JP2006093218A - Lamp heating device and manufacturing method of semiconductor device - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a lamp heating device of good stability and reproducibility in temperature for a thermal process condition. <P>SOLUTION: The lamp heating device comprises a chamber 30 which has a transparent window 15 to house a substrate 1 to be annealed, a heating lamp 5 which heats the substrate 1 by its heat radiation through the transparent window 15, a radiation thermometer in which a sensing part 6 is provided in the chamber 30 to optically detect temperature of the substrate 1, a radical generating part 20 which generates radical outside the chamber 30 and supplies it in the chamber 30, and a light quantity sensor which judges when to clean the inside of chamber 30 according to the blurring state of the surface of transparent window 15 and sensing part 6, allowing a series of operations for heating/annealing the substrate 1 and cleaning the inside of chamber 30. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

  The present invention relates generally to lamp heating devices, and more particularly to lamp heating devices that rapidly heat a substrate in the manufacture of semiconductor devices. The present invention also relates to a method for manufacturing a semiconductor device using such a lamp heating apparatus.

  A furnace and RTA (Rapid Thermal Annealing) are roughly used for heat treatment used for manufacturing a semiconductor device represented by memory or logic. In particular, in recent years, miniaturization and thinning (film) of devices have been accelerated rapidly, and reduction of the thermal history (thermal budget) of the substrate is desired. In order to cope with this, RTA processing for rapidly heating / cooling the substrate is frequently used.

  A general RTA process is a method in which a substrate is rapidly heated by a high heat output of a heating lamp, and after reaching a predetermined temperature, heating is immediately stopped and the substrate is rapidly cooled. As an apparatus for realizing such an RTA process, a heating lamp such as a halogen lamp disposed above a susceptor that supports a substrate, a chamber having a temperature sensor that detects a substrate temperature by a non-contact method such as an optical method, and the like. Is effective.

  When the RTA process is performed using the lamp heating apparatus described above, a process gas such as nitrogen or oxygen is supplied into the chamber after a substrate such as an Si wafer is placed on a support by an automatic transfer mechanism. Next, the substrate is rapidly heated to a predetermined temperature while the substrate temperature is fed back by the temperature sensor. When an optical sensor is used as the temperature sensor, for example, an optical sensor in which a light receiving unit that receives radiation generated from the back side of the substrate is installed inside the chamber, and the obtained light is installed outside the chamber through an optical fiber. Detect with. Then, after the substrate reaches a predetermined temperature, the temperature is maintained for a desired annealing time. Finally, the heating lamp is turned off to rapidly cool the substrate to a predetermined temperature, and then the substrate is taken out of the chamber by automatic transfer.

  By the way, in the above conventional heat treatment, the substance on the substrate and inside the substrate diffuses to the outside of the substrate by heating, and the diffused substance is sensed by the temperature sensor, the inner wall of the chamber, the members installed in the chamber, and the like. Part, its measuring terminal part, etc. In particular, when diffusing substances such as P, As, and B adhere to and accumulate on the temperature sensor and clouding of the sensing portion occurs, the stability of temperature measurement and temperature control decreases, and the temperature uniformity within the wafer surface, Temperature reproducibility for each process is impaired. In addition, these adhesions and deposits may be sublimated during heat treatment and taken into the substrate. As a result, the performance of the device changes, and the product as designed cannot be obtained.

  In particular, in recent years, shallower (shallow bonding) has been progressed, and in order to achieve both low resistance and high resistance (for example, about 1000 ° C.) and a short time (for example, 1) In order to form a fine transistor, it has become very important to perform a heat treatment at a second or less). For this reason, the danger that the cloudiness will occur is increasing. In addition, in the polysilicon used as the wiring, the impurity concentration to be implanted is increasing with the miniaturization, and when RTA is used for the activation of impurities, the diffusion of the diffusing substance on both sides of the wafer is increased. The diffusion material adheres to the inner wall of the chamber, members installed in the chamber, and the like, as well as the sensing portion of the temperature sensor, the measurement terminal portion, and the like.

  For this reason, the chamber is opened and manual cleaning is performed, but this method results in a reduction in the operating time of the apparatus. Further, the period of normal processing between the cleaning processes is affected by fogging that occurs over time.

  In order to solve this problem, a lamp heating apparatus shown in FIG. 3 has been proposed (see, for example, Patent Document 1).

  The lamp heating device includes a transparent window 15, and a chamber 30 that accommodates the substrate 1 to be annealed, and a heating lamp 5 that heats the substrate 1 by radiant heat through the transparent window 15. The lamp heating apparatus further includes a radiation thermometer (not shown) that optically detects the temperature of the substrate 1 in which the sensing unit 6 formed of an optical fiber is provided in the chamber 30. After the wafer (for example, silicon wafer) 1 is loaded into the chamber 30 by an automatic transfer mechanism (not shown), the chamber 30 is separated by the substrate support 4 and the wafer 1 to form two closed spaces. As a result, the front surface (surface on which the semiconductor device is formed) side of the wafer 1 and the back surface side of the wafer 1 have an independent space. Of each space, the front side of the wafer 1 is defined as a space A2, and the back side of the wafer 1 is defined as a space B3.

  A plurality of heating lamps 5 are installed on the space A2 side through transparent windows 15 for lamps. At the time of annealing, the radiant heat of the heating lamp 5 is transmitted to the wafer 1 through the transparent window 15. On the space B3 side, a sensing unit 6 formed of an optical fiber connected to a radiation thermometer (not shown) that optically detects the temperature of the wafer 1 is provided.

  Further, a gas supply port 16 and a gas discharge port 17 are provided on the side wall portion of the chamber 30 so as to face each other. The gas supply port 16 is connected to a gas supply system 7 for supplying helium gas as a process gas in the space A2. On the other hand, a gas discharge system 9 for discharging the gas in the space A <b> 2 to the outside of the chamber 30 is connected to the gas discharge port 17.

  Further, a gas supply port 18 and a gas discharge port 19 are provided on the space B3 side. The gas supply port 18 is connected to a gas supply system 10 for supplying a gas composed of oxygen gas and helium gas as a dilution gas in the space B3, and the gas discharge port 19 is configured to supply the gas in the space B3. A gas discharge system 11 for discharging to the outside of the chamber 30 is connected.

  Hereinafter, an example of the RTA processing procedure will be described. First, the wafer 1 is automatically transferred into the chamber 30 where the inside is replaced with an inert gas such as He gas or the like, and the space A2 and the space B3 are formed by placing the wafer 1 on the substrate support 4. To do.

  Next, helium gas as a process gas is supplied to form a process atmosphere in the chamber 30. The gas in the space B3 is discharged at a predetermined flow rate. Incidentally, since the space B3 is maintained in a substantially closed state by the weight of the wafer 1 as described above, there is almost no leakage of He gas from the back space B3 to the front space A2. The space B3 is set to have a negative pressure compared to the space A2.

  Thereafter, each heating lamp 5 is turned on, and the temperature of the wafer 1 is rapidly increased from room temperature (25 ° C.) with a temperature gradient of, for example, about 100 to 150 ° C./second (substrate heating step). During this time, the back surface temperature of the wafer 1 is measured in a non-contact manner over time by a temperature sensor having a plurality of sensing units 6, and the in-plane temperature in the wafer 1 is made uniform by a control device (not shown). Then, adjustment of the heat output of each heating lamp 5 or control of lighting / extinguishing is performed.

  Such heating is performed for several seconds to several tens of seconds, and when the wafer 1 reaches a predetermined, for example, 1000 ° C., each heating lamp 5 is turned off or adjusted to have a preheated heat output. Subsequently, He gas is supplied into the space B3 together with the space A2 in the chamber 30 so that the wafer 1 is cooled from the front surface side and the back surface side. This substrate cooling process is continued until the temperature of the wafer 1 reaches a predetermined unloading temperature, for example, 750 ° C. In this case, it is preferable to lower the temperature at a temperature lowering rate that preferably has a temperature gradient of about 50 to 90 ° C./second.

Next, oxygen gas (O ₂ ) is added to and mixed with helium gas, and this is supplied into the space B3. At this time, the oxygen gas and helium gas are mixed by the control device so that the concentration of the oxygen gas in the mixed gas is 500 ppm or more, more preferably 500 to 1000 ppm, and particularly preferably 650 to 800 ppm. The mixed gas supplied into the space B3 is given thermal energy by radiation from the wafer 1 or heat conduction by He gas which is a dilution gas, and active species including oxygen atoms are generated in the vicinity of the back surface of the wafer 1. Such active species are modified into stable SiO ₂ by oxidizing silicon suboxide (SiO), which is a natural oxide film formed on the back surface of the wafer 1, and suppressing sublimation of SiO. In addition, if there is a portion where Si is exposed microscopically on the back surface, it may be oxidized to generate SiO ₂ . Therefore, an SiO ₂ film that effectively prevents external diffusion of a sublimation substance and a dopant such as phosphorus implanted in the wafer 1 is formed on the entire back surface of the wafer 1. Thereby, it becomes possible to suppress fogging of the surface of the sensing unit 6 on the back side of the wafer 1.

JP 2003-77851 A

  However, although the above method is effective in suppressing the generation of sublimation substances on the back side of the wafer 1, no consideration is given to the transparent window 15 on the front side of the wafer 1. In addition, although the oxidation treatment suppresses the outward diffusion of the diffusing material, it cannot be completely eliminated, and the transparent window 15 for the lamp and the surface of the sensing unit 6 still fog up. Cleaning is required. In addition, when the wafer 1 is in the chamber 30, the introduction of the oxidizing gas involved in the process for the purpose of cleaning may be affected by the wraparound even if it is a minute amount in terms of process control which is being miniaturized. Is undesirable.

  The present invention has been made to solve the above-described problems, and an object thereof is to provide a lamp heating apparatus that stabilizes a measurement system and the like related to temperature control of a substrate by removing fogging of a transparent window.

  Another object of the present invention is to provide a lamp heating apparatus having good temperature stability and reproducibility of heat treatment conditions.

  Still another object of the present invention is to provide a lamp heating apparatus with improved process stability.

  Still another object of the present invention is to provide a lamp heating device that can maintain the inside of a chamber in a clean state and can suppress generation of foreign matters such as particles.

  Still another object of the present invention is to provide a method of manufacturing a semiconductor device using such a lamp heating apparatus.

  The lamp heating apparatus according to claim 1 has a transparent window, a chamber for accommodating the substrate, a heating lamp for heating the substrate by the radiant heat through the transparent window, and a sensing unit in the chamber. A radiation thermometer for optically detecting the temperature of the substrate; radical supply means for generating radicals outside the chamber and supplying the radicals into the chamber; and the transparent window and the sensing unit. And a means for judging the timing of cleaning the inside of the chamber from the cloudy state of the surface, and enabling a series of operations of annealing the substrate and cleaning the inside of the chamber.

  According to the lamp heating apparatus of the present invention, a radical supply means for supplying the radical into the chamber, and a means for judging the timing for cleaning the inside of the chamber from the cloudy state of the surfaces of the transparent window and the sensing unit. And a series of operations for heating and annealing the substrate and cleaning the inside of the chamber are possible, so that the measurement system for controlling the temperature of the substrate is stabilized. Further, since radicals are generated outside the chamber, physical damage due to plasma irradiation does not occur, and the surface of the transparent window and the sensing unit does not become rough.

  A lamp heating apparatus according to a second aspect is the lamp heating apparatus according to the first aspect, wherein the radical is selected from the group consisting of hydrogen, oxygen and a fluorocarbon compound.

  According to a third aspect of the present invention, there is provided the lamp heating apparatus according to the first aspect, further comprising means for detecting a cloudy state of the surfaces of the transparent window and the sensing unit. With this configuration, it is possible to determine the timing for cleaning the inside of the chamber.

  According to a fourth aspect of the present invention, there is provided a method for manufacturing a semiconductor device, wherein the transparent window and the sensing unit are formed during one or a plurality of annealing processes in the manufacturing process of the semiconductor device using the lamp heating device according to the first aspect. The surface is cleaned with the radicals.

  According to this method, it is possible to create a state in which the measurement system relating to the temperature control of the substrate is stabilized, the temperature stability and reproducibility of the heat treatment conditions are improved, and the process stability is improved. In addition, the inside of the chamber can be kept clean, and the generation of foreign matters such as particles can be suppressed.

  According to a fifth aspect of the present invention, there is provided a method for manufacturing a semiconductor device, wherein in the manufacturing process of the semiconductor device using the lamp heating device according to the first aspect, a cloudy state of the surfaces of the transparent window and the sensing unit is detected and a predetermined cloudy state is detected. It is characterized in that cleaning with the radicals is carried out every time exceeding the above.

  According to a sixth aspect of the present invention, there is provided a method for manufacturing a semiconductor device, comprising: performing annealing once in a process of manufacturing a semiconductor device using the lamp heating device according to claim 1; It is characterized by being divided into two. Thereby, the thermal history (thermal budget) of the substrate can be reduced.

  According to the present invention, in the RTA processing apparatus, since oxygen, hydrogen, radicals such as carbon fluoride can be supplied into the chamber from the outside of the chamber during the substrate processing, phosphorus generated by heat treatment in In-Situ, Contaminants due to dopants such as arsenic and boron can be cleaned. Further, since plasma is not generated inside the chamber, physical damage due to plasma irradiation does not occur, and the surface of the transparent window and the sensor introduction part does not occur. As a result, the measurement system relating to the temperature control of the substrate is stabilized, the temperature stability and reproducibility of the heat treatment conditions are improved, and the process stability is improved. In addition, there is an advantage that the inside of the chamber can be kept clean and the generation of foreign matters such as particles can be suppressed.

  The purpose of providing a lamp heating apparatus that stabilizes a measurement system related to temperature control of a substrate is to clean the inside of the chamber with radicals when the cloudy state of the surface of the transparent window and the sensing unit exceeds a predetermined cloudy state. This was realized by enabling a series of operations of heating annealing and cleaning the inside of the chamber. Embodiments of the present invention will be described below with reference to the drawings.

  FIG. 1 is a simplified cross-sectional view of a lamp heating apparatus according to an embodiment, and FIG. 2 is a flowchart of a method for manufacturing a semiconductor device using the lamp heating apparatus. In FIG. 1, the same parts as those in the conventional apparatus shown in FIG.

  The lamp heating apparatus according to the embodiment includes a transparent window 15, a chamber 30 that houses the substrate 1 to be annealed, and a heating lamp 5 that heats the substrate 1 by radiant heat through the transparent window 15. The lamp heating apparatus further includes a radiation thermometer (not shown) that optically detects the temperature of the substrate 1 in which the sensing unit 6 formed of an optical fiber is provided in the chamber 30.

  After the wafer 1 is loaded by an automatic transfer mechanism (not shown), the chamber 30 is separated by the substrate support 4 and the wafer 1 to form two closed spaces. As a result, the front surface (surface on which the semiconductor device is formed) side of the wafer 1 and the back surface side of the wafer 1 have an independent space. The front side of the wafer 1 is defined as a space A2, and the back side of the wafer 1 is defined as a space B3. However, although the structure is separated by the wafer 1, the object of the present invention is not impaired even if the structure is not separated.

  A plurality of heating lamps 5 are installed on the space A2 side through transparent windows 15 for lamps. At the time of annealing, the radiant heat of the heating lamp 5 is transmitted to the wafer 1 through the transparent window 15. On the space B3 side, a radiation thermometer (not shown) for optically detecting the temperature of the wafer 1 and a sensing unit 6 made of an optical fiber connected to a light amount sensor (not shown) are provided. The radiation thermometer and the light quantity sensor can be switched by an optical switch (not shown).

  An optical fiber 14 connected to an LED light source (not shown) is provided at a position symmetrical to the sensing unit 6 with the chamber 30 interposed therebetween. When the wafer 1 is automatically unloaded and there is no obstruction, the light emitted from the LED light source passes through the optical fiber 14, passes through the transparent window 15, and passes through the optical path indicated by the dotted line in the chamber. It passes through 30 and reaches the sensing unit 6 from the surface of the sensing unit 6 constituted by an optical fiber. For this reason, when the wafer 1 is not installed, the amount of light reaching the sensing unit 6 can be obtained to detect clouding of both fiber surfaces and clouding of the transparent window 15.

Further, a gas supply port 16 and a gas discharge port 17 are provided on the side wall portion of the chamber 30 so as to face each other. A gas supply system 7 for supplying N ₂ gas as a process gas and a gas supply system 8 for supplying hydrogen radicals as a cleaning gas are connected to the gas supply port 16 in the space A2.

  The radical generator 20 is of a remote plasma type separated from the chamber 30. By applying a high frequency (eg, 2.45 GHz) supplied from the waveguide 12 from the outside while reducing the pressure in the pipe (eg, 200 Pa), the hydrogen gas in the pipe is turned into plasma. Thereby, hydrogen radicals are generated. On the other hand, a gas discharge system 9 for discharging the gas in the space A <b> 2 to the outside of the chamber 30 is connected to the gas discharge port 17.

In this embodiment, the case where a single hydrogen gas is used as the gas supplied to the radical generating unit 20 is exemplified. However, in addition to the single hydrogen gas, oxygen, carbon fluoride, or each mixed gas is used. Alternatively, it is possible to select a gas diluted with an inert gas such as helium. In addition to N ₂ , an inert gas such as helium, an oxygen-containing gas (for example, N ₂ O) or a gas obtained by diluting them with an inert gas such as helium is used as the process gas. It is also possible to do.

Further, a gas supply port 18 and a gas discharge port 19 are provided in the space B3. A gas supply system 10 for supplying N ₂ gas into the space B 3 is connected to the gas supply port 18, and a gas for discharging the gas in the space B 3 to the outside of the chamber 30 is connected to the gas discharge port 19. A discharge system 11 is connected. Also in this gas system, in addition to N ₂ , in the same manner as the above process gas, an inert gas such as helium, an oxidizing gas containing oxygen (for example, N ₂ O) or the like is diluted with an inert gas such as helium. It is also possible to use gas that has been removed.

  Next, an example of the RTA processing procedure of the semiconductor device will be described with reference to the flowchart of FIG.

  Referring to FIGS. 1 and 2, in step S1, the inside of chamber 30 is replaced with nitrogen gas (process gas). In step S2, the wafer (Si wafer) 1 is automatically transported (substrate loaded) into the chamber 30 where the inside is replaced with nitrogen gas, and placed on the substrate support portion 4, thereby forming the space A2 and the space B3. Form.

  Next, the gas in the space B3 is supplied and exhausted at a predetermined flow rate. The flow rate and the exhaust amount are controlled so that the space B3 is slightly negative compared to the space A2 so that the wafer 1 does not float. Usually, in the annealing at the time of phosphorus doping, the outward diffusion 13 of phosphorus occurs, so that diffusion and activation are performed while the oxidation is advanced by an oxidizing agent such as oxygen gas. However, since this apparatus has a cleaning mechanism, it does not oxidize due to process restrictions (for example, when boron dopant and phosphorous dopant implanted without a screen oxide film are activated simultaneously), and outward diffusion 13 is allowed. Even if it does, it is possible to reset the stain | pollution | contamination for every process. Furthermore, a desired thermal budget can be obtained by performing a single annealing process and a plurality of cleaning processes in between.

  Thereafter, in step S3, each heating lamp 5 is turned on, and the temperature of the wafer 1 is raised from room temperature (25 ° C.) to idle temperature (about 100 ° C.) to the uniformity stabilization temperature (about 400 ° C.). The temperature is rapidly increased (temperature increase) at a temperature gradient of about 50 to 300 ° C./second. During this time, the temperature of the back surface of the wafer 1 is measured over time without contact with a plurality of temperature sensors, and each heating lamp 5 is adjusted so that the in-plane temperature within the wafer 1 becomes uniform by a control device (not shown). Adjusts the heat output of or controls on / off. Such heating is performed for several seconds to several tens of seconds (temperature increase), and in step S4, the temperature is kept constant for a predetermined time from the time when the wafer 1 reaches a predetermined temperature, for example, 1000 ° C. (hold). . Note that the hold time may be zero as in spike annealing.

  In step S5, the lamp group is adjusted to be extinguished or to have a preheating heat output (temperature decrease). Subsequently, He gas is supplied into the space B3 together with the space A2 in the chamber 30 so that the wafer 1 is cooled from the front surface side and the back surface side. This substrate cooling process is continued until the temperature of the wafer 1 reaches a predetermined unloading temperature, for example, 750 ° C. In this case, the temperature is preferably lowered at a temperature lowering rate having a temperature gradient of about 50 to 300 ° C./second.

  Next, in step S6, the wafer 1 is automatically unloaded (substrate unloading). As a result, there is no obstacle between the light source and the sensor, and the amount of light can be checked. In this system, if a predetermined amount of light cannot be obtained due to the occurrence of fogging in step S7, the system automatically switches to the cleaning sequence by setting the threshold value of the light amount sensor (checking of the cloudy state). ).

  When the threshold value is exceeded, in step S8, supply of the process gas into the chamber 30 is stopped, and the inside of the chamber is evacuated (evacuation). After the evacuation is completed, hydrogen gas is supplied into a pipe for generating remote plasma (cleaning gas introduction) in step S9. In step S10, for example, after the piping and the chamber 30 are held at about 200 Pa, a high frequency of 2.45 GHz is applied to generate plasma. Thereby, hydrogen radicals are generated. By supplying hydrogen radicals into the chamber 30, phosphorus, boron, and arsenic adhering to the chamber 30 react with hydrogen and exhaust as hydrogenated gas.

  At this time, the light quantity is continuously checked in step S11. When the predetermined light quantity is reached, the high frequency is stopped (plasma stop) in step S12. Subsequently, in step S13, the supply of hydrogen is stopped (gas stop), and vacuuming is performed (evacuation). In step S14, the chamber atmosphere is replaced with nitrogen gas as a process gas (process gas replacement). Returning to S2, the next wafer 1 is carried in and processed.

  In the above embodiment, the process flow is completed for one sheet at a time. However, the heat treatment is divided into a plurality of times by preliminarily collecting data on fogging, and the equivalent heat is obtained. It is also possible to obtain a history.

  Moreover, although the silicon wafer was illustrated as a wafer in the said Example, this invention is not limited to this.

  It should be understood that the embodiments disclosed herein are illustrative and non-restrictive in every respect. The scope of the present invention is defined by the terms of the claims, rather than the description above, and is intended to include any modifications within the scope and meaning equivalent to the terms of the claims.

  According to the present invention, the thermal history of the substrate can be reduced, so that the device can be miniaturized and thinned.

1 is a simplified cross-sectional view of a heat treatment apparatus according to the present invention. It is a flowchart of the process in the heat processing apparatus shown in FIG. It is a simplified sectional view of a conventional heat treatment apparatus.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Wafer 4 Substrate support part 5 Heating lamp 6 Sensing part 7 Gas supply system (process gas)
8 Gas supply system (cleaning gas)
9 Gas exhaust system (process gas & cleaning gas)
10 Gas supply system (for space B)
11 Gas exhaust system (for space B)
DESCRIPTION OF SYMBOLS 12 Waveguide 13 Outward diffusion 14 Optical fiber 15 Transparent window 16, 18 Gas supply port 17, 19 Gas discharge port 20 Radical generation part 30 Chamber

Claims (6)

A chamber having a transparent window and containing a substrate;
A heating lamp for heating the substrate by the radiant heat through the transparent window;
A radiation thermometer that is provided in the chamber and optically detects the temperature of the substrate;
Radical supplying means for generating radicals outside the chamber and supplying the radicals into the chamber;
Means for determining when to clean the inside of the chamber from the cloudy state of the surface of the transparent window and the sensing unit;
Lamp heating device that enables a series of operations to anneal the substrate and clean the inside of the chamber.   2. The lamp heating apparatus according to claim 1, wherein the radical is selected from the group consisting of hydrogen, oxygen, and a fluorocarbon compound.   The lamp heating apparatus according to claim 1, further comprising means for detecting a cloudy state of surfaces of the transparent window and the sensing unit.   2. The process of manufacturing a semiconductor device using the lamp heating apparatus according to claim 1, wherein the surface of the transparent window and the sensing unit is cleaned with the radicals during one or more annealing processes. A method for manufacturing a semiconductor device.   2. A process of manufacturing a semiconductor device using the lamp heating device according to claim 1, wherein the cloudy state of the surface of the transparent window and the sensing unit is detected, and cleaning with the radical is performed every time a predetermined cloudy state is exceeded. A method of manufacturing a semiconductor device. 2. A semiconductor device manufacturing process using a lamp heating device according to claim 1, wherein one annealing process is performed in a plurality of times with the radical cleaning step in between. Manufacturing method.

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