JP2005212186A - Decorating method for molded article - Google Patents

Decorating method for molded article Download PDF

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JP2005212186A
JP2005212186A JP2004019646A JP2004019646A JP2005212186A JP 2005212186 A JP2005212186 A JP 2005212186A JP 2004019646 A JP2004019646 A JP 2004019646A JP 2004019646 A JP2004019646 A JP 2004019646A JP 2005212186 A JP2005212186 A JP 2005212186A
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molded product
transfer ink
fixing layer
ink fixing
transfer
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JP4297217B2 (en
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Noriyasu Iwatsubo
徳泰 岩坪
Toshiro Ariga
利郎 有賀
Toshio Yamagishi
敏夫 山岸
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DIC Corp
Sekisui Home Techno KK
Shin Dick Kako KK
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Dainippon Ink and Chemicals Co Ltd
Sekisui Home Techno KK
Shin Dick Kako KK
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a decorating method for a molded article, which enables a pattern excellent in hot/warm water resistance and fixability to be evenly transferred to a decorating surface of the molded article by using a hydraulic transfer method. <P>SOLUTION: In a process provided in this decorating method for the molded article, a coating for forming a transfer ink fixing layer is applied to the decorating surface of the molded article, heated and dried up to a predetermined degree of drying, so that the transfer ink fixing layer can be formed; and after that, a printing pattern is hydraulically transferred and printed onto the transfer ink fixing layer from a transfer sheet, whereon the printing pattern is pre-drawn, by means of transfer ink. The decorating method is characterized in that the coating for forming the coating for forming the transfer ink fixing layer is heated and dried while the whole decorating surface of the molded article is kept at an almost uniform temperature. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、たとえば、浴室ユニットで使用される浴槽、カウンター、エプロン等のFRP製成形品等の化粧面を加飾する方法に関する。   The present invention relates to a method for decorating a decorative surface such as a molded product made of FRP such as a bathtub, a counter, and an apron used in a bathroom unit.

浴室ユニットで使用される浴槽、カウンター、エプロン等のFRP製成形品等の化粧面を加飾する方法として、予め加工成形した昇華転写シートを熱プレス印刷する方法が既に提案されている(たとえば、特許文献1参照)。
しかしながら、上記昇華転写シートを用いた加飾方法の場合、昇華転写シートを予め加工成形しなければならないため、コストがかかるという問題がある。
As a method for decorating decorative surfaces such as FRP molded products such as bathtubs, counters, and aprons used in bathroom units, a method of hot press printing a preliminarily processed sublimation transfer sheet has been proposed (for example, Patent Document 1).
However, in the case of the decorating method using the sublimation transfer sheet, there is a problem that the sublimation transfer sheet has to be processed and molded in advance, which increases costs.

一方、曲面への絵柄の転写性に優れた水圧転写法(たとえば、特許文献2等参照)の場合、特許文献1にも開示されているように転写された絵柄の耐熱水性や定着性に問題がある。   On the other hand, in the case of a hydraulic transfer method (for example, see Patent Document 2) excellent in transferability of a pattern to a curved surface, there is a problem in the hot water resistance and fixability of the transferred pattern as disclosed in Patent Document 1 There is.

すなわち、水圧転写法の場合、転写インキによって印刷された転写紙の絵柄を成形品の加飾面に転写する前に成形品の加飾面に転写インキ定着層を形成し、この転写インキ定着層に絵柄を転写するようになっているのであるが、本発明の発明者らが得た知見によれば、転写インキ定着層を構成する転写インキ定着層形成用塗料の乾燥度が絵柄の耐熱水性や定着性に大きく影響する。詳しく説明すると、転写インキ定着層は、転写インキ定着層形成用塗料を成形品の加飾面に塗布し加熱乾燥することによって得られるが、乾燥しすぎると、転写インキの定着性に不具合が発生し、柄の流れが発生したりする。また、乾燥が不十分であると、転写インキは定着するものの耐熱水性に不具合が生じる。しかも、乾燥条件の許容範囲が狭く、乾燥温度分布が異なると、部分的に定着性の悪い部分や耐熱水性に欠ける部分が生じやすい。特に、背面側の補強リブやフィン等が部分的に突出するような成形品の場合、転写インキ定着層形成用塗料を塗布後、熱風乾燥炉中に成形品を入れて転写インキ定着層形成用塗料を乾燥させようとすると、補強リブと補強リブあるいはフィンで囲まれた部分に熱風滞留が発生し、成形品表面側の温度分布がばらつきやすくより乾燥むらが生じやすくなる。   That is, in the case of the hydraulic transfer method, the transfer ink fixing layer is formed on the decorative surface of the molded product before the transfer paper image printed with the transfer ink is transferred to the decorative surface of the molded product. According to the knowledge obtained by the inventors of the present invention, the dryness of the transfer ink fixing layer forming paint constituting the transfer ink fixing layer is determined by the heat resistance of the pattern. And fixability greatly. Explaining in detail, the transfer ink fixing layer is obtained by applying the transfer ink fixing layer forming paint to the decorative surface of the molded product and drying it by heating. However, a pattern flow may occur. Further, if the drying is insufficient, the transfer ink is fixed, but there is a problem in hot water resistance. In addition, if the allowable range of the drying conditions is narrow and the drying temperature distribution is different, a part having poor fixability or a part lacking hot water resistance tends to occur. In particular, in the case of molded products in which the reinforcing ribs and fins on the back side partially protrude, after applying the transfer ink fixing layer forming paint, the molded product is placed in a hot air drying oven to form the transfer ink fixing layer. When the paint is to be dried, hot air stays in the portions surrounded by the reinforcing ribs and the reinforcing ribs or fins, and the temperature distribution on the surface side of the molded product tends to vary, resulting in uneven drying.

特開2000−1096号公報JP 2000-1096 A 特開2003−251999号公報JP 2003-251999 A

本発明は、上記事情に鑑みて、水圧転写法を用いて成形品の加飾面にムラなく耐熱温水性および定着性に優れた絵柄を転写できる成形品の加飾方法を提供することを目的としている。   The present invention has been made in view of the above circumstances, and an object of the present invention is to provide a method for decorating a molded product that can transfer a pattern having excellent heat resistance, hot water resistance and fixing properties to the decorative surface of the molded product using a hydraulic transfer method. It is said.

上記目的を達成するために、本発明にかかる成形品の加飾方法は、成形品の加飾面に転写インキ定着層形成用塗料を塗布し、転写インキ定着層形成用塗料を所定の乾燥度になるまで加熱乾燥して転写インキ定着層を形成したのち、この転写インキ定着層に転写インキで予め印刷絵柄が描かれた転写シートから前記絵柄を水圧転写印刷する工程を備える成形品の加飾方法であって、前記成形品の加飾面全体を略均一な温度に保ちながら転写インキ定着層形成用塗料を加熱乾燥することを特徴としている。   In order to achieve the above object, a method for decorating a molded product according to the present invention comprises applying a transfer ink fixing layer forming coating to the decorative surface of the molded product, and applying the transfer ink fixing layer forming coating to a predetermined degree of dryness. After forming a transfer ink fixing layer by heating and drying until it becomes, decoration of a molded article comprising a step of hydraulic transfer printing the pattern from a transfer sheet on which a print pattern is previously drawn with transfer ink on the transfer ink fixing layer The method is characterized in that the coating material for forming a transfer ink fixing layer is heated and dried while maintaining the entire decorative surface of the molded article at a substantially uniform temperature.

また、本発明の加飾方法の場合、転写インキ定着層形成用塗料を加熱乾燥時、成形品の非加飾面に部分的に放熱効率の異なる治具を添設させて加飾面全体を略均一な温度に制御すること、成形品の非加飾面側が、転写インキ定着層形成用塗料を加熱乾燥時、加飾面全体を略均一な温度になるような凹凸形状に形成されていること、あるいは、成形品が、転写インキ定着層形成用塗料を加熱乾燥時、加飾面全体を略均一な温度になるように成形品内部の所望位置に熱伝導度の異なる部材を埋設されていることが好ましい。   In addition, in the case of the decorating method of the present invention, when the transfer ink fixing layer forming coating is heated and dried, a jig having a different heat dissipation efficiency is partially attached to the non-decorated surface of the molded product to completely decorate the decorated surface. By controlling the temperature to a substantially uniform temperature, the non-decorated surface side of the molded product is formed in a concavo-convex shape so that the entire decorated surface becomes a substantially uniform temperature when the transfer ink fixing layer forming paint is heated and dried. Or, when the molded product is dried by heating the coating material for forming the transfer ink fixing layer, a member having a different thermal conductivity is embedded at a desired position inside the molded product so that the entire decorative surface is at a substantially uniform temperature. Preferably it is.

また、本発明の加飾方法は、特に限定されないが、たとえば、浴室ユニットの浴槽、エプロン、カウンター等のように熱水に曝される成形品に好適に用いられる。また、成形品の材質は、特に限定されないが、たとえば、繊維強化プラスチック(FRP)が挙げられる。
本発明において、転写シートとは、水溶性あるいは水膨潤性のベースフィルムの上に転写インキによって印刷絵柄が印刷されているものを言い、ベースフィルムの材質としては、特に限定されないが、ポリビニルアルコール(ポバール)を主成分とし、これにポリアクリル酸アミドや他の水溶性高分子、デンプン、ゼラチン、にかわ等を必要に応じて混合した公知のものが好適に使用される。
Moreover, the decorating method of this invention is although it does not specifically limit, For example, it uses suitably for the molded article exposed to hot water like the bathtub of a bathroom unit, an apron, a counter etc., for example. The material of the molded product is not particularly limited, and examples thereof include fiber reinforced plastic (FRP).
In the present invention, the transfer sheet refers to a printed picture printed with a transfer ink on a water-soluble or water-swellable base film. The material of the base film is not particularly limited, but polyvinyl alcohol ( Poval) is used as a main component, and a known product obtained by mixing polyacrylamide, other water-soluble polymer, starch, gelatin, glue or the like as necessary is preferably used.

本発明にかかる成形品の加飾方法は、加飾面全体の温度を略均一な温度に制御しながら転写インキ定着層形成用塗料を加熱乾燥を加熱乾燥するようにしたので、加飾面全体で略均一に転写インキ定着層形成用塗料が乾燥される。したがって、得られる転写インキ定着層は加飾面全体でむら無く所定の乾燥度となり、しっかりと転写インキを水圧転写することができ、結果として耐熱水性、耐久性に優れた加飾を成形品の加飾面に形成することができる。   Since the decoration method of the molded product according to the present invention is such that the transfer ink fixing layer forming coating is dried by heating while controlling the temperature of the entire decorative surface to a substantially uniform temperature, the entire decorative surface is heated. The coating material for forming the transfer ink fixing layer is dried almost uniformly. Therefore, the transfer ink fixing layer obtained has a predetermined dryness evenly on the entire decorative surface, and the transfer ink can be firmly hydraulically transferred, resulting in a decoration with excellent hot water resistance and durability. It can be formed on the decorative surface.

以下に、本発明を、その実施の形態をあらわす図面を参照しつつ詳しく説明する。
図1〜図3は、本発明にかかる成形品の加飾方法の第1の実施の形態をあらわしている。
Hereinafter, the present invention will be described in detail with reference to the drawings showing embodiments thereof.
1 to 3 show a first embodiment of a method for decorating a molded product according to the present invention.

この加飾方法は、図1に示すような加飾面11の背面にリブ12が設けられた成形品1に加飾を施すようになっていて、図2(a)に示すように、まず、成形品1の背面形状にほぼ沿う形状のハンドレイアップ法等で形成されたFRP製の治具本体21と、治具本体21の成形品1のリブ12とリブ12とによって囲まれた部分に沿う位置に埋設されたアルミニウム製の伝熱材22とから構成されている温度均一化治具2を形成しておく。
そして、図1に示すFRP製の成形品1を成形し、溶剤を用いて成形品1に残る離型剤を脱脂除去し、たとえば、エポキシ系プライマー塗料を成形品1の加飾面11に塗布したのち、加熱乾燥炉(図示せず)中に成形品1を入れて焼き付け乾燥してプライマー塗料層(図示せず)を加飾面11に形成する。
In this decoration method, decoration is applied to the molded product 1 in which the rib 12 is provided on the back surface of the decoration surface 11 as shown in FIG. 1, and as shown in FIG. A portion surrounded by the FRP jig body 21 formed by a hand lay-up method or the like having a shape substantially conforming to the back surface shape of the molded article 1, and the rib 12 and the rib 12 of the molded article 1 of the jig body 21. The temperature equalizing jig 2 composed of the heat transfer material 22 made of aluminum embedded in a position along the line is formed in advance.
Then, the FRP molded product 1 shown in FIG. 1 is molded, and the release agent remaining in the molded product 1 is degreased and removed using a solvent. For example, an epoxy primer coating is applied to the decorative surface 11 of the molded product 1. After that, the molded product 1 is put in a heating and drying furnace (not shown) and baked and dried to form a primer coating layer (not shown) on the decorative surface 11.

つぎに、図2(b)に示すように、温度均一化治具2を成形品1の背面に添設させた状態で、たとえば、転写インキ定着層形成用塗料をプライマー塗料層の表面に塗布したのち、温度均一化治具2を成形品1の背面に添設させた状態で成形品1を加熱乾燥炉に入れて加熱乾燥させて転写インキ定着層を形成する。
その後、図3(a)に示すように、ポリビニルアルコールを主成分とするベースフィルムに印刷図柄が印刷された転写シート3を水の上に浮かべ、ベースフィルムを構成するポリビニルアルコールを水4に溶解させるとともに、転写シート3の転写インキに活性剤(たとえば、シンナー等の有機溶剤)を噴霧して転写インキを溶解させたのち、図3(b)に示すように、温度均一化治具2を取り外した状態で転写インキ定着層が形成された成形品1aをその加飾面11側を溶解状態の転写シート31に押し当てて水中に沈め、水圧によって転写シート31の印刷図柄を転写インキ定着層に転写する。
Next, as shown in FIG. 2B, for example, a transfer ink fixing layer forming coating is applied to the surface of the primer coating layer with the temperature equalizing jig 2 attached to the back surface of the molded product 1. After that, with the temperature equalizing jig 2 attached to the back surface of the molded product 1, the molded product 1 is placed in a heating and drying furnace and dried by heating to form a transfer ink fixing layer.
Thereafter, as shown in FIG. 3 (a), the transfer sheet 3 on which a printed pattern is printed on a base film mainly composed of polyvinyl alcohol is floated on water, and the polyvinyl alcohol constituting the base film is dissolved in water 4. In addition, after spraying an activator (for example, an organic solvent such as thinner) on the transfer ink of the transfer sheet 3 to dissolve the transfer ink, as shown in FIG. The molded product 1a on which the transfer ink fixing layer is formed in the detached state is pressed against the transfer sheet 31 in the dissolved state on the decorative surface 11 side and submerged in water, and the print pattern of the transfer sheet 31 is transferred to the transfer ink fixing layer by water pressure Transcript to.

つぎに、成形品1を引き上げて転写後に残るベースフィルム成分の残渣を温水で洗い流したのち、表面の水滴を拭取り、乾燥炉内に入れ塗膜に吸収された水分を乾燥除去する。
そして、必要に応じて転写インキ層の上に、たとえば、アクリルウレタン系のトップコート塗料を塗布したのち、トップコート塗料を焼付け乾燥する。
Next, the molded product 1 is pulled up and the residue of the base film component remaining after the transfer is washed away with warm water. Then, water droplets on the surface are wiped off and placed in a drying furnace to dry and remove moisture absorbed in the coating film.
Then, for example, after applying an acrylic urethane topcoat paint on the transfer ink layer as necessary, the topcoat paint is baked and dried.

この加飾方法は、以上のように、温度均一化治具2を成形品1に添接させた状態で加飾面に塗装された転写インキ定着層用塗料を加熱乾燥するようにしたので、リブ12とリブ12との間部分で、熱風滞留によって加熱が悪くても、温度均一化治具2に埋め込まれた伝熱材22によって加熱炉からの熱が他の部分より効率よく伝わり、結果として、加飾面側では全面にわたってほぼ均一な条件で転写インキ定着層用塗料が乾燥される。
したがって、得られる転写インキ定着層は加飾面全体でむら無く所定の乾燥度となり、しっかりと転写シート3の転写インキを転写インキ定着層に水圧転写することができ、結果として耐熱水性、耐久性に優れた加飾を成形品の加飾面に形成することができる。
Since this decorating method is as described above, the coating material for the transfer ink fixing layer coated on the decorating surface in the state where the temperature equalizing jig 2 is attached to the molded product 1 is dried by heating. Even if the heating between the ribs 12 and the ribs 12 is poor due to hot air retention, the heat transfer material 22 embedded in the temperature uniformizing jig 2 allows the heat from the heating furnace to be transmitted more efficiently than the other parts, resulting in a result. As described above, the coating material for the transfer ink fixing layer is dried on the decorative surface side under substantially uniform conditions.
Therefore, the obtained transfer ink fixing layer has a predetermined dryness evenly on the entire decorative surface, and the transfer ink of the transfer sheet 3 can be firmly hydraulically transferred to the transfer ink fixing layer, resulting in hot water resistance and durability. Can be formed on the decorative surface of the molded product.

しかも、プライマー塗料、トップコート塗料および転写インキ定着層形成用塗料の加熱乾燥温度(焼き付け乾燥温度)が異なっても、温度均一化治具2を成形品1に添設させることによって、昇温時間を制御し、プライマー塗料、トップコート塗料および転写インキ定着層形成用塗料を同一設備条件で乾燥させるこができる。また、成形品のサイズが異なる場合であっても、温度均一化治具2を変更するだけで、同一の乾燥炉を用いて乾燥させることができる。
したがって、乾燥炉等の設備コストを低減できるとともに、生産性もよくなる。
Moreover, even if the heat drying temperature (baking drying temperature) of the primer paint, the top coat paint, and the transfer ink fixing layer forming paint is different, the temperature raising time can be increased by attaching the temperature equalizing jig 2 to the molded product 1. Thus, the primer paint, the top coat paint, and the transfer ink fixing layer forming paint can be dried under the same equipment conditions. Moreover, even when the sizes of the molded products are different, they can be dried using the same drying furnace only by changing the temperature equalizing jig 2.
Therefore, equipment costs such as a drying furnace can be reduced, and productivity is improved.

図4は、本発明にかかる成形品の加飾方法の第2の実施の形態をあらわしている。
図4に示すように、この加飾方法は、加熱乾燥炉に成形品5を入れたとき、成形品5の加飾面50の表面温度が全面にわたってほぼ均一になるように、成形品本体51内に伝熱性を考慮した位置に成形品本体と熱伝導度が異なる材料(たとえば、アルミニウム等の金属材料)からなる補強材52を埋設した成形品5を用い、温度均一化治具2を用いないようにした以外は、上記第1の実施の形態と同様になっている。
FIG. 4 shows a second embodiment of the method for decorating a molded product according to the present invention.
As shown in FIG. 4, in this decorating method, when the molded product 5 is put in a heating and drying furnace, the molded product main body 51 so that the surface temperature of the decorated surface 50 of the molded product 5 is substantially uniform over the entire surface. A temperature equalizing jig 2 is used by using a molded product 5 in which a reinforcing material 52 made of a material (for example, a metal material such as aluminum) having a thermal conductivity different from that of the molded product main body is embedded in a position considering heat conductivity. Except for the above, it is the same as the first embodiment.

本発明にかかる成形品の加飾方法は、上記の実施の形態に限定されない。たとえば、温度均一化治具2を用いたりせず、成形品のリブの形状や配置、あるいは肉厚を調整することによって、加飾面の温度を均一化するようにしても構わない。
また、成形品の加飾面には、必要に応じてゲルコート層を設けるようにしても構わない。
The decoration method of the molded product concerning this invention is not limited to said embodiment. For example, the temperature of the decorative surface may be made uniform by adjusting the shape and arrangement of the ribs of the molded product or the thickness without using the temperature uniformizing jig 2.
Moreover, you may make it provide a gel coat layer in the decorating surface of a molded article as needed.

本発明にかかる成形品の加飾方法によって加飾される成形品の1例をあらわす断面図である。It is sectional drawing showing one example of the molded product decorated by the decoration method of the molded product concerning this invention. 図1の成形品を加飾する本発明にかかる成形品の加飾方法の第1の実施の形態を工程順に説明する図であって、同図(a)はその温度均一化治具装着前の状態をあらわす断面図、同図(b)はその温度均一化治具装着後の状態をあらわす断面図である。It is a figure explaining 1st Embodiment of the decoration method of the molded product concerning this invention which decorates the molded product of FIG. 1 in order of a process, The figure (a) is the temperature equalization jig | tool before mounting | wearing FIG. 4B is a cross-sectional view showing the state after the temperature equalizing jig is mounted. 図1の成形品を加飾する本発明にかかる成形品の加飾方法の第1の実施の形態を工程順に説明する図であって、同図(a)は転写シートを水に浮かべた状態をあらわす断面図、同図(b)は成形品に水圧転写する状態をあらわす断面図である。It is a figure explaining 1st Embodiment of the decoration method of the molded product concerning this invention which decorates the molded product of FIG. 1 in order of a process, The figure (a) is the state which floated the transfer sheet in water FIG. 4B is a cross-sectional view showing a state of hydraulic transfer to a molded product. 本発明にかかる成形品の加飾方法の第2の実施の形態であって、その加飾される成形品の1例をあらわす断面図である。It is 2nd Embodiment of the decoration method of the molded product concerning this invention, Comprising: It is sectional drawing showing 1 example of the molded product decorated.

符号の説明Explanation of symbols

1,5 成形品
2 温度均一化治具
3 転写シート
4 水
11 加飾面
12 リブ
21 治具本体
22 伝熱材
51 補強材
1, 5 Molded product 2 Temperature uniformizing jig 3 Transfer sheet 4 Water 11 Decorating surface 12 Rib 21 Jig body 22 Heat transfer material 51 Reinforcing material

Claims (4)

成形品の加飾面に転写インキ定着層形成用塗料を塗布し、転写インキ定着層形成用塗料を所定の乾燥度になるまで加熱乾燥して転写インキ定着層を形成したのち、この転写インキ定着層に転写インキで予め印刷絵柄が描かれた転写シートから前記絵柄を水圧転写印刷する工程を備える成形品の加飾方法であって、
前記成形品の加飾面全体を略均一な温度に保ちながら転写インキ定着層形成用塗料を加熱乾燥することを特徴とする成形品の加飾方法。
The transfer ink fixing layer forming coating is applied to the decorative surface of the molded product, and the transfer ink fixing layer forming coating is heated and dried to a predetermined dryness to form a transfer ink fixing layer. A method for decorating a molded article comprising a step of hydraulic transfer printing the pattern from a transfer sheet on which a printed pattern is previously drawn with transfer ink on a layer,
A method for decorating a molded product, comprising: drying the coating for forming a transfer ink fixing layer while maintaining the entire decorative surface of the molded product at a substantially uniform temperature.
転写インキ定着層形成用塗料を加熱乾燥時、成形品の非加飾面に部分的に放熱効率の異なる治具を添設させて加飾面全体を略均一な温度に制御する請求項1に記載の成形品の加飾方法。   The heat transfer drying of the coating material for forming the transfer ink fixing layer is performed by adding a jig having a different heat dissipation efficiency to the non-decorated surface of the molded product to control the entire decorated surface to a substantially uniform temperature. The method of decorating the described molded product. 成形品の非加飾面側が、転写インキ定着層形成用塗料を加熱乾燥時、加飾面全体を略均一な温度になるような凹凸形状に形成されている請求項1に記載の成形品の加飾方法。   The molded article according to claim 1, wherein the non-decorated surface side of the molded article is formed in a concavo-convex shape so that the entire decorated surface has a substantially uniform temperature when the transfer ink fixing layer forming paint is heated and dried. Decoration method. 成形品が、転写インキ定着層形成用塗料を加熱乾燥時、加飾面全体を略均一な温度になるように成形品内部の所望位置に熱伝導度の異なる部材を埋設されている請求項1に記載の成形品の加飾方法。   2. The molded product is embedded with members having different thermal conductivities at desired positions inside the molded product so that the entire decorative surface has a substantially uniform temperature when the transfer ink fixing layer forming coating is heated and dried. A method for decorating a molded product according to 1.
JP2004019646A 2004-01-28 2004-01-28 Jig for molded product and method for decorating molded product Expired - Fee Related JP4297217B2 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007130954A (en) * 2005-11-14 2007-05-31 Sekisui Home Techno Kk Manufacturing method of decorative molded article
CN114345600A (en) * 2021-12-31 2022-04-15 贵州电网有限责任公司 Painting device and construction method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007130954A (en) * 2005-11-14 2007-05-31 Sekisui Home Techno Kk Manufacturing method of decorative molded article
CN114345600A (en) * 2021-12-31 2022-04-15 贵州电网有限责任公司 Painting device and construction method thereof
CN114345600B (en) * 2021-12-31 2023-01-06 贵州电网有限责任公司 Painting device and construction method thereof

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