JP2005269978A - Low-odor water-soluble composition - Google Patents

Low-odor water-soluble composition Download PDF

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JP2005269978A
JP2005269978A JP2004087501A JP2004087501A JP2005269978A JP 2005269978 A JP2005269978 A JP 2005269978A JP 2004087501 A JP2004087501 A JP 2004087501A JP 2004087501 A JP2004087501 A JP 2004087501A JP 2005269978 A JP2005269978 A JP 2005269978A
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water
treated
odor
enzyme
weight
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Naoko Yoda
直子 依田
Sumihisa Iida
純久 飯田
Takashi Yumoto
隆 湯本
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Toyo Sugar Refining Co Ltd
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Toyo Sugar Refining Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a low-odor water-soluble composition significantly reduced in the odor of plant extract such as hesperidin, rutin or stevia or its enzyme-treated product. <P>SOLUTION: The low-odor water-soluble composition comprises a water-soluble edible(a) and 0.01 pt. wt. or more of α-cyclodextrin(b) per pt. wt. of the component(a)(on a solid basis). Foods/drinks, cosmetics, drugs or feed each containing this composition are also provided, respectively. In this composition, it is preferable that the component(a) be obtained by making cyclodextrin glucanotransferase act on a plant extract in the presence of a saccharide donor and the plant extract consist mainly of one or more of stevia, hesperidin and rutin, more preferably hesperidin. Further, it is preferable that the component(a) have been treated with an ion exchange resin. This composition is in the form of a food additive, cosmetic additive, pharmaceutical additive, vitamin P enhancer, etc. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、低臭気性水溶性組成物に関し、さらに詳しくは、酵素処理ヘスペリジンなどの臭気性成分が含まれた水溶性可食物の臭気を低減した水溶性組成物に関する。   The present invention relates to a low odor water-soluble composition, and more particularly, to a water-soluble composition that reduces the odor of water-soluble edible foods containing odorous components such as enzyme-treated hesperidin.

従来より、柑橘由来の成分である「ヘスペリジン」、ソバ、ジャガイモ、アスパラガス等由来の成分である「ルチン」、南米原産のキク科植物由来の高甘味度甘味料である「ステビア」、あるいはそれらの水溶性などを高めた酵素処理物等は、種々の有用な作用を有し、それらの特性を生かして様々な分野で用いられている。   Conventionally, "Hesperidin" which is a component derived from citrus, "Ruchin" which is a component derived from buckwheat, potato, asparagus, "Stevia" which is a high-sweetness sweetener derived from a Compositae plant originating in South America, or those Enzyme-treated products with improved water solubility have various useful effects and are used in various fields by taking advantage of their properties.

例えば、ヘスペリジン、酵素処理ヘスペリジンは、共に天然色素の退色防止、血行促進、ビタミンP様作用を示し、特に酵素処理ヘスペリジンは糖転移ビタミンPとして飲食物、化粧品等に添加して用いられている(例えば、非特許文献1、2、3)。   For example, both hesperidin and enzyme-treated hesperidin exhibit natural pigment fading prevention, blood circulation promotion, and vitamin P-like action. In particular, enzyme-treated hesperidin is used as a glycosylated vitamin P added to foods and drinks, cosmetics and the like ( For example, non-patent documents 1, 2, 3).

また、ルチン、酵素処理ルチンは、酸化防止剤、着色料、強化剤等として用いられ(例えば、非特許文献3)、またステビア、酵素処理ステビアは、ノンカロリーの高甘味度甘味料として、食品等に添加して用いられている(例えば、非特許文献3)。   Rutin and enzyme-treated rutin are used as antioxidants, colorants, reinforcing agents, and the like (for example, Non-Patent Document 3). Stevia and enzyme-treated stevia are non-caloric high-sweetness sweeteners. (For example, Non-Patent Document 3).

しかしながら、これらヘスペリジン、ルチン、ステビア等の植物抽出物やそれらの酵素処理物は、それぞれ特有の臭気を有しており、その利用分野が制限されている。
そこで、本発明者らは上記問題点を解決すべく鋭意研究を重ねた結果、これらヘスペリジン、ルチン、ステビア等の酵素処理物に、(好ましくは、さらに多孔性合成吸着樹脂処理したものに、)特定の成分を配合すれば、その臭気を著しく低減できることなどを見出して、本発明を完成するに至った。
However, these plant extracts such as hesperidin, rutin and stevia and their enzyme-treated products have their own odors, and their fields of use are limited.
Accordingly, as a result of intensive studies to solve the above problems, the present inventors have made these enzyme-treated products such as hesperidin, rutin, stevia, etc. (preferably, those treated with a porous synthetic adsorption resin). The inventors have found that the addition of a specific component can significantly reduce the odor, leading to the completion of the present invention.

なお、特開平3−7593号公報(特許文献1)には、ヘスペリジンにD−グルコース残基が等モル以上α結合しているα−グリコシルヘスペリジンが開示され、また、その製造法として、ヘスペリジンとα−グルコシル糖化合物とを含有する溶液に糖転移酵素を作用させてα−グリコシルヘスペリジン(反応混合物)を生成させ、これを採取する、α−グリコシルヘスペリジン(ヘスペリジン誘導体)の製造方法が開示され、得られた反応混合物をさらに合成樹脂吸着剤で処理する態様も示されている。また、α−グルコシル糖化合物として、アミロース、デキストリンなどの他に、シクロデキストリン等も挙げられ、その実施例ではデキストリンを用いた態様のみが示されている。また該特許文献1には、得られるヘスペリジン誘導体は、水溶性に優れ、実質的に無味無臭で、毒性の懸念もなく、生体内で生理活性を発揮し得る旨記載されている。   JP-A-3-7593 (Patent Document 1) discloses α-glycosyl hesperidin in which D-glucose residue is α-bonded to hesperidin in an equimolar amount or more. Disclosed is a method for producing α-glycosyl hesperidin (hesperidin derivative), in which a glycosyltransferase is allowed to act on a solution containing an α-glucosyl sugar compound to generate α-glycosyl hesperidin (reaction mixture), and this is collected. An embodiment in which the obtained reaction mixture is further treated with a synthetic resin adsorbent is also shown. In addition to amylose, dextrin and the like, examples of the α-glucosyl sugar compound include cyclodextrin and the like. In the examples, only an embodiment using dextrin is shown. Patent Document 1 describes that the obtained hesperidin derivative has excellent water solubility, is substantially tasteless and odorless, has no concern about toxicity, and can exhibit physiological activity in vivo.

しかしながら、該公報に記載のα−グリコシルヘスペリジンでは、用いられる用途によっては、特に、口紅などに配合して用いるには、臭気の点で更なる改善の余地がある。なお、上記糖転移反応の際にシクロデキストリンなどのα−グルコシル糖化合物を用いる場合でも、シクロデキストリン等は酵素反応中に分解され、また多孔性合成吸着樹脂でも分離、除去されるため実質上製品中には存在していない。
「食品化学新聞」、食品化学新聞社刊、平成13年10月25日発行。 「化学工業日報」(株)化学工業日報社、平成13年11月9日発行。 東洋精糖(株)「Toyo Sugur ホームページ」、[online]、平成16年2月24日検索、インターネット、<URL:http://www.toyosugar.co.jp/item/agst/agst_n04.html> 特開平3−7593号公報
However, the α-glycosyl hesperidin described in the publication has room for further improvement in terms of odor, particularly when used in combination with lipsticks, depending on the intended use. Even when an α-glucosyl sugar compound such as cyclodextrin is used in the above sugar transfer reaction, cyclodextrin is decomposed during the enzyme reaction, and is also separated and removed by the porous synthetic adsorption resin. It does not exist inside.
Published by "Food Chemistry Newspaper", published by Food Chemical Newspaper, October 25, 2001. "Chemical Industry Daily", published by Chemical Industry Daily, November 9, 2001. Toyo Sugar Co., Ltd. “Toyo Sugar homepage”, [online], February 24, 2004 search, Internet, <URL: http: // www. toyosugar. co. jp / item / agst / agst_n04. html> JP-A-3-7593

本発明は、上記のような従来技術に伴う問題点を解決しようとするものであって、ヘスペリジン、ルチン、ステビア等の酵素処理物を含み、それらの臭気が著しく低減された、低臭気性水溶性組成物を提供することを目的としている。   The present invention seeks to solve the problems associated with the prior art as described above, and includes an enzyme-treated product such as hesperidin, rutin, stevia, and the like, and has a significantly reduced odor. It is intended to provide a sex composition.

本発明に係る低臭気性水溶性組成物は、水溶性可食物(a)と、該水溶性可食物(a)(固形分)1重量部に対して0.01重量部以上の量のα−シクロデキストリン(b)とを含むことを特徴としている。   The low odor water-soluble composition according to the present invention comprises a water-soluble edible product (a) and an amount of α of 0.01 parts by weight or more with respect to 1 part by weight of the water-soluble edible product (a) (solid content). -Cyclodextrin (b).

本発明においては、上記水溶性可食物(a)が、植物抽出物に糖付与体の存在下にシクロデキストリングルカノトランスフェラーゼを作用させて得られたものであることが好ましい。   In the present invention, the water-soluble edible product (a) is preferably obtained by allowing cyclodextrin glucanotransferase to act on a plant extract in the presence of a sugar donor.

本発明においては、上記植物抽出物が、ステビア、ヘスペリジン、ルチンの何れか1種または2種以上を主成分として含有するものであることが好ましい。
本発明においては、上記水溶性可食物(a)が、酵素処理ヘスペリジンであることが好ましい。
In the present invention, it is preferable that the plant extract contains one or more of stevia, hesperidin, and rutin as a main component.
In the present invention, the water-soluble edible material (a) is preferably enzyme-treated hesperidin.

本発明においては、上記水溶性可食物(a)が、多孔性合成吸着樹脂にて処理されていることが好ましい。
本発明においては、上記低臭気性水溶性組成物が、食品添加物、化粧品用添加物、医薬用添加物の何れかであることが好ましい。
In the present invention, the water-soluble edible material (a) is preferably treated with a porous synthetic adsorption resin.
In the present invention, the low-odor water-soluble composition is preferably any of food additives, cosmetic additives, and pharmaceutical additives.

本発明に係る飲食物、化粧品、医薬品または飼料は、上記の何れかに記載の低臭気性水溶性組成物を含むことを特徴としている。   A food, drink, cosmetic, pharmaceutical product or feed according to the present invention is characterized by including the low odor water-soluble composition described above.

本発明によれば、ヘスペリジン、ルチン、ステビア等の酵素処理物の臭気が著しく低減された低臭気性水溶性組成物が提供される。特に、これら酵素処理物を予め多孔性合成吸着樹脂などにて処理したものに、α−シクロデキストリンが配合されていると、得られる低臭気性水溶性組成物は、ヘスペリジン、ルチン、ステビア等の植物抽出物やその酵素処理物の臭気が一層低減され、上記したような広汎な用途に好適に使用される。   ADVANTAGE OF THE INVENTION According to this invention, the low odor property water-soluble composition in which the odor of enzyme processed materials, such as hesperidin, rutin, and stevia is reduced significantly is provided. In particular, when α-cyclodextrin is blended with the enzyme-treated product previously treated with a porous synthetic adsorption resin or the like, the resulting low-odor water-soluble composition can be obtained from hesperidin, rutin, stevia, etc. The odor of the plant extract and its enzyme-treated product is further reduced, and it is suitably used for a wide range of uses as described above.

以下、本発明に係る低臭気性水溶性組成物について具体的に説明する。
[低臭気性水溶性組成物]
本発明に係る低臭気性水溶性組成物は、水溶性可食物(a)と、該水溶性可食物(a)(固形分)1重量部に対して、α−シクロデキストリン(b)を0.01重量部以上、好ましくは0.1重量部以上、特に好ましくは0.5重量部以上の量で含んでいる。
Hereinafter, the low odor water-soluble composition according to the present invention will be described in detail.
[Low odor water-soluble composition]
The low-odor water-soluble composition according to the present invention contains 0-α-cyclodextrin (b) for 1 part by weight of water-soluble edible (a) and the water-soluble edible (a) (solid content). .01 part by weight or more, preferably 0.1 part by weight or more, particularly preferably 0.5 part by weight or more.

このα−シクロデキストリンの含有量が、上記範囲より少ないと水溶性可食物臭例えば、ヘスペリジン、酵素素処理ヘスペリジン等に共通したビタミンP臭などの特有の臭気が強く感じられる傾向があり、最終製品への添加量を減らすかまたは使用できなくなる。   If the content of this α-cyclodextrin is less than the above range, water-soluble edible odors such as vitamin P odor common to hesperidin, enzyme-treated hesperidin, etc. tend to be strongly felt, and the final product The amount added to the product is reduced or cannot be used.

なお、このα−シクロデキストリンの添加量の上限値は、最終製品の種類や形態、また
は最終製品に及ぼす影響も異なるため特に限定しないが、約100万倍以下が好ましい。
なお、本発明では、本発明の目的に反しない範囲で、このα−シクロデキストリン(b)の一部をβ−シクロデキストリン、γ−シクロデキストリンなどで置換、代用してもよい。但し、上記α−シクロデキストリンの添加効果である臭気低減効果などを考慮すると、α−シクロデキストリンからβ−、γ−シクロデキストリンなどへの置換量はできるだけ少ないことが望ましく、例えば、β、γ−シクロデキストリンの合計で、40重量%以下、さらには20重量%以下、特に10重量%以下の範囲であることが望ましい。
The upper limit of the amount of α-cyclodextrin added is not particularly limited because the type and form of the final product or the effect on the final product is different, but is preferably about 1 million times or less.
In the present invention, a part of this α-cyclodextrin (b) may be substituted with β-cyclodextrin, γ-cyclodextrin, or the like without departing from the object of the present invention. However, considering the effect of reducing the odor, which is the effect of adding α-cyclodextrin, the amount of substitution from α-cyclodextrin to β-, γ-cyclodextrin and the like is desirably as small as possible. For example, β, γ- The total of cyclodextrins is desirably 40% by weight or less, more preferably 20% by weight or less, and particularly preferably 10% by weight or less.

なお、本発明では、このような低臭気性水溶性組成物の性状は、特に限定されず、用いられる用途等に応じて適宜決定可能であり、例えば、常温で液状、ゼリー状、固形物、粉末などの何れでもよい。
<水溶性可食物(a)>
この低臭気性水溶性組成物に含まれる水溶性可食物(a)としては、ステビア、ヘスペリジン、ルチンなど、特有の臭気を有する植物抽出物に、デンプン等の糖付与体の存在下でシクロデキストリングルカノトランスフェラーゼ等の糖転移酵素を作用させて得られた、酵素処理ステビア、酵素処理ヘスペリジン、酵素処理ルチンなどのα−グリコシル化物(α−グリコシル化ステビア、α−グリコシル化ヘスペリジン、α−グリコシル化ルチンとも言う。)等が挙げられる。なかでも酵素処理ヘスペリジンは固有の臭気が強く、α−シクロデキストリンを添加すると顕著な臭気低減効果が得られる。
In the present invention, the properties of such a low-odor water-soluble composition are not particularly limited, and can be appropriately determined according to the application used, for example, liquid at normal temperature, jelly, solid, Any of powder etc. may be sufficient.
<Water-soluble edible (a)>
As the water-soluble edible material (a) contained in the low-odor water-soluble composition, a cyclodextrin in the presence of a sugar donor such as starch is added to a plant extract having a specific odor such as stevia, hesperidin or rutin. Α-glycosylated products such as enzyme-treated stevia, enzyme-treated hesperidin and enzyme-treated rutin (α-glycosylated stevia, α-glycosylated hesperidin, α-glycosylated) obtained by the action of glycosyltransferases such as glucanotransferase Also called rutin). Among them, enzyme-treated hesperidin has a strong intrinsic odor, and when α-cyclodextrin is added, a remarkable odor reduction effect is obtained.

このような水溶性可食物(a)は、1種または2種以上組合わせて用いてもよい。これら水溶性可食物(a)は、好ましくは多孔性合成樹脂による処理をしたものであれば、その後で、さらに精製されていてもよく、未精製物でもよい。   Such water-soluble edible (a) may be used alone or in combination of two or more. These water-soluble edible products (a) may be further purified or unpurified after that, as long as they are preferably treated with a porous synthetic resin.

上記水溶性可食物(a)としては、従来より公知の方法で得られるものを用いることができる。
本発明においては、上記水溶性可食物(a)が好ましくは多孔性合成樹脂により処理された後、さらにイオン交換樹脂、活性炭の何れか1種または2種、好ましくは両方にて処理されているものが固有の臭気、例えば酵素処理ヘスペリジンでは、ビタミンP様の臭気のより顕著な低減効果が得られる点で好ましい。
As said water-soluble edible (a), what is obtained by a conventionally well-known method can be used.
In the present invention, the water-soluble edible product (a) is preferably treated with a porous synthetic resin, and then further treated with either one or two of ion exchange resin and activated carbon, preferably both. A natural odor, such as enzyme-treated hesperidin, is preferable in that a more remarkable effect of reducing vitamin P-like odor can be obtained.

多孔性吸着樹脂剤としては、水溶性可食物(a)中のデンプン分解物および臭い成分を除去できれば無極性樹脂、中間極性樹脂の何れでもよい。
具体的には、例えば無極性樹脂としてHP−10,HP−20,HP−50(三菱化成(株)製)、中間極性としてXAD−7(オルガノ(株)製)が挙げられる。
The porous adsorbent resin agent may be either a nonpolar resin or an intermediate polar resin as long as it can remove the starch degradation product and the odor component in the water-soluble edible material (a).
Specifically, for example, HP-10, HP-20, and HP-50 (manufactured by Mitsubishi Kasei Co., Ltd.) are used as nonpolar resins, and XAD-7 (manufactured by Organo Corporation) is used as an intermediate polarity.

上記多孔性吸着樹脂剤よる処理物としては、例えば特開平3−7593号公報(特許文献1)に記載されているように、ヘスペリジンにD−グルコース残基が等モル以上α1−4結合しているα−グリコシルヘスペリジンが挙げられる。   Examples of the processed product using the porous adsorbent resin agent include hesperidin having a D-glucose residue of an equimolar amount or more α1-4 bonded to Hesperidin as described in JP-A-3-7593 (Patent Document 1). Α-glycosyl hesperidin.

酵素処理ヘスペリジンの製造法としては、この特開平3−7593号公報に記載されているように、ヘスペリジンとα−グルコシル糖化合物(デンプン部分分解物)とを含有する溶液に上記したような糖転移酵素を作用させてα−グリコシルヘスペリジン(反応混合物)を生成させる方法が挙げられる。   As described in JP-A-3-7593, the method for producing enzyme-treated hesperidin is a sugar transfer as described above in a solution containing hesperidin and an α-glucosyl sugar compound (starch partial degradation product). There is a method in which an enzyme is allowed to act to produce α-glycosyl hesperidin (reaction mixture).

このようにして得られた反応混合物の多孔性合成樹脂処理を行うと、臭気成分、不純物がより一層低減された処理物が得られる。なお上記多孔性合成樹脂に加えて、イオン交換樹脂、活性炭などを用いて臭気成分、イオン類などの低減処理をしてもよい。   When the reaction mixture thus obtained is treated with a porous synthetic resin, a treated product in which odor components and impurities are further reduced is obtained. In addition to the porous synthetic resin, an odor component, ions, or the like may be reduced using an ion exchange resin, activated carbon, or the like.

上記α−グルコシル糖化合物としては、従来より公知のアミロース、デキストリン、シ
クロデキストリン等が挙げられる。
また、ステビアあるいは酵素処理ステビアとしては、特開2000−287642号公報の[0014]〜[0015]欄に記載されているように、ステビア抽出物を使用してもよく、ステビア抽出物とは、キク料ステビア(Stevia rebaudiana BERTONI)の地上部
より、室温〜熱水で抽出し、精製して得られたものである。主甘味成分はステビオサイド、レバウディオサイドA等であり、ステビア抽出物の乾燥物では、ステビオール配糖体として通常80.0%以上の量でこれら成分を含有する。本発明ではこのステビア抽出物を単独で使用でき、またステビア抽出物と希釈剤、賦形剤等を組合わせて用いた希釈品である液体、粉末、顆粒品等を使用できる。
Examples of the α-glucosyl sugar compound include conventionally known amylose, dextrin, cyclodextrin and the like.
As stevia or enzyme-treated stevia, stevia extract may be used as described in columns [0014] to [0015] of JP-A No. 2000-287642. Extracted from the ground part of chrysanthemum stevia (Stevia rebaudiana BERTONI) with room temperature to hot water and purified. The main sweetening components are stevioside, rebaudioside A and the like, and stevia extract dried products usually contain these components in an amount of 80.0% or more as steviol glycosides. In the present invention, this stevia extract can be used alone, or a liquid, powder, granule or the like which is a diluted product using a stevia extract in combination with a diluent, an excipient or the like can be used.

酵素処理ステビアは、例えば、ステビア抽出物にα−グルコシルトランスフェラーゼ等を用いてグルコースを付加して得られ、その主甘味成分はα−グルコシルステビオサイド、α−グルコシルレバウディオサイドA等であり、乾燥物は、ステビオール配糖体として80.0%(重量%)以上の量で含有し、未反応のステビオール配糖体含量は、15.0%以下である。この酵素処理ステビアとしては、酵素処理ステビア単独または、酵素処理ステビアと共に希釈剤、賦形剤等を用いてなる希釈品である液体、粉末、顆粒品等を使用できる。   Enzyme-treated stevia is obtained, for example, by adding glucose to stevia extract using α-glucosyltransferase or the like, and its main sweetening component is α-glucosyl stevioside, α-glucosyl rebaudioside A, etc., and dried. The product contains 80.0% (% by weight) or more of steviol glycoside, and the content of unreacted steviol glycoside is 15.0% or less. As this enzyme-treated stevia, enzyme-treated stevia alone or a liquid, powder, granule or the like that is a diluted product using an enzyme-treated stevia together with a diluent, excipient, or the like can be used.

酵素処理ステビアとしては、市販品を用いてもよく、例えば、「αGスイートPX」(東洋精糖(株)製)等が挙げられる。また、ステビア抽出物としては、例えば、「ステビロース90」(東洋精糖(株)製)が挙げられる。   A commercially available product may be used as the enzyme-treated stevia, and examples thereof include “αG sweet PX” (manufactured by Toyo Seika Co., Ltd.). Examples of stevia extract include “Stevirose 90” (manufactured by Toyo Seika Co., Ltd.).

また、酵素処理ルチンについては、例えば、特開2004−59522号公報の[0014]欄に記載されているように、ルチン(ケルセチン−3−ルチノース)とデキストリンの溶解液に、シクロマルトデキストリングルカノトランスフェラーゼを作用させてデキストリンから糖をルチンに転移させ、上記水溶性可食物(a)と同様に精製して製造することができる。   As for the enzyme-treated rutin, for example, as described in [0014] column of JP-A No. 2004-59522, cyclomaltodextrin glucano is added to a solution of rutin (quercetin-3-lutinose) and dextrin. A sugar can be transferred from dextrin to rutin by the action of transferase and purified in the same manner as in the above water-soluble edible product (a).

また、酵素処理ルチンとしては、市販品を使用してもよく、市販品としては、例えば、東洋精糖(株)製の「αG−ルチンPS」あるいは「αG−ルチンP」等が挙げられる。
本発明に係る上記低臭気性水溶性組成物には、必須成分である上記水溶性可食物(a)と、α−シクロデキストリン(b)とに加えて、必要により、さらに賦型剤、ビタミンC等の酸化防止剤などが適宜量で含まれていてもよい。
As the enzyme-treated rutin, a commercially available product may be used. Examples of the commercially available product include “αG-rutin PS” and “αG-rutin P” manufactured by Toyo Seika Co., Ltd.
In addition to the water-soluble edible component (a) and the α-cyclodextrin (b), which are essential components, the low-odor water-soluble composition according to the present invention further includes an excipient, vitamin if necessary. An antioxidant such as C may be contained in an appropriate amount.

[低臭気性水溶性組成物の製造]
この低臭気性水溶性組成物を得るには、上記のような水溶性可食物(a)と、α−シクロデキストリン(b)とを、この水溶性可食物(a)(固形分)1重量部に対して、α−シクロデキストリン(b)を0.01重量部以上、好ましくは0.1重量部以上、特に好ましくは0.5重量部以上の量で配合し、攪拌、混練等すればよい。この際には攪拌機などを用いてもよい。また、配合成分の物性が変化、変質等しない範囲で、溶解、過熱、ろ過、乾燥等をしてもよい。また必要により、この低臭気性水溶性組成物の調製の際に、デンプンなどの賦型剤、ビタミンC等の酸化防止剤、水、エタノールなどの溶剤あるいは分散媒を任意の時期に添加、混合してもよい。
[Production of low odor water-soluble composition]
In order to obtain this low-odor water-soluble composition, the above-mentioned water-soluble edible product (a) and α-cyclodextrin (b) are mixed with 1 weight of the water-soluble edible product (a) (solid content). If α-cyclodextrin (b) is blended in an amount of 0.01 parts by weight or more, preferably 0.1 parts by weight or more, particularly preferably 0.5 parts by weight or more, and stirring, kneading, etc. Good. In this case, a stirrer or the like may be used. Moreover, you may melt | dissolve, heat, filter, dry, etc. in the range which the physical property of a mixing | blending component does not change or change in quality. In addition, when preparing this low-odor water-soluble composition, an excipient such as starch, an antioxidant such as vitamin C, a solvent or dispersion medium such as water or ethanol is added and mixed at any time. May be.

[低臭気性水溶性組成物の用途]
このような低臭気性水溶性組成物が、例えば、ヘスペリジン、酵素処理ヘスペリジンを臭気成分として含有するものである場合は、毛細血管の強化、出血予防、血圧調整などの生理作用を持つビタミンP様物質としての機能を有し、食品、医薬品、化粧品など極めて広い範囲で利用される。
[Use of low odor water-soluble composition]
When such a low-odor water-soluble composition contains, for example, hesperidin or enzyme-treated hesperidin as an odor component, vitamin P-like having physiological effects such as strengthening of capillaries, prevention of bleeding and blood pressure adjustment It has a function as a substance and is used in a wide range of foods, pharmaceuticals, cosmetics and the like.

このように、その安全性が確認されているヘスペリジン、酵素処理ヘスペリジンなどを含む本発明の低臭気性水溶性組成物は、それらの特性を生かして、例えば、食品用添加物、化粧品用添加物、医薬用添加物、ビタミンP強化剤、健康補助食品等として好適に用いることができる。   As described above, the low-odor water-soluble composition of the present invention containing hesperidin, enzyme-treated hesperidin, etc. whose safety has been confirmed can be used, for example, for food additives and cosmetic additives, taking advantage of these characteristics. It can be suitably used as a pharmaceutical additive, vitamin P fortifier, health supplement and the like.

例えば、ステビア、酵素処理ステビアを臭気成分として含有するものである場合は、食品用添加物、医薬用添加物に好適に用いられる。
また、ルチン、酵素処理ルチンなどを含む場合には、食品用添加物、化粧品用添加物、医薬用添加物、ビタミンP強化剤に好適に用いられる。
For example, when stevia or enzyme-treated stevia is contained as an odor component, it is suitably used for food additives and pharmaceutical additives.
In addition, when it contains rutin, enzyme-treated rutin, etc., it is suitably used for food additives, cosmetic additives, pharmaceutical additives, and vitamin P fortifiers.

これら低臭気性水溶性組成物は、その用途に応じて、前述したような任意の剤型を採ることができ、該組成物中の水溶性可食物(a)あるいはα−シクロデキストリン(b)の含有量は、それぞれ上記範囲にある限り、特に限定されず、例えば、該組成物中に、水溶性可食物(a)(固形分)は、0.1〜99.9重量%の量で含まれている。   These low-odor water-soluble compositions can take any dosage form as described above depending on their use, and are water-soluble edible (a) or α-cyclodextrin (b) in the composition. The content of is not particularly limited as long as it is in the above-mentioned range. For example, the water-soluble edible (a) (solid content) is 0.1 to 99.9% by weight in the composition. include.

また、この低臭気性水溶性組成物は、飲食物、化粧品、医薬品または飼料などに任意量で添加して用いることもできる。
飲食物としては、例えば、酸性飲料、例えば、酢飲料、乳酸飲料、柑橘飲料、酸性野菜飲料、(酸性の)生薬含有飲料などが挙げられる。
[実施例]
以下、本発明に係る低臭気性水溶性組成物について実施例によりさらに具体的に説明するが、本発明は係る実施例により何ら限定されるものではない。
Moreover, this low-odor water-soluble composition can also be added and used for food and drink, cosmetics, a pharmaceutical, or a feed in arbitrary amounts.
Examples of the food and drink include acidic beverages such as vinegar beverages, lactic acid beverages, citrus beverages, acidic vegetable beverages, and (acidic) herbal medicine-containing beverages.
[Example]
Examples Hereinafter, the low-odor water-soluble composition according to the present invention will be described more specifically with reference to examples. However, the present invention is not limited to the examples.

ヘスペリジン(イ)1重量部およびデキストリン(DE20)6重量部の配合物に水5,000(5千)重量部を加えて温度80℃に加熱し、ヘスペリジン及びデキストリンを
溶解させ、これにシクロマルトデキストリン グルカノトランスフェラ−ゼをデキストリン1g当たり30単位加え、pH6.0、70℃に維持して18時間反応させ、酵素処理ヘスペリジン反応液を得た。
5,000 (5,000) parts by weight of water is added to a blend of 1 part by weight of hesperidin (ii) and 6 parts by weight of dextrin (DE20) and heated to a temperature of 80 ° C. to dissolve hesperidin and dextrin. 30 units of dextrin glucanotransferase was added per 1 g of dextrin, and the mixture was reacted at pH 6.0 and 70 ° C. for 18 hours to obtain an enzyme-treated hesperidin reaction solution.

この反応液を多孔性合成樹脂吸着剤(商品名「HP−10」、三菱化成(株)製)が充填されたカラムにSV2.0で通液し、酵素処理ヘスペリジンを吸着させた。
次いで、このカラムを水で洗浄しデキストリン分解物、臭い物質を洗浄・除去した後、50 v/v%エタノ−ルを通液し酵素処理ヘスペリジンなどを脱着した。
This reaction solution was passed through a column packed with a porous synthetic resin adsorbent (trade name “HP-10”, manufactured by Mitsubishi Kasei Co., Ltd.) at SV 2.0 to adsorb enzyme-treated hesperidin.
Next, this column was washed with water to wash and remove dextrin degradation products and odorous substances, and then passed 50 v / v% ethanol to desorb enzyme-treated hesperidin and the like.

得られた脱着液を濃縮して溶出液中のエタノ−ルを留去し、乾燥して酵素処理ヘスペリジン粉末(ロ)を得た。
酵素処理ヘスペリジン粉末1重量部にイオン交換水10重量部を加えて温度60℃に加熱し溶解した後、約30℃に冷却して強酸性陽イオン交換樹脂(商品名「ダイアイオンSK1B」、三菱化成(株)製)と強塩基性イオン交換樹脂(商品名「ダイアイオンSA10A」、三菱化成(株)製)に接触させて脱塩、脱色、脱臭を行った。
The obtained desorption liquid was concentrated to distill off ethanol in the eluate and dried to obtain enzyme-treated hesperidin powder (b).
After adding 10 parts by weight of ion-exchanged water to 1 part by weight of enzyme-treated hesperidin powder and heating to 60 ° C. to dissolve, the solution is cooled to about 30 ° C. and then strongly acidic cation exchange resin (trade name “Diaion SK1B”, Mitsubishi Kasei Co., Ltd.) and a strongly basic ion exchange resin (trade name “Diaion SA10A”, manufactured by Mitsubishi Kasei Co., Ltd.) were subjected to desalting, decolorization, and deodorization.

得られた流出液を濃縮・乾燥し、イオン交換樹脂による処理が行なわれた酵素処理ヘスペリジン粉末(ハ)(イオン交換樹脂・酵素処理ヘスペリジン粉末)を得た。
このイオン交換樹脂・酵素処理ヘスペリジン粉末1重量部にイオン交換水10重量部を加えて温度60℃に加熱し、該粉末を溶解させた液を試料Aとした。
The obtained effluent was concentrated and dried to obtain enzyme-treated hesperidin powder (c) (ion exchange resin / enzyme-treated hesperidin powder) that had been treated with an ion exchange resin.
A sample A was prepared by adding 10 parts by weight of ion-exchanged water to 1 part by weight of this ion-exchange resin / enzyme-treated hesperidin powder and heating to 60 ° C. to dissolve the powder.

また、このイオン交換樹脂による処理が行なわれた酵素処理ヘスペリジン粉末(ハ)1重量部およびα−サイクロデキストリン1重量部にイオン交換水10重量部を加えて温度80℃で加熱し固形分を溶解した液を試料Bとした。   In addition, 10 parts by weight of ion-exchanged water is added to 1 part by weight of the enzyme-treated hesperidin powder (c) treated with this ion-exchange resin and 1 part by weight of α-cyclodextrin and heated at a temperature of 80 ° C. to dissolve the solid content. The liquid obtained was designated as Sample B.

なお、イオン交換樹脂による処理が行なわれていない酵素処理ヘスペリジン粉末(ロ)1重量部にイオン交換水10重量部を加えて加熱・溶解した液を対照とした。
試料A、Bおよび対照の各50mlを、100mlのスクリューキャップ付三角フラスコに充填し、密栓して60℃で1日(24時間)保温した後、30〜40℃に冷却しパネラー8人で官能検査を行った。その平均値を示す。
A solution obtained by adding 10 parts by weight of ion-exchanged water to 1 part by weight of enzyme-treated hesperidin powder (ii) not treated with an ion-exchange resin and heating and dissolving it was used as a control.
50 ml each of Samples A and B and the control were filled into a 100 ml Erlenmeyer flask with a screw cap, sealed and kept at 60 ° C. for 1 day (24 hours), then cooled to 30 to 40 ° C. and functionalized by 8 panelists. Inspected. The average value is shown.

Figure 2005269978
Figure 2005269978

実施例1の、イオン交換樹脂による処理が施されていない酵素処理ヘスペリジン粉末(ロ)1重量部にイオン交換水10重量部を加えて加熱・溶解後、粉末活性炭(商品名「精製白鷺」、武田薬品工業(株)製)0.05重量部を添加し、60℃で1時間攪拌した後、ろ過により粉末活性炭を除去した。得られたこの液を濃縮・乾燥し、活性炭処理した酵素処理ヘスペリジン粉末(ニ)を得た。   In Example 1, 10 parts by weight of ion-exchanged water was added to 1 part by weight of enzyme-treated hesperidin powder (B) not treated with an ion-exchange resin, heated and dissolved, and then powdered activated carbon (trade name “Purified Shirakaba”, 0.05 parts by weight of Takeda Pharmaceutical Co., Ltd.) was added and stirred at 60 ° C. for 1 hour, and then the powdered activated carbon was removed by filtration. The liquid thus obtained was concentrated and dried to obtain activated hesperidin powder (d) treated with activated carbon.

この活性炭処理した酵素処理ヘスペリジン粉末(ニ)1重量部にイオン交換水10重量部を加え、60℃で加熱・溶解した液を試料Cとした。
また、この活性炭処理した酵素処理ヘスペリジン粉末(ニ)1重量部およびα−サイクロデキストリン1重量部の配合物にイオン交換水10重量部を加えて温度80℃で加熱し固形分を溶解した液を試料Dとした。
Sample C was obtained by adding 10 parts by weight of ion-exchanged water to 1 part by weight of the enzyme-treated hesperidin powder (d) treated with activated carbon, and heating and dissolving at 60 ° C.
In addition, a solution in which 10 parts by weight of ion-exchanged water is added to a mixture of 1 part by weight of the enzyme-treated hesperidin powder (d) and 1 part by weight of α-cyclodextrin treated with activated carbon and heated at a temperature of 80 ° C. to dissolve a solid content. Sample D was designated.

なお、実施例1の、イオン交換樹脂による処理が施されていない酵素処理ヘスペリジン粉末(ロ)1重量部にイオン交換水10重量部を加えて加熱・溶解した液を対照とした。
試料C、Dおよび対照の各50mlを、100mlのスクリュ−キャップ付三角フラスコに充填し、密栓して60℃・1日保温した後、30〜40℃に冷却しパネラー8人で官能検査を行った。その平均値を示す。
In addition, the liquid which heated and melt | dissolved by adding 10 weight part of ion-exchange water to 1 weight part of enzyme-treated hesperidin powder (b) of Example 1 that has not been treated with an ion exchange resin was used as a control.
Fill 50ml each of sample C, D and control into a 100ml Erlenmeyer flask with screw cap, seal tightly and incubate at 60 ° C for 1 day, then cool to 30-40 ° C and perform sensory test with 8 panelists It was. The average value is shown.

Figure 2005269978
Figure 2005269978

実施例1から得られたイオン交換樹脂・酵素処理ヘスペリジン粉末(ハ)2重量部に、イオン交換水10重量部を加えて温度60℃に加熱し該粉末(ハ)を溶解させ、次いで、粉末活性炭(商品名「精製白鷺」、武田薬品工業(株)製)0.01重量部を添加し、60℃で1時間攪拌した。   10 parts by weight of ion-exchanged water is added to 2 parts by weight of the ion exchange resin / enzyme-treated hesperidin powder (c) obtained from Example 1 and heated to a temperature of 60 ° C. to dissolve the powder (c). 0.01 parts by weight of activated carbon (trade name “Purified Shirakaba”, manufactured by Takeda Pharmaceutical Co., Ltd.) was added and stirred at 60 ° C. for 1 hour.

次いで、ろ過により粉末活性炭を除去した後、濃縮・乾燥し、「イオン交換樹脂及び活性炭処理した酵素処理ヘスペリジン粉末」(ホ)を得た。
この粉末(ホ)1重量部にイオン交換水10重量部を加え、60℃で加熱・溶解した液を試料Eとした。
Next, the powdered activated carbon was removed by filtration, followed by concentration and drying to obtain “enzyme-treated hesperidin powder treated with an ion exchange resin and activated carbon” (e).
Sample E was prepared by adding 10 parts by weight of ion-exchanged water to 1 part by weight of this powder (e) and heating and dissolving at 60 ° C.

またこの粉末(ホ) 1重量部に、α−サイクロデキストリン(実施例3)1重量部{
またはβ−サイクロデキストリン(参考例1)1重量部またはγ−サイクロデキストリン
(参考例2)1重量部}、イオン交換水10重量部を加えて温度80℃に加熱し、これら配合成分を溶解した。
Further, 1 part by weight of this powder (e) and 1 part by weight of α-cyclodextrin (Example 3) {
Or 1 part by weight of β-cyclodextrin (Reference Example 1) or 1 part by weight of γ-cyclodextrin (Reference Example 2)} and 10 parts by weight of ion-exchanged water and heated to a temperature of 80 ° C. to dissolve these ingredients. .

得られた処理液をそれぞれ試料F(実施例3)、試料G(参考例1)、試料H(参考例2)とした。
なお、実施例1の、イオン交換樹脂による処理が施されていない酵素処理ヘスペリジン粉末(ロ)1重量部にイオン交換水10重量部を加えて加熱・溶解した液を対照とした。
The obtained processing solutions were designated as Sample F (Example 3), Sample G (Reference Example 1), and Sample H (Reference Example 2).
In addition, the liquid which heated and melt | dissolved by adding 10 weight part of ion-exchange water to 1 weight part of enzyme-treated hesperidin powder (b) of Example 1 that has not been treated with an ion exchange resin was used as a control.

試料E、F、G、Hおよび対照の各50mlを、100mlのスクリュ−キャップ付三角フラスコに充填し、密栓して60℃・1日保温した後、30〜40℃に冷却しパネラー8人で官能検査を行った。その平均値を示す。   Fill 50ml each of Samples E, F, G, H and Control into a 100ml Erlenmeyer flask with screw cap, seal tightly and incubate at 60 ° C for 1 day, then cool to 30-40 ° C and use 8 panelists. A sensory test was performed. The average value is shown.

Figure 2005269978
Figure 2005269978

ルチン1重量部およびデキストリン(DE20)6重量部の配合物に水5,000(5
千)重量部を加えて温度80℃に加熱し、ルチン及びデキストリンを溶解させ、これにシクロマルトデキストリン グルカノトランスフェラ−ゼをデキストリン1g当たり30単位加え、pH6.0、70℃に維持して18時間反応させ、酵素処理ルチン反応液を得た。
A mixture of 1 part by weight of rutin and 6 parts by weight of dextrin (DE20) is mixed with 5,000 water (5
1,000) parts by weight and heated to a temperature of 80 ° C. to dissolve rutin and dextrin, to which 30 units of cyclomaltodextrin glucanotransferase is added per 1 g of dextrin and maintained at pH 6.0, 70 ° C. The reaction was carried out for 18 hours to obtain an enzyme-treated rutin reaction solution.

この反応液を、多孔性合成樹脂吸着剤(商品名「HP−10」、三菱化成(株)製)が充填されたカラムにSV2.0で通液した。
ついで、このカラムを水で洗浄しデキストリン分解物、臭い物質を流出させた後、50
v/v%エタノ−ルを通液し、酵素処理ルチンを脱離・溶出させた。
This reaction solution was passed through a column packed with a porous synthetic resin adsorbent (trade name “HP-10”, manufactured by Mitsubishi Kasei Co., Ltd.) at SV 2.0.
Next, the column was washed with water to discharge the decomposition product of dextrin and odorous substances, and then 50
V / v% ethanol was passed through to desorb and elute enzyme-treated rutin.

次いで、この溶出液を濃縮してエタノ−ルを留去し、乾燥して酵素処理ルチン粉末(ヘ)を得た。
次いで、酵素処理ルチン粉末1重量部にイオン交換水10重量部を加えて温度60℃に加熱し、含まれる固形分(すなわち酵素処理ルチン)を溶解させた後、約30℃に冷却して強酸性陽イオン交換樹脂(商品名「ダイアイオンSK1B」、三菱化成(株)製)と強塩基性イオン交換樹脂(商品名「ダイアイオンSA10A」、三菱化成(株)製)に接触させて脱塩、脱色、脱臭を行った。
Subsequently, this eluate was concentrated to distill off ethanol and dried to obtain enzyme-treated rutin powder (f).
Next, 10 parts by weight of ion-exchanged water is added to 1 part by weight of the enzyme-treated rutin powder and heated to a temperature of 60 ° C. to dissolve the solid content (ie, the enzyme-treated rutin). In contact with a basic cation exchange resin (trade name “Diaion SK1B”, manufactured by Mitsubishi Kasei Co., Ltd.) and a strongly basic ion exchange resin (trade name “Diaion SA10A”, manufactured by Mitsubishi Kasei Co., Ltd.) , Decolorization and deodorization.

得られた流出液を濃縮・乾燥し、イオン交換樹脂処理した酵素処理ルチン粉末(ト)を得た。
このイオン交換樹脂・酵素処理ルチン粉末(ト)1重量部にイオン交換水10重量部を加えて加熱・溶解した液を試料Iとした。
The obtained effluent was concentrated and dried to obtain an enzyme-treated rutin powder (g) treated with an ion exchange resin.
Sample I was prepared by adding 10 parts by weight of ion-exchanged water to 1 part by weight of this ion-exchange resin / enzyme-treated rutin powder (g) and heating and dissolving it.

また、このイオン交換樹脂・酵素処理ヘスペリジン粉末1重量部およびα−サイクロデキストリン1重量部にイオン交換水10重量部を加えて温度80℃に加熱し、含まれる固形分を溶解させた液を試料Jとした。   Further, 10 parts by weight of ion-exchanged water was added to 1 part by weight of this ion exchange resin / enzyme-treated hesperidin powder and 1 part by weight of α-cyclodextrin and heated to a temperature of 80 ° C. to dissolve the contained solids. J.

なお、酵素処理ルチン粉末(ヘ)1重量部にイオン交換水10重量部を加えて加熱・溶
解した液を対照とした。
試料I、Jおよび対照の各50mlを、100mlのスクリュ−キャップ付三角フラスコに充填し、密栓して60℃・1日保温した後、30〜40℃に冷却しパネラー8人で官能検査を行った。その平均値を示す。
A solution obtained by adding 10 parts by weight of ion-exchanged water to 1 part by weight of enzyme-treated rutin powder (f) and heating and dissolving was used as a control.
Fill each 100ml sample I, J and control into a 100ml Erlenmeyer flask with screw cap, seal tightly and incubate at 60 ° C for 1 day, then cool to 30-40 ° C and perform sensory test with 8 panelists It was. The average value is shown.

Figure 2005269978
Figure 2005269978

ステビア1重量部およびデキストリン(DE20)5重量部の配合物に水5,000(5千)重量部を加えて温度80℃に加熱し固形分のステビア、デキストリンを溶解し、こ
れにシクロマルトデキストリン グルカノトランスフェラ−ゼをデキストリン1g当たり20単位加え、pH6.0、70℃に維持して18時間反応させ、酵素処理ステビア反応液を得た。
Stevia 1 part by weight and dextrin (DE20) 5 parts by weight Add 5,000 (5,000) parts by weight of water and heat to a temperature of 80 ° C. to dissolve solid stevia and dextrin. 20 units of glucanotransferase was added per 1 g of dextrin, and the mixture was reacted at a pH of 6.0 and 70 ° C. for 18 hours to obtain an enzyme-treated stevia reaction solution.

この反応液を多孔性合成樹脂吸着剤(商品名「HP−10」、三菱化成(株)製)を充填したカラムにSV2.0で通液した。
次いでこのカラムを水で洗浄しデキストリン分解物、臭い物質を除去した後、50 v/v%エタノ−ルを通液し酵素処理ステビアを溶出させた。この溶出液を濃縮してエタノ−ルを留去し、乾燥して酵素処理ステビア粉末(チ)を得た。
This reaction solution was passed through a column packed with a porous synthetic resin adsorbent (trade name “HP-10”, manufactured by Mitsubishi Kasei Co., Ltd.) at SV 2.0.
The column was then washed with water to remove dextrin degradation products and odorous substances, and then 50 v / v% ethanol was passed through to elute the enzyme-treated stevia. The eluate was concentrated to remove ethanol and dried to obtain enzyme-treated stevia powder (H).

酵素処理ステビア粉末1重量部にイオン交換水10重量部を加えて60℃に加熱し含まれる固形分(酵素処理ステビア)を溶解させた後、約30℃に冷却して強酸性陽イオン交換樹脂(商品名「ダイアイオンSK1B」、三菱化成(株)製)と強塩基性イオン交換樹脂(商品名「ダイアイオンSA10A」、三菱化成(株)製)に接触させ、脱塩、脱色、脱臭を行った。   After adding 10 parts by weight of ion-exchanged water to 1 part by weight of enzyme-treated stevia powder and heating to 60 ° C. to dissolve the solid content (enzyme-treated stevia), the solution is cooled to about 30 ° C. and then strongly acidic cation exchange resin. (Product name “Diaion SK1B”, manufactured by Mitsubishi Kasei Co., Ltd.) and strong basic ion exchange resin (Product name “Diaion SA10A”, manufactured by Mitsubishi Kasei Co., Ltd.) to remove desalting, decolorization and deodorization. went.

得られた流出液を濃縮・乾燥し、イオン交換樹脂処理した酵素処理ステビア粉末(リ)を得た。
このイオン交換樹脂・酵素処理ステビア粉末(リ)0.1重量部にイオン交換水100重量部を加えて加熱・溶解した液を試料Kとした。
The obtained effluent was concentrated and dried to obtain an enzyme-treated stevia powder (re) treated with an ion exchange resin.
A sample K was prepared by adding 100 parts by weight of ion-exchanged water to 0.1 part by weight of this ion-exchange resin / enzyme-treated stevia powder (Li) and heating and dissolving it.

また、イオン交換樹脂処理した酵素処理ステビア粉末0.1重量部およびα−サイクロデキストリン0.1重量部にイオン交換水100重量部を加えて加熱・溶解した液を試料Lとした。   Sample L was a solution obtained by adding 100 parts by weight of ion-exchanged water to 0.1 parts by weight of enzyme-treated stevia powder treated with an ion-exchange resin and 0.1 parts by weight of α-cyclodextrin and heating and dissolving them.

なお、酵素処理ステビア粉末(チ)0.1重量部にイオン交換水100重量部を加えて加熱・溶解した液を対照とした。
試料K、Lおよび対照の各50mlを、100mlのスクリュ−キャップ付三角フラスコに充填し、密栓して60℃・1日保温した後、30〜40℃に冷却しパネラー8人で官能検査を行った。その平均値を示す。
A solution obtained by adding 100 parts by weight of ion-exchanged water to 0.1 part by weight of enzyme-treated stevia powder (H) and heating and dissolving it was used as a control.
Fill 50ml each of sample K, L and control into a 100ml Erlenmeyer flask with screw cap, seal tightly and incubate at 60 ° C for 1 day, then cool to 30-40 ° C and perform sensory test with 8 panelists It was. The average value is shown.

Figure 2005269978
Figure 2005269978

Claims (7)

水溶性可食物(a)と、該水溶性可食物(a)(固形分)1重量部に対して0.01重量部以上の量のα−シクロデキストリン(b)とを含むことを特徴とする、低臭気性水溶性組成物。   It contains water-soluble edible (a) and α-cyclodextrin (b) in an amount of 0.01 parts by weight or more with respect to 1 part by weight of the water-soluble edible (a) (solid content). A low odor water-soluble composition. 上記水溶性可食物(a)が、植物抽出物に糖付与体の存在下にシクロデキストリングルカノトランスフェラーゼを作用させて得られたものであることを特徴とする請求項1に記載の低臭気性水溶性組成物。   The low odor property according to claim 1, wherein the water-soluble edible product (a) is obtained by allowing a cyclodextrin glucanotransferase to act on a plant extract in the presence of a sugar donor. Water-soluble composition. 上記植物抽出物が、ステビア、ヘスペリジン、ルチンの何れか1種または2種以上を主成分とするものであることを特徴とする請求項2に記載の低臭気性水溶性組成物。   The low-odor water-soluble composition according to claim 2, wherein the plant extract contains one or more of stevia, hesperidin and rutin as a main component. 上記水溶性可食物(a)が、酵素処理ヘスペリジンであることを特徴とする請求項1〜2の何れかに記載の低臭気性水溶性組成物。   The said water-soluble edible (a) is enzyme-treated hesperidin, The low-odor water-soluble composition in any one of Claims 1-2 characterized by the above-mentioned. 上記水溶性可食物(a)が、多孔性合成吸着樹脂にて処理されていることを特徴とする請求項1〜4の何れかに記載の低臭気性水溶性組成物。   The low-odor water-soluble composition according to any one of claims 1 to 4, wherein the water-soluble edible material (a) is treated with a porous synthetic adsorption resin. 上記低臭気性水溶性組成物が、食品用添加物、化粧品用添加物、医薬用添加物の何れかである請求項1〜5の何れかに記載の低臭気性水溶性組成物。   The low-odor water-soluble composition according to any one of claims 1 to 5, wherein the low-odor water-soluble composition is any one of a food additive, a cosmetic additive, and a pharmaceutical additive. 請求項1〜6の何れかに記載の低臭気性水溶性組成物を含むことを特徴とする飲食物、化粧品、医薬品または飼料。   A food, drink, cosmetic, pharmaceutical product or feed comprising the low-odor water-soluble composition according to any one of claims 1 to 6.
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007143413A (en) * 2005-11-24 2007-06-14 Maruzen Pharmaceut Co Ltd Method for eliminating unfavorable smell-causing component and bitter taste component, method for producing quillai extract, and quillai extract
JP2008271839A (en) * 2007-04-27 2008-11-13 Toyo Seito Kk Water-soluble flavonoid composition, preparing method therefor and foodstuff etc. containing water-soluble flavonoid composition
JP2010150163A (en) * 2008-12-24 2010-07-08 House Foods Corp Compound material and method for producing the same
CN102051397A (en) * 2010-11-22 2011-05-11 成都神农本草生物科技有限公司 Method for preparing alpha-glucosylhesperidin
JP2017012069A (en) * 2015-06-30 2017-01-19 株式会社 伊藤園 Process for producing hesperidin-containing tea beverage composition

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007143413A (en) * 2005-11-24 2007-06-14 Maruzen Pharmaceut Co Ltd Method for eliminating unfavorable smell-causing component and bitter taste component, method for producing quillai extract, and quillai extract
JP2008271839A (en) * 2007-04-27 2008-11-13 Toyo Seito Kk Water-soluble flavonoid composition, preparing method therefor and foodstuff etc. containing water-soluble flavonoid composition
JP2010150163A (en) * 2008-12-24 2010-07-08 House Foods Corp Compound material and method for producing the same
CN102051397A (en) * 2010-11-22 2011-05-11 成都神农本草生物科技有限公司 Method for preparing alpha-glucosylhesperidin
JP2017012069A (en) * 2015-06-30 2017-01-19 株式会社 伊藤園 Process for producing hesperidin-containing tea beverage composition

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