JP2006061861A - Apparatus and method for treating organic sludge - Google Patents
Apparatus and method for treating organic sludge Download PDFInfo
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本発明は、有機性汚泥を高温高圧処理してスラリー化したのち可燃性固形原料として回収し、燃料等として有効利用を図る有機性汚泥の処理装置及び処理方法に関する。 TECHNICAL FIELD The present invention relates to an organic sludge treatment apparatus and treatment method in which organic sludge is slurried by high-temperature and high-pressure treatment, recovered as a combustible solid material, and effectively used as fuel or the like.
従来、下水、し尿及び各種産業排水を処理する水処理設備から発生する有機性汚泥を処理する方法として、汚泥を濃縮、脱水したのち焼却又は埋め立て処分する方法が一般的に行われているが、汚泥の濃縮、脱水後においても含水率が75〜82wt%と高いため嵩が大きく、廃棄物業者に処分を依頼する場合には、引き取りコストが高くなり、排水処理全体にかかるコストの多くを占めているのが現状である。更に、埋め立て処分においては、産業廃棄物埋立処分場の残余年数が少なくなっており、引き取りコストも年々高騰している。また、焼却処分においては、含水率が高いため燃料消費量が多くなりエネルギーコストが嵩み、更に、近年は排出ガスや焼却灰に含まれるダイオキシン問題等から焼却処理自体が困難になってきている状況である。 Conventionally, as a method of treating organic sludge generated from water treatment facilities for treating sewage, human waste and various industrial wastewater, a method of incineration or landfill disposal after the sludge is concentrated and dehydrated has been generally performed. Even after concentration and dehydration of sludge, the water content is high at 75-82 wt%, so the bulk is large, and when requesting disposal to a waste contractor, the take-up cost is high and occupies much of the overall cost of wastewater treatment. This is the current situation. Furthermore, in landfill disposal, the remaining years of the industrial waste landfill site are decreasing, and the collection cost is also rising year by year. Moreover, in incineration disposal, high water content increases fuel consumption and increases energy costs. In recent years, incineration treatment itself has become difficult due to problems such as dioxins contained in exhaust gas and incineration ash. Is the situation.
また、前記の問題に鑑みて、有機性汚泥を高温高圧条件で処理し、液体化又はガス化して燃料等として有効活用を図ろうとする方法がある。その一例として、有機性汚泥を脱水する脱水装置と、脱水汚泥を後述する予熱器、反応器、冷却器へ直列に圧入するための圧入装置と、圧入される脱水汚泥を後段の冷却器で加熱した熱媒体によって予熱する予熱器と、予熱した脱水汚泥を熱媒体によって加熱し、250℃以上の温度とこの温度における水蒸気圧以上の圧力で反応させる反応器と、反応物を熱媒体によって冷却する冷却器と、冷却した反応物を大気圧に開放する大気開放装置と、開放した反応物中の可燃性液体を回収する回収装置と、回収した可燃性液体を燃焼させて熱媒体を間接的に加熱する加熱炉とによって構成した汚泥油化装置がある。(例えば、特許文献1参照) In view of the above problems, there is a method in which organic sludge is treated under high-temperature and high-pressure conditions to be liquefied or gasified for effective use as a fuel. As an example, a dehydrator for dewatering organic sludge, a press-fitting device for press-fitting the dehydrated sludge into a preheater, a reactor, and a cooler, which will be described later, and the dewatered sludge to be injected are heated by a subsequent cooler. A preheater that preheats with the heated heat medium, a reactor that heats the preheated dewatered sludge with the heat medium, reacts at a temperature of 250 ° C. or higher and a pressure equal to or higher than the water vapor pressure at this temperature, and cools the reactants with the heat medium. A cooler, an air opening device that opens the cooled reactant to atmospheric pressure, a recovery device that recovers the flammable liquid in the opened reactant, and indirectly burns the recovered flammable liquid to heat medium. There is a sludge oil making apparatus constituted by a heating furnace for heating. (For example, see Patent Document 1)
また、他の例として、各種ごみや褐炭等の低級な炭素質物質をスラリー化し、高温高圧処理して炭素質物質中の酸素を二酸化炭素として分離すると共に炭素質スラリーを生成し、生成ガス及び炭素質スラリーを燃料として有効利用する方法がある。(例えば、特許文献2参照) In addition, as another example, low-grade carbonaceous materials such as various garbage and lignite are slurried, and high-temperature and high-pressure treatment is performed to separate oxygen in the carbonaceous materials as carbon dioxide and to produce a carbonaceous slurry, There is a method of effectively using carbonaceous slurry as fuel. (For example, see Patent Document 2)
また、他の例として、下水汚泥を強脱水処理し、脱水汚泥を高温高圧処理(約150〜340℃)して下水汚泥スラリーを生成し、フラッシュ蒸発により水分を蒸発分離したのち補助燃料と混合して熱量調節したスラリー燃料を製造する方法がある。(例えば、特許文献3参照)
解決しようとする課題は、特許文献1に記載された汚泥を油化する方法や装置においては、汚泥から油状物質を生成する油化反応は、低い温度や圧力で反応させようとすると反応速度が遅く、反応時間が極めて長時間となり、エネルギーコストが嵩むと共に、過大な設備となるため設備コストや設備設置面積が嵩む問題がある。従って、効率的な反応速度を得るために、通常は高温高圧条件で処理されるが、その温度及び圧力が高過ぎるため、昇温エネルギーコストや反応槽の高圧設計、予熱器や加熱器等による設備コストが嵩む問題がある。 The problem to be solved is that, in the method and apparatus for converting sludge to oil described in Patent Document 1, the oil conversion reaction for generating an oily substance from the sludge has a reaction rate when attempting to react at a low temperature or pressure. There is a problem that the reaction time is slow and the reaction time is extremely long, the energy cost is increased, and the facility cost and the installation area of the facility are increased due to excessive facilities. Therefore, in order to obtain an efficient reaction rate, it is usually processed under high temperature and high pressure conditions. However, because the temperature and pressure are too high, the temperature rise energy cost, the high pressure design of the reaction tank, the preheater, the heater, etc. There is a problem that the equipment cost increases.
また、従来の特許文献2に記載された方法においては、油状物質を生成させる反応ではないため、必要なエネルギーは少なくなり、各種ごみや汚泥等の廃棄物を燃料等として利用を図る方法としては有効な手段であるが、スラリー化するために外部から多量の粘性調整水を必要とする。特に、下水汚泥等は脱水汚泥として供給され、含水率は概ね78〜82wt%で、高粘質であるため、供給配管や各種装置内の圧力損失が高くなり、輸送効率が低いと共に加熱時の総括伝熱係数が低くなる。従って、流動性を有する汚泥を得るには、更に多量の粘性調整水を必要とすることにより設備が過大となる問題がある。 Further, in the conventional method described in Patent Document 2, since it is not a reaction for generating an oily substance, the required energy is reduced, and as a method of using wastes such as various garbage and sludge as fuel, etc. Although it is an effective means, a large amount of viscosity adjusting water is required from the outside in order to make a slurry. In particular, sewage sludge and the like are supplied as dehydrated sludge and have a moisture content of approximately 78 to 82 wt% and high viscosity, resulting in high pressure loss in the supply piping and various devices, low transportation efficiency and heating. The overall heat transfer coefficient is lowered. Therefore, in order to obtain sludge having fluidity, there is a problem that the facility becomes excessive due to the necessity of a larger amount of viscosity adjusting water.
また、従来の特許文献3に記載された方法においては、脱水汚泥をさらに高度脱水した固形物として高温高圧処理しているため、前記のように流体送給と比較して供給配管や各種装置内の圧力損失が高くなり、輸送効率が低いと共に加熱時の総括伝熱係数が低いため、エネルギー効率が悪く、エネルギーコストや設備費が嵩む問題がある。 Moreover, in the method described in the conventional patent document 3, since the dewatered sludge is processed at high temperature and high pressure as a solid material that has been further highly dehydrated, as described above, in the supply piping and various devices as compared with the fluid feed. There is a problem that the energy loss is low and the energy cost and the equipment cost are increased because the pressure loss is low, the transport efficiency is low and the overall heat transfer coefficient during heating is low.
本発明は、前記事情に鑑みてなされたものであり、有機性汚泥を高温高圧処理してスラリー化したのち可燃性固形原料として回収し、燃料等として有効利用を図るにあたり、必要設備の削減化を図ると共に、反応に使用するエネルギーや粘性調整水等の使用量をできるだけ少なくし、エネルギーコストや設備コストを低廉化することのできる有機性汚泥の処理装置と処理方法を提供する目的で成されたものである。 The present invention has been made in view of the above circumstances, and organic sludge is slurried by high-temperature and high-pressure treatment, and then recovered as a flammable solid raw material. The purpose is to provide an organic sludge treatment device and treatment method that can reduce energy and equipment costs by reducing the amount of energy and viscosity-adjusted water used for the reaction as much as possible. It is a thing.
前記目的を達成するための本発明の要旨は、請求項1に記載の第一発明においては、有機性汚泥を高温高圧処理してスラリー状物質を生成する高温高圧処理装置と、前記スラリー状物質を脱水処理して脱水固形物を回収する脱水処理装置と、前記脱水処理装置により分離された分離液を浄化処理する水処理設備を少なくとも設けた有機性汚泥の処理装置において、前記高温高圧処理装置に加圧スチーム吹き込み手段を設け、該高温高圧処理装置が、有機性汚泥の一定量を充填して前記加圧スチーム吹き込み手段から加圧スチームを吹き込んで、加熱、加圧及び攪拌しながら所定時間反応させる回分式反応槽として形成され、前記水処理設備の少なくとも一部に膜分離処理装置が設けられていることを特徴とする有機性汚泥の処理装置である。 The gist of the present invention for achieving the above object is that, in the first invention according to claim 1, a high-temperature and high-pressure treatment apparatus for producing a slurry-like substance by subjecting organic sludge to a high-temperature and high-pressure treatment, and the slurry-like substance In the organic sludge treatment apparatus provided with at least a dehydration treatment apparatus for dewatering and recovering dehydrated solids, and a water treatment facility for purifying the separated liquid separated by the dehydration treatment apparatus, the high temperature and high pressure treatment apparatus Provided with a pressurized steam blowing means, and the high-temperature high-pressure treatment apparatus is charged with a certain amount of organic sludge and blows pressurized steam from the pressurized steam blowing means for a predetermined time while being heated, pressurized and stirred. An organic sludge treatment apparatus, which is formed as a batch reaction tank to be reacted, and a membrane separation treatment apparatus is provided in at least a part of the water treatment facility.
また、請求項2に記載の第二発明は、請求項1の有機性汚泥の処理装置における脱水処理装置がデカンタ型遠心分離機である有機性汚泥の処理装置である。 The second invention according to claim 2 is an organic sludge treatment apparatus in which the dewatering treatment apparatus in the organic sludge treatment apparatus of claim 1 is a decanter centrifuge.
また、請求項3に記載の第三発明は、請求項1又は請求項2記載の有機性汚泥の処理装置に、前記有機性汚泥に液状物を混合して有機性汚泥の含水率を調整する汚泥混合装置が配設されている有機性汚泥の処理装置である。 A third invention according to claim 3 adjusts the moisture content of the organic sludge by mixing the organic sludge with a liquid material in the organic sludge treatment apparatus according to claim 1 or claim 2. This is an organic sludge treatment apparatus provided with a sludge mixing apparatus.
また、請求項4に記載の第四発明は、有機性汚泥を高温高圧処理してスラリー状物質を生成する高温高圧処理工程と、前記高温高圧処理工程で生成されたスラリー状物質を脱水処理して脱水固形物を回収する脱水処理工程と、前記脱水処理工程により分離された分離液を浄化処理する水処理工程とを少なくとも設けた有機性汚泥の処理方法において、前記高温高圧処理工程が、一定量の有機性汚泥に加圧スチーム吹き込み手段から加圧スチームを吹き込んで攪拌しながら、温度160〜250℃、該温度における水蒸気圧以上の圧力で5〜120min反応させる回分反応工程であり、前記水処理工程の少なくとも一部に膜分離処理工程を設け、前記分離液中の残留固形物を濃縮液として分離処理することを特徴とする有機性汚泥の処理方法である。 A fourth invention according to claim 4 is a high-temperature and high-pressure treatment step in which organic sludge is subjected to high-temperature and high-pressure treatment to produce a slurry-like material, and the slurry-like material produced in the high-temperature and high-pressure treatment step is dehydrated. In the organic sludge treatment method provided with at least a dehydration treatment step for recovering dehydrated solids and a water treatment step for purifying the separated liquid separated in the dehydration treatment step, the high temperature and high pressure treatment step is constant. A batch reaction step of reacting 5 to 120 minutes at a temperature of 160 to 250 ° C. at a pressure equal to or higher than the water vapor pressure at a temperature of 160 to 250 ° C. while stirring by blowing pressurized steam from a pressurized steam blowing means into a quantity of organic sludge, A method for treating organic sludge, characterized in that a membrane separation treatment step is provided in at least a part of the treatment step, and the residual solid in the separation liquid is separated as a concentrate. A.
また、請求項5に記載の第五発明は、請求項4記載の有機性汚泥の処理方法における有機性汚泥に液状物を混合して前記有機性汚泥の含水率を80〜88wt%となるように調整する有機性汚泥の処理方法である。 In a fifth aspect of the present invention, the liquid content is mixed with the organic sludge in the organic sludge treatment method according to the fourth aspect so that the water content of the organic sludge becomes 80 to 88 wt%. It is a processing method of organic sludge to adjust to.
また、請求項6に記載の第六発明は、請求項4又は請求項5に記載の有機性汚泥の処理方法における液状物が高温高圧処理工程で生成したスラリー状物質、脱水処理工程により分離された分離液及び/又は膜分離処理工程で濃縮された濃縮液である有機性汚泥の処理方法である。 According to a sixth aspect of the present invention, the liquid substance in the organic sludge treatment method according to the fourth or fifth aspect is separated by the slurry-like substance produced in the high-temperature and high-pressure treatment step and the dehydration treatment step. This is a method for treating organic sludge which is a concentrated liquid concentrated in the separated liquid and / or membrane separation treatment step.
また、請求項7に記載の第七発明は、請求項4乃至請求項6のいずれか1項に記載の有機性汚泥の処理方法における高温高圧処理工程で生成したスラリー状物質の温度を40〜90℃に調整して脱水処理工程に供給する有機性汚泥の処理方法である。 The seventh invention according to claim 7 is characterized in that the temperature of the slurry-like substance generated in the high-temperature and high-pressure treatment step in the method for treating organic sludge according to any one of claims 4 to 6 is 40 to 40. It is the processing method of the organic sludge which adjusts to 90 degreeC and supplies to a dehydration process process.
また、請求項8に記載の第八発明は、請求項4乃至請求項7のいずれか1項に記載の有機性汚泥の処理方法における高温高圧処理工程で生成したスラリー状物質の一部を残留させて、次に回分処理する有機性汚泥を供給して混合処理する有機性汚泥の処理方法である。 Further, according to an eighth aspect of the present invention, a part of the slurry-like substance generated in the high-temperature and high-pressure treatment step in the organic sludge treatment method according to any one of the fourth to seventh aspects remains. Then, the organic sludge is processed by supplying the organic sludge to be batch-processed next and mixing it.
第一発明の構成により、高温高圧処理装置における高温高圧処理において、従来必要とした有機性汚泥の予熱器や加熱器を不要とし、また、従来は、汚泥を高圧状態の反応槽へ供給するため、高圧ポンプを必要としたが、回分式反応槽にしたことにより、反応槽内圧力を低くして汚泥を供給できるため、通常のポンプが使用でき、システム構成の簡略化や設備費の低減化を図ることができる。また、加圧スチーム吹き込み手段を配設して加熱、加圧及び攪拌するため、反応槽における汚泥の均一加熱や均一攪拌による反応の効率化を図ることができる。特に下水汚泥を有機性汚泥として処理し、得られる可燃性固形原料は、セメントの原料となる粘土を多量に含有しているため、セメント原料且つ焼成燃料として極めて有効に利用することができる。また、水処理設備の一部に膜分離処理装置を設けることにより、高温高圧処理で生成する難分解性COD成分の除去並びに溶解性有機物の回収を行うことができる。 According to the configuration of the first invention, in the high-temperature and high-pressure treatment in the high-temperature and high-pressure treatment apparatus, the conventionally required organic sludge preheater or heater is unnecessary, and conventionally, the sludge is supplied to the high-pressure reaction tank. A high-pressure pump was required, but because a batch-type reaction tank was used, sludge could be supplied by lowering the pressure in the reaction tank, so normal pumps could be used, simplifying the system configuration and reducing equipment costs Can be achieved. In addition, since the pressurized steam blowing means is disposed to heat, pressurize and stir, it is possible to improve the efficiency of the reaction by uniform heating and uniform stirring of sludge in the reaction tank. In particular, the combustible solid raw material obtained by treating sewage sludge as organic sludge contains a large amount of clay as a raw material for cement, and therefore can be used very effectively as a cement raw material and a calcined fuel. Further, by providing a membrane separation treatment apparatus in a part of the water treatment facility, it is possible to remove the hardly decomposable COD component generated by the high temperature and high pressure treatment and to recover the soluble organic matter.
第二発明の構成により、高温高圧処理により生成したスラリー状物質の脱水処理を効率的に行うことができ、含水率の低いケーキを得ることができるため、後段の可燃性固形原料として回収するケーキ乾燥装置等の後処理装置を小型化でき、エネルギーコストや設備コストの低廉化を図ることができる。 According to the configuration of the second invention, the slurry material generated by the high-temperature and high-pressure treatment can be efficiently dehydrated, and a cake having a low water content can be obtained. A post-processing apparatus such as a drying apparatus can be downsized, and energy costs and equipment costs can be reduced.
第三発明の構成により、有機性汚泥の流動性を改善して反応槽への供給を容易にするための粘性調整水等の使用量を低減できると共に、流動性が改善されることにより、均一攪拌及び均一加熱が行われ、反応効率の向上を図ることができる。 According to the configuration of the third invention, it is possible to improve the fluidity of organic sludge and reduce the amount of use of viscosity-adjusted water, etc. for facilitating the supply to the reaction tank, and by improving the fluidity, it is uniform Stirring and uniform heating are performed, and the reaction efficiency can be improved.
第四発明の構成により、高温高圧処理において従来必要とした有機性汚泥の予熱工程や加熱工程を不要とし、また、汚泥を常圧で供給できるため、通常のポンプが使用でき、設備費の低減化を図ることができる。また、加圧スチームを吹き込んで加熱、加圧及び攪拌するため、汚泥の均一加熱や均一攪拌による反応の効率化を図ることができる。さらに、温度160〜250℃の比較的低温域でスラリー化反応を完結することができるため反応に使用されるエネルギーが少なくなり、設備費を低廉化することができる。 The configuration of the fourth invention eliminates the need for organic sludge preheating and heating processes conventionally required in high-temperature and high-pressure treatment, and also enables sludge to be supplied at normal pressure, allowing the use of ordinary pumps and reducing equipment costs. Can be achieved. Moreover, since heating, pressurizing, and stirring are performed by blowing pressurized steam, it is possible to improve the efficiency of the reaction by uniform heating and uniform stirring of sludge. Further, since the slurrying reaction can be completed in a relatively low temperature range of 160 to 250 ° C., the energy used for the reaction is reduced, and the equipment cost can be reduced.
第五発明の構成により、できるだけ少ない液体割合によって良好な流動状態が得られ、反応槽への供給が容易となると共に、流動性が改善されることにより、均一攪拌及び均一加熱が行われ、反応効率も高くすることができる。 With the configuration of the fifth invention, a good fluid state can be obtained with the smallest possible liquid ratio, the supply to the reaction vessel is facilitated, and the fluidity is improved, whereby uniform stirring and uniform heating are performed, and the reaction is performed. Efficiency can also be increased.
第六発明の構成により、反応生成物であるスラリー状物質、脱水処理により分離された分離液や水処理装置の一部である膜分離装置で濃縮された濃縮液により有機性汚泥のスラリー化を行うため、有機性汚泥の流動化を改善して反応槽への供給を容易にするための粘性調整水等の使用量を低減でき、設備の小型化を図ることができる。 According to the configuration of the sixth invention, slurry of organic sludge is slurried with a slurry-like substance as a reaction product, a separation liquid separated by a dehydration treatment or a concentrated liquid concentrated in a membrane separation apparatus which is a part of a water treatment apparatus. Therefore, it is possible to reduce the amount of viscosity-adjusted water or the like for improving the fluidization of organic sludge and facilitating the supply to the reaction tank, and to reduce the size of the equipment.
第七発明の構成により、従来は脱水処理に供給するスラリー状物質の温度を40℃以下に冷却していたため、脱水後の固形分の含水率が60〜70wt%であり、含水率を下げるためには反応槽における反応時間を長くする必要があったが、スラリー状物質の温度を40〜90℃として脱水処理に供給することにより、反応槽における反応時間を大幅に低減し、且つ脱水後の固形分の含水率を60wt%以下とすることができるため、後段のケーキ乾燥装置等の後処理装置を小型化できエネルギーコストや設備費の低廉化を図ることができる。 According to the configuration of the seventh invention, the temperature of the slurry-like substance supplied to the dehydration process has been conventionally cooled to 40 ° C. or less, so that the moisture content of the solid content after dehydration is 60 to 70 wt%, so as to reduce the moisture content It was necessary to lengthen the reaction time in the reaction tank, but by supplying the slurry-like substance to the dehydration treatment at a temperature of 40 to 90 ° C., the reaction time in the reaction tank was greatly reduced, and after the dehydration Since the moisture content of the solid content can be set to 60 wt% or less, a post-treatment device such as a subsequent cake drying device can be downsized, and energy costs and equipment costs can be reduced.
第八発明の構成により、反応工程における汚泥の流動化をさらに改善することができ、均一攪拌及び均一加熱が行われ、反応効率も高くすることができる。 According to the configuration of the eighth invention, the fluidization of sludge in the reaction step can be further improved, uniform stirring and uniform heating are performed, and the reaction efficiency can be increased.
本発明の実施の形態により、有機性汚泥を高温高圧処理してスラリー化したのち可燃性固形原料として回収し、燃料等として有効利用を図るにあたり、必要設備の削減化と共に、反応に使用するエネルギーや粘性調整水等の使用量をできるだけ少なくし、エネルギーコストや設備コストを低廉化することのできる有機性汚泥の処理装置と処理方法を提供する目的を、加圧スチーム吹き込み手段を設けた回分式反応槽により、有機性汚泥の一定量を充填し、加圧スチーム吹き込み手段から加圧スチームを吹き込んで加熱、加圧及び攪拌しながら所定時間反応させる回分反応方法により達成した。また、処理設備の一部に膜分離処理装置を設けることにより、高温高圧処理で生成する難分解性COD成分の除去並びに溶解性有機物の回収を行うことができる。 According to the embodiment of the present invention, organic sludge is slurried by high-temperature and high-pressure treatment, and then recovered as a combustible solid raw material. For the purpose of providing organic sludge treatment equipment and treatment methods that can reduce energy and equipment costs by reducing the amount of water used and viscosity adjustment water as much as possible. This was achieved by a batch reaction method in which a certain amount of organic sludge was filled in a reaction tank, and pressurized steam was blown from the pressurized steam blowing means to react for a predetermined time while heating, pressing and stirring. Further, by providing a membrane separation processing apparatus in a part of the processing equipment, it is possible to remove the hardly decomposable COD component generated by the high-temperature and high-pressure processing and recover the soluble organic matter.
本発明の実施の形態を図面に基づいて説明する。図1は本発明の1実施形態の有機性汚泥の処理装置の系統図である。
図1において、1は有機性汚泥受け入れ設備の汚泥貯留槽であり、後記の高温高圧処理する回分式反応槽4で生成したスラリー状物質の熱量を回収し、汚泥の温度を高めて流動性を改善するための、熱交換手段1bが内設されているのが好ましい。1aは貯留された有機性汚泥を所定の流量で後段装置に供給する汚泥排出機である。
Embodiments of the present invention will be described with reference to the drawings. FIG. 1 is a system diagram of an organic sludge treatment apparatus according to one embodiment of the present invention.
In FIG. 1, 1 is a sludge storage tank of an organic sludge receiving facility, recovering the calorie | heat amount of the slurry-like substance produced | generated in the batch-type reaction tank 4 which processes high temperature and high pressure mentioned later, and raises the temperature of sludge and makes fluidity | liquidity. It is preferable that a heat exchange means 1b is provided for improvement. 1a is a sludge discharger that supplies the stored organic sludge to a subsequent apparatus at a predetermined flow rate.
2は有機性汚泥と後記の回分式反応槽4で処理され循環されるスラリー状物質、脱水装置で分離された分離液及び/又は膜分離装置で濃縮された濃縮液等の液状物とを混合して所定含水率の混合汚泥を製造する汚泥混合装置であり、汚泥混合装置2としては、スクリュウ型混合装置等が使用されるが、混合槽にリボン型攪拌機、パドル型攪拌機等が付設された装置を使用することも好ましい。 2 is a mixture of organic sludge and a liquid substance such as a slurry substance processed and circulated in a batch reaction tank 4 described later, a separated liquid separated by a dehydrator and / or a concentrated liquid concentrated by a membrane separator. A sludge mixing device for producing a mixed sludge having a predetermined moisture content. As the sludge mixing device 2, a screw-type mixing device or the like is used, but a ribbon-type stirrer, a paddle-type stirrer, or the like is attached to the mixing tank. It is also preferred to use an apparatus.
3は所定含水率に調整された混合汚泥を貯留する混合汚泥貯留槽であり、3aは貯留された混合汚泥を後記の回分式反応槽4に一定量づつ回分供給する汚泥供給ポンプである。なお、汚泥供給ポンプ3aは供給する混合汚泥の流動性が高く、また、減圧して低圧状態とした後の回分式反応槽4に供給するため、高圧ポンプを使用する必要はない。 Reference numeral 3 denotes a mixed sludge storage tank that stores mixed sludge adjusted to a predetermined moisture content, and 3a denotes a sludge supply pump that supplies the stored mixed sludge to a batch-type reaction tank 4 described later in batches. The sludge supply pump 3a has a high fluidity of the mixed sludge to be supplied, and it is not necessary to use a high-pressure pump because the sludge supply pump 3a is supplied to the batch-type reaction tank 4 after the pressure is reduced to a low pressure state.
4は、一定量充填された混合汚泥に加圧スチームを吹き込んで、加熱、加圧及び攪拌しながら高温高圧条件で所定時間反応させ、スラリー状物質を生成する高温高圧処理装置の回分式反応槽(以下単に反応槽という。)であり、できるだけ均一加熱及び攪拌されるよう上下に複数段の加圧スチーム吹き込み手段4a、4bが設けられている。なお、加圧スチーム吹き込み手段4a、4bは、吹き込みノズルを反応槽4の横断面に対して所定間隔で均等配置するのが好ましい。また、配設される段数は、反応槽が小型の場合等では単段でもよく、反応槽容積により適宜に設定される。 4 is a batch type reaction tank of a high-temperature and high-pressure treatment apparatus that generates a slurry-like substance by blowing pressurized steam into a certain amount of mixed sludge and reacting it under high-temperature and high-pressure conditions while heating, pressurizing and stirring. (Hereinafter simply referred to as a reaction vessel), and a plurality of stages of pressurized steam blowing means 4a and 4b are provided on the upper and lower sides so as to be heated and stirred as uniformly as possible. In addition, it is preferable that the pressurized steam blowing means 4 a and 4 b have the blowing nozzles arranged uniformly at a predetermined interval with respect to the cross section of the reaction tank 4. Further, the number of stages to be arranged may be a single stage when the reaction tank is small or the like, and is appropriately set depending on the reaction tank volume.
5は反応後のスラリー状物質を所定温度まで冷却する冷却装置であり、スパイラル式熱交換器、シェルアンドチューブ式熱交換器、又はプレート式熱交換器等が用いられる。6はスラリー状物質を貯留するスラリー貯留槽であり、スラリーの沈降分離を防止するため、攪拌手段6bが付設されている。6aは貯留されたスラリー状物質を所定の流量で後段の脱水装置7に供給するスラリー供給ポンプである。 A cooling device 5 cools the slurry-like substance after the reaction to a predetermined temperature, and a spiral heat exchanger, a shell and tube heat exchanger, a plate heat exchanger, or the like is used. 6 is a slurry storage tank for storing a slurry-like substance, and an agitation means 6b is attached to prevent the slurry from settling and separating. 6a is a slurry supply pump for supplying the stored slurry-like substance to the subsequent dehydrator 7 at a predetermined flow rate.
7はスラリー状物質から液分を分離して固形分を回収する脱水装置であり、脱水装置としては、デカンタ型遠心分離機、フィルタプレス、スクリュープレス、ベルトプレス等の装置が使用されるが、デカンタ型遠心分離機を使用するのが好ましい。 7 is a dehydrator that separates the liquid from the slurry-like substance and collects the solid, and as the dehydrator, devices such as a decanter centrifuge, a filter press, a screw press, and a belt press are used. It is preferred to use a decanter centrifuge.
8は脱水装置7で脱水されて回収された脱水ケーキを貯留する脱水ケーキ貯留槽、9は脱水装置7で分離された分離液を貯留する分離液貯留槽、9aは貯留された分離液を所定の流量で後段水処理設備の一部である膜分離装置に送液する分離液排出ポンプである。 8 is a dehydrated cake storage tank for storing the dehydrated cake dehydrated and recovered by the dehydrator 7, 9 is a separation liquid storage tank for storing the separated liquid separated by the dehydrator 7, and 9a is a predetermined stored liquid. Is a separation liquid discharge pump for sending liquid to a membrane separation apparatus which is a part of the latter-stage water treatment facility.
10は前記分離液を浄化処理する水処理設備の一部として配設された膜分離装置であり、膜分離装置としては、精密ろ過膜装置、限外ろ過膜装置、ナノフィルタ膜装置、逆浸透膜装置等の装置が使用されるが、ナノフィルタ膜装置を使用するのが好ましい。 Reference numeral 10 denotes a membrane separation device disposed as part of a water treatment facility for purifying the separation liquid. The membrane separation device includes a microfiltration membrane device, an ultrafiltration membrane device, a nanofilter membrane device, a reverse osmosis device. Although a device such as a membrane device is used, it is preferable to use a nanofilter membrane device.
なお、図示しないが、脱水ケーキを可燃性固形原料製品とする設備が脱水ケーキ貯留槽8の後段に配設されており、その設備としては、少なくとも脱水ケーキを乾燥するケーキ乾燥設備、乾燥された乾燥ケーキを貯留する製品貯留槽が設けられ、ケーキ乾燥設備としては、伝熱乾燥機、温風乾燥機、マイクロ波乾燥機、減圧乾燥機等の装置が使用されるが、伝熱乾燥機を使用するのが好ましい。 In addition, although not shown in figure, the equipment which uses a dehydrated cake as a combustible solid raw material product is arrange | positioned in the back | latter stage of the dehydrated cake storage tank 8, As the equipment, the cake drying equipment which dries a dehydrated cake at least, and was dried A product storage tank is provided to store the dried cake, and equipment such as a heat transfer dryer, hot air dryer, microwave dryer, and vacuum dryer is used as the cake drying equipment. It is preferred to use.
また、水処理設備としては、膜分離装置10の透過液をさらに浄化する好気性処理又は嫌気性処理等の浄化処理装置が配設され、浄化処理装置としては、活性汚泥処理装置、固定床式生物処理装置、流動床式処理装置、接触酸化処理装置、上向流嫌気性処理装置等の装置が使用される。 Further, as the water treatment facility, a purification treatment device such as an aerobic treatment or an anaerobic treatment for further purifying the permeate of the membrane separation device 10 is disposed. As the purification treatment device, an activated sludge treatment device, a fixed bed type, etc. Devices such as biological treatment devices, fluidized bed treatment devices, catalytic oxidation treatment devices, and upflow anaerobic treatment devices are used.
また、汚泥によっては汚泥中に大径化した汚泥や繊維質や毛髪等の夾雑物が含有されている場合があり、それらを破砕処理する粉砕装置が必要により配設される。破砕装置としては、単段の破砕機を配設するだけでもよいが、粗破砕機により破砕の後に微粉砕機を設けて、2段で破砕する構成が好ましい。 Further, depending on the sludge, sludge having a large diameter or impurities such as fibers and hair may be contained in the sludge, and a pulverizing apparatus for crushing them is provided if necessary. As the crushing apparatus, a single-stage crusher may be provided, but a configuration in which a fine crusher is provided after crushing by a coarse crusher and crushing in two stages is preferable.
次に前記構成の有機性汚泥の処理装置を用いて、下水汚泥等の有機性汚泥(以下単に汚泥という。)を処理する方法について以下詳述する。 Next, a method for treating organic sludge such as sewage sludge (hereinafter simply referred to as sludge) using the organic sludge treatment apparatus having the above configuration will be described in detail below.
水処理設備から発生した汚泥を汚泥貯留槽1に受け入れる。なお受け入れる汚泥は、通常、水処理設備に脱水装置が配設されているため、脱水装置から得られる含水率75〜82wt%の脱水汚泥であるが、それには限定されない。また、汚泥貯留槽1に受け入れられた汚泥は、内設されている熱交換手段1bにより後段の反応槽4で生成したスラリー状物質と熱交換され、スラリー状物質の熱量を回収すると共に、加熱による温度上昇により汚泥の流動性が改善される。 Sludge generated from the water treatment facility is received in the sludge storage tank 1. The sludge to be accepted is usually a dewatered sludge having a water content of 75 to 82 wt% obtained from the dewatering device because the dewatering device is disposed in the water treatment facility, but is not limited thereto. Moreover, the sludge received in the sludge storage tank 1 is heat-exchanged with the slurry-like substance generated in the subsequent reaction tank 4 by the heat exchange means 1b installed therein, recovering the heat amount of the slurry-like substance, and heated. The fluidity of the sludge is improved by the temperature rise due to.
汚泥貯留槽1から汚泥排出機1aで抜き出された汚泥は、管路L1を経て汚泥混合装置2に供給されるが、前記のとおり、汚泥の含水率変動が大きく、後段の反応槽4における反応条件が安定しない恐れがあるため、汚泥混合装置2により、反応槽4で処理され循環されるスラリー状物質、脱水装置8で分離された分離液及び/又は膜分離装置10で濃縮された濃縮液等の液状物が混合され、汚泥の含水率が調整される。なお、汚泥の含水率は80〜88wt%となるように調整するのが好ましく、これにより、少ない液体割合によって良好な流動状態が得られ、反応槽4への供給が容易となる。また、反応槽4内における流動性が大きくなるため、反応効率も高くすることができると共に反応槽4において常に安定した反応条件で処理を行うことができる。前記において、含水率が80wt%よりも低いと流動性が不十分となる問題があり、また、含水率が88wt%よりも高いとエネルギーコストが高くなりすぎる問題がある。 The sludge extracted from the sludge storage tank 1 by the sludge discharger 1a is supplied to the sludge mixing device 2 via the pipe L1, but as described above, the fluctuation of the moisture content of the sludge is large, and the reaction tank 4 in the latter stage Since the reaction conditions may not be stable, the sludge mixing device 2 causes the slurry-like material to be processed and circulated in the reaction tank 4, the separated liquid separated by the dehydration device 8 and / or the concentration concentrated by the membrane separation device 10. Liquids such as liquid are mixed to adjust the moisture content of the sludge. In addition, it is preferable to adjust so that the moisture content of sludge may be 80-88 wt%, and, thereby, a favorable fluid state is obtained with a small liquid ratio, and supply to the reaction tank 4 becomes easy. Moreover, since the fluidity | liquidity in the reaction tank 4 becomes large, while being able to make reaction efficiency high, it can process on the reaction tank 4 always on the stable reaction conditions. In the above, if the water content is lower than 80 wt%, there is a problem that the fluidity becomes insufficient, and if the water content is higher than 88 wt%, there is a problem that the energy cost becomes too high.
汚泥混合装置2で含水率が調整された混合汚泥は、管路L2を経て混合汚泥貯留槽3に貯留され、混合汚泥供給ポンプ3aにより一定量の混合汚泥が反応槽4に回分供給される。反応槽4に混合汚泥が所定量供給されたのちバルブV6を閉弁し、複数段配設されている加圧スチーム吹き込み手段4a、4b及び管路L25から加圧スチームを吹き込んで攪拌しながら温度160〜250℃、該温度における水蒸気圧以上の圧力で5〜120min反応させる。この高温高圧処理により汚泥がスラリー化され、スラリー状物質が生成する。加圧スチームの吹き込みは、管路L22を経て管路L23及び管路L24から夫々接続する加圧スチーム吹き込み手段4a、4bに供給されると共に管路L25に供給されるが、夫々に供給されるスチームの流量調整は、流量コントローラF1の指示に基づいてバルブV1の開度が自動調整されると共にバルブV2、バルブV3及びバルブV4により調整される。 The mixed sludge whose water content has been adjusted by the sludge mixing device 2 is stored in the mixed sludge storage tank 3 via the pipe L2, and a fixed amount of mixed sludge is supplied to the reaction tank 4 by the mixed sludge supply pump 3a. After a predetermined amount of mixed sludge is supplied to the reaction tank 4, the valve V6 is closed, and the pressure steam is blown from the pressurized steam blowing means 4a, 4b and the pipe line L25 arranged in a plurality of stages, and the temperature is being stirred. The reaction is performed at 160 to 250 ° C. at a pressure equal to or higher than the water vapor pressure at the temperature for 5 to 120 minutes. Sludge is slurried by this high-temperature and high-pressure treatment, and a slurry-like substance is generated. The pressurized steam is supplied to the pressurized steam blowing means 4a and 4b, which are connected from the pipeline L23 and the pipeline L24, respectively, via the pipeline L22, and is supplied to the pipeline L25. The flow rate of the steam is adjusted by the valve V2, the valve V3, and the valve V4 while the opening degree of the valve V1 is automatically adjusted based on an instruction from the flow controller F1.
前記加圧スチームを上下複数段の加圧スチーム吹き込み手段4a、4b及び管路L25から吹き込むことにより、汚泥が均一に加熱及び攪拌される。なお、温度が160℃以下では、スラリー状物質の生成が不十分となったり、長時間の処理が必要となる問題があり、また、250℃以上では、エネルギーコストや高級材質の装置が必要性となることによる設備費の増加をきたす問題を生じる。 Sludge is uniformly heated and stirred by blowing the pressurized steam from the upper and lower stages of pressurized steam blowing means 4a, 4b and the pipe line L25. When the temperature is 160 ° C. or lower, there is a problem that the generation of the slurry-like substance is insufficient or a long-time treatment is required, and when the temperature is 250 ° C. or higher, the energy cost and the equipment of high-grade material are necessary. As a result, there is a problem that the equipment cost increases.
所定の反応時間が経過したのち、バルブV5及びバルブV8を開弁して高温高圧処理により生成したスラリー状物質を管路L4を経て汚泥貯留槽1に内設されている熱交換手段1bに供給し、スラリー状物質は汚泥と熱交換して冷却され、さらにシェルアンドチューブ型の冷却装置5のチューブ側に供給されて、L16からシェル側を経てL17に流通する冷却水により所定温度まで冷却され、管路L5を経てスラリー貯留槽6に供給される。 After a predetermined reaction time has passed, the valve V5 and the valve V8 are opened, and the slurry-like substance generated by the high-temperature and high-pressure treatment is supplied to the heat exchanging means 1b provided in the sludge storage tank 1 via the pipe L4. Then, the slurry-like substance is cooled by exchanging heat with sludge, supplied to the tube side of the shell-and-tube type cooling device 5, and cooled to a predetermined temperature by cooling water flowing from L16 through the shell side to L17. The slurry is supplied to the slurry storage tank 6 via the pipe L5.
前記において、反応槽4からのスラリー状物質の抜き出しは、一点鎖線で示したレベルAまでの一定量を反応槽4に残留させて、次に回分処理する有機性汚泥を供給して混合処理するのが好ましい。また、反応槽4内の減圧及び高温高圧処理により発生した炭酸ガス等の排出は、バルブV7を開弁し、管路L20から図示しない後段の脱臭装置を経て大気に排出されるか、又は一点鎖線で示したバルブV7aを開弁し、管路L21から管路L4を経由してスラリー貯留槽6に供給するか、直接スラリー貯留槽6に供給して管路L19から図示しない後段の脱臭装置を経て大気に排出されることにより行われる。 In the above, extraction of the slurry-like substance from the reaction tank 4 is carried out by leaving a certain amount up to level A indicated by the alternate long and short dash line in the reaction tank 4 and supplying organic sludge to be batch-processed next for mixing treatment. Is preferred. Further, the discharge of carbon dioxide gas or the like generated by the decompression and high-temperature and high-pressure treatment in the reaction tank 4 is performed by opening the valve V7 and exhausting it from the pipe L20 to the atmosphere through a deodorizing device not shown in the drawing or one point. The valve V7a indicated by the chain line is opened and supplied to the slurry storage tank 6 from the pipe L21 via the pipe L4, or directly supplied to the slurry storage tank 6 and not shown from the pipe L19. It is performed by being discharged to the atmosphere via.
スラリー貯留槽6では、スラリー状物質中の固形物の沈降を防止するため、攪拌手段6bにより攪拌されながら貯留され、貯留されたスラリー状物質は、管路L6からスラリー供給ポンプ6aで一定量づつ連続的に抜き出されて後段の脱水装置7に供給される。なお、スラリー状物質の一部は管路L15及びL12を経て汚泥混合装置2に供給され、汚泥の流動性調整に使用することもできる。 In the slurry storage tank 6, in order to prevent sedimentation of solid substances in the slurry-like substance, the slurry-like substance is stored while being stirred by the stirring means 6b, and the stored slurry-like substance is supplied by a fixed amount from the pipe L6 by the slurry supply pump 6a. It is continuously extracted and supplied to the subsequent dewatering device 7. In addition, a part of slurry-like substance is supplied to the sludge mixing apparatus 2 via the pipe lines L15 and L12, and can also be used for the fluidity | liquidity adjustment of sludge.
脱水装置7によりスラリー状物質から液分が分離されて固形分であるケーキが回収され、回収された脱水ケーキは管路L8を経て脱水ケーキ貯留槽8に貯留されたのち、管路L9から図示しないケーキ乾燥設備等の製品化設備に供給されて可燃性固形原料製品とされ、回収された可燃性固形原料製品は、セメント原料且つ焼成燃料等として有効利用することができる。なお、脱水装置7に供給されるスラリー状物質の温度を40〜90℃に調整して供給することにより脱水効率を高めることができる。因みに、20℃で供給すると脱水後固形分の含水率は60wt%以上となるが、80℃で供給すると50wt%近傍にすることができる。 The liquid component is separated from the slurry-like substance by the dehydrating device 7 to collect a cake that is a solid content. The recovered dehydrated cake is stored in the dehydrated cake storage tank 8 via the line L8, and then illustrated from the line L9. The flammable solid raw material product supplied to a commercialization equipment such as a cake drying equipment that is not used and made into a combustible solid raw material product can be effectively used as a cement raw material and a calcined fuel. In addition, dehydration efficiency can be improved by adjusting and supplying the temperature of the slurry-like substance supplied to the dehydration apparatus 7 to 40-90 degreeC. Incidentally, when supplied at 20 ° C., the water content of the solid content after dehydration becomes 60 wt% or more, but when it is supplied at 80 ° C., it can be in the vicinity of 50 wt%.
また、脱水装置7で分離された分離液は、管路L7から分離液貯留槽9に供給されて貯留され、管路L10から分離液排出ポンプ9aにより所定の流量で後段の水処理設備の一部である膜分離装置10に送液される。 In addition, the separated liquid separated by the dehydrator 7 is supplied to and stored in the separated liquid storage tank 9 from the pipe L7, and is separated from the pipe L10 by a separated liquid discharge pump 9a at a predetermined flow rate in one of the subsequent water treatment facilities. The liquid is sent to the membrane separation apparatus 10 as a part.
膜分離装置10に送液された分離液は、分離膜を隔てて非透過側10aに分離液中の難分解性COD成分や溶解性有機物を濃縮した濃縮液と透過側10bに膜を透過して高濃度の有機物等が除去された透過液とに分離される。なお、分離液の一部は一点鎖線で示した管路L14及びL12を経て汚泥混合装置2に供給されて汚泥の含水率調整に使用することもできる。前記の透過液は管路L11を経て図示しない活性汚泥処理装置等の水処理設備に供給されて、最終的に有機物等が浄化処理されたのち放流される。また、濃縮液は管路L12を経て汚泥混合装置2に供給されて汚泥の含水率調整と共に残留有機物の回収が図られる。 The separation liquid sent to the membrane separation device 10 passes through the membrane through the separation membrane and the permeation side 10b through the concentrated solution obtained by concentrating the hardly decomposable COD components and soluble organic substances in the separation solution on the non-permeation side 10a. And separated from the permeate from which high-concentration organic substances and the like have been removed. A part of the separated liquid can also be supplied to the sludge mixing device 2 through the pipelines L14 and L12 indicated by the alternate long and short dash line and used for adjusting the moisture content of the sludge. The permeate is supplied to a water treatment facility such as an activated sludge treatment apparatus (not shown) through a pipe L11, and finally the organic matter is purified and discharged. Further, the concentrated liquid is supplied to the sludge mixing device 2 through the pipe L12, and the residual organic matter is recovered while adjusting the moisture content of the sludge.
1:汚泥貯留槽
2:汚泥混合装置
3:混合汚泥貯留槽
4:高温高圧処理装置(回分式反応槽)
5:冷却装置
6:スラリー貯留槽
7:脱水装置
8:脱水ケーキ貯留槽
9:分離液貯留槽
10:膜分離装置
1: Sludge storage tank 2: Sludge mixing device 3: Mixed sludge storage tank 4: High-temperature high-pressure treatment device (batch type reaction tank)
5: Cooling device 6: Slurry storage tank 7: Dehydration apparatus 8: Dehydrated cake storage tank 9: Separation liquid storage tank 10: Membrane separation apparatus
Claims (8)
The organic substance according to any one of claims 4 to 7, wherein a part of the slurry-like substance generated in the high-temperature and high-pressure treatment step is left to be mixed and treated with organic sludge to be subsequently treated. Sludge treatment method.
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2006117934A1 (en) * | 2005-04-27 | 2006-11-09 | Mitsubishi Kakoki Kaisha, Ltd. | Organic waste disposal facility and method of disposal |
JP2008100218A (en) * | 2006-09-21 | 2008-05-01 | Tsukishima Kikai Co Ltd | Method and apparatus for treating sludge |
JP2009067872A (en) * | 2007-09-12 | 2009-04-02 | Hitachi Plant Technologies Ltd | Fuel production method and device |
JP2009202121A (en) * | 2008-02-28 | 2009-09-10 | Chugoku Electric Power Co Inc:The | Method and system for preparing slurry |
JP2010158616A (en) * | 2009-01-07 | 2010-07-22 | Mitsubishi Heavy Industries Environment & Chemical Engineering Co Ltd | Sludge drying apparatus and sludge drying method |
JP2010284622A (en) * | 2009-06-15 | 2010-12-24 | Chugoku Electric Power Co Inc:The | Method for setting production condition of organic sludge slurry and method for producing organic sludge slurry |
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2004
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WO2006117934A1 (en) * | 2005-04-27 | 2006-11-09 | Mitsubishi Kakoki Kaisha, Ltd. | Organic waste disposal facility and method of disposal |
EP1894893A1 (en) * | 2005-04-27 | 2008-03-05 | Mitsubishi Kakoki Kaisha, Ltd | Organic waste disposal facility and method of disposal |
US8043505B2 (en) | 2005-04-27 | 2011-10-25 | Enertech Environmental, Inc. | Treatment equipment of organic waste and treatment method |
JP4888911B2 (en) * | 2005-04-27 | 2012-02-29 | 三菱化工機株式会社 | Organic waste treatment facility and treatment method |
EP1894893A4 (en) * | 2005-04-27 | 2012-12-26 | Mitsubishi Kakoki Kk | Organic waste disposal facility and method of disposal |
US8551337B2 (en) | 2005-04-27 | 2013-10-08 | SGC Advisors, LLC | Treatment equipment of organic waste and treatment method |
JP2008100218A (en) * | 2006-09-21 | 2008-05-01 | Tsukishima Kikai Co Ltd | Method and apparatus for treating sludge |
JP2009067872A (en) * | 2007-09-12 | 2009-04-02 | Hitachi Plant Technologies Ltd | Fuel production method and device |
JP2009202121A (en) * | 2008-02-28 | 2009-09-10 | Chugoku Electric Power Co Inc:The | Method and system for preparing slurry |
JP2010158616A (en) * | 2009-01-07 | 2010-07-22 | Mitsubishi Heavy Industries Environment & Chemical Engineering Co Ltd | Sludge drying apparatus and sludge drying method |
JP2010284622A (en) * | 2009-06-15 | 2010-12-24 | Chugoku Electric Power Co Inc:The | Method for setting production condition of organic sludge slurry and method for producing organic sludge slurry |
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