JP2006034872A - Female member for hook-and-loop fastener and production method of the same - Google Patents

Female member for hook-and-loop fastener and production method of the same Download PDF

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JP2006034872A
JP2006034872A JP2004223100A JP2004223100A JP2006034872A JP 2006034872 A JP2006034872 A JP 2006034872A JP 2004223100 A JP2004223100 A JP 2004223100A JP 2004223100 A JP2004223100 A JP 2004223100A JP 2006034872 A JP2006034872 A JP 2006034872A
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hook
nonwoven fabric
female material
melting point
loop fastener
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Toshiya Yamamoto
俊也 山本
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Toyobo Co Ltd
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<P>PROBLEM TO BE SOLVED: To provide a female member for a hook-and-loop fastener, which raises fewer naps after the exfoliation of a male material, is easy to peel off, makes less peeling sound, is capable of bearing clear printed patterns, offers a soft texture, is pearmeable to gas, and enables the vaccum carriage on production. <P>SOLUTION: This female member for a hook-and-loop fastener is a nonwoven fabric that is made of continuous fibers with a fineness of 1.1 to 11 dtex, containing 1 to 20 percent by weight of an aromatic copolymeric polyester (melting point:Tm2≤Tm1-30°C) to an aromatic polyester (melting point:Tm1), and that has a basis weight of 20 to 80 g/m<SP>2</SP>. The surface of the nonwoven fabric is bonded by heat, and subjected to embossing working having a surface ratio of 10 to 60 percent of its surface. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は面ファスナー雌材に関し、さらに詳しくは、雄材を剥離後の毛羽立ちが少なく、鮮明な色の印刷を行うことができ、更には剥がし易く、風合いも柔らかく、剥離音が静かであり、かつ生産性に優れた安価な面ファスナー雌材に関する。   The present invention relates to a female material for hook-and-loop fasteners, and more specifically, the fluff after peeling off the male material can be printed with clear colors, it is easy to peel off, the texture is soft, the peeling sound is quiet, and The present invention relates to an inexpensive surface fastener female material excellent in productivity.

近年、紙おむつ等の止着用テープとして、面ファスナー方式のものが種々提案されている。面ファスナー方式とは、雄材と雌材が対になっており、雄材はフック型の樹脂成形体であり、雌材はそのフックをつなぎ止める役目を担っている。これらは粘着テープ方式と異なり着け剥がしが自在であり、粘着テープの欠点であったつけ間違いによる問題(紙おむつに使用した場合のオムツの破あるいは乳児の皮膚への接着等)を回避することができる。これまでに提案された面ファスナー雌材としては、フィルムと編み物を接着剤で積層したタイプがある。かかる面ファスナー雌材は、印刷性にも優れておりキャラクターデザイン付与にも対応した部材である。しかしながらかかるフィルムと編み物を接着した面ファスナー雌材は、生産性が悪く、高価な部材となっている。   In recent years, various types of hook-and-loop fasteners have been proposed as fastening tapes for paper diapers and the like. In the hook-and-loop fastener method, a male material and a female material are paired, and the male material is a hook-shaped resin molded body, and the female material plays a role of holding the hook. Unlike the adhesive tape method, these can be peeled off and peeled off, and can prevent problems caused by incorrect attachment (breaking of diapers when used on paper diapers or adhesion to infants' skin, etc.). . As a surface fastener female material proposed so far, there is a type in which a film and a knitted fabric are laminated with an adhesive. Such a hook-and-loop female material is a member that is excellent in printability and that can be used for character design. However, the surface fastener female material in which such a film and a knitted material are bonded has low productivity and is an expensive member.

上述の問題を解消する面ファスナー雌材として、2層の異なった繊度及び目付で構成された比較的安価でファスニング性に優れた面ファスナー雌材が提案されている(例えば特許文献1)。しかしながら、かかる部材は印刷性が劣り、キャラクターデザイン等を印刷して、最終製品の意匠性を付与するには不向きであった。   As a hook-and-loop female material that solves the above-described problems, a hook-and-loop female material that is relatively inexpensive and excellent in fastening properties, which has two layers of different fineness and basis weight, has been proposed (for example, Patent Document 1). However, such a member is inferior in printability, and is unsuitable for printing a character design or the like and imparting design properties of the final product.

また、不織布の片面にニードルパンチによってループを形成し、表面を樹脂加工によってループを固定した面ファスナー雌材も提案されている(例えば特許文献2)。しかしながらこの部材においてはニードルパンチ加工によって不織布の斑が大きくなっていまい、オムツ製造工程でのバキューム搬送性ができなくなってしまう。   In addition, a surface fastener female material in which a loop is formed on one side of a nonwoven fabric by needle punching and the surface is fixed by resin processing has been proposed (for example, Patent Document 2). However, in this member, the unevenness of the nonwoven fabric is increased by the needle punching process, and the vacuum transportability in the diaper manufacturing process cannot be performed.

更に、10μm以下の繊維からなる不織布を含む基材と短繊維ウェブが積層されてなり、かつ熱融着領域と非熱融着領域が存在することを特徴とする面ファスナー 雌材が提案されている。この部材はバキューム搬送性にはすぐれているが、繰り返し剥離耐久性に劣り、付け直しをした場合、毛羽立ちが多く見られ且つ剥がし難くなるという欠点を有する。   Furthermore, a surface fastener female material is proposed in which a base material including a nonwoven fabric made of fibers of 10 μm or less and a short fiber web are laminated, and a heat fusion region and a non-heat fusion region exist. Yes. Although this member is excellent in vacuum transportability, it has a drawback that it is inferior in repeated peeling durability, and when it is reattached, a lot of fluff is seen and it is difficult to peel off.

特許第3187423号公報Japanese Patent No. 3187423 特開平10−304909号公報JP-A-10-304909 特開2004−12548号公報JP 2004-12548 A

本発明は、雄材を剥離後の毛羽立ちが少なく、剥がし易く、剥離音が小さく、鮮明な印刷柄を付与することができ、風合いが柔らかく、通気性があり、かつ製造時のバキューム搬送性が可能な面ファスナー雌材を提供することを課題とするものである。   The present invention has less fuzz after peeling off the male material, is easy to peel off, has a low peeling sound, can give a clear printed pattern, has a soft texture, has air permeability, and can carry a vacuum during production. An object of the present invention is to provide a female hook-and-loop fastener material.

本発明は、上記課題を解決するために鋭利検討した結果得られたものであり、以下の構成を採用するものである。
すなわち(a)芳香族ポリエステル(融点:Tm1)に対し、芳香族共重合ポリエステル(融点:Tm2≦Tm1−30℃)を1〜20重量%含有した繊度1.1〜11dtexの連続繊維からなる目付が20〜80g/m2の不織布であって、当該不織布の表面を面積率が10〜60%のエンボス加工によって熱接着加工されていることを特徴とする面ファスナー雌材(b)芳香族ポリエステルがポリブチレンテレフタレート(以下PBT)、及び/又はポリトリメチレンテレフタレート(以下PTT)であることを特徴とする(a)記載の面ファスナー雌材、(c)不織布の表面に樹脂加工剤を含む着色剤を印刷することを特徴とする(a)又は(b)記載の面ファスナー雌材、(d)樹脂加工がグラビア、オフセットグラビア及びフレキソ法のいずれかであることを特徴とする(c)記載の面ファスナー雌材の製造方法、(e)樹脂加工により形成される柄が全面、ドット、格子柄のいずれかであることを特徴する(d)記載の面ファスナー雌材の製造方法である。
The present invention has been obtained as a result of keen studies to solve the above-described problems, and employs the following configuration.
That is, (a) The basis weight comprising a continuous fiber having a fineness of 1.1 to 11 dtex containing 1 to 20% by weight of an aromatic copolymer polyester (melting point: Tm2 ≦ Tm1-30 ° C.) with respect to the aromatic polyester (melting point: Tm1). Is a non-woven fabric of 20 to 80 g / m 2 , and the surface of the non-woven fabric is heat bonded by embossing with an area ratio of 10 to 60%. (B) Aromatic polyester Is a surface fastener female material according to (a), characterized in that is polybutylene terephthalate (hereinafter referred to as PBT) and / or polytrimethylene terephthalate (hereinafter referred to as PTT), and (c) a color containing a resin processing agent on the surface of the nonwoven fabric. The surface fastener female material according to (a) or (b), wherein the agent is printed, (d) the resin processing is gravure, offset gravure and flare (C) The method for producing a female material for a hook-and-loop fastener according to (c), (e) the pattern formed by resin processing is any one of a whole surface, a dot, and a lattice pattern (D) is a method for manufacturing the female fastener of the surface fastener described in (d).

本発明によれば、雄材を剥離後の毛羽立ちが少なく、剥がし易く、キャラクターデザインなどの鮮明な印刷柄を有し、かつ風合いが柔らかく、ファスナー面に印刷した際の耐色落ち性が良く、バキューム搬送性が可能な面ファスナー雌材を提供することができる。   According to the present invention, there is little fuzz after peeling off the male material, it is easy to peel off, has a clear printed pattern such as a character design, has a soft texture, has good color fading resistance when printed on a fastener surface, and is vacuum A hook-and-loop female material capable of being conveyed can be provided.

以下、本発明を詳細に説明する。
本発明における面ファスナー雌材の不織布の目付は、20〜80g/m2であることが好ましい。目付が20g/m2未満であると、製造時のバキューム搬送性が難しくなる傾向があり、目付が80g/m2を超えるとファスナーの剥離力が弱く、乳幼児などの着用者の動きによって外れる場合がある。好ましい目付は25〜70g/m2であり、より好ましくは30〜50g/m2である。
Hereinafter, the present invention will be described in detail.
It is preferable that the fabric weight of the nonwoven fabric of the hook-and-loop fastener female material in this invention is 20-80 g / m < 2 >. When the basis weight is less than 20 g / m 2 , there is a tendency that the vacuum transportability at the time of manufacture tends to be difficult, and when the basis weight exceeds 80 g / m 2 , the peeling force of the fastener is weak and it is detached by the movement of a wearer such as an infant. There is. A preferable basis weight is 25 to 70 g / m 2 , and more preferably 30 to 50 g / m 2 .

本発明にかかる面ファスナー雌材を形成する不織布の繊度は1.1〜11.0dtexであることが好ましい。繊度が1.1dtex未満であるとファスナーの剥離力が弱く、乳幼児などの着用者の動きによって面ファスナーが剥離する場合がある。また繊度が11.0dtexを超えると、ファスナーが剥がし難くなり、更に斑が悪化するためオムツラインでのバキューム搬送ができなくなる場合がある。更に好ましい繊度は1.1〜5.5dtexであり、より好ましくは1.1〜2.2dtexである。   The fineness of the nonwoven fabric forming the female hook-and-loop fastener material according to the present invention is preferably 1.1 to 11.0 dtex. When the fineness is less than 1.1 dtex, the peeling force of the fastener is weak, and the hook-and-loop fastener may peel off due to the movement of a wearer such as an infant. On the other hand, if the fineness exceeds 11.0 dtex, it is difficult to peel off the fastener, and the spots are further deteriorated, so that vacuum conveyance on the diaper line may not be possible. The fineness is more preferably 1.1 to 5.5 dtex, more preferably 1.1 to 2.2 dtex.

本発明にかかる面ファスナー雌材を形成する不織布は、エンボス面積率が10%〜60%であることが好ましい。10%未満であると面ファスナー剥離後の毛羽立ちが顕著になり、繰り返して貼ることが困難となる。一方、60%を越えると、面ファスナーの係合力が不足する。更に好ましいエンボス面積の範囲は15〜55%、最も好ましくは20〜40%である。   It is preferable that the nonwoven fabric which forms the surface fastener female material according to the present invention has an embossed area ratio of 10% to 60%. If it is less than 10%, fluffing after peeling of the surface fastener becomes remarkable, and it becomes difficult to repeatedly apply. On the other hand, if it exceeds 60%, the engaging force of the surface fastener is insufficient. A more preferred embossed area range is 15-55%, most preferably 20-40%.

本発明でいう芳香族ポリエステルとは、ポリエチレンテレフタレート、ポリエチレンナフタレート、ポリブチレンテレフタレート、ポリブチレンナフタレート、ポリシクロヘキシレンジメチルテレフタレートなどの芳香族ジカルボン酸とジオールのポリエステルをいう。本発明に用いる芳香族ポリエステルは、保持できる融点(以下Tmと略す)が220℃〜250℃であり、結晶性が高く、モジュラスがやや低い芳香族ポリエステルであることが好ましく、これらの特性を満足するものとして、ポリトリメチレンテレフタレート(以下PTTと略す:Tm;221℃)、ポリトリメチレンナフタレート(以下PTNと略す:Tm;238℃)、ポリブチレンテレフタレート(以下PBTと略す:Tm1;233℃)やポリブチレンナフタレート(以下PBNと略す:Tm1;243℃)などがあげられる。これらの芳香族ポリエステルを用いることにより、柔らかく、剥がし易く、剥離音が小さい面ファスナー雌材を得ることが可能となる。 The aromatic polyester referred to in the present invention means a polyester of an aromatic dicarboxylic acid and a diol such as polyethylene terephthalate, polyethylene naphthalate, polybutylene terephthalate, polybutylene naphthalate, polycyclohexylene dimethyl terephthalate. The aromatic polyester used in the present invention is preferably an aromatic polyester having a melting point (hereinafter abbreviated as Tm) of 220 ° C. to 250 ° C., high crystallinity, and slightly low modulus, and satisfying these characteristics. Polytrimethylene terephthalate (hereinafter abbreviated as PTT: Tm; 221 ° C.), polytrimethylene naphthalate (hereinafter abbreviated as PTN: Tm; 238 ° C.), polybutylene terephthalate (hereinafter abbreviated as PBT: Tm 1; 233 ° C.) ) And polybutylene naphthalate (hereinafter abbreviated as PBN: Tm1; 243 ° C.). By using these aromatic polyesters, it is possible to obtain a female female hook-and-loop fastener that is soft, easy to peel off and has a small peeling sound.

本発明でいう芳香族共重合ポリエステルとは、上記芳香族ポリエステルに他の第三成分を共重合したポリエステルをいい、例えば、他の第三成分としては、酸成分では、イソフタール酸、アジピン酸、セバチン酸、グルタル酸等の第三成分を共重合したものや、ジオール成分としては、ジエチレングリコール、ネオペンチルグリコール、ブタンジオール/エチレングリコール、などのジオール成分を共重合したポリエステルをいう。 The aromatic copolyester referred to in the present invention refers to a polyester obtained by copolymerizing the above aromatic polyester with another third component. For example, as the other third component, in the acid component, isophthalic acid, adipic acid, A copolymer obtained by copolymerizing a third component such as sebacic acid or glutaric acid or a diol component refers to a polyester obtained by copolymerizing a diol component such as diethylene glycol, neopentyl glycol, or butanediol / ethylene glycol.

本発明で用いる芳香族共重合ポリエステルの融点(以下Tm2と略す)は、Tm2 ≦Tm1−30℃)である。Tm1−30℃を超えるTm2では、繊維間の接着性を向上し難いという不具合を生じる。Tm2は共重合成分と共重合量で変化するので、必要に応じて、Tm2をTm1+30℃になるように処方して重合させる必要がある。 The melting point (hereinafter abbreviated as Tm2) of the aromatic copolyester used in the present invention is Tm2 ≦ Tm1-30 ° C.). At Tm2 exceeding Tm1-30 ° C., the problem that it is difficult to improve the adhesion between fibers is caused. Since Tm2 varies depending on the copolymerization component and the amount of copolymerization, it is necessary to prescribe and polymerize Tm2 to be Tm1 + 30 ° C., if necessary.

本発明の芳香族共重合ポリエステルを用いることにより、面ファスナーとして必要な係合力を保持し、且つ剥離音が小さく、更には鮮明な印刷が可能となる。 By using the aromatic copolymer polyester of the present invention, it is possible to maintain the engaging force required as a hook-and-loop fastener, to reduce the peeling noise, and to achieve clear printing.

本発明で共重合芳香族ポリエステルを芳香族ポリエステルに含有させる理由は以下の通りである。すなわち、溶融した芳香族ポリエステルのマトリックス中に共重合芳香族ポリエステルが分散した状態で溶融紡糸されるが、このとき、接触界面では、共重合ポリエステルと芳香族ポリエステルとの共重合が進み、添加量が少ないと比較的短時間で共重合は完結してマトリックス中に分散している。次いで、紡糸オリフィスで大きなせん断力を受けると、溶融粘度の低い共重合体はオリフィス壁面へと弾き出されてシースコア構造を形成すると類推される。かくして紡糸された繊維は、固化点付近まで冷却しつつネット上にウエッブ状に引き取られるが、このとき、共重合ポリエステルを含有させたものは、接触する繊維間の界面の接合力が、高くなり、次いで、エンボス加工等をおこなっても、不織布強力は非常に向上してくる。この結果から、シースコア構造化している可能性が考えられる。 The reason why the aromatic aromatic polyester is contained in the aromatic polyester in the present invention is as follows. In other words, melt spinning is performed in a state where the copolymerized aromatic polyester is dispersed in the matrix of the melted aromatic polyester. At this time, the copolymerization of the copolymerized polyester and the aromatic polyester proceeds at the contact interface, and the addition amount If the amount is small, the copolymerization is completed in a relatively short time and dispersed in the matrix. Next, when a large shearing force is applied to the spinning orifice, it is assumed that the copolymer having a low melt viscosity is ejected to the wall surface of the orifice to form a seascore structure. The fiber thus spun is taken up in the form of a web on the net while cooling to the vicinity of the solidification point. At this time, those containing a copolyester have a high bonding force at the interface between the contacting fibers. Then, even if embossing or the like is performed, the strength of the nonwoven fabric is greatly improved. From this result, it is possible that the seascore is structured.

このときの繊維を構成する樹脂の平均的特性である融点及び流動開始温度はわずかに低下するに留まる。すなはち、主成分である芳香族ポリエステルの特性をほとんど損なわない挙動を示す。本発明では、このような効果が発現できる芳香族共重合ポリエステルの含有量は1〜20重量%である。1%未満では効果がほとんど認められない。20重量%を超える含有量では、主成分である芳香族ポリエステルの特性がやや低下する場合があるので好ましくない。 At this time, the melting point and the flow start temperature, which are average characteristics of the resin constituting the fiber, are only slightly lowered. In other words, it exhibits a behavior that does not substantially impair the characteristics of the aromatic polyester as the main component. In the present invention, the content of the aromatic copolymer polyester capable of exhibiting such an effect is 1 to 20% by weight. If it is less than 1%, almost no effect is observed. A content exceeding 20% by weight is not preferable because the characteristics of the aromatic polyester as the main component may be slightly deteriorated.

共重合芳香族ポリエステル(B)を芳香族ポリエステル(A)に含有させる方法としては以下の方策が実施できる。
一つ目は両乾燥レジンを投入してブレンダーで混合させる方法、二つ目はAペレット製造段階にB成分を直接練り込む方法、三つ目はレジン溶融工程前にAペレット供給配管横からスクリューフィーダーによって一定量のBペレットを供給する。
The following measures can be implemented as a method for incorporating the copolymerized aromatic polyester (B) into the aromatic polyester (A).
The first is a method in which both dry resins are added and mixed in a blender, the second is a method in which the B component is directly kneaded into the A pellet production stage, and the third is a screw from the side of the A pellet supply pipe before the resin melting step. A certain amount of B pellet is supplied by a feeder.

かくして、共重合したポリエステルの融点及び流動開始温度は低下する。本発明での流動開始温度は、好ましくは110℃〜240℃、より好ましくは120℃〜230℃、最も好ましくは130℃〜180℃である。流動開始温度は、本発明では、示差走査型熱量計にて測定した吸熱開始温度で代替することができる。110℃以下では、後加工や貼りあわせラミネート加工等で熱収縮による幅入りが発生し好ましくない。240℃を超えると、成形時のセット性が悪くなるので好ましくない。また、不織布製造工程での不織布形成時の加熱処理を高温で行う必要が出てくるので省エネルギー的に不利になる問題がある。 Thus, the melting point and flow start temperature of the copolymerized polyester are reduced. The flow start temperature in the present invention is preferably 110 ° C to 240 ° C, more preferably 120 ° C to 230 ° C, and most preferably 130 ° C to 180 ° C. In the present invention, the flow start temperature can be replaced by the endothermic start temperature measured with a differential scanning calorimeter. When the temperature is 110 ° C. or lower, a width is caused by heat shrinkage in post-processing, laminating, and the like, which is not preferable. If it exceeds 240 ° C., the setability at the time of molding is deteriorated, which is not preferable. Moreover, since it becomes necessary to perform the heat processing at the time of nonwoven fabric formation in a nonwoven fabric manufacturing process at high temperature, there exists a problem which becomes disadvantageous in terms of energy saving.

本発明スパンボンド不織布を構成する繊維の接合形態は特には限定されないが、薄物で強力が必要なものは、エンボス加工が適当である。エンボス加工は、ドット加工、表面平滑を要求される場合は、プレーン加工が好ましい。厚もので嵩高なものが必要な場合は、ニードルパンチ加工が適当である。 The form of bonding of the fibers constituting the spunbonded nonwoven fabric of the present invention is not particularly limited, but embossing is appropriate for thin materials that require strength. Embossing is preferably plane processing when dot processing or surface smoothing is required. If a thick and bulky material is required, needle punching is appropriate.

以下に本発明不織布の製法の一例を示す。
固有粘度1.20以上、1.80以下のポリブチレンテレフタレート(以下PBTと略す)とポリエチレンテレフタレートにジオールを例えば30モル%共重合した融点が180℃の芳香族ポリエステル(PET共重合体)を混合しつつ真空乾燥して、少なくとも水分率を0.003重量%以下として紡糸に供することが推奨される。本発明での好ましい水分率は0.002重量%以下である。乾燥工程を省略して、紡糸段階でベントより水分を除去する場合は、押出機で溶融される直前及び直後に高真空で水分を除去する方法が推奨される。
Below, an example of the manufacturing method of this invention nonwoven fabric is shown.
Polybutylene terephthalate (hereinafter abbreviated as PBT) having an intrinsic viscosity of 1.20 or more and 1.80 or less and an aromatic polyester (PET copolymer) having a melting point of 180 ° C. obtained by copolymerizing, for example, 30 mol% of diol with polyethylene terephthalate However, it is recommended that it be vacuum-dried and used for spinning at a moisture content of 0.003% by weight or less. A preferable moisture content in the present invention is 0.002% by weight or less. When the drying process is omitted and moisture is removed from the vent at the spinning stage, a method of removing moisture at a high vacuum immediately before and after being melted by an extruder is recommended.

ついで、常法により、溶融紡糸を行う。紡糸温度は、ポリブチレンテレフタレートの融点より15℃〜40℃高い温度が推奨される。好ましくは25℃〜35℃高い温度が推奨される。オリフィスから溶融ポリマーを吐出するに際し、本発明では、せん断速度を高く設定できる孔径が推奨できる。吐出量はせん断速度を高くした構造形成と引取速度に応じて所望の繊度となる最適量とするのが好ましい。本発明では、好ましい繊度が1dtexから8dtexであるから、引取速度が4000m/分であれば、単孔あたりの吐出量は0.4g/分〜3.2g/分とするのが好ましい。吐出するノズルは多数列の小さなノズルを必要個数設置しても良いし、多列の孔を有する一枚のノズルを用いてもよい。吐出された溶融線条は、冷却しつつ細化させて引取る。スパンボンド法では、アスピレーター機能をもつエジェクターで引取り、搬送ネット上に振落として繊維配列をランダムな状態に開繊積層したウエッブを形成する。   Next, melt spinning is performed by a conventional method. The spinning temperature is recommended to be 15 ° C to 40 ° C higher than the melting point of polybutylene terephthalate. A temperature higher by 25 ° C. to 35 ° C. is recommended. In discharging molten polymer from an orifice, in the present invention, a hole diameter that can set a high shear rate can be recommended. The discharge amount is preferably set to an optimum amount that achieves a desired fineness according to the structure formation with a high shear rate and the take-up rate. In the present invention, since the preferred fineness is 1 dtex to 8 dtex, when the take-up speed is 4000 m / min, the discharge rate per single hole is preferably 0.4 g / min to 3.2 g / min. As the nozzles to be ejected, a required number of small nozzles in multiple rows may be installed, or a single nozzle having multiple rows of holes may be used. The discharged molten filament is thinned while being cooled and taken off. In the spunbonding method, a web is formed by picking up with an ejector having an aspirator function, and shaking on a transport net to open and laminate the fiber arrangement in a random state.

このとき、繊維は弾性回復限界内で遅延回復して力学特性が低下する場合がある。このため、本発明では、開繊積層したウエッブの遅延回復を直ちに抑制してウエッブ形態を固定する方法を強く推奨する。具体的には、引取りネットでの挟み込み固定化する方法や、押さえローラーによる固定化方法が例示できる。振り落とす繊維量は、所望の目付けになるように引取ネット速度に応じて調整し振り落とす。振り落とし繊維本数が一定の場合では、引取ネット速度を早くしていくと、開繊された繊維は、ネットの進行方向(以下MDと略す)に配列する確率が多くなる傾向を示す。このような場合は振り落とす繊維本数を多くすることでランダムな状態を調整することが可能となり、より生産性も向上する。引取りウエッブ形成の工程では、必要な厚み調整も配慮する必要がある。   At this time, the fiber may be delayed and recovered within the elastic recovery limit, resulting in deterioration of mechanical properties. For this reason, in the present invention, a method of fixing the web form by immediately suppressing delayed recovery of the spread-laminated web is strongly recommended. Specifically, a method of pinching and fixing with a take-off net and a method of fixing with a pressing roller can be exemplified. The amount of fibers to be shaken off is adjusted according to the take-up net speed so as to obtain a desired basis weight. In the case where the number of spun fibers is constant, when the take-up net speed is increased, the opened fibers tend to be more likely to be arranged in the net traveling direction (hereinafter abbreviated as MD). In such a case, it is possible to adjust the random state by increasing the number of fibers to be shaken off, and the productivity is further improved. In the process of forming the take-up web, it is necessary to consider necessary thickness adjustment.

次いで、積層ウエッブは連続して、又は、非連続でエンボス加工を施される。エンボス形状は所望する不織布表面の必要機能に応じてドット形状、ドーナツ形状等の最適なものを選択して処理する。ただ面ファスナー性能を発現するには格子柄或いは十字柄等が好ましい。エンボス加工の温度はPBTでは180℃〜220℃、線圧は60Nf〜200Nfが適当である。   The laminated web is then embossed continuously or discontinuously. As the embossed shape, an optimum shape such as a dot shape or a donut shape is selected and processed according to the required function of the desired nonwoven fabric surface. However, a lattice pattern or a cross pattern or the like is preferable for exhibiting the surface fastener performance. The embossing temperature is suitably 180 ° C. to 220 ° C. and the linear pressure is 60 Nf to 200 Nf for PBT.

かくして得られた本発明のエンボス加工したスパンボンド不織布は、印刷加工布として提供できるが、印刷の際に、樹脂加工剤を含む着色剤を用いても良い。着色すると同時に毛羽を抑制することができるからである。   The embossed spunbond nonwoven fabric of the present invention thus obtained can be provided as a printed fabric, but a colorant containing a resin processing agent may be used during printing. It is because fluff can be suppressed simultaneously with coloring.

さらに印刷と毛羽押さえのための樹脂加工剤の付与方法としては、グラビア法、オフセットグラビア法、フレキソ印刷法で行なわれる。好ましくはオフセットグラビア法である。毛羽押さえと印刷は、ファスナー面で実施するのが毛羽押さえ効果の点で好ましい。柄は全面樹脂加工、格子柄或いはドット柄の樹脂加工であることが好ましい。   Further, as a method of applying a resin processing agent for printing and fluff pressing, a gravure method, an offset gravure method, and a flexographic printing method are performed. The offset gravure method is preferable. It is preferable in terms of the fluff holding effect that the fuzz holding and printing are performed on the fastener surface. It is preferable that the handle is a resin processing of the entire surface, a lattice pattern or a dot pattern.

ファスナー面に印刷を行なわない場合は、毛羽押さえ剤が印刷剤のアンカー剤の役割を担わせるために、印刷剤と毛羽押さえ剤は同一又は類似の樹脂を使用することが好ましく、同一であることがより好ましい。
同一系統の樹脂を使用しなければ、湿布条件での耐色落ち性が悪くなり、乳児などのズボン等への色写りが発生してしまうことがある。
毛羽押さえコーティング柄は全面、格子柄、ドット柄等が行なわれる。好ましくは全面柄である。
When printing is not performed on the zipper surface, it is preferable that the printing agent and the fluff pressing agent use the same or similar resin, since the fluff pressing agent plays the role of the anchor agent of the printing agent. Is more preferable.
If resins of the same system are not used, the color fading resistance under poultice conditions may deteriorate and color transfer to pants such as infants may occur.
The entire surface, lattice pattern, dot pattern, etc. are applied to the fluff-pressing coating pattern. Preferably, the entire pattern is used.

以下、実施例により、本発明を具体的に説明する。しかしながら、本発明はこれらによって限定されるものではない。なお、以下の実施例の評価および特性値は、以下の測定法によった。
(1)目付
JIS−L1906(2000)に準拠して測定。
(2)厚さ(mm)
JIS−L1906(2000)に準拠して測定。
(3)通気度(cc/cm2・sec)
JIS L1096 A法(フラジール形式)に準じて測定した。
(4)融点(℃)
示差走査型熱量計にて、20℃から300℃まで、20℃/分にて昇温せしめたと きの溶融により生じる吸熱現象の吸熱ピーク温度を融点とする。
(5)剥離係合力
オムツに使用されている市販の係合部材(キノコ状フック、スリーエム社製89Y 面積 5.6cm2)を5cm×25cmアクリル板の端に両面テープにて固定 する。一方、巾5cm、長さ25cmの面ファスナー雌材を、アクリル板の上に載 せる。次に用意したそれぞれの係合部材を重ねた上から2Kgのローラーを10往 復させて結合させた。
その後、テンシロン機(ORIENTEC製 型式 RTC−1250)RTを用 いて、アクリル板と面ファスナー雌材が角度180度の方向にチャック間隔10c mでつかみ、速度200mm/分で剥離させて、最大値を読み取った(測定数:n =6)。全測定値の平均を剥離強度とした。
繰り返し係合力については上記評価を繰り替えし実施した値である。
Hereinafter, the present invention will be described specifically by way of examples. However, the present invention is not limited to these. The evaluation and characteristic values of the following examples were based on the following measurement methods.
(1) Basis weight Measured according to JIS-L1906 (2000).
(2) Thickness (mm)
Measured according to JIS-L1906 (2000).
(3) Air permeability (cc / cm 2 · sec)
Measured according to JIS L1096 A method (Fragile format).
(4) Melting point (° C)
The melting point is the endothermic peak temperature of the endothermic phenomenon caused by melting when the temperature is raised from 20 ° C. to 300 ° C. at 20 ° C./min with a differential scanning calorimeter.
(5) Peeling engagement force A commercially available engagement member (mushroom-like hook, 89Y area 5.6 cm 2 manufactured by 3M) used for diapers is fixed to the end of a 5 cm × 25 cm acrylic plate with a double-sided tape. On the other hand, a hook-and-loop female material having a width of 5 cm and a length of 25 cm is placed on the acrylic plate. Next, 10 kg of a 2 kg roller was moved back and forth from each of the prepared engaging members.
Then, using a Tensilon machine (ORIENTEC model RTC-1250) RT, the acrylic plate and the hook-and-loop female material are gripped at a chuck interval of 10 cm in the direction of an angle of 180 degrees and peeled at a speed of 200 mm / min. Read (number of measurements: n = 6). The average of all measured values was defined as peel strength.
The repeated engagement force is a value obtained by repeating the above evaluation.

(6)モニター評価
作成したこれらの面ファスナー雌材を、市販の紙オムツ材(雄材がキノコ状フック、スリーエム社製89Y)のフロント部に両面テープ(ニチバン社製・ナイススタック)を用いて貼り付けたものを作成した。これらの作成したオムツについて、5名のモニターによって、面ファスナー部の剥離を行ってもらい、モニター評価を実施した。評価項目は、剥がす際の取り外しやすさ、長時間(2時間以上)使用時におけるファスナー部脱落の有無、印刷鮮明さ、毛羽立ち、柔らかさである。
なお、前記キノコ型フックの面ファスナー雄材は、以下のものである。
(スリーエム社製:縦及び横のピッチ間隔0.65mm、高さ0.3mm、フック頭部面積0.33mm2
(6) Monitor evaluation The created surface fastener female material is pasted to the front part of a commercially available paper diaper material (male material is a mushroom-like hook, 89M manufactured by 3M) using a double-sided tape (Nichiban Co., Ltd./Nice Stack). I made something with it. About these created diapers, the monitor fastener evaluation was performed by having the hook-and-loop fastener part peeled off by five monitors. The evaluation items are ease of removal at the time of peeling, presence / absence of detachment of the fastener portion when used for a long time (2 hours or more), print sharpness, fluffing, and softness.
The surface fastener male material of the mushroom type hook is as follows.
(Manufactured by 3M: vertical and horizontal pitch interval 0.65 mm, height 0.3 mm, hook head area 0.33 mm 2 )

判定は、以下の基準で行った。
取り外しやすさ: ○;外しやすい、△;やや外しにくい、×;かなり外し にくい
使用時脱落の有無: ○;取れない、△;取れることあり、×;取れやすい
印刷鮮明さ: 〇:鮮明 △:ふつう ×:鮮明でない
毛羽立ち: ○:ほとんどわからない、△:少し目立つ、×:かなり目立つ
柔らかさ:○:柔らかい、△:ふつう、×:堅い
The determination was made according to the following criteria.
Ease of removal: ○: Easy to remove, △: Slightly difficult to remove, ×: Very difficult to remove Presence of omission: ○: Unable to remove, △; Sometimes removed, ×: Easy to remove Print clarity: 〇: Clear △: Normal x: Not clear Fluff: ○: Almost unknown, △: Slightly noticeable, x: Slightly noticeable Softness: ○: Soft, △: Normal, x: Hard

(7)耐色写り性
LIS0801 湿布 100回
1〜3級:× 4級:△ 5級:○
(7) Color fastness LIS0801 Wet pack 100 times 1st to 3rd class: × 4th class: △ 5th class: ○

(実施例1)
テレフタル酸(以下TPAと略す)100部、エチレングリコ−ル(以下EGと略す)40部、ネオペンチルグリコール(以下NPGと略す)15部を少量の触媒と仕込み、常法にてエステル交換−重合後ペレタイズして、融点178℃、固有粘度0.780の芳香族共重合ポリエステルA(以下COPES−Aと略す)を得た。
TPA100部、1・4ブタンジオール(以下BGと略す)70部を少量の触媒と仕込み、常法にてエステル交換−重合後ペレタイズして、融点230℃、固有粘度1.205のPBT−Aを得た。
Example 1
100 parts of terephthalic acid (hereinafter abbreviated as TPA), 40 parts of ethylene glycol (hereinafter abbreviated as EG) and 15 parts of neopentyl glycol (hereinafter abbreviated as NPG) were charged with a small amount of catalyst, and transesterification and polymerization were conducted in a conventional manner. After pelletization, an aromatic copolymer polyester A (hereinafter abbreviated as COPES-A) having a melting point of 178 ° C. and an intrinsic viscosity of 0.780 was obtained.
100 parts of TPA, 70 parts of 1,4 butanediol (hereinafter abbreviated as BG) are charged with a small amount of catalyst, and transesterification is carried out by a conventional method. After polymerization, PBT-A having a melting point of 230 ° C. and an intrinsic viscosity of 1.205 is obtained. Obtained.

COPES−A7部、PBT−A93部をロータリー式真空乾燥機に投入して、混合乾燥(水分率0.002重量%まで乾燥)し、紡糸に供した。紡糸温度260℃にて、オリフィス径φ0.18mmのノズルより、単孔吐出量0.7g/分で紡糸し、ノズル下50mmより20℃の空気を風速0.5m/秒にて冷却しつつ、ノズル下0.8mの点に設置したエジェクターで糸速4100m/分の速度で吸引させつつ引取り、ノズル下1.5m点で、50m/分の速度で移動している引取ネット面へ繊維束を開繊させつつ振り落とし積層した。ネット面に積層されたウエッブは直ちに仮押さえローラーでプレ圧縮して引取ローラーに巻き取った。次いで、巻き取った不織布を7mmピッチ面積率23%の十字柄エンボスローラーにて、200℃で線圧9.8Nfにてエンボス加工したスパンボンド不織布を得た。   7 parts of COPES-A and 93 parts of PBT-A were put into a rotary vacuum dryer, mixed and dried (dried to a moisture content of 0.002% by weight), and subjected to spinning. Spinning at a spinning temperature of 260 ° C. from a nozzle with an orifice diameter of 0.18 mm, spinning at a single hole discharge rate of 0.7 g / min, and cooling air at 20 ° C. from 50 mm below the nozzle at a wind speed of 0.5 m / sec. The fiber bundle is pulled to the take-up net surface moving at a speed of 50 m / min at a point 1.5 m below the nozzle with an ejector installed at a point 0.8 m below the nozzle while sucking at a yarn speed of 4100 m / min. The film was sprinkled and laminated while the fiber was opened. The web laminated on the net surface was immediately pre-compressed with a temporary pressing roller and wound around a take-up roller. Next, a spunbond nonwoven fabric obtained by embossing the wound nonwoven fabric with a 7 mm pitch area ratio 23% cross pattern embossing roller at 200 ° C. and a linear pressure of 9.8 Nf was obtained.

さらに印刷用の透明ウレタン樹脂をループ面に2cmピッチの格子柄で目付2g/m2コ−トして、さらにウレタン樹脂をバインダーとして含有する顔料によってループを有しない不織布面(裏面)に、オフセットグラビア印刷法によって3色刷りを実施して面ファスナー雌材を得た。得られた面ファスナー雌材の評価結果を表1に示す。 Furthermore, a transparent urethane resin for printing is coated on the loop surface with a grid pattern of 2 cm pitch with a basis weight of 2 g / m 2 , and further offset by a pigment containing urethane resin as a binder on the non-woven fabric surface (back surface). A three-color printing was carried out by a gravure printing method to obtain a female female fastener. Table 1 shows the evaluation results of the obtained surface fastener female material.

(実施例2)
COPES−Aを5部、PBTを95部用いた以外は実施例1と同様にしてスパンボンド不織布を得た。表面コーティング及び印刷も実施例1と同様にして面ファスナー雌材を得た。得られた面ファスナー雌材の評価結果を表1に示す。
(Example 2)
A spunbonded nonwoven fabric was obtained in the same manner as in Example 1 except that 5 parts of COPES-A and 95 parts of PBT were used. A surface fastener female material was obtained in the same manner as in Example 1 for surface coating and printing. Table 1 shows the evaluation results of the obtained surface fastener female material.

(実施例3)
COPES−Aを15部、PBTを85部用いた以外は実施例1と同様にしてスパンボンド不織布を得た。表面コーティング及び印刷も実施例1と同様にして面ファスナー雌材を得た。得られた面ファスナー雌材の評価結果を表1に示す。
Example 3
A spunbonded nonwoven fabric was obtained in the same manner as in Example 1 except that 15 parts of COPES-A and 85 parts of PBT were used. A surface fastener female material was obtained in the same manner as in Example 1 for surface coating and printing. Table 1 shows the evaluation results of the obtained surface fastener female material.

(実施例4)
TPA100部、トリメチレングリコール(以下TGと略す)60部を少量の触媒と仕込み、常法にてエステル交換後、重合してペレット化し、融点221℃、固有粘度1.310のPTT−Aを得た。
PTT−Aを95部、COPES−Aを5部用いた以外、実施例1と同様にしてスパ ンボンド不織布を得た。
表面コーティング及び印刷も実施例1と同様にして面ファスナー雌材を得た。得られた面ファスナー雌材の評価結果を表1に示す。
Example 4
100 parts of TPA and 60 parts of trimethylene glycol (hereinafter abbreviated as TG) are charged with a small amount of catalyst, transesterified by a conventional method, polymerized and pelletized to obtain PTT-A having a melting point of 221 ° C. and an intrinsic viscosity of 1.310. It was.
A span bond nonwoven fabric was obtained in the same manner as in Example 1 except that 95 parts of PTT-A and 5 parts of COPES-A were used.
A surface fastener female material was obtained in the same manner as in Example 1 for surface coating and printing. Table 1 shows the evaluation results of the obtained surface fastener female material.

(実施例5)
COPES−Aを5部、PBNを95部用いた以外は実施例1と同様にしてスパンボンド不織布を得た。
表面コーティング及び印刷も実施例1と同様にして面ファスナー雌材を得た。得られた面ファスナー雌材の評価結果を表1に示す。
(Example 5)
A spunbonded nonwoven fabric was obtained in the same manner as in Example 1 except that 5 parts of COPES-A and 95 parts of PBN were used.
A surface fastener female material was obtained in the same manner as in Example 1 for surface coating and printing. Table 1 shows the evaluation results of the obtained surface fastener female material.

(比較例1)
PBTを100部用いた以外は実施例1と同様にしてスパンボンド不織布を得た。表面コーティング及び印刷も実施例1と同様にして面ファスナー雌材を得た。得られた面ファスナー雌材の評価結果を表1に示す。
(Comparative Example 1)
A spunbonded nonwoven fabric was obtained in the same manner as in Example 1 except that 100 parts of PBT was used. A surface fastener female material was obtained in the same manner as in Example 1 for surface coating and printing. Table 1 shows the evaluation results of the obtained surface fastener female material.

(比較例2)
PBTを100部用いた以外は実施例1と同様にしてスパンボンド不織布を得た。
表面コーティングを実施せずに印刷のみ実施例1と同様の方法で実施して面ファスナー雌材を得た。得られた面ファスナー雌材の評価結果を表1に示す。
(Comparative Example 2)
A spunbonded nonwoven fabric was obtained in the same manner as in Example 1 except that 100 parts of PBT was used.
A surface fastener female material was obtained by carrying out printing only in the same manner as in Example 1 without performing surface coating. Table 1 shows the evaluation results of the obtained surface fastener female material.

(比較例3)
ポリエチレンテレフタテートを溶融紡糸し、フィラメントをネット上にランダム捕集した後、フラットローラで軽く圧着して表1に示した太さ、目付のスパンボンド不織布シートを製造した。次いで、得られた不織布シートをニードルパンチマシンに導入し、該不織布の上からニードルを挿入してニードルパンチすることにより、多数のスパンボンドの繊維によるループを形成させた。
次いで、該ループを有する不織布面に、ポリアクリル酸エステル系エマルジョン樹脂をオフセットグラビア印刷法による表面コーティングで該樹脂の含有量が面ファスナー雌材全重量に対して9重量%になるように全面に樹脂加工し、さらに該コーティング面に前記と同一のポリアクリル酸エステル系エマルジョン樹脂をバインダーとして含有する顔料で3色刷りの印刷を実施して面ファスナー雌材を得た。得られた面ファスナー雌材の評価結果を表1に示す。
(Comparative Example 3)
Polyethylene terephthalate was melt spun, filaments were randomly collected on a net, and lightly pressed with a flat roller to produce a spunbond nonwoven fabric sheet with the thickness and basis weight shown in Table 1. Subsequently, the obtained nonwoven fabric sheet was introduced into a needle punch machine, needles were inserted from above the nonwoven fabric, and needle punching was performed to form loops of a large number of spunbond fibers.
Next, on the non-woven fabric surface having the loop, a polyacrylic ester emulsion resin is coated on the entire surface by surface coating by an offset gravure printing method so that the content of the resin is 9% by weight with respect to the total weight of the surface fastener female material. The resin was processed, and further, three-color printing was performed on the coating surface with a pigment containing the same polyacrylate emulsion resin as a binder as described above to obtain a female hook-and-loop material. Table 1 shows the evaluation results of the obtained surface fastener female material.

(比較例4)
ポリエチレンテレフタレート(融点255℃)を芯成分、ポリエチレン(融点130℃)を鞘成分とする芯鞘型複合繊維で、単繊維繊度が6.7dtexと2.0dtexの複合繊維を用い、前者を60%、後者を40%で充分に混綿した目付40g/m2のカードウェブを作製した。このカードウェブを基材である目付重量15g/m2のポリプロピレン製スパンボンド不織布−ポリプロピレン製メルトブロー不織布−ポリプロピレン製スパンボンド不織布貼り合せ基材に積層した。
(Comparative Example 4)
A core-sheath type composite fiber having polyethylene terephthalate (melting point 255 ° C.) as a core component and polyethylene (melting point 130 ° C.) as a sheath component, and using a composite fiber having single fiber fineness of 6.7 dtex and 2.0 dtex, the former being 60% A card web having a basis weight of 40 g / m 2 was prepared by fully blending the latter with 40%. This card web was laminated on a base material having a basis weight of 15 g / m 2, a polypropylene spunbond nonwoven fabric-a polypropylene melt blown nonwoven fabric-a polypropylene spunbond nonwoven fabric bonded base material.

積層した後、熱エンボス法で熱圧着させた。用いたエンボスロールは直径が5mmで、深さが2mmの円形孔が5.5mm間隔で一列に並び、その円形孔列に対して次の円形孔列が千鳥状に並ぶように配列されたもので、対ローラーとしてフラットローラーを用いた。処理のエンボス圧力は45Kg/cm、エンボス温度は155℃であった。エンボス領域の面積率は76.3%であった。得られた面ファスナー雌材の評価結果を表1に示す。

Figure 2006034872
After the lamination, thermocompression bonding was performed by a hot embossing method. The embossing roll used has a diameter of 5 mm, a depth of 2 mm, and circular holes arranged in a row at intervals of 5.5 mm, and the next circular hole row is arranged in a staggered manner with respect to the circular hole row. Then, a flat roller was used as a counter roller. The embossing pressure for the treatment was 45 kg / cm, and the embossing temperature was 155 ° C. The area ratio of the embossed region was 76.3%. Table 1 shows the evaluation results of the obtained surface fastener female material.
Figure 2006034872

表1から明らかなように、本願発明の構成要件を満たす面ファスナー雌材は、面ファスナーとして市場の要望が強い特性である、剥離係合力、通気性、耐色写り性、取り外しやすさ、脱落の有無、印刷の鮮明さ、毛羽立ち、柔らかさを全てかね添えたものとなった。   As is apparent from Table 1, the female material for the surface fastener that satisfies the constituent requirements of the present invention is a characteristic that has a strong market demand as a surface fastener, such as peeling engagement force, air permeability, color fastness, ease of removal, and dropout. The presence, absence of printing, sharpness of printing, fluff and softness were all added.

本発明の面ファスナー雌材は、雄材を剥離後の毛羽立ちが少なく、鮮明な色の印刷を行うことができ、更には剥がし易く、風合いも柔らかく、剥離音が静かであり、紙おむつや衛材等の幅広い用途分野に利用することができ、産業界の寄与することが大である。   The surface fastener female material of the present invention has less fuzz after peeling off the male material, can be printed in a clear color, is easy to peel off, has a soft texture, and has a quiet peeling sound, such as a paper diaper or sanitary material. It can be used in a wide range of application fields, and the industry contributes greatly.

本発明面ファスナーエンボス柄の一例である。It is an example of this invention surface fastener embossing pattern.

Claims (5)

芳香族ポリエステル(融点:Tm1)に対し、芳香族共重合ポリエステル(融点:Tm2≦Tm1−30℃)を1〜20重量%含有した繊度1.1〜11dtexの連続繊維からなる目付が20〜80g/m2の不織布であって、当該不織布の表面を面積率が10〜60%のエンボス加工によって熱接着加工されていることを特徴とする面ファスナー雌材。 A basis weight of 20 to 80 g composed of continuous fibers having a fineness of 1.1 to 11 dtex containing 1 to 20% by weight of an aromatic copolymer polyester (melting point: Tm2 ≦ Tm1-30 ° C.) with respect to the aromatic polyester (melting point: Tm1). / m a second nonwoven, surface fastener Mesuzai, characterized in that the surface area ratio of the nonwoven fabric are thermally bonded processed by 10% to 60% of the embossing. 芳香族ポリエステルがポリブチレンテレフタレート(以下PBT)、及び/又はポリトリメチレンテレフタレート(以下PTT)であることを特徴とする請求項1記載の面ファスナー雌材。 The surface fastener female material according to claim 1, wherein the aromatic polyester is polybutylene terephthalate (hereinafter referred to as PBT) and / or polytrimethylene terephthalate (hereinafter referred to as PTT). 不織布の表面に樹脂加工剤を含む着色剤を印刷することを特徴とする請求項1又は2記載の面ファスナー雌材 3. A surface fastener female material according to claim 1, wherein a colorant containing a resin processing agent is printed on the surface of the nonwoven fabric. 樹脂加工がグラビア、オフセットグラビア及びフレキソ法のいずれかであることを特徴とする請求項3記載の面ファスナー雌材の製造方法。 4. The method for producing a female material for a hook-and-loop fastener according to claim 3, wherein the resin processing is any one of gravure, offset gravure and flexographic methods. 樹脂加工により形成される柄が全面、ドット、格子柄のいずれかであることを特徴する請求項4記載の面ファスナー雌材の製造方法。 The method for manufacturing a female material for a hook-and-loop fastener according to claim 4, wherein the pattern formed by resin processing is any one of the entire surface, dots, and lattice patterns.
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