JP2005337060A - Geothermal power generation-hydrogen manufacturing system - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To efficiently manufacture hydrogen for a fuel battery by geothermal power generation. <P>SOLUTION: Geothermal fluid from a geothermal production well 1 is separated to steam and hot water, a turbine 3 is driven by the separated steam and natural water such as sea water, river water and lake water is used as cooling water thereof to perform power generation. Electrolysis is performed making the temperature-raised natural water after cooling the turbine and/or the hot water separated from the geothermal fluid as original water by the thus obtained electric power to manufacture hydrogen. The hot water is mixed with the temperature-raised natural water after cooling the turbine to further raise the temperature and the electrolysis is preferably performed making the mixture water as original water. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

  The present invention relates to a system for producing hydrogen by geothermal power generation.

As is well known, fuel cells are a new energy source that uses hydrogen and oxygen as fuel to obtain electrical energy through their chemical reaction, and are considered extremely effective when used in power sources and cogeneration systems for automobiles (fuel cell vehicles). It has been. As the fuel for the fuel cell, oxygen in the air can be used as it is, but hydrogen is mainly produced from fossil fuels such as natural gas or by electrolyzing water into hydrogen and oxygen. For example, Patent Document 1 proposes a system for producing hydrogen by combining a power plant and a water electrolysis plant.
JP 2003-328172 A

  Although the system shown in Patent Document 1 is not only complicated and large in size as a whole, it is assumed that the power plant uses natural energy such as geothermal, hot spring water, solar heat, etc. As power generation is assumed, carbon dioxide (greenhouse gas) is not a cause of generation, and water to be electrolyzed is simply fresh water or fresh water obtained by freezing seawater. Therefore, sufficient electrolysis efficiency is not always obtained.

  In any case, at present, an effective and appropriate method for efficiently producing hydrogen for fuel cells on an industrial scale has not been established. The development of an excellent hydrogen production system with excellent environmental compatibility is indispensable and urgent.

  In view of the above circumstances, the geothermal power generation and hydrogen production system of the present invention separates the geothermal fluid from the geothermal production well into steam and hot water, drives the turbine with the separated steam and uses seawater, river water, Electric power is generated using natural water such as lake water, and hydrogen is produced by electrolyzing the heated water separated from the heated natural water and / or geothermal fluid after cooling the turbine as raw water. It is characterized by doing so. In the present invention, it is particularly preferable to mix hot water with the heated natural water after cooling the turbine, further raise the temperature, and perform electrolysis using the mixed water as raw water.

  The present invention organically combines a geothermal power generation system and a hydrogen production system by electrolyzing water, and produces hydrogen using only natural energy called geothermal by performing electrolysis with electric power obtained from the geothermal power generation system. Therefore, it does not cause an increase in environmental load as in the case of a power generation system based on the combustion of fossil fuel. In particular, in the geothermal power generation system according to the present invention, the turbine is driven by geothermal steam and natural water such as inexhaustible seawater, river water or lake water is used as cooling water for condensate. The required large-scale cooling tower equipment can be eliminated, simplifying the entire system and reducing equipment costs and operating costs. Moreover, natural water heated for cooling, geothermal hot water, or a mixture of them is electrolyzed as raw water to produce hydrogen, compared to simply electrolyzing normal temperature fresh water. The electrolysis efficiency is greatly improved and excellent hydrogen production efficiency is obtained. From the above, the hydrogen production unit price can be sufficiently reduced.

  Furthermore, according to the present invention, hot water is mixed with the heated natural water after cooling the turbine, the temperature is further raised, and electrolysis is performed using the mixed water as raw water, so that both turbine cooling and electrolysis can be performed. However, it is possible to set each water temperature independently so that it can be performed most efficiently, thereby further improving the efficiency.

  FIG. 1 shows an embodiment of a geothermal power generation / hydrogen production system of the present invention. The system of the present embodiment is provided in islands and coastal areas where geothermal energy is present, and a geothermal power generation system using geothermal energy and hydrogen that is produced by electrolysis using the electric power obtained thereby. It is an organic combination of manufacturing systems.

  That is, the system of this embodiment separates the geothermal fluid (steam and hot water) obtained from the geothermal production well 1 into steam and hot water in the separator 2 (two stages in the illustrated example), and the separated steam is turbine 3. Is generated by driving the generator 5 via the speed reducer 4. Exhaust steam from the turbine 3 is cooled by the condenser 6 and condensed, and seawater, which is natural water, is pumped up by the pump 7 for use as the cooling water. A non-condensable gas is taken out from the condenser 6 by a gas extraction vacuum pump 8, and heated seawater (including condensed exhaust steam) whose water temperature has been increased by cooling the exhaust steam from the turbine 3 is recovered from the condenser. 6 leads to the sealed water pit 9 and is stored there.

  Then, the heated seawater from the sealed water pit 9 is appropriately mixed with a part of the hot water separated by the separator 2 and further heated, and the electrolyzed water tank 10 (illustrated example) using the mixed water as raw water for electrolysis. 3 tanks are arranged side by side), where electrolysis is performed with the electric power obtained by the generator 5, and the obtained hydrogen is charged into the cylinder 12 from the gas holder 11, and the excess water is discharged. To do. In addition, what is necessary is just to utilize the remainder of hot water to reduce | subtract from a reduction well to the ground, or if possible. Moreover, what is necessary is just to discharge | emit the surplus geothermal fluid from the geothermal production well 1 suitably through the silencer 13. FIG.

  According to the system of the present embodiment, hydrogen is produced by electrolysis only with the electric power obtained by the geothermal power generation system, and therefore, by the generation of carbon dioxide gas as in the case of the conventional thermal power generation system by fossil fuel combustion. There are no factors that increase the environmental impact. Geothermal energy is much denser and more stable than other natural energies such as solar energy and wind energy, and the potential for geothermal energy is particularly high in Japan, which is a volcanic country. It is said that the power generation capacity reaches 1.2 million kW, and the system according to this embodiment can sufficiently utilize such geothermal energy, which is extremely rational and effective.

  In addition, in this embodiment, inexhaustible seawater is used as cooling water in the geothermal power generation system, so a large-scale cooling tower facility that is indispensable in a normal turbine power generation system is unnecessary, and simplification of the entire system and equipment cost・ Operation costs can be reduced sufficiently.

  Moreover, since hot water is mixed with the heated seawater after cooling used for turbine cooling and heated further, and used as the raw water for electrolysis, electrolysis is performed compared to the case of simply electrolyzing fresh water at room temperature. The efficiency is greatly improved and excellent hydrogen production efficiency is obtained, and the hydrogen production unit price can be sufficiently reduced. In this case, it is preferable that the cooling temperature by seawater is sufficiently low (for example, 25 ° C. or less) in order to increase the power generation efficiency by the turbine 3. Conversely, in order to increase the electrolysis efficiency in the electrolysis water tank 10, Since the temperature of the raw water is preferably sufficiently high (for example, about 60 ° C.), the turbine cooling temperature by seawater and the amount of hot water mixed with the temperature rising seawater should be optimally set so as to satisfy both conditions. good.

  Although the embodiment of the present invention has been described above, the above embodiment is merely an example, and the present invention is not limited to the above embodiment and can be appropriately modified and applied.

  For example, in the above-described embodiment, both turbine cooling and electrolysis can be efficiently performed by mixing hot water with the heated seawater after turbine cooling and further raising the temperature to use it as raw water for electrolysis. However, this is not always the case, and in the case where sufficient hot water cannot be obtained, only the heated seawater after cooling can be used as raw water. It may be disassembled. In this case, in order for both the cooling by seawater and the subsequent electrolysis using only the heated seawater as raw water to be performed most efficiently, the temperature of the heated seawater after cooling the turbine (water temperature as the raw water for electrolysis) ) Is preferably set to about 50 to 60 ° C., and the amount of cooling water may be adjusted so as to maintain such a water temperature.

  On the contrary, when high-temperature hot water is sufficiently obtained, only the hot water may be electrolyzed as raw water, and the heated seawater after turbine cooling may be discharged as it is. In this case, since the water temperature of the heated seawater after the turbine cooling is not related to the electrolysis efficiency, the cooling water temperature and the cooling water amount may be set optimally considering only the turbine cooling efficiency.

  In the above embodiment, the cylinder 12 is filled with the produced hydrogen, but it may be adsorbed by a hydrogen storage alloy and stored in it. Of course, oxygen can also be obtained as a by-product by electrolysis, so that it can be recovered and used if necessary. The electric power obtained by the geothermal power generation system may be used as in-house electric power, and may be appropriately used when surplus electric power is generated.

  In the above embodiment, seawater is adopted as the raw water for turbine cooling and electrolysis, but other natural waters such as river water and lake water can be used in the same manner instead of seawater. In any case, in the present invention, since natural water, geothermal hot water, or a mixed water thereof is electrolyzed as raw water, impurities may be mixed into the produced hydrogen depending on their water quality. If necessary, an appropriate purification step may be added to the final stage to remove impurities.

1 is a system diagram showing a configuration of a geothermal power generation / hydrogen production system according to an embodiment of the present invention.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Geothermal production well 2 Separator 3 Turbine 4 Reducer 5 Generator 6 Condenser 7 Pumping pump 8 Gas extraction vacuum pump 9 Sealed pit 10 Electrolysis water tank 11 Gas holder 12 Cylinder 13 Silencer

Claims (2)

  The geothermal fluid from the geothermal well is separated into steam and hot water, and the turbine is driven by the separated steam, and power is generated using natural water such as seawater, river water, and lake water as its cooling water. A geothermal power generation / hydrogen production system characterized in that hydrogen is produced by electrolyzing hot water separated from a heated natural water and / or a geothermal fluid after cooling the turbine by using the obtained electric power.   The geothermal power generation / hydrogen production system according to claim 1, wherein hot water is mixed with heated natural water after turbine cooling, the temperature is further raised, and electrolysis is performed using the mixed water as raw water.

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