JP2006055544A - Dental small brush - Google Patents

Dental small brush Download PDF

Info

Publication number
JP2006055544A
JP2006055544A JP2004243132A JP2004243132A JP2006055544A JP 2006055544 A JP2006055544 A JP 2006055544A JP 2004243132 A JP2004243132 A JP 2004243132A JP 2004243132 A JP2004243132 A JP 2004243132A JP 2006055544 A JP2006055544 A JP 2006055544A
Authority
JP
Japan
Prior art keywords
brush
resin composition
hair
photopolymerizable resin
bundle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2004243132A
Other languages
Japanese (ja)
Inventor
Takasuke Abiko
貴祐 安孫子
Tomoyuki Sato
智之 佐藤
Daiki Machida
大樹 町田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GC Corp
Original Assignee
GC Corp
GC Dental Industiral Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GC Corp, GC Dental Industiral Corp filed Critical GC Corp
Priority to JP2004243132A priority Critical patent/JP2006055544A/en
Publication of JP2006055544A publication Critical patent/JP2006055544A/en
Pending legal-status Critical Current

Links

Abstract

<P>PROBLEM TO BE SOLVED: To provide an excellent dental small brush which makes it difficult for a photopolymerizable resin composition remaining on an end and bundle of the brush to polymerize even if the photopolymerizable resin composition is left on the end and bundle of the brush as it sticks thereon, and which needs nearly no dissolution and removal of the cured resin on the end and bundle of the brush by using a commercial organic solvent-based brush cleaner consisting mainly of chloroform, acetone or the like. <P>SOLUTION: In the dental small brush, a brush portion is dyed yellow, and the photopolymerizable resin composition remaining on the end and bundle of the brush is hard to polymerize. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、歯科で使用される光重合型樹脂組成物を使用する際に用いられる歯科用小筆に関するものである。   The present invention relates to a dental brush used when using a photopolymerizable resin composition used in dentistry.

現在、歯科治療において、義歯床用レジンやコンポジットレジン等の歯科用重合性樹脂組成物は操作性、審美性、強度に優れる事から、広く使用されるに至っている。特に、可視光によって重合する光重合型樹脂組成物は、生体に対して安全に光重合型樹脂組成物を重合することができる上、任意のタイミングで硬化させることが可能な操作性や硬化物の強度が高い等が評価され歯科治療分野で最も広く使用されている(例えば、特許文献1参照。)。   Currently, in dental treatment, dental polymerizable resin compositions such as denture base resins and composite resins are widely used because of their excellent operability, aesthetics and strength. In particular, the photopolymerizable resin composition that is polymerized by visible light is capable of polymerizing the photopolymerizable resin composition safely with respect to the living body, and is also operable and hardened so that it can be cured at any timing. It is most widely used in the dental treatment field because of its high strength (see, for example, Patent Document 1).

光重合型樹脂組成物は、重合可能な単量体と光重合開始剤を含み、光を照射すると光重合開始剤が光を吸収して活性化し、ラジカル分子や水素イオン等の物質が生成され単量体の重合反応が開始される。歯科で用いられる光重合型樹脂組成物に含まれる光重合開始剤としてはカンファーキノン等の光波長域が400nm〜520nmまでの可視光に感応する物質が主に用いられている。   The photopolymerizable resin composition contains a polymerizable monomer and a photopolymerization initiator, and when irradiated with light, the photopolymerization initiator absorbs light and activates to generate substances such as radical molecules and hydrogen ions. The monomer polymerization reaction is initiated. As a photopolymerization initiator contained in a photopolymerizable resin composition used in dentistry, a substance sensitive to visible light having a light wavelength range of 400 nm to 520 nm such as camphorquinone is mainly used.

歯科で用いられる光重合型樹脂組成物としては、硬質レジンのオペーク材等ペースト状のものや、エアーバリヤー材や表面滑沢材等液状から成るものがあり、これらを歯科用補綴物の適用箇所に塗布する際には筆が用いられることがある(例えば、非特許文献1参照。)。このとき、使用後の筆から光重合型樹脂組成物を単に布等で拭き取っただけでは筆の毛部内部には光重合型樹脂組成物が残存したままなので、そのまま環境光下に放置してしまうと光重合型樹脂組成物が硬化して毛先や毛束が固着してしまい、次に筆を使用する際に非常に扱い難くなってしまうという問題があった。更に筆への残存量が多かったり長時間放置して重合が進んでしまうと筆から除去することは非常に困難であった。   Photopolymerization resin compositions used in dentistry include pastes such as hard resin opaque materials, and liquids such as air barrier materials and surface lubricants, which are applied to dental prostheses. A brush may be used when applying to (for example, refer nonpatent literature 1). At this time, simply wiping the photopolymerizable resin composition from the used brush with a cloth or the like, the photopolymerizable resin composition remains inside the brush hair, so leave it under ambient light. As a result, the photopolymerizable resin composition is cured and the hair ends and the hair bundles are fixed, which makes it very difficult to handle the next time the brush is used. Further, when the amount remaining in the brush is large or the polymerization proceeds after being left for a long time, it was very difficult to remove from the brush.

そこで、クロロホルムやアセトン等やそれらを主成分とする市販の有機溶剤系の筆クリーナーを利用して毛先や毛束内で硬化した樹脂を溶解して除去する方法が行われている。しかし、強力な有機溶剤は環境や人体に悪いばかりでなく、これらを用いると毛束を筆の柄に固定している接着剤をも溶解されてしまい筆の柄から毛束が脱落し再使用できなくなるという虞もあった。   Therefore, a method of dissolving and removing the resin cured in the hair tips and hair bundles using chloroform, acetone or the like or a commercially available organic solvent brush cleaner mainly containing them has been performed. However, strong organic solvents are not only bad for the environment and human body, but if they are used, the adhesive that fixes the hair bundle to the handle of the brush will be dissolved, and the hair bundle will fall off the brush handle and be reused. There was also a risk that it would be impossible.

特開昭48−49875号公報JP 48-49875 A 坪田明史、他4名,「『アイサイト』を応用した前装補綴装置」,日本歯科評論 別冊2003,p.95-98Akifumi Tsubota, 4 others, “A front-dressing prosthetic device using“ Eyesight ””, Japan Dental Review, separate volume 2003, p.95-98

本発明は、筆の毛先や毛束に光重合型樹脂組成物が付着したまま放置されても、毛先や毛束に残存した光重合型樹脂組成物が重合し難い歯科用小筆であって、有機溶媒を用いる必要が殆どない優れた歯科用小筆を提供することを課題とする。   The present invention is a dental small brush that is difficult to polymerize the photopolymerizable resin composition remaining on the hair tip or hair bundle even if the photopolymerizable resin composition is left on the hair tip or hair bundle of the brush. Therefore, an object of the present invention is to provide an excellent dental brush with little need for using an organic solvent.

本発明者らは前記課題を解決するために鋭意検討した結果、筆の毛部に、光重合開始剤であるカンファーキノン等の励起光波長域である400nm〜520nmの光を吸収してしまう効果を与えると前記課題を解決できることを見いだし本発明を完成した。   As a result of intensive studies to solve the above-mentioned problems, the present inventors have absorbed the light of 400 nm to 520 nm, which is an excitation light wavelength region such as camphorquinone, which is a photopolymerization initiator, into the hair of the brush. And the present invention was completed.

即ち本発明は、毛部が黄色に着色され、毛先や毛束に残存した光重合型樹脂組成物が重合し難いことを特徴とする歯科用小筆である。   That is, the present invention is a dental small brush characterized in that the hair part is colored yellow and the photopolymerizable resin composition remaining on the hair tips and hair bundles is difficult to polymerize.

本発明に係る歯科用小筆は、毛先が黄色いため、歯科で用いられる光重合型樹脂組成物に含まれる光重合開始剤であるカンファーキノン等の励起光波長域である400nm〜520nmの光が吸収されるので毛先や毛束に残存した光重合型樹脂組成物が硬化し難く、筆の毛先や毛束に光重合型樹脂組成物が付着したまま長時間放置されても、毛先や毛束の光重合型樹脂組成物が重合して固着してしまうことが起こり難い。そのため次回の使用時にも通常の使用感を維持することができるのである。   Since the dental brush according to the present invention has a yellow hair tip, light having a wavelength of 400 nm to 520 nm which is an excitation light wavelength region such as camphorquinone which is a photopolymerization initiator contained in a photopolymerization type resin composition used in dentistry. The photopolymerizable resin composition remaining on the hair tips and hair bundles is hard to be cured, and even if the photopolymerizable resin composition remains attached to the brush tips and hair bundles, It is unlikely that the photopolymerizable resin composition of the tip or hair bundle will be polymerized and fixed. Therefore, a normal feeling of use can be maintained at the next use.

本発明に係る歯科用小筆の毛部の材質及び形状は、歯科で通常用いられるものであれば特に限定されず使用することができる。例えば毛材としては各種獣毛、またはナイロン 、ポリブチレンテレフタレート,ポリプロピレン等の化学合成繊維を用いることができる。また、本発明においては毛部の材質が光不透過性であると毛束の内部に光が入り難いのでより高い効果を望める。また、励起光波長域である波長400nm〜520nmの光を吸収する効果があるので毛部の材質が透明であっても十分にその効果を得ることができる。   The material and shape of the hair part of the dental brush according to the present invention are not particularly limited as long as they are usually used in dentistry. For example, as the hair material, various animal hairs or chemically synthetic fibers such as nylon, polybutylene terephthalate, and polypropylene can be used. In the present invention, if the material of the hair portion is light-impermeable, it is difficult for light to enter the inside of the hair bundle, so that a higher effect can be expected. In addition, since there is an effect of absorbing light having a wavelength of 400 nm to 520 nm which is an excitation light wavelength region, the effect can be sufficiently obtained even if the material of the hair portion is transparent.

本発明に於いて毛部を着色する黄色は、光重合開始剤であるカンファーキノン等の励起光波長域である波長400nm〜520nmの光を吸収する効果を筆の毛部に与えるために選択された色であり、波長400nm〜520nmの所謂青色に対する補色関係にある色である。従って、波長400nm〜520nmの光を吸収する効果を有している黄色であれば詳細は特に限定はされない。   The yellow color of the hair in the present invention is selected in order to give the brush hair the effect of absorbing light having a wavelength of 400 nm to 520 nm, which is an excitation light wavelength region such as camphorquinone which is a photopolymerization initiator. This color is complementary to the so-called blue color having a wavelength of 400 nm to 520 nm. Accordingly, the details are not particularly limited as long as the yellow color has an effect of absorbing light having a wavelength of 400 nm to 520 nm.

本発明に係る歯科用小筆の毛部を黄色に着色する手段としては、黄色い顔料を練りこんだ化学合成毛を用いる方法や黄色い染料で染める方法等が自由に利用できる。このとき、光重合型樹脂組成物と反応して変色や脱色が生じないこと、及び、光重合型樹脂組成物そのものの物性に影響を与えないことは必要である。   As a means for coloring the hair of the dental brush according to the present invention to yellow, a method using chemically synthesized hair kneaded with a yellow pigment, a method of dyeing with a yellow dye, or the like can be used freely. At this time, it is necessary that the discoloration or decoloration does not occur by reacting with the photopolymerizable resin composition, and that the physical properties of the photopolymerizable resin composition itself are not affected.

Claims (1)

毛部が黄色に着色され、毛先や毛束に残存した光重合型樹脂組成物が重合し難いことを特徴とする歯科用小筆。   A dental small brush characterized in that the hair part is colored yellow and the photopolymerizable resin composition remaining on a hair tip or a hair bundle is difficult to polymerize.
JP2004243132A 2004-08-24 2004-08-24 Dental small brush Pending JP2006055544A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2004243132A JP2006055544A (en) 2004-08-24 2004-08-24 Dental small brush

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2004243132A JP2006055544A (en) 2004-08-24 2004-08-24 Dental small brush

Publications (1)

Publication Number Publication Date
JP2006055544A true JP2006055544A (en) 2006-03-02

Family

ID=36103493

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2004243132A Pending JP2006055544A (en) 2004-08-24 2004-08-24 Dental small brush

Country Status (1)

Country Link
JP (1) JP2006055544A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04176453A (en) * 1990-11-12 1992-06-24 Norimichi Kawamura Aethetic bracket and aethetic arch wire
JP2000237207A (en) * 1999-02-23 2000-09-05 Gc Corp Dental malaxation base material
JP2000282327A (en) * 1999-03-29 2000-10-10 Toray Monofilament Co Ltd Black polyester yarn, its use, its production and black polyester master batch
JP2003189929A (en) * 2001-10-16 2003-07-08 Aubex Corp Application device, and method for manufacturing the same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04176453A (en) * 1990-11-12 1992-06-24 Norimichi Kawamura Aethetic bracket and aethetic arch wire
JP2000237207A (en) * 1999-02-23 2000-09-05 Gc Corp Dental malaxation base material
JP2000282327A (en) * 1999-03-29 2000-10-10 Toray Monofilament Co Ltd Black polyester yarn, its use, its production and black polyester master batch
JP2003189929A (en) * 2001-10-16 2003-07-08 Aubex Corp Application device, and method for manufacturing the same

Similar Documents

Publication Publication Date Title
Aksornmuang et al. Effects of C-factor and resin volume on the bonding to root canal with and without fibre post insertion
Bonfante et al. SEM observation of the bond integrity of fiber-reinforced composite posts cemented into root canals
JP5851407B2 (en) Removable colored layer for artificial nail coating and method therefor
Daood et al. In vitro analysis of riboflavin-modified, experimental, two-step etch-and-rinse dentin adhesive: Fourier transform infrared spectroscopy and micro-Raman studies
Cadenaro et al. Effect of adhesive hydrophilicity and curing time on the permeability of resins bonded to water vs. ethanol-saturated acid-etched dentin
Miletic et al. Monomer-to-polymer conversion and micro-tensile bond strength to dentine of experimental and commercial adhesives containing diphenyl (2, 4, 6-trimethylbenzoyl) phosphine oxide or a camphorquinone/amine photo-initiator system
Ferreira et al. Improvement of exposure times: effects on adhesive properties and resin-dentin bond strengths of etch-and-rinse adhesives
Meereis et al. Stability of initiation systems in acidic photopolymerizable dental material
BR112018067870B1 (en) Photocurable composition.
JP4401959B2 (en) Nonvolatile dental composition
JP4774195B2 (en) Dental member and surface modification treatment method for dental member
Muñoz et al. The sonic application of universal adhesives in self-etch mode improves their performance on enamel
JP2006055544A (en) Dental small brush
CN104546509A (en) Elastic layer material for preventing micro leakage after caries repair as well as preparation method and application thereof
Ogliari et al. 2, 3-Epithiopropyl methacrylate as functionalized monomer in a dental adhesive
Furukawa et al. All-in-one self-etch model adhesives: HEMA-free and without phase separation
Shakya et al. Analysis of micro-shear bond strength of self-etch adhesive systems with dentine: An in vitro study
Dimitriadi et al. Effect of curing mode on the conversion and IIT-derived mechanical properties of core build-up resin composites
Mirzaei et al. The effect of dentin surface pretreatment using dimethyl sulfoxide on the bond strength of a universal bonding agent to dentin
JP2006312596A (en) Nail manicure
Schoon et al. Cosmetics for abnormal and pathological nails
Penelas et al. Development and characterization of biological bovine dentin posts
JP4931398B2 (en) Dental adhesive
CN116490096A (en) Photocurable artificial nails, methods of making and using the same
Ayar et al. Effect of ethanol-wet-bonding technique on resin–enamel bonds

Legal Events

Date Code Title Description
A621 Written request for application examination

Effective date: 20070606

Free format text: JAPANESE INTERMEDIATE CODE: A621

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20100512

A02 Decision of refusal

Effective date: 20101005

Free format text: JAPANESE INTERMEDIATE CODE: A02