JP2006063060A5

JP2006063060A5 -

Info

Publication number: JP2006063060A5
Application number: JP2004326437A
Authority: JP
Filing date: 2004-11-10
Publication date: 2007-10-04
Anticipated expiration: 2024-11-10

Description

（式（１）中、ａおよびｂは当量を表し、ａは０．３〜１．１の範囲内であり、ｂは０．８〜２．４の範囲内であり、かつ、２ａ＋ｂの値は２．７〜３．３の範囲内である。）
［５］上記［１］〜［３］のいずれかに記載の化粧料配合用Ｌ−アスコルビン酸−２
−リン酸エステルマグネシウムナトリウム塩を含有することを特徴とする化粧料。
［６］前記化粧料が美白化粧料として使用されることを特徴とする［５］に記載の化
粧料。
［７］前記Ｌ−アスコルビン酸−２−リン酸エステルマグネシウムナトリウム塩が１〜１０質量％の量で配合されていることを特徴とする［６］に記載の化粧料。
(In Formula (1), a and b represent an equivalent, a is in the range of 0.3 to 1.1, b is in the range of 0.8 to 2.4, and a value of 2a + b. Is within the range of 2.7 to 3.3.)
[5] L-ascorbic acid-2 for cosmetic formulation according to any one of [1] to [3]
-Cosmetics containing phosphoric acid ester magnesium sodium salt.
[6] The chemical composition according to [5], wherein the cosmetic is used as a whitening cosmetic.
Cosmetics.
[7] The cosmetic according to [6], wherein the L-ascorbic acid-2-phosphate magnesium magnesium salt is blended in an amount of 1 to 10% by mass.

［８］上記［１］〜［３］のいずれかに記載の化粧料配合用Ｌ−アスコルビン酸−２
−リン酸エステルマグネシウムナトリウム塩と、
陰イオン界面活性剤、陽イオン界面活性剤、両性界面活性剤および非イオン界面活性剤からなる群から選ばれる少なくとも１種の界面活性剤と
を含有することを特徴とする化粧料。
[ 8 ] L-ascorbic acid-2 for cosmetic preparation according to any one of [1] to [3]
-Magnesium phosphate phosphate sodium salt;
A cosmetic comprising at least one surfactant selected from the group consisting of an anionic surfactant, a cationic surfactant, an amphoteric surfactant, and a nonionic surfactant.

［９］上記［１］〜［３］のいずれかに記載の化粧料配合用Ｌ−アスコルビン酸−２
−リン酸エステルマグネシウムナトリウム塩と、
クエン酸、クエン酸ナトリウム、酒石酸、酒石酸ナトリウム、リンゴ酸、リンゴ酸ナトリウム、グルタミン酸、グルタミン酸ナトリウム、アスパラギン酸、アスパラギン酸ナトリウム、エデト酸、エデト酸二ナトリウム、エデト酸三ナトリウム、エデト酸四ナトリウム、ヒドロキシエタンジホスホン酸四ナトリウム、グリセリン、ジグリセリン、１，３−ブタンジオール、１，２−ペンタンジオール、１，２−ヘキサンジオール、プロピレング
リコール、ジプロピレングリコール、エタノール、グリチルリチン酸ジカリウム、グリチルレチン酸ステアリル、アラントイン、ヒアルロン酸、ヒアルロン酸ナトリウム、アルカリゲネス・レータスＢ−１６ポリマー、キサンタンガム、ヒドロキシエチルセルロース
、ヒドロキシプロピルセルロース、カルボキシビニルポリマー、合成ケイ酸ナトリウムマグネシウム、海藻エキス、レシチン、水添レシチン、フェノキシエタノール、パラヒドロキシ安息香酸メチル、パラヒドロキシ安息香酸プロピル、Ｌ−アスコルビン酸、Ｌ−アスコルビン酸ナトリウム、Ｌ−アスコルビン酸−２−グルコシド、Ｌ−アスコルビン酸−２−リン酸−６−パルミチン酸ナトリウム、アルブチン、サーファクチンナトリウム、塩化カリウム、塩化ナトリウム、硫酸ナトリウム、硫酸マグネシウム、塩化マグネシウム、水酸化カリウム、水酸化ナトリウム、アルギニン、セリン、ピロリドンカルボン酸ナトリウム、乳酸ナトリウム、セタノール、ステアリルアルコール、セトステアリルアルコール、ベヘニルアルコール、オクチルドデカノール、バチルアルコール、メチルポリシロキサン、デカメチルシクロペンタシロキサン、２−エチルヘキサン酸セチル、イソノナン酸イソノニル、ミリスリン酸オクチルドデシル、ネオペンタン酸オクチルドデシル、パルミチン酸セチル、トリ２−エチルヘキサン酸グリセリル、トリ（カプリル酸／カプリン酸）グリセリル、オリーブ油、流動パラフィン、スクワラン、炭酸ジカプリル、モノミリスチン酸ポリ（１０）グリセリル、モノイソステアリン酸ポリ（１０）グリセリル、モノステアリン酸ポリ（１０）グリセリル、ペンタステアリン酸デカグリセリル、縮合リシノレイン酸ポリ（６）グリセリル、パルミチン酸デキストリン、ステアリン酸デキストリン、ミリスチン酸デキストリン、ステアロイル乳酸ナトリウム、イソステアロイル乳酸ナトリウム、ビタミンＥ類、コレステロールおよびフィトステロールからなる群から選ばれる少なくとも１種の化合物と
を含有することを特徴とする化粧料。 [ 9 ] L-ascorbic acid-2 for cosmetic preparation according to any one of [1] to [3]
-Magnesium phosphate phosphate sodium salt;
Citric acid, sodium citrate, tartaric acid, sodium tartrate, malic acid, sodium malate, glutamic acid, sodium glutamate, aspartic acid, sodium aspartate, edetic acid, disodium edetate, trisodium edetate, tetrasodium edetate, hydroxy Ethanediphosphonate tetrasodium, glycerin, diglycerin, 1,3-butanediol, 1,2-pentanediol, 1,2-hexanediol, propylene glycol, dipropylene glycol, ethanol, dipotassium glycyrrhizinate, stearyl glycyrrhetinate Allantoin, hyaluronic acid, sodium hyaluronate, Alkaline Genes Latus B-16 polymer, xanthan gum, hydroxyethyl cellulose, hydroxypropyl cellulose , Carboxyvinyl polymer, synthetic sodium magnesium silicate, seaweed extract, lecithin, hydrogenated lecithin, phenoxyethanol, methyl parahydroxybenzoate, propyl parahydroxybenzoate, L-ascorbic acid, sodium L-ascorbate, L-ascorbic acid- 2-glucoside, L-ascorbic acid-2-phosphate-6-palmitic acid sodium, arbutin, surfactin sodium, potassium chloride, sodium chloride, sodium sulfate, magnesium sulfate, magnesium chloride, potassium hydroxide, sodium hydroxide, arginine , Serine, sodium pyrrolidone carboxylate, sodium lactate, cetanol, stearyl alcohol, cetostearyl alcohol, behenyl alcohol, octyldodecanol, batyl alcohol , Methylpolysiloxane, decamethylcyclopentasiloxane, cetyl 2-ethylhexanoate, isononyl isononanoate, octyldodecyl myristate, octyldodecyl neopentanoate, cetyl palmitate, glyceryl tri-2-ethylhexanoate, tri (caprylic acid / caprin Acid) glyceryl, olive oil, liquid paraffin, squalane, dicapryl carbonate, poly (10) glyceryl monomyristate, poly (10) glyceryl monoisostearate, poly (10) glyceryl monostearate, decaglyceryl pentastearate, condensed ricinoleic acid Poly (6) glyceryl, dextrin palmitate, dextrin stearate, dextrin myristate, sodium stearoyl lactate, sodium isostearoyl lactate, bi Min E group, cosmetic characterized by containing at least one compound is selected from the group consisting of cholesterol and phytosterols.

Claims

L-ascorbic acid-2-phosphate magnesium sodium salt for cosmetics blending represented by the following formula (1).

(In Formula (1), a and b represent an equivalent, a is in the range of 0.3 to 1.1, b is in the range of 0.8 to 2.4, and a value of 2a + b. Is within the range of 2.7 to 3.3.)

Infrared absorption spectrum measured by KBr disk transmission method has absorption peaks in the ranges of wave numbers 1410 to 1417 cm ⁻¹ , 1146 to 1150 cm ⁻¹ and 1115 to 1118 cm ⁻¹ , and wave numbers 1284 to 1286 cm ⁻¹ and 1162. The L-ascorbic acid-2-phosphate magnesium sodium salt for cosmetic preparation according to claim 1, which does not have an absorption peak in the range of -1164 cm ^-1 and 1122 to 1123 cm ^-1 .

The L-ascorbic acid-2-phosphate magnesium sodium salt for cosmetic preparation according to claim 1 or 2, which is amorphous.

Cosmetics represented by the following formula (1), characterized by spray drying or freeze-drying an aqueous solution of L-ascorbic acid-2-phosphate magnesium salt and L-ascorbic acid-2-phosphate sodium salt A method for producing L-ascorbic acid-2-phosphate magnesium sodium salt for blending.

Cosmetics containing the L-ascorbic acid-2-phosphate magnesium sodium salt for cosmetics formulation in any one of Claims 1-3.

The cosmetic according to claim 5, wherein the cosmetic is used as a whitening cosmetic.

The cosmetic according to claim 6, wherein the L-ascorbic acid-2-phosphate magnesium sodium salt is blended in an amount of 1 to 10% by mass.

L-ascorbic acid-2-phosphate magnesium sodium salt for cosmetic preparation according to any one of claims 1 to 3,
A cosmetic comprising at least one surfactant selected from the group consisting of an anionic surfactant, a cationic surfactant, an amphoteric surfactant, and a nonionic surfactant.

L-ascorbic acid-2-phosphate magnesium sodium salt for cosmetic preparation according to any one of claims 1 to 3,
Citric acid, sodium citrate, tartaric acid, sodium tartrate, malic acid, sodium malate, glutamic acid, sodium glutamate, aspartic acid, sodium aspartate, edetic acid, disodium edetate, trisodium edetate, tetrasodium edetate, hydroxy Ethanediphosphonate tetrasodium, glycerin, diglycerin, 1,3-butanediol, 1,2-pentanediol, 1,2-hexanediol, propylene glycol, dipropylene glycol, ethanol, dipotassium glycyrrhizinate, stearyl glycyrrhetinate Allantoin, hyaluronic acid, sodium hyaluronate, Alkaline Genes Latus B-16 polymer, xanthan gum, hydroxyethyl cellulose, hydroxypropyl cellulose , Carboxyvinyl polymer, synthetic sodium magnesium silicate, seaweed extract, lecithin, hydrogenated lecithin, phenoxyethanol, methyl parahydroxybenzoate, propyl parahydroxybenzoate, L-ascorbic acid, sodium L-ascorbate, L-ascorbic acid- 2-glucoside, L-ascorbic acid-2-phosphate-6-palmitic acid sodium, arbutin, surfactin sodium, potassium chloride, sodium chloride, sodium sulfate, magnesium sulfate, magnesium chloride, potassium hydroxide, sodium hydroxide, arginine , Serine, sodium pyrrolidone carboxylate, sodium lactate, cetanol, stearyl alcohol, cetostearyl alcohol, behenyl alcohol, octyldodecanol, batyl alcohol , Methylpolysiloxane, decamethylcyclopentasiloxane, cetyl 2-ethylhexanoate, isononyl isononanoate, octyldodecyl myristate, octyldodecyl neopentanoate, cetyl palmitate, glyceryl tri-2-ethylhexanoate, tri (caprylic acid / caprin Acid) glyceryl, olive oil, liquid paraffin, squalane, dicapryl carbonate, poly (10) glyceryl monomyristate, poly (10) glyceryl monoisostearate, poly (10) glyceryl monostearate, decaglyceryl pentastearate, condensed ricinoleic acid Poly (6) glyceryl, dextrin palmitate, dextrin stearate, dextrin myristate, sodium stearoyl lactate, sodium isostearoyl lactate, bi Min E group, cosmetic characterized by containing at least one compound is selected from the group consisting of cholesterol and phytosterols.