hollow spherical resin powder thus obtained can be coated with a metal oxide or the like as desired. Examples of such metal oxides include talc, sericite, mica, titanium dioxide, zinc oxide, iron oxide, cerium oxide, zirconium oxide, and silica. Particularly preferred are talc, titanium dioxide, and cerium oxide, with titanium dioxide being particularly preferred. The coating with the metal oxide may be performed according to a conventional method. (For example, refer to Patent Document 8) In such a coating, a preferable mass ratio of the hollow spherical resin powder and the inorganic oxide is 5:95 to 60:40, more preferably 1: 9 to 1: 1. The hollow resin spherical powder that may be coated with the metal oxide thus obtained preferably has an average particle size of 10 to 30 μm, more preferably 15 to 25 μm. This is because if the average particle size is too small, the effect of reflecting infrared rays may be reduced, and if it is too large, the optical effect will be excessive and the cosmetic effect may be impaired. Such powders already exist on the market, and such commercial products can be purchased and used. Preferable examples of commercially available products include Expancel (manufactured by KEMANODPLAST AB), Matsumoto Microsphere F series, Matsumoto Microsphere MFL series (both manufactured by Matsumoto Yushi Seiyaku Co., Ltd.), and among others, Matsumoto Microsphere MFL. A series is preferable, and in the series, MFL80GTA (talc-coated polyacrylonitrile hollow spherical powder; average particle size 20 μm), MFL50STI (silica / titanium dioxide-coated polyacrylonitrile hollow spherical powder average particle size 20 μm), MFL30STI (titanium dioxide-coated polyacrylonitrile) A hollow spherical powder; an average particle diameter of 20 μm is particularly preferable. The infrared reflecting powder of the present invention can contain only one species or a combination of two or more species. In the infrared protective cosmetic of the present invention described later, the powder is preferably contained in an amount of 1 to 50% by mass, more preferably 2 to 30% by mass, based on the total amount of the cosmetic.
（２）本発明の化粧料
本発明の化粧料は、金属酸化物で被覆されていても良い、中空樹脂球状粉体を、赤外線反射用の目的含有することを特徴とする。従って、本発明の化粧料の用途は赤外線防護用であることが好ましい。赤外線防護用の化粧料とは、赤外線を反射させて皮膚に至らなくさせ、これにより紫外線との組合せ作用による老化促進から肌を守る作用、赤外線が皮膚にいたり、熱エネルギーに変換し、該熱エネルギーにより、熱感を皮膚が感じ、発汗などが促進されるのを防ぐ作用などの、直接的或いは間接的に赤外線が皮膚の生理に与える影響から皮膚を防護する作用の総称を意味する。本発明の化粧料に於いては、前記の必須成分以外に、通常化粧料で使用されている任意成分を含有することが出来る。この様な任意成分としては、例えば、マカデミアナッツ油、アボガド油、トウモロコシ油、オリーブ油、ナタネ油、ゴマ油、ヒマシ油、サフラワー油、綿実油、ホホバ油、ヤシ油、パーム油、液状ラノリン、硬化ヤシ油、硬化油、モクロウ、硬化ヒマシ油、ミツロウ、キャンデリラロウ、カルナウバロウ、イボタロウ、ラノリン、還元ラノリン、硬質ラノリン、ホホバロウ等のオイル、ワックス類、流動パラフィン、スクワラン、プリスタン、オゾケライト、パラフィン、セレシン、ワセリン、マイクロクリスタリンワックス等の炭化水素類、オレイン酸、イソステアリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸、ウンデシレン酸等の高級脂肪酸類、セチルアルコール、ステアリルアルコール、イソステアリルアルコール、ベヘニルアルコール、オクチルドデカノール、ミリスチルアルコール、セトステアリルアルコール等の高級アルコール等、イソオクタン酸セチル、ミリスチン酸イソプロピル、イソステアリン酸ヘキシルデシル、アジピン酸ジイソプロピル、セバチン酸ジ−２−エチルヘキシル、乳酸セチル、リンゴ酸ジイソステアリル、ジ−２−エチルヘキサン酸エチレングリコール、ジカプリン酸ネオペンチルグリコール、ジ−２−ヘプチルウンデカン酸グリセリン、トリ−２−エチルヘキサン酸グリセリン、トリ−２−エチルヘキサン酸トリメチロールプロパン、トリイソステアリン酸トリメチロールプロパン、テトラ−２−エチルヘキサン酸ペンタンエリトリット等の合成エステル油類、ジメチルポリシロキサン、メチルフェニルポリシロキサン、ジフェニルポリシロキサン等の鎖状ポリシロキサン、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサンシロキサン等の環状ポリシロキサン、アミノ変性ポリシロキサン、ポリエーテル変性ポリシロキサン、アルキル変性ポリシロキサン、フッ素変性ポリシロキサン等の変性ポリシロキサン等のシリコーン油等の油剤類、脂肪酸セッケン（ラウリン酸ナトリウム、パルミチン酸ナトリウム等）、ラウリル硫酸カリウム、アルキル硫酸トリエタノールアミンエーテル等のアニオン界面活性剤類、塩化ステアリルトリメチルアンモニウム、塩化ベンザルコニウム、ラウリルアミンオキサイド等のカチオン界面活性剤類、イミダゾリン系両性界面活性剤（２−ココイル−２−イミダゾリニウムヒドロキサイド−１−カルボキシエチロキシ２ナトリウム塩等）、ベタイン系界面活性剤（アルキルベタイン、アミドベタイン、スルホベタイン等）、アシルメチルタウリン等の両性界面活性剤類、ソルビタン脂肪酸エステル類（ソルビタンモノステアレート、セスキオレイン酸ソルビタン等）、グリセリン脂肪酸類（モノステアリン酸グリセリン等）、プロピレングリコール脂肪酸エステル類（モノステアリン酸プロピレングリコール等）、硬化ヒマシ油誘導体、グリセリンアルキルエーテル、ＰＯＥソルビタン脂肪酸エステル類（ＰＯＥソルビタンモノオレエート、モノステアリン酸ポリオキエチレンソルビタン等）、ＰＯＥソルビット脂肪酸エステル類（ＰＯＥ−ソルビットモノラウレート等）、ＰＯＥグリセリン脂肪酸エステル類（ＰＯＥ−グリセリンモノイソステアレート等）、ＰＯＥ脂肪酸エステル類（ポリエチレングリコールモノオレート、ＰＯＥジステアレート等）、ＰＯＥアルキルエーテル類（ＰＯＥ２−オクチルドデシルエーテル等）、ＰＯＥアルキルフェニルエーテル類（ＰＯＥノニルフェニルエーテル等）、プルロニック型類、ＰＯＥ・ＰＯＰアルキルエーテル類（ＰＯＥ・ＰＯＰ２−デシルテトラデシルエーテル等）、テトロニック類、ＰＯＥヒマシ油・硬化ヒマシ油誘導体（ＰＯＥヒマシ油、ＰＯＥ硬化ヒマシ油等）、ショ糖脂肪酸エステル、アルキルグルコシド等の非イオン界面活性剤類、ポリエチレングリコール、グリセリン、１，３−ブチレングリコール、エリスリトール、ソルビトール、キシリトール、マルチトール、プロピレングリコール、ジプロピレングリコール、ジグリセリン、イソプレングリコール、１，２−ペンタンジオール、２，４−ヘキシレングリコール、１，２−ヘキサンジオール、１，２−オクタンジオール等の多価アルコール類、ピロリドンカルボン酸ナトリウム、乳酸、乳酸ナトリウム等の保湿成分類、グアガム、クインスシード、カラギーナン、ガラクタン、アラビアガム、ペクチン、マンナン、デンプン、キサンタンガム、カードラン、メチルセルロース、ヒドロキシエチルセルロース、カルボキシメチルセルロース、メチルヒドロキシプロピルセルロース、コンドロイチン硫酸、デルマタン硫酸、グリコーゲン、ヘパラン硫酸、ヒアルロン酸、ヒアルロン酸ナトリウム、トラガントガム、ケラタン硫酸、コンドロイチン、ムコイチン硫酸、ヒドロキシエチルグアガム、カルボキシメチルグアガム、デキストラン、ケラト硫酸，ローカストビーンガム，サクシノグルカン，カロニン酸，キチン，キトサン、カルボキシメチルキチン、寒天、ポリビニルアルコール、ポリビニルピロリドン、カルボキシビニルポリマー、ポリアクリル酸ナトリウム、ポリエチレングリコール、ベントナイト等の増粘剤、表面を処理されていても良い、マイカ、タルク、カオリン、合成雲母、炭酸カルシウム、炭酸マグネシウム、無水ケイ酸（シリカ）、酸化アルミニウム、硫酸バリウム等の粉体類、表面を処理されていても良い、ベンガラ、黄酸化鉄、黒酸化鉄、酸化コバルト、群青、紺青、酸化チタン、酸化亜鉛の無機顔料類、表面を処理されていても良い、雲母チタン、魚燐箔、オキシ塩化ビスマス等のパール剤類、レーキ化されていても良い赤色２０２号、赤色２２８号、赤色２２６号、黄色４号、青色４０４号、黄色５号、赤色５０５号、赤色２３０号、赤色２２３号、橙色２０１号、赤色２１３号、黄色２０４号、黄色２０３号、青色１号、緑色２０１号、紫色２０１号、赤色２０４号等の有機色素類、ポリエチレン末、ポリメタクリル酸メチル、ナイロン粉末、オルガノポリシロキサンエラストマー等の有機粉体類、パラアミノ安息香酸系紫外線吸収剤、アントラニル酸系紫外線吸収剤、サリチル酸系紫外線吸収剤、桂皮酸系紫外線吸収剤、ベンゾフェノン系紫外線吸収剤、糖系紫外線吸収剤、２−（２’−ヒドロキシ−５’−ｔ−オクチルフェニル)ベンゾトリアゾール、４−メトキシ−４’−ｔ−ブチルジベンゾイルメタン等の紫外線吸収剤類、エタノール、イソプロパノール等の低級アルコール類、ビタミンＡ又はその誘導体、ビタミンＢ6塩酸塩，ビタミンＢ6トリパルミテート，ビタミンＢ6ジオクタノエート，ビタミンＢ2又はその誘導体，ビタミンＢ12，ビタミンＢ15又はその誘導体等のビタミンＢ類、α−トコフェロール，β−トコフェロール，γ−トコフェロール，ビタミンＥアセテート等のビタミンＥ類、ビタミンＤ類、ビタミンＨ、パントテン酸、パンテチン、ピロロキノリンキノン等のビタミン類などが好ましく例示できる。これらの中で、特に好ましい成分としては、表面を処理されていても良い、マイカ、タルク、カオリン、合成雲母、炭酸カルシウム、炭酸マグネシウム、無水ケイ酸（シリカ）、酸化アルミニウム、硫酸バリウム等の粉体類、表面を処理されていても良い、ベンガラ、黄酸化鉄、黒酸化鉄、酸化コバルト、群青、紺青の無機顔料類、表面を処理されていても良い、雲母チタン、魚燐箔、オキシ塩化ビスマス等のパール剤類が例示でき、中でもその表面を１〜１０質量％のパーフルオロアルキルシリル化して処理したものが特に好ましい。かかるパーフルオロアルキルシリル化処理した粉体の好ましい含有量は、総量で、化粧料全量に対して、３０〜７０質量％であり、より好ましくは、４０〜６０質量％である。又、本発明の化粧料では、紫外線と赤外線の組合せ効果による、皮膚への悪影響を防止或いは抑制することを目的としているので、紫外線を吸収するような成分、例えば、表面処理をされていても良い、酸化チタン或いは酸化亜鉛等が好ましく例示できる。特に好ましいものは、金属石鹸処理酸化チタン、シリカ、アルミナ、ジルコニア処理酸化チタンなどである。かかる成分は唯一種を含有することも出来るし、二種以上を組み合わせて含有させることも出来る。かかる成分の好ましい含有量は、総量で、化粧料全量に対して、１０〜８５質量％であり、より好ましくは２０〜８０質量％である。これらの必須成分及び任意成分を常法に従って処理することにより、本発明の化粧料は製造することが出来る。かくして得られた本発明の化粧料は、赤外線からの防護作用に優れるため、紫外線防護剤とともに夏の、紫外線量、赤外線量ともに多い時期に用いる化粧料に適用し、赤外線と紫外線の組合せ効果による、肌ダメージの予防用に用いることが好ましい。
(2) Cosmetics of this invention The cosmetics of this invention are characterized by containing the hollow resin spherical powder which may be coat | covered with the metal oxide for the purpose of infrared reflection. Therefore, the use of the cosmetic of the present invention is preferably for infrared protection. Infrared protective cosmetics reflect infrared rays so that they do not reach the skin, thereby protecting the skin from promoting aging by the combined action of ultraviolet rays, infrared rays entering the skin, and converting into heat energy. It is a general term for the action of protecting the skin from the influence of infrared rays directly or indirectly on the physiology of the skin, such as the action of preventing the skin from feeling heat and sweating by energy. In the cosmetic of the present invention, in addition to the above essential components, optional components usually used in cosmetics can be contained. Such optional ingredients include, for example, macadamia nut oil, avocado oil, corn oil, olive oil, rapeseed oil, sesame oil, castor oil, safflower oil, cottonseed oil, jojoba oil, coconut oil, palm oil, liquid lanolin, hydrogenated coconut oil Oils such as hardened oil, mole, hardened castor oil, beeswax, candelilla wax, carnauba wax, ibotarou, lanolin, reduced lanolin, hard lanolin, jojoba wax, waxes, liquid paraffin, squalane, pristane, ozokerite, paraffin, ceresin, petrolatum , Hydrocarbons such as microcrystalline wax, higher fatty acids such as oleic acid, isostearic acid, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, undecylenic acid, cetyl alcohol, stearyl alcohol, isostearyl Alcohol, behenyl alcohol, octyldodecanol, higher alcohol such as myristyl alcohol, cetostearyl alcohol, cetyl isooctanoate, isopropyl myristate, hexyldecyl isostearate, diisopropyl adipate, di-2-ethylhexyl sebacate, cetyl lactate, malic acid Diisostearyl, di-2-ethylhexanoic acid ethylene glycol, dicaprate neopentyl glycol, di-2-heptylundecanoic acid glycerin, tri-2-ethylhexanoic acid glycerin, tri-2-ethylhexanoic acid trimethylolpropane, tri Synthetic ester oils such as trimethylolpropane isostearate and pentane erythritol tetra-2-ethylhexanoate, dimethylpolysiloxane, methylphenylpoly Loxane, linear polysiloxane such as diphenylpolysiloxane, cyclic polysiloxane such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexanesiloxane, amino-modified polysiloxane, polyether-modified polysiloxane, alkyl-modified polysiloxane, Oil agents such as silicone oil such as modified polysiloxane such as fluorine-modified polysiloxane, anionic surfactants such as fatty acid soap (sodium laurate, sodium palmitate, etc.), potassium lauryl sulfate, triethanolamine ether of alkyl sulfate, chloride Cationic surfactants such as stearyltrimethylammonium, benzalkonium chloride, laurylamine oxide, imidazoline-based amphoteric surfactants (2-cocoyl-2-imida Zolinium hydroxide-1-carboxyethyloxy disodium salt, etc.), betaine surfactants (alkyl betaine, amide betaine, sulfobetaine, etc.), amphoteric surfactants such as acylmethyltaurine, sorbitan fatty acid esters (sorbitan) Monostearate, sorbitan sesquioleate, etc.), glycerin fatty acids (glyceryl monostearate, etc.), propylene glycol fatty acid esters (propylene glycol monostearate, etc.), hardened castor oil derivatives, glycerin alkyl ethers, POE sorbitan fatty acid esters (POE sorbitan monooleate, polyoxyethylene sorbitan monostearate, etc.), POE sorbite fatty acid esters (POE-sorbitol monolaurate, etc.), POE glycerin fatty acid ester Tells (POE-glycerol monoisostearate, etc.), POE fatty acid esters (polyethylene glycol monooleate, POE distearate, etc.), POE alkyl ethers (POE2-octyldodecyl ether, etc.), POE alkyl phenyl ethers (POE nonylphenyl) Ethers, etc.), Pluronic types, POE / POP alkyl ethers (POE / POP2-decyltetradecyl ether, etc.), Tetronics, POE castor oil / hardened castor oil derivatives (POE castor oil, POE hardened castor oil, etc.), Nonionic surfactants such as sucrose fatty acid ester and alkyl glucoside, polyethylene glycol, glycerin, 1,3-butylene glycol, erythritol, sorbitol, xylitol, maltitol, propylene Polyols such as recall, dipropylene glycol, diglycerin, isoprene glycol, 1,2-pentanediol, 2,4-hexylene glycol, 1,2-hexanediol, 1,2-octanediol, pyrrolidone carboxylic acid Moisturizing ingredients such as sodium, lactic acid, sodium lactate, guar gum, quince seed, carrageenan, galactan, gum arabic, pectin, mannan, starch, xanthan gum, curdlan, methylcellulose, hydroxyethylcellulose, carboxymethylcellulose, methylhydroxypropylcellulose, chondroitin sulfate , Dermatan sulfate, glycogen, heparan sulfate, hyaluronic acid, sodium hyaluronate, tragacanth gum, keratan sulfate, chondroitin, mucoitin sulfate, hyaluronan Droxyethyl guar gum, carboxymethyl guar gum, dextran, keratosulfuric acid, locust bean gum, succinoglucan, caronic acid, chitin, chitosan, carboxymethylchitin, agar, polyvinyl alcohol, polyvinylpyrrolidone, carboxyvinyl polymer, sodium polyacrylate, Thickeners such as polyethylene glycol and bentonite, surface may be treated, powder such as mica, talc, kaolin, synthetic mica, calcium carbonate, magnesium carbonate, silicic anhydride (silica), aluminum oxide, barium sulfate The surface may be treated, bengara, yellow iron oxide, black iron oxide, cobalt oxide, ultramarine, bitumen, titanium oxide, zinc oxide inorganic pigments, the surface may be treated, mica titanium, Fish phosphorus foil, bismuth oxychloride Pearl agents, which may be raked Red 202, Red 228, Red 226, Yellow 4, Blue 404, Yellow 5, Red 505, Red 230, Red 223, Orange 201 No., Red No. 213, Yellow No. 204, Yellow No. 203, Blue No. 1, Green No. 201, Purple No. 201, Red No. 204, and the like, polyethylene powder, polymethyl methacrylate, nylon powder, organopolysiloxane elastomer Organic powders such as paraaminobenzoic acid UV absorbers, anthranilic acid UV absorbers, salicylic acid UV absorbers, cinnamic acid UV absorbers, benzophenone UV absorbers, sugar UV absorbers, 2- ( UV of 2'-hydroxy-5'-t-octylphenyl) benzotriazole, 4-methoxy-4'-t-butyldibenzoylmethane, etc. Absorbents, lower alcohols such as ethanol and isopropanol, vitamin A or derivatives thereof, vitamin B6 hydrochloride, vitamin B6 tripalmitate, vitamin B6 dioctanoate, vitamin B2 or derivatives thereof, vitamin B12, vitamin B15 or derivatives thereof, etc. Vitamin E such as vitamin B, α-tocopherol, β-tocopherol, γ-tocopherol and vitamin E acetate, vitamin D such as vitamin D, vitamin H, pantothenic acid, panthetin, pyrroloquinoline quinone and the like can be preferably exemplified. Among these, as a particularly preferred component, powders such as mica, talc, kaolin, synthetic mica, calcium carbonate, magnesium carbonate, anhydrous silicic acid (silica), aluminum oxide, barium sulfate, etc. whose surface may be treated Body, surface may be treated, bengara, yellow iron oxide, black iron oxide, cobalt oxide, ultramarine, bitumen inorganic pigments, surface may be treated, mica titanium, fish phosphorus foil, oxy Pearl agents such as bismuth chloride can be exemplified, and among them, those treated with 1 to 10% by mass of perfluoroalkylsilylated surface are particularly preferable. The preferred content of the perfluoroalkylsilylated powder is 30 to 70% by mass, and more preferably 40 to 60% by mass, based on the total amount of the cosmetic. In addition, the cosmetic of the present invention is intended to prevent or suppress adverse effects on the skin due to the combined effect of ultraviolet and infrared rays. Therefore, even if it is subjected to surface treatment, such as a component that absorbs ultraviolet rays. A good example is titanium oxide or zinc oxide. Particularly preferred are metal soap-treated titanium oxide, silica, alumina, zirconia-treated titanium oxide, and the like. Such a component may contain only one species or may contain two or more species in combination. The preferred content of such components is 10 to 85% by mass, and more preferably 20 to 80% by mass, based on the total amount of the cosmetics. The cosmetic of the present invention can be produced by treating these essential components and optional components according to a conventional method. The cosmetic material of the present invention thus obtained is excellent in protective action from infrared rays, and therefore applied to cosmetics used in summer, when the amount of both ultraviolet rays and infrared rays is large, together with ultraviolet protective agents, due to the combined effect of infrared rays and ultraviolet rays. It is preferably used for preventing skin damage.
以下に、実施例を挙げて、本発明について更に詳細に説明を加えるが、本発明がかかる実施例にのみ限定されないことは言うまでもない。 Hereinafter, the present invention will be described in more detail with reference to examples, but it is needless to say that the present invention is not limited to such examples.
本発明の赤外線反射用粉体の効果を調べた。即ち、下記の処方で擂壊機を用いてペーストを作成し、これをドクターブレードを用いて３０ミルの厚さにガラス板上に延展させ、ガラス板上１０ｃｍのところに赤外線ランプを、ガラス板下５ｃｍに温度計を設置し、赤外線ランプを１０分間照射し、温度を測定した。結果を表１に示す。これより、本発明の赤外線反射用粉体は優れた赤外線遮蔽作用を有することが判る。 The effect of the infrared reflecting powder of the present invention was examined. That is, a paste was prepared using a breaker with the following formulation, and this was spread on a glass plate to a thickness of 30 mils using a doctor blade, an infrared lamp was placed at a position 10 cm above the glass plate, A thermometer was installed 5 cm below, irradiated with an infrared lamp for 10 minutes, and the temperature was measured. The results are shown in Table 1. This shows that the infrared reflecting powder of the present invention has an excellent infrared shielding effect.
（ペースト処方）
表１に記載の粉体 ２５質量％
ひまし油 ７５質量％
(Paste formulation)
25% by mass of powders listed in Table 1
Castor oil 75% by mass
以下に示す処方に従って、本発明の化粧料であるパウダーファンデーションを作成した。即ち、処方成分をヘンシェルミキサーで混合し、しかる後、１ｍｍヘリングボーンスクリーンを装着したパルベライザーで粉砕し、金型に詰め加圧成型してパウダーファンデーションを得た。 A powder foundation, which is a cosmetic of the present invention, was prepared according to the prescription shown below. That is, the prescription ingredients were mixed with a Henschel mixer, then pulverized with a palverizer equipped with a 1 mm herringbone screen, filled in a mold and press-molded to obtain a powder foundation.
実施例２と同様に、下記の処方に従って、本発明のパウダーファンデーションを作成した。 Similarly to Example 2, a powder foundation of the present invention was prepared according to the following formulation.
実施例２と同様に、下記の処方に従って、本発明のパウダーファンデーションを作成した。 Similarly to Example 2, a powder foundation of the present invention was prepared according to the following formulation.
実施例２と同様に、下記の処方に従って、本発明のパウダーファンデーションを作成した。 Similarly to Example 2, a powder foundation of the present invention was prepared according to the following formulation.
実施例２〜５のパウダーファンデーションを用いて、赤外線反射効果を調べた。即ち、パネラー１名を用い、右半顔を検体でメークし、左半顔を素顔のままとし、赤外線ランプを用いて赤外線を照射し、顔からの赤外線の反射状況をサーモグラフィーを用いて計測した。サーモグラフィーの画像より、輻射熱に換算して、平均的な素顔との温度差を求めた。結果を表６に示す。尚、比較として、実施例１の「マツモトマイクロスフェアＭＦＬ３０ＳＴＩ」を二酸化チタンに置換したものも、比較例１として同様に計測を行った。 Using the powder foundations of Examples 2 to 5, the infrared reflection effect was examined. That is, using one panelist, the right half face was made with a sample, the left half face was left as a bare face, infrared rays were irradiated using an infrared lamp, and the reflection state of infrared rays from the face was measured using thermography. . From the thermographic image, the temperature difference from the average face was calculated in terms of radiant heat. The results are shown in Table 6. As a comparison, the same measurement as in Comparative Example 1 was performed for “Matsumoto Microsphere MFL30STI” in Example 1 replaced with titanium dioxide.
本発明は、赤外線からの防護用の化粧料に応用できる。 The present invention can be applied to cosmetics for protection from infrared rays.
Claims (10)
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| JP2004328857A JP2006137704A (en) | 2004-11-12 | 2004-11-12 | Infrared-reflecting powder and use thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014233844A (en) * | 2013-05-30 | 2014-12-15 | 日本ペイントホールディングス株式会社 | Multilayer coating film and method for forming a multilayer coating film |
| KR101832847B1 (en) * | 2016-06-29 | 2018-04-13 | 한양대학교 산학협력단 | Organic-inorganic composite particles for blocking near infrared rays, and method for preparing the same |
| KR101861985B1 (en) * | 2017-09-29 | 2018-05-29 | 코스맥스 주식회사 | Cosmetic composition containing organic-inorganic composite particles for blocking near infrared rays |
| US9993397B2 (en) | 2010-11-23 | 2018-06-12 | Conopco Inc. | Composite particles and compositions with composite particles |
-
2004
- 2004-11-12 JP JP2004328857A patent/JP2006137704A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9993397B2 (en) | 2010-11-23 | 2018-06-12 | Conopco Inc. | Composite particles and compositions with composite particles |
| JP2014233844A (en) * | 2013-05-30 | 2014-12-15 | 日本ペイントホールディングス株式会社 | Multilayer coating film and method for forming a multilayer coating film |
| KR101832847B1 (en) * | 2016-06-29 | 2018-04-13 | 한양대학교 산학협력단 | Organic-inorganic composite particles for blocking near infrared rays, and method for preparing the same |
| KR101861985B1 (en) * | 2017-09-29 | 2018-05-29 | 코스맥스 주식회사 | Cosmetic composition containing organic-inorganic composite particles for blocking near infrared rays |
| WO2019066142A1 (en) * | 2017-09-29 | 2019-04-04 | 코스맥스 주식회사 | Cosmetic composition comprising organic-inorganic composite particles for blocking near infrared rays |
| US10806684B2 (en) | 2017-09-29 | 2020-10-20 | Cosmax Inc. | Cosmetic composition containing organic-inorganic composite particles for blocking near infrared rays |
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