JP2006007511A - Manufacturing method of foamed sheet made of propylene resin - Google Patents

Manufacturing method of foamed sheet made of propylene resin Download PDF

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JP2006007511A
JP2006007511A JP2004186031A JP2004186031A JP2006007511A JP 2006007511 A JP2006007511 A JP 2006007511A JP 2004186031 A JP2004186031 A JP 2004186031A JP 2004186031 A JP2004186031 A JP 2004186031A JP 2006007511 A JP2006007511 A JP 2006007511A
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propylene
wall surface
sheet
based resin
outer cylinder
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Akinobu Sakamoto
昭宣 坂本
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Sumika Plastech Co Ltd
Sumitomo Chemical Co Ltd
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Sumika Plastech Co Ltd
Sumitomo Chemical Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34Auxiliary operations
    • B29C44/3403Foaming under special conditions, e.g. in sub-atmospheric pressure, in or on a liquid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34Auxiliary operations
    • B29C44/36Feeding the material to be shaped
    • B29C44/46Feeding the material to be shaped into an open space or onto moving surfaces, i.e. to make articles of indefinite length
    • B29C44/50Feeding the material to be shaped into an open space or onto moving surfaces, i.e. to make articles of indefinite length using pressure difference, e.g. by extrusion or by spraying
    • B29C44/507Feeding the material to be shaped into an open space or onto moving surfaces, i.e. to make articles of indefinite length using pressure difference, e.g. by extrusion or by spraying extruding the compound through an annular die
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/10Polymers of propylene
    • B29K2023/12PP, i.e. polypropylene

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  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Molding Of Porous Articles (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a manufacturing method of a foamed sheet made of a propylene resin having a smooth surface. <P>SOLUTION: A molten foamed sheet made of the propylene resin, which is obtained by melting and kneading the propylene resin and a foaming agent in an extruder and extruding the molten kneaded mixture into the atmosphere from a circular die, is passed through an inner cylindrical part and an outer cylindrical part to be brought into contact with the outer wall surface of the inner cylindrical part and the inner wall surface of the outer cylindrical part to manufacture the foamed sheet made of the propylene resin. A plurality of holes are provided to the inner wall surface of the outer cylindrical part and the space between the molten foamed sheet made of the propylene resin and the outer cylindrical part is depressurized through the holes to bring the molten foamed sheet made of the propylene resin into contact with the inner wall surface of the outer cylindrical part. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明はプロピレン系樹脂製発泡シートの製造方法に関する。   The present invention relates to a method for producing a propylene-based resin foam sheet.

プロピレン系樹脂からなる発泡シートは、断熱性や軽量性、耐熱性、リサイクル性に優れることから、食品包装容器や自動車部材等幅広い分野で使用されている。特にサーキュラーダイを用いてプロピレン系樹脂製発泡シートを製造する場合、ダイから押し出した溶融状の発泡シートを円筒状の内筒部と接触させて冷却することにより製造する方法が一般的である。この方法によれば、得られる発泡シートの内筒部と接触するシート面は平滑化されるが、内筒部と接触しないシート面は大気中で自然冷却されるため、内筒部との接触面に比べて平滑性に劣ることが多かった。
表面が平滑な発泡シートを得る方法として、表面温度が70℃〜160℃の発泡シート表面に、冷却水により温度調整された外マンドレルをあてる方法が知られている(例えば特許文献1参照)。
Foamed sheets made of propylene-based resins are excellent in heat insulation, light weight, heat resistance, and recyclability, and are therefore used in a wide range of fields such as food packaging containers and automobile members. In particular, when a propylene-based resin foam sheet is manufactured using a circular die, a method of manufacturing the melted foam sheet extruded from the die by bringing it into contact with the cylindrical inner cylinder portion and cooling is common. According to this method, the sheet surface in contact with the inner cylinder portion of the obtained foamed sheet is smoothed, but the sheet surface not in contact with the inner cylinder portion is naturally cooled in the atmosphere, so that it contacts with the inner cylinder portion. The smoothness was often inferior to the surface.
As a method for obtaining a foam sheet having a smooth surface, a method is known in which an outer mandrel whose temperature is adjusted by cooling water is applied to the surface of a foam sheet having a surface temperature of 70 ° C. to 160 ° C. (see, for example, Patent Document 1).

特開2001−328155号公報JP 2001-328155 A

しかしながら上記の方法では、外マンドレルと発泡シートとを均一に接触させることが困難であるため、外マンドレルをあてずに得られる発泡シートよりは表面が平滑ではあるものの、未だその平滑性は不十分であった。
本発明の目的は、表面が平滑なプロピレン系樹脂製発泡シートの製造方法を提供することにある。
However, in the above method, since it is difficult to make the outer mandrel and the foamed sheet contact uniformly, the surface is smoother than the foamed sheet obtained without applying the outer mandrel, but the smoothness is still insufficient. Met.
An object of the present invention is to provide a method for producing a propylene-based resin foam sheet having a smooth surface.

すなわち本発明は、プロピレン系樹脂および発泡剤を押出機にて溶融混練した後サーキュラーダイから大気圧中に押出して得られる溶融状プロピレン系樹脂製発泡シートを、円筒状の内筒部と外筒部の間を通して内筒部の外壁面および外筒部の内壁面と接触させてプロピレン系樹脂製発泡シートを製造する方法であって、外筒部内壁面には複数の孔が設けられており、該孔を通じて溶融状プロピレン系樹脂製発泡シートと外筒部との間を減圧することにより溶融状プロピレン系樹脂製発泡シートを外筒部内壁面に接触させるプロピレン系樹脂製発泡シートの製造方法を提供するものである。   That is, the present invention relates to a molten propylene-based resin foam sheet obtained by melt-kneading a propylene-based resin and a foaming agent with an extruder and then extruding the same from a circular die to atmospheric pressure. Is a method of producing a propylene-based resin foam sheet by contacting the outer wall surface of the inner cylinder part and the inner wall surface of the outer cylinder part through between the parts, the inner wall surface of the outer cylinder part is provided with a plurality of holes, Providing a method for producing a propylene-based resin foam sheet in which the molten propylene-based resin foam sheet is brought into contact with the inner wall surface of the outer cylinder portion by reducing the pressure between the molten propylene-based resin foam sheet and the outer cylinder portion through the holes. To do.

本発明の製造方法により、表面が平滑なプロピレン系樹脂製発泡シートを製造することができる。   By the production method of the present invention, a propylene-based resin foam sheet having a smooth surface can be produced.

以下、本発明を詳細に説明する。 Hereinafter, the present invention will be described in detail.

プロピレン系樹脂としては、公知のホモポリプロピレン、ブロックポリプロピレン、ランダムポリプロピレン等のプロピレン系樹脂を使用することができる。発泡性の観点から、190℃におけるメルトテンション(MT(190))と230℃におけるメルトフローレート(MFR(230))とが下式1を満足するプロピレン系重合体を含むものが好ましい。
MT(190)≧7.52×MFR(230)(-0.576) [式1]
As the propylene-based resin, known propylene-based resins such as homopolypropylene, block polypropylene, and random polypropylene can be used. From the viewpoint of foaming properties, it is preferable to include a propylene polymer in which the melt tension at 190 ° C. (MT (190)) and the melt flow rate at 230 ° C. (MFR (230)) satisfy the following formula 1.
MT (190) ≧ 7.52 × MFR (230) (−0.576) [Formula 1]

式1を満たすプロピレン系重合体としては、高分子量成分を含有する直鎖状重合体や分岐状重合体が挙げられる。
直鎖状重合体としては、例えば特開平11−228629号公報に開示された、超高分子量成分を導入したプロピレン系重合体(T)、すなわち、極限粘度が5dl/g以上の結晶性プロピレン系重合体部分(A)を製造する工程および極限粘度が3dl/g未満の結晶性プロピレン系重合体部分(B)を製造する工程を含む重合方法により得られ、極限粘度が3dl/g未満であり、結晶性プロピレン系重合体部分(A)の割合が0.05重量%以上35重量%未満であるプロピレン系重合体(T)が挙げられる。
また、分岐状重合体としては、特開昭62−121704号公報に開示された、通常の直鎖状重合体に電子線が照射されたものなどが挙げられ、株式会社サンアロマよりPF814、SD632等として上市されている。
Examples of the propylene polymer satisfying Formula 1 include linear polymers and branched polymers containing a high molecular weight component.
As the linear polymer, for example, a propylene polymer (T) introduced with an ultrahigh molecular weight component disclosed in JP-A-11-228629, that is, a crystalline propylene polymer having an intrinsic viscosity of 5 dl / g or more. Obtained by a polymerization method comprising a step of producing a polymer part (A) and a step of producing a crystalline propylene polymer part (B) having an intrinsic viscosity of less than 3 dl / g, and the intrinsic viscosity is less than 3 dl / g And a propylene polymer (T) in which the proportion of the crystalline propylene polymer portion (A) is 0.05% by weight or more and less than 35% by weight.
Examples of the branched polymer include those obtained by irradiating an ordinary linear polymer with an electron beam as disclosed in JP-A No. 62-121704. PF814, SD632 from Sun Aroma Co., Ltd. Etc.

230℃におけるメルトフローレート(MFR(230))とは、JIS K7210に従って、温度230℃、荷重2.16kgfで測定される値である(単位 g/10分)。190℃におけるメルトテンション(MT(190))とは、市販のメルトテンションテスターを用いて、サンプル量5g、加熱温度190℃、加熱時間5分間、押出速度5.7mm/分で、長さ8mm、直径2mmのオリフィスからストランドを押し出し、該ストランドを直径50mmのローラーを用いて巻取速度100rpmで巻き取ったときの張力である(単位 g)。 The melt flow rate at 230 ° C. (MFR (230)) is a value measured in accordance with JIS K7210 at a temperature of 230 ° C. and a load of 2.16 kgf (unit: g / 10 minutes). Melt tension at 190 ° C. (MT (190)) means a sample amount of 5 g, a heating temperature of 190 ° C., a heating time of 5 minutes, an extrusion speed of 5.7 mm / min, a length of 8 mm, using a commercially available melt tension tester. This is the tension when a strand is extruded from an orifice having a diameter of 2 mm and the strand is wound at a winding speed of 100 rpm using a roller having a diameter of 50 mm (unit: g).

プロピレン系樹脂は、全プロピレン系樹脂中に式1を満たすプロピレン系重合体を通常10%以上含むことが好ましく、他に式1を満たさない公知のホモポリプロピレン、ブロックポリプロピレン、ランダムポリプロピレンを含んでいてもよい。式1を満たすプロピレン系重合体を含むプロピレン系樹脂は、破泡しにくく発泡性に優れたものである。またプロピレン系樹脂は、発泡性を損なわない程度にエチレン系樹脂やその他のオレフィン系樹脂を含んでいてもよい。 The propylene resin preferably contains 10% or more of a propylene polymer satisfying the formula 1 in all propylene resins, and includes other known homopolypropylene, block polypropylene, and random polypropylene that do not satisfy the formula 1. Also good. A propylene-based resin containing a propylene-based polymer that satisfies Formula 1 is less foamed and excellent in foamability. The propylene-based resin may contain an ethylene-based resin and other olefin-based resins to the extent that foamability is not impaired.

本発明で用いられる発泡剤は特に限定されるものではなく、公知の発泡剤を用いることができる。例えば物理発泡剤としては、炭酸ガス、窒素ガス、空気、プロパン、ブタン、ペンタン、ヘキサン、ジクロルエタン、ジクロロジフルオロメタン、ジクロロモノフルオロメタン、トリクロロモノフルオロメタンを挙げることができ、窒素ガス、炭酸ガス、空気等の安全で環境にやさしい無機ガスを用いることが好ましく、プロピレン系樹脂への溶解性が高いことから、炭酸ガスを用いることがより好ましい。炭酸ガスを用いる場合は、7.4MPa以上、31℃以上の超臨界状態でプロピレン系樹脂に混合することが、樹脂への拡散、溶解性の観点から好ましい。 The foaming agent used by this invention is not specifically limited, A well-known foaming agent can be used. Examples of physical foaming agents include carbon dioxide gas, nitrogen gas, air, propane, butane, pentane, hexane, dichloroethane, dichlorodifluoromethane, dichloromonofluoromethane, and trichloromonofluoromethane, such as nitrogen gas, carbon dioxide gas, It is preferable to use a safe and environmentally friendly inorganic gas such as air, and it is more preferable to use carbon dioxide gas because of its high solubility in a propylene-based resin. When using carbon dioxide gas, it is preferable to mix with a propylene-based resin in a supercritical state of 7.4 MPa or more and 31 ° C. or more from the viewpoint of diffusion into the resin and solubility.

本発明で用いられる化学発泡剤の例としては、重曹、重曹とクエン酸、クエン酸ナトリウム、ステアリン酸などの有機酸との混合物、アゾジカルボンアミド、トリレンジイソシアネート、4,4’ジフェニルメタンジイソシアネートなどのイソシアネート化合物、アゾビスブチロニトリル、バリウム・アゾジカルボキシレート、ジアゾアミノベンゼン、トリヒドラジノトリアジンなどのアゾ、ジアゾ化合物、ベンゼン・スルホニル・ヒドラジド、P,P’−オキシビス(ベンゼンスルホニル・ヒドラジド)、トルエン・スルホニル・ヒドラジドなどのヒドラジン誘導体、N,N’−ジニトロソ・ペンタメチレン・テトラミン、N,N’−ジメチル−N,N’−ジニトロソ・テレフタルアミドなどのニトロソ化合物、P−トルエン・スルホニル・セミカルバジド、4,4’オキシビスベンゼンスルホニルセミカルバジドなどのセミカルバジド化合物の他アジ化合物やトリアゾール化合物を挙げることができる。特に、重曹、クエン酸、アゾジカルボンアミドが好ましい。 Examples of chemical blowing agents used in the present invention include sodium bicarbonate, a mixture of sodium bicarbonate and an organic acid such as citric acid, sodium citrate, stearic acid, azodicarbonamide, tolylene diisocyanate, 4,4′diphenylmethane diisocyanate, etc. Isocyanate compounds, azobisbutyronitrile, barium azodicarboxylate, azo such as diazoaminobenzene, trihydrazinotriazine, diazo compounds, benzene sulfonyl hydrazide, P, P'-oxybis (benzenesulfonyl hydrazide), Hydrazine derivatives such as toluene sulfonyl hydrazide, nitroso compounds such as N, N′-dinitroso pentamethylene tetramine, N, N′-dimethyl-N, N′-dinitroso terephthalamide, P-toluene sulfonyl Semicarbazide, can be given other azide compound or a triazole compound of semicarbazide compounds such as 4,4 'oxybisbenzenesulfonyl semicarbazide. In particular, sodium bicarbonate, citric acid, and azodicarbonamide are preferable.

上記の物理発泡剤や化学発泡剤は単体で使用してもよく、2種類以上を併用してもよい。また、化学発泡剤を用いる場合には、その分解温度や分解速度を調整するために発泡助剤を併用してもよい。例えば、アゾジカルボンアミド単体では分解温度が約200℃と高いため、低温で加工したい場合には発泡助剤として酸化亜鉛、ステアリン酸亜鉛、尿素などを少量添加してもよい。 The above physical foaming agent and chemical foaming agent may be used alone or in combination of two or more. When a chemical foaming agent is used, a foaming aid may be used in combination in order to adjust the decomposition temperature and decomposition rate. For example, since the decomposition temperature of azodicarbonamide alone is as high as about 200 ° C., a small amount of zinc oxide, zinc stearate, urea or the like may be added as a foaming aid when processing at a low temperature is desired.

物理発泡剤を用いる場合には、気泡核剤を添加することできる。気泡核剤としては、タルク、シリカ、珪藻土、炭酸カルシウム、炭酸マグネシウム、硫酸バリウム、水酸化アルミニウム、水酸化マグネシウム、水酸化カルシウム、ケイ酸カルシウム、ゼオライト、マイカ、クレー、ワラストナイト、ハイドロタルサイト、酸化マグネシウム、酸化亜鉛、ステアリン酸亜鉛、ステアリン酸カルシウム、PMMA等のポリマービーズ、合成アルミノシリケートや上記の化学発泡剤が例示される。 When a physical foaming agent is used, a cell nucleating agent can be added. Bubble nucleating agents include talc, silica, diatomaceous earth, calcium carbonate, magnesium carbonate, barium sulfate, aluminum hydroxide, magnesium hydroxide, calcium hydroxide, calcium silicate, zeolite, mica, clay, wollastonite, hydrotalcite Examples thereof include polymer beads such as magnesium oxide, zinc oxide, zinc stearate, calcium stearate, PMMA, synthetic aluminosilicate, and the above chemical foaming agents.

プロピレン系樹脂に対する発泡剤の添加量は、所望の発泡倍率に応じて適宜設定される。物理発泡剤として炭酸ガスを用いる場合、その添加量は一般に0.1〜4PHRであり、例えば発泡倍率3倍の発泡シートを製造する場合には0.3PHR、発泡倍率5倍の場合には0.6PHR程度である。 The amount of the foaming agent added to the propylene-based resin is appropriately set according to the desired expansion ratio. When carbon dioxide is used as the physical foaming agent, the amount added is generally 0.1 to 4 PHR. For example, 0.3 PHR is used when producing a foam sheet with a foaming ratio of 3 times, and 0 when foaming ratio is 5 times. About 6 PHR.

押出機としては、単軸や多軸の通常の押出成形に用いられる押出機を使用することができ、複数の押出機を組み合わせたタンデム押出機も使用可能である。特に同方向回転2軸押出機が好ましく、スクリュー1回転あたりの押出量が多くて所定の押出量を低回転で得ることができ、スクリュー回転によるせん断発熱の少ない構造の押出機であることがより好ましく、スクリュー本体に冷却媒体を循環させて温調可能な押出機であることがさらに好ましい。 As the extruder, an extruder used for single-screw or multi-screw ordinary extrusion molding can be used, and a tandem extruder combining a plurality of extruders can also be used. In particular, a twin-screw extruder rotating in the same direction is preferable, and an extruder having a structure in which the amount of extrusion per screw rotation is large and a predetermined extrusion amount can be obtained at a low rotation and the shear heat generation due to screw rotation is small. More preferably, the extruder is capable of adjusting the temperature by circulating a cooling medium in the screw body.

押出機とサーキュラーダイとの間にギヤポンプを設け、原料供給用に定量フィーダーを設けて、スクリューまたはギアポンプの回転数や原料供給量へフィードバックしてギアポンプ入口圧力を一定に制御するシステムも押出発泡状態の安定化に有効である。
また、押出機とサーキュラーダイとをつなぐアダプタには、スタティックミキサーなどを挿入して樹脂温度均一化をはかるのも発泡状態の安定化に有効である。
A gear pump is installed between the extruder and the circular die, a metering feeder is installed to supply the raw material, and the system that controls the gear pump inlet pressure constant by feeding back to the rotational speed of the screw or gear pump and the raw material supply amount is also in the extruded foam state It is effective for stabilization.
In addition, it is also effective for stabilizing the foamed state that a static mixer or the like is inserted into the adapter connecting the extruder and the circular die to equalize the resin temperature.

物理発泡剤を用いる場合、押出機は溶融した樹脂中に発泡剤を圧入できる構造であるが、圧入位置以前には樹脂原料を十分に溶融可塑化させ、圧入以降は樹脂と発泡剤を十分に混合均一化させ、発泡に適切な樹脂温度に制御できることが必要である。 When a physical foaming agent is used, the extruder has a structure that allows the foaming agent to be pressed into the molten resin, but the resin raw material is sufficiently melt-plasticized before the press-fitting position, and after the press-fitting, the resin and the foaming agent are sufficiently injected. It is necessary to be able to mix and homogenize and control the resin temperature suitable for foaming.

サーキュラーダイとしては、通常の押出成形に用いられるダイを使用することができ、円周方向の厚み分布を均一にするため、円周方向におけるリップ開度やダイ温度を調整できる構造が好ましい。また、通常、リップの口径は50mm〜500mmであり、リップ開度は0.3mm〜3mmである。 As the circular die, a die used for normal extrusion molding can be used, and a structure capable of adjusting the lip opening degree and the die temperature in the circumferential direction is preferable in order to make the thickness distribution in the circumferential direction uniform. In general, the lip diameter is 50 mm to 500 mm, and the lip opening is 0.3 mm to 3 mm.

本発明の製造方法では、サーキュラーダイから大気圧中に押し出された筒状の溶融状プロピレン系樹脂製発泡シートを、円筒状の内筒部と外筒部の間を通して内筒部の外壁面および外筒部の内壁面と接触させる。内筒部の外壁面とは、外筒部と対向する壁面であり、外筒部の内壁面とは、内筒部と対向する壁面である。溶融状プロピレン系樹脂製発泡シートは、内筒部の外壁面および外筒部の内壁面に接触することで冷却され、プロピレン系樹脂製発泡シートが得られる。 In the production method of the present invention, the cylindrical molten propylene-based resin foam sheet extruded from the circular die into the atmospheric pressure is passed between the cylindrical inner cylinder part and the outer cylinder part, and the outer wall surface of the inner cylinder part and It is made to contact with the inner wall surface of an outer cylinder part. The outer wall surface of the inner tube portion is a wall surface facing the outer tube portion, and the inner wall surface of the outer tube portion is a wall surface facing the inner tube portion. The molten propylene-based resin foam sheet is cooled by contacting the outer wall surface of the inner cylinder portion and the inner wall surface of the outer cylinder portion, and a propylene-based resin foam sheet is obtained.

内筒部は、その外壁面がサーキュラーダイより押し出された溶融状プロピレン系樹脂製発泡シートの内面と均一に接触するように設置される。内筒部の外径はサーキュラーダイのリップ口径に対して通常1.5倍〜5倍であり、内筒部の押出方向の長さは通常300mm〜1500mmである。内筒部の素材には熱伝導率の高いアルミニウムやステンレス鋼などを用いることが好ましく、シートと接触する面にはテフロン(登録商標)処理などを施し、滑りやすくすることが好ましい。また内筒部に冷却水を循環させ、円周方向の温度が均一になるようにすることが好ましい。 The inner cylinder portion is installed so that the outer wall surface thereof is in uniform contact with the inner surface of the molten propylene-based resin foam sheet extruded from the circular die. The outer diameter of the inner cylinder part is usually 1.5 to 5 times the lip diameter of the circular die, and the length of the inner cylinder part in the extrusion direction is usually 300 mm to 1500 mm. It is preferable to use aluminum, stainless steel, or the like having high thermal conductivity as the material for the inner cylinder portion, and it is preferable to make the surface in contact with the sheet a Teflon (registered trademark) treatment to make it slippery. Moreover, it is preferable to circulate cooling water through the inner cylinder portion so that the temperature in the circumferential direction becomes uniform.

外筒部は、内筒部の外壁面と外筒部の内壁面とが対向し、かつ外筒部の内壁面がサーキュラーダイより押し出された溶融状プロピレン系樹脂製発泡シートの外面と均一に接触するように設置される。外筒部の押出方向の長さは、内筒部の押出し方向の長さと同じかあるいは短くてもよい。外筒部の素材には熱伝導率の高いアルミニウムやステンレス鋼などを用いることが好ましく、シートと接触する面にはテフロン処理などを施し、滑りやすくすることが好ましい。また外筒部に冷却水を循環させ、円周方向の温度が均一になるようにすることが好ましい。 The outer cylinder part is uniform with the outer surface of the molten propylene-based resin foam sheet in which the outer wall surface of the inner cylinder part and the inner wall surface of the outer cylinder part face each other and the inner wall surface of the outer cylinder part is extruded from a circular die. Installed in contact. The length of the outer cylinder part in the extrusion direction may be the same as or shorter than the length of the inner cylinder part in the extrusion direction. It is preferable to use aluminum, stainless steel, or the like having high thermal conductivity as the material of the outer tube portion, and it is preferable to make the surface in contact with the sheet teflon-treated to make it slippery. Further, it is preferable to circulate cooling water through the outer cylinder portion so that the circumferential temperature becomes uniform.

溶融状プロピレン系樹脂製発泡シートと接する外筒部壁面(内壁面)には複数の孔が設けられており、真空ポンプを用いて、これら孔を通じてシートと外筒部との間を減圧し、シートを外筒部内壁面に均一に接触させる。孔の孔径は通常0.1mm〜1mmであり、孔の数は通常1〜10個/cm2である。また減圧度は通常、大気圧よりも0.02〜0.05MPa低くする。 The outer cylinder part wall surface (inner wall surface) in contact with the molten propylene-based resin foam sheet is provided with a plurality of holes, and using a vacuum pump, the pressure between the sheet and the outer cylinder part is reduced through these holes, The sheet is brought into uniform contact with the inner wall surface of the outer cylinder. The hole diameter is usually 0.1 mm to 1 mm, and the number of holes is usually 1 to 10 holes / cm 2 . The degree of vacuum is usually 0.02 to 0.05 MPa lower than the atmospheric pressure.

外筒部は、シート押出方向における位置や外筒部と内筒部の対向する壁面の距離を調整できる構造が好ましい。外筒部のダイ側開口部と接触する溶融状プロピレン系樹脂製発泡シートの表面温度が100℃以上160℃以下となるように、押出条件や外筒部の押出方向における位置を調整することが好ましい。シート表面温度は、110℃以上140℃以下であることがより好ましい。前記温度範囲の表面温度であるシートと外筒部壁面とを接触させることによって、表面平滑性に極めて優れるプロピレン系樹脂製発泡シートを得ることができる。 The outer cylinder part preferably has a structure capable of adjusting the position in the sheet pushing direction and the distance between the opposing wall surfaces of the outer cylinder part and the inner cylinder part. It is possible to adjust the extrusion conditions and the position of the outer cylinder part in the extrusion direction so that the surface temperature of the molten propylene-based resin foam sheet in contact with the die side opening of the outer cylinder part is 100 ° C. or higher and 160 ° C. or lower. preferable. The sheet surface temperature is more preferably 110 ° C. or higher and 140 ° C. or lower. By bringing a sheet having a surface temperature in the above temperature range into contact with the outer cylinder wall surface, a propylene-based resin foam sheet having extremely excellent surface smoothness can be obtained.

内筒部と外筒部の対向する壁面の距離は、以下のように設定することが好ましい。まず外筒部を用いずに内筒部のみを用いてプロピレン系樹脂製発泡シートを製造し、得られる発泡シートの厚みをtとする。外筒部を用いる以外は同一の条件で製造する場合に、前記発泡シートの厚みt以上かつ該発泡シート厚みtの1.5倍以下に内筒部と外筒部の対向する壁面の距離を設定することが好ましく、1.3倍以下に設定することがより好ましい。内筒部と外筒部の対向する壁面の距離が短すぎるとシート表面が外筒部内壁面との摩擦で荒れることがあり、長すぎると減圧度を保持しにくく、シートを外筒部に密着させることが困難となることがある。 The distance between the opposing wall surfaces of the inner cylinder part and the outer cylinder part is preferably set as follows. First, a propylene-based resin foam sheet is manufactured using only the inner cylinder part without using the outer cylinder part, and the thickness of the resulting foam sheet is defined as t. In the case of manufacturing under the same conditions except that the outer cylinder part is used, the distance between the wall surfaces of the inner cylinder part and the outer cylinder part facing each other is set to be not less than the thickness t of the foam sheet and not more than 1.5 times the foam sheet thickness t. It is preferable to set it, and it is more preferable to set it to 1.3 times or less. If the distance between the opposing wall surfaces of the inner cylinder part and outer cylinder part is too short, the seat surface may become rough due to friction with the inner wall surface of the outer cylinder part. May be difficult to do.

溶融状プロピレン系樹脂製発泡シートと接する内筒部外壁面にも外筒部同様に複数の孔を設けて、これら孔を通じて減圧し、シートを内筒部に密着させてもよい。 A plurality of holes may be provided on the outer wall surface of the inner cylinder portion in contact with the molten propylene-based resin foamed sheet in the same manner as the outer cylinder portion, and the pressure may be reduced through these holes to bring the sheet into close contact with the inner cylinder portion.

本発明で得られるプロピレン系樹脂製発泡シートには、通常発泡シートの表面に施される、コロナ処理、オゾン処理や帯電防止剤塗布などの表面処理を行うこともできる。 The foamed sheet made of propylene resin obtained in the present invention can be subjected to surface treatment such as corona treatment, ozone treatment or antistatic agent application, which is usually applied to the surface of the foamed sheet.

本発明で得られる発泡シートの発泡倍率や厚みは特に限定されることはないが、通常、厚みが0.5〜4mmであり、発泡倍率は2〜15倍である。なお本発明で得られる発泡シートは、通常の多層共押出成形による多層発泡シートであってもよい。 The foaming ratio and thickness of the foamed sheet obtained in the present invention are not particularly limited, but usually the thickness is 0.5 to 4 mm and the foaming ratio is 2 to 15 times. The foamed sheet obtained in the present invention may be a multilayer foamed sheet formed by ordinary multilayer coextrusion molding.

本発明で得られる発泡シートは、包装、通函、仕切り板、食品容器、文具、建材、自動車内装材等に使用することができる。また、発泡シートの片面または両面にシートやフィルム(薄板状物)を貼合したり、帯電防止剤溶液やガスバリア性樹脂組成物溶液等の溶液を塗布してコーティング層を設けてもよい。この場合、発泡シートの表面にコロナ処理、オゾン処理等の表面処理を行うことが好ましい。
貼合する薄板状物としては用途に応じて公知のものを使用することができ、例えば、アルミニウムや鉄等の金属、熱可塑性樹脂、紙、合成紙、麻、ガラスウール等からなる薄板状物や、不織布、織布等を挙げることができる。
The foam sheet obtained by the present invention can be used for packaging, boxing, partition plates, food containers, stationery, building materials, automobile interior materials, and the like. In addition, a coating layer may be provided by bonding a sheet or film (thin plate-like material) on one or both sides of the foamed sheet, or applying a solution such as an antistatic agent solution or a gas barrier resin composition solution. In this case, it is preferable to perform surface treatment such as corona treatment or ozone treatment on the surface of the foam sheet.
As the thin plate to be bonded, known ones can be used depending on the application, for example, a thin plate made of metal such as aluminum or iron, thermoplastic resin, paper, synthetic paper, hemp, glass wool, etc. And non-woven fabrics and woven fabrics.

本発明で得られる発泡シートを食品包装材として用いる場合、該シートの少なくとも片面に、10〜100μm厚みのプロピレン系樹脂フィルム、またはガスバリア性樹脂フィルムを貼合することが好ましい。ガスバリア性樹脂としては、エチレン・ビニルアルコール共重合体、ポリ塩化ビニリデン、ポリビニルアルコール、ポリアミドなど公知のガスバリア性樹脂が用いられる。 When the foamed sheet obtained in the present invention is used as a food packaging material, it is preferable to paste a propylene-based resin film or a gas barrier resin film having a thickness of 10 to 100 μm on at least one side of the sheet. As the gas barrier resin, known gas barrier resins such as an ethylene / vinyl alcohol copolymer, polyvinylidene chloride, polyvinyl alcohol, and polyamide are used.

また本発明で得られる発泡シートを自動車内装材として用いる場合には、該シートの少なくとも片面に不織布、織布、麻、ガラスウール等を貼合して用いることが好ましい。
発泡シートを箱の仕切り板等として使用する場合には、内容物保護のため、発泡倍率の高い他の発泡シートを少なくとも片面に貼合することが好ましい。
Moreover, when using the foamed sheet obtained by this invention as a vehicle interior material, it is preferable to bond and use a nonwoven fabric, a woven fabric, hemp, glass wool etc. at least on one side of this sheet | seat.
When the foam sheet is used as a box partition plate or the like, it is preferable that another foam sheet having a high expansion ratio is bonded to at least one surface in order to protect the contents.

本発明で得られる発泡シートにフィルム、薄板状物を貼合する方法は特に限定されるものではなく、例えば、(1)接着剤を発泡シート表面および/または薄板状物表面に塗布して貼合する方法、(2)接着性樹脂フィルムがラミネートされた薄板状物を用い、該接着性樹脂フィルム面を加熱溶融して発泡シートと貼合する方法、(3)ヒーターや熱風などによって発泡シート表面および/または薄板状物表面を溶融させて貼合する方法、(4)溶融樹脂を薄板状物と発泡シートとの間に押出しラミネートして貼合する方法等が挙げられる。 The method for laminating a film or thin plate on the foamed sheet obtained in the present invention is not particularly limited. For example, (1) an adhesive is applied to the surface of the foamed sheet and / or the surface of the thin plate. (2) A method of using a thin plate laminated with an adhesive resin film, heating and melting the adhesive resin film surface and pasting it to the foamed sheet, (3) a foamed sheet with a heater or hot air, etc. Examples of the method include melting and bonding the surface and / or the surface of the thin plate, and (4) a method of extruding and laminating the molten resin between the thin plate and the foamed sheet.

本発明で得られる発泡シートおよび薄板状物などが貼合された発泡シートに、真空成形等の熱成形を行い所望の形状に成形した成形品として使用することもできる。
熱成形法としては、公知の方法を用いることができ、例えば真空成形や熱罫線加工が挙げられる。
It can also be used as a molded product obtained by molding the foamed sheet obtained by the present invention, a foamed sheet and the like into a desired shape by thermoforming such as vacuum forming.
A known method can be used as the thermoforming method, and examples thereof include vacuum forming and heat ruled line processing.

以下、実施例によって本発明をさらに詳細に説明するが、本発明はこれらの例に何ら限定されるものではない。 EXAMPLES Hereinafter, although an Example demonstrates this invention further in detail, this invention is not limited to these examples at all.

(1)重合体の極限粘度
ウベローデ型粘度計を用いて135℃テトラリン中で測定を行った。なお、結晶性プロピレン重合体部分(B)の極限粘度は結晶性プロピレン重合体部分(A)および全体のプロピレン系重合体(T)の極限粘度より特開平11−228629号公報に記載の計算式より求めた。
(1) Intrinsic Viscosity of Polymer The measurement was performed in 135 ° C. tetralin using an Ubbelohde viscometer. The intrinsic viscosity of the crystalline propylene polymer portion (B) is calculated from the intrinsic viscosity of the crystalline propylene polymer portion (A) and the entire propylene polymer (T) as described in JP-A-11-228629. I asked more.

(2)MFR
JIS K7210に従い、温度230℃、荷重2.16kgfで測定した。単位はg/10分。
(2) MFR
According to JIS K7210, measurement was performed at a temperature of 230 ° C. and a load of 2.16 kgf. The unit is g / 10 minutes.

(3)メルトテンション(MT)
東洋精機社製メルトテンションテスターMT−501D3型を用いて、サンプル量5g、加熱温度190℃、加熱時間5分間、押出速度5.7mm/分で、長さ8mm、直径2mmのオリフィスからストランドを押し出し、該ストランドを直径50mmのローラーを用いて巻取速度100rpmで巻き取ったときの張力を、メルトテンション(MT)として測定した(単位=g)。
(3) Melt tension (MT)
Using a melt tension tester MT-501D3 manufactured by Toyo Seiki Co., Ltd., a strand was extruded from an orifice having a length of 8 mm and a diameter of 2 mm at a sample amount of 5 g, a heating temperature of 190 ° C., a heating time of 5 minutes, and an extrusion speed of 5.7 mm / min. The tension when the strand was wound at a winding speed of 100 rpm using a roller having a diameter of 50 mm was measured as melt tension (MT) (unit: g).

(4)発泡倍率
JIS K7112に従い、水中置換法による測定方法を使用し発泡シートの密度ρfを求め、樹脂密度ρs(0.90)を用いて下式2により発泡倍率χを計算した。
χ=ρs/ρf [式2]
ρs:樹脂密度(g/cm3)、ρf:発泡体密度(g/cm3
(4) Foaming ratio According to JIS K7112, the density ρf of the foamed sheet was obtained using a measurement method by an underwater substitution method, and the foaming ratio χ was calculated by the following formula 2 using the resin density ρs (0.90).
χ = ρs / ρf [Formula 2]
ρs: Resin density (g / cm 3 ), ρf: Foam density (g / cm 3 )

(5)表面粗さ
(株)東京精密製表面粗さ測定装置SURFCOM200Cを用い、触針先端は半径5μmのダイアモンド製を用いた。測定部位はシートの幅方向から3箇所、幅方向80mm×押出方向40mmのサンプルを切り出し、測定距離は幅方向に50mmとした。変位の最大と最小の差を表面粗さとし、3箇所を平均した。
(5) Surface roughness The surface precision measuring device SURFCOM200C made by Tokyo Seimitsu Co., Ltd. was used, and the tip of the stylus was made of diamond having a radius of 5 μm. Three measurement sites were taken from the width direction of the sheet, a sample having a width direction of 80 mm × extrusion direction of 40 mm was cut out, and the measurement distance was 50 mm in the width direction. The difference between the maximum and minimum displacement was defined as the surface roughness, and three locations were averaged.

[参考例1](プロピレン系樹脂PP1の製造)
特開平11−228629号公報に開示された方法により、プロピレン系重合体粉末を製造した。該プロピレン系重合体粉末は、極限粘度7.7dl/gの結晶性プロピレン重合体部分Aと、極限粘度1.2dl/gの結晶性プロピレン重合体部分Bを有するものであった。なお、AとBの重量比は11:89であり、プロピレン系重合体全体の極限粘度は1.9dl/gであった。
上記プロピレン系重合体粉末100重量部に対して、ステアリン酸カルシウム0.1重量部、商品名イルガノックス1010(チバガイギー株式会社製)0.05重量部、商品名スミライザーBHT(住友化学工業株式会社製)0.2重量部を加えて混合し、230℃で溶融混練し、メルトフローレートMFRが12g/10分であるペレット(プロピレン系樹脂PP1)を得た。このペレットのメルトテンションMTを測定したところ、4.7gであり、[式1]の右辺7.52×MFR(230)(-0.576)は1.80となり、[式1]を満足するものであった。
[Reference Example 1] (Production of propylene-based resin PP1)
Propylene polymer powder was produced by the method disclosed in JP-A-11-228629. The propylene polymer powder had a crystalline propylene polymer portion A having an intrinsic viscosity of 7.7 dl / g and a crystalline propylene polymer portion B having an intrinsic viscosity of 1.2 dl / g. The weight ratio of A and B was 11:89, and the intrinsic viscosity of the entire propylene polymer was 1.9 dl / g.
0.1 parts by weight of calcium stearate, 0.05 parts by weight of trade name Irganox 1010 (manufactured by Ciba Geigy Co., Ltd.), trade name of Sumilizer BHT (manufactured by Sumitomo Chemical Co., Ltd.) 0.2 parts by weight was added and mixed, and melt-kneaded at 230 ° C. to obtain pellets (propylene resin PP1) having a melt flow rate MFR of 12 g / 10 minutes. The melt tension MT of the pellet was measured to be 4.7 g, and the right side of [Formula 1] 7.52 × MFR (230) (−0.576) was 1.80, which satisfies [Formula 1]. there were.

[実施例1](押出発泡試験)
下記に示す方法にて中間層に発泡層を、その両面に非発泡層を設けた2種3層のプロピレン系樹脂製多層発泡シートを作製した。
発泡層用押出機として先端にギアポンプを設けた65mmΦ同方向回転2軸押出機(L/D=41.5、Lはスクリュー有効長さ、Dはスクリュー径)を、非発泡層用押出機として60mmΦ単軸押出機(L/D=30)を使用し、これら押出機にリップ口径230mmΦの多層サーキュラーダイ(外リップ半径r2 =11.6cm、内リップ半径r1 =11.5cm、リップ開度r2 − r1 =0.1cm)を接続した装置を使用した。
上記参考例1で得られたポリプロピレン系樹脂PP1(MFR=12)70重量部と低密度ポリエチレンPE1(住友化学工業(株)製、スミカセンG201)30重量部の配合物に対して、気泡核剤(日本ベーリンガーインゲルハイム(株)製、ハイドロセロールCF40E)を1PHRブレンドした原料樹脂を定量フィーダーを経て発泡層用押出機ホッパーに投入して溶融混錬を行い、溶融が進んだ位置(L/D=20)で液化炭酸ガス2.7PHRをダイヤフラム式定量ポンプを用いて高圧で注入した。原料樹脂と炭酸ガスを十分溶融混練したのち、185℃に調整し、吐出量110Kg/hでギアポンプを用いて多層ダイに導入した。
一方、ポリプロピレン系樹脂PP2((株)サンアロマ製、PF814(MFR=3))70重量部と低密度ポリエチレンPE1(住友化学工業(株)製、スミカセンG201)30重量部の配合物を定量フィーダーを経て非発泡層用押出機ホッパーに投入して溶融混錬を行い、185℃に調整し、吐出量55Kg/hで多層ダイに導入した。
多層ダイから大気圧中に押出した円筒状の溶融状プロピレン系樹脂製発泡シートを、ダイ出口より250mm離れたところに設置された外径700mmφ(リップ口径に対して3倍)、長さ1000mmの内筒部および外筒部の間を通して内筒部外壁面と外筒部内壁面に接触させた。内筒部および外筒部はともにアルミニウム製であり、シートと接触する面にはテフロン処理を施し、内部には冷却水を循環させ、円周方向均一に温度制御した。
外筒部は内筒部を円周方向全体に覆い、シートが接触する外筒部の押出方向の長さは300mmであり、内筒部の押出方向の中央付近に設置した。
また、外筒部のシート接触面には孔(直径0.5mm)が密度5個/cm2で設けられており、前記孔を通じて大気圧よりも0.02MPa減圧し、シートを外筒部に密着させた。外筒部入口における溶融状プロピレン系樹脂製シート表面温度は120℃であって、内筒部と外筒部の隙間は内筒部のみを使用して得られた比較例1の発泡シートの厚みの1.1倍とした。
内筒部と外筒部の壁面と接触して冷却された円筒状プロピレン系樹脂製発泡シートに左右からカッターでスリットを入れ、円筒を平板状に切り開いて上下2枚の約1100mm幅の平板状シートとし、各々のシートをニップロールを備えた引取機で引取ったのち、2軸ターレット電動反転式巻取機にて巻き取った。
得られた発泡シートは、発泡倍率9.2倍、厚み1.9mm、外筒部内壁面に接触した面の表面粗さは142μmであり、内筒部外壁面に接触した面の表面粗さは150μmであり、表面平滑性良好なシートであった。
[Example 1] (Extrusion Foam Test)
A two-layer, three-layer, propylene-based resin multilayer foam sheet in which a foam layer was provided on the intermediate layer and a non-foam layer was provided on both sides thereof was prepared by the method described below.
A 65 mmΦ co-rotating twin screw extruder (L / D = 41.5, L is the effective screw length, D is the screw diameter) with a gear pump at the tip as the foam layer extruder, and the non-foam layer extruder A 60 mmΦ single screw extruder (L / D = 30) was used, and a multilayer circular die with a lip diameter of 230 mmΦ (external lip radius r 2 = 11.6 cm, inner lip radius r 1 = 11.5 cm, lip opening) Device with a degree of r 2 -r 1 = 0.1 cm) was used.
A cell nucleating agent for a blend of 70 parts by weight of the polypropylene resin PP1 (MFR = 12) obtained in Reference Example 1 and 30 parts by weight of low density polyethylene PE1 (Sumitomo Chemical Co., Ltd., Sumikasen G201). A raw resin obtained by blending 1 PHR blend (Nippon Boehringer Ingelheim Co., Ltd., Hydrocerol CF40E) into a foaming layer extruder hopper through a quantitative feeder, melt kneading, and the position where melting has progressed (L / In D = 20), 2.7 PHR of liquefied carbon dioxide gas was injected at a high pressure using a diaphragm metering pump. After sufficiently melting and kneading the raw material resin and carbon dioxide, the temperature was adjusted to 185 ° C. and introduced into the multilayer die using a gear pump at a discharge rate of 110 kg / h.
On the other hand, a quantitative feeder comprising a blend of 70 parts by weight of polypropylene resin PP2 (manufactured by Sun Aroma Co., Ltd., PF814 (MFR = 3)) and 30 parts by weight of low density polyethylene PE1 (manufactured by Sumitomo Chemical Co., Ltd., Sumikasen G201). Then, the mixture was introduced into a non-foamed layer extruder hopper and melt kneaded, adjusted to 185 ° C., and introduced into a multilayer die at a discharge rate of 55 kg / h.
A cylindrical molten propylene-based resin foam sheet extruded from a multilayer die into the atmospheric pressure has an outer diameter of 700 mmφ (three times the lip diameter) and a length of 1000 mm installed 250 mm away from the die outlet. The inner cylinder part and the outer cylinder part were made to contact between the inner cylinder part outer wall surface and the outer cylinder part inner wall surface. Both the inner cylinder part and the outer cylinder part were made of aluminum, the surface in contact with the sheet was subjected to Teflon treatment, cooling water was circulated inside, and the temperature was uniformly controlled in the circumferential direction.
The outer cylinder portion covered the entire inner cylinder portion in the circumferential direction, and the length of the outer cylinder portion in contact with the sheet in the extrusion direction was 300 mm, and was installed near the center of the inner cylinder portion in the extrusion direction.
Further, holes (diameter 0.5 mm) are provided at a density of 5 holes / cm 2 on the sheet contact surface of the outer cylinder portion, and the pressure is reduced by 0.02 MPa from atmospheric pressure through the holes, and the sheet is placed in the outer cylinder portion. Adhered. The thickness of the foamed sheet of Comparative Example 1 obtained by using only the inner cylinder portion as the molten propylene-based resin sheet surface temperature at the outer cylinder portion entrance is 120 ° C., and the gap between the inner cylinder portion and the outer cylinder portion is used. 1.1 times.
A cylindrical propylene resin foam sheet cooled in contact with the wall surfaces of the inner and outer cylinder portions is slit with a cutter from the left and right sides, and the cylinder is cut into a flat plate shape. Each sheet was taken up by a take-up machine equipped with a nip roll, and then taken up by a twin-screw turret electric reversing winder.
The obtained foamed sheet has an expansion ratio of 9.2 times, a thickness of 1.9 mm, a surface roughness of the surface in contact with the inner wall surface of the outer cylinder portion is 142 μm, and a surface roughness of the surface in contact with the outer wall surface of the inner cylinder portion is The sheet had a surface smoothness of 150 μm.

[比較例1]
外筒部を使用せず、内筒部のみを使用して冷却成形した以外は実施例1と同様に行った。得られた発泡シートは、発泡倍率8.4倍、厚み1.7mm、内筒部外壁面に接触した面の表面粗さは150μmであったが、該面と反対側の面の表面粗さは228μmであり、表面平滑性に劣るシートであった。
[Comparative Example 1]
The same procedure as in Example 1 was performed except that the outer cylinder portion was not used and only the inner cylinder portion was used for cooling molding. The obtained foamed sheet had a foaming ratio of 8.4 times, a thickness of 1.7 mm, and the surface roughness of the surface in contact with the outer wall surface of the inner cylinder portion was 150 μm. Was 228 μm and was a sheet inferior in surface smoothness.

[比較例2]
外筒部内壁面と内筒部外壁面との距離を比較例1のシート厚み1.7mmの1.6倍である2.7mmとした以外は実施例1と同様にして、プロピレン系樹脂製発泡シートの製造を試みたが、減圧度を保持することができず、得られた発泡シートは比較例1と同等の平滑性に劣るものであった。
[Comparative Example 2]
Propylene-based resin foaming in the same manner as in Example 1, except that the distance between the inner wall surface of the outer cylinder part and the outer wall surface of the inner cylinder part was set to 2.7 mm, which is 1.6 times the sheet thickness of Comparative Example 1. Although production of the sheet was attempted, the degree of vacuum could not be maintained, and the obtained foamed sheet was inferior in smoothness equivalent to that of Comparative Example 1.

図1は本発明におけるプロピレン系樹脂製発泡シートの製造方法の例を示す図である。FIG. 1 is a diagram showing an example of a method for producing a propylene-based resin foam sheet in the present invention.

符号の説明Explanation of symbols

1:サーキュラーダイ
2:溶融状プロピレン系樹脂製発泡シート
3:内筒部
4:外筒部

1: Circular die 2: Molten propylene resin foam sheet 3: Inner cylinder part 4: Outer cylinder part

Claims (1)

プロピレン系樹脂および発泡剤を押出機にて溶融混練した後サーキュラーダイから大気圧中に押出して得られる溶融状プロピレン系樹脂製発泡シートを、円筒状の内筒部と外筒部の間を通して内筒部の外壁面および外筒部の内壁面と接触させてプロピレン系樹脂製発泡シートを製造する方法であって、外筒部内壁面には複数の孔が設けられており、該孔を通じて溶融状プロピレン系樹脂製発泡シートと外筒部との間を減圧することにより溶融状プロピレン系樹脂製発泡シートを外筒部内壁面に接触させるプロピレン系樹脂製発泡シートの製造方法。
A melted propylene resin foam sheet obtained by extruding a propylene resin and a foaming agent into an atmospheric pressure from a circular die after being melt kneaded by an extruder is inserted between the cylindrical inner cylinder part and the outer cylinder part. A method for producing a propylene-based resin foam sheet by contacting with an outer wall surface of a cylindrical portion and an inner wall surface of an outer cylindrical portion, wherein a plurality of holes are provided in the inner wall surface of the outer cylindrical portion, and a molten state is formed through the holes. A method for producing a propylene-based resin foam sheet in which a molten propylene-based resin foam sheet is brought into contact with the inner wall surface of the outer cylinder portion by reducing the pressure between the propylene-based resin foam sheet and the outer cylinder portion.
JP2004186031A 2004-06-24 2004-06-24 Manufacturing method of foamed sheet made of propylene resin Pending JP2006007511A (en)

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