JP2006134894A5 - - Google Patents

Download PDF

Info

Publication number
JP2006134894A5
JP2006134894A5 JP2005368032A JP2005368032A JP2006134894A5 JP 2006134894 A5 JP2006134894 A5 JP 2006134894A5 JP 2005368032 A JP2005368032 A JP 2005368032A JP 2005368032 A JP2005368032 A JP 2005368032A JP 2006134894 A5 JP2006134894 A5 JP 2006134894A5
Authority
JP
Japan
Prior art keywords
active material
negative electrode
material layer
lithium
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2005368032A
Other languages
Japanese (ja)
Other versions
JP3906342B2 (en
JP2006134894A (en
Filing date
Publication date
Application filed filed Critical
Priority to JP2005368032A priority Critical patent/JP3906342B2/en
Priority claimed from JP2005368032A external-priority patent/JP3906342B2/en
Publication of JP2006134894A publication Critical patent/JP2006134894A/en
Publication of JP2006134894A5 publication Critical patent/JP2006134894A5/ja
Application granted granted Critical
Publication of JP3906342B2 publication Critical patent/JP3906342B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Claims (5)

リチウム化合物の形成能の低い金属材料からなる一対の集電用表面層間に活物質層を有し、An active material layer between a pair of current collecting surface layers made of a metal material having a low ability to form a lithium compound;
少なくとも一方の前記集電用表面層には、その表面において開孔していると共にその厚さ方向へ延び且つ非水電解液の浸透が可能な微細空隙が多数形成されており、At least one of the current collecting surface layers is formed with a large number of fine voids which are open in the surface thereof and extend in the thickness direction and allow the nonaqueous electrolyte to penetrate,
前記活物質層が、リチウムを吸蔵したリチウム化合物の形成能の高い活物質の粒子を含み、また該活物質層においては、リチウム化合物の形成能の低い金属材料が該活物質層の厚み方向全域に亘って浸透しており、The active material layer includes particles of an active material having a high lithium compound-forming ability that occludes lithium, and in the active material layer, a metal material having a low lithium compound-forming ability is present in the entire thickness direction of the active material layer. Penetrating through,
芯材としての導電性金属箔層を備えていないことを特徴とする非水電解液二次電池用負極。A negative electrode for a non-aqueous electrolyte secondary battery, characterized by not having a conductive metal foil layer as a core material.
前記微細空隙の平均開孔面積が0.1〜50μmThe average pore area of the fine voids is 0.1 to 50 μm 22 で且つ開孔率が0.1〜20%である請求項1記載の非水電解液二次電池用負極。The negative electrode for a non-aqueous electrolyte secondary battery according to claim 1, wherein the porosity is 0.1 to 20%. 前記集電用表面層が、電解めっきによって形成されている請求項1又は2記載の非水電解液二次電池用負極。The negative electrode for a nonaqueous electrolyte secondary battery according to claim 1 or 2, wherein the current collecting surface layer is formed by electrolytic plating. 請求項2記載の非水電解液二次電池用負極の製造方法であって、A method for producing a negative electrode for a non-aqueous electrolyte secondary battery according to claim 2,
キャリア箔上に電解めっきによって集電用表面層を形成し、A surface layer for current collection is formed on the carrier foil by electrolytic plating,
該集電用表面層上に、活物質の粒子を含む導電性スラリーを塗布して活物質層を形成して、該キャリア箔上に該集電用表面層と該活物質層とをこの順で備えた負極前駆体を形成し、A conductive slurry containing active material particles is applied to the current collecting surface layer to form an active material layer, and the current collecting surface layer and the active material layer are arranged in this order on the carrier foil. Forming the negative electrode precursor prepared in
各負極前駆体における前記活物質層どうしが対向するように、金属リチウム箔を両負極前駆体間に挟み込んで、該金属リチウム箔と両負極前駆体とを貼り合わせにより一体化させ、The metal lithium foil is sandwiched between both negative electrode precursors so that the active material layers in each negative electrode precursor face each other, and the metal lithium foil and both negative electrode precursors are integrated by bonding,
リチウムが熱拡散するに十分な温度に加熱して、前記金属リチウム箔からリチウムを前記活物質層へ拡散させ、然る後、Lithium is heated to a temperature sufficient for thermal diffusion to diffuse lithium from the metallic lithium foil into the active material layer, and then
前記キャリア箔を各負極前駆体から剥離分離することを特徴とする非水電解液二次電池用負極の製造方法。A method for producing a negative electrode for a non-aqueous electrolyte secondary battery, wherein the carrier foil is peeled and separated from each negative electrode precursor.
リチウム化合物の形成能の低い金属材料からなる一対の集電用表面層間に活物質層を有し、An active material layer between a pair of current collecting surface layers made of a metal material having a low ability to form a lithium compound;
少なくとも一方の前記集電用表面層には、その表面において開孔していると共にその厚さ方向へ延び且つ非水電解液の浸透が可能な微細空隙が多数形成されており、At least one of the current collecting surface layers is formed with a large number of fine voids which are open in the surface thereof and extend in the thickness direction and allow the nonaqueous electrolyte to penetrate,
前記活物質層が、リチウムを吸蔵したリチウム化合物の形成能の高い活物質の粒子を含み、また該活物質層においては、リチウム化合物の形成能の低い金属材料が該活物質層の厚み方向全域に亘って浸透しており、The active material layer includes particles of an active material having a high lithium compound-forming ability that occludes lithium, and in the active material layer, a metal material having a low lithium compound-forming ability is present in the entire thickness direction of the active material layer. Penetrating through,
芯材としての導電性金属箔層を備えていることを特徴とする非水電解液二次電池用負極。A negative electrode for a non-aqueous electrolyte secondary battery, comprising a conductive metal foil layer as a core material.
JP2005368032A 2004-05-12 2005-12-21 Negative electrode for non-aqueous electrolyte secondary battery and method for producing the same Active JP3906342B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2005368032A JP3906342B2 (en) 2004-05-12 2005-12-21 Negative electrode for non-aqueous electrolyte secondary battery and method for producing the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2004141981 2004-05-12
JP2005368032A JP3906342B2 (en) 2004-05-12 2005-12-21 Negative electrode for non-aqueous electrolyte secondary battery and method for producing the same

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
JP2005061280A Division JP3799049B2 (en) 2004-05-12 2005-03-04 Negative electrode for non-aqueous electrolyte secondary battery and method for producing the same

Publications (3)

Publication Number Publication Date
JP2006134894A JP2006134894A (en) 2006-05-25
JP2006134894A5 true JP2006134894A5 (en) 2006-07-06
JP3906342B2 JP3906342B2 (en) 2007-04-18

Family

ID=36728201

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2005368032A Active JP3906342B2 (en) 2004-05-12 2005-12-21 Negative electrode for non-aqueous electrolyte secondary battery and method for producing the same

Country Status (1)

Country Link
JP (1) JP3906342B2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8206569B2 (en) 2009-02-04 2012-06-26 Applied Materials, Inc. Porous three dimensional copper, tin, copper-tin, copper-tin-cobalt, and copper-tin-cobalt-titanium electrodes for batteries and ultra capacitors
WO2010090956A2 (en) * 2009-02-04 2010-08-12 Applied Materials, Inc. Porous three dimensional copper, tin, copper-tin, copper-tin-cobalt, and copper-tin-cobalt-titanium electrodes for batteries and ultra capacitors
JP7187661B2 (en) * 2019-03-01 2022-12-12 ビークルエナジージャパン株式会社 Electrodes for lithium secondary batteries and lithium secondary batteries

Similar Documents

Publication Publication Date Title
US10020514B2 (en) Ionically permeable structures for energy storage devices
JP3985849B2 (en) Negative electrode for lithium secondary battery, lithium secondary battery using the same, and manufacturing method thereof
ES2942483T3 (en) Silicon Nanostructure Active Materials for Lithium Ion Batteries and Related Processes, Compositions, Components and Devices
WO2005109548B1 (en) Negative electrode for nonaqueous electrolyte secondary battery and method for producing same
JP3764470B1 (en) Anode for non-aqueous electrolyte secondary battery
JP2013016800A (en) Lithium plate, method for lithiation of electrode and energy storage device
CN108400284A (en) A kind of perforation positive plate of lithium ion battery and preparation method thereof
WO2023102955A1 (en) Novel microporous composite foil and preparation method therefor
WO2012163247A1 (en) Lithium ion battery negative electrode with metallic lithium composite structure
JP2018063850A (en) Laminate green sheet, all-solid type secondary battery, and method for fabricating the same
JP6255768B2 (en) Nonaqueous electrolyte secondary battery separator and nonaqueous electrolyte secondary battery including the same
JP4764232B2 (en) Anode for non-aqueous electrolyte secondary battery and non-aqueous electrolyte secondary battery
JP3987851B2 (en) Secondary battery negative electrode and secondary battery including the same
JP2008171788A (en) Collector for lithium ion cells and method for manufacturing it
KR20130136150A (en) Solid high-ionic conductor for lithium battery and lithium battery using the same
JP2006134894A5 (en)
JP2004139954A5 (en)
CN113506877A (en) High-energy-density microporous lithium battery electrode and preparation method thereof
US20180337402A1 (en) Robust amorphous silicon anodes, rechargable batteries having amorphous silicon anodes, and associated methods
JP2005197217A (en) Anode for non-aqueous electrolytic solution secondary battery
JP2001040402A (en) Porous metallic thin sheet body and its manufacture
JP2016058258A (en) Negative electrode for lithium ion secondary battery, and lithium ion secondary battery
JP2013182667A (en) Lithium air secondary battery and method for manufacturing lithium air secondary battery
WO2023019741A1 (en) Current collector preparation method and pole piece
WO2014156053A1 (en) Negative electrode for non-aqueous electrolyte secondary batteries and non-aqueous electrolyte secondary battery