JP2006097199A - Method for producing kraft pulp and apparatus for producing the same - Google Patents

Method for producing kraft pulp and apparatus for producing the same Download PDF

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JP2006097199A
JP2006097199A JP2004286881A JP2004286881A JP2006097199A JP 2006097199 A JP2006097199 A JP 2006097199A JP 2004286881 A JP2004286881 A JP 2004286881A JP 2004286881 A JP2004286881 A JP 2004286881A JP 2006097199 A JP2006097199 A JP 2006097199A
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pulp
cooking
producing
kraft pulp
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Itsuo Kondo
逸生 近藤
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Daio Paper Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for producing kraft pulp, by which the pulp can be obtained in a high yield and in a high pulp strength (especially a tensile index), and to provide an apparatus for producing the same. <P>SOLUTION: In this method for producing the kraft pulp, the cooking degree of a pulp raw material is lowered to enhance a kappa number. The pulp raw material is mechanically beat and perfectly pulped with a refiner at the exit of a continuous digester and before or in a refining process to produce the kraft pulp in a high yield. The pulp raw material is mechanically beat with the refiner in a pulp concentration of 10 to 20% to accelerate the fibrillation of the pulp fibers, thereby enabling the production of the pulp having a high strength and containing few knotted fibers. Thus, the employments of steam / a cooking agent liquid in the cooking process can be reduced by lowering a cooking degree in the cooking process. The kraft pulp having a high pulp strength (especially a tensile index) can be produced by beating the pulp raw material with the refiner in a high pulp concentration. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本願発明は、クラフトパルプの製造方法及びその製造装置に関するものである。   The present invention relates to a method for producing kraft pulp and an apparatus for producing the same.

リグノセルロース物質からなるパルプ原料(広葉樹チップや針葉樹チップ)を蒸解薬液で蒸解し、その後精選工程でパルプ成分とノット等の夾雑物とを分離する工程を経てパルプを製造するクラフトパルプ(広葉樹クラフトパルプ又は針葉樹クラフトパルプ)の製造工程では、クラフトパルプは、蒸解工程でパルプ化し、精選工程では蒸解できなかったノット(及びその他の夾雑物)を取除くことが行われる。そして、蒸解工程で生成するノットは、従来の一般的なクラフトパルプ製造設備では、ノッター又はノットセパレーター等と称されているノット処理設備で除去することとされている。リファイナーを有していない工程においてはノットを発生させないようにするため、カッパー価を低くして操業する必要があり歩留低下の要因になっている。ノットの量は蒸解度によって増減する。その場合、チップ蒸解の度合いはカッパー価で表し、カッパー価の数値が大きい方(カッパー価が高い)が歩留りが高くなるがノットも多くなる。また、パルプ強度(特に、比引裂度)はカッパー価が高い方が高い、という一般的傾向がある。   Kraft pulp (hardwood kraft pulp) that produces pulp through the process of cooking pulp raw materials (hardwood chips and softwood chips) made of lignocellulosic material with cooking chemicals and then separating pulp components and knots and other contaminants in the selection process Alternatively, in the production process of coniferous kraft pulp, kraft pulp is pulped in the cooking process and knots (and other contaminants) that could not be cooked in the selective process are removed. And the knot produced | generated at a cooking process is supposed to be removed with the knot processing equipment called a knotter or a knot separator etc. in the conventional common kraft pulp manufacturing equipment. In order not to generate knots in a process that does not have a refiner, it is necessary to operate with a lower kappa number, which is a factor in yield reduction. The amount of knots increases and decreases with the degree of cooking. In that case, the degree of chip cooking is represented by the kappa number, and the higher the kappa number (higher kappa number), the higher the yield but the more knots. Moreover, there exists a general tendency that pulp strength (especially specific tear degree) is so high that a copper number is high.

なお、クラフトパルプ製造工程で行われるノットの除去に関しては、後記非特許文献1に一般的記述がある。   In addition, regarding the knot removal performed in the kraft pulp manufacturing process, there is a general description in Non-Patent Document 1 below.

紙パルプ技術協会発行 紙パルプ製造技術シリーズ(3)「パルプの洗浄・精選・漂白」第31頁〜32頁「2.2 ノッタ」の項。Paper Pulp Technology Association, Paper Pulp Manufacturing Technology Series (3) “Pulp washing, selection and bleaching”, pages 31-32 “2.2 Nota”.

本願発明者は、クラフトパルプ(特に、針葉樹クラフトパルプ)の蒸解工程における蒸解度を従来より下げることにより、パルプ強度(特に、比引裂度)が高く、かつ高歩留りでパルプを得ることのできるクラフトパルプの製造方法及び製造装置を開発することを目的とし、本願発明に到達したものである。   The inventor of the present application is a craft that has a high pulp strength (particularly, specific tear) and can obtain pulp with a high yield by lowering the degree of cooking in the cooking process of kraft pulp (especially softwood kraft pulp). The object of the present invention is to develop a pulp manufacturing method and manufacturing apparatus, and the present invention has been achieved.

すなわち、本願発明のクラフトパルプ製造方法及び製造装置は、クラフトパルプの製造工程では通常、紙料の調成工程(抄紙工程の前工程)で行われるパルプの叩解処理を、パルプの蒸解工程後と、精選工程前又は精選工程の途中において行うことを基本的特徴とする。   That is, in the kraft pulp manufacturing method and the manufacturing apparatus of the present invention, in the kraft pulp manufacturing process, the pulp beating process normally performed in the stock preparation process (the pre-process of the paper making process) is performed after the pulp cooking process. The basic feature is that it is performed before or during the selection process.

本願発明のクラフトパルプの製造方法及び製造装置が対象とするパルプ原料は、広葉樹材でも、針葉樹材でもよいが、本願発明は、針葉樹クラフトパルプに対して適用すれば特に有利である。   The pulp raw material targeted by the kraft pulp manufacturing method and manufacturing apparatus of the present invention may be hardwood or softwood, but the present invention is particularly advantageous when applied to softwood kraft pulp.

本願発明を実施するにあたっては、パルプ原料の蒸解度を下げてカッパー価を高くし、連続蒸解釜出口と、精選工程前又は精選工程の途中でリファイナーにて機械的に叩解して完全にパルプ化し、高歩留クラフトパルプを製造する。パルプ濃度10%〜20%でリファイナーにて機械的に叩解処理することで、パルプ繊維のフィブリル化を促進し、強度が高く結束繊維の少ないパルプを製造することができる。また、このように、蒸解工程での蒸解度を下げることで、蒸解工程での蒸気・蒸解薬液の使用量を低減することができると共に、リファイナーで高濃度叩解することによりパルプ強度(特に、比引裂度)の高いクラフトパルプを製造することができる。このように、蒸解薬液(苛性ソーダ・硫化ソーダ等)の添加量を減少させれば、パルプ繊維の傷みを減少させてパルプ強度(特に、比引裂度)を高くすることができる。   In carrying out the invention of the present application, the pulp value of the pulp raw material is lowered to increase the kappa number, and the pulp is completely pulped by a continuous digester outlet and mechanically beaten with a refiner before or during the selection process. , Producing high yield kraft pulp. By mechanically beating with a refiner at a pulp concentration of 10% to 20%, fibrillation of the pulp fibers can be promoted, and a pulp having high strength and few binding fibers can be produced. In addition, by reducing the degree of cooking in the cooking process in this way, the amount of steam and cooking chemical used in the cooking process can be reduced, and the pulp strength (particularly the ratio) can be reduced by high concentration beating with a refiner. Kraft pulp having a high degree of tearing can be produced. Thus, if the amount of the cooking chemical solution (caustic soda, sodium sulfide, etc.) is decreased, it is possible to reduce the damage of the pulp fibers and increase the pulp strength (particularly, the specific tear rate).

本願発明を実施するにあたっては、蒸解工程での蒸解度を示すカッパー価は、30以上とするのがよい。このカッパー価が30を下回るとノットがほとんど無くなりリファイナーで叩解する必要がなくなる。   In carrying out the present invention, the kappa number indicating the degree of cooking in the cooking process is preferably 30 or more. When the copper number is below 30, knots are almost eliminated and it is not necessary to beat with a refiner.

蒸解工程での蒸解度を抑えると、従来に比して比較的多量のノットが発生するが、本願発明では、このノットをあえてリファイナーで機械的に叩解することによりパルプ化させ、それによって歩留りの高いクラフトパルプ(特に針葉樹クラフトパルプ)を得るものである。   If the degree of cooking in the cooking process is suppressed, a relatively large amount of knots is generated compared to the conventional method. In the present invention, the knots are deliberately beaten mechanically with a refiner, thereby producing a yield. High kraft pulp (especially softwood kraft pulp) is obtained.

上記の観点から、本願発明を実施するにあたっては、パルプ製造の全工程中に、ノッター又はノットセパレーター等と称されているノット処理設備をあえて設置しない場合もある。なお、本願発明の方法で製造されるパルプは、特に限定するものではないが、ライナー用の原料パルプや米麦等の穀物袋用の原料パルプとして好適である。   From the above viewpoint, in carrying out the present invention, a knot processing facility called a knotter or a knot separator may not be installed during the entire pulp manufacturing process. The pulp produced by the method of the present invention is not particularly limited, but is suitable as a raw material pulp for liners and a raw material pulp for grain bags such as rice wheat.

本願発明のクラフトパルプの製造方法及び製造装置は、クラフトパルプ製造工程中の蒸解工程後と、精選工程前又は精選工程の途中においてパルプ成分を叩解することにより、パルプ繊維のフィブリル化を促進し、強度が高く結束繊維の少ないパルプを製造することができる効果がある。また、本願発明によれば、蒸解工程後と、精選工程前又は精選工程の途中でのパルプ成分の叩解という手段をとることにより、蒸解工程での蒸解度を低下させ(カッパー価は通常の蒸解の場合より高くなる)、それによって蒸解工程での蒸気・蒸解薬液の使用量を低減させるとともに、パルプ強度(特に、比引裂度)が高く、且つ歩留りの高いクラフトパルプを製造し得る効果がある(特に、針葉樹クラフトパルプについて有利である)。また、本願発明の実施にあたり、ノッター又はノットセパレーター等のノット処理設備を省略すれば、設備費用の低減についても効果が得られる。   The kraft pulp manufacturing method and manufacturing apparatus of the present invention promotes fibrillation of pulp fibers by beating the pulp components after the cooking process in the kraft pulp manufacturing process and before the screening process or in the middle of the screening process, There is an effect that a pulp having high strength and few binding fibers can be produced. In addition, according to the present invention, the degree of cooking in the cooking process is reduced by taking the means of beating the pulp components after the cooking process and before or during the refinement process. As a result, the amount of steam and cooking chemical used in the cooking process is reduced, and it is possible to produce kraft pulp with high pulp strength (particularly, specific tear) and high yield. (Especially advantageous for softwood kraft pulp). Moreover, in the implementation of the present invention, if knot processing equipment such as a knotter or a knot separator is omitted, an effect can be obtained for reduction of equipment cost.

続いて図1を参照して本願発明を実施するための具体例を説明すると、図1において符号1は連続蒸解釜で、連続蒸解釜1では蒸解薬液により原料チップ(この実施例では、針葉樹チップ)の蒸解が行われ、そこで生成された黒液混じりの(未洗浄)パルプスラリーP1が連続蒸解釜1の底部から取り出される。この実施例ではパルプスラリーP1のカッパー価(蒸解度)は、30以上としている。   Next, a specific example for carrying out the present invention will be described with reference to FIG. 1. In FIG. 1, reference numeral 1 is a continuous digester, and in the continuous digester 1, raw material chips (in this embodiment, softwood chips) by cooking chemicals. ) And the black liquor-mixed (unwashed) pulp slurry P <b> 1 is taken out from the bottom of the continuous digester 1. In this embodiment, the pulp slurry P1 has a copper number (cooking degree) of 30 or more.

図1の実施例においては、このパルプスラリーP1は連続蒸解釜1の出口に設けられている一次リファイナー2に送給されて一次的に叩解される。   In the embodiment of FIG. 1, this pulp slurry P1 is fed to a primary refiner 2 provided at the outlet of the continuous digester 1 and is first beaten.

以上のようにして、一次叩解されたパルプスラリーP1は、ブローパルプタンク3に貯留され、次いで洗浄機(ドラムウォッシャ)4に送給されて洗浄水によって洗浄された後、(洗浄)パルプスラリーP2として精選工程の入口部に設けられた二次リファイナー5に送給されて二次的に叩解される。   The pulp slurry P1 that has been primarily beaten as described above is stored in the blow pulp tank 3, and then fed to the washing machine (drum washer) 4 and washed with washing water, and then (washed) pulp slurry P2. Are fed to the secondary refiner 5 provided at the entrance of the selection process and secondarily beaten.

リファイナーは、パルプ成分を機械的に叩解処理するので、パルプ濃度を10%〜20%で供給し、セグメント(固定刃・回転刃)の間隔により変化する電動機の負荷で叩解の度合いを管理しパルプを処理することで、パルプ繊維のフィブリル化を促進し強度が高く結束繊維の少ないパルプを製造することができる。   The refiner mechanically beats the pulp components, so the pulp concentration is supplied at 10% to 20%, and the degree of beating is controlled by the load of the electric motor that changes depending on the interval between the segments (fixed blade / rotating blade). By treating this, it is possible to produce a pulp that promotes fibrillation of the pulp fiber and has high strength and few binding fibers.

二次的に叩解されたパルプスラリーP3は、続いて精選スクリーン6及び精選クリーナー7に送給されてパルプスラリーから夾雑物(樹皮等の未蒸解木片やノット等)の一部(N1,N2)を分離して系外に排出する。   The pulp slurry P3 that has been secondarily beaten is then fed to the selection screen 6 and the selection cleaner 7, and is part of the impurities (undigested wood pieces such as bark and knots) from the pulp slurry (N1, N2). Is separated and discharged out of the system.

精選工程を終えたパルプスラリーP4は、続いて洗浄機(ドラムウォッシャー)8で洗浄され、次いで仕上りパルフストックタンク9へ送られて貯留される。   The pulp slurry P4 that has undergone the selection process is subsequently washed by a washing machine (drum washer) 8, and then sent to the finished parfstock tank 9 for storage.

図示の実施例では、蒸解工程での蒸解度を下げるために、蒸解薬液の使用を減少させるとともに、蒸解釜の最高温度を下げ、温度分布を緩やかに維持することで高濃度・高温度の蒸解薬液に依るセルロースを含む炭水化物の分解・消失を防ぎ、パルプ歩留を高くしている。このように、蒸解工程で蒸解度を下げると、蒸解薬液の温度コントロールに使用する蒸気と蒸解薬液の使用量を低減することができる。   In the embodiment shown in the figure, in order to reduce the degree of cooking in the cooking process, the use of cooking chemicals is reduced, the maximum temperature of the digester is lowered, and the temperature distribution is maintained gently so that cooking at a high concentration / high temperature is achieved. Prevents decomposition and disappearance of carbohydrates including cellulose due to chemicals, and increases pulp yield. Thus, if the degree of cooking is lowered in the cooking step, the amount of steam and cooking chemical used for controlling the temperature of the cooking chemical can be reduced.

また、図示の実施例では、パルプ成分をリファイナーで高濃度叩解することにより、蒸解工程で蒸解度を下げ、カッパー価を高くすることによりパルプ歩留が5%(46%→51%)向上し、パルプ強度の高い(比引裂度190→240(JIS))針葉樹クラフトパルプを製造することができた。   In the illustrated embodiment, the pulp component is beaten with a refiner at a high concentration to lower the degree of cooking in the cooking process and increase the kappa number to improve the pulp yield by 5% (46% → 51%). Conifer kraft pulp having high pulp strength (specific tear degree 190 → 240 (JIS)) could be produced.

なお、図示の実施例においては、その全工程中(連続蒸解釜1から仕上りパルフストックタンク8までの間)、ノッター又はノットセパレーター等と称されているノット処理設備を設けていない(それによって、パルプのさらなる歩留り向上を図っている)。   In the illustrated embodiment, a knot processing facility called a knotter or a knot separator is not provided during the entire process (between the continuous digester 1 and the finished parfstock tank 8). , Further improving the yield of pulp).

本願発明の実施例にかかる製造方法及び製造装置の要部概念図である。It is a principal part conceptual diagram of the manufacturing method and manufacturing apparatus concerning the Example of this invention.

符号の説明Explanation of symbols

1は連続蒸解釜、2は一次リファイナー、4は洗浄機、5は二次リファイナー、6は精選スクリーン、7は精選クリーナー、8は洗浄機である。   1 is a continuous digester, 2 is a primary refiner, 4 is a washing machine, 5 is a secondary refiner, 6 is a screening screen, 7 is a screening cleaner, and 8 is a cleaning machine.

Claims (5)

リグノセルロース物質からなるパルプ原料を蒸解する蒸解工程と、該蒸解工程で生成されたパルプ成分を精選する精選工程とを含むクラフトパルプの製造方法であって、前記蒸解工程後と精選工程前又は精選工程の途中において前記パルプ成分を叩解することを特徴とするクラフトパルプの製造方法。   A method for producing kraft pulp, comprising a cooking step for cooking a pulp raw material comprising a lignocellulosic material, and a selection step for selecting a pulp component produced in the cooking step, after the cooking step and before or after the selection step. A method for producing kraft pulp, wherein the pulp component is beaten in the middle of the process. パルプ原料が針葉樹材であることを特徴とする請求項1記載のクラフトパルプの製造方法。   The method for producing kraft pulp according to claim 1, wherein the pulp raw material is a softwood material. 蒸解工程における蒸解度をカッパー価30以上の範囲にすることを特徴とする請求項1又は2記載のクラフトパルプの製造方法。   The method for producing kraft pulp according to claim 1 or 2, wherein the cooking degree in the cooking step is set to a kappa value of 30 or more. 蒸解工程を行う連続蒸解釜の出口と、精選工程前又は精選工程の途中にパルプ成分を叩解処理するリファイナー設備を設置したことを特徴とするクラフトパルプ製造装置。   An apparatus for producing kraft pulp, comprising an outlet of a continuous digester for performing a cooking process and a refiner facility for beating the pulp components before or during the selection process. パルプの全製造工程中に、ノッター又はノットセパレーター等のノット処理設備を設けないことを特徴とする請求項4記載のクラフトパルプ製造装置。
The kraft pulp manufacturing apparatus according to claim 4, wherein a knot processing facility such as a knotter or a knot separator is not provided during the entire pulp manufacturing process.
JP2004286881A 2004-09-30 2004-09-30 Method for producing kraft pulp and apparatus for producing the same Pending JP2006097199A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010529326A (en) * 2007-06-12 2010-08-26 ミードウエストベコ・コーポレーション High yield and high performance fiber
US10060075B2 (en) 2007-06-12 2018-08-28 Westrock Mwv, Llc Fiber blend having high yield and enhanced pulp performance and method for making same

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010529326A (en) * 2007-06-12 2010-08-26 ミードウエストベコ・コーポレーション High yield and high performance fiber
US10000889B2 (en) 2007-06-12 2018-06-19 Westrock Mwv, Llc High yield and enhanced performance fiber
US10060075B2 (en) 2007-06-12 2018-08-28 Westrock Mwv, Llc Fiber blend having high yield and enhanced pulp performance and method for making same

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