JP2005344248A - Wrinkle-removing agent - Google Patents
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- JP2005344248A JP2005344248A JP2004166166A JP2004166166A JP2005344248A JP 2005344248 A JP2005344248 A JP 2005344248A JP 2004166166 A JP2004166166 A JP 2004166166A JP 2004166166 A JP2004166166 A JP 2004166166A JP 2005344248 A JP2005344248 A JP 2005344248A
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Abstract
Description
本発明は、繊維製品のしわを除去することができる、繊維製品のしわ除去剤、及びそれを含有する洗浄剤組成物、柔軟剤組成物、漂白剤組成物並びに糊剤組成物に関する。 The present invention relates to a textile product wrinkle removing agent capable of removing wrinkles of a textile product, and a cleaning composition, a softener composition, a bleaching composition and a paste composition containing the same.
一般に衣類等の繊維製品を洗濯すると、しわが生じ、しわを取るために、一般にアイロンがけやスチームプレス等の熱処理を行っている。このような洗濯によるしわを低減するための洗剤組成物や仕上げ剤組成物が提案されている。例えば、特許文献１には、特定の変性シリコーンを含有する液体仕上げ剤組成物が開示されている。また、特許文献２には、環式アミンベースポリマー、疎水性修飾セルロースベースポリマー等を含有する洗剤組成物が開示されている。 In general, when a textile product such as clothing is washed, wrinkles are generated. In order to remove wrinkles, heat treatment such as ironing or steam press is generally performed. Detergent compositions and finish compositions for reducing such wrinkles due to washing have been proposed. For example, Patent Document 1 discloses a liquid finish composition containing a specific modified silicone. Patent Document 2 discloses a detergent composition containing a cyclic amine base polymer, a hydrophobic modified cellulose base polymer and the like.
しかしながら、これらの組成物では、しわ低減効果が十分満足できるものではなかった。
本発明の課題は、繊維製品のしわを十分に除去することができる、しわ除去剤、及びそれを含有する洗浄剤組成物、柔軟剤組成物、漂白剤組成物及び糊剤組成物を提供することにある。 An object of the present invention is to provide a wrinkle removing agent capable of sufficiently removing wrinkles of a textile product, and a cleaning composition, a softener composition, a bleaching composition and a paste composition containing the same. There is.
本発明は、式（Ｉ）で表されるマクロモノマー（以下マクロモノマー（Ｉ）という）単位の割合が、全構成モノマー単位中５０質量％以上であるポリマクロモノマーを含む、繊維製品のしわ除去剤、それを含有する洗浄剤組成物、柔軟剤組成物、漂白剤組成物及び糊剤組成物を提供する。 The present invention is a method for removing wrinkles from a textile product, comprising a polymacromonomer in which the proportion of the macromonomer (hereinafter referred to as macromonomer (I)) unit represented by the formula (I) is 50% by mass or more in all the constituent monomer units An agent, a detergent composition, a softener composition, a bleaching composition and a paste composition containing the same are provided.
（式中、Ｒ1は水素原子又は炭素数１〜２２の直鎖又は分岐鎖アルキル基、Ａは炭素数２〜３の直鎖又は分岐鎖アルキレン基を示す。ｘは１〜１２の数であり、ｙは平均で５〜２００の数である。） (In the formula, R 1 represents a hydrogen atom or a linear or branched alkyl group having 1 to 22 carbon atoms, A represents a linear or branched alkylene group having 2 to 3 carbon atoms. X is a number of 1 to 12. And y is an average number of 5 to 200.)
本発明により、繊維製品の洗浄時、柔軟仕上げ時、漂白時あるいは糊付け時に、繊維製品のしわを効果的に除去することができる。 According to the present invention, wrinkles of a textile product can be effectively removed when the textile product is washed, softly finished, bleached or glued.
［しわ除去剤］
本発明のしわ除去剤に用いられるポリマクロモノマーは、マクロモノマー（Ｉ）を重合するか、あるいはマクロモノマー（Ｉ）と他のモノマーを共重合することにより得ることができる。
[Wrinkle remover]
The polymacromonomer used for the wrinkle removing agent of the present invention can be obtained by polymerizing the macromonomer (I) or copolymerizing the macromonomer (I) with another monomer.
マクロモノマー（Ｉ）において、Ｒ1は水素原子又は炭素数１〜２２の直鎖又は分岐鎖アルキル基を示すが、炭素数１〜５のアルキル基が好ましく、メチル基が更に好ましい。、Ａは炭素数２〜３の直鎖又は分岐鎖アルキレン基を示すが、エチレン基が好ましい。ｘは１〜１２の数であるが、１〜１０の数が好ましい。ｙは平均で５〜２００の数であるが、４０〜１００の数が好ましい。 In the macromonomer (I), R 1 represents a hydrogen atom or a linear or branched alkyl group having 1 to 22 carbon atoms, preferably an alkyl group having 1 to 5 carbon atoms, and more preferably a methyl group. , A represents a linear or branched alkylene group having 2 to 3 carbon atoms, preferably an ethylene group. x is a number from 1 to 12, but a number from 1 to 10 is preferred. y is an average number of 5 to 200, but a number of 40 to 100 is preferable.
マクロモノマー（Ｉ）と共重合可能なモノマーとしては、例えば、アクリル酸、メタクリル酸等のカルボン酸系モノマー、及びこれらのエステル化合物、エチレン、プロピレン、ｎ−ブチレン、イソブチレン、酢酸ビニル、スチレン、ビニルトルエン、α−メチルスチレン等のモノマーを挙げることができる。 Examples of monomers copolymerizable with the macromonomer (I) include carboxylic acid monomers such as acrylic acid and methacrylic acid, and ester compounds thereof, ethylene, propylene, n-butylene, isobutylene, vinyl acetate, styrene, vinyl, and the like. Mention may be made of monomers such as toluene and α-methylstyrene.
本発明のポリマクロモノマーを構成するモノマー成分中の、マクロモノマー（Ｉ）の割合は、繊維に滑り性能を効率的に付与出来る観点から、５０質量％以上であり、７０質量％以上が好ましく、８０質量％以上が更に好ましい。 The proportion of the macromonomer (I) in the monomer component constituting the polymacromonomer of the present invention is 50% by mass or more, preferably 70% by mass or more, from the viewpoint of efficiently imparting slip performance to the fiber. 80 mass% or more is still more preferable.
本発明に用いられるポリマクロモノマーの重量平均分子量（以下Ｍｗと略記）は、１００，０００〜３００，０００，０００が好ましく、１，０００，０００〜３０，０００，０００が更に好ましく、１０，０００，０００〜２５，０００，０００が特に好ましい。 The weight average molecular weight (hereinafter abbreviated as Mw) of the polymacromonomer used in the present invention is preferably 100,000 to 300,000,000, more preferably 1,000,000 to 30,000,000, and 10,000. 2,000 to 25,000,000 is particularly preferred.
尚、本発明において、ポリマクロモノマーのＭｗは、多角度光散乱検出器付きサイズ排除クロマトグラフィー（ＭＡＬＬＳ−ＳＥＣ）により測定する。ＭＡＬＬＳ−ＳＥＣ測定は、ＭＡＬＬＳ（ワイアットテクノロジー社製 ＤＡＷＮ−ＤＳＰ）と昭和電工（株）製System 21ＳＥＣを、カラムは、昭和電工（株）製、ＫＦ−８０４Ｌ＋ＫＦ−８０６Ｌ＋ＫＦ−８０６Ｌの３本連結を用いて行う。溶離液は０．１μｍのフィルターで濾過したＤＭＦを用い、流速１ｍＬ／ｍｉｎとして、カラム温度は４０℃、試料濃度は０．１重量％、１００μＬの流入量で測定する。分子量は、東ソー（株）製のＰＥＯ標準サンプルで換算した値である。 In the present invention, Mw of the polymacromonomer is measured by size exclusion chromatography with a multi-angle light scattering detector (MALLS-SEC). MALLS-SEC measurement uses MALLS (DAWN-DSP manufactured by Wyatt Technology) and Showa Denko Co., Ltd. System 21SEC, and the column uses Showa Denko KK KF-804L + KF-806L + KF-806L. Do it. The eluent is DMF filtered through a 0.1 μm filter, the flow rate is 1 mL / min, the column temperature is 40 ° C., the sample concentration is 0.1 wt%, and the inflow is 100 μL. The molecular weight is a value converted with a PEO standard sample manufactured by Tosoh Corporation.
本発明においては、上記のようなポリマクロモノマーを、１種又は２種以上組み合わせて用いることができる。 In the present invention, the above polymacromonomer can be used alone or in combination of two or more.
本発明に用いられるポリマクロモノマーの製法は特に限定されないが、マクロモノマー（Ｉ）及び必要により他のモノマーを含むモノマー成分を連鎖重合する方法により製造することができる。この方法によれば、枝鎖の数を数本から千本以上に広範囲に変えた規則性のポリマクロモノマーを容易に合成できる。具体的には、特開２００１−６４１２３号公報に記載の方法で製造することができる。 The production method of the polymacromonomer used in the present invention is not particularly limited, but it can be produced by a method of chain polymerization of the monomer component containing the macromonomer (I) and, if necessary, other monomers. According to this method, it is possible to easily synthesize a regular polymacromonomer in which the number of branches is changed from a few to a thousand or more. Specifically, it can be produced by the method described in JP-A-2001-64123.
本発明のしわ除去剤は、上記のような本発明に係わるポリマクロモノマーを含むものであり、本発明のしわ除去剤中の、本発明に係わるポリマクロモノマーの含有量は、１．０〜１００質量％が好ましく、５．０〜８０質量％が更に好ましい。 The wrinkle removal agent of the present invention contains the polymacromonomer according to the present invention as described above, and the content of the polymacromonomer according to the present invention in the wrinkle removal agent of the present invention is 1.0 to 100 mass% is preferable and 5.0-80 mass% is still more preferable.
本発明のしわ除去剤中には、本発明に係わるポリマクロモノマー以外に、しわ低減効果を発現することが一般に知られている化合物（例えば、ジメチルポリシロキサン、アミノ基やポリエーテル基で置換された変性シリコーン等）を併用することも可能であり、また、ポリマクロモノマーを安定に配合する目的、ポリマクロモノマーを均一に塗布する目的で非イオン界面活性剤やアルコール系の有機溶剤を含有することができる。 In the wrinkle removing agent of the present invention, in addition to the polymacromonomer related to the present invention, a compound generally known to exhibit a wrinkle reducing effect (for example, dimethylpolysiloxane, substituted with an amino group or a polyether group). Modified silicone, etc.) can be used in combination, and it contains nonionic surfactants and alcohol-based organic solvents for the purpose of stably blending the polymacromonomer and for the uniform application of the polymacromonomer. be able to.
本発明のしわ除去剤は、洗浄剤、柔軟剤、漂白剤、糊剤等に添加して用いることにより、繊維製品のしわを効果的に除去することができる。 The wrinkle removing agent of the present invention can effectively remove wrinkles from textile products by adding it to detergents, softeners, bleaches, glues and the like.
［洗浄剤組成物］
本発明の洗浄剤組成物は、必須成分として、本発明のしわ除去剤を含有する。洗浄剤組成物中の本発明のしわ除去剤の含有量は、０．１〜２０質量％が好ましく、５〜１５質量％が更に好ましい。
[Cleaning composition]
The cleaning composition of the present invention contains the wrinkle removing agent of the present invention as an essential component. 0.1-20 mass% is preferable and, as for content of the wrinkle removal agent of this invention in a cleaning composition, 5-15 mass% is still more preferable.
本発明の洗浄剤組成物は、衣類を洗浄するための洗剤等として使用され、しわ除去剤以外に、界面活性剤、ビルダー、アルカリ剤、漂白成分等の従来の洗浄剤組成物に配合される成分を含有することができる。 The detergent composition of the present invention is used as a detergent for washing clothes, and is blended with conventional detergent compositions such as surfactants, builders, alkaline agents and bleaching components in addition to wrinkle removers. Ingredients can be included.
本発明に用いられる界面活性剤としては、陰イオン界面活性剤、非イオン界面活性剤、両性界面活性剤、陽イオン界面活性剤等が挙げられる。 Examples of the surfactant used in the present invention include an anionic surfactant, a nonionic surfactant, an amphoteric surfactant, and a cationic surfactant.
陰イオン界面活性剤としては、高級アルコールの硫酸エステル塩、高級アルコールのエトキシル化物の硫酸エステル塩、アルキルベンゼンスルホン酸塩、パラフィンスルホン酸塩、α−オレフィンスルホン酸塩、α−スルホ脂肪酸塩若しくはそのエステル塩、又は脂肪酸塩等が挙げられる。特に、アルキル鎖の炭素数が１０〜１８（好ましくは１２〜１４）の直鎖アルキルベンゼンスルホン酸塩、炭素数が１０〜２０のα−スルホ脂肪酸アルキルエステル塩が好ましい。また、対イオンとしては、アルカリ金属、アルカリ土類金属、アンモニウム、アルカノールアミン等が挙げられる。 Anionic surfactants include higher alcohol sulfates, higher alcohol ethoxylate sulfates, alkylbenzene sulfonates, paraffin sulfonates, α-olefin sulfonates, α-sulfo fatty acid salts or esters thereof. Examples thereof include salts or fatty acid salts. In particular, linear alkylbenzene sulfonates having 10 to 18 (preferably 12 to 14) carbon atoms in the alkyl chain and α-sulfo fatty acid alkyl ester salts having 10 to 20 carbon atoms are preferred. Examples of the counter ion include alkali metals, alkaline earth metals, ammonium, and alkanolamine.
非イオン界面活性剤としては、高級アルコールのエチレンオキシド（以下「ＥＯ」という）付加物、若しくはＥＯ／プロピレンオキシド（以下「ＰＯ」という）付加物、脂肪酸アルカノールアミド、アルキル（ポリ）グリコシド等が挙げられる。特に炭素数が１０〜１６のアルコールのＥＯ平均１〜１０モル付加物が皮脂汚れの除去、耐硬水性、生分解性の点、及び直鎖アルキルベンゼンスルホン酸塩との相性の点で好ましい。 Nonionic surfactants include ethylene oxide (hereinafter referred to as “EO”) adducts of higher alcohols, or EO / propylene oxide (hereinafter referred to as “PO”) adducts, fatty acid alkanolamides, alkyl (poly) glycosides, and the like. . In particular, an EO average 1 to 10 mol adduct of an alcohol having 10 to 16 carbon atoms is preferable in terms of removal of sebum soil, hard water resistance, biodegradability, and compatibility with linear alkylbenzene sulfonate.
陽イオン界面活性剤としては、アルキルトリメチルアンモニウム塩等が、両性界面活性剤としては、カルボベタイン型、スルホベタイン型両性界面活性剤等が挙げられる。 Examples of the cationic surfactant include alkyltrimethylammonium salts, and examples of the amphoteric surfactant include carbobetaine-type and sulfobetaine-type amphoteric surfactants.
本発明の洗浄剤組成物中の界面活性剤の含有量は、特に限定されないが、５〜５０質量％が好ましく、１５〜５０質量％が更に好ましい。 Although content of surfactant in the cleaning composition of this invention is not specifically limited, 5-50 mass% is preferable and 15-50 mass% is still more preferable.
本発明に用いられるビルダーとしては、結晶性アルミノ珪酸塩、非晶質アルミノ珪酸塩、結晶性珪酸ナトリウム、トリポリリン酸ナトリウム、ピロリン酸ナトリウム等の無機ビルダー、式（II） Builders used in the present invention include crystalline aluminosilicates, amorphous aluminosilicates, crystalline sodium silicates, sodium tripolyphosphates, sodium pyrophosphates, etc., formula (II)
〔式中、Ｒ2は−（ＣＨ2）n−Ｂで表される基であり、Ｂは水素原子、水酸基又は−ＣＯＯＭ1であり、Ｍ1は水素原子、アルカリ金属（好ましくはＮａ、Ｋ）又はアンモニウムであり、ｎは０〜３の数である。〕
で表されるアミノポリカルボン酸等の有機ビルダーが挙げられる。本発明の洗浄剤組成物中のビルダーの含有量は、特に限定されないが、１０〜５０質量％が好ましく、１５〜４０質量％が更に好ましい。
[Wherein, R 2 is a group represented by — (CH 2 ) n —B, B is a hydrogen atom, a hydroxyl group or —COOM 1 , M 1 is a hydrogen atom, an alkali metal (preferably Na, K ) Or ammonium, and n is a number from 0 to 3. ]
Organic builder such as aminopolycarboxylic acid represented by Although content of the builder in the cleaning composition of this invention is not specifically limited, 10-50 mass% is preferable and 15-40 mass% is still more preferable.
本発明に用いられるアルカリ剤としては、炭酸塩、珪酸塩、アミン類（アルキルアミン、アルカノールアミン等）等が挙げられ、炭酸塩、珪酸塩がより好ましい。本発明の洗浄剤組成物中のアルカリ剤の含有量は、特に限定されないが、５〜５０質量％が好ましく、１０〜４０質量％が更に好ましい。 Examples of the alkaline agent used in the present invention include carbonates, silicates, amines (alkylamines, alkanolamines, etc.), and carbonates and silicates are more preferable. The content of the alkaline agent in the cleaning composition of the present invention is not particularly limited, but is preferably 5 to 50% by mass, and more preferably 10 to 40% by mass.
本発明に用いられる漂白成分としては、水溶液中で過酸化水素を放出する物質（以下過酸化水素放出物質という）や漂白活性化剤が挙げられる。過酸化水素放出物質としては、炭酸塩・過酸化水素付加物、硼酸塩・過酸化水素付加物、トリポリリン酸塩・過酸化水素付加物、ピロリン酸塩・過酸化水素付加物、尿素・過酸化水素付加物等が挙げられる。この中でも、炭酸塩・過酸化水素付加物、硼酸塩・過酸化水素付加物が好ましく、過炭酸ナトリウム、過硼酸ナトリウムがより好ましい。本発明の洗浄剤組成物中の過酸化水素放出物質の含有量は、特に限定されないが、０．１〜８０質量％が好ましく、０．５〜７０質量％が更に好ましい。 Examples of the bleaching component used in the present invention include substances that release hydrogen peroxide in aqueous solutions (hereinafter referred to as hydrogen peroxide releasing substances) and bleach activators. Hydrogen peroxide releasing substances include carbonate / hydrogen peroxide adduct, borate / hydrogen peroxide adduct, tripolyphosphate / hydrogen peroxide adduct, pyrophosphate / hydrogen peroxide adduct, urea / peroxidation. Examples thereof include hydrogen adducts. Among these, carbonate / hydrogen peroxide adduct and borate / hydrogen peroxide adduct are preferable, and sodium percarbonate and sodium perborate are more preferable. The content of the hydrogen peroxide releasing substance in the cleaning composition of the present invention is not particularly limited, but is preferably 0.1 to 80% by mass, and more preferably 0.5 to 70% by mass.
本発明に用いられる漂白活性化剤としては、式(III)又は(IV)で表される化合物が挙げられる。 Examples of the bleach activator used in the present invention include compounds represented by the formula (III) or (IV).
〔式中、Ｒ3は炭素数４〜１３、好ましくは１０〜１３のアルキル基、Ｒ4は炭素数５〜１３、好ましくは７〜１１のアルキル基、Ｍ2は水素原子又はアルカリ金属、アルカリ土類金属、アンモニウム若しくはアルカノールアミンを示す。〕
本発明の洗浄剤組成物中の漂白活性化剤の含有量は、特に限定されないが、０．０５〜２０質量％が好ましく、０．１〜１０質量％が更に好ましい。
[Wherein R 3 is an alkyl group having 4 to 13 carbon atoms, preferably 10 to 13 carbon atoms, R 4 is an alkyl group having 5 to 13 carbon atoms, preferably 7 to 11 carbon atoms, M 2 is a hydrogen atom or an alkali metal, an alkali Indicates earth metal, ammonium or alkanolamine. ]
The content of the bleach activator in the cleaning composition of the present invention is not particularly limited, but is preferably 0.05 to 20% by mass, and more preferably 0.1 to 10% by mass.
本発明の洗浄剤組成物には、上記成分以外に、洗浄剤の分野で公知の成分、例えば、カルボン酸系ポリマー、カルボキシメチルセルロース、可溶性澱粉、糖類等の水溶性ポリマーや、再汚染防止剤、柔軟化剤、蛍光増白剤、泡コントロール剤、酵素、香料等を含有させることができる。 In addition to the above components, the cleaning composition of the present invention includes components known in the field of cleaning agents, such as water-soluble polymers such as carboxylic acid polymers, carboxymethyl cellulose, soluble starch, and saccharides, anti-staining agents, Softening agents, fluorescent whitening agents, foam control agents, enzymes, fragrances and the like can be included.
［柔軟剤組成物］
本発明の柔軟剤組成物は、必須成分として、本発明のしわ除去剤を含有する。柔軟剤組成物中の本発明のしわ除去剤の含有量は、０．１〜２０質量％が好ましく、５〜１５質量％が更に好ましい。
[Softener composition]
The softener composition of the present invention contains the wrinkle removing agent of the present invention as an essential component. 0.1-20 mass% is preferable and, as for content of the wrinkle removal agent of this invention in a softening agent composition, 5-15 mass% is still more preferable.
本発明の柔軟剤組成物は、本発明のしわ除去剤以外に、柔軟基剤、抗菌剤等を含有することができる。 The softening agent composition of the present invention can contain a softening base, an antibacterial agent and the like in addition to the wrinkle removal agent of the present invention.
本発明に用いられる柔軟基剤としては、下記式（Ｖ）〜(Ｘ)で表される化合物が挙げられる。 Examples of the flexible base used in the present invention include compounds represented by the following formulas (V) to (X).
〔式中、Ｒ5及びＲ6はそれぞれ炭素数１１〜２３の直鎖又は分岐鎖の飽和又は不飽和炭化水素基、Ｒ7は炭素数１〜２４の直鎖又は分岐鎖の飽和又は不飽和炭化水素基、ヒドロキシエチル基あるいはヒドロキシプロピル基、ｍは２又は３、Ｒ8，Ｒ9，Ｒ13及びＲ14はそれぞれ炭素数１０〜２４のアルキル基、アルケニル基又はβ−ヒドロキシアルキル基であり、Ｒ10，Ｒ11及びＲ12はそれぞれ炭素数１〜３のアルキル基もしくはヒドロキシアルキル基、ベンジル基又は−（Ｃ2Ｈ4Ｏ）p−Ｈ（但し、ｐは１〜３である）を示し、Ｘ-はハロゲンイオン、炭素数１〜３のアルキル基を有するモノアルキル硫酸イオン等の陰イオン基を示す。〕
本発明の柔軟剤組成物中の柔軟基剤の含有量は、特に限定されないが、３〜５０質量％が好ましく、５〜４０質量％が更に好ましい。
Wherein linear or branched, saturated or unsaturated hydrocarbon group of R 5 and R 6 carbon atoms, respectively 11 to 23, R 7 is a saturated or unsaturated straight-chain or branched-chain having 1 to 24 carbon atoms A hydrocarbon group, a hydroxyethyl group or a hydroxypropyl group, m is 2 or 3, and R 8 , R 9 , R 13 and R 14 are each an alkyl group, alkenyl group or β-hydroxyalkyl group having 10 to 24 carbon atoms. , R 10 , R 11 and R 12 are each an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group, a benzyl group or — (C 2 H 4 O) p —H (wherein p is 1 to 3). shows, X - represents a halogen ion, an anion group of monoalkyl sulfate or the like having an alkyl group having 1 to 3 carbon atoms. ]
Although content of the softening base in the softening agent composition of this invention is not specifically limited, 3-50 mass% is preferable and 5-40 mass% is still more preferable.
本発明に用いられる抗菌剤としては、下記式（XI）〜(XII)で表される化合物が挙げられる。 Examples of the antibacterial agent used in the present invention include compounds represented by the following formulas (XI) to (XII).
〔式中、Ｒ15及びＲ20はそれぞれ炭素数５〜１９の直鎖又は分岐鎖のアルキル基又はアルケニル基、Ｒ17及びＲ18はそれぞれ炭素数１〜３のアルキル基又はヒドロキシアルキル基、Ｔは−ＣＯＯ−、−ＯＣＯ−、−ＣＯＮＨ−、−ＮＨＣＯ−又はフェニレン基、Ｒ16は炭素数１〜６のアルキレン基又は−（ＯＲ21）r−（ここで、Ｒ21は炭素数２〜３のアルキレン基、ｒは１〜１０の数）、Ｒ19は炭素数１〜３のアルキレン基、ｑは０又は１、Ｚ-はハロゲンイオン、炭素数１〜３のアルキル基を有するモノアルキル硫酸イオン等の陰イオン基を示す。〕
本発明の柔軟剤組成物中の抗菌剤の含有量は、特に限定されないが、０．００１〜１０質量％が好ましく、０．００１〜３．０質量％が更に好ましい。
[Wherein, R 15 and R 20 are each a linear or branched alkyl group or alkenyl group having 5 to 19 carbon atoms, R 17 and R 18 are each an alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms, T Is —COO—, —OCO—, —CONH—, —NHCO— or a phenylene group, R 16 is an alkylene group having 1 to 6 carbon atoms, or — (OR 21 ) r — (wherein R 21 is 2 to 2 carbon atoms). 3 is an alkylene group, r is a number from 1 to 10, R 19 is an alkylene group having 1 to 3 carbon atoms, q is 0 or 1, Z − is a halogen ion, and a monoalkyl having an alkyl group having 1 to 3 carbon atoms. An anion group such as sulfate ion is shown. ]
Although content of the antibacterial agent in the softening agent composition of this invention is not specifically limited, 0.001-10 mass% is preferable and 0.001-3.0 mass% is still more preferable.
更に本発明の柔軟剤組成物には、貯蔵安定剤を向上させるために、アルキルグリセリルエーテル、ジ又はトリアルキレングルコールモノアリールエーテル、ジ又はトリアルキレングリコール、ジ又はトリアルキレングリコールモノアルキルエーテル、ジ又はトリアルキレングリコールジアルキルエーテル、１ ，６ −ヘキサンジオール、２ ，５ −ヘキサンジオール、シクロヘキサノール、２ −ヘキサノール、１−オクタノール、ジプロピレングリコール等を配合することができる。また、更に炭素数８〜２２の飽和又は不飽和脂肪酸と多価アルコールとのエステル化合物を配合することが貯蔵安定性の点から好ましい。本発明の柔軟剤組成物中のこれらの化合物の含有量は０．１〜１０質量％が好ましく、０．５〜５質量％が更に好ましい。 Further, the softener composition of the present invention includes an alkyl glyceryl ether, a di- or trialkylene glycol monoaryl ether, a di- or trialkylene glycol, a di- or trialkylene glycol monoalkyl ether, di- Alternatively, a trialkylene glycol dialkyl ether, 1,6-hexanediol, 2,5-hexanediol, cyclohexanol, 2-hexanol, 1-octanol, dipropylene glycol and the like can be blended. Further, it is preferable from the viewpoint of storage stability that an ester compound of a saturated or unsaturated fatty acid having 8 to 22 carbon atoms and a polyhydric alcohol is blended. The content of these compounds in the softener composition of the present invention is preferably 0.1 to 10% by mass, and more preferably 0.5 to 5% by mass.
また更に本発明の柔軟剤組成物は、貯蔵安定性の点から非イオン界面活性剤を含有することもできる。非イオン界面活性剤としては炭素数８〜２０のアルキル基またはアルケニル基を１つ以上有するポリオキシエチレンアルキルエーテルが好ましい。非イオン界面活性剤の含有量は、組成物中、０．５〜１０質量％が好ましく、１〜８質量％が更に好ましい。 Furthermore, the softener composition of the present invention can also contain a nonionic surfactant from the viewpoint of storage stability. The nonionic surfactant is preferably a polyoxyethylene alkyl ether having at least one alkyl group or alkenyl group having 8 to 20 carbon atoms. 0.5-10 mass% is preferable in a composition, and, as for content of a nonionic surfactant, 1-8 mass% is still more preferable.
本発明の柔軟剤組成物は、繊維製品の風合いを向上させる目的で陰イオン界面活性剤を含有することができる。陰イオン界面活性剤としては、脂肪酸又はその塩類が好ましい。陰イオン界面活性剤の含有量は、組成物中０．０１〜５質量％が好ましく、０．５〜３質量％が更に好ましい。 The softener composition of the present invention can contain an anionic surfactant for the purpose of improving the texture of the textile product. As the anionic surfactant, a fatty acid or a salt thereof is preferable. The content of the anionic surfactant is preferably 0.01 to 5% by mass, more preferably 0.5 to 3% by mass in the composition.
本発明の柔軟剤組成物は、貯蔵安定性の点から、塩化カルシウム等の無機塩を含有することができる。無機塩の含有量は、組成物中０〜１０００ｐｐｍが好ましく、１０〜５００ｐｐｍが更に好ましい。 The softening agent composition of the present invention can contain an inorganic salt such as calcium chloride from the viewpoint of storage stability. The content of the inorganic salt is preferably 0 to 1000 ppm, more preferably 10 to 500 ppm in the composition.
本発明の柔軟剤組成物には、製品の外観や、使用時及び仕上がり後の趣向を良くするために、通常配合される香料あるいは色素等の成分を配合することもできる。 In the softener composition of the present invention, components such as fragrances and pigments that are usually blended can be blended in order to improve the appearance of the product and the taste after use and after finishing.
［漂白剤組成物］
本発明の漂白剤組成物は、必須成分として、本発明のしわ除去剤を含有する。漂白剤組成物中の本発明のしわ除去剤の含有量は、０．１〜２０質量％が好ましく、５〜１５質量％が更に好ましい。
[Bleaching composition]
The bleaching composition of the present invention contains the wrinkle removing agent of the present invention as an essential component. 0.1-20 mass% is preferable and, as for content of the wrinkle removal agent of this invention in a bleaching agent composition, 5-15 mass% is still more preferable.
本発明の漂白剤組成物は、本発明のしわ除去剤以外に、漂白成分等の従来の漂白剤組成物に配合される成分を含有することができる。 The bleaching composition of the present invention can contain components blended in a conventional bleaching composition such as a bleaching component in addition to the wrinkle removal agent of the present invention.
本発明に用いられる漂白成分としては、水溶液中で過酸化水素を放出する化合物（過酸化水素放出物質）又は過酸化水素、及び要すれば水溶液中で過酸化水素と反応し有機過酸を発生させる化合物（漂白活性化剤）等が挙げられる。 The bleaching component used in the present invention is a compound that releases hydrogen peroxide in an aqueous solution (hydrogen peroxide releasing substance) or hydrogen peroxide, and if necessary, reacts with hydrogen peroxide in an aqueous solution to generate an organic peracid. Compound (bleach activator) to be used.
過酸化水素放出物質や漂白活性化剤としては、例えば、上記、洗浄剤組成物の欄に配合可能な剤として記載されている過酸化水素放出物質、式(III)又は(IV)で表される化合物が挙げられる。 Examples of the hydrogen peroxide-releasing substance and the bleach activator include, for example, the hydrogen peroxide-releasing substance described as an agent that can be blended in the above-described column of the detergent composition, and the formula (III) or (IV). Compounds.
本発明の漂白剤組成物中の過酸化水素放出物質又は過酸化水素の含有量は、０．１〜２０質量％が好ましく、０．５〜１０質量％が更に好ましい。また、漂白活性化剤の含有量は、０．１〜１０質量％が好ましく、０．２〜５．０質量％が更に好ましい。 The content of the hydrogen peroxide releasing substance or hydrogen peroxide in the bleaching composition of the present invention is preferably 0.1 to 20% by mass, and more preferably 0.5 to 10% by mass. Moreover, 0.1-10 mass% is preferable and, as for content of a bleach activator, 0.2-5.0 mass% is still more preferable.
本発明の漂白剤組成物には、更に、漂白力を向上させる観点から、カルシウム捕捉量２００〜６００CaCO3mg/g、且つカルシウム安定度定数３〜１０である化合物を０．０５〜３０質量％含有させることが好ましく、０．１〜２０質量％含有させることがより好ましい。 The bleaching agent composition of the present invention further contains 0.05 to 30% by mass of a compound having a calcium capture amount of 200 to 600 CaCO 3 mg / g and a calcium stability constant of 3 to 10 from the viewpoint of improving bleaching power. It is preferable to contain, and it is more preferable to contain 0.1-20 mass%.
本発明の漂白剤組成物には、更に、漂白力を向上させる観点から、０．０２５質量％濃度の水溶液もしくは分散液の最大ｐＨが１０．０以上（２０℃）であり、且つ該水溶液もしくは分散液１リットルをｐＨ９にするために０．１Ｎの塩酸水溶液を１０ｍｌ以上必要とする化合物を１〜３０質量％含有することが好ましく、３〜２５質量％含有することががより好ましく、５〜２０質量％含有することが更に好ましく、５〜１５質量％含有することが特に好ましい。このような化合物としては、炭酸ナトリウム、炭酸カリウム、珪酸ナトリウム、リン酸三ナトリウム、モノエタノールアミン等が挙げられる。中でも炭酸ナトリウム、炭酸カリウム、珪酸ナトリウムがより好ましく、特に炭酸ナトリウムが好ましい。 In the bleaching composition of the present invention, from the viewpoint of improving bleaching power, the maximum pH of an aqueous solution or dispersion having a concentration of 0.025% by mass is 10.0 or more (20 ° C.), and the aqueous solution or It is preferable to contain 1 to 30% by mass, more preferably 3 to 25% by mass of a compound that requires 10 ml or more of a 0.1N hydrochloric acid aqueous solution in order to bring 1 liter of the dispersion to pH 9. The content is more preferably 20% by mass, and particularly preferably 5 to 15% by mass. Examples of such compounds include sodium carbonate, potassium carbonate, sodium silicate, trisodium phosphate, monoethanolamine and the like. Of these, sodium carbonate, potassium carbonate, and sodium silicate are more preferable, and sodium carbonate is particularly preferable.
本発明の漂白剤組成物には、更に、再汚染防止剤（カルボキシメチルセルロース等）、柔軟化剤（ジアルキル型第四級アンモニウム塩、粘土鉱物等）、蛍光増白剤（ビフェニル型、アミノスチルベン型等）、泡コントロール剤（シリコーン等）、香料、酵素（プロテアーゼ、ペクチナーゼ、アミラーゼ、リパーゼ等）、その他のビルダー（ゼオライト等）等の添加剤を含有させることができる。 The bleach composition of the present invention further includes a recontamination inhibitor (such as carboxymethylcellulose), a softening agent (such as a dialkyl quaternary ammonium salt and a clay mineral), and a fluorescent whitening agent (biphenyl type, aminostilbene type). Etc.), foam control agents (silicone, etc.), fragrances, enzymes (proteases, pectinases, amylases, lipases, etc.) and other builders (zeolites, etc.).
［糊剤組成物］
本発明の糊剤組成物は、必須成分として、本発明のしわ除去剤を含有する。糊剤組成物中の本発明のしわ除去剤の含有量は、０．１〜２０質量％が好ましく、５〜１５質量％が更に好ましい。
[Glue composition]
The paste composition of the present invention contains the wrinkle removing agent of the present invention as an essential component. 0.1-20 mass% is preferable and, as for content of the wrinkle removal agent of this invention in a paste composition, 5-15 mass% is still more preferable.
本発明の糊剤組成物は、本発明のしわ除去剤以外に、糊料基剤を含有する。糊料基剤としては、低級脂肪酸ビニルエステル（ａ）と、不飽和カルボン酸類（ｂ）を必須モノマー成分とするビニル重合体（ｉ）、低級脂肪酸ビニルエステル（ａ）とカチオン性不飽和単量体（ｃ）を必須モノマー成分とするビニル重合体（ii）等が挙げられる。 The paste composition of the present invention contains a paste base in addition to the wrinkle removing agent of the present invention. As a paste base, a lower fatty acid vinyl ester (a) and a vinyl polymer (i) having unsaturated carboxylic acids (b) as essential monomer components, a lower fatty acid vinyl ester (a) and a cationic unsaturated monomer And vinyl polymer (ii) having the body (c) as an essential monomer component.
低級脂肪酸ビニルエステル（ａ）としては、酢酸ビニル、酪酸ビニル、プロピオン酸ビニル等が挙げられ、これらの１種又は２種以上を組み合わせて用いることができるが、酢酸ビニルが好ましい。 Examples of the lower fatty acid vinyl ester (a) include vinyl acetate, vinyl butyrate, vinyl propionate, and the like, and one or more of these can be used in combination, with vinyl acetate being preferred.
不飽和カルボン酸類（ｂ）としては、アクリル酸、メタクリル酸、クロトン酸、マレイン酸、フマル酸、イタコン酸、アコニチン酸、ソルビン酸、ケイ皮酸、α−クロロソルビン酸、シトラコン酸、ｐ−ビニル安息香酸等の不飽和カルボン酸；イタコン酸、マレイン酸、フマル酸等の不飽和ポリカルボン酸のアルキルエステル、部分エステル（好ましくは炭素数１〜６の低級アルキルモノエステル）又は部分アミドが挙げられる。これらのうちアクリル酸、メタクリル酸、クロトン酸、イタコン酸モノメチル、イタコン酸モノブチル、フマル酸モノメチル、フマル酸モノブチル、マレイン酸モノブチル等が特に好ましい。 As unsaturated carboxylic acids (b), acrylic acid, methacrylic acid, crotonic acid, maleic acid, fumaric acid, itaconic acid, aconitic acid, sorbic acid, cinnamic acid, α-chlorosorbic acid, citraconic acid, p-vinyl Unsaturated carboxylic acids such as benzoic acid; alkyl esters, partial esters (preferably lower alkyl monoesters having 1 to 6 carbon atoms) or partial amides of unsaturated polycarboxylic acids such as itaconic acid, maleic acid, and fumaric acid. . Of these, acrylic acid, methacrylic acid, crotonic acid, monomethyl itaconate, monobutyl itaconate, monomethyl fumarate, monobutyl fumarate, monobutyl maleate and the like are particularly preferable.
カチオン性不飽和単量体（ｃ）としては、一般式(XIII)〜(XIX)で表されるものが挙げられる。 Examples of the cationic unsaturated monomer (c) include those represented by the general formulas (XIII) to (XIX).
（式中、Ｒ22は水素原子又は炭素数１〜３のアルキル基（好ましくはメチル基）、Ｒ23，Ｒ24及びＲ25はそれぞれ水素原子又は炭素数１〜４のアルキル基、Ｒ26，Ｒ27及びＲ28はそれぞれ水素原子又は炭素数１〜３（好ましくは１〜２）のアルキル基、Ｒ29，Ｒ30及びＲ31はそれぞれ炭素数１〜３のアルキル基（好ましくはメチル基）、ｓは１〜１０の数、Ｘ-は前記の意味を示す。）
本発明の糊剤組成物中の糊料基剤の含有量は、特に限定されないが、２０〜６０質量％が好ましく、３０〜５０質量％が更に好ましい。
Wherein R 22 is a hydrogen atom or an alkyl group having 1 to 3 carbon atoms (preferably a methyl group), R 23 , R 24 and R 25 are each a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, R 26 , R 27 and R 28 are each a hydrogen atom or an alkyl group having 1 to 3 carbon atoms (preferably 1 to 2), and R 29 , R 30 and R 31 are each an alkyl group having 1 to 3 carbon atoms (preferably a methyl group). , S is a number from 1 to 10, and X − represents the above-mentioned meaning.)
Although content of the paste base in the paste composition of this invention is not specifically limited, 20-60 mass% is preferable and 30-50 mass% is still more preferable.
本発明の糊剤組成物の糊料基剤がビニル重合体（ii）である場合には、更に式(XX)で表される化合物を含有することが好ましい。 When the paste base of the paste composition of the present invention is a vinyl polymer (ii), it is preferable to further contain a compound represented by the formula (XX).
（式中、Ｒ32，Ｒ33及びＲ34はそれぞれ炭素数１〜６のアルキル基、Ｒ35は炭素数１〜６のヒドロキシアルキル基、Ｘ-は前記の意味を示す。）
式(XX)で表される化合物の含有量は、組成物中０．０５〜４質量％が好ましく、０．３〜２質量％が更に好ましい。
(Wherein R 32 , R 33 and R 34 are each an alkyl group having 1 to 6 carbon atoms, R 35 is a hydroxyalkyl group having 1 to 6 carbon atoms, and X − represents the above-mentioned meaning.)
0.05-4 mass% is preferable in a composition, and, as for content of the compound represented by Formula (XX), 0.3-2 mass% is still more preferable.
本発明の糊剤組成物は、上記成分以外に、繊維への吸着性を向上させる目的で、カチオン性セルロース、カチオン性澱粉等のカチオン性の水溶性高分子を含有することができる。カチオン性水溶性高分子の含有量は、組成物中０．００１〜５質量％が好ましく、０．２〜３質量％が更に好ましい。 In addition to the components described above, the paste composition of the present invention can contain a cationic water-soluble polymer such as cationic cellulose and cationic starch for the purpose of improving the adsorptivity to fibers. The content of the cationic water-soluble polymer is preferably 0.001 to 5 mass%, more preferably 0.2 to 3 mass% in the composition.
また、本発明の糊剤組成物は、布に対する風合いを向上させる観点から、ヒドロキシエチル化澱粉、ヒドロキシプロピル化澱粉等の非イオン性化工澱粉；ポリビニルアルコール；ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、メチルセルロース等の非イオン性セルロース誘導体等の水溶性非イオン性重合体を含有させることができる。水溶性非イオン性重合体の含有量は、組成物中１０質量％以下が好ましく、１〜４質量％が更に好ましい。 Further, the paste composition of the present invention is made from non-ionic modified starch such as hydroxyethylated starch and hydroxypropylated starch; polyvinyl alcohol; hydroxyethylcellulose, hydroxypropylcellulose, methylcellulose, etc. A water-soluble nonionic polymer such as a nonionic cellulose derivative can be contained. The content of the water-soluble nonionic polymer is preferably 10% by mass or less, more preferably 1 to 4% by mass in the composition.
本発明の糊剤組成物には、低温保存安定性を向上させる目的で、グリセリン、エチレングリコール、プロピレングリコール等の多価アルコール、低温での張り性を発現させる目的で、フタル酸、アジピン酸、セバシン酸等のジカルボン酸のジエステルを配合することもできる。さらに必要に応じて、シリコーン化合物、香料、殺菌剤、防腐剤、蛍光染料、顔料等を配合することができる。 In the paste composition of the present invention, for the purpose of improving low-temperature storage stability, polyhydric alcohols such as glycerin, ethylene glycol, and propylene glycol, phthalic acid, adipic acid, A diester of a dicarboxylic acid such as sebacic acid can also be blended. Furthermore, a silicone compound, a fragrance | flavor, a disinfectant, an antiseptic | preservative, a fluorescent dye, a pigment, etc. can be mix | blended as needed.
例中の％は特記しない限り質量％である。また、以下の実施例では、次のポリマクロモノマー１及び２を用いた。
ポリマクロモノマー１：特開２００１−６４１２３号公報の表２に記載のポリマクロモノマー（２）［式(XXI)
Unless otherwise specified,% in the examples is% by mass. In the following examples, the following polymacromonomers 1 and 2 were used.
Polymacromonomer 1: Polymacromonomer (2) described in Table 2 of JP-A-2001-64123 [Formula (XXI)
で表されるマクロモノマー（１０．５ｇ）を、重合開始剤として４，４’−アゾビス（４−シアノ吉草酸）（０．２８ｇ）を用いて重合して得られた、Ｍｗ２４，８００，０００、Ｍｗ／Ｍｎ＝１．４のポリマー］
ポリマクロモノマー２：特開２００１−６４１２３号公報の表２に記載のポリマクロモノマー（３）［前記式(XXI)で表されるマクロモノマー（１０．５ｇ）を、重合開始剤として４，４’−アゾビス（４−シアノ吉草酸）（０．５６ｇ）を用いて重合して得られた、Ｍｗ２０，５００，０００、Ｍｗ／Ｍｎ＝１．６のポリマー］
実施例１〜２及び比較例１
洗剤ベースで、直鎖アルキル（アルキル基の炭素数１０〜１４）ベンゼンスルホン酸カリウム１０％、α−オレフィン（炭素数１４〜１８）スルホン酸カリウム１０％、非イオン界面活性剤（アルキル基の炭素数が１２〜１４でＥＯ平均付加モル数が７であるポリオキシエチレンアルキルエーテル）７％、ポリエチレングリコール（平均分子量８５００）１％、ゼオライト１５％、アクリル酸−マレイン酸コポリマーのナトリウム塩（７０モル％中和物、モノマー比はアクリル酸／マレイン酸＝３／７（モル比）、平均分子量７００００）０．５％、脂肪酸石鹸（パーム核油由来）５．５％、１号ケイ酸ナトリウム４％、炭酸カリウム８％、硫酸ナトリウム２％、亜硫酸ナトリウム１％、及び蛍光染料（チノパールＣＢＳ−Ｘ、チバガイギー社製）０．１％からなる、スラリー（固形分５０％）を調製し、噴霧乾燥して噴霧乾燥組成物を得た。これに洗剤ベースで、炭酸ナトリウム１２％をリボンミキサーに投入して混合を行った。得られた混合物を前押し出し式２軸型押し出し造粒機（ペレッターダブル：不二パウダル（株）製）で直径が１０ｍｍの円柱状に押し出し成形して圧密化した。得られたペレット状物を、ポリマクロモノマー１：１０％及びゼオライト５％とともにフラッシュミル（不二パウダル（株）製）で粉砕造粒して表面被覆を行った。２０００μｍの篩を通過させた後、リボンミキサーに移し、ゼオライト５％、酵素（セルラーゼＫ（特開昭６３−２６４６９９号公報記載の方法で製造）、リポラーゼ１００Ｔ（ノボ社製）を３：１の重量比で混合したもの）１％、香料０．４％を加え、混合して洗剤１を得た。また、ポリマクロモノマー２：１０％をポリマクロモノマー１の代わりに用いて同様の手法で調製し、洗剤２を得た。比較品として、ポリマクロモノマー１及び２共に未配合のものを同様の手法で調製し、洗剤３を得た。
Mw 24,800,000 obtained by polymerizing the macromonomer represented by the formula (10.5 g) using 4,4′-azobis (4-cyanovaleric acid) (0.28 g) as a polymerization initiator. , Mw / Mn = 1.4 polymer]
Polymacromonomer 2: Polymacromonomer (3) described in Table 2 of JP-A-2001-64123 [macromonomer (10.5 g) represented by the above formula (XXI) as a polymerization initiator) Polymer obtained by polymerization using '-azobis (4-cyanovaleric acid) (0.56 g), Mw 20,500,000, Mw / Mn = 1.6 polymer]
Examples 1-2 and Comparative Example 1
Based on detergent, linear alkyl (alkyl group having 10 to 14 carbon atoms) potassium benzenesulfonate 10%, α-olefin (carbon number 14 to 18) potassium sulfonate 10%, nonionic surfactant (alkyl group carbon 7% polyoxyethylene alkyl ether having 12 to 14 EO average addition moles of 7), 1% polyethylene glycol (average molecular weight 8500), 15% zeolite, sodium salt of acrylic acid-maleic acid copolymer (70 mol) % Neutralized product, monomer ratio: acrylic acid / maleic acid = 3/7 (molar ratio), average molecular weight 70,000) 0.5%, fatty acid soap (derived from palm kernel oil) 5.5%, No. 1 sodium silicate 4 %, Potassium carbonate 8%, sodium sulfate 2%, sodium sulfite 1%, and fluorescent dye (Chinopearl CBS-X, Ciba Geigy Ltd.) and 0.1% to prepare a slurry (50% solids) to give a spray-dried composition was spray-dried. To this, 12% sodium carbonate was added to a ribbon mixer on a detergent base and mixed. The obtained mixture was extruded into a columnar shape having a diameter of 10 mm with a pre-extrusion type twin-screw type extrusion granulator (Peletter Double: manufactured by Fuji Powder Co., Ltd.) to be consolidated. The obtained pellets were pulverized and granulated with a flash mill (manufactured by Fuji Powder Co., Ltd.) together with polymacromonomer 1: 10% and zeolite 5% for surface coating. After passing through a 2000 μm sieve, it was transferred to a ribbon mixer, and 3% zeolite, cellulase K (manufactured by the method described in JP-A 63-264699), and lipolase 100T (manufactured by Novo) were mixed at a ratio of 3: 1. 1% by weight) and 0.4% fragrance were added and mixed to obtain detergent 1. Also, detergent 2 was obtained by preparing polymacromonomer 2: 10% in the same manner using polymacromonomer 1 instead. As a comparative product, a non-blended polymacromonomer 1 and 2 was prepared in the same manner, and detergent 3 was obtained.
実施例３及び比較例２
２−ジメチルアミノエタノール脂肪酸エステル（脂肪酸の炭素数１６、１８）：１４％、ステアリル硫酸ナトリウム：６％、ステアリン酸：０．５％、炭素数１２の飽和アルコールにＥＯを平均２０モル付加させたもの：３％、エキセル１５０（ステアリン酸モノ、ジ、トリグリセリド混合物（モノ：ジ：トリ＝６０：３５：５）、花王（株））：０．５％、塩化ナトリウム：０．００５％、エチレングリコール：１％、シリコーン（ジーイー東芝シリコーン製、ＴＳＡ７３０）：０．１％、ポリマクロモノマー１：１０％、香料：０．２％、残部：水、を混合し、４８％水酸化ナトリウム水溶液を用い２０℃のｐＨが７になるように調製し、柔軟剤１を得た。比較品として、ポリマクロモノマー１未配合のものを同様の手法にて調製し、柔軟剤２を得た。
Example 3 and Comparative Example 2
2-dimethylaminoethanol fatty acid ester (16,18 carbon atoms of fatty acid): 14%, sodium stearyl sulfate: 6%, stearic acid: 0.5%, EO was added in an average of 20 moles to a saturated alcohol having 12 carbon atoms. Things: 3%, Excel 150 (stearic acid mono, di, triglyceride mixture (mono: di: tri = 60: 35: 5), Kao Corporation): 0.5%, sodium chloride: 0.005%, ethylene Glycol: 1%, silicone (manufactured by GE Toshiba Silicone, TSA730): 0.1%, polymacromonomer 1: 10%, perfume: 0.2%, balance: water, 48% sodium hydroxide aqueous solution The softening agent 1 was obtained by adjusting the pH at 20 ° C. to 7 to be used. As a comparative product, a non-polymacromonomer 1 blend was prepared in the same manner, and a softening agent 2 was obtained.
実施例４及び比較例３
過炭酸ナトリウム：４０％、特開平１１−４３６９２号公報の製造例１と同様に合成した式(XXII)
Example 4 and Comparative Example 3
Sodium percarbonate: 40%, formula (XXII) synthesized in the same manner as in Production Example 1 of JP-A-11-43692
で表される漂白活性化剤（ａ）：５％、ポリエチレングリコール（平均分子量８５００）：１％、アルキル（炭素数１２〜１４）硫酸ナトリウム：２％、硫酸マグネシウム：０．５％、炭酸ナトリウム：３６．４％、重炭酸ナトリウム：２％、アルキル（炭素数１２〜１４）ベンゼンスルホン酸ナトリウム：１％、ソフタノール１２０（日本触媒（株）製）：１％、ポリアクリル酸ナトリウム：１％、香料：１％、ポリマクロモノマー１：１０％となる割合で混合して、漂白剤１を得た。比較品として、ポリマクロモノマー１未配合のものを同様の手法にて調製し、漂白剤２を得た。 Bleach activator (a): 5%, polyethylene glycol (average molecular weight 8500): 1%, alkyl (carbon number 12-14) sodium sulfate: 2%, magnesium sulfate: 0.5%, sodium carbonate : 36.4%, sodium bicarbonate: 2%, alkyl (carbon number 12-14) sodium benzenesulfonate: 1%, Softanol 120 (manufactured by Nippon Shokubai Co., Ltd.): 1%, sodium polyacrylate: 1% , Fragrance: 1%, Polymacromonomer: 1: 10% were mixed to obtain Bleach 1. As a comparative product, a compound containing no polymacromonomer 1 was prepared in the same manner, and bleach 2 was obtained.
実施例５及び比較例４
特開２００１−３０２４号公報段落番号００１７と同様の方法で調製した糊料基剤Ａ［酢酸ビニル／アクリル酸／Ｎ，Ｎ−ジメチルアクリルアミドの質量比が９５．５／２．５／２であるビニル重合体のエマルジョン（ビニル重合体を約５０質量％含有）］：６０％、プロピレングリコール：２％、シリコーンエマルジョン（シリコーンＫ−９７Ｋ、信越化学工業（株）製）：０．２％、香料：０．２％、ポリマクロモノマー２：１０％、残部：水、を混合して糊剤１を得た。比較品として、ポリマクロモノマー２未配合のものを同様の手法にて調製し、糊剤２を得た。
Example 5 and Comparative Example 4
Glue base A prepared in the same manner as in paragraph No. 0017 of JP 2001-3024 A [mass ratio of vinyl acetate / acrylic acid / N, N-dimethylacrylamide is 95.5 / 2.5 / 2. Emulsion of vinyl polymer (containing about 50% by mass of vinyl polymer)]: 60%, propylene glycol: 2%, silicone emulsion (silicone K-97K, manufactured by Shin-Etsu Chemical Co., Ltd.): 0.2%, perfume : 0.2%, polymacromonomer 2: 10%, balance: water were mixed to obtain paste 1. As a comparative product, a non-polymacromonomer 2 blend was prepared in the same manner, and paste 2 was obtained.
実施例１〜２及び比較例１で得られた洗剤、実施例３及び比較例２で得られた柔軟剤、実施例４及び比較例３で得られた漂白剤、実施例５及び比較例４で得られた糊剤について、下記方法でしわ除去性を評価した。結果を表１に示す。 Detergents obtained in Examples 1 and 2 and Comparative Example 1, softeners obtained in Example 3 and Comparative Example 2, bleaches obtained in Examples 4 and 3 and Examples 5 and 4 The wrinkle removability was evaluated by the following method for the paste obtained in 1. The results are shown in Table 1.
＜しわ除去性評価法＞
（１）木綿繊維布の処理
ＪＩＳ Ｌ０８０３：１９９８に規定する試験布、単一繊維布（II）綿１０（Ｆ０１）を１１０×１３０ｍｍに裁断する。
<Wrinkle removability evaluation method>
(1) Treatment of cotton fiber cloth A test cloth defined in JIS L0803: 1998, a single fiber cloth (II) cotton 10 (F01) is cut into 110 × 130 mm.
洗剤及び漂白剤については、これらををＪＩＳ Ｋ３３６２：１９９８記載の使用水に溶解し、０．１％水溶液を調製する。この水溶液に上記試験布５枚を添加し、２０℃、１０分間、１００ｒ／minでターゴトメーターにて撹拌処理する。流水下で濯いだ後、遠心脱水機にかけ充分水分を除去した後、平らなプレート上に試験布を並べ、２５℃、５０％RHの室内で１2時間乾燥させる。 About a detergent and a bleaching agent, these are melt | dissolved in the use water of JISK3362: 1998, and 0.1% aqueous solution is prepared. Five sheets of the test cloth are added to this aqueous solution, and the mixture is stirred with a talometer at 20 ° C. for 10 minutes at 100 r / min. After rinsing under running water and removing water sufficiently by a centrifugal dehydrator, the test cloths are arranged on a flat plate and dried in a room at 25 ° C. and 50% RH for 12 hours.
柔軟剤及び糊剤については、ＪＩＳ Ｋ３３６２：１９９８記載の洗浄力判定用指標洗剤（蛍光増白剤無添加）をＪＩＳ Ｋ３３６２：１９９８記載の使用水に溶解し、０．１％水溶液を調製する。この水溶液に上記試験布５枚を添加し、２０℃、１０分間、１００ｒ／minでターゴトメーターにて撹拌処理する。流水下で濯いだ後、遠心脱水機にかけ充分水分を除去した後、２５℃、５０％RHの室内で１時間以上乾燥させる。次に、柔軟剤又は糊剤をＪＩＳ Ｋ３３６２：１９９８記載の使用水に溶解し、０．１％水溶液を調製する。この水溶液に上記乾燥させた試験布５枚を添加し、２０℃、１０分間、１００ｒ／minでターゴトメーターにて撹拌処理する。遠心脱水機にかけ充分水分を除去した後、平らなプレート上に試験布を並べ、２５℃、５０％RHの室内で１２時間乾燥させる。 As for the softener and the paste, a cleaning power determination index detergent (without adding a fluorescent brightener) described in JIS K3362: 1998 is dissolved in use water described in JIS K3362: 1998 to prepare a 0.1% aqueous solution. Five sheets of the test cloth are added to this aqueous solution, and the mixture is stirred with a talometer at 20 ° C. for 10 minutes at 100 r / min. After rinsing under running water, the water is removed sufficiently with a centrifugal dehydrator, and then dried in a room at 25 ° C. and 50% RH for 1 hour or longer. Next, a softening agent or a paste is dissolved in water used described in JIS K3362: 1998 to prepare a 0.1% aqueous solution. Five sheets of the dried test cloth are added to this aqueous solution, and the mixture is stirred with a talometer at 20 ° C. for 10 minutes at 100 r / min. After removing moisture sufficiently by applying a centrifugal dehydrator, the test cloths are arranged on a flat plate and dried in a room at 25 ° C. and 50% RH for 12 hours.
（２）しわ判定
上記処理終了後、試験布のしわの取れ具合を判定した。 評価は処理した布と、処理前の布（対照）とを、５名のパネラーに以下の基準で採点してもらい、その平均値を求めて評価点とした。
・しわ判定基準
５：全くしわがない
４：ほとんどしわがない
３：僅かにしわが残っている
２：相当しわが残っている
１：著しくしわが残っている。
(2) Wrinkle determination After completion of the above processing, the degree of wrinkle removal of the test cloth was determined. For the evaluation, the treated cloth and the cloth (control) before the treatment were scored on the basis of the following criteria by five panelists, and the average value was obtained as an evaluation score.
-Wrinkle determination criteria 5: No wrinkles 4: Almost no wrinkles 3: Slightly wrinkles remain 2: Corresponding wrinkles remain 1: Remarkably wrinkles remain.
また、上記処理終了後、処理後の各試験布を家庭用アイロン（松下電器製ＮＩ−Ａ５５自動アイロン、温度は木綿設定）でアイロンがけ処理を行い、その処理布を２５℃／５０％RHの恒温室に１２時間以上放置した後、試験布のしわの取れ具合を判定した。評価は上記と同様に５名のパネラーが上記基準で採点した。 In addition, after the above-described processing is completed, each test cloth after treatment is ironed with a household iron (NI-A55 automatic iron manufactured by Matsushita Electric, temperature is set to cotton), and the treated cloth is 25 ° C / 50% RH. After leaving in a thermostatic chamber for 12 hours or more, the degree of wrinkle removal of the test cloth was determined. In the same manner as above, five panelists scored according to the above criteria.
Claims (6)
A paste composition containing the wrinkle removing agent according to claim 1.
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| JP2001064123A (en) * | 1999-08-25 | 2001-03-13 | Kao Corp | Hair cosmetic |
| JP2002105492A (en) * | 2000-10-03 | 2002-04-10 | Kao Corp | Liquid detergent composition |
| WO2005097857A1 (en) * | 2004-04-09 | 2005-10-20 | Shiseido Company, Ltd. | Brush-form alternative copolymer and process for producing the same |
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Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01201579A (en) * | 1988-01-30 | 1989-08-14 | Osaka Aerosol Ind Corp | Aerosol-type fiber wrinkle eliminator |
| JPH0820619A (en) * | 1994-07-08 | 1996-01-23 | Toyo Ink Mfg Co Ltd | Curable resin |
| JPH1181143A (en) * | 1997-09-09 | 1999-03-26 | Nikka Chem Co Ltd | Quality improving agent in bath for treating fiber |
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| WO2005097857A1 (en) * | 2004-04-09 | 2005-10-20 | Shiseido Company, Ltd. | Brush-form alternative copolymer and process for producing the same |
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