JP2005511682A5 - - Google Patents
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- Publication number
- JP2005511682A5 JP2005511682A5 JP2003549300A JP2003549300A JP2005511682A5 JP 2005511682 A5 JP2005511682 A5 JP 2005511682A5 JP 2003549300 A JP2003549300 A JP 2003549300A JP 2003549300 A JP2003549300 A JP 2003549300A JP 2005511682 A5 JP2005511682 A5 JP 2005511682A5
- Authority
- JP
- Japan
- Prior art keywords
- olefin
- producing
- aryl
- sulfonate
- bromine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- -1 aryl olefins Chemical class 0.000 claims 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-L Sulphite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 239000000010 aprotic solvent Substances 0.000 claims 1
- 150000001491 aromatic compounds Chemical class 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 125000004435 hydrogen atoms Chemical group [H]* 0.000 claims 1
- 239000011630 iodine Substances 0.000 claims 1
- 229910052740 iodine Inorganic materials 0.000 claims 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 229910052763 palladium Inorganic materials 0.000 claims 1
Claims (1)
- アリールオレフィンの製造法において、
−一般式（Ｉ）
Ａｒ−［Ｘ］ｎ （Ｉ）
［式中、
ｎは、１又は２を表し、かつ
Ａｒは、置換又は非置換の芳香族基を表し、かつ
Ｘは、その都度無関係に、塩素、臭素、ヨウ素又はスルホネートを表す］
の芳香族化合物を、
−パラジウム−触媒、
−少なくとも１種の立体的に要求の多い窒素塩基の存在下に、
−二重結合上に少なくとも１個の水素原子を有するオレフィンと、
−双極性非プロトン性溶剤の存在で
反応させることを特徴とする、アリールオレフィンの製造法。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10159269A DE10159269A1 (de) | 2001-12-03 | 2001-12-03 | Arylierung von Olefinen |
| PCT/EP2002/012994 WO2003048107A1 (de) | 2001-12-03 | 2002-11-20 | Arylierung von olefinen |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005511682A JP2005511682A (ja) | 2005-04-28 |
| JP2005511682A5 true JP2005511682A5 (ja) | 2006-01-05 |
| JP4426301B2 JP4426301B2 (ja) | 2010-03-03 |
Family
ID=7707838
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003549300A Expired - Fee Related JP4426301B2 (ja) | 2001-12-03 | 2002-11-20 | オレフィンのアリール化法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6858756B2 (ja) |
| EP (1) | EP1467963A1 (ja) |
| JP (1) | JP4426301B2 (ja) |
| AU (1) | AU2002358519A1 (ja) |
| DE (1) | DE10159269A1 (ja) |
| IL (1) | IL162238A0 (ja) |
| WO (1) | WO2003048107A1 (ja) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2548925A1 (en) | 2003-12-12 | 2005-06-23 | Solvias Ag | Method for producing orthometalated and orthosubstituted metallocences |
| WO2005123662A1 (en) * | 2004-06-18 | 2005-12-29 | Janssen Pharmaceutica N.V. | Modified heck reaction |
| SG187425A1 (en) | 2008-01-04 | 2013-02-28 | Intellikine Llc | Certain chemical entities, compositions and methods |
| US8193182B2 (en) | 2008-01-04 | 2012-06-05 | Intellikine, Inc. | Substituted isoquinolin-1(2H)-ones, and methods of use thereof |
| ES2637113T3 (es) | 2011-01-10 | 2017-10-10 | Infinity Pharmaceuticals, Inc. | Procedimientos para preparar isoquinolinonas y formas sólidas de isoquinolinonas |
| WO2012120070A1 (en) | 2011-03-10 | 2012-09-13 | Lonza Ltd | Method for preparation of 3-(2,3-dimethylphenyl)-2-butenal |
| US8828998B2 (en) | 2012-06-25 | 2014-09-09 | Infinity Pharmaceuticals, Inc. | Treatment of lupus, fibrotic conditions, and inflammatory myopathies and other disorders using PI3 kinase inhibitors |
| US20150320755A1 (en) | 2014-04-16 | 2015-11-12 | Infinity Pharmaceuticals, Inc. | Combination therapies |
| AU2017281797A1 (en) | 2016-06-24 | 2019-01-24 | Infinity Pharmaceuticals, Inc. | Combination therapies |
| CN114085300B (zh) * | 2021-12-24 | 2023-09-15 | 南亚新材料科技股份有限公司 | 改性聚丁二烯树脂及其制备方法、应用 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3922299A (en) * | 1974-03-05 | 1975-11-25 | Univ Delaware | Vinylic substitution reactions |
| CH654286A5 (de) * | 1981-11-04 | 1986-02-14 | Ciba Geigy Ag | Verfahren zur pd-katalysierten arylierung von olefinen mit arylhalogeniden. |
| DE19825454A1 (de) * | 1998-06-06 | 1999-12-16 | Aventis Res & Tech Gmbh & Co | Verfahren zur Herstellung von aromatischen Olefinen unter Katalyse von Palladiumkatalysatoren mit Phosphitliganden |
-
2001
- 2001-12-03 DE DE10159269A patent/DE10159269A1/de not_active Withdrawn
-
2002
- 2002-11-20 EP EP02792778A patent/EP1467963A1/de not_active Withdrawn
- 2002-11-20 IL IL16223802A patent/IL162238A0/xx not_active IP Right Cessation
- 2002-11-20 JP JP2003549300A patent/JP4426301B2/ja not_active Expired - Fee Related
- 2002-11-20 AU AU2002358519A patent/AU2002358519A1/en not_active Abandoned
- 2002-11-20 WO PCT/EP2002/012994 patent/WO2003048107A1/de active Application Filing
- 2002-11-27 US US10/305,877 patent/US6858756B2/en not_active Expired - Fee Related
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