JP2005314292A - Microbicide and fertilizer for hydroponics, and apparatus for hydroponics using the same - Google Patents

Microbicide and fertilizer for hydroponics, and apparatus for hydroponics using the same Download PDF

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JP2005314292A
JP2005314292A JP2004134241A JP2004134241A JP2005314292A JP 2005314292 A JP2005314292 A JP 2005314292A JP 2004134241 A JP2004134241 A JP 2004134241A JP 2004134241 A JP2004134241 A JP 2004134241A JP 2005314292 A JP2005314292 A JP 2005314292A
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nutrient solution
soluble glass
glass
cultivation
mass
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JP4525157B2 (en
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Noriyuki Yamamoto
則幸 山本
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Toagosei Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/062Glass compositions containing silica with less than 40% silica by weight
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/062Glass compositions containing silica with less than 40% silica by weight
    • C03C3/064Glass compositions containing silica with less than 40% silica by weight containing boron
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/062Glass compositions containing silica with less than 40% silica by weight
    • C03C3/064Glass compositions containing silica with less than 40% silica by weight containing boron
    • C03C3/066Glass compositions containing silica with less than 40% silica by weight containing boron containing zinc
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/076Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/078Glass compositions containing silica with 40% to 90% silica, by weight containing an oxide of a divalent metal, e.g. an oxide of zinc
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/076Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/089Glass compositions containing silica with 40% to 90% silica, by weight containing boron
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/076Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/097Glass compositions containing silica with 40% to 90% silica, by weight containing phosphorus, niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D9/00Other inorganic fertilisers
    • C05D9/02Other inorganic fertilisers containing trace elements
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/20Liquid fertilisers
    • C05G5/23Solutions

Abstract

<P>PROBLEM TO BE SOLVED: To establish a method for sterilizing a nutritious liquid at a low cost, facilitating the management thereof and having high sterilizing effects; to provide a sterilizing apparatus in hydroponics of a plant using the method, and a method for the hydroponics; and to provide a method for continuously feeding a silicate ion sterilizing the nutritious liquid and capable of imparting resistivity against the infection with diseases such as mildew to the plant. <P>SOLUTION: The nutritious liquid-sterilizing agent comprises a soluble glass containing 15-60% SiO<SB>2</SB>, 10-40% K<SB>2</SB>O, 0.1-5% Ag<SB>2</SB>O, and 10-50% P<SB>2</SB>O<SB>5</SB>and/or 5-50% B<SB>2</SB>O<SB>3</SB>by mass proportions expressed in terms of oxides. The soluble glass may further contain ≤15% MgO, ≤35% CaO, ≤2% MnO<SB>2</SB>, ≤3% Fe<SB>2</SB>O<SB>3</SB>, ≤1% CuO, ≤1% ZnO and/or ≤1% MoO<SB>3</SB>. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、植物の養液栽培に関し、当該養液の殺菌および肥料に係わるものである。   The present invention relates to plant hydroponics and relates to sterilization of the nutrient solution and fertilizer.

植物の養液栽培は、土壌を使用せずに植物に必要な栄養成分を含む水溶液、すなわち養液を用いて作物を栽培する方法である。土壌栽培に比較して、成育が早い、収穫量が高い、および作物のバラツキが少ないといった利点がある。これまでの養液栽培は一度使用した養液をそのまま排出する所謂かけ流しという方法が主流であったが、排養液中に含まれる窒素分などの栄養分による河川や湖沼の富栄養化の問題から、養液を再使用する循環式養液栽培への変更が求められている。   Plant hydroponics is a method of cultivating crops using an aqueous solution containing nutrient components necessary for plants without using soil, that is, a nutrient solution. Compared to soil cultivation, there are advantages such as faster growth, higher yield, and less variation in crops. So far, nourishing liquid culture has been mainly the so-called pouring method that drains the used nutrient solution as it is, but the problem of eutrophication of rivers and lakes due to nutrients such as nitrogen contained in the nutrient solution Therefore, a change to circulation type hydroponics that reuses nutrient solution is required.

循環式養液栽培は、土壌伝染性の病害による汚染の機会は少ないが、その反面、土壌とは異なり、病原菌に対する拮抗菌も存在しないため、栽培ベッドや培養液循環系に一旦病原菌が混入すると養液の循環とともに被害は非常に大きいものとなる。   Circulation-type hydroponic cultivation has few opportunities for contamination due to soil-borne diseases. On the other hand, unlike soil, there are no antagonists against pathogenic bacteria, so once pathogenic bacteria are mixed into the cultivation bed or culture fluid circulation system. The damage will be very great with the circulation of nutrient solution.

一般に、養液中の病原菌は胞子、菌糸、遊走子の形で液中を伝播し、栽培中の植物の根から侵入し、根腐れ病などを引き起こす。特に、ピシウム菌、リゾクトニア菌、フザリウム菌などによる立ち枯れ病、萎凋病などは、ほとんどの作物が被害の対象となる。
そこで、養液の殺菌が求められ、農薬、紫外線、オゾン、加熱、ろ過、殺菌金属イオンなどによる殺菌や除菌が検討されている。
In general, pathogenic bacteria in nutrient solution propagate in the liquid in the form of spores, hyphae, and zoospores, invade from the roots of the plant being cultivated, and cause root rot. In particular, most crops are subject to damage, such as withering and wilt disease caused by Psium, Rhizoctonia, and Fusarium.
Therefore, sterilization of nutrient solution is required, and sterilization and sterilization using agricultural chemicals, ultraviolet rays, ozone, heating, filtration, sterilizing metal ions, and the like are being studied.

養液の殺菌に農薬を使用すると、残留農薬による人体に対する影響が懸念されるため好ましくない。また養液の殺菌に紫外線だけでは十分な効果が得られ難く、オゾンの場合は、オゾン発生装置などの維持管理が煩雑で、装置が高価であるなどの問題がある。養液の加熱による殺菌は、大量の養液を処理しなければならないため、コストと時間がかかる問題がある。養液の砂ろ過による方法は、ろ過機に住み着く拮抗微生物により発病が抑制されると考えられているが,これは制御したものではないため、方法が確立されていない。   Use of agricultural chemicals for sterilization of nutrient solution is not preferable because residual agricultural chemicals may affect the human body. In addition, it is difficult to obtain a sufficient effect only by ultraviolet rays for sterilization of nutrient solution, and in the case of ozone, there are problems such as complicated maintenance and management of an ozone generator and an expensive device. Sterilization by heating the nutrient solution has a problem of cost and time because a large amount of nutrient solution must be processed. The method of sand filtration of nutrient solution is thought to be controlled by antagonistic microorganisms that settle in the filter, but this is not controlled, so no method has been established.

新しい殺菌方法として銀イオンなどを添加する下記のような方法も提案されている。
抗菌性能をもつイオンを溶出する銀、銅、亜鉛およびそれらの金属化合物の少なくとも1つを抗菌イオン源とし、この抗菌イオン源を吸着担持する炭酸カルシウム、リン酸カルシウム、セラミックス材からなる担持体と、単結晶テトラポット状の三次元構造の酸化亜鉛ウイスカの三者を主体として配合した抗菌・防錆兼用剤を設置または混入した水耕栽培装置が報告されている(例えば、特許文献1参照)。
塩化錫などで処理した繊維品またはポリウレタンフォームを硝酸銀水溶液に浸漬して得た抗かび性および抗菌性付与材料を用いる水耕栽培における抗かび性および抗菌性付与材料が報告されている(例えば、特許文献2参照)。
銀添着活性炭を用いる循環式養液栽培装置用の殺菌装置が報告されている(例えば、特許文献3参照)。
銀ゼオライトを用いた養液栽培におけるピシウム根腐病の防除効果が報告されている(例えば、非特許文献1参照。)。
これらは効果が認められるものの、抗菌イオンの担持体を頻繁に交換してやる必要があり、管理が煩雑である。
The following method of adding silver ions or the like as a new sterilization method has also been proposed.
At least one of silver, copper, zinc, and their metal compounds that elute ions having antibacterial performance is used as an antibacterial ion source, and a carrier made of calcium carbonate, calcium phosphate, and ceramic material that adsorbs and carries this antibacterial ion source; There has been reported a hydroponic cultivation apparatus in which an antibacterial and rustproofing agent, which is mainly composed of three crystal tetrapot-shaped three-dimensional zinc oxide whiskers, is installed or mixed (see, for example, Patent Document 1).
Antifungal and antibacterial property-imparting materials in hydroponic cultivation using antifungal and antibacterial property-imparting materials obtained by immersing textiles or polyurethane foam treated with tin chloride in silver nitrate aqueous solution have been reported (for example, Patent Document 2).
A sterilization apparatus for circulation type hydroponic cultivation apparatus using silver impregnated activated carbon has been reported (for example, see Patent Document 3).
The effect of controlling Psium root rot in hydroponic cultivation using silver zeolite has been reported (for example, see Non-Patent Document 1).
Although these are effective, it is necessary to frequently replace the antibacterial ion carrier, and management is complicated.

○抗菌ガラス
銀イオンを含有する粒径が50μm以下の溶解性ガラス粉末を樹脂繊維素材中に練り込んだものが報告されている(例えば、特許文献4参照)。これは、繊維に抗菌性を付与するもので、養液栽培について開示も示唆もない。
Ag2Oを0.2〜5重量%、ZnOを1〜50重量%、P25を30〜80重量%、CaOを1〜20重量%、CeO2を0.1〜5重量%含有する溶解性ガラスが報告されている(例えば、特許文献5参照)。
また、B23を20〜50重量%、ZnOを50〜80重量%、アルカリ土類金属酸化物を10重量%以下、Ag2Oを2重量%含有する溶解性ガラスが報告されている(例えば、特許文献6参照)。
また、ZnOを50〜70モル%、B23および/またはP25を20〜50モル%、Al23およびZrO2より選ばれる少なくとも1種以上を0.5〜15モル%、アルカリ金属酸化物(Na2O)を5〜10モル%およびSiO2を0〜20モル%含有するものが報告されている(例えば、特許文献7参照)。
これらのものは、溶解性ガラスすなわち抗菌ガラスの配合組成のものであり、養液栽培について開示も示唆もない。
O Antibacterial glass The thing which knead | dissolved the soluble glass powder containing the silver ion in which the particle size is 50 micrometers or less in the resin fiber raw material is reported (for example, refer patent document 4). This imparts antibacterial properties to the fiber, and there is no disclosure or suggestion about hydroponics.
The Ag 2 O 0.2 to 5% by weight, ZnO of 1-50% by weight, P 2 O 5 30 to 80 wt%, the CaO 1 to 20% by weight, containing CeO 2 0.1 to 5 wt% A soluble glass has been reported (see, for example, Patent Document 5).
Further, a soluble glass containing 20 to 50% by weight of B 2 O 3 , 50 to 80% by weight of ZnO, 10% by weight or less of alkaline earth metal oxide, and 2% by weight of Ag 2 O has been reported. (For example, refer to Patent Document 6).
Further, the ZnO 50-70 mol%, B 2 O 3 and / or P 2 O 5 20 to 50 mol%, Al 2 O 3 and at least one or more chosen from ZrO 2 0.5 to 15 mol% , alkali metal oxide (Na 2 O) those 5-10 mol% and SiO 2 which contained 0-20 mole% have been reported (e.g., see Patent Document 7).
These are the compositions of soluble glass, that is, antibacterial glass, and there is no disclosure or suggestion about hydroponics.

25:20.4wt%、MgO:15.7wt%、CaO:30.0wt%、SiO2:26.3wt%の組成を有する溶成燐肥100重量部に酸化銀(Ag2O)、酸化銅(CuO)をそれぞれ所定量配合し、アルミナツボに入れて1400℃、10分間溶融後、融液を水中に流し込んで急冷した枸溶性ガラス粉末が報告されている(例えば、特許文献8参照)。そして、これの用途として土壌改良、農作物、芝生、植木、園芸用品の病害の予防又は抵抗性を付与するために散布することが記載されている。 Silver oxide (Ag 2 O) is added to 100 parts by weight of dissolved phosphorus fertilizer having a composition of P 2 O 5 : 20.4 wt%, MgO: 15.7 wt%, CaO: 30.0 wt%, SiO 2 : 26.3 wt%. , Copper oxide (CuO) is blended in a predetermined amount, melted at 1400 ° C. for 10 minutes in an alumina crucible, and then melted and poured into water to rapidly dissolve the glass (for example, Patent Document 8). reference). And as application of this, it is described that it is sprayed in order to impart soil prevention, crop prevention, lawn, planting, prevention of disease or resistance to gardening supplies.

稲は好ケイ酸植物であり、水稲に吸収されたケイ酸は稲体を強剛にする効果は古くからよく知られている。近年イチゴなどの野菜においてケイ酸イオンがうどんこ病などに感染しにくくなる効果があることが報告されている(例えば非特許文献2、非特許文献3参照)。
養液栽培においてケイ酸を含む肥料は知られていない(例えば非特許文献4参照)。
Rice is a silicic acid plant, and silicic acid absorbed by paddy rice has long been well known for its effect of making the rice body strong. In recent years, it has been reported that silicate ions are less likely to be infected with powdery mildew in vegetables such as strawberries (see, for example, Non-Patent Document 2 and Non-Patent Document 3).
Fertilizers containing silicic acid are not known in hydroponics (see, for example, Non-Patent Document 4).

○先行文献
特開平5−095739号公報(特許請求の範囲) 特開平7−203787号公報(特許請求の範囲) 特開平9−313055号公報(特許請求の範囲) 特開平3−124810号公報(特許請求の範囲) 特開2000−191339号公報(特許請求の範囲) 特開2000−281380号公報(特許請求の範囲) 特開2001−026438号公報(特許請求の範囲) 特開平07−206566号公報(特許請求の範囲、実施例) 草刈 眞一,外5名,「銀ゼオライトによる養液栽培におけるPythium根腐病の防除効果」,日本防菌防黴学会第29回年次大会,2002年5月30日,B−25 「ケイ酸カリウム水溶液施用によるイチゴうどんこ病の発生抑制技術」,ひょうごの農業技術,No.110,2000年7月 「イチゴうどんこ病抑制に有効なケイ酸カリ資材とその効果」,ひょうごの農業技術,No.116,2001年7月 大塚化学株式会社ホームページ、大塚ハウス肥料シリーズ<URL:http://www.tok.otsukac.co.jp/otsukac/agro/catalog_hiryo/index_h.html>
○ Prior literature
JP-A-5-095739 (Claims) JP-A-7-203787 (Claims) JP-A-9-313055 (Claims) Japanese Patent Laid-Open No. 3-124810 (Claims) JP 2000-191339 A (Claims) JP 2000-281380 A (Claims) Japanese Patent Laid-Open No. 2001-026438 (Claims) Japanese Patent Application Laid-Open No. 07-206566 (Claims and Examples) Seiichi Kusakari, 5 others, “Control effect of Pythium root rot in nutrient solution cultivation with silver zeolite”, 29th Annual Meeting of the Japan Society for Antimicrobial Prevention, May 30, 2002, B-25 “Suppression of strawberry powdery mildew by applying potassium silicate aqueous solution”, Hyogo Agricultural Technology, No. 110, July 2000 “Effective Potassium Silicate and its Effect on Strawberry Powdery Mildew Suppression”, Hyogo Agricultural Technology, No. 116, July 2001 Otsuka Chemical Co., Ltd. website, Otsuka House Fertilizer Series <URL: http://www.tok.otsukac.co.jp/otsukac/agro/catalog_hiryo/index_h.html>

本発明は、低コストで管理が容易な、しかも殺菌効果の高い養液殺菌方法の確立と、当該方法を使用した植物の養液栽培における殺菌装置および養液栽培方法を提供することであり、養液を殺菌するとともに、うどんこ病など病害罹患に対する抵抗性を植物に付与することができるケイ酸イオンを連続的に供給する方法を提供することである。   The present invention is to establish a nutrient solution sterilization method that is easy to manage at low cost and has a high sterilization effect, and to provide a sterilization apparatus and a nutrient solution cultivation method in the nutrient solution cultivation of plants using the method, It is intended to provide a method for continuously supplying silicate ions capable of sterilizing a nutrient solution and imparting resistance to diseases such as powdery mildew to plants.

本発明者は、鋭意検討した結果、酸化物換算の質量比で、SiO2が15〜60%、K2Oが10〜40%およびAg2Oが0.1〜5%に、P25が10〜50%および/またはB23が5〜50%を含有する溶解性ガラスからなる養液栽培における養液殺菌剤により上記課題を解決できることを見出した。また、この溶解性ガラスにMgOが15%以下、CaOが35%以下、MnO2が2%以下、Fe23が3%以下、CuOが1%以下、ZnOが1%以下、および/またはMoO3が1%以下を含有する養液栽培における養液殺菌剤である。また、この養液殺菌剤を肥料として使用するものである。
養液殺菌剤を使用する養液栽培装置であり、これを使用する養液栽培方法である。
As a result of intensive studies, the inventor has found that the mass ratio in terms of oxide is 15 to 60% SiO 2 , 10 to 40% K 2 O and 0.1 to 5% Ag 2 O, P 2 O It has been found that the above-mentioned problems can be solved by a nourishing liquid fungicide in nourishing liquid culture consisting of soluble glass containing 5 to 10% and / or 5 to 50% of B 2 O 3 . Further, the soluble glass has MgO of 15% or less, CaO of 35% or less, MnO 2 of 2% or less, Fe 2 O 3 of 3% or less, CuO of 1% or less, ZnO of 1% or less, and / or MoO 3 is a nutrient solution disinfectant in nutrient solution cultivation containing 1% or less. Moreover, this nutrient solution disinfectant is used as a fertilizer.
It is a nutrient solution cultivation apparatus using a nutrient solution disinfectant, and is a nutrient solution cultivation method using this.

以下、本発明について詳細に説明する。   Hereinafter, the present invention will be described in detail.

○溶解性ガラス
本発明の養液殺菌剤に用いる溶解性ガラスは、抗菌性を有する金属を養液中に溶出できるものであり、当該抗菌性を有する金属としては、銀が挙げられる。
○ Dissolvable glass The soluble glass used in the nutrient solution bactericide of the present invention is capable of eluting a metal having antibacterial properties into the nutrient solution, and examples of the metal having antibacterial properties include silver.

当該溶解性ガラスは、銀イオンとケイ酸イオンとを養液中に溶出しうるものであればいずれでもよく、ガラスの種類は限定されない。
水溶解性があり、抗菌金属イオンの溶解速度を調整しやすい当該溶解性ガラスに用いることができるガラスとしては、リンケイ酸ガラス、ホウケイ酸ガラスなどが挙げられる。また、溶解性があり、ケイ酸イオンの溶解速度を調整しやすい当該溶解性ガラスに用いることができるガラスとしては、リンケイ酸ガラス、ホウケイ酸ガラスなどが挙げられる。当該溶解性ガラスからの抗菌性金属イオン並びに抗菌性金属イオンおよびケイ酸イオンの溶出速度は、抗菌性金属の含有量、シリカの含有量、ガラス形成成分の含有量や組成、ガラス修飾成分の含有量や組成、さらにその他の成分の含有量や組成によって調整することができる。本発明の養液殺菌剤は、常に植物栽培用の養液と接触していることから鉢物などの園芸栽培用と異なる抗菌金属イオンの溶出条件または抗菌金属イオンとケイ酸イオンの溶出条件に調節している。
The soluble glass may be any glass that can elute silver ions and silicate ions into the nutrient solution, and the type of glass is not limited.
Examples of the glass that has water solubility and can be used for the soluble glass that easily adjusts the dissolution rate of the antibacterial metal ions include phosphosilicate glass and borosilicate glass. Examples of the glass that is soluble and can be used for the soluble glass that easily adjusts the dissolution rate of silicate ions include phosphosilicate glass and borosilicate glass. The dissolution rate of antibacterial metal ions and antibacterial metal ions and silicate ions from the soluble glass is determined by the content of antibacterial metals, the content of silica, the content and composition of glass forming components, and the content of glass modifying components. The amount and composition can be adjusted by the content and composition of other components. Since the nutrient solution fungicide of the present invention is always in contact with a nutrient solution for plant cultivation, it is adjusted to different elution conditions for antibacterial metal ions or antibacterial metal ions and silicate ions than those for horticultural cultivation such as pots. doing.

当該溶解性ガラスは例えば、SiO2を15〜60質量%、B23を5〜50質量%、K2Oを10〜40質量%、MgOを0〜15質量%、CaOを0〜35質量%、MnO2を0〜2質量%、Fe23を0〜3質量%、CuOを0〜1質量%、ZnOを0〜1質量%、MoO3を0〜1質量%、Ag2Oを0.1〜5質量%含有する溶解性ガラス、SiO2を15〜60質量%、P25を10〜50質量%、K2Oを10〜40質量%、MgOを0〜15質量%、CaOを0〜35質量%、MnO2を0〜2質量%、Fe23を0〜3質量%、CuOを0〜1質量%、ZnOを0〜1質量%、MoO3を0〜1質量%、Ag2Oを0.1〜5質量%含有する溶解性ガラス、SiO2を15〜60質量%、B23を5〜50質量%、P25を10〜50質量%、K2Oを10〜40質量%、MgOを0〜15質量%、CaOを0〜35質量%、MnO2を0〜2質量%、Fe23を0〜3質量%、CuOを0〜1質量%、ZnOを0〜1質量%、MoO3を0〜1質量%、Ag2Oを0.1〜5質量%含有する溶解性ガラス、SiO2を15〜50質量%、P25を25〜50質量%、K2Oを10〜40質量%、MgOを0〜15質量%、CaOを0〜35質量%、MnO2を0〜2質量%、Fe23を0〜3質量%、CuOを0〜1質量%、ZnOを0〜1質量%、MoO3を0〜1質量%、Ag2Oを0.1〜5質量%含有する溶解性ガラスなどが挙げられる。 The soluble glass, for example, a SiO 2 15 to 60 wt%, the B 2 O 3 5 to 50 wt%, the K 2 O 10 to 40 wt%, the MgO 0 to 15 mass%, the CaO 0 to 35 % By mass, 0-2% by mass of MnO 2 , 0-3% by mass of Fe 2 O 3 , 0-1% by mass of CuO, 0-1% by mass of ZnO, 0-1% by mass of MoO 3 , Ag 2 O from 0.1 to 5 mass% content for soluble glass, a SiO 2 15 to 60 wt%, P 2 O 5 10 to 50 wt%, 10 to 40 wt% of K 2 O, the MgO 0 to 15 0 to 35% by mass, CaO 0 to 35% by mass, MnO 2 0 to 2% by mass, Fe 2 O 3 0 to 3% by mass, CuO 0 to 1% by mass, ZnO 0 to 1% by mass, MoO 3 0 to 1 mass%, soluble glass containing Ag 2 O 0.1 to 5% by weight, the SiO 2 15 to 60 wt%, the B 2 O 3 5 to 50 wt%, P 2 5 10 to 50 wt%, the K 2 O 10 to 40 wt%, MgO 0 to 15 wt%, 0 to 35 wt% of CaO, the MnO 2 0 to 2 wt%, 0 to Fe 2 O 3 3% by mass, 0 to 1% by mass of CuO, 0 to 1% by mass of ZnO, 0 to 1% by mass of MoO 3 , 15 to 5% by mass of Ag 2 O, 15 of SiO 2 50 mass%, P 2 O 5 25 to 50 wt%, the K 2 O 10 to 40 wt%, the MgO 0 to 15 wt%, 0 to 35 wt% of CaO, the MnO 2 0 to 2 wt% the Fe 2 O 3 0 to 3 wt%, CuO and 0-1% by weight, ZnO 0 to 1 wt%, the MoO 3 0 to 1 mass%, containing Ag 2 O 0.1 to 5 wt% Examples include soluble glass.

更に好ましくは、SiO2を15〜60質量%、B23を5〜50質量%、K2Oを10〜40質量%、MgOを0〜15質量%、CaOを0〜35質量%、MnO2を0〜2質量%、Fe23を0〜3質量%、CuOを0〜1質量%、ZnOを0〜1質量%、MoO3を0〜1質量%、Ag2Oを0.1〜5質量%含有する溶解性ガラス、SiO2を15〜60質量%、P25を10〜50質量%、K2Oを10〜40質量%、MgOを0〜15質量%、CaOを0〜35質量%、MnO2を0〜2質量%、Fe23を0〜3質量%、CuOを0〜1質量%、ZnOを0〜1質量%、MoO3を0〜1質量%、Ag2Oを0.1〜5質量%含有する溶解性ガラスである。 More preferably, the SiO 2 15 to 60 wt%, the B 2 O 3 5 to 50 wt%, the K 2 O 10 to 40 wt%, the MgO 0 to 15 wt%, 0 to 35 wt% of CaO, MnO 2 is 0 to 2% by mass, Fe 2 O 3 is 0 to 3% by mass, CuO is 0 to 1% by mass, ZnO is 0 to 1% by mass, MoO 3 is 0 to 1% by mass, and Ag 2 O is 0%. .1-5 mass% soluble glass, SiO 2 15-60 mass%, P 2 O 5 10-50 mass%, K 2 O 10-40 mass%, MgO 0-15 mass%, CaO 0 to 35 wt%, the MnO 2 0 to 2 wt%, the Fe 2 O 3 0 to 3 wt%, the CuO 0 to 1 mass%, the ZnO 0 to 1 wt%, the MoO 3 0 to 1 It is a soluble glass containing 0.1% to 5% by mass of Ag 2 O.

本発明に用いる溶解性ガラスは、酸化物、水酸化物、ホウ酸塩、リン酸塩、塩化物、硝酸塩、硫酸塩、炭酸塩等、必要成分を含有している化合物を所定の混合量になるようによく混合した後、加熱溶融し、急冷、破砕、分級することにより得ることができる。   The soluble glass used in the present invention is a compound containing necessary components such as oxides, hydroxides, borates, phosphates, chlorides, nitrates, sulfates, carbonates, etc. in a predetermined mixing amount. After being mixed well, it can be obtained by heating and melting, rapid cooling, crushing, and classification.

溶解性ガラスからの銀イオンやケイ酸イオンの溶出速度は、ガラスの溶解速度を調整することにより可能である。すなわち、ガラス組成中のホウ酸(B23)、リン酸(P25)、アルカリ金属イオン、あるいはアルカリ土類金属イオン含有量を上げることにより溶解速度を大きくすることができることから、養液への銀イオンやケイ酸イオンの溶出速度をコントロールすることができる。 The elution rate of silver ions and silicate ions from the soluble glass can be achieved by adjusting the dissolution rate of the glass. That is, since the dissolution rate can be increased by increasing the content of boric acid (B 2 O 3 ), phosphoric acid (P 2 O 5 ), alkali metal ions, or alkaline earth metal ions in the glass composition, The elution rate of silver ions and silicate ions into the nutrient solution can be controlled.

上記溶解性ガラスは、分級することで養液栽培に最適な粒子径を得ることができる。また、ガラス製造時に、任意の粒径の球状とすることができる。この球状のガラス(ガラスビーズ)は通常の方法で得ることができる。例えば、溶融したガラスを液滴として滴下させ、球状に固化させる方法や、ガラス原料のスラリーを火焔中に噴霧し、溶融、固化させる方法などがある。
さらに粉末状のガラスを粒状に成形することもできる。
粒状抗菌剤の作りかたは特に限定されず、粒状セラミックなどの表面に担持させる方法、バインダーなどを用いて粒状品に成形する方法などが挙げられる。
The said soluble glass can obtain the optimal particle diameter for hydroponics by classifying. Moreover, it can be set as the spherical shape of arbitrary particle sizes at the time of glass manufacture. The spherical glass (glass beads) can be obtained by a usual method. For example, there are a method in which molten glass is dropped as droplets and solidified into a spherical shape, and a method in which a glass raw material slurry is sprayed into a flame to melt and solidify.
Furthermore, powdery glass can be formed into a granular shape.
There are no particular limitations on the method of making the granular antibacterial agent, and examples thereof include a method of supporting the surface on a surface of a granular ceramic and the like, a method of forming a granular product using a binder, and the like.

ここで粒状セラミックとは、天然あるいは人工的に作製された無機質固体材料、および粒状のガラスを指す。すなわち、世間一般で言われているセラミックス、窯業製品、ガラス、砂、小石などを指す。例えば、シリカ、アルミナ、ジルコニア、ムライト、ガラスのビーズ、あるいはボールなどが挙げられる。形状は球状、円柱状、円盤状、立方体状、直方体状、さらには、不定形状のものなど特に限定されない。   Here, the granular ceramic refers to a natural or artificially produced inorganic solid material and granular glass. In other words, it refers to ceramics, ceramic products, glass, sand, pebbles, etc., which are generally said to the public. Examples include silica, alumina, zirconia, mullite, glass beads, or balls. The shape is not particularly limited, such as a spherical shape, a cylindrical shape, a disk shape, a cubic shape, a rectangular parallelepiped shape, or an indefinite shape.

微粉末の溶解性ガラスを、粒状セラミックなどの表面に担持させる方法として、粒状セラミック表面に溶解性ガラスの原料粉末あるいは原料スラリーを付着させ、加熱することに担持させることができる。   As a method for supporting the fine powder of soluble glass on the surface of the granular ceramic or the like, the raw material powder or raw material slurry of the soluble glass can be adhered to the surface of the granular ceramic and heated.

また、結合剤として、ポリテトラフルオロエチレン、ポリフッ化ビニリデン、ポリ塩化ビニル、ポリアクリル酸エステル、エポキシ樹脂、ポリエチレン、ポリプロピレン、ABS樹脂、ポリエステルなどを用いて、粒状セラミック表面に付着させた後、熱可塑性樹脂であれば軟化点以上に加熱することにより、熱硬化性樹脂であれば硬化温度温度以上に加熱することにより、UV硬化樹脂であればUV照射により硬化させることで、粒状セラミック表面に担持させればよい。   In addition, polytetrafluoroethylene, polyvinylidene fluoride, polyvinyl chloride, polyacrylic acid ester, epoxy resin, polyethylene, polypropylene, ABS resin, polyester, etc. are used as a binder, If it is a plastic resin, it is supported on the surface of the granular ceramic by heating it above the softening point, if it is a thermosetting resin, it is heated above the curing temperature, and if it is a UV curable resin, it is cured by UV irradiation. You can do it.

粒状化の別の方法として、担持体を用いず、成形用バインダーを用いて粒状化させる方法もある。例えば、シリカゲルを用いる方法がある。シリカゲルは、物理的強度は粒状セラミックなどに担持させたものより低いものの、非常にポーラスな材料であるため、微粉末の溶解性ガラスと養液との接触効率が高く、殺菌効果も高い利点がある。   As another granulation method, there is a method of granulating using a molding binder without using a carrier. For example, there is a method using silica gel. Silica gel is a very porous material, although its physical strength is lower than that supported on granular ceramics, etc., so it has the advantages of high contact efficiency between soluble powder of fine powder and nutrient solution and high bactericidal effect. is there.

用いるシリカゲルについては特に限定がない。一般に言われるA型、B型、ID型などいずれでもよい。シリカゲルへの担持方法として、通常シリカゲルに無機化合物を担持する方法はいずれも適用することができる。例えば、ケイ酸ソーダ水溶液に微粉末の溶解性ガラスを添加した後、硫酸または塩酸を添加してケイ酸コロイド溶液を調製し、これを水中に滴下することにより粒状品が得られる。得られた粒状品は、水を多量に含んだいわゆるハイドロゲルである。これをそのまま用いることも出来るが、耐水性を向上させるためには、これを100〜300℃程度で乾燥させたほうが好ましい。ケイ酸ソーダ水溶液ではなく、硫酸または塩酸に微粉末の溶解性ガラスを添加しておき、ケイ酸ソーダ水溶液を添加して粒状品を得ることもできる。さらにケイ酸コロイド溶液が生成した直後に微粉末の溶解性ガラスを添加しても良い。   There is no limitation in particular about the silica gel to be used. Any of A type, B type, ID type, etc., which are generally referred to, may be used. As a method for supporting silica gel, any method of supporting an inorganic compound on silica gel can be applied. For example, after adding a fine powder of soluble glass to an aqueous sodium silicate solution, sulfuric acid or hydrochloric acid is added to prepare a colloidal silicate solution, which is dropped into water to obtain a granular product. The obtained granular product is a so-called hydrogel containing a large amount of water. Although this can be used as it is, in order to improve water resistance, it is preferable to dry it at about 100 to 300 ° C. A granular product can be obtained by adding a fine powder of soluble glass to sulfuric acid or hydrochloric acid instead of a sodium silicate aqueous solution, and then adding the sodium silicate aqueous solution. Further, a fine powder of soluble glass may be added immediately after the silicate colloid solution is formed.

その他に、結合剤として、ポリテトラフルオロエチレン、ポリフッ化ビニリデン、ポリ塩化ビニル、ポリアクリル酸エステル、エポキシ樹脂、ポリエチレン、ポリプロピレン、ABS樹脂、ポリエステルなどを用いて、押し出し造粒機、または押し出し機などで押し出した後、カッティングし、整粒により粒状品を成形することも出来る。   In addition, as a binder, use is made of polytetrafluoroethylene, polyvinylidene fluoride, polyvinyl chloride, polyacrylic ester, epoxy resin, polyethylene, polypropylene, ABS resin, polyester, etc. After extruding, it is possible to cut and granulate by granulation.

養液栽培に用いる溶解性ガラスの大きさは特に限定はないが、カラムやろ過塔などに充填して使用する場合は、粉末よりも粒状品のほうが好ましい。
カラムやろ過塔に充填して使用する溶解性ガラスの粒径は、0.05mm程度以上が好ましく、更に好ましくは粒径1mm以上である。一方、粒径が大きすぎると表面積が小さくなるため、実質的には粒径20mm程度以下であることが好ましく、更に好ましくは15mm以下である。即ち、粒状抗菌剤の大きさは、0.05〜20mmが好ましく、0.1〜15mmが更に好ましく、1〜15mmが特に好ましい。なお、微粉末の溶解性ガラスとは、粒径が0.05mm未満のものをいうが、使い方によっては、微粉末の溶解性ガラスをそのまま使用することもできる。
There is no particular limitation on the size of the soluble glass used for hydroponics, but a granular product is preferable to a powder when used in a column or a filtration tower.
The particle size of the soluble glass used by being packed in a column or a filtration tower is preferably about 0.05 mm or more, more preferably 1 mm or more. On the other hand, if the particle size is too large, the surface area becomes small. Therefore, the particle size is substantially preferably about 20 mm or less, more preferably 15 mm or less. That is, the size of the granular antibacterial agent is preferably 0.05 to 20 mm, more preferably 0.1 to 15 mm, and particularly preferably 1 to 15 mm. The fine powder soluble glass means a glass having a particle size of less than 0.05 mm, but depending on how it is used, the fine powder soluble glass can be used as it is.

○養液栽培方法
図1に、一般的な循環式養液栽培装置の構成を示した。混合タンク5において、排液タンク4からの戻り養液と養液原液タンク3からの養液原液を混合し、栽培ベッド1に養液を送液する。なお、図1では栽培ベッドを2カ所しか表示していないが、実際の装置または栽培方法においては、栽培規模に応じて栽培ベッドをさらに設置することができる。本発明の溶解性ガラスは、このような例示した養液栽培装置に組み込むことができる。例えば、網籠、メッシュ袋などに溶解性ガラスを充填し排液タンク内や混合タンク内に設置する方法、ろ過塔やカラムに溶解性ガラスを充填し、栽培ベッドと排液タンクの間の配管、排液タンクと混合タンクの間の配管、あるいは混合タンクと栽培ベッドの間の配管に組み込む方法などがある。
また、養液栽培装置のいずれかの配管あるいはタンクから、養液の一部をバイパスにより抜き出して、溶解性ガラスを充填したカートリッジ、充填塔またはカラムなどに流して処理し、再び系内に戻す方法でもよい。さらに、砂ろ過などのろ過装置を系内に設け、ろ材の中に溶解性ガラスを交ぜ込む、あるいは溶解性ガラスの層を砂ろか層の前か後ろに組み込む方法もある。
本発明の溶解性ガラスは、養液の殺菌剤として少なくとも一ヶ所以上に養液栽培装置に組み込むことができ、少なくとも2ヶ所以上に養液栽培装置に組み込むことが好ましい。なお、この養液栽培は、かけ流しであっても循環式であってもよく、好ましくは、循環式である。
本発明において、オゾンや紫外線などによる殺菌装置を併用してもよい。
O Hydroponic cultivation method In FIG. 1, the structure of the general circulation type hydroponic cultivation apparatus was shown. In the mixing tank 5, the returning nutrient solution from the drainage tank 4 and the nutrient solution stock solution from the nutrient solution stock tank 3 are mixed, and the nutrient solution is sent to the cultivation bed 1. In FIG. 1, only two cultivation beds are displayed. However, in an actual apparatus or cultivation method, cultivation beds can be further installed according to the cultivation scale. The soluble glass of the present invention can be incorporated into such an exemplified hydroponic cultivation apparatus. For example, a method of filling a mesh bag or mesh bag with soluble glass and installing it in a drainage tank or a mixing tank, filling a filtration tower or column with soluble glass, and piping between the cultivation bed and the drainage tank In addition, there is a method of incorporating in a pipe between the drainage tank and the mixing tank, or a pipe between the mixing tank and the cultivation bed.
In addition, a part of the nutrient solution is withdrawn from one of the pipes or tanks of the nutrient solution cultivation apparatus by bypass, and is treated by flowing it into a cartridge, packed tower or column filled with soluble glass, and then returned to the system again. The method may be used. Further, there is a method in which a filtration device such as sand filtration is provided in the system, and a soluble glass is mixed in the filter medium, or a layer of the soluble glass is incorporated in front of or behind the sand filter.
The soluble glass of the present invention can be incorporated into a nutrient solution cultivating apparatus as at least one place as a nutrient solution fungicide, and is preferably incorporated into the nutrient solution cultivating apparatus in at least two places. In addition, this hydroponic cultivation may be a pouring type or a circulation type, and is preferably a circulation type.
In the present invention, a sterilizer using ozone or ultraviolet rays may be used in combination.

抗菌金属、ケイ酸イオンの養液中への溶出濃度は、養液栽培の条件によって異なるが、おおよそ銀イオンであれば20ppb以上に調節すれば良い。また、ケイ酸イオン濃度は、養液中1ppm以上に、好ましくは10ppm以上になるように調節すれば良い。但し、これらの濃度が高くなり過ぎるものは、ランニングにおける溶解性ガラスの交換頻度が多くなり、コストおよびメンテナンスが悪くなり好ましくない。また、植物に対して障害が出る場合がある。
当該溶解性ガラスから溶出するリンなどを肥料として用いることもできる。
養液栽培装置中の当該溶解性ガラスの交換時期は、養液中の抗菌金属イオンをモニターして決定してもよく、当該溶解性ガラスの嵩から決めてもよく、交換時期を決めておいて行ってもよい。
The elution concentration of the antibacterial metal and silicate ions in the nutrient solution varies depending on the conditions of the nutrient solution cultivation, but may be adjusted to 20 ppb or more if it is approximately silver ions. Further, the silicate ion concentration may be adjusted to 1 ppm or more, preferably 10 ppm or more in the nutrient solution. However, those having excessively high concentrations are not preferable because the frequency of replacement of the soluble glass during running increases and the cost and maintenance deteriorate. In addition, the plant may be damaged.
Phosphorus eluted from the soluble glass can also be used as a fertilizer.
The time for replacement of the soluble glass in the nutrient solution cultivation apparatus may be determined by monitoring the antibacterial metal ions in the nutrient solution, may be determined from the volume of the soluble glass, and the replacement time is determined. You may go.

養液殺菌剤は、かけ流し栽培にも循環式養液栽培にも用いることもでき、好ましくは病原菌の管理を厳しく行う必要がある循環式養液栽培に用いるものことが好ましい。これらの養液殺菌剤は、使用条件によるが土壌を用いる栽培にも用いることが可能である。なお、これらの養液殺菌剤は、例えば溶出する各種イオンのコントロールが容易であることから土壌での栽培より養液栽培に用いることが好ましい。   The nutrient solution bactericidal agent can be used for both the flow-through cultivation and the circulation type nutrient solution cultivation, and is preferably used for the circulation type nutrient solution cultivation in which pathogenic bacteria need to be strictly controlled. These nutrient solution fungicides can be used for cultivation using soil, depending on the conditions of use. In addition, since these nutrient solution disinfectants are easy to control, for example, various ions to be eluted, it is preferable to use them in nutrient solution cultivation rather than soil cultivation.

<実施例>
以下、本発明を実施例により更に詳細に説明する。なお、部は質量部を示す。
<Example>
Hereinafter, the present invention will be described in more detail with reference to examples. In addition, a part shows a mass part.

<製造例1>
表1に示した組成(各質量部)を良く混合して調製した調合物を1000〜1400℃で溶融してガラスを作製後、得られたガラスを破砕、分級して粒径約1mm〜5mmの溶解性ガラスを得た(試料イ〜ホ)。
<Production Example 1>
A composition prepared by thoroughly mixing the composition (each part by mass) shown in Table 1 was melted at 1000 to 1400 ° C. to produce glass, and the obtained glass was crushed and classified to obtain a particle size of about 1 mm to 5 mm. (1) to (6) were obtained.

Figure 2005314292
Figure 2005314292

Figure 2005314292
Figure 2005314292

製造例1で作製した溶解性ガラス(試料ハ)と銀ゼオライトにおける養液への銀イオンの溶出を調べた。即ち、
1)大塚ハウス肥料1号(大塚化学(株)製)150gを水道水1,000mLに溶解させる(100倍原液)。
2)大塚ハウス肥料2号(大塚化学(株)製)100gを水道水1,000mLに溶解させる(100倍原液)。
3)大塚ハウス肥料1号及び2号の100倍原液を各30mLと水道水2,940mLを混合し、試験養液とした(大塚ハウス肥料シリーズA処方)。
4)室温で試験養液3,000mLに、メッシュ袋に3gの試料ハまたは3gの銀ゼオライトを入れて糸で吊下げ浸漬させた。
5)室温でゆっくり21日間攪拌した。
そして所定時間毎にサンプリングし、銀イオン濃度をICP発光分光分析計を用いて測定した。
6)7日経過後、試験養液を新しいものの入れ替え、同様の試験を行なう。
7)さらに7日後、同様に行なう。
このようにして得た各サンプル中の銀イオン濃度(mg/L)を表3に示す。
The dissolution of silver ions into the nutrient solution in the soluble glass (sample C) prepared in Production Example 1 and silver zeolite was examined. That is,
1) 150 g of Otsuka House Fertilizer No. 1 (manufactured by Otsuka Chemical Co., Ltd.) is dissolved in 1,000 mL of tap water (100-fold stock solution).
2) 100 g of Otsuka House Fertilizer No. 2 (Otsuka Chemical Co., Ltd.) is dissolved in 1,000 mL of tap water (100-fold stock solution).
3) Otsuka House Fertilizer No. 1 and No. 2 100-fold stock solutions were mixed with 30 mL each and 2,940 mL of tap water to make a test nutrient solution (Otsuka House Fertilizer Series A prescription).
4) In a test nutrient solution of 3,000 mL at room temperature, 3 g of sample C or 3 g of silver zeolite was placed in a mesh bag and dipped in a suspended thread.
5) Slowly stirred at room temperature for 21 days.
Then, sampling was performed every predetermined time, and the silver ion concentration was measured using an ICP emission spectrometer.
6) After 7 days, replace the test solution with a new one and perform the same test.
7) After another 7 days, do the same.
The silver ion concentration (mg / L) in each sample thus obtained is shown in Table 3.

Figure 2005314292
Figure 2005314292

表3から分かるように銀ゼオライトから養液中への銀イオンの溶出は、溶解性ガラスに比べ立ち上がりが早いが、長期間溶出し続けることはできない。これに比べ溶解性ガラスから養液への銀イオンの溶出は、立ち上がりが銀ゼオライトに比べ小さいが長期間必要な濃度の銀イオンを溶出し続けることができる。
このことから、溶解性ガラスは養液栽培の装置に組込んで長期間使用することができ、且つ装置や薬液などのメンテナンスも軽減できるものである。
As can be seen from Table 3, the elution of silver ions from the silver zeolite into the nutrient solution starts faster than the soluble glass, but it cannot be eluted for a long period of time. Compared to this, elution of silver ions from the soluble glass into the nutrient solution can continue to elute silver ions at a required concentration for a long period of time, although the rise is smaller than that of silver zeolite.
Therefore, the soluble glass can be used for a long period of time by being incorporated in a hydroponic apparatus, and maintenance of the apparatus and chemicals can be reduced.

<実施例2〜6>
10Lの養液原液タンク2基、50Lの混合タンク1基、50Lの排液タンク1基、幅20cm、深さ20cm、長さ200cmの栽培ベッド(ベッドはロックウール)2基、および循環ポンプを備えた養液栽培装置を作製した。この概念図を図1に示した。栽培ベッドには、トマト10株を移植し、1日あたり20Lの養液(大塚ハウス肥料シリーズA処方)を断続的に循環させた。排液は1日に1回、混合タンクに戻した。減少した養液は新規に作製し、1日に1回追加した。
養液には、Pythium aphanidermatum を接種した。養液栽培装置には、表4に示したように溶解性ガラス(試料イ〜ホ)を組み込んだ。
試験を開始し8週間後のトマトの状況を観察した。
<Examples 2 to 6>
Two 10L nutrient solution stock tanks, one 50L mixing tank, one 50L drainage tank, two 20cm wide, 20cm deep, 200cm long cultivation beds (bed is rock wool), and a circulation pump The provided hydroponic device was prepared. This conceptual diagram is shown in FIG. Ten tomato plants were transplanted to the cultivation bed, and 20 L of nutrient solution (Otsuka House Fertilizer Series A formulation) was circulated intermittently. The drainage was returned to the mixing tank once a day. The reduced nutrient solution was newly prepared and added once a day.
The nutrient solution was inoculated with Pythium aphanidermatum. As shown in Table 4, soluble glass (samples i to e) was incorporated into the hydroponic cultivation apparatus.
The test was started and the situation of the tomatoes was observed 8 weeks later.

Figure 2005314292
Figure 2005314292

<実施例7〜8>
10Lの養液原液タンク2基、50Lの混合タンク1基、50Lの排液タンク1基、幅20cm、深さ20cm、長さ200cmの栽培ベッド(ベッドはロックウール)2基、および循環ポンプを備えた養液栽培装置を作製した。この概念図を図1に示した。栽培ベッドには、トマト10株を移植し、1日あたり20Lの養液(大塚ハウス肥料シリーズA処方)を断続的に循環させた。排液は1日に1回、混合タンクに戻した。減少した養液は新規に作製し、1日に1回追加した。養液栽培装置には、表5に示したように溶解性ガラス(試料イ、ハ)を組み込んだ。試験を開始し8週間後のトマトの状況を観察した。
<Examples 7 to 8>
Two 10L nutrient solution stock tanks, one 50L mixing tank, one 50L drainage tank, two 20cm wide, 20cm deep, 200cm long cultivation beds (bed is rock wool), and a circulation pump The provided hydroponic device was prepared. This conceptual diagram is shown in FIG. Ten tomato plants were transplanted to the cultivation bed, and 20 L of nutrient solution (Otsuka House Fertilizer Series A formulation) was circulated intermittently. The drainage was returned to the mixing tank once a day. The reduced nutrient solution was newly prepared and added once a day. As shown in Table 5, soluble glass (samples A and C) was incorporated into the hydroponic cultivation apparatus. The test was started and the situation of the tomatoes was observed 8 weeks later.

Figure 2005314292
Figure 2005314292

溶解性ガラスを用いることにより、栽培植物の循環式養液栽培における病害感染を防止できる。また、うどんこ病などの病害に感染しにくくなる。溶解性ガラスを養液とどの時点で接触させても病害感染の防止効力に差が認められなかったことから、循環式養液栽培に本発明の方法を組み込むことは、容易である。即ち、循環式養液栽培の設置場所およびメンテナンスなどの面を考慮して、いずれの場所にも行えることが明らかであり、また既存の循環式養液栽培装置に組み込むことも容易である。   By using the soluble glass, it is possible to prevent disease infection in the circulating hydroponic cultivation of cultivated plants. In addition, it becomes difficult to be infected with diseases such as powdery mildew. It was easy to incorporate the method of the present invention into the circulation type hydroponic culture because no difference was observed in the preventive effect of disease infection regardless of when the soluble glass was brought into contact with the nutrient solution. That is, it is clear that it can be carried out in any place in consideration of the installation location and maintenance of the circulation type hydroponic cultivation, and can be easily incorporated into an existing circulation type hydroponic cultivation apparatus.

本発明の養液殺菌剤を循環式養液栽培に用いることにより、養液栽培装置中を循環している養液に混入した病原菌による栽培植物の病害感染を阻止することができる。また、うどんこ病などの病害に感染しにくくなる。このことから、長期間養液栽培を続けることができる。また、本発明の栽培方法は、環境への負荷も少なくすることができる。   By using the nutrient solution fungicide of the present invention for circulation type nutrient solution culture, it is possible to prevent disease infection of cultivated plants caused by pathogenic bacteria mixed in the nutrient solution circulating in the nutrient solution culture apparatus. In addition, it becomes difficult to be infected with diseases such as powdery mildew. From this, it is possible to continue the hydroponics for a long time. Moreover, the cultivation method of this invention can also reduce the load to an environment.

代表的な循環式養液栽培装置の図Figure of typical circulation type hydroponic cultivation equipment

符号の説明Explanation of symbols

1 栽培ベッド
2 ポンプ
3 養液原液タンク
4 排液タンク
5 混合タンク
6 給水
7 排水
← 養液の流れる方向
1 Cultivation Bed 2 Pump 3 Nutrient Solution Stock Tank 4 Drainage Tank 5 Mixing Tank 6 Water Supply 7 Drainage ← Direction of Nutrient Solution Flow

Claims (3)

酸化物換算の質量比で、SiO2が15〜60%、K2Oが10〜40%およびAg2Oが0.1〜5%に、P25が10〜50%および/またはB23が5〜50%を含有する溶解性ガラスからなる養液栽培における養液殺菌剤。 At a weight ratio of oxide equivalent, SiO 2 15 to 60% and K 2 O is 10-40% and Ag 2 O is 0.1 to 5% P 2 O 5 from 10 to 50% and / or B A nutrient solution bactericidal agent in nutrient solution culture composed of soluble glass containing 5 to 50% 2 O 3 . 請求項1記載の溶解性ガラスにMgOが15%以下、CaOが35%以下、MnO2が2%以下、Fe23が3%以下、CuOが1%以下、ZnOが1%以下、および/またはMoO3が1%以下を含有する養液栽培における養液殺菌剤。 The soluble glass of claim 1, wherein MgO is 15% or less, CaO is 35% or less, MnO 2 is 2% or less, Fe 2 O 3 is 3% or less, CuO is 1% or less, ZnO is 1% or less, and A nutrient solution bactericidal agent in nutrient solution cultivation containing MoO 3 of 1% or less. 請求項1または請求項2に記載の養液殺菌剤を使用する養液栽培装置。   A nutrient solution cultivation apparatus using the nutrient solution disinfectant according to claim 1 or 2.
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