JP2006083434A - Electric protection method and electric protection apparatus - Google Patents

Electric protection method and electric protection apparatus Download PDF

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JP2006083434A
JP2006083434A JP2004270125A JP2004270125A JP2006083434A JP 2006083434 A JP2006083434 A JP 2006083434A JP 2004270125 A JP2004270125 A JP 2004270125A JP 2004270125 A JP2004270125 A JP 2004270125A JP 2006083434 A JP2006083434 A JP 2006083434A
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electrode body
rod
shaped electrode
insulating material
vertical pipe
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Yoshihiko Kudo
義彦 工藤
Masakazu Yamamoto
政和 山本
Akihiro Ito
彰洋 伊藤
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Kureha Engineering Co Ltd
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Kureha Engineering Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To stably, electrolytically protect a water-distribution vertical pipe in which a fire hydrant is installed, with a simple configuration. <P>SOLUTION: This electric protection apparatus is a cathodic protection apparatus for electrolytically protecting the inside of the water-distribution vertical pipe 5 in which the fire hydrant 8 is installed; and comprises a two-chamber type lead storage battery 4 as an external power source, a bar-type electrode body 1 composing an anode, and an insulating material that has a plurality of openings of which the open area ratio is set, and that covers the bar-type electrode body 1. The open area ratio of the openings is adjusted such that a desired protection current can be obtained. The bar-type electrode body 1 is inserted from a short pipe or the underground hydrant 8, which is installed in the upper part of the water-distribution vertical pipe 5. Not only the insertion part 11 of the bar-type electrode body 1, but also the insertion part 13 of an endoscope camera 12 is also installed in the short pipe or the underground hydrant 8. Accordingly, the inside of the water-distribution vertical pipe 5 can be observed through the endoscope camera 12. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、電気防食方法および電気防食装置に関し、特に、消火栓が設置される配水管の縦管内に錆が生じるのを防止する電気防食方法および電気防食装置に関するものである。   The present invention relates to an anticorrosion method and an anticorrosion device, and more particularly to an anticorrosion method and an anticorrosion device for preventing rust from being generated in a vertical pipe of a water pipe where a fire hydrant is installed.

消火栓が設置される配水管の縦管は、エアー溜りができやすく錆こぶが発生し易い。このような錆こぶは、水質を悪化させるだけでなく、水の出を悪くして消火活動にも悪影響を及ぼすおそれがある。ところが、従来、この配水縦管についての防食技術は知られていない。   The vertical pipe of the water pipe where the fire hydrant is installed is prone to air accumulation and rust humps are likely to occur. Such rust humps not only deteriorate the water quality, but also have a risk of adversely affecting fire fighting activities by deteriorating water. However, conventionally, there is no known anticorrosion technique for this water distribution vertical pipe.

一方、電気防食技術は、従来から知られている。一般的な電気防食は、防食対象をアノード(陽極)ではなく、カソード(陰極)としている。そして、電気防食の適用方式としては、外部電源方式と、流電陽極方式(犠牲陽極方式)とがある。外部電源方式は、直流電源を用い、流電陽極方式は、防食対象に、これより卑な金属を接続し、両者間の電位差を利用して防食電流を流す方法である。   On the other hand, the anti-corrosion technique has been conventionally known. In general anticorrosion, the object of corrosion protection is not an anode (anode) but a cathode (cathode). And as an application system of cathodic protection, there are an external power supply system and a galvanic anode system (sacrificial anode system). The external power source method uses a DC power source, and the galvanic anode method is a method in which a base metal is connected to the object to be protected and a corrosion preventing current is caused to flow by utilizing a potential difference between the two.

消火栓が設置される配水縦管内の電気防食を考えた場合、種々の解決すべき課題がある。まず、流電陽極方式を採用した場合には、消火栓が設置される配水管は上水道と兼用であるから、金属イオン(Al3+、Mg2+、Zn2+)の溶出が問題となる。 When considering the anti-corrosion in the water distribution vertical pipe where the fire hydrant is installed, there are various problems to be solved. First, when the galvanic anode method is adopted, since the water pipe in which the fire hydrant is installed is also used as the water supply, elution of metal ions (Al 3+ , Mg 2+ , Zn 2+ ) becomes a problem.

一方、外部電源方式を採用した場合には、電源の確保が問題となる。通常の外部電源方式では、商用電源(100V交流)を所望の電圧に変圧した後、整流(交流から直流へ変換)して、所望の直流電源を得ていた。ところが、消火栓が設置される配水縦管は、通常、道路の地下にあるため、商用電源の確保が問題となる。   On the other hand, when the external power supply method is adopted, securing the power supply becomes a problem. In a normal external power supply system, a commercial power supply (100 V AC) is transformed to a desired voltage and then rectified (converted from AC to DC) to obtain a desired DC power supply. However, since the water distribution vertical pipe where the fire hydrant is installed is usually in the basement of the road, securing a commercial power source becomes a problem.

外部電源方式でかつ商用電源(100V交流)が使えないとすると、各種電池から電力を供給することが考えられる。しかしながら、太陽電池を使用する場合には、構成が複雑となる上、昼間しか発電できないし、発生電圧も防食に必要な電圧と一致するとは限らず、確実で安定した電気防食を図れないおそれがある。また、マンガン乾電池やアルカリ乾電池などを使用する場合には、形状が単一・単二・単三と限られており、これを多数格納する容器を準備する必要があり実用的ではない。たとえば、1m長さの縦管を1年間防食するのに、単一乾電池では約100個も必要となる。消火栓は地下にあるのが殆どであり、小さなBOX内に収納されており、この中に電源を格納するためには、コンパクトでかつ自由度の高い形状である必要がある。   If it is an external power supply system and a commercial power supply (100 V AC) cannot be used, it is conceivable to supply power from various batteries. However, when a solar cell is used, the configuration is complicated and power can be generated only during the daytime, and the generated voltage does not always match the voltage required for anticorrosion, and there is a possibility that reliable and stable electrocorrosion cannot be achieved. is there. Further, when using a manganese dry battery, an alkaline dry battery or the like, the shape is limited to single, single, single or three, and it is necessary to prepare a container for storing a large number of them, which is not practical. For example, in order to prevent corrosion of a 1 m long vertical tube for one year, a single dry battery requires about 100 pieces. The fire hydrant is mostly in the basement and is housed in a small BOX, and in order to store the power supply in this, it is necessary to have a compact and highly flexible shape.

本発明は、上記事情に鑑みてなされたものであり、その主たる目的は、簡易な構成で安定した電気防食を図ることができ、特に消火栓が設置される配水縦管内を確実に防食するのに適する電気防食方法および電気防食装置を提供することにある。   The present invention has been made in view of the above circumstances, and its main purpose is to achieve stable anticorrosion with a simple configuration, particularly to reliably prevent corrosion in a water distribution vertical pipe where a fire hydrant is installed. The object is to provide a suitable cathodic protection method and cathodic protection device.

本発明は、前記課題を解決するためになされたもので、請求項1に記載の発明は、外部電源方式によるカソード防食方法であって、所定電圧を維持する外部電源を用い、防食電流の調整は、アノードを被覆する絶縁材の開口部を調整して行うことを特徴とする電気防食方法である。   The present invention has been made to solve the above-mentioned problems, and the invention according to claim 1 is a cathodic protection method using an external power supply system, and uses an external power supply that maintains a predetermined voltage to adjust the anticorrosion current. Is an anticorrosion method characterized by adjusting the opening of the insulating material covering the anode.

請求項2に記載の発明は、消火栓が設置される配水縦管内部を電気防食するカソード防食方法であって、外部電源として二室型鉛蓄電池を用い、アノードとして複数の開口部を有する絶縁材により被覆した棒状電極体を用い、所望防食電流が得られるように前記開口部の開口率が調整された棒状電極体を前記縦管内部に設置することを特徴とする電気防食方法である。   The invention according to claim 2 is a cathodic protection method for electrically protecting the inside of a water distribution vertical pipe in which a fire hydrant is installed, wherein a two-chamber lead storage battery is used as an external power source, and an insulating material having a plurality of openings as an anode The rod-shaped electrode body covered with the above-described method is used, and the rod-shaped electrode body in which the aperture ratio of the opening is adjusted so as to obtain a desired corrosion-proof current is installed inside the vertical pipe.

請求項3に記載の発明は、外部電源方式によるカソード防食装置であって、所定電圧を維持する外部電源と、アノードを構成する電極体と、この電極体を被覆し開口率が調整される絶縁材とを備えることを特徴とする電気防食装置である。   According to a third aspect of the present invention, there is provided an external power source type cathodic protection device, an external power source that maintains a predetermined voltage, an electrode body that constitutes an anode, and an insulation that covers the electrode body and adjusts an aperture ratio. It is an anticorrosion apparatus characterized by including a material.

請求項4に記載の発明は、消火栓が設置される配水縦管内部を電気防食するカソード防食装置であって、外部電源としての二室型鉛蓄電池と、アノードを構成する棒状電極体と、複数の開口部を有しかつ開口率が設定されて前記棒状電極体を被覆する絶縁材とを備えることを特徴とする電気防食装置である。   The invention according to claim 4 is a cathodic protection device that catalyzes the inside of a water distribution vertical pipe in which a fire hydrant is installed, and includes a two-chamber lead storage battery as an external power source, a rod-shaped electrode body that constitutes an anode, And an insulating material that covers the rod-shaped electrode body with an opening ratio set.

さらに、請求項5に記載の発明は、請求項4に記載の構成要件に加えて、前記配水縦管上部に設けられる短管または地下式消火栓に、前記棒状電極体と内視鏡カメラの挿入部が設けられており、この挿入部から前記配水縦管内に、前記棒状電極体および前記内視鏡カメラが挿入されることを特徴とする電気防食装置である。   Furthermore, in addition to the constituent features of claim 4, the invention according to claim 5 inserts the rod-shaped electrode body and the endoscope camera into a short pipe or an underground fire hydrant provided at the upper part of the water distribution vertical pipe. The rod-shaped electrode body and the endoscopic camera are inserted into the water distribution vertical pipe from the insertion portion.

本発明の電気防食方法および電気防食装置によれば、簡易な構成で安定した電気防食を図ることができる。特に、消火栓が設置される配水縦管内の電気防食を、簡易な構成で実現できる。   According to the cathodic protection method and the cathodic protection device of the present invention, stable cathodic protection can be achieved with a simple configuration. In particular, the anticorrosion in the water distribution vertical pipe where the fire hydrant is installed can be realized with a simple configuration.

つぎに、本発明の実施の形態について説明する。本発明の電気防食方法および電気防食装置は、上水道配水管の縦管部に好適に適用される。そこで、ここでは本発明をこの配水縦管へ適用した例について説明する。この配水縦管の上部には、補修弁を介して消火栓が設置される。   Next, an embodiment of the present invention will be described. The cathodic protection method and the cathodic protection device of the present invention are preferably applied to a vertical pipe portion of a water supply water pipe. Therefore, here, an example in which the present invention is applied to this water distribution vertical pipe will be described. A fire hydrant is installed in the upper part of the water distribution pipe through a repair valve.

本実施形態の電気防食装置は、配水縦管内に差し込まれる棒状電極体と、防食電流発生用の外部電源装置とを主要部として備える。そして、外部電源装置により、棒状電極体をアノード、配水縦管をカソードとして通電することで、配水縦管を電気防食するものである。導電性の棒状電極体は、絶縁材により被覆されており、この絶縁材には、複数の開口部が形成されている。従って、棒状電極体は、個々の開口部において外部へ露出し、その開口部を介して配水縦管との間に防食電流を流して、配水縦管を電気防食する。なお、棒状電極体は、配水縦管の上部に設置される消火栓や短管などから、外部に対し水密状態で配水縦管の下部まで挿入されて設置される。   The cathodic protection device of the present embodiment includes a rod-shaped electrode body inserted into a water distribution vertical pipe and an external power supply device for generating a corrosive protection current as main parts. Then, the water distribution vertical pipe is electrically anticorrosive by energizing the rod-shaped electrode body as an anode and the water distribution vertical pipe as a cathode by an external power supply device. The conductive rod-shaped electrode body is covered with an insulating material, and a plurality of openings are formed in the insulating material. Therefore, the rod-shaped electrode body is exposed to the outside at each opening, and an anticorrosion current is passed between the opening and the water distribution vertical pipe to electrically prevent the water distribution vertical pipe. In addition, the rod-shaped electrode body is inserted and installed from a fire hydrant or a short pipe installed at the upper part of the water distribution vertical pipe to the lower part of the water distribution vertical pipe in a watertight state with respect to the outside.

消火栓が設置される配水縦管においては、商用電源(100V交流)を確保しにくいので、本実施形態では外部電源として鉛蓄電池を用いる。特に、次に述べる理由により、二室型鉛蓄電池が好適に用いられる。鉛蓄電池の電圧は、一室(1セル)当たり2Vであるから、二室型鉛蓄電池は4Vとなる。   In a water distribution vertical pipe where a fire hydrant is installed, it is difficult to secure a commercial power supply (100 V AC), and therefore, in this embodiment, a lead storage battery is used as an external power supply. In particular, a two-chamber lead storage battery is preferably used for the following reason. Since the voltage of the lead storage battery is 2 V per room (one cell), the voltage of the two-chamber lead storage battery is 4 V.

二室型鉛蓄電池を用いる理由は、次のとおりである。すなわち、まず消火栓の口径は、75mmまたは100mmなどと限定されている。このため電極(アノード)と、配水縦管壁(カソード)との距離も限定される。そして、日本の上水道の導電率は、50〜300μS/cm程度であり、また防食所要電流として、50mA/m(カソード面積)が標準とされている。これら事情(導電率、カソードとアノード間の距離、防食に必要な電流)を勘案すると、およそ、3〜4Vが必要となる。よって、配水縦管の電気防食において、鉛蓄電池を外部電源として使用する場合、一室(2V)では所要電圧が不足し、三室(6V)では電圧が不必要に高過ぎ、電力が無駄となる。 The reason for using the two-chamber lead storage battery is as follows. That is, first, the diameter of the fire hydrant is limited to 75 mm or 100 mm. For this reason, the distance between the electrode (anode) and the water distribution vertical pipe wall (cathode) is also limited. And the electrical conductivity of Japanese waterworks is about 50-300 micro S / cm, and 50 mA / m < 2 > (cathode area) is standard as an anticorrosion required electric current. Considering these circumstances (conductivity, distance between cathode and anode, current necessary for anticorrosion), approximately 3 to 4 V is required. Therefore, when using lead-acid batteries as an external power source in the cathodic protection of water distribution vertical pipes, the required voltage is insufficient in one room (2V), the voltage is unnecessarily high in three rooms (6V), and power is wasted. .

ところで、従前の一般的な外部電源方式の電気防食方法は、所要の防食電流を得るためには、電圧を調整すればよかった。つまり、従前は、商用電源(100V交流)を外部電源として用い、所望の電圧に変圧した後、整流(交流から直流へ変換)して、所望の直流電圧を得ていた。ところが、本実施形態のように、所定電圧(ここでは4V)を維持する外部電源を使用した場合、防食電流の調整を如何に行うかが問題となる。   By the way, in a conventional general external power source type anticorrosion method, the voltage should be adjusted in order to obtain a required anticorrosion current. That is, in the past, a commercial power supply (100V AC) was used as an external power supply, transformed to a desired voltage, and then rectified (converted from AC to DC) to obtain a desired DC voltage. However, when an external power supply that maintains a predetermined voltage (here, 4 V) is used as in this embodiment, there is a problem of how to adjust the anticorrosion current.

本発明においては、従前のような電圧調整によらず、むしろ印加電圧は一定に維持しつつ、防食電流の調整を可能に構成した。すなわち、アノードを構成する棒状電極体を絶縁材で被覆し、その絶縁材に形成する開口部(その大きさ・数・割合など)を変化させることで対応したことによる。本実施形態では、物理的機械的強度を保持するために、アノードとして直径2〜5mmの棒状金属材を用い、これを被覆する絶縁材に形成する多数の小穴の数を変化させて、アノード面積(小穴部の面積)を変化させ、防食電流を制御する。なお、このような制御が可能となる理由は、アノードの酸素過電圧がアノード電流密度に依存し、変化するためである。   In the present invention, the anticorrosion current can be adjusted while maintaining the applied voltage constant rather than the voltage adjustment as before. That is, this is because the rod-shaped electrode body constituting the anode is covered with an insulating material, and the openings (the size, number, ratio, etc.) formed in the insulating material are changed. In this embodiment, in order to maintain the physical mechanical strength, a rod-shaped metal material having a diameter of 2 to 5 mm is used as the anode, and the number of small holes formed in the insulating material covering the anode is changed to change the anode area. The (corrosion prevention current) is controlled by changing (the area of the small hole). The reason why such control is possible is that the oxygen overvoltage of the anode changes depending on the anode current density.

以下、本発明の具体的実施例を図面に基づいて詳細に説明する。
図1は、本発明の電気防食装置のアノードを示す概略拡大図であり、(A)は正面図、(B)はそのX−X断面図である。この図に示すように、本実施例のアノードは、細長い導電性の棒状電極体1からなり、その外面は絶縁性の被膜(絶縁材)2によって被覆されている。本実施例では、絶縁材2として細長い円筒状の熱収縮チューブが用いられ、予め適宜の小穴3(3a,3b)を多数形成した後、棒状電極体1にはめ込んで、加熱して収縮させ、棒状電極体1に密着させて一体化している。
Hereinafter, specific embodiments of the present invention will be described in detail with reference to the drawings.
FIG. 1: is a schematic enlarged view which shows the anode of the cathodic protection apparatus of this invention, (A) is a front view, (B) is the XX sectional drawing. As shown in this figure, the anode of the present embodiment is composed of an elongated conductive rod-shaped electrode body 1 whose outer surface is covered with an insulating coating (insulating material) 2. In this embodiment, an elongated cylindrical heat-shrinkable tube is used as the insulating material 2, and after forming a large number of appropriate small holes 3 (3a, 3b) in advance, it is fitted into the rod-shaped electrode body 1 and heated to shrink, The rod-shaped electrode body 1 is brought into close contact with and integrated.

棒状電極体1への絶縁材2の取付状態では、棒状電極体1の外周面および先端面は絶縁材2で被覆されるが、棒状電極体1の基端部1aは絶縁材2から露出される。そして、このようなアノードは、棒状電極体1の前記露出部1aを介して外部電源4(図2参照)へ電気的に接続される。なお、熱収縮チューブからなる絶縁材2への小穴3の形成は、棒状電極体1に被せる前に、予めその円形断面をつぶすように平らにした状態で、パンチにより小穴3を貫通形成している。   In the state in which the insulating material 2 is attached to the rod-shaped electrode body 1, the outer peripheral surface and the distal end surface of the rod-shaped electrode body 1 are covered with the insulating material 2, but the base end portion 1 a of the rod-shaped electrode body 1 is exposed from the insulating material 2. The And such an anode is electrically connected to the external power supply 4 (refer FIG. 2) through the said exposed part 1a of the rod-shaped electrode body 1. FIG. The small holes 3 are formed in the insulating material 2 made of a heat-shrinkable tube by penetrating the small holes 3 with a punch in a state in which the circular cross section is flattened in advance before covering the rod-shaped electrode body 1. Yes.

棒状電極体1の材質や大きさは、適宜に設定される。本実施例の棒状電極体1は、たとえば直径4mmのチタン製の棒材からなり、その表面には、たとえば厚さ0.3μmの酸化イリジウム(IrO2)を主成分とするコーティングが施されている。棒状電極体1の長さは、設置時に配水縦管5の底部、すなわち縦管5下部の配水管6まで延出する程度の長さとするのが好ましい(図4参照)。棒状電極体1を被覆する絶縁材2も適宜のものが採用されるが、本実施例の絶縁材2は、厚さ0.25mmの樹脂製熱収縮チューブを採用した。 The material and size of the rod-shaped electrode body 1 are appropriately set. The rod-shaped electrode body 1 of the present embodiment is made of, for example, a titanium rod having a diameter of 4 mm, and the surface thereof is coated with, for example, iridium oxide (IrO 2 ) having a thickness of 0.3 μm as a main component. . The length of the rod-shaped electrode body 1 is preferably set to a length that extends to the bottom of the water distribution vertical pipe 5, that is, the water distribution pipe 6 below the vertical pipe 5 at the time of installation (see FIG. 4). As the insulating material 2 covering the rod-shaped electrode body 1, an appropriate one is adopted, but the insulating material 2 of the present embodiment employs a resin heat shrinkable tube having a thickness of 0.25 mm.

絶縁材2に形成される小穴3の開口率を調整することで、棒状電極体1の露出部を調整し、防食電流を調整することができる。どのような開口率で使用するかは、防食装置適用箇所の水の導電率を考慮して決定される。水の導電率と絶縁仕様との相関をみるために、ここでは図2に示すような実験装置にて実験を行った。   By adjusting the aperture ratio of the small holes 3 formed in the insulating material 2, the exposed portion of the rod-shaped electrode body 1 can be adjusted, and the anticorrosion current can be adjusted. The aperture ratio to be used is determined in consideration of the conductivity of water at the location where the anticorrosion device is applied. In order to see the correlation between the electrical conductivity of the water and the insulation specifications, an experiment was conducted using an experimental apparatus as shown in FIG.

この実験装置では、100A(内径105.3mm)、長さ0.95mの鋼管(SGP管)5を立てた状態で用いた。この鋼管5の底部は、透明塩ビ製の底板7で蓋がなされており、この底板7の上面中心部には凹穴7aを形成している。そして、この鋼管5に、上述した直径4mm棒状電極体1を差し込み、その先端部(下端部)を前記凹穴7aに差し込み固定した。さらに、棒状電極体1をアノード、鋼管5をカソードとするために、外部電源(直流4V)4の正極(+)に棒状電極体1の基端部1aを接続し、外部電源4の負極(−)に鋼管5を接続した。その状態で、鋼管5内を水道水で満たして通電し、防食電流を計測する。ここでは、福島県いわき市と兵庫県神戸市の各上水道について実験した。実験に用いた水道水の導電率は、いわき市の水が64μS/cm、神戸市の水が267μS/cmであり、さらに352μS/cmの水についても調査した。   In this experimental apparatus, a steel pipe (SGP pipe) 5 of 100A (inner diameter 105.3 mm) and length 0.95 m was used. The bottom of the steel pipe 5 is covered with a bottom plate 7 made of transparent vinyl chloride, and a concave hole 7a is formed at the center of the upper surface of the bottom plate 7. And the 4 mm diameter rod-shaped electrode body 1 mentioned above was inserted in this steel pipe 5, and the front-end | tip part (lower end part) was inserted and fixed to the said concave hole 7a. Further, in order to use the rod-shaped electrode body 1 as an anode and the steel tube 5 as a cathode, the base end portion 1a of the rod-shaped electrode body 1 is connected to the positive electrode (+) of the external power source (DC 4V) 4 and the negative electrode ( The steel pipe 5 was connected to-). In that state, the steel pipe 5 is filled with tap water and energized, and the anticorrosion current is measured. Here, experiments were conducted on waterworks in Iwaki City, Fukushima Prefecture and Kobe City, Hyogo Prefecture. The conductivity of tap water used in the experiment was 64 μS / cm for water in Iwaki City, 267 μS / cm for water in Kobe City, and 352 μS / cm water was also investigated.

実験においては、絶縁仕様を変えた複数の棒状電極体1を作成し、それぞれの場合の防食電流を計測した。実験に用いた絶縁仕様は、次の[絶縁材A]〜[絶縁材E]である。   In the experiment, a plurality of rod-shaped electrode bodies 1 having different insulation specifications were created, and the anticorrosion current in each case was measured. The insulation specifications used in the experiment are the following [insulating material A] to [insulating material E].

[絶縁材A] 図1に示すように、長さ10cmに付き38個の小穴3(3a,3b)を、棒状電極体1の正面と背面の両側に、それぞれ複列形成した絶縁材(複列)。各小穴3の直径は、それぞれ1.14mmである。厳密には、各小穴3は多少の大小があり、また直径測定にも誤差があるが、この場合の開口率は、概ね次のとおり計算される。すなわち、この場合の開口率は、{(1.14mm)2×(π/4)×38×2×2}/{100mm×4mm×π}=0.123として計算される。なお、この場合、1m当たりの開口面積は、15.5cm2/mである。 [Insulating Material A] As shown in FIG. 1, an insulating material (compounds) in which 38 small holes 3 (3a, 3b) each having a length of 10 cm are formed in double rows on both the front and back sides of the rod-shaped electrode body 1, respectively. Column). Each small hole 3 has a diameter of 1.14 mm. Strictly speaking, each small hole 3 is somewhat large and there is an error in diameter measurement. In this case, the aperture ratio is calculated as follows. That is, the aperture ratio in this case is calculated as {(1.14 mm) 2 × (π / 4) × 38 × 2 × 2} / {100 mm × 4 mm × π} = 0.123. In this case, the opening area per meter is 15.5 cm 2 / m.

[絶縁材B] 前記Aを単列にした絶縁材(単列)。すなわち、長さ10cmに付き38個の小穴3が、棒状電極体1の正面と背面の両側に、それぞれ一列だけ(図1において小穴3aのみ)形成された絶縁材。この場合の開口率は、前記Aの1/2となる。   [Insulating material B] An insulating material (single row) in which A is arranged in a single row. That is, an insulating material in which 38 small holes 3 each having a length of 10 cm are formed in a single row (only the small holes 3 a in FIG. 1) on both sides of the front surface and the back surface of the rod-shaped electrode body 1. In this case, the aperture ratio is ½ of A.

[絶縁材C] 前記Bの穴を一つおきとした絶縁材(単列1/2)。   [Insulating material C] Insulating material (single row 1/2) in which every other B hole is provided.

[絶縁材D] 前記Bの穴を8個おきとした絶縁材(単列1/8)。   [Insulating Material D] Insulating material (single row 1/8) in which the B holes are every eight holes.

[絶縁材E] 前記Bの穴を16個ごとに一つとした絶縁材(単列1/16)。   [Insulating Material E] An insulating material (single row 1/16) in which the B holes are one for every 16 holes.

実験の結果、たとえば複列の絶縁材Aの場合、いわき市の水に対し22mAの電流が流れた。これは、防食電流密度としては74mA/mとなり、通常必要とされる50mA/mより多く十分防食されているといえる値である。なお、この状態のまま1週間を経過したが、内部の水に何らの濁りを認められなかった。一方、比較例として、通電せず放置した場合には、一日にて若干の濁り(赤いさび)が認められた。また、一週間後には、鋼管5の底部に、赤いさびが薄く沈積した。 As a result of the experiment, for example, in the case of the double row insulating material A, a current of 22 mA flowed to the water in Iwaki City. This is as a protective current density is a value said to be more fully corrosion than 50 mA / m 2 to be 74mA / m 2, and the normally required. One week passed in this state, but no turbidity was observed in the internal water. On the other hand, as a comparative example, when left unpowered, some turbidity (red rust) was observed in one day. Further, after one week, red rust was thinly deposited on the bottom of the steel pipe 5.

図3には、両対数グラフにて実験結果を示した。この図では、縦軸に計測した防食電流値(mA)をとり、横軸にアノード露出面積(cm/m)および開口率をとっている。この図から、被膜2がなくなるほど、大きな防食電流が流れることが分かる。所要の防食電流密度は50mA/mであるから、各水道水に対し有効な開口率は、その電流値になる開口率を逆算すればよい。実験例では、いわき市については、単列絶縁材において、2/3が穴ありで、残り1/3が穴なしに形成すればよいことが分かった。また、神戸市については、単列絶縁材において、1/20が穴ありで、残り19/20が穴なしに形成すればよいことが分かった。このようにして、各地の市水の導電率に合わせて、開口率(小穴の数)を変え、適正な防食電流密度(約50mA/m)となるようすればよい。 FIG. 3 shows the experimental results in a log-log graph. In this figure, the vertical axis represents the measured anticorrosion current value (mA), and the horizontal axis represents the anode exposed area (cm 2 / m) and the aperture ratio. From this figure, it can be seen that the greater the coating 2, the greater the anticorrosion current flows. Since the required anticorrosion current density is 50 mA / m 2 , the effective aperture ratio for each tap water may be calculated by calculating back the aperture ratio at which the current value is obtained. In the experimental example, it was found that in Iwaki City, it is sufficient to form a single-row insulating material with 2/3 having holes and the remaining 1/3 without holes. As for Kobe city, it was found that in a single-row insulating material, 1/20 should be formed with holes and the remaining 19/20 without holes. In this way, the aperture ratio (number of small holes) may be changed in accordance with the conductivity of city water in each place so as to obtain an appropriate anticorrosion current density (about 50 mA / m 2 ).

図4は、本発明の電気防食装置の一実施例の使用状態を示す図であり、一部を断面にして示している。
浄水場や配水場からの配水管6には、垂直上方へ向けて分岐する金属製管(鋼管、鋳鉄管)からなる縦管5を介して消火栓8が設けられる。この消火栓8は、配水管6から分岐した縦管5の上端部に、補修弁9を介して設けられる。この消火栓8や補修弁9は、地下に埋設されたボックス10内に収容されている。なお、配水管6には、サドル分水栓を介して給水管(不図示)が接続分岐され、この給水管を介して各家庭へ水が供給される。
FIG. 4 is a view showing a use state of an embodiment of the cathodic protection device of the present invention, and a part thereof is shown in cross section.
The water distribution pipe 6 from the water purification plant or the water distribution station is provided with a fire hydrant 8 through a vertical pipe 5 made of a metal pipe (steel pipe, cast iron pipe) that branches vertically upward. The fire hydrant 8 is provided at the upper end of the vertical pipe 5 branched from the water distribution pipe 6 via a repair valve 9. The fire hydrant 8 and the repair valve 9 are accommodated in a box 10 buried underground. A water supply pipe (not shown) is connected and branched to the water distribution pipe 6 via a saddle water faucet, and water is supplied to each household via this water supply pipe.

消火栓8は、地下式消火栓であり、排気弁または空気弁が備えられているものがよい(地下式消火栓排気弁付、地下式空気弁消火栓)。また、空気弁が内蔵されたものがより好ましい(地下式空気弁内蔵消火栓)。さらに、本実施例の地下式消火栓8には、電気防食装置の棒状電極体1の挿入部11と、内視鏡カメラ12の挿入部13とが設けられている。前記各挿入部11,13は、消火栓8の下部フランジ8aよりも上方で、消火栓8内部の開閉弁による封止部(不図示)よりも下方に設けられる。なお、消火栓8の下部フランジ8aは、補修弁9の上部フランジ9aに水密状態に連結され、補修弁9の下部フランジ9bは、縦管5の上部フランジ5aに水密状態に連結される。   The fire hydrant 8 is an underground fire hydrant and is preferably provided with an exhaust valve or an air valve (with underground fire hydrant exhaust valve, underground air valve fire hydrant). Moreover, the thing with the built-in air valve is more preferable (underground air valve built-in fire hydrant). Furthermore, the underground fire hydrant 8 of the present embodiment is provided with an insertion portion 11 for the rod-shaped electrode body 1 and an insertion portion 13 for the endoscope camera 12 of the electric protection device. The insertion portions 11 and 13 are provided above the lower flange 8a of the fire hydrant 8 and below a sealing portion (not shown) formed by an on-off valve inside the fire hydrant 8. The lower flange 8a of the fire hydrant 8 is connected to the upper flange 9a of the repair valve 9 in a watertight state, and the lower flange 9b of the repair valve 9 is connected to the upper flange 5a of the vertical tube 5 in a watertight state.

棒状電極体1の挿入部11は、消火栓8の弁箱(外壁)を貫通した開口部に、パッキン(不図示)が収容保持されて構成される。このパッキンを介して、棒状電極体1が消火栓8ひいては配水縦管5内へ湾曲しながら挿入される。このパッキンは、絶縁材2付き棒状電極体1の外周部を締め付けた状態であるが、棒状電極体1の進退は可能である。従って、配水管6からの水漏れを防ぎつつ、消火栓8の外側から内側へ配水縦管5内に、棒状電極体1を送り込んで設置することができる。   The insertion part 11 of the rod-shaped electrode body 1 is configured such that a packing (not shown) is accommodated and held in an opening that penetrates the valve box (outer wall) of the fire hydrant 8. Through this packing, the rod-shaped electrode body 1 is inserted into the fire hydrant 8 and thus into the water distribution vertical pipe 5 while being bent. This packing is in a state in which the outer peripheral portion of the rod-shaped electrode body 1 with the insulating material 2 is fastened, but the rod-shaped electrode body 1 can be advanced and retracted. Therefore, the rod-shaped electrode body 1 can be sent and installed in the water distribution vertical pipe 5 from the outside to the inside of the fire hydrant 8 while preventing water leakage from the water distribution pipe 6.

ところで、棒状電極体1は、前記実験で用いたもの、すなわち絶縁材(熱収縮チューブ)2により被覆された酸化イリジウムコーティングのチタン棒1を使用することができる。そして、熱収縮チューブからなる絶縁材2には、設置箇所の水の導電率に合わせた開口率で小穴3が形成されている。この小穴3は、棒状電極体1の使用時に、配水縦管5内へ挿入される箇所に形成すれば足りる。また、このような棒状電極体1は、その基端側においてチタン棒1が、二室型鉛蓄電池4の正極(+)に接続され、その負極(−)は消火栓8(またはそれに接続される補修弁9や縦管5)に接続される。なお、チタン棒1の表面には絶縁材2が被覆されているので、仮に棒状電極体1が縦管5内面に接触しても、電気的に導通することはない。このようにして、縦管5の電気防食が有効に図られる。   By the way, the rod-shaped electrode body 1 can be the same as that used in the experiment, that is, the iridium oxide-coated titanium rod 1 covered with the insulating material (heat shrinkable tube) 2. And the small hole 3 is formed in the insulating material 2 which consists of a heat-shrinkable tube with the aperture ratio matched with the electrical conductivity of the water of an installation location. It is sufficient that the small hole 3 is formed at a place where the small electrode 3 is inserted into the water distribution vertical pipe 5 when the rod-shaped electrode body 1 is used. Further, in such a rod-shaped electrode body 1, the titanium rod 1 is connected to the positive electrode (+) of the two-chamber lead-acid battery 4 at the base end side, and the negative electrode (−) is connected to the fire hydrant 8 (or to it). It is connected to the repair valve 9 and the vertical pipe 5). Since the surface of the titanium rod 1 is covered with the insulating material 2, even if the rod-shaped electrode body 1 comes into contact with the inner surface of the vertical tube 5, there is no electrical conduction. In this way, the anticorrosion of the vertical pipe 5 is effectively achieved.

内視鏡カメラ12は、縦管5内の状況を観察するためのものである。先端部にカメラ本体12aを有するカメラケーブル12bは、基端部においてドラム12cに巻かれている。このドラム12cからケーブル12bを繰り出したり、逆にドラム12cにケーブル12bを巻き取ったりすることができる。このような内視鏡カメラ12は、消火栓8に設けたカメラ挿入口13から、消火栓8ひいては配水縦管5内へ挿入される。   The endoscope camera 12 is for observing the situation inside the vertical tube 5. A camera cable 12b having a camera body 12a at the distal end is wound around a drum 12c at the proximal end. The cable 12b can be fed out from the drum 12c, and conversely, the cable 12b can be wound around the drum 12c. Such an endoscope camera 12 is inserted into the fire hydrant 8 and thus into the water distribution vertical pipe 5 from the camera insertion port 13 provided in the fire hydrant 8.

カメラ挿入口13は、消火栓8の弁箱から分岐して設けられた管体からなり、その管末部は、カメラ挿入具14が着脱可能となる挿入具取付部13a(図5参照)とされている。具体的には、この挿入具取付部13aは、フランジまたはネジ部などに形成されている。また、カメラ挿入口13を構成する管体の中央部には、開閉弁13b(図5参照)が設けられている。   The camera insertion port 13 is composed of a pipe body branched from the valve box of the fire hydrant 8, and the tube end portion is an insertion tool attachment portion 13 a (see FIG. 5) to which the camera insertion tool 14 can be attached and detached. ing. Specifically, the insertion tool attachment portion 13a is formed on a flange or a screw portion. In addition, an opening / closing valve 13b (see FIG. 5) is provided in the central portion of the tubular body constituting the camera insertion port 13.

一方、カメラ挿入具14は中空ボックス状とされ、この中空ボックスは、前記挿入具取付部13への連結側となる先端側に開口している。また、この中空ボックス14内には、カメラ本体12aが収容可能である。そして、カメラケーブル12bは、中空ボックス14の基端部からパッキンを介して外部へ導出されている。従って、消火栓8のカメラ挿入口13から配水縦管5内へカメラ12を挿入するには、まず前記開閉弁13bを閉じた状態で、挿入具取付部13aにカメラ挿入具14を連結し、開閉弁13bを開けた後、カメラケーブル12bを押し込むことで、カメラ本体12aを消火栓8ひいては配水縦管5内へ挿入できる。   On the other hand, the camera insertion tool 14 has a hollow box shape, and this hollow box is open to the distal end side which is a connection side to the insertion tool mounting portion 13. The hollow box 14 can accommodate the camera body 12a. The camera cable 12b is led out from the base end of the hollow box 14 through a packing. Therefore, in order to insert the camera 12 from the camera insertion port 13 of the fire hydrant 8 into the water distribution vertical pipe 5, first, the camera insertion tool 14 is connected to the insertion tool mounting portion 13a with the opening / closing valve 13b closed, and the opening / closing operation is performed. After opening the valve 13b, the camera body 12a can be inserted into the fire hydrant 8 and thus into the water distribution vertical pipe 5 by pushing the camera cable 12b.

このように、本実施例の構成によれば、不断水で容易にカメラ12の挿入が可能である。しかも、設置状態においても、中空ボックス14のパッキンを介してカメラケーブル12bは、外部へ水密状態に導出されるので、消火栓8の外側へ水が漏れるおそれもない。逆に、カメラ12を取り外す際には、ケーブル12bを引っ張ってカメラ挿入具(中空ボックス)14内にカメラ本体12aを収容した後、前記開閉弁13bを閉じてから、カメラ挿入具14を消火栓8から取り外せばよい。そして、カメラ挿入具14を取り付けない通常時には、挿入具取付部13aには、蓋をしておけばよい。   As described above, according to the configuration of the present embodiment, the camera 12 can be easily inserted with continuous water. Moreover, even in the installed state, the camera cable 12b is led out to the outside in a watertight state through the packing of the hollow box 14, so that there is no risk of water leaking outside the fire hydrant 8. Conversely, when removing the camera 12, the cable 12b is pulled to house the camera body 12a in the camera insertion tool (hollow box) 14, and then the on-off valve 13b is closed, and then the camera insertion tool 14 is connected to the fire hydrant 8 You can remove it. When the camera insertion tool 14 is not normally attached, the insertion tool attachment portion 13a may be covered.

このようにして、本実施例によれば、配水縦管5内に内視鏡カメラ12を挿入することで、管内の錆こぶや赤水の状況や原因確認が容易にできる。また、防食装置の効果や検証も可能となり、鉛蓄電池4の能力や個数、あるいは棒状電極体1の絶縁材2に形成する小穴3の開口率の調整(開口率の異なる棒状電極体1の入換え)なども行うことができる。よって、鉛蓄電池4の寿命の検討もできる。さらに、棒状電極体1が望ましい位置にあるかの確認も可能である。   In this way, according to the present embodiment, by inserting the endoscope camera 12 into the water distribution vertical pipe 5, it is possible to easily check the status and cause of rust humps and red water in the pipe. In addition, the effect and verification of the anticorrosion device can be made, and the capacity and number of the lead storage batteries 4 or the opening ratio of the small holes 3 formed in the insulating material 2 of the rod-shaped electrode body 1 can be adjusted (the insertion of the rod-shaped electrode bodies 1 having different opening ratios). Can also be performed. Therefore, the life of the lead storage battery 4 can also be examined. Furthermore, it is possible to confirm whether the rod-shaped electrode body 1 is at a desired position.

ところで、図4では消火栓8に、棒状電極体1の挿入部11と内視鏡カメラ12の挿入部13とを設けた例を説明したが、図5に示すように補修弁9の上部に設置する短管15に設けてもよい。この短管15は、円筒形状であり、下部フランジ15aが補修弁9の上部フランジ9aへ水密状態に接続される。そして、この短管15の外周面には、図4と同様の構成で、棒状電極体1の挿入部11と内視鏡カメラ12の挿入部13とが設けられている。この短管15の上部には、消火栓8などが設置され、あるいは蓋がなされる。   By the way, although FIG. 4 demonstrated the example which provided the insertion part 11 of the rod-shaped electrode body 1 and the insertion part 13 of the endoscope camera 12 in the fire hydrant 8, it installed in the upper part of the repair valve 9 as shown in FIG. The short tube 15 may be provided. The short pipe 15 has a cylindrical shape, and the lower flange 15a is connected to the upper flange 9a of the repair valve 9 in a watertight state. An outer peripheral surface of the short tube 15 is provided with an insertion portion 11 of the rod-shaped electrode body 1 and an insertion portion 13 of the endoscope camera 12 with the same configuration as in FIG. A fire hydrant 8 or the like is installed on the upper portion of the short tube 15 or a lid is formed.

以上詳述した本実施例の電気防食装置やそれを用いた電気防食方法によれば、配水縦管5を有効に防錆することができる。また、直流で使われる防食装置に直流電源を使用することで、構成も簡易化される。さらに、内視鏡カメラ12を挿入可能とすることで、その効果確認なども可能である。なお、本実施例の電気防食装置の設置に際しては、配水縦管5内に既に付着している錆こぶを除去してから取り付けるのがよい。縦管5の錆こぶを除去するには、先に提案済みの錆こぶ除去装置(特願2003−31643号)を用いることができる。   According to the cathodic protection device of the present embodiment described in detail above and the cathodic protection method using the same, the water distribution vertical pipe 5 can be effectively rustproofed. Moreover, a structure is also simplified by using a direct-current power supply for the anticorrosion apparatus used by direct current. Furthermore, the effect can be confirmed by enabling insertion of the endoscope camera 12. In addition, when installing the anticorrosion apparatus of a present Example, it is good to attach after removing the rust hump already adhering in the water distribution vertical pipe 5. FIG. In order to remove the rust humps in the vertical tube 5, a previously proposed rust hump removing device (Japanese Patent Application No. 2003-31643) can be used.

なお、本発明の電気防食装置および電気防食方法は、上記実施例の構成に限らず、適宜変更可能である。たとえば、上記実施例では、棒状電極体1は、熱収縮チューブ2により被覆された酸化イリジウムコーティングのチタン棒を使用したが、アノードの表面を絶縁性素材で被覆し、そのアノードに形成する開口部3の面積を調整することで、所望の防食電流を得る構成であれば、前記実施例の構成に限られない。また、上記実施例では、消火栓8が設置された配水縦管5の電気防食に用いた例について説明したが、その他の箇所の電気防食にも適用可能である。   In addition, the cathodic protection device and the cathodic protection method of the present invention are not limited to the configuration of the above embodiment, and can be changed as appropriate. For example, in the above embodiment, the rod-shaped electrode body 1 uses an iridium oxide-coated titanium rod covered with the heat shrinkable tube 2, but the anode surface is covered with an insulating material and the opening formed in the anode is formed. If it is the structure which obtains a desired anticorrosion current by adjusting the area of 3, it will not be restricted to the structure of the said Example. Moreover, although the said Example demonstrated the example used for the cathodic protection of the water distribution vertical pipe 5 in which the fire hydrant 8 was installed, it is applicable also to the cathodic protection of another location.

本発明の電気防食装置のアノードを示す概略拡大図であり、(A)は正面図、(B)はそのX−X断面図である。It is a schematic enlarged view which shows the anode of the cathodic protection apparatus of this invention, (A) is a front view, (B) is the XX sectional drawing. 本発明の電気防食装置の実施例の実験装置を示す概略図である。It is the schematic which shows the experimental apparatus of the Example of the cathodic protection apparatus of this invention. 図2の装置による実験結果を示す図である。It is a figure which shows the experimental result by the apparatus of FIG. 本発明の電気防食装置の一実施例の使用状態を示す図であり、一部を断面にして示している。It is a figure which shows the use condition of one Example of the cathodic protection apparatus of this invention, and has shown it by making a part into a cross section. 図4の変形例を示す図である。It is a figure which shows the modification of FIG.

符号の説明Explanation of symbols

1 棒状電極体
2 絶縁材(熱収縮チューブ)
3 開口部(小穴)
4 外部電源(二室型鉛蓄電池)
5 配水縦管
6 配水管
8 消火栓
9 補修弁
11 棒状電極体挿入口
12 内視鏡カメラ
13 カメラ挿入口
15 短管
1 Rod-shaped electrode body 2 Insulation material (heat shrinkable tube)
3 openings (small holes)
4 External power supply (two-chamber lead acid battery)
5 Water Distribution Vertical Pipe 6 Water Distribution Pipe 8 Fire Hydrant 9 Repair Valve 11 Rod Electrode Insertion Port 12 Endoscope Camera 13 Camera Insertion Port 15 Short Pipe

Claims (5)

外部電源方式によるカソード防食方法であって、
所定電圧を維持する外部電源を用い、防食電流の調整は、アノードを被覆する絶縁材の開口部を調整して行う
ことを特徴とする電気防食方法。
Cathodic protection method by external power supply method,
An anticorrosion method characterized by using an external power source that maintains a predetermined voltage and adjusting the anticorrosion current by adjusting an opening of an insulating material covering the anode.
消火栓が設置される配水縦管内部を電気防食するカソード防食方法であって、
外部電源として二室型鉛蓄電池を用い、アノードとして複数の開口部を有する絶縁材により被覆した棒状電極体を用い、所望防食電流が得られるように前記開口部の開口率が調整された棒状電極体を前記縦管内部に設置する
ことを特徴とする電気防食方法。
A cathodic protection method that catalyzes the inside of a water distribution pipe where a fire hydrant is installed,
A rod-shaped electrode using a two-chamber lead-acid battery as an external power source and a rod-shaped electrode body covered with an insulating material having a plurality of openings as an anode, and adjusting the opening ratio of the openings so as to obtain a desired anticorrosive current An anti-corrosion method characterized by installing a body inside the vertical pipe.
外部電源方式によるカソード防食装置であって、
所定電圧を維持する外部電源と、アノードを構成する電極体と、この電極体を被覆し開口率が調整される絶縁材と
を備えることを特徴とする電気防食装置。
Cathodic protection device with external power supply system,
An anticorrosion apparatus comprising: an external power source that maintains a predetermined voltage; an electrode body that constitutes an anode; and an insulating material that covers the electrode body and has an aperture ratio adjusted.
消火栓が設置される配水縦管内部を電気防食するカソード防食装置であって、
外部電源としての二室型鉛蓄電池と、アノードを構成する棒状電極体と、複数の開口部を有しかつ開口率が設定されて前記棒状電極体を被覆する絶縁材と
を備えることを特徴とする電気防食装置。
A cathodic protection device that catalyzes the inside of a water distribution pipe where a fire hydrant is installed,
A two-chamber lead-acid battery as an external power source, a rod-shaped electrode body constituting an anode, and an insulating material having a plurality of openings and having an aperture ratio set to cover the rod-shaped electrode body An anti-corrosion device.
前記配水縦管上部に設けられる短管または地下式消火栓に、前記棒状電極体と内視鏡カメラの挿入部が設けられており、
この挿入部から前記配水縦管内に、前記棒状電極体および前記内視鏡カメラが挿入される
ことを特徴とする請求項4に記載の電気防食装置。
In the short pipe or underground fire hydrant provided at the upper part of the water distribution vertical pipe, an insertion part of the rod-shaped electrode body and the endoscope camera is provided,
The cathodic protection device according to claim 4, wherein the rod-shaped electrode body and the endoscope camera are inserted into the water distribution vertical pipe from the insertion portion.
JP2004270125A 2004-09-16 2004-09-16 Electric protection method and electric protection apparatus Pending JP2006083434A (en)

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Country Link
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011252186A (en) * 2010-05-31 2011-12-15 Ihi Corp Electrode for electrolytic protection and method for constructing concrete structure
US10072398B2 (en) * 2016-05-02 2018-09-11 Ion Irrigation Management Inc. Outdoor water service enclosure and system
CN111094614A (en) * 2017-10-12 2020-05-01 安赛乐米塔尔公司 Method for treating metal plate and metal plate treated by the method
US11319633B2 (en) 2017-10-12 2022-05-03 Arcelormittal Metal sheet treatment method and metal sheet treated with this method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59189869U (en) * 1983-06-01 1984-12-17 株式会社ダイヘン Corrosion protection equipment for underground objects
JPS6475693A (en) * 1987-09-18 1989-03-22 Nishihara Eisei Kogyosho Kk Method for stopping red water
JP2000129733A (en) * 1998-10-20 2000-05-09 Kurimoto Ltd Underground fire hydrant construction
JP2005126804A (en) * 2003-10-27 2005-05-19 Masakazu Yamamoto Rust prevention device, and method of fitting the rust prevention device

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59189869U (en) * 1983-06-01 1984-12-17 株式会社ダイヘン Corrosion protection equipment for underground objects
JPS6475693A (en) * 1987-09-18 1989-03-22 Nishihara Eisei Kogyosho Kk Method for stopping red water
JP2000129733A (en) * 1998-10-20 2000-05-09 Kurimoto Ltd Underground fire hydrant construction
JP2005126804A (en) * 2003-10-27 2005-05-19 Masakazu Yamamoto Rust prevention device, and method of fitting the rust prevention device

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011252186A (en) * 2010-05-31 2011-12-15 Ihi Corp Electrode for electrolytic protection and method for constructing concrete structure
US10072398B2 (en) * 2016-05-02 2018-09-11 Ion Irrigation Management Inc. Outdoor water service enclosure and system
CN111094614A (en) * 2017-10-12 2020-05-01 安赛乐米塔尔公司 Method for treating metal plate and metal plate treated by the method
CN111094614B (en) * 2017-10-12 2021-12-03 安赛乐米塔尔公司 Method for treating metal plate and metal plate treated by the method
US11319631B2 (en) 2017-10-12 2022-05-03 Arcelormittal Metal sheet treatment method and metal sheet treated with this method
US11319633B2 (en) 2017-10-12 2022-05-03 Arcelormittal Metal sheet treatment method and metal sheet treated with this method

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