JP2005284263A - Photosensitive thermal development recording material, its case, and developing method and manufacturing method of the photosensitive thermal development recording material - Google Patents

Photosensitive thermal development recording material, its case, and developing method and manufacturing method of the photosensitive thermal development recording material Download PDF

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JP2005284263A
JP2005284263A JP2005045695A JP2005045695A JP2005284263A JP 2005284263 A JP2005284263 A JP 2005284263A JP 2005045695 A JP2005045695 A JP 2005045695A JP 2005045695 A JP2005045695 A JP 2005045695A JP 2005284263 A JP2005284263 A JP 2005284263A
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recording material
photosensitive
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heat
developable recording
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Yasuyoshi Ota
恭義 大田
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Fujifilm Holdings Corp
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Fuji Photo Film Co Ltd
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<P>PROBLEM TO BE SOLVED: To provide a photosensitive thermal development recording material which is easily handled and does not require working in a dark room, and to provide a case for the material and a development method and a manufacturing method of the photosensitive thermal development recording material. <P>SOLUTION: The case has a case body, having a housing section to house a photosensitive thermal development recording material having an image forming layer containing a photosensitive silver halide; a non-photosensitive organic silver salt; a reducing agent and a binder on at least one surface of a supporting body, wherein at least the surface of the body is made of a light-shielding material. The housing section is provided with a sensitized member. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、X線照射によって潜像が形成される感光性熱現像記録材料、その収容体及び感光性熱現像記録材料の現像方法並びに製造方法に関する。   The present invention relates to a photosensitive heat-developable recording material on which a latent image is formed by X-ray irradiation, a container thereof, a developing method and a manufacturing method of the photosensitive heat-developable recording material.

近年、湿式処理を行うことがないドライシステムによる熱現像装置や熱現像記録装置が提案されている。このような熱現像装置や熱現像記録装置では、記録媒体として、感光性および/または感熱性記録材料(感光感熱記録材料)や、熱現像感光材料を含むフィルム状の記録材料(以下、感光性熱現像記録材料という)が用いられている。
このようなドライシステムとして、病院などの医療施設で使用されるX線撮影装置がある。X線撮影装置は、感光性熱現像記録材料をカセッテに保持させ、X線管からX線を照射し、被写体にX線を透過させて上記感光性熱現像記録材料に潜像を形成する構成である(例えば、特許文献1及び2参照)。
In recent years, thermal development apparatuses and thermal development recording apparatuses using dry systems that do not perform wet processing have been proposed. In such a heat development apparatus or heat development recording apparatus, a photosensitive and / or heat-sensitive recording material (photosensitive heat-sensitive recording material) or a film-like recording material containing a heat-developable photosensitive material (hereinafter, photosensitive) is used as a recording medium. A heat-developable recording material).
As such a dry system, there is an X-ray imaging apparatus used in a medical facility such as a hospital. An X-ray imaging apparatus is configured to hold a photosensitive heat-developable recording material in a cassette, irradiate X-rays from an X-ray tube, and transmit X-rays to a subject to form a latent image on the photosensitive heat-developable recording material. (For example, see Patent Documents 1 and 2).

特開平4−256946号公報JP-A-4-256946 特開昭60−153000号公報JP 60-153000 A

感光性熱現像記録材料は明室で扱うと感光してしまうため、X線撮影を行う前に暗室において感光性熱現像記録材料をカセッテにセットする作業が行われる必要がる。しかし、暗室での作業はできる限り避けたいという要望があり、特に、小さい規模の病院などX線撮影を頻繁に行わない施設においては場所の有効利用の点からも暗室設備をできるだけ備えたくないという要求がある。
本発明は、このような事情に鑑みてなされたもので、その目的は、暗室での作業を必要とせず、取り扱い易い感光性熱現像記録材料、その収容体及び感光性熱現像記録材料の現像方法並びに製造方法を提供することにある。
Since the photosensitive heat-developable recording material is exposed to light when handled in a bright room, it is necessary to perform an operation of setting the photosensitive heat-developable recording material in the cassette in the dark room before performing X-ray photography. However, there is a request to avoid working in the dark room as much as possible, especially in facilities that do not frequently perform X-ray imaging, such as small hospitals, from the viewpoint of effective use of the place, it is said that you do not want to have dark room equipment as much as possible There is a request.
The present invention has been made in view of such circumstances, and its purpose is to develop a photosensitive heat-developable recording material that does not require work in a dark room and is easy to handle, its container, and photosensitive heat-developable recording material. It is to provide a method and a manufacturing method.

本発明の上記目的は、支持体の少なくとも一方の面上に、感光性ハロゲン化銀、非感光性有機銀塩、還元剤、及びバインダを含有する画像形成層を設けた感光性熱現像記録材料を収納する感光性熱現像記録材料の収容体であって、感光性熱現像記録材を収容する収容部を有し、少なくとも表面が遮光性材料からなる収容体本体を備え、収容部内面に増感部材が備えられていることを特徴とする感光性熱現像記録材料の収容体によって達成される。   The object of the present invention is to provide a photosensitive heat-developable recording material provided with an image forming layer containing a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder on at least one surface of a support. A photosensitive heat-developable recording material container having a housing part for housing a photosensitive heat-developable recording material, and having a container body made of a light-shielding material at least on the surface, and being provided on the inner surface of the housing part. This is achieved by a photosensitive heat-developable recording material container characterized in that a photosensitive member is provided.

この感光性熱現像記録材料の収容体では、遮光性材料からなる収容体本体を備えており、この収容体に感光性熱現像記録材料を収容しておくことで、感光性熱現像記録材料が明室において感光してしまうことを防止することができるうえ、感光性熱現像記録材料に直接手が触れることがないため、指紋等の汚れが付着することを避けることができる。また、収容体には増感部材が装着されているため、感光性熱現像記録材料を収容体に収容したままでX線撮影を行うことができ、X線撮影装置において撮影を行う際に、感光性熱現像記録材料を保持するカセッテが必要なくなる。   The photosensitive heat-developable recording material container includes a container body made of a light-shielding material. By storing the photosensitive heat-developable recording material in the container, the photosensitive heat-developable recording material is stored in the container. In addition to preventing exposure to light in a bright room, the photosensitive heat-developable recording material is not directly touched by hands, so that it is possible to avoid contamination such as fingerprints. In addition, since the sensitizing member is mounted on the container, X-ray imaging can be performed while the photosensitive heat-developable recording material is stored in the container, and when the X-ray imaging apparatus performs imaging, There is no need for a cassette for holding the photosensitive heat-developable recording material.

上記感光性熱現像記録材料の収容体は、増感部材が収容部の感光性熱現像記録材料の画像形成層に対向する内側面に貼り付けられていることが好ましい。   In the photosensitive heat-developable recording material container, the sensitizing member is preferably affixed to the inner surface of the housing portion facing the image forming layer of the photosensitive heat-developable recording material.

こうすれば、記録材料を収容体に挿入する際や収容体から取り出す際に収容部の内部で増感部材が移動して捩れやしわが生じてしまうことを防止することができる。   By doing so, it is possible to prevent the sensitizing member from moving inside the housing portion and causing twisting and wrinkling when the recording material is inserted into the housing body or taken out from the housing body.

上記感光性熱現像記録材料の収容体は、収容部が仕切り部によって一対のポケット部が区画され、一対のポケット部のうち一方に、感光性熱現像記録材料が保持され、他方に、増感部材が保持され、仕切り部には潜像を形成する部分に相当する箇所に窓部が開孔するように形成されていることが好ましい。   In the photosensitive heat-developable recording material container, a pair of pocket portions is partitioned by a partition portion, the photosensitive heat-developable recording material is held in one of the pair of pocket portions, and the sensitization is performed on the other side. Preferably, the member is held, and the partition portion is formed so that a window portion is opened at a portion corresponding to a portion where a latent image is formed.

この感光性熱現像記録材料の収容体では、一対のポケット部のうち一方に保持された感光性熱現像記録材料をX線撮影ごとに取り替えて、他方のポケット部に保持された比較的高価な増感部材を使い回すことで、収容体を繰り返し使用すること(リサイクル)ができる。   In this photosensitive heat-developable recording material container, the photosensitive heat-developable recording material held in one of the pair of pocket portions is replaced for each X-ray imaging, and is relatively expensive held in the other pocket portion. By repeatedly using the sensitizing member, the container can be repeatedly used (recycled).

上記遮光性材料が500nm以下の波長の有色光を遮断することが好ましい。   It is preferable that the light-shielding material blocks colored light having a wavelength of 500 nm or less.

こうすれば、500nm以下の波長を有する有色光を遮断するとともに、感光フィルタ機能を有する材料として透明又は半透明な材料を使用することで、収容体に収容した記録材料の状態を収容体外部から視認することができる。このため、収容体を直接熱現像装置に装填して熱現像を行う際に、収容体から記録材料を取り出すことなく現像の状態を確認することができるため使い勝手が良い。   In this way, colored light having a wavelength of 500 nm or less is blocked, and a transparent or translucent material is used as a material having a photosensitive filter function, so that the state of the recording material accommodated in the container can be externally determined. It can be visually recognized. For this reason, when carrying out thermal development by directly loading the container into the thermal development apparatus, the state of development can be confirmed without taking out the recording material from the container, which is convenient.

さらに、本発明の上記目的は、上記感光性熱現像記録材料の収容体を保持するとともに前記感光性熱現像記録材にX線を照射して潜像を形成するX線撮影装置に装填可能なカセッテによって達成される。   Furthermore, the object of the present invention can be loaded into an X-ray imaging apparatus that holds a photosensitive heat-developable recording material container and irradiates the photosensitive heat-developable recording material with X-rays to form a latent image. Achieved by cassette.

このカセッテは、上記収容体の内部に収容された記録材料と増感部材との密着度合を強くすることができる。また、従来のようにカセッテ内部に増感部材を取り付ける必要がなく、カセッテの清掃等のメンテナンスが容易になる。   This cassette can increase the degree of adhesion between the recording material and the sensitizing member accommodated in the container. Further, it is not necessary to attach a sensitizing member inside the cassette as in the conventional case, and maintenance such as cleaning of the cassette becomes easy.

さらに、本発明の上記目的は、支持体の少なくとも一方の面上に、感光性ハロゲン化銀、非感光性有機銀塩、還元剤、及びバインダを含有する画像形成層を設けた感光性熱現像記録材料の現像方法であって、感光性熱現像記録材料を、少なくとも表面が遮光性材料からなる収容体に収容し、収容体に増感部材を備えた状態で、X線を照射した後、収容体に感光性熱現像記録材料を収容した状態のまま熱現像することで、潜像を顕像化することを特徴とする感光性熱現像記録材料の現像方法によって達成される。   Furthermore, the object of the present invention is to provide photosensitive heat development in which an image forming layer containing a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder is provided on at least one surface of a support. A method for developing a recording material, wherein the photosensitive heat-developable recording material is accommodated in a container having at least a surface made of a light-shielding material, and the container is provided with a sensitizing member. This is achieved by a method for developing a photosensitive heat-developable recording material, characterized in that the latent image is visualized by heat development in a state where the photosensitive heat-developable recording material is accommodated in the container.

この現像方法では、収容体が遮光性材料からなるため、この収容体に収容された感光性熱現像記録材料を明室で取り扱うことができ、また、収容体に増感部材が備えられているため、従来のような増感部材として機能するスクリーンを備えたカセッテが必要ない。収容体に感光性熱現像記録材料を収容した状態のまま熱現像することで、カセッテに感光性熱現像記録材料を装填するといった作業を省くことができるため、特に、X線撮影の回数が少ない環境(例えば、開業医など小規模の医療現場)では使い勝手が良い。   In this developing method, since the container is made of a light shielding material, the photosensitive heat-developable recording material accommodated in the container can be handled in a bright room, and the sensitizer is provided in the container. Therefore, there is no need for a cassette having a screen that functions as a sensitizing member as in the prior art. By performing heat development while the photosensitive heat-developable recording material is accommodated in the container, the operation of loading the photosensitive heat-developable recording material into the cassette can be omitted, and in particular, the number of X-ray imaging is small. It is easy to use in an environment (for example, a small medical site such as a practitioner).

さらに、本発明の上記目的は、支持体と、該支持体の少なくとも一方の面上に、感光性ハロゲン化銀、非感光性有機銀塩、還元剤、及びバインダを含有する画像形成層とを有し、画像形成層の表面に増感層が形成され、増感層の表面が遮光層に覆われていることを特徴とする感光性熱現像記録材料によって達成される。   Furthermore, the object of the present invention is to provide a support and an image forming layer containing a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder on at least one surface of the support. And a sensitizing layer is formed on the surface of the image forming layer, and the surface of the sensitizing layer is covered with a light-shielding layer.

この感光性熱現像記録材料は、遮光層で覆われているため、遮光材料からなる収容体や従来のカセッテに収容しない状態でも明室で取り扱うことができるため、暗室での作業を必要としない点で使い勝手がよい。また、X線撮影時には、この感光性熱現像記録材料にX線照射を行なうことができ、熱現像時には、この記録材料をそのまま熱現像装置に装填することで、熱現像処理を施すことができ、熱現像後に、遮光層及び増感層とを剥離することで、現像した記録材料を得ることができる。   Since this photosensitive heat-developable recording material is covered with a light-shielding layer, it can be handled in a bright room even if it is not housed in a container made of a light-shielding material or a conventional cassette, so there is no need for work in a dark room. Convenient in terms. Further, at the time of X-ray imaging, the photosensitive heat development recording material can be irradiated with X-rays, and at the time of heat development, the recording material can be directly loaded into a heat development apparatus to perform heat development processing. After the heat development, the developed recording material can be obtained by peeling off the light shielding layer and the sensitizing layer.

さらに、本発明の上記目的は、支持体の少なくとも一方の面上に、感光性ハロゲン化銀、非感光性有機銀塩、還元剤、及びバインダを含有する画像形成層を設けた感光性熱現像材料の製造方法であって、供給された支持体に画像形成層を形成し、画像形成層の表面に増感層をラミネートし、増感層の表面に遮光層をラミネートし、その後、支持体を裁断することを特徴とする感光性熱現像記録材料の製造方法によって達成される。   Furthermore, the object of the present invention is to provide photosensitive heat development in which an image forming layer containing a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder is provided on at least one surface of a support. A method for producing a material, wherein an image forming layer is formed on a supplied support, an sensitizing layer is laminated on the surface of the image forming layer, a light shielding layer is laminated on the surface of the sensitizing layer, and then the support Is achieved by a method for producing a photosensitive heat-developable recording material, characterized in that

この製造方法では、1つの製造工程の中で、支持体に画像形成層を形成する工程と画像形成層の表面に増感層をラミネートする工程と、増感層の表面に遮光層をラミネートする工程と、支持体を裁断する工程を有しているため、明室で取り扱うことができる感光性熱現像記録材料を効率良く製造することができる。   In this manufacturing method, in one manufacturing process, a step of forming an image forming layer on a support, a step of laminating a sensitizing layer on the surface of the image forming layer, and a light shielding layer on the surface of the sensitizing layer are laminated. Since the method includes a step and a step of cutting the support, a photosensitive heat-developable recording material that can be handled in a bright room can be efficiently produced.

本発明によれば、暗室での作業を必要とせず、取り扱い易い感光性熱現像記録材料、その収容体及び感光性熱現像記録材料の現像方法並びに製造方法を提供できる。   According to the present invention, it is possible to provide a photosensitive heat-developable recording material that does not require work in a dark room and is easy to handle, a container for the photosensitive heat-developable recording material, and a developing method and manufacturing method for the photosensitive heat-developable recording material.

以下、本発明に係る感光性熱現像記録材料、その収容体及び感光性熱現像記録材料の現像方法並びに製造方法の好適な実施の形態を図面を参照して説明する。
図1は、本発明に係る感光性熱現像記録材料の収容体の第1の実施形態を説明する図である。収容体1は、X線照射によって潜像が形成される感光性熱現像記録材料(以下、記録材料ともいう。)Fを収容するものである。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Preferred embodiments of a photosensitive heat-developable recording material, a container for the same, a developing method for the photosensitive heat-developable recording material, and a manufacturing method according to the present invention will be described below with reference to the drawings.
FIG. 1 is a view for explaining a first embodiment of a photosensitive heat-developable recording material container according to the present invention. The container 1 contains a photosensitive heat-developable recording material (hereinafter also referred to as a recording material) F on which a latent image is formed by X-ray irradiation.

記録材料Fは、支持体の少なくとも一方の面上に、感光性ハロゲン化銀、非感光性有機銀塩、還元剤、及びバインダを含有する画像形成層を設けたものであり、X線照射によって画像形成層に予め潜像が形成され、記録材料Fに熱現像を施すことで画像形成層の潜像が顕像化するものである。以下、画像形成層を感光層ともいう。   The recording material F is provided with an image forming layer containing a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder on at least one surface of a support. A latent image is formed in advance on the image forming layer, and the latent image on the image forming layer is visualized by subjecting the recording material F to heat development. Hereinafter, the image forming layer is also referred to as a photosensitive layer.

収容体1は、収容体本体1aと、該収容体本体1aの内部に設けられた、記録材料を収容するための収容部2とを有している。収容体本体1aは、底を有する長尺の袋状部材であり、一方の端部に形成された開口3から記録材料Fを挿入可能な構成である。収容体1は、収容体本体1aにおいて少なくとも表面が遮光性材料からなる部材である。遮光性材料としては、例えば、アルミ箔などの金属や黒色からなる樹脂あるいはそれらの複合部材を用いることができる。   The container 1 has a container body 1a and a container 2 provided inside the container body 1a for containing a recording material. The container body 1a is a long bag-like member having a bottom, and has a configuration in which the recording material F can be inserted from the opening 3 formed at one end. The container 1 is a member having at least a surface made of a light shielding material in the container body 1a. As the light-shielding material, for example, a metal such as aluminum foil, a resin made of black, or a composite member thereof can be used.

収容体1の収容部2には、記録材料Fと、収容部2の内部で該記録材料Fの両面側にそれぞれ配置される増感部材5とが挿入される。収容部2に記録材料Fと増感部材5とを収容した後に、収容体本体1aに、開口3が形成された側の端辺を所定の幅で繰り返し折り返してなる折返部4を形成することで、開口3が遮蔽され、収容部2内部の遮光性が確保される。収容体1から記録材料Fを取り出す際は、折返部4を折り開いて開放された開口3から記録材料Fを取り出すことができる。なお、本実施形態の収容体1では、折返部4に限定されず、例えば、開口3が形成された側の端辺をチャックによって開閉可能にするチャック部を設けてもよい。   A recording material F and sensitizing members 5 disposed on both sides of the recording material F inside the storage part 2 are inserted into the storage part 2 of the storage body 1. After the recording material F and the sensitizing member 5 are accommodated in the accommodating portion 2, the folded portion 4 is formed in the accommodating body 1a by repeatedly folding the end on the side where the opening 3 is formed with a predetermined width. Thus, the opening 3 is shielded, and the light shielding property inside the housing portion 2 is ensured. When taking out the recording material F from the container 1, the recording material F can be taken out from the opening 3 that is opened by folding the folded portion 4. In addition, in the container 1 of this embodiment, it is not limited to the folding | returning part 4, For example, you may provide the chuck | zipper part which can open and close the edge of the side in which the opening 3 was formed with a chuck | zipper.

収容体1は、本実施形態のように収容部2に増感部材5を収容した構成に限られない。図2は、本実施形態の収容体の他の実施形態を示す断面図である。図2に示すように、収容体1は、収容部2の内側面に貼り付けた構成としてもよい。こうすれば、記録材料Fの挿入する際や取り出す際に収容部2の内部で増感部材5が移動して捩れやしわが生じることを防止することができる。   The housing 1 is not limited to the configuration in which the sensitizing member 5 is housed in the housing portion 2 as in the present embodiment. FIG. 2 is a cross-sectional view showing another embodiment of the container of the present embodiment. As shown in FIG. 2, the container 1 may be configured to be affixed to the inner surface of the container 2. In this way, when the recording material F is inserted or taken out, it is possible to prevent the sensitizing member 5 from moving inside the housing portion 2 and causing twists and wrinkles.

この収容体1は、遮光性材料からなる収容体本体1aを備えており、この収容体1に記録材料Fを収容しておくことで、記録材料Fが明室において感光してしまうことを防止することができるうえ、記録材料Fに直接手が触れることがないため指紋等の汚れが付着することを避けることができる。また、収容体1には増感部材5が装着されているため、記録材料Fを収容体1に収容したままでX線撮影を行うことができ、X線撮影装置において撮影を行う際に、記録材料を保持するカセッテ側に増感部材と同じ機能を奏するスクリーンを設ける必要がない。   The container 1 includes a container body 1a made of a light-shielding material. By storing the recording material F in the container 1, the recording material F is prevented from being exposed to light in a bright room. In addition, since the hand does not directly touch the recording material F, it is possible to avoid contamination such as fingerprints. Further, since the sensitizing member 5 is mounted on the container 1, X-ray imaging can be performed while the recording material F is stored in the container 1, and when imaging is performed in the X-ray imaging apparatus, It is not necessary to provide a screen having the same function as the sensitizing member on the cassette side holding the recording material.

図3は、本発明に係るカセッテを示す全体斜視図である。図3に示すように、カセッテ11は、記録材料Fを収容保持して、X線撮影装置に装填し、保持した記録材料にX線照射するためのものである。   FIG. 3 is an overall perspective view showing a cassette according to the present invention. As shown in FIG. 3, the cassette 11 is for accommodating and holding the recording material F, loading the X-ray imaging apparatus, and irradiating the held recording material with X-rays.

図3に示すように、カセッテ11は、記録材料Fと面接触する四角形状の底面12aとこの底面12aの周縁部を囲うようにして立設されたリブ14とを有するカセッテ本体12を備えている。また、カセッテ11は、この本体12のリブによって囲まれた部位に記録材料Fを配置可能で、この部位を開放/遮蔽する蓋部13を備えている。カセッテ11に記録材料Fをセットする場合は、蓋部13を開き、カセッテ本体12に記録材料Fを配置して蓋部13を閉じる。   As shown in FIG. 3, the cassette 11 includes a cassette body 12 having a rectangular bottom surface 12 a in surface contact with the recording material F and a rib 14 erected so as to surround the peripheral edge of the bottom surface 12 a. Yes. Further, the cassette 11 can be provided with a recording material F at a portion surrounded by the ribs of the main body 12 and includes a lid portion 13 that opens / shields the portion. When setting the recording material F in the cassette 11, the lid portion 13 is opened, the recording material F is disposed on the cassette body 12, and the lid portion 13 is closed.

カセッテ本体12に収容体1を収容させて蓋部13を閉じることで、収容体1の内部に収容された記録材料と増感部材との密着度合を強くすることができる。   By accommodating the container 1 in the cassette body 12 and closing the lid 13, the degree of adhesion between the recording material and the sensitizing member accommodated in the container 1 can be increased.

記録材料Fには増感部材5が備えられているため、カセッテ11の底面12aや蓋部13の内側面(蓋部13を閉じた場合における底面12a側の面)には、従来のようにスクリーンなどを設ける必要がない。このため、カセッテの清掃等のメンテナンスが容易になる。   Since the recording material F includes the sensitizing member 5, the bottom surface 12 a of the cassette 11 and the inner surface of the lid portion 13 (the surface on the bottom surface 12 a side when the lid portion 13 is closed) are provided as in the conventional case. There is no need to provide a screen. For this reason, maintenance such as cleaning of the cassette becomes easy.

次に、本発明に係る感光性熱現像記録材料を図面を参照して説明する。
図4は、本発明に係る感光性熱現像記録材料の断面図である。図4に示すように記録材料40は、支持体41と、該支持体41の両側の面に設けられた感光層42とを有している。
Next, the photosensitive heat-developable recording material according to the present invention will be described with reference to the drawings.
FIG. 4 is a cross-sectional view of the photosensitive heat-developable recording material according to the present invention. As shown in FIG. 4, the recording material 40 includes a support 41 and photosensitive layers 42 provided on both sides of the support 41.

また、記録材料40において、上記感光層42の表面には増感層43が設けられている。なお、記録材料40は、支持体の片側の面にのみ感光層42が設けられた構成としてもよく、支持体41の両側の面に設けられた感光層42のうち、一方の感光層42の表面にのみ増感層43が設けられた構成としてもよい。   Further, in the recording material 40, a sensitizing layer 43 is provided on the surface of the photosensitive layer. The recording material 40 may have a structure in which the photosensitive layer 42 is provided only on one side of the support. Of the photosensitive layers 42 provided on both sides of the support 41, one of the photosensitive layers 42 is provided. The sensitizing layer 43 may be provided only on the surface.

以下、図4に示す感光性熱現像記録材料の製造工程を説明する。図5は、図4の感光性熱現像記録材料の製造工程を概念的に説明する図である。
図5に示すように、支持体原反ロールR11から支持体41が巻き出される。巻き出された支持体41の両側の面には感光材が塗布され、感光層42が形成される。感光層42の形成された支持体41の搬送路を挟む上方と下方には増感材原反ロールR13が配設される。増感材原反ロールR13から巻き出された増感材(増感層43)は、ガイドローラ25によってガイドされながら吸着ローラ対27によって支持体41の両面に押し付けられ、搬送方向下流側に配設された一対の加熱圧着ローラ29によってヒートシールされる。このようにして表裏両側に増感層43が設けられた支持体41は、加熱圧着ローラ29の下流側で所定の寸法で裁断されて、記録材料40となる。
Hereinafter, the manufacturing process of the photosensitive heat-developable recording material shown in FIG. 4 will be described. FIG. 5 is a diagram conceptually illustrating the manufacturing process of the photosensitive heat-developable recording material of FIG.
As shown in FIG. 5, the support body 41 is unwound from the support body roll R11. A photosensitive material is applied to both sides of the unwound support 41 to form a photosensitive layer 42. A sensitizer original roll R13 is disposed above and below the conveyance path of the support 41 on which the photosensitive layer 42 is formed. The sensitizing material (sensitizing layer 43) unwound from the sensitizing material roll R13 is pressed against both surfaces of the support 41 by the suction roller pair 27 while being guided by the guide roller 25, and is arranged downstream in the transport direction. Heat sealing is performed by a pair of thermocompression-bonding rollers 29 provided. Thus, the support 41 having the sensitizing layers 43 provided on both the front and back sides is cut to a predetermined size on the downstream side of the heat press roller 29 to be the recording material 40.

この記録材料40の製造方法では、感光材を塗布した直後の支持体41に、一対の増感層43を表裏両面からラミネートし、ラミネート後に支持体41、感光層42及び増感層43を裁断する。   In this method of manufacturing the recording material 40, a pair of sensitizing layers 43 are laminated on both sides of the support 41 immediately after applying the photosensitive material, and after the lamination, the support 41, the photosensitive layer 42 and the sensitizing layer 43 are cut. To do.

裁断されて得られる記録材料40が収容体21に収容される。収容体21は、少なくとも外側が遮光材料からなり、その構成は図1で説明した収容体1と基本的に同じであるが、収容体本体に増感部材5を備えていない点で相違する。   The recording material 40 obtained by cutting is accommodated in the container 21. The housing 21 is made of a light shielding material at least on the outside, and the configuration thereof is basically the same as that of the housing 1 described with reference to FIG. 1, but is different in that the sensitizing member 5 is not provided in the housing body.

図5に示す記録材料の製造工程で得られた記録材料を収容する収容体にX線撮影を行う工程を説明する。図6は、記録材料の収容体にX線撮影を行う工程を模式的に説明する図である。
収容体21に収容された記録材料40にX線Xを照射して、該記録材料40の感光層に潜像を形成する。X線を照射した後、記録材料40を収容した収容体21を熱現像装置48によって熱現像する。熱現像後、収容体21から記録材料40を取り出し、増感層43を感光層42(支持体41)から剥離する。
A process of performing X-ray imaging on a container that accommodates the recording material obtained in the recording material manufacturing process shown in FIG. 5 will be described. FIG. 6 is a diagram schematically illustrating a process of performing X-ray imaging on a recording material container.
The recording material 40 accommodated in the container 21 is irradiated with X-rays X to form a latent image on the photosensitive layer of the recording material 40. After the X-ray irradiation, the container 21 containing the recording material 40 is thermally developed by the heat developing device 48. After the thermal development, the recording material 40 is taken out from the container 21, and the sensitizing layer 43 is peeled off from the photosensitive layer 42 (support 41).

図4に示す感光性熱現像記録材料40では、感光層42の表面に増感層43が設けられる構成であり、同じ製造工程で、支持体41に感光層42を形成するとともにこの感光層42の表面に増感層43をラミネートすればよいため、製造が容易である。また、感光性熱現像記録材料40は増感層43を備えているため、従来のようにX線撮影装置に供されるカセッテ内部に増感部材として機能するスクリーンを装着する必要がない。   The photosensitive heat-developable recording material 40 shown in FIG. 4 has a structure in which a sensitizing layer 43 is provided on the surface of the photosensitive layer 42. In the same manufacturing process, the photosensitive layer 42 is formed on the support 41 and the photosensitive layer 42 is formed. Since the sensitizing layer 43 may be laminated on the surface, the manufacture is easy. Further, since the photosensitive heat-developable recording material 40 is provided with the sensitizing layer 43, it is not necessary to attach a screen functioning as a sensitizing member inside a cassette provided for an X-ray imaging apparatus as in the prior art.

また、図5で示すように、1つの製造工程の中で、本発明に係る感光性熱現像記録材料の製造方法は、支持体41に感光層42を形成する工程と感光層42の表面に増感層43をラミネートする工程と、支持体41を裁断する工程を有しているため、感光性熱現像記録材料を効率良く製造することができる。   Further, as shown in FIG. 5, in one manufacturing process, the method for manufacturing a photosensitive heat-developable recording material according to the present invention includes a step of forming a photosensitive layer 42 on a support 41 and a surface of the photosensitive layer 42. Since the method includes the step of laminating the sensitizing layer 43 and the step of cutting the support 41, the photosensitive heat-developable recording material can be produced efficiently.

図7は、本発明に係る感光性熱現像記録材料の収容体の第2の実施形態を示す斜視図である。
図7に示すように、収容体31は、収容体本体31aと、該収容体本体31aの内部に設けられた、記録材料(例えば、図1の記録材料Fを用いることができる。)を収容するための収容部32とを有している。収容体本体31aは、底を有する長尺の袋状部材であり、一方の端部に形成された開口34から記録材料Fを挿入可能な構成である。収容体31は、収容体本体1aにおいて少なくとも表面が遮光性材料からなる部材である。遮光性材料としては、上記と同じものを使用することができる。
FIG. 7 is a perspective view showing a second embodiment of the photosensitive heat-developable recording material container according to the present invention.
As shown in FIG. 7, the container 31 houses a container body 31a and a recording material (for example, the recording material F shown in FIG. 1) provided in the container body 31a. And an accommodating portion 32 for carrying out the operation. The container main body 31a is a long bag-like member having a bottom, and is configured such that the recording material F can be inserted through an opening 34 formed at one end. The container 31 is a member having at least a surface made of a light shielding material in the container body 1a. As the light shielding material, the same materials as described above can be used.

本実施形態の収容体31の収容部本体31aには、収容部32を2つの区間に仕切るように収容部32の内部の周縁と一体に成形された仕切り部35が設けられている。この仕切り部35によって開口34も上面側開口36と下面側開口37との2つに分割されている。   The housing portion 31a of the housing body 31 of the present embodiment is provided with a partition portion 35 formed integrally with the inner periphery of the housing portion 32 so as to partition the housing portion 32 into two sections. The opening 34 is also divided into two, an upper surface side opening 36 and a lower surface side opening 37, by the partition portion 35.

言い換えると、収容部32において仕切り部35によって区画された空間が一対のポケット部となり、これら一対のポケット部がそれぞれ分割された上面側開口36と下面側開口37を介して収容体31の外部とそれぞれ連通している。   In other words, the space defined by the partition portion 35 in the storage portion 32 becomes a pair of pocket portions, and the pair of pocket portions are respectively separated from the outside of the storage body 31 via the upper surface side opening 36 and the lower surface side opening 37. Each communicates.

本実施形態の収容部32は、一対のポケット部のうち一方で感光性熱現像記録材料(例えば、図1の記録材料Fを用いることができる。以下省略)を保持でき、他方で増感部材5を保持できるように構成されている。   The accommodating portion 32 of the present embodiment can hold a photosensitive heat-developable recording material (for example, the recording material F of FIG. 1 can be used; hereinafter omitted) out of a pair of pocket portions, and on the other hand, a sensitizing member. 5 can be held.

仕切り部35には、記録材料Fの型やこの記録材料にX線照射によって形成される潜像のサイズ並びに位置に応じた寸法の窓部35aが形成されている。   The partition portion 35 is formed with a window portion 35a having a size corresponding to the type of the recording material F and the size and position of the latent image formed on the recording material by X-ray irradiation.

収容体31の収容部32の内部に区画されるポケット部の数は本実施形態のように2つに限定されず、仕切り部35によって3つ以上に区画されてもよい。   The number of pocket portions defined inside the accommodating portion 32 of the accommodating body 31 is not limited to two as in this embodiment, and may be divided into three or more by the partition portion 35.

図8は、図7に示す収容体に感光性熱現像記録材料と増感材料とを収容させた状態を示す断面図である。図7及び図8に示すように、収容体31の収容部32には記録材料Fと増感材料5とが仕切り部35で仕切られた状態で保持されている。また、収容体31は、仕切り部35の中央部に窓部35aが形成され、この窓部35aによって開放された箇所においては、記録材料Fと増感材料5とが互いに露呈しあい、直接接触する構成である。このため、収容体31にX線照射すると、記録材料Fにおいて窓部35aによって開放された箇所では増感部材5により感光層の反応が強められつつ潜像が形成されるようになる。   FIG. 8 is a cross-sectional view showing a state in which the photosensitive heat-developable recording material and the sensitizing material are accommodated in the container shown in FIG. As shown in FIGS. 7 and 8, the recording material F and the sensitizing material 5 are held in the storage portion 32 of the storage body 31 in a state of being partitioned by the partition portion 35. The container 31 has a window 35a formed at the center of the partition 35, and the recording material F and the sensitizing material 5 are exposed to each other and are in direct contact with each other at a position opened by the window 35a. It is a configuration. For this reason, when the container 31 is irradiated with X-rays, a latent image is formed while the reaction of the photosensitive layer is intensified by the sensitizing member 5 in the portion of the recording material F opened by the window 35a.

図9は、図7、8に示す感光性熱現像記録材料の収容体を使用してX線撮影及び熱現像の工程を模式的に説明する図である。収容体31の一対のポケットの一方に記録材料Fを収容し、他方に増感部材5を収容する。記録材料F及び増感部材5を収容した収容体31にX線Xを照射して記録材料Fの感光層に潜像を形成する。X線撮影の際には収容部31をカセット(図3参照)に収容保持させた状態でX線を照射してもよい。次に、収容体31を直接、熱現像装置に装填し、熱現像を行なう。熱現像後に、収容体31から記録材料Fを取り出す。このとき、増感部材5を所定回数使用可能に構成すれば、そのままポケット部に収容させた状態で、新しい記録材料Fを収容することで、収容体31を繰り返して使用すること(リサイクル)ができる。   FIG. 9 is a diagram schematically illustrating the steps of X-ray imaging and heat development using the photosensitive heat-developable recording material container shown in FIGS. The recording material F is accommodated in one of the pair of pockets of the accommodating body 31, and the sensitizing member 5 is accommodated in the other. The container 31 containing the recording material F and the sensitizing member 5 is irradiated with X-rays X to form a latent image on the photosensitive layer of the recording material F. In X-ray imaging, X-rays may be irradiated in a state where the accommodating portion 31 is accommodated and held in a cassette (see FIG. 3). Next, the container 31 is directly loaded into the heat developing apparatus, and heat development is performed. After the thermal development, the recording material F is taken out from the container 31. At this time, if the sensitizing member 5 is configured to be usable a predetermined number of times, it is possible to repeatedly use (recycle) the container 31 by accommodating the new recording material F while being accommodated in the pocket portion as it is. it can.

次に、本発明に係る感光性熱現像記録材料の第3の実施形態を説明する。なお、以下に説明する実施形態において、すでに説明した部材などと同等な構成・作用を有する部材等については説明を簡略化或いは省略する。本実施形態の収容体の基本的な構成は図1に示す収容体の構成と同じであるが、遮光性材料として収容体本体が感光波長を遮断するための感光フィルタ機能を有する材料で構成されている点で相違する。感光フィルタ機能を有する材料としては、例えば、500nm以下の波長を有する有色光を遮断する遮光性材料を使用することができる。   Next, a third embodiment of the photosensitive heat-developable recording material according to the present invention will be described. In the embodiments described below, the description of members having the same configuration / action as the members already described is simplified or omitted. The basic structure of the container of the present embodiment is the same as the structure of the container shown in FIG. 1, but the container body is made of a material having a photosensitive filter function for blocking the photosensitive wavelength as a light shielding material. Is different. As a material having a photosensitive filter function, for example, a light-shielding material that blocks colored light having a wavelength of 500 nm or less can be used.

本実施形態において、500nm以下の波長を有する有色光を遮断する遮光性材料を使用することで、収容体に収容した記録材料の状態を収容体外部から視認することができる。このため、収容体を直接熱現像装置に装填して熱現像を行う際に、収容体から記録材料を取り出すことなく現像の状態を確認することができるため使い勝手が良い。   In this embodiment, by using a light-shielding material that blocks colored light having a wavelength of 500 nm or less, the state of the recording material accommodated in the container can be visually recognized from the outside of the container. For this reason, when carrying out thermal development by directly loading the container into the thermal development apparatus, the state of development can be confirmed without taking out the recording material from the container, which is convenient.

次に、本発明の蛍光増感紙(放射線増感スクリーン)について説明する。放射線増感スクリーンは、基本構造として、支持体と、その片面に形成された蛍光体層とからなる。蛍光体層は、蛍光体が結合剤(バインダ)中に分散されてなる層である。なお、この蛍光体層の支持体とは反対側の表面(支持体に面していない側の表面)には一般に、透明な保護膜が設けられていて、蛍光体層を化学的な変質あるいは物理的な衝撃から保護している。   Next, the fluorescent intensifying screen (radiation intensifying screen) of the present invention will be described. The radiation intensifying screen includes, as a basic structure, a support and a phosphor layer formed on one side thereof. The phosphor layer is a layer in which a phosphor is dispersed in a binder. In general, a transparent protective film is provided on the surface of the phosphor layer opposite to the support (the surface not facing the support), and the phosphor layer is chemically altered or Protects against physical shock.

本発明において、好ましい蛍光体としては、以下に示すものが挙げられる。
タングステン酸塩系蛍光体(CaWO4、MgWO4、CaWO4:Pb等)、テルビウム賦活希土類酸硫化物系蛍光体〔Y22S:Tb、Gd22S:Tb、La22S:Tb、(Y,Gd)22S:Tb、(Y,Gd)O2S:Tb,Tm等〕、テルビウム賦活希土類燐酸塩系蛍光体(YPO4:Tb、GdPO4:Tb、LaPO4:Tb等)、テルビウム賦活希土類オキシハロゲン化物系蛍光体(LaOBr:Tb、LaOBr:Tb,Tm、LaOCl:Tb、LaOCl:Tb,Tm、LaOBr:Tb、GdOBr:Tb、GdOCl:Tb等)、ツリウム賦活希土類オキシハロゲン化物系蛍光体(LaOBr:Tm、LaOCl:Tm等)、硫酸バリウム系蛍光体〔BaSO4:Pb、BaSO4:Eu2+、(Ba,Sr)SO4:Eu2+等〕、2価のユーロピウム賦活アルカリ土類金属燐酸塩系蛍光体〔(Ba2PO42:Eu2+、(Ba2PO42:Eu2+等〕、2価のユーロピウム賦活アルカリ土類金属弗化ハロゲン化物系蛍光体〔BaFCl:Eu2+、BaFBr:Eu2+、BaFCl:Eu2+,Tb、BaFBr:Eu2+,Tb、BaF2・BaCl・KCl:Eu2+、(Ba,Mg)F2・BaCl・KCl:Eu2+等〕、沃化物系蛍光体(CsI:Na、CsI:Tl、NaI、KI:Tl等)、硫化物系蛍光体〔ZnS:Ag(Zn,Cd)S:Ag、(Zn,Cd)S:Cu、(Zn,Cd)S:Cu,Al等〕、燐酸ハフニウム系蛍光体(HfP27:Cu等)、YTaO4 及びそれに発光中心として各種付活剤を加えたもの。但し本発明に用いられる蛍光体はこれらに限定されるものではなく、放射線の照射によって可視又は近紫外領域の発光を示す蛍光体であれば使用できる。
In the present invention, preferred phosphors include those shown below.
Tungstate phosphors (CaWO 4 , MgWO 4 , CaWO 4 : Pb, etc.), terbium activated rare earth oxysulfide phosphors [Y 2 O 2 S: Tb, Gd 2 O 2 S: Tb, La 2 O 2 S: Tb, (Y, Gd) 2 O 2 S: Tb, (Y, Gd) O 2 S: Tb, Tm, etc.], terbium-activated rare earth phosphate phosphors (YPO 4 : Tb, GdPO 4 : Tb, LaPO 4 : Tb, etc.), terbium activated rare earth oxyhalide phosphors (LaOBr: Tb, LaOBr: Tb, Tm, LaOCl: Tb, LaOCl: Tb, Tm, LaOBr: Tb, GdOBr: Tb, GdOCl: Tb, etc.) , Thulium activated rare earth oxyhalide phosphors (LaOBr: Tm, LaOCl: Tm, etc.), barium sulfate phosphors [BaSO 4 : Pb, BaSO 4 : Eu 2+ , (Ba , Sr) SO 4 : Eu 2+ etc.], divalent europium activated alkaline earth metal phosphate phosphor [(Ba 2 PO 4 ) 2 : Eu 2+ , (Ba 2 PO 4 ) 2 : Eu 2+ Etc.] Divalent europium activated alkaline earth metal fluoride halide phosphor [BaFCl: Eu 2+ , BaFBr: Eu 2+ , BaFCl: Eu 2+ , Tb, BaFBr: Eu 2+ , Tb, BaF 2 BaCl · KCl: Eu 2+ , (Ba, Mg) F 2 .BaCl · KCl: Eu 2+ etc.], iodide phosphors (CsI: Na, CsI: Tl, NaI, KI: Tl etc.), sulfide Physical phosphors [ZnS: Ag (Zn, Cd) S: Ag, (Zn, Cd) S: Cu, (Zn, Cd) S: Cu, Al, etc.], hafnium phosphate phosphors (HfP 2 O 7 : Cu, etc.), was also added various activator as YTaO 4 and the light emission center to it . However, the phosphor used in the present invention is not limited to these, and any phosphor that emits light in the visible or near ultraviolet region when irradiated with radiation can be used.

本発明で用いる蛍光増感紙は、傾斜粒径構造で蛍光体を充填することが好ましい。特に表面保護層側に大粒径の蛍光体粒子を塗布し、支持体側に小粒径の蛍光体粒子を塗布することが好ましく、小粒径のものは0.5〜2.0μmで、大粒径のものは10〜30μmの範囲が好ましい。   The fluorescent intensifying screen used in the present invention is preferably filled with a phosphor with an inclined particle size structure. In particular, it is preferable to apply phosphor particles having a large particle size to the surface protective layer side, and to apply phosphor particles having a small particle size to the support side, and those having a small particle size are 0.5 to 2.0 μm and large. The thing of a particle size has the preferable range of 10-30 micrometers.

また、本発明で用いる蛍光増感紙は、80〜250℃の温度において現像されるため、支持体であるPET(ポリエチレンテレフタレート)は耐熱グレードタイプであると共に、蛍光体を透明なシリコン樹脂でモールディングすることが好ましい。   In addition, since the fluorescent intensifying screen used in the present invention is developed at a temperature of 80 to 250 ° C., the support PET (polyethylene terephthalate) is a heat-resistant grade type, and the phosphor is molded with a transparent silicone resin. It is preferable to do.

(紫外蛍光スクリーンとの組合せ)
本発明の熱現像感光材料を用いた画像形成方法としては、好ましくは400nm以下に主ピークを持つ蛍光体との組み合わせで画像形成する方法を用いることができる。さらに好ましくは380nm以下に主ピークを持つ蛍光体と組み合わせて画像形成する方法が良い。両面感材、片面感材のいずれでも組立て体として用いることができる。400nm以下に主発光ピークであるスクリーンは特開平6−11804号、WO93/01521号に記載のスクリーンなどが使われるがこれに限られるものではない。紫外線のクロスオーバーカット(両面感光材料)とアンチハレーション(片面感光材料)の技術としては、特開平8−76307号公報に記載の技術を用いることができる。紫外線吸収染料としては、特願2000−320809号に記載の染料は特に好ましい。
(Combination with ultraviolet fluorescent screen)
As an image forming method using the photothermographic material of the present invention, a method of forming an image by combining with a phosphor having a main peak preferably at 400 nm or less can be used. More preferably, a method of forming an image in combination with a phosphor having a main peak at 380 nm or less is preferable. Either a double-sided sensitive material or a single-sided sensitive material can be used as an assembly. As the screen having a main emission peak at 400 nm or less, the screens described in JP-A-6-11804 and WO93 / 01521 are used, but not limited thereto. As a technique of ultraviolet crossover cut (double-sided photosensitive material) and antihalation (single-sided photosensitive material), the technique described in JP-A-8-76307 can be used. As the ultraviolet absorbing dye, the dye described in Japanese Patent Application No. 2000-320809 is particularly preferable.

次に、本発明に係る感光性熱現像記録材料の収容体の第4の実施形態を説明する。
図10は、本実施形態の感光性熱現像記録材料の収容体を示す斜視図である。図11は、図10に示す感光性熱現像記録材料の収容体のA−A線断面図である。図10及び図11に示すように、本実施形態の収容体51は、収容体本体51aと収容体本体51の内部に設けられた収容部52とを有している。収容体本体51aは、底を有する長尺の袋状部材であり、一方の端部に開口54が形成され、この開口54から記録材料F及び増感部材5を挿入可能な構成である。収容体51は、収容体本体51aの少なくとも表面が上記遮光性材料からなる部材である。
Next, a fourth embodiment of the photosensitive heat-developable recording material container according to the present invention will be described.
FIG. 10 is a perspective view showing a photosensitive heat-developable recording material container according to the present embodiment. 11 is a cross-sectional view taken along the line AA of the photosensitive heat-developable recording material container shown in FIG. As shown in FIGS. 10 and 11, the container 51 of the present embodiment includes a container body 51 a and a container 52 provided inside the container body 51. The container body 51 a is a long bag-like member having a bottom, and has an opening 54 formed at one end, and the recording material F and the sensitizing member 5 can be inserted through the opening 54. The container 51 is a member in which at least the surface of the container body 51a is made of the light shielding material.

本実施形態の収容体51の収容体本体51aには、収容部52を3つの空間に仕切るように収容部52の内部の周縁と一体に成形された2つの仕切り部55,56が設けられている。収容部52はこれら仕切り部55,56によって3つのポケット部52a,52b,52cに区画される。   The container body 51a of the container 51 of the present embodiment is provided with two partition parts 55 and 56 that are formed integrally with the inner periphery of the container part 52 so as to partition the container part 52 into three spaces. Yes. The accommodating portion 52 is divided into three pocket portions 52a, 52b, and 52c by the partition portions 55 and 56.

また、これら仕切り部55,56のそれぞれには窓部55a,56aが形成されている。これら窓部55a,56aは、記録材料Fの型やこの記録材料FにX線照射によって形成される潜像のサイズ並びに位置に適応する寸法である。   In addition, window portions 55a and 56a are formed in the partition portions 55 and 56, respectively. The window portions 55a and 56a have dimensions adapted to the type of the recording material F and the size and position of the latent image formed on the recording material F by X-ray irradiation.

3つのポケット部52a,52b,52cのうち、外側の2つのポケット部52a及び52cには、それぞれ増感部材5が収容され、内側のポケット部52bには、記録材料Fが収容される。   Of the three pocket portions 52a, 52b, and 52c, the outer two pocket portions 52a and 52c each contain the sensitizing member 5, and the inner pocket portion 52b contains the recording material F.

本実施形態の収容体51は、両面に感光層が形成された記録材料Fを収容し、該記録材料Fの両面側のポケット部52a,52cに収容された増感部材5によってこれら感光層でのX線照射による潜像が明瞭に形成されるようになる。   The container 51 of the present embodiment accommodates a recording material F having a photosensitive layer formed on both sides, and the sensitizing member 5 accommodated in the pocket portions 52a and 52c on both sides of the recording material F is used for these photosensitive layers. The latent image by X-ray irradiation is clearly formed.

次に、本発明に係る感光性熱現像記録材料の他の実施形態を説明する。
図12は、本実施形態の感光性熱現像記録材料の収容体を示す断面図である。図12に示すように、感光性熱現像記録材料60は、支持体61と、支持体61の両側の面に設けられた感光層62と、これら感光層62それぞれの表面に形成された増感層63と有している。
Next, another embodiment of the photosensitive heat-developable recording material according to the present invention will be described.
FIG. 12 is a cross-sectional view showing a photosensitive heat-developable recording material container according to this embodiment. As shown in FIG. 12, the photosensitive heat-developable recording material 60 includes a support 61, photosensitive layers 62 provided on both sides of the support 61, and sensitization formed on the surfaces of these photosensitive layers 62. Layer 63.

さらに、感光性熱現像記録材料60は、これら増感層63それぞれの表面が遮光層64で覆われている。   Further, the surface of each of the sensitized layers 63 of the photosensitive heat development recording material 60 is covered with a light shielding layer 64.

この感光性熱現像記録材料60は、遮光層64で覆われているため、遮光材料からなる収容体や従来のカセッテに収容しない状態でも明室で取り扱うことができるため、暗室での作業を必要としない点で使い勝手がよい。また、X線撮影時には、この感光性熱現像記録材料60にX線照射を行なうことができ、熱現像時には、この記録材料60をそのまま熱現像装置に装填することで、熱現像処理を施すことができ、熱現像後に、遮光層64及び増感層63とを剥離することで、現像した記録材料60を得ることができる。   Since this photosensitive heat-developable recording material 60 is covered with a light-shielding layer 64, it can be handled in a bright room even if it is not housed in a container made of a light-shielding material or a conventional cassette. It ’s easy to use. Further, at the time of X-ray imaging, the photosensitive heat development recording material 60 can be irradiated with X-rays, and at the time of heat development, the recording material 60 is directly loaded into a heat development apparatus to perform heat development processing. After the heat development, the light-shielding layer 64 and the sensitizing layer 63 are peeled off, whereby the developed recording material 60 can be obtained.

次に、図12に示す感光性熱現像記録材料の製造工程を説明する。
図13は、図12の感光性熱現像記録材料の製造工程を概念的に説明する図である。図13に示すように、支持体原反ロールR61から支持体61が巻き出される。巻き出された支持体61の両側の面には感光材が塗布され、感光層62が形成される。感光層62の形成された支持体61の搬送路を挟む上方と下方には増感材原反ロールR63が配設される。増感材原反ロールR63から巻き出された増感材(増感層63)は、ガイドローラ65によってガイドされながら吸着ローラ対67によって支持体61の両面に押し付けられ、搬送方向下流側に配設された一対の加熱圧着ローラ69によってヒートシールされる。このようにして表裏両側に増感層63が設けられた支持体61の搬送路を挟む上方と下方には遮光材原反ロールR64が配設される。増感材原反ロールR64から巻き出された遮光材(遮光層64)は、ガイドローラ71によってガイドされながら吸着ローラ対72によって支持体61の両面に押し付けられ、搬送方向下流側に配設された一対の加熱圧着ローラ73によってヒートシールされる。表裏両側に遮光層64が設けられた支持体61は、加熱圧着ローラ73の下流側で所定の寸法で裁断されて、記録材料60となる。
Next, the manufacturing process of the photosensitive heat development recording material shown in FIG. 12 will be described.
FIG. 13 is a diagram conceptually illustrating the manufacturing process of the photosensitive heat-developable recording material of FIG. As shown in FIG. 13, the support body 61 is unwound from the support body roll R61. A photosensitive material is applied to both sides of the unwound support 61 to form a photosensitive layer 62. A sensitizer original fabric roll R63 is disposed above and below the conveyance path of the support 61 on which the photosensitive layer 62 is formed. The sensitizing material (sensitized layer 63) unwound from the sensitizing material roll R63 is pressed against both surfaces of the support 61 by the suction roller pair 67 while being guided by the guide roller 65, and is arranged downstream in the transport direction. Heat sealing is performed by a pair of thermocompression-bonding rollers 69 provided. Thus, the light-shielding material roll R64 is disposed above and below the conveyance path of the support 61 provided with the sensitizing layers 63 on both the front and back sides. The light shielding material (light shielding layer 64) unwound from the sensitizing material roll R64 is pressed against both surfaces of the support 61 by the suction roller pair 72 while being guided by the guide roller 71, and is disposed downstream in the transport direction. The pair of heat press rollers 73 are heat sealed. The support 61 provided with the light shielding layers 64 on both the front and back sides is cut to a predetermined size on the downstream side of the heat press roller 73 to become the recording material 60.

この記録材料Fの製造方法では、1つの製造工程の中で、支持体61に感光層62を形成する工程と感光層62の表面に増感層63をラミネートする工程と、増感層63の表面に遮光層64をラミネートする工程と、支持体61を裁断する工程を有しているため、図12に示す明室で取り扱うことができる感光性熱現像記録材料60を効率良く製造することができる。   In the manufacturing method of the recording material F, in one manufacturing process, the step of forming the photosensitive layer 62 on the support 61, the step of laminating the sensitizing layer 63 on the surface of the photosensitive layer 62, Since the method includes the step of laminating the light shielding layer 64 on the surface and the step of cutting the support 61, the photosensitive heat development recording material 60 that can be handled in the bright room shown in FIG. 12 can be efficiently manufactured. it can.

本発明の熱現像感光材料はいかなる方法で現像されても良いが、通常イメージワイズに露光した熱現像感光材料を昇温して現像される。好ましい現像温度としては80〜250℃であり、さらに好ましくは100〜140℃である。
現像時間としては1〜60秒が好ましく、5〜30秒がさらに好ましく、5〜20秒が特に好ましい。
The photothermographic material of the present invention may be developed by any method, but is usually developed by raising the temperature of the photothermographic material exposed imagewise. The preferred development temperature is 80 to 250 ° C, more preferably 100 to 140 ° C.
The development time is preferably 1 to 60 seconds, more preferably 5 to 30 seconds, and particularly preferably 5 to 20 seconds.

熱現像の方式としてはプレートヒーター方式が好ましい。プレートヒーター方式による熱現像方式とは特開平11-133572号に記載の方法が好ましく、潜像を形成した熱現像感光材料を熱現像部にて加熱手段に接触させることにより可視像を得る熱現像装置であって、前記加熱手段がプレートヒータからなり、かつ前記プレートヒータの一方の面に沿って複数個の押えローラが対向配設され、前記押えローラと前記プレートヒータとの間に前記熱現像感光材料を通過させて熱現像を行うことを特徴とする熱現像装置である。プレートヒータを2〜6段に分けて先端部については1〜10℃程度温度を下げることが好ましい。   A plate heater method is preferred as the heat development method. The heat development method using a plate heater method is preferably a method described in JP-A-11-133572, in which a heat-developable photosensitive material on which a latent image has been formed is brought into contact with a heating means in a heat-development section to obtain a visible image In the developing device, the heating unit includes a plate heater, and a plurality of press rollers are disposed to face each other along one surface of the plate heater, and the heat is interposed between the press roller and the plate heater. A thermal development apparatus that performs thermal development by passing a development photosensitive material. It is preferable to divide the plate heater into 2 to 6 stages and lower the temperature about 1 to 10 ° C. at the tip.

このような方法は特開昭54-30032号にも記載されており、熱現像感光材料に含有している水分や有機溶媒を系外に除外させることができ、また、急激に熱現像感光材料が加熱されることでの熱現像感光材料の支持体形状の変化を押さえることもできる。   Such a method is also described in JP-A-54-30032, which can exclude moisture and organic solvents contained in the photothermographic material out of the system, and can be rapidly developed in the photothermographic material. It is also possible to suppress changes in the shape of the support of the photothermographic material due to heating of the photothermographic material.

本発明に係る感光性熱現像記録材料の収容体の第1の実施形態を説明する図である。It is a figure explaining 1st Embodiment of the container of the photosensitive heat development recording material which concerns on this invention. 第1の実施形態の収容体の他の実施形態を示す断面図である。It is sectional drawing which shows other embodiment of the container of 1st Embodiment. 本発明に係るカセッテを示す全体斜視図である。1 is an overall perspective view showing a cassette according to the present invention. 本発明に係る感光性熱現像記録材料の断面図である1 is a cross-sectional view of a photosensitive heat development recording material according to the present invention. 図5は、図4の感光性熱現像記録材料の製造工程を概念的に説明する図である。FIG. 5 is a diagram conceptually illustrating the manufacturing process of the photosensitive heat-developable recording material of FIG. 記録材料の収容体にX線撮影を行う工程を模式的に説明する図である。It is a figure which illustrates typically the process of performing a X-ray imaging on the container of a recording material. 本発明に係る感光性熱現像記録材料の収容体の第2の実施形態を示す斜視図である。It is a perspective view which shows 2nd Embodiment of the container of the photosensitive heat development recording material which concerns on this invention. 図7に示す収容体に感光性熱現像記録材料と増感材料とを収容させた状態を示す断面図である。It is sectional drawing which shows the state which accommodated the photosensitive heat development recording material and the sensitizing material in the container shown in FIG. 図7、8に示す感光性熱現像記録材料の収容体を使用してX線撮影及び熱現像の工程を模式的に説明する図である。It is a figure which illustrates typically the process of a radiography and heat development using the container of the photosensitive heat development recording material shown in FIG. 本発明に係る感光性熱現像記録材料の収容体の第4の実施形態を示す図である。It is a figure which shows 4th Embodiment of the container of the photosensitive heat development recording material which concerns on this invention. 図10に示す感光性熱現像記録材料の収容体のA−A線断面図である。FIG. 11 is a cross-sectional view taken along the line AA of the photosensitive heat-developable recording material container shown in FIG. 10. 本発明に係る感光性熱現像記録材料の他の実施形態を示す断面図である。It is sectional drawing which shows other embodiment of the photosensitive heat development recording material which concerns on this invention. 図12に示す感光性熱現像記録材料の製造工程を概念的に説明する図である。It is a figure which illustrates notionally the manufacturing process of the photosensitive heat development recording material shown in FIG.

符号の説明Explanation of symbols

1,21,31,51 (感光性熱現像記録材料の)収容体
2 収容部
5 増感部材
11 カセッテ
40,60 感光性熱現像記録材料
1, 2, 31, 51 (for photosensitive heat-developable recording material) container 2 container 5 sensitizing member 11 cassette 40, 60 photosensitive heat-developable recording material

Claims (8)

支持体の少なくとも一方の面上に、感光性ハロゲン化銀、非感光性有機銀塩、還元剤、及びバインダを含有する画像形成層を設けた感光性熱現像記録材料を収納する感光性熱現像記録材料の収容体であって、
前記感光性熱現像記録材を収容する収容部を有し、少なくとも表面が遮光性材料からなる収容体本体を備え、
前記収容部に増感部材が備えられていることを特徴とする感光性熱現像記録材料の収容体。
Photosensitive thermal development containing a photosensitive thermal development recording material provided with an image forming layer containing photosensitive silver halide, non-photosensitive organic silver salt, reducing agent, and binder on at least one surface of the support A container for recording material,
A housing portion for housing the photosensitive heat-developable recording material, and comprising a housing body having at least a surface made of a light-shielding material;
A photosensitive heat-developable recording material container, wherein the container is provided with a sensitizing member.
前記増感部材が収容部の前記感光性熱現像記録材料の前記画像形成層に対向する内側面に貼り付けられていることを特徴とする請求項1に記載の感光性熱現像記録材料の収容体。   2. The photosensitive heat-developable recording material according to claim 1, wherein the sensitizing member is affixed to an inner surface of the accommodating portion facing the image forming layer of the photosensitive heat-developable recording material. body. 前記収容部が仕切り部によって一対のポケット部が区画され、前記一対のポケット部のうち一方に、前記感光性熱現像記録材料が保持され、他方に、前記増感部材が保持され、前記仕切り部には潜像を形成する部分に相当する箇所に窓部が開孔するように形成されていることを特徴とする請求項1に記載の感光性熱現像記録材料の収容体。   A pair of pocket portions is defined by the partition portion by the accommodating portion, the photosensitive heat-developable recording material is held in one of the pair of pocket portions, and the sensitizing member is held in the other, and the partition portion 2. The photosensitive heat-developable recording material container according to claim 1, wherein a window portion is formed in a portion corresponding to a portion where a latent image is formed. 前記遮光性材料が500nm以下の波長の有色光を遮断することを特徴とする請求項1に記載の感光性熱現像記録材料の収容体。   2. The photosensitive heat-developable recording material container according to claim 1, wherein the light-shielding material blocks colored light having a wavelength of 500 nm or less. 上記請求項1から4のうちいずれか1つに記載の感光性熱現像記録材料の収容体を保持するとともに前記感光性熱現像記録材にX線を照射して潜像を形成するX線撮影装置に装填可能なカセッテ。   X-ray imaging for holding a photosensitive heat-developable recording material container according to any one of claims 1 to 4 and irradiating the photosensitive heat-developable recording material with X-rays to form a latent image. A cassette that can be loaded into the device. 支持体の少なくとも一方の面上に、感光性ハロゲン化銀、非感光性有機銀塩、還元剤、及びバインダを含有する画像形成層を設けた感光性熱現像記録材料の現像方法であって、
前記感光性熱現像記録材料を、少なくとも表面が遮光性材料からなる収容体に収容し、前記収容体に増感部材を備えた状態で、X線を照射した後、前記収容体に前記感光性熱現像記録材料を収容した状態のまま熱現像することで、潜像を顕像化することを特徴とする感光性熱現像記録材料の現像方法。
A method for developing a photosensitive heat-developable recording material provided with an image forming layer containing a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder on at least one surface of a support,
The photosensitive heat-developable recording material is housed in a container made of a light-shielding material at least on the surface, and after irradiating the container with an sensitizing member, X-ray irradiation is performed on the container. A developing method for a photosensitive heat-developable recording material, wherein a latent image is visualized by heat development in a state where the heat-developable recording material is accommodated.
支持体と、
該支持体の少なくとも一方の面上に、感光性ハロゲン化銀、非感光性有機銀塩、還元剤、及びバインダを含有する画像形成層とを有し、
前記画像形成層の表面に増感層が形成され、
前記増感層の表面が遮光層に覆われていることを特徴とする感光性熱現像記録材料。
A support;
An image forming layer containing a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder on at least one surface of the support;
A sensitizing layer is formed on the surface of the image forming layer,
A photosensitive heat-developable recording material, wherein the surface of the sensitizing layer is covered with a light-shielding layer.
支持体の少なくとも一方の面上に、感光性ハロゲン化銀、非感光性有機銀塩、還元剤、及びバインダを含有する画像形成層を設けた感光性熱現像材料の製造方法であって、
供給された前記支持体に前記画像形成層を形成し、前記画像形成層の表面に増感層をラミネートし、前記増感層の表面に遮光層をラミネートし、その後、前記支持体を裁断することを特徴とする感光性熱現像記録材料の製造方法。
A method for producing a photosensitive heat-developable material comprising an image forming layer containing a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder on at least one surface of a support,
The image forming layer is formed on the supplied support, the sensitizing layer is laminated on the surface of the image forming layer, the light shielding layer is laminated on the surface of the sensitizing layer, and then the support is cut. A method for producing a photosensitive heat-developable recording material.
JP2005045695A 2004-03-04 2005-02-22 Photosensitive thermal development recording material, its case, and developing method and manufacturing method of the photosensitive thermal development recording material Withdrawn JP2005284263A (en)

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