JP2005334779A - Equipment for treating oil cake - Google Patents

Equipment for treating oil cake Download PDF

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JP2005334779A
JP2005334779A JP2004157670A JP2004157670A JP2005334779A JP 2005334779 A JP2005334779 A JP 2005334779A JP 2004157670 A JP2004157670 A JP 2004157670A JP 2004157670 A JP2004157670 A JP 2004157670A JP 2005334779 A JP2005334779 A JP 2005334779A
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oil
slurry
water
oil cake
particles
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Yoshikazu Kobayashi
由和 小林
Hidemasa Kobayashi
秀匡 小林
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Miike Inc
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Miike Inc
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses

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Abstract

<P>PROBLEM TO BE SOLVED: To provide equipment for treating oil cake, in which the oil cake generated when edible oil is manufactured is hydrolyzed to obtain slurry and then pulverized by exerting the impact action and shear action of a high-speed water current on the obtained slurry so that the pulverized oil cake can be annihilated efficiently by adding fermentative bacteria or can be used variously as liquid fertilizer, and the like. <P>SOLUTION: The equipment 1 for treating oil cake is composed of: a fermentative bacterium supplying unit 10 in which a large quantity of fermentative bacteria are cultivated; a slurry producing unit 20 for producing slurry by hydrolyzing the oil cake A from an oil mill 5 in an alkaline condition; a pulverization unit 30 for pulverizing oil cake particles in the oil cake slurry S sent from the slurry producing unit 20 by exerting the impact action and shear action of the high-speed water current mainly on the oil cake particles; and a fermentation unit 50 in which the pulverized oil cake particles are fermented after receiving the water current S' which contains the pulverized oil cake particles and is supplied from the pulverization unit 30 and the large quantity of fermentative bacteria F supplied from the fermentative bacterium supplying unit 10. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、大豆、菜種、綿実、亜麻仁、落花生などの植物種子を圧搾又は浸出して油分を取った粕や、魚油かすなどの油粕を微粉砕処理する処理設備、特に発酵菌によって効果的に処理ができるように油粕をミクロンレベルに微粉砕する食用油製造粕の処理設備に関する。   INDUSTRIAL APPLICABILITY The present invention is effective with processing equipment for pulverizing oil seeds such as soybean oil, rapeseed, cottonseed, flaxseed, peanuts, etc. by squeezing or leaching plant seeds, fish oil cake, etc. The present invention relates to a processing equipment for edible oil production soot that finely pulverizes the soot to a micron level so that it can be processed.

油粕の主要なものは、大豆粕で、味噌、醤油などの原料や飼料や肥料に用いられるが、他の油粕は有害成分を含んでいたり、産出量が少なかったりするために肥料にされていた。しかし、大豆粕の産出量は群を抜いていたために、焼却処分されるものも多かった。しかし、植物性油粕は、窒素に富んでいて、リン酸及びカリウムも含み、緩効性の基肥として有望であった。従って、油粕様肥料の製造に廃棄食用油に大豆粕を混合し、熟成させるものがある。(例えば、特許文献1参照)。
特開平8−26872号公報([発明の詳細な説明])
The main component of soybean cake is soybean cake, which is used as a raw material for miso and soy sauce, as well as feed and fertilizer, but other soybean cake contains fertilizer because it contains harmful components and produces less. . However, because the production of soybean meal was outstanding, many were incinerated. However, vegetable oil meal is rich in nitrogen and contains phosphoric acid and potassium, and is promising as a slow-release base fertilizer. Therefore, there is a method of mixing soybean meal with waste cooking oil for the production of oil cake-like fertilizer and aging. (For example, refer to Patent Document 1).
JP-A-8-26872 ([Detailed Description of the Invention])

上述のような大豆粕の利用処理では、大量に産出されるものには効果的では無い。近年汚泥やヘドロの有機分を処理するのに効果が注目されている発酵菌を大量に培養するための培養地として、また連作障害も克服する効果のある液体肥料としても大量に利用できるようにする要望に答える必要があった。
本願発明の目的は、油粕をミクロンレベルまで微粉砕して単位表面積を大幅に大きくして、発酵菌の大量培養のための培養地として利用できるようにすると共に、混合された発酵菌が多数付着して増殖過程で短時間で効率的に摂取消費できるようにしたり、培養した発酵菌を大量に含み連作障害も克服する効果のある液体肥料の製造にも役立つ食用油製造粕の処理設備を提供するものである。
The soybean meal utilization process as described above is not effective for large-scale production. It can be used in large quantities as a culture site for culturing a large amount of fermenting bacteria that have been attracting attention for the treatment of sludge and sludge organic content in recent years, and also as a liquid fertilizer effective in overcoming continuous cropping obstacles. There was a need to answer the request.
The object of the present invention is to finely pulverize the oil cake to the micron level to greatly increase the unit surface area, and to use it as a culture place for mass culture of fermenting bacteria, and to adhere a large number of mixed fermenting bacteria Providing processing equipment for edible oil production paddles that can be efficiently consumed and consumed in a short time during the growth process, and that is also useful for the production of liquid fertilizers that contain a large amount of cultured fermented bacteria to overcome continuous cropping obstacles To do.

本願発明の油粕の処理設備は、
食用油の油粕と水とが供給されて油粕スラリーを生成するスラリー生成手段と、
筒状容器内の複数の筒状壁の間に形成された環状流路内に水が高圧ポンプによって供給されて高速水流が発生されると共に上記スラリー生成手段からポンプによって供給される油粕スラリーを環状流路において、高速水流の流れ方向変更部での衝撃作用、筒状壁近傍の剪断作用及び/又は水流中の空気によるキャビテーション作用によってスラリー中の油粕をミクロンレベルの粒子に微粉砕して排出する微粉砕手段と、
を有していることを特徴としている。
The processing equipment for oil scum of the present invention
A slurry generating means for supplying oil cake and water of edible oil to produce an oil cake slurry;
Water is supplied by a high-pressure pump into an annular channel formed between a plurality of cylindrical walls in the cylindrical container to generate a high-speed water flow, and at the same time, oil-slurry slurry supplied by the pump from the slurry generating means is annular. In the flow path, oil bubbles in the slurry are pulverized into micron-level particles and discharged by impact action at the flow direction changing portion of the high-speed water flow, shearing action near the cylindrical wall, and / or cavitation action by air in the water flow. Fine grinding means;
It is characterized by having.

更に、本油粕の処理設備は、発酵菌供給手段と、上記微粉砕手段から微粉砕された微細油粕粒子を含んだ微細油粕粒子含有水流の供給を受けると共に上記発酵菌供給手段から発酵菌の供給を受けて油粕粒子を発酵菌で処理する処理槽とを有することができる。   Furthermore, the processing equipment of the present oil cake receives the supply of fermenting bacteria from the fermenting bacteria supply means and the supply of the fermenting bacteria from the fermenting bacteria supply means while receiving the supply of the water stream containing fine oil cake particles containing the fine oil cake particles finely pulverized from the fine grinding means. And a treatment tank for treating the oil cake particles with the fermenting bacteria.

上記スラリー生成手段は、油粕と水とを重量比で約1:9の割合で混合してスラリーを生成できるように構成され、そのためにpH調節手段を有することできる。   The slurry generating means is configured to be able to generate slurry by mixing oil cake and water in a ratio of about 1: 9 by weight ratio, and may have pH adjusting means for that purpose.

上記発酵菌供給手段は、種菌を収容した種菌槽と、糖蜜栄養槽と、水クラスタを微粉砕する水微粉砕装置と、該水微粉砕装置から微細クラスタの水が供給されると共に上記種菌槽から発酵種菌が供給されると共に糖蜜栄養槽から糖蜜栄養が供給される培養槽とを有することできる。   The fermenting bacteria supply means includes an inoculum tank containing an inoculum, a molasses nutrient tank, a water pulverizer for pulverizing a water cluster, and water of the fine cluster is supplied from the water pulverizer, and the inoculum tank And a culture tank to which molasses nutrients are supplied from a molasses nutrient tank.

上記微粉砕手段は、略同心状に2層以上の円筒状壁を有し、隣り合う円筒状壁間に環状流路を設けた竪形の円筒状容器と、環状流路に接線方向に加圧流体を注入して円周方向の8m/秒以上の高速水流をつくって円筒状壁近傍の流体に対して剪断作用を発生させる噴出部と、上記隣り合ういずれかの円筒壁に配置して油粕スラリーを上記高速水流中に供給するスロットと、スロット部での衝撃作用や高速水流への混合時の剪断作用で油粕をミクロンレベルの粒子を含むまで微粉砕された微粉砕粒子を含む微細油粕粒子含有水流を排出する出口部とを有することできる。   The pulverizing means includes a cylindrical container having a cylindrical wall having two or more cylindrical walls substantially concentrically and provided with an annular channel between adjacent cylindrical walls, and a tangentially applied to the annular channel. A pressure fluid is injected to create a high-speed water flow of 8 m / second or more in the circumferential direction and generate a shearing action on the fluid in the vicinity of the cylindrical wall, and arranged on one of the adjacent cylindrical walls. A slot for supplying oil slurry into the high-speed water stream, and a fine oil tank containing finely pulverized particles obtained by pulverizing the oil tank to micron-level particles by impact action at the slot portion or shearing action when mixing into the high-speed water stream And an outlet for discharging the particle-containing water stream.

上記微粉砕手段は、高圧ポンプによる高速水流によるエゼクター効果で吸入した油粕スラリーと共に、三層の円筒壁によって三つに区画された環状流路の内の第二環状流路に8m/秒以上の混合高速水流を供給し、内円筒壁のスロットを経て又は内円筒壁の上端からの溢流で流入する内側の第三環状流路から別のポンプによって中間混合水流を吸入して出口部のある外側の第一環状流路に8m/秒以上の高速度で供給し、これまでの過程で微粉砕された油粕粒子を含む微細油粕粒子含有水流を出口部から排出するように構成される。   The finely pulverizing means includes oil slurries sucked by an ejector effect by a high-speed water flow by a high-pressure pump, and a second annular flow path of 8 m / second or more in an annular flow path divided into three by a three-layer cylindrical wall. Supplying mixed high-speed water flow, the intermediate mixed water flow is sucked by another pump from the inner third annular flow path which flows in through the slot of the inner cylindrical wall or by overflow from the upper end of the inner cylindrical wall, and has an outlet It is configured to supply the outer first annular flow path at a high speed of 8 m / second or more, and to discharge the water flow containing fine oil soot particles including the oil soot particles finely pulverized in the process so far from the outlet.

上記筒状壁は、楕円筒状、又は部分的に平坦な部分を有した円筒状を成すことができる。   The cylindrical wall can be an elliptic cylinder or a cylinder having a partially flat portion.

本発明の効果として、本願発明の食用油製造粕の処理設備では、スラリー生成手段によってペースト状の油粕がアルカリ性化学剤を利用した加水分解等でpH調節しながら水と混合され流動可能な油粕スラリーを生成でき、ポンプで微粉砕手段に供給される。微粉砕手段では、複数の筒状壁の間に形成された環状流路内で水が高圧ポンプで供給されて発生された8m/秒以上の高速水流にスラリー生成手段から油粕スラリーが供給され、高速水流の流れ方向変更部での衝撃作用、筒状壁近傍の剪断作用及び/又は水流中の空気によるキャビテーションによってスラリー中の油粕がミクロンレベルの粒子に微粉砕されることになる。このレベルまで油粕粒子が微粉砕されると大幅に単位表面積が大きくなり、例えば発酵菌を加えると油粕粒子に極めて多数の発酵菌が付着して棲息すると共に油粕粒子を摂取して増殖し、その発酵過程で大量の油粕粒子を炭酸ガスと熱等に効率的に分解消費する。因みに、半径が1mmの球状有機物の比表面積が0.00120m2 /gにすぎなかったものが、半径が0.0001mmの球状に微細化されているとすると、比表面積は12.0m2 /gと1万倍にも成り、従って1万倍の数の発酵菌が表面に付着することができて、発酵菌を効率的に極めて大量に培養することができる。従って、上述のように油粕が微粉砕されると微細油粕粒子含有水は、発酵菌の培養地として非常に有効であり、また大量の発酵菌が培養された状態の微細油粕粒子含有水は液体肥料としても利用され、含まれている発酵菌によって連作障害を緩和してくれる。土壌に重金属やヒ素類が含まれていても、極めて大量の発酵菌が増殖の過程で微量栄養源として発酵菌内に摂取され、人畜には無害な状態になる副次的効果を享受できる。 As an effect of the present invention, in the processing equipment for edible oil production lees according to the present invention, an oil lees slurry in which paste-like lees are mixed with water while the pH is adjusted by hydrolysis or the like using an alkaline chemical agent by the slurry generating means. And can be supplied to the pulverizing means by a pump. In the pulverizing means, the oil slurry is supplied from the slurry generating means to a high-speed water flow of 8 m / second or more generated by supplying water with a high-pressure pump in an annular flow path formed between a plurality of cylindrical walls, Oil bubbles in the slurry are finely pulverized into micron-level particles by impact action at the flow direction changing portion of the high-speed water stream, shearing action near the cylindrical wall, and / or cavitation by air in the water stream. When oil candy particles are finely pulverized to this level, the unit surface area is greatly increased.For example, if fermented bacteria are added, a large number of fermentation bacteria adhere to the oil candy particles and inhabit, and the oil candy particles are ingested and proliferated. A large amount of oil cake particles are efficiently decomposed and consumed by carbon dioxide and heat in the fermentation process. Incidentally, if the specific surface area of a spherical organic substance having a radius of 1 mm is only 0.00120 m 2 / g, but is refined into a spherical shape having a radius of 0.0001 mm, the specific surface area is 12.0 m 2 / g. Thus, 10,000 times as many fermenting bacteria can adhere to the surface, and the fermenting bacteria can be efficiently cultured in a very large amount. Therefore, when the oil cake is finely pulverized as described above, the fine oil cake particle-containing water is very effective as a culture site for fermentation bacteria, and the fine oil cake particle-containing water in a state where a large amount of fermentation bacteria are cultured is liquid. It is also used as a fertilizer and relieves continuous cropping problems by the contained fermentative bacteria. Even if heavy metals and arsenic are contained in the soil, a very large amount of fermenting bacteria can be taken into the fermenting bacteria as a micronutrient source in the process of growth and can enjoy the secondary effect of becoming harmless to human livestock.

更に、本食用油製造粕の処理設備が、発酵菌供給手段と、上記微粉砕手段から微粉砕された微細油粕粒子を含んだ微細油粕粒子含有水流の供給を受けると共に上記発酵菌供給手段から発酵菌の供給を受けて油粕粒子を発酵菌で処理する処理槽とを有すると、処理槽において上述のように大幅に単位表面積が大きくなった油粕粒子によって発酵菌を効率的に極めて大量に培養することができ、連作障害を緩和してくれる発酵菌を大量に含んだ液体肥料の他に、生ゴミ保管場所や処理場での悪臭防止剤や、汚泥やヘドロの処理剤や、家畜下水処理剤や、魚介類加工場の残渣処理剤や、飼料処理剤を生成できる。   Further, the processing equipment for the edible oil production mash receives the fermenting bacteria supply means and the fine oil candy particle-containing water stream containing the fine oil mash particles finely pulverized from the fine pulverization means and fermented from the fermenting bacteria supply means. When having a treatment tank that receives the supply of bacteria and treats the oil cake particles with fermentation bacteria, the fermentation bacteria are efficiently cultured in an extremely large amount by the oil cake particles whose unit surface area is greatly increased as described above in the treatment tank. In addition to liquid fertilizers that contain a large amount of fermenting bacteria that can alleviate continuous cropping problems, a foul odor prevention agent at a garbage storage place or treatment plant, a sludge or sludge treatment agent, a livestock sewage treatment agent In addition, it is possible to produce a residue treatment agent for a seafood processing plant and a feed treatment agent.

スラリー生成手段が、油粕と水とを重量比で約1:9の割合で混合してスラリーを生成するようにアルカリ性状態で加水分解するために重曹や炭酸ナトリウム等を供給するpH調節手段を有することで、pH調節手段から加えられる重曹や炭酸ナトリウムや苛性ソーダ等のpH調節剤によってペースト状の油分のある油粕でも約9倍の量の水に懸濁でき、流動性に富んだスラリーと生成することができる。   The slurry generating means has a pH adjusting means for supplying sodium bicarbonate, sodium carbonate, etc. to hydrolyze in an alkaline state so as to produce a slurry by mixing oil cake and water in a weight ratio of about 1: 9. By using a pH adjuster such as sodium bicarbonate, sodium carbonate, or caustic soda added from the pH adjusting means, even an oil cake with a paste-like oil content can be suspended in about 9 times the amount of water, resulting in a slurry with high fluidity. be able to.

発酵菌供給手段は、種菌を収容した種菌槽と、糖蜜栄養槽と、水クラスタを微粉砕する水微粉砕装置と、該水微粉砕装置から微細クラスタの水が供給されると共に上記種菌槽から発酵種菌が供給されると共に糖蜜栄養槽から糖蜜栄養が供給される培養槽とを有することでき、培養槽において種菌槽からの増殖能力に富んだ種菌を糖蜜栄養槽からの糖蜜を栄養にして水微粉砕装置からの微細クラスタの水で増殖力の旺盛な発酵菌を大量に培養できる。   The fermenting bacteria supply means includes an inoculum tank containing the inoculum, a molasses nutrient tank, a water pulverizer for pulverizing the water cluster, and water of the fine cluster is supplied from the water pulverizer, And a culture tank to which molasses nutrients are supplied from the molasses nutrient tank and fermented inoculum, and inoculate the inoculum with high growth ability from the inoculum tank with nutrient molasses from the molasses nutrient tank. A large amount of fermenting bacteria having a vigorous growth ability can be cultured with fine clusters of water from a pulverizer.

微粉砕手段では、略同心状に2層以上設けられた隣り合う円筒壁間に環状流路を形成し、この環状流路に噴出部から接線方向に加圧流体を注入して、例えば10m/秒以上の円周方向の高速水流をつくって円筒壁近傍の流体に対して剪断作用を発生させ、供給部からの油粕含有のスラリーをこの高速水流中でその剪断作用でミクロンレベルの粒子を大量に含むまで微粉砕して、連続的に微細油粕粒子を含む流体の出口部から排出することで、微粉砕粒子を含む微細油粕粒子含有水が発酵菌の優れた培養地として利用できると共に、発酵菌の添加によって微細油粕粒子含有水流の油粕粒子を短時間で効率的な分解消失処理でき、更に上述のように多様に利用される。   In the fine pulverizing means, an annular flow path is formed between adjacent cylindrical walls provided in two or more layers substantially concentrically, and a pressurized fluid is injected into the annular flow path in a tangential direction from the ejection portion, for example, 10 m / A high-speed water flow in the circumferential direction of more than a second is generated to generate a shearing action on the fluid near the cylindrical wall, and a slurry containing oil slag from the supply section is used to generate a large amount of micron-level particles in this high-speed water flow. By pulverizing until it is contained, and continuously discharging it from the outlet of the fluid containing fine oil particles, water containing fine oil particles containing finely pulverized particles can be used as an excellent culture site for fermentation bacteria, and fermentation By adding the fungus, the oil cake particles in the water stream containing the fine oil cake particles can be efficiently decomposed and eliminated in a short time, and further used in various ways as described above.

微粉砕手段では、高圧ポンプによる高速度水流によるエゼクター効果で吸入した油粕スラリーと共に、三層の円筒壁によって三つに区画された環状流路の内の第二環状流路に混合高速度水流が供給され、内円筒壁のスロットを経て又は内円筒壁の上端からの溢流で流内側の第三環状流路に流入されるとスロット部の流れ方向変更部での衝撃作用や溢流による滝壷効果、即ち大きな衝撃作用で油粕粒子が微粉砕される。これは、高圧ポンプによるによる押し込みと別のポンプによる吸引による相乗作用で大きな衝撃力が発生される。その後に別のポンプによって更に中間混合水流が吸入されて出口部のある外側の第一環状流路に高速度で供給されて剪断作用を受け、これらの過程で微粉砕された油粕粒子を含む微細油粕粒子含有水流が出口部から排出される。微細油粕粒子含有水は発酵菌の優れた培養地として利用され、発酵菌の添加によって微細油粕粒子含有水は、その油粕粒子が短時間で効率的な分解消失され、更に上述のように多様に利用される。   In the pulverizing means, the mixed high-speed water flow is fed into the second annular flow channel of the annular flow channel divided into three by the three-layered cylindrical wall, together with the oil cake slurry sucked by the ejector effect by the high-speed water flow by the high-pressure pump. When supplied to the third annular flow channel inside the flow through the slot of the inner cylindrical wall or by overflow from the upper end of the inner cylindrical wall, impact action at the flow direction change portion of the slot portion or waterfall caused by overflow The oil slag particles are finely pulverized by an effect, that is, a large impact. This is because a large impact force is generated by a synergistic action by pushing by a high-pressure pump and suction by another pump. Thereafter, the intermediate mixed water flow is further sucked in by another pump and supplied at high speed to the outer first annular flow path having the outlet portion, subjected to a shearing action, and finely containing finely pulverized oil cake particles in these processes. Oil stream containing water is discharged from the outlet. Water containing fine oil cake particles is used as an excellent culture site for fermenting bacteria, and by adding fermentative bacteria, water containing fine oil cake particles is efficiently decomposed and disappeared in a short time. Used.

筒状壁が楕円筒状や部分的に平坦な部分を有した円筒状を成すと、それら非円形部分において高圧ポンプによって発生された高速度水流は更に大きな衝撃作用と剪断作用を起こして水流中の油粕粒子を微粉砕できる。   If the cylindrical wall has an elliptical cylindrical shape or a cylindrical shape with a partly flat part, the high-speed water flow generated by the high-pressure pump in these non-circular parts causes a larger impact and shearing action, causing Can be finely pulverized.

次に、本発明の代表的な実施形態に係る食用油製造粕の処理設備を図面によって説明する。
図1において、本発明の代表的な実施形態の食用油製造粕の処理設備1は、発酵菌供給装置10と、搾油機5からの油粕Aをスラリー化するスラリー生成装置20と、スラリー生成装置20からの油粕スラリーS中の油粕粒子を微粉砕する微粉砕装置30と、微粉砕装置30から微細油粕粒子含有水流S’の供給を、発酵菌供給装置10から大量の発酵菌Fの供給をそれぞれ受けて発酵処理する処理装置50とから構成されている。微粉砕装置30からの微細油粕粒子含有水流は、発酵培地として出荷可能である。処理装置50からの大量に培養された発酵菌を含んだ処理液S”は、連作障害を緩和してくれる液体肥料、生ゴミ保管場所や処理場での悪臭防止剤、汚泥やヘドロの処理剤、家畜下水処理剤、魚介類加工場の残渣処理剤、飼料処理剤として、グリーストラップ、レンダリング等に使用される。
Next, a processing facility for cooking oil production tanks according to representative embodiments of the present invention will be described with reference to the drawings.
In FIG. 1, the processing equipment 1 of the edible oil production tank of typical embodiment of this invention is the fermenting microbe supply apparatus 10, the slurry production | generation apparatus 20 which slurries the oil cake A from the oil press 5, and the slurry production | generation apparatus. The fine pulverizer 30 for finely pulverizing the oil pod particles in the oil pulverized slurry S 20, the supply of the fine oil pod particle-containing water stream S ′ from the fine pulverizer 30, and the supply of a large amount of fermenting bacteria F from the fermenter supply apparatus 10 It is comprised from the processing apparatus 50 which each receives and ferments. The fine oil cake particle-containing water stream from the pulverizer 30 can be shipped as a fermentation medium. The processing liquid S ”containing fermented bacteria cultured in large quantities from the processing apparatus 50 is a liquid fertilizer that alleviates continuous cropping obstacles, an anti-odor agent at a garbage storage place or processing plant, a sludge or sludge processing agent. It is used for grease traps, rendering, etc., as a livestock sewage treatment agent, a residue treatment agent for seafood processing plants, and a feed treatment agent.

発酵菌供給装置10は、現地で採取されたラクトバチルス菌などの発酵菌種を収容した種菌槽11と、糖蜜を含む栄養物を収容した糖蜜栄養槽12と、供給される上水wの水クラスターを高圧水中ポンプP0で発生される8m/秒以上の、好ましくは20〜30m/秒の高速水流による衝撃作用と剪断作用とによって微粉砕する水微粉砕装置13(ポンプP0は該装置13から水を吸引する)と、該水微粉砕装置13から処理水が供給されると共に種菌槽11から発酵菌種を、糖蜜栄養槽12から糖蜜栄養分をそれぞれ供給されて発酵菌を大量に培養する培養槽14とから構成されている。水微粉砕装置13は、後述の微粉砕装置30と同じ原理で流れ方向変更部での衝撃作用と筒状壁部での水流速度差による剪断作用と気泡破裂の超音波とによって水のクラスタを微細化するものである。培養槽14内では、供給されたクラスタの微細化された水が、発酵菌や糖蜜栄養分のキメ細かな分散を促して増殖力の旺盛な発酵菌の大量培養を可能にする。   The fermenting fungus supply device 10 includes an inoculum tank 11 containing fermented bacterial species such as Lactobacillus collected locally, a molasses nutrient tank 12 containing a nutrient containing molasses, and water of the supplied water w A water pulverizing device 13 (pump P0 is supplied from the device 13) that pulverizes the cluster by impact action and shear action by a high-speed water flow of 8 m / second or more, preferably 20 to 30 m / second, generated by the high-pressure submersible pump P0. When water is sucked), treated water is supplied from the water pulverizer 13 and fermented bacterial species are supplied from the inoculum tank 11 and molasses nutrients are supplied from the molasses nutrient tank 12 to culture a large amount of fermented bacteria. The tank 14 is constituted. The water pulverizing device 13 forms a cluster of water by an impact action at the flow direction changing portion, a shearing action due to a difference in water flow velocity at the cylindrical wall portion, and ultrasonic waves of bubble rupture based on the same principle as the pulverizing device 30 described later. It is to be miniaturized. In the culture tank 14, the fine water of the supplied clusters facilitates fine dispersion of the fermenting bacteria and molasses nutrients, and enables mass cultivation of fermenting bacteria with a strong growth potential.

発酵菌Fとしては、ラクトバチルス菌などの乳酸菌や酵母菌や酪酸菌や納豆菌が一般的に知られている。ラクトバチルス菌などの発酵菌種は、油粕の処理現場や発酵菌の培養現場で採取されたものが、その現場での気候風土で生存してきたもので好ましく、細菌生存圏にできるだけ余計な摩擦をもたらさないようにして存分に効力を発揮できる丈夫な発酵菌種を得ることができる。また培養槽14には、共生関係を取る光合成菌が添加されると、互いに必要とする物質を供給しあって培養を早めてくれるほか、光合成菌は腐敗菌が発生させる悪臭物質を栄養源として摂取してくれ、次に説明するように発酵菌が増殖力を高める。即ち、光合成菌は、アミノ酸やミネラルやビタミン等の優れた栄養分に富んでいて菌体自身が有機肥料としても有用であるが、腐敗物に会うと硫酸還元菌が発生させる硫化水素を栄養源として積極的に摂取するばかりでなく、有毒アミンであるプトレシンやカタベリン、また発癌催奇性のジメチルニトロサミンも好んで基質として摂取して分解除去してくれる。   As the fermenting bacteria F, lactic acid bacteria such as Lactobacillus, yeasts, butyric acid bacteria, and natto bacteria are generally known. Fermented bacterial species such as Lactobacillus are preferably collected at the site of oil lees and at the culture site of the fermented bacteria and have survived in the climate of the site. It is possible to obtain a robust fermented bacterial species that can fully exert its effect without causing any effects. In addition, when photosynthetic bacteria having a symbiotic relationship are added to the culture tank 14, the necessary substances are supplied to each other and the culture is accelerated, and the photosynthetic bacteria use malodorous substances generated by spoilage bacteria as nutrients. Take it and fermented bacteria will increase the growth potential as explained below. In other words, photosynthetic bacteria are rich in excellent nutrients such as amino acids, minerals, and vitamins, and the cells themselves are useful as organic fertilizers, but when they encounter septic substances, hydrogen sulfide generated by sulfate-reducing bacteria is used as a nutrient source. In addition to active intake, toxic amines such as putrescine and cataverine and carcinogenic teratogenic dimethylnitrosamine are also preferred as a substrate and decomposed and removed.

スラリー生成装置20では、搾油機5から油を絞った粕として供給される、例えば大豆粕等の油粕Aは、重量比で約1:9の割合で水Wと混合されると共に、pHが10前後のアルカリ性状態で加水分解するために、また低pHの油粕の場合には必要に応じて重曹や炭酸ナトリウムや苛性ソーダ等のpH調節剤BがpH調節装置6からスラリー生成装置20に供給されて撹拌混合され、ペースト状の油分のある油粕でも約9倍の量の水Wに懸濁され、流動性に富んだ弱アルカリ性のスラリーSが生成される。スラリーSは、その中の油粕粒子がミクロンレベルまで微粉砕されるようにポンプP1によって微粉砕装置30に供給される。   In the slurry production apparatus 20, the oil cake A such as soybean meal supplied from the oil press 5 as oiled rice cake is mixed with the water W at a ratio of about 1: 9 by weight, and the pH is 10 In order to hydrolyze in the alkaline state before and after, and in the case of low pH oil cake, a pH adjuster B such as sodium bicarbonate, sodium carbonate or caustic soda is supplied from the pH adjuster 6 to the slurry generator 20 as necessary. Even if the oil cake with a paste-like oil content is stirred and mixed, it is suspended in about 9 times as much water W, and a weakly alkaline slurry S rich in fluidity is produced. The slurry S is supplied to the pulverizing apparatus 30 by the pump P1 so that the oil slag particles therein are pulverized to the micron level.

第一実施例の微粉砕装置30は、例えば図3(A)と図3(B)に示すように、中空円筒容器32を天板32aと底板32bと周囲壁32cとから形成し、内部に円筒内壁33cを同心状に設けて外側の環状流路33と内腔室34とを形成している。周囲壁32cの底板32bの近くに噴出管31aの吐出口部31bを接線方向から内部に向けて取り付け、高圧ポンプP3から供給される水流によって環状流路33内で循環する、例えば約8m/秒以上の、好ましくは20〜30m/秒の高速水流H1を発生させる。微粒化すべき上水w(水微粉砕装置13の場合)やスラリーSを高速水流H1に略直角に衝突させるために、円筒内壁33cに縦長のスロット33dを複数形成すると共に上水やスラリーの給管35を内腔室34に開口するように天板32aに取り付けて、上水wやスラリーSを内腔室34を経て縦長のスロット33dから環状流路33へ供給するようにしている。スロット33dから出た処の混合領域Mで、上水wのクラスタやスラリーSの油粕粒子を方向変化による衝撃作用と、高速水流H1と円筒内壁33cの外面や周囲壁32cの内面に沿った付着水との大きな速度差による剪断作用と、水中の空気のキャビテーション作用とによって1〜10μmまで微粒化する。水噴出管31aからの水流に気泡を混入する気泡発生器を水噴出管31aに付設してもよい。クラスタが微細化された上水w’や油粕粒子が微粉砕された微細粒子含有水流S’は、排出管36(必要に応じて複数個所に設けられる)から排出される。高圧ポンプP3は、別の排出管37から吸入して水を循環するようにしている。このように微粉砕された微細油粕粒子の場合は、例えば微粉砕前に半径が1mmの球状物の比表面積が0.00120m2 /gにすぎなかったものが、半径が0.0001mmの球状に微粉砕されると、比表面積は12.0m2 /gと1万倍にも成り、従って1万倍の数の発酵菌が表面に付着することができて、発酵菌の優れた培養地U1として利用できると共に、処理装置50において発酵菌を効率的に大量に培養したり、油粕粒子を短時間で効率的な分解消失処理でき、更に処理液S”は上述のように多様に利用される。 For example, as shown in FIGS. 3 (A) and 3 (B), the pulverizing apparatus 30 of the first embodiment forms a hollow cylindrical container 32 from a top plate 32a, a bottom plate 32b, and a peripheral wall 32c. A cylindrical inner wall 33 c is provided concentrically to form an outer annular flow path 33 and a lumen chamber 34. The discharge port 31b of the ejection pipe 31a is attached from the tangential direction to the inside near the bottom plate 32b of the peripheral wall 32c, and circulates in the annular flow path 33 by the water flow supplied from the high-pressure pump P3, for example, about 8 m / sec. The above high speed water flow H1 of preferably 20 to 30 m / sec is generated. In order to make the water w to be atomized (in the case of the water pulverizer 13) and the slurry S collide with the high-speed water flow H1 at a substantially right angle, a plurality of elongated slots 33d are formed in the cylindrical inner wall 33c and the supply of the water or slurry is performed. The pipe 35 is attached to the top plate 32 a so as to open to the lumen chamber 34, and the clean water w and the slurry S are supplied to the annular flow path 33 from the vertically long slot 33 d via the lumen chamber 34. In the mixing region M at the place where it exits from the slot 33d, the impact action caused by the direction change of the cluster of the clean water w and the oil spilled particles of the slurry S, and the high-speed water flow H1 adhere along the outer surface of the cylindrical inner wall 33c and the inner surface of the peripheral wall 32c It atomizes to 1-10 micrometers by the shearing effect by the big speed difference with water, and the cavitation effect | action of the air in water. A bubble generator that mixes bubbles into the water flow from the water ejection pipe 31a may be attached to the water ejection pipe 31a. The fine water-containing water flow S ′ and the fine particle-containing water flow S ′ in which the oil slag particles are finely pulverized are discharged from the discharge pipes 36 (provided at a plurality of places as necessary). The high-pressure pump P3 sucks in through another discharge pipe 37 and circulates water. In the case of finely pulverized fine soot particles, for example, the specific surface area of a sphere having a radius of 1 mm before pulverization was only 0.00120 m 2 / g, but the sphere having a radius of 0.0001 mm was obtained. When finely pulverized, the specific surface area is 12.0 m 2 / g, which is 10,000 times larger. Therefore, 10,000 times the number of fermentation bacteria can adhere to the surface, and the excellent culture site U1 for fermentation bacteria In addition, the processing apparatus 50 can efficiently culture a large amount of fermenting bacteria, and can efficiently decompose and eliminate the oil cake particles in a short time, and the processing solution S ″ can be used in various ways as described above. .

図2と図4に示す第二実施例の微粉砕装置40は、天板42aと底板42b、42cとによって上下が塞がれた容器43の三層の円筒壁43a、43b、43c(第三円筒壁43cのみ天板42aに対して隙間を取っている)によって三つに区画された環状流路の内の中間の第二環状流路44bに油粕スラリーSと共に水をポンプP4によって8m/秒以上の、好ましくは20〜30m/秒の高速水流H2で供給し、第三円筒内壁43cの上端からの溢流で強烈に落下して流入する(流れ方向変更部を構成)内側中央の第三環状流路44cの底から配管46を介して別のポンプP5によって中間処理の微細油粕粒子含有の混合水流を吸入して出口部(配管48を介して処理装置50に接続されている)のある外側の第一環状流路44aに8m/秒以上の、好ましくは20〜30m/秒の高速水流H2’で供給するようにしており、衝撃作用と剪断作用とが繰り返し加えられる。第二と第三の円筒壁43b、43cに第一実施例のスロット33dやスリットを形成することもできる。高速水流H2へのスラリーSの取り込みは、高圧ポンプP4が配管47を介して第一環状流路44aから吸引して吐出した高速水流を利用したエゼクター部41で行われ、吸入した油粕スラリーSと共に混合高速水流H2が第二環状流路44bに供給される。円筒壁43cにスロットを設けた場合はスロットを経て、又は内円筒壁42cの上端からの溢流で内側の第三環状流路44cに流入されるとスロット部の流れ方向変更部での衝撃作用や溢流による滝壷効果、即ち大きな衝撃作用で油粕粒子が微粉砕される。これは、高圧ポンプP4によるによる押し込みと別のポンプP5による吸引による相乗作用で大きな衝撃力が発生される。微細油粕粒子含有水S’は上述のように優れた培養地として利用され、発酵菌が添加されて増殖した発酵微細油粕粒子含有水である処理水S”は、その油粕粒子が短時間で効率的な分解消失され、更に上述のように多様に利用される。   The pulverizing apparatus 40 of the second embodiment shown in FIGS. 2 and 4 has three layers of cylindrical walls 43a, 43b, 43c (third) of a container 43 whose top and bottom are closed by a top plate 42a and bottom plates 42b, 42c. Only the cylindrical wall 43c has a gap with respect to the top plate 42a), and water is fed into the second annular channel 44b in the middle of the annular channel divided into three by the pump P4 at 8 m / sec. The above-mentioned, preferably 20 to 30 m / second high-speed water flow H2 is supplied, and the third cylinder at the center of the inner side falls into and flows in strongly due to the overflow from the upper end of the third cylindrical inner wall 43c (constitutes the flow direction changing portion). There is an outlet portion (connected to the processing device 50 via the pipe 48) by sucking the mixed water stream containing fine oil soot particles for intermediate processing from the bottom of the annular flow path 44c via the pipe 46 by another pump P5. 8m in the outer first annular channel 44a Above seconds, preferably is then supplied at a high speed water flow H2 'of 20 to 30 m / sec, it is repeatedly applied and impact action and shearing action. The slots 33d and slits of the first embodiment can be formed in the second and third cylindrical walls 43b and 43c. The intake of the slurry S into the high-speed water flow H2 is performed by the ejector section 41 using the high-speed water flow sucked and discharged from the first annular flow path 44a through the pipe 47 by the high-pressure pump P4. The mixed high-speed water flow H2 is supplied to the second annular flow path 44b. When a slot is provided in the cylindrical wall 43c, if it flows into the inner third annular flow path 44c through the slot or by overflow from the upper end of the inner cylindrical wall 42c, the impact action at the flow direction change portion of the slot portion Oilfall particles are finely pulverized by the waterfall effect caused by the overflow and the large impact. This is because a large impact force is generated by the synergistic action of the pushing by the high pressure pump P4 and the suction by the other pump P5. The fine oil lees particle-containing water S ′ is used as an excellent culture site as described above, and the treated water S ″, which is fermented fine oil lees particle-containing water that has been proliferated with the addition of fermentative bacteria, is effective in a short time. It can be used for various purposes as described above.

筒状壁32c、33c、43a、43b、43cが、円筒形状以外に楕円筒状や部分的に平坦な部分を有した円筒状を成すと、それら非円形部分において高圧ポンプによって発生された高速水流は更に大きな衝撃作用と剪断作用を起こして水流中の油粕粒子を効果的に微粉砕できる。   When the cylindrical walls 32c, 33c, 43a, 43b, and 43c have an elliptical cylinder shape or a cylindrical shape having a partially flat portion in addition to the cylindrical shape, high-speed water flow generated by the high-pressure pump in these non-circular portions Can cause fine impact and shearing action to effectively finely pulverize the oil cake particles in the water stream.

処理装置50は、微粉砕装置から微粉砕された微細油粕粒子を含んだ微細油粕粒子含有水流S”の供給を受けると共に発酵菌供給装置10から大量の発酵菌の供給を受けて油粕粒子を発酵菌Fの増殖の餌として消費処理して炭酸ガスと熱に転換する他に、更に増えた大量の発酵菌を含んだ処理液S”は、連作障害を緩和してくれる液体肥料、生ゴミ保管場所や処理場等での悪臭防止剤、汚泥やヘドロの処理剤、家畜下水処理剤、魚介類加工場の残渣処理剤、飼料処理剤等として、またグリーストラップやレンダリング等に使用される。   The processing device 50 receives the supply of the fine oil cake particle-containing water stream S ″ containing the fine oil cake particles finely pulverized from the fine grinding device, and also receives the supply of a large amount of fermentation bacteria from the fermenting fungus supply device 10 to ferment the oil cake particles. In addition to converting to carbon dioxide and heat as consumption food for the growth of fungus F, the treatment liquid S ”containing a larger amount of fermented bacteria is a liquid fertilizer and raw garbage storage that alleviates continuous cropping problems. It is used as a foul odor prevention agent in places and treatment plants, sludge and sludge treatment agents, livestock sewage treatment agents, residue treatment agents in seafood processing plants, feed treatment agents, etc., and in grease traps and rendering.

本発明の代表的な実施形態の油粕の処理設備を示した説明図。Explanatory drawing which showed the processing equipment of the oil bottle of typical embodiment of this invention. 同設備の第二実施例の微粉砕装置の概略説明図。The schematic explanatory drawing of the pulverization apparatus of the 2nd Example of the installation. 同設備の第一実施例の微粉砕装置を示しており、(A)は一部切り欠き平面図、(B)は一部切り欠き立面図。The fine crushing apparatus of the 1st Example of the installation is shown, (A) is a partially cutaway top view, (B) is a partially cutaway elevation view. 同設備の第二実施例の微粉砕装置の一部切り欠き立面図。The partially cutaway elevation view of the pulverizing apparatus of the second embodiment of the same equipment.

符号の説明Explanation of symbols

1: 油粕の処理設備
6:pH調節手段
10:発酵菌供給手段
11:種菌槽
12:糖蜜栄養槽
13:水微粉砕装置
15:発酵菌培養槽
20:スラリー生成手段
30:微粉砕手段
32:筒状容器
32c、33c:筒状壁
33:環状流路
40:微粉砕手段
41:エゼクター手段
43:筒状容器
43a、43b、43c:筒状壁
44a:第一環状流路
44b:第二環状流路
44c:第三環状流路
50:処理装置
A:油粕
B:pH調節剤
F:発酵菌
H1:高速水流
H2:混合高速水流
P3:高圧ポンプ
P4:高圧ポンプ
P5:別のポンプ
S:油粕スラリー
S’:微細油粕粒子含有水流
W:水
1: Oil tank treatment equipment 6: pH adjusting means 10: Fermentation bacteria supply means 11: Inoculum tank 12: Molasses nutrient tank 13: Water fine grinding device 15: Fermentation fungus culture tank 20: Slurry producing means 30: Fine grinding means 32: Cylindrical containers 32c and 33c: Cylindrical wall 33: Annular channel 40: Fine grinding means 41: Ejector means 43: Cylindrical containers 43a, 43b, 43c: Cylindrical wall 44a: First annular channel 44b: Second annular Channel 44c: Third annular channel 50: Processing device A: Oil bottle B: pH regulator F: Fermentation bacteria H1: High-speed water stream H2: Mixed high-speed water stream P3: High-pressure pump P4: High-pressure pump P5: Another pump S: Oil tank Slurry S ': Water flow containing fine oil soot particles W: Water

Claims (8)

食用油の油粕と水とが供給されて油粕スラリーを生成するスラリー生成手段と、
筒状容器内の複数の筒状壁の間に形成された環状流路内に水が高圧ポンプによって供給されて高速水流が発生されると共に上記スラリー生成手段からポンプによって供給される油粕スラリーを環状流路において、高速水流の流れ方向変更部での衝撃作用、筒状壁近傍の剪断作用及び/又は水流中の空気によるキャビテーション作用によってスラリー中の油粕をミクロンレベルの粒子に微粉砕して排出する微粉砕手段と、
を有していることを特徴とする食用油製造粕の処理設備。
A slurry generating means for supplying oil cake and water of edible oil to produce an oil cake slurry;
Water is supplied by a high-pressure pump into an annular channel formed between a plurality of cylindrical walls in the cylindrical container to generate a high-speed water flow, and at the same time, oil-slurry slurry supplied by the pump from the slurry generating means is annular. In the flow path, oil bubbles in the slurry are pulverized into micron-level particles and discharged by impact action at the flow direction changing portion of the high-speed water flow, shearing action near the cylindrical wall, and / or cavitation action by air in the water flow. Fine grinding means;
A processing facility for cooking oil production tanks.
更に、発酵菌供給手段と、
上記微粉砕手段から微粉砕された微細油粕粒子を含んだ微細油粕粒子含有水流の供給を受けると共に上記発酵菌供給手段から発酵菌の供給を受けて油粕粒子を発酵菌で処理する処理手段とを有している請求項1記載の設備。
Furthermore, fermenting bacteria supply means,
A processing means for receiving the supply of the fine oil cake particle-containing water stream containing the fine oil cake particles finely pulverized from the fine pulverization means and receiving the supply of the fermentation bacteria from the fermentation bacteria supply means to treat the oil cake particles with the fermentation bacteria. The equipment according to claim 1.
上記スラリー生成手段は、油粕と水とを重量比で約1:9の割合で混合してスラリーを生成する請求項1記載の設備。   The equipment according to claim 1, wherein the slurry generating means mixes oil slag and water at a weight ratio of about 1: 9 to generate a slurry. 上記スラリー生成手段は、pH調節手段を有している請求項1又は3記載の設備。   The equipment according to claim 1 or 3, wherein the slurry generating means has pH adjusting means. 上記発酵菌供給手段は、種菌を収容した種菌槽と、糖蜜栄養槽と、水クラスタを微粉砕する水微粉砕装置と、該水微粉砕装置から微細クラスタの水が供給されると共に上記種菌槽から発酵種菌が供給されると共に糖蜜栄養槽から糖蜜栄養が供給される培養槽とを有している請求項2記載の設備。   The fermenting bacteria supply means includes an inoculum tank containing an inoculum, a molasses nutrient tank, a water pulverizer for pulverizing a water cluster, and water of the fine cluster is supplied from the water pulverizer, and the inoculum tank The apparatus according to claim 2, further comprising a culture tank that is supplied with fermentation inoculum and is supplied with molasses nutrients from a molasses nutrient tank. 上記微粉砕手段は、略同心状に2層以上の円筒状壁を有し、隣り合う円筒状壁間に環状流路を設けた竪形の円筒状容器と、環状流路に接線方向に加圧流体を注入して円周方向の高速水流をつくって円筒状壁近傍の流体に対して剪断作用を発生させる噴出部と、上記隣り合ういずれかの円筒壁に配置して油粕スラリーを上記高速水流中に供給するスロットと、スロット部での衝撃作用や高速水流への混合時の剪断作用で油粕をミクロンレベルの粒子を含むまで微粉砕された微粉砕粒子を含む微細油粕粒子含有水流を排出する出口部とを有している請求項1記載の設備。   The pulverizing means includes a cylindrical container having a cylindrical wall having two or more cylindrical walls substantially concentrically and provided with an annular channel between adjacent cylindrical walls, and a tangentially applied to the annular channel. Injecting pressurized fluid to create a high-speed water flow in the circumferential direction and generating a shearing action on the fluid near the cylindrical wall, and placing it on any one of the adjacent cylindrical walls, Discharges the water stream containing fine oil particles including finely pulverized particles that are finely pulverized until they contain micron-level particles by the slot supplied into the water flow and the impact action at the slot and shearing action when mixing into the high-speed water flow The facility according to claim 1, further comprising an outlet portion. 上記微粉砕手段は、エゼクター部で高圧ポンプによる高速水流によるエゼクター作用で吸入した油粕スラリーと共に、三層の円筒壁によって三つに区画された環状流路の内の第二環状流路に混合高速水流を供給し、内円筒壁のスロットを経て又は内円筒壁の上端からの溢流で流入する内側の第三環状流路から別のポンプによって中間の混合水流を吸入して出口部のある外側の第一環状流路に高速度で供給し、これまでの過程で微粉砕された油粕粒子を含む微細油粕粒子含有水流を出口部から排出するようにしている請求項1記載の設備。   The above fine pulverizing means is mixed with the second annular flow channel of the annular flow channel divided into three by the three-layer cylindrical wall together with the oil sludge slurry sucked by the ejector action by the high speed water flow by the high pressure pump in the ejector part. Supply the water flow and suck the intermediate mixed water flow by another pump from the inner third annular flow path which flows in through the slot of the inner cylindrical wall or by overflow from the upper end of the inner cylindrical wall, and the outer side with the outlet part The equipment according to claim 1, wherein the first annular flow path is supplied at a high speed, and the fine oil soot particle-containing water stream containing the oil soot particles finely pulverized in the process so far is discharged from the outlet portion. 上記筒状壁は、楕円筒状、又は部分的に平坦な部分を有した円筒状を成している請求項1記載の設備。

The said cylindrical wall is the installation of Claim 1 which has comprised the cylindrical shape which has an elliptical cylinder shape or a partially flat part.

JP2004157670A 2004-05-27 2004-05-27 Equipment for treating oil cake Pending JP2005334779A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005334778A (en) * 2004-05-27 2005-12-08 Miike Iron Works Co Ltd Method and equipment for fermenting organic waste

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005334778A (en) * 2004-05-27 2005-12-08 Miike Iron Works Co Ltd Method and equipment for fermenting organic waste
JP4515825B2 (en) * 2004-05-27 2010-08-04 株式会社御池鐵工所 Fermentation treatment method for organic waste and its treatment equipment

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