JP2005209599A - Application of rice hull carbonized fiber - Google Patents

Application of rice hull carbonized fiber Download PDF

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JP2005209599A
JP2005209599A JP2004048737A JP2004048737A JP2005209599A JP 2005209599 A JP2005209599 A JP 2005209599A JP 2004048737 A JP2004048737 A JP 2004048737A JP 2004048737 A JP2004048737 A JP 2004048737A JP 2005209599 A JP2005209599 A JP 2005209599A
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carbonized fiber
paper
fiber
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snow
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Hideaki Tanaka
秀明 田中
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract

<P>PROBLEM TO BE SOLVED: To enhance the value added of rice hulls and bamboo sheath, and rationalize production. <P>SOLUTION: Rise hulls, bamboo sheath, wood chips, sawdusts, etc., as raw materials are charged together with water in a globe digester, heated to 165 to 200°C at 20 atm to obtain carbon fibers and a crude cancerocidal raw liquid, which is absorbed in rice bran or bean curd lees, dried and powdered to obtain a carcerocidal immunopotentiation material containing nonsteroidal saponin, polyphenol, catechin, mannan and polysaccharide. In this substance, Aspergillus, urea, the carbonized fibers and a nutrient are added, and fermented to obtain an organic fertilizer. The carbonized fibers are processed into an electric resistance heater, which is used for snow melting heaters, hothouse heating and baths, and also as electromagnetic wave absorbing mediums and mobile phone electromagnetic wave absorbing mediums. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明はモミガラ、竹皮、カラ松などの植物質を165℃で20気圧の水蒸気で加熱処理し、これを瀘別して瀘液は濃縮乾燥して制癌剤の原料とし、瀘別した固形物のモミガラ炭素化繊維質を回収する。このモミガラ炭素化繊維は80%の含水率のものでは電気抵抗値が厚み10m/m、長さ1mで電流を通すと80〜160Ωである。
また電流値は0.1アンペアー〜1アンペアーは電圧によって変化する導電性であり、これら黒鉛や炭素繊維を加えてブレンドしたモミガラ炭素化繊維は電導性を高める。
元来モミガラ炭素化繊維の含水繊維は通電によって含水分を加熱蒸発し、次第に電導性を低下するから安定性の上からも黒鉛と炭素繊維を混合する必要がある。
In the present invention, plant materials such as rice crackers, bamboo skins, and pine trees are heat-treated at 165 ° C. with water vapor of 20 atm, and this is separated, and the filtrate is concentrated and dried to obtain a raw material for the anticancer agent. Collect carbonized fiber. If the moisture content of this rice bran carbonized fiber is 80%, the electric resistance value is 10 m / m in thickness, 1 m in length, and 80 to 160Ω when current is passed.
Moreover, the electric current value is 0.1 amperes to 1 ampere, and the conductivity varies depending on the voltage, and the rice bran carbonized fiber blended by adding these graphite and carbon fibers increases the conductivity.
Originally, the water-containing fibers of carbonized carbonized fibers heat and evaporate the water content by energization, and gradually reduce the conductivity. Therefore, it is necessary to mix graphite and carbon fibers in terms of stability.

またこれを利用するには雪害対策として帆立貝やカキガラの産業廃棄物を粉砕したものとモミガラ炭素化繊維を混合し散布すると、太陽光の照射によって溶雪作用がおこり雪は溶解水となって雪害を防ぐ。しかし、降雪量が多いと太陽光の照射エネルギーだけでは融解速度が遅く、また曇天の日には融解の電流を通すとモミガラ炭素化繊維に電流が流れてジュール熱で80〜90℃に温度が上昇すると、盛んに水蒸気を発生して水分は沸騰して水分は蒸発するが、電導体の炭素粉や黒鉛粉が混合されていると含水物が水蒸気となり、発散しても温度は引き続き加温される。これにグライコールを入れたり塩類を入れておくと電導性を増大し加熱は継続される。従って、この積雪地での溶雪速度を増加せしめるに、このモミガラ炭素化繊維を合成樹脂袋に密封して、これを積雪の上面中間に配列し、これに導線を接続して通電すると発熱して水蒸気を発生すると雪はこの水蒸気によって融解し、融解した水は炭素繊維袋に取り入れると連続的水蒸気発生と加熱温によって雪溶は速度をまして迅速に除雪する様になり、積雪が崩れても加熱は続くが水分が少なくなると水蒸気発生は止まる。このモミガラ炭素化繊維の電気抵抗値が高くなると次第に電流値は小さくなり、温度は30〜50℃で恒温化する事になると、依然として解雪は続き雪は無くなる事になる。この炭素化繊維は積雪部から自己的に上雪から融解しながら雪中に入り、水蒸気の源の雪水を補給しながら落下するので地面に接するまで融雪は続くので自動的に操作が行われる。  In order to use this, as a measure against snow damage, when scallops and oysters are crushed and mixed with carbonized fiber, the snow melting action occurs due to the irradiation of sunlight, and the snow becomes dissolved water. prevent. However, when the amount of snowfall is large, the melting rate is slow only by the irradiation energy of sunlight, and when the current of melting is passed on a cloudy day, the current flows through the carbonized carbon fiber and the temperature reaches 80-90 ° C due to Joule heat. When it rises, water vapor is vigorously generated, the water boils and the water evaporates, but when the conductor carbon powder or graphite powder is mixed, the water content becomes water vapor, and the temperature continues to be warmed even if it is emitted Is done. If Glycol or salt is added to this, the conductivity is increased and heating is continued. Therefore, in order to increase the snow melting speed in this snowy area, this paddy carbonized fiber is sealed in a synthetic resin bag, and this is arranged in the middle of the upper surface of the snow, and when a conducting wire is connected to this and energized, heat is generated. When water vapor is generated, the snow melts with this water vapor, and when the melted water is taken into the carbon fiber bag, the snow melt is quickly removed by the continuous water vapor generation and heating temperature. Although heating continues, the generation of water vapor stops when the water content decreases. When the electric resistance value of the rice bran carbonized fiber is increased, the current value is gradually decreased. When the temperature is kept constant at 30 to 50 ° C., the snow melting continues and the snow disappears. This carbonized fiber enters the snow while melting from the snow on its own from the snow, and falls while replenishing the water source of water vapor, so the snow melt continues until it touches the ground, so the operation is performed automatically .

この様にモミガラ炭素化繊維は粉末状の繊維であるから含水性に富み、断熱性を保持するのであるが、合成樹脂の発泡体の断熱材を炭素繊維袋の底部に接合しておくと、下面の熱伝導は遅くなり、温度調整が行われるから、布団状に炭素繊維袋を屋根上に敷き詰めると、その布団状上の降雪は加温されて炭素繊維に水を補給しながら水蒸気を発生し加温し、降雪しても雪は溜らない。従ってこれを菜園や花壇のビニールハウスの地面の土壌に設置すると、温室内が加温されて気温をあげて保温効果を発揮するので温室の湿度調整に役立つ効果がある。  In this way, the rice bran carbonized fiber is powdery fiber, so it is rich in water content and retains heat insulation properties, but if the synthetic resin foam heat insulating material is bonded to the bottom of the carbon fiber bag, Since heat conduction on the bottom surface is slowed and temperature adjustment is performed, if a carbon fiber bag is laid on the roof in a futon shape, the snowfall on the futon shape is heated and water vapor is generated while supplying water to the carbon fiber Even if it heats up, it will not accumulate even if it snows. Therefore, when this is installed on the soil in the ground of a vegetable garden or a flowerbed greenhouse, the inside of the greenhouse is heated to raise the temperature and exert a heat retaining effect, which has the effect of helping to adjust the humidity of the greenhouse.

この炭素化繊維をナノ粒子に粉砕して、これを合成樹脂や導電性樹脂に混合してフィルム状に黒鉛と混合して導電性を高めると帯状加熱体が作られ、暖房用に利用される。
またこの電力としては、5〜20ボルト、80〜200アンペアーの変圧器によって通電されて20〜60kwの容量のものがよい結果を得る。業務用としての大型のものは5〜〜20ボルト100アンペアーの容量の変圧器が利用される。
When this carbonized fiber is pulverized into nanoparticles and mixed with synthetic resin or conductive resin and mixed with graphite in the form of a film to increase conductivity, a belt-like heating body is made and used for heating .
Moreover, as this electric power, it is energized by a transformer of 5 to 20 volts and 80 to 200 amperes, and a thing with a capacity of 20 to 60 kw gives a good result. Large transformers for business use use transformers having a capacity of 5 to 20 volts and 100 amperes.

このモミガラの炭素化繊維は水蒸気加圧化される時は、6〜12%の硅酸成分は網の目構造で、炭素化繊維の表面を包着し極めて安定した炭素化繊維で、形而変化は少ないので電気抵抗値の変化も少ないが、交流でも整流でも直流でも使用し得る。この電気抵抗媒体としてのモミガラ炭素化繊維、即ち石油を低温で加熱分解してシエール法で水素ガスを回収するときに副生するオイルカーボン粉を回収してモミガラの炭素化繊維と混合したものを抄紙機で抄紙した導電性紙も加熱紙としてまたカーボン電極としても使用され電池に利用される。  When the carbonized fiber of this rice bran is steam-pressurized, 6-12% of the oxalic acid component is a network structure, and the carbonized fiber is a very stable carbonized fiber that encapsulates the surface of the carbonized fiber. Since the change is small, the change in electrical resistance value is also small, but it can be used for AC, rectification, or DC. As an electrical resistance medium, rice bran carbonized fiber, that is, oil carbon powder produced as a by-product when oil is thermally decomposed at low temperature and hydrogen gas is recovered by the Sierre method, and mixed with rice bran carbonized fiber is used. Conductive paper made with a paper machine is also used as a heated paper and as a carbon electrode, and is used for batteries.

またモミガラの主要な需要は物理的な押出機を通じて圧縮しモミガラを粉砕して加熱加圧したものを屈曲した押出ノズルからペレット状に加工すると共に、これを粉砕して粉末化したものを牛や豚等の飼料の増容飼料として使用され、またこれをアスペルギリウス菌で発酵して土壌改良材や飼料添加剤として利用されたほか、炭化して炭素物として利用されてきたが、生産量が多いので他は灰化して土壌改良等に使用され、海草の乾燥材に利用されてきたが、より付加価値の高い新企用途による生産性の合理化が要求されていた。  The main demand for rice bran is that it is compressed through a physical extruder, crushed and heated and pressed into pellets from a bent extrusion nozzle. It has been used as a volume-enhancing feed for pigs, etc., fermented with Aspergillus bacteria and used as a soil conditioner and feed additive, and carbonized and used as a carbonaceous material. Others have been ashed and used for soil improvement, etc., and have been used for seaweed desiccants, but there has been a demand for rationalization of productivity by new enterprise applications with higher added value.

そこで、まずモミガラをロータリーキルン又は電子レンジで加熱して有害農薬を揮酸せしめたものを20気圧165℃の高圧水蒸気で加熱したものを瀘別し、瀘液は制癌剤に加工し、田七粉や脱農薬の米糠や大豆オカラに吸収せしめて乾燥し、健康食品の原料として加工し、瀘別した固形物のモミガラ炭素化繊維はこれにアスペルギリウス菌を混合して発酵して有機肥料に加工し、家庭園芸用客土に加工してまた脱臭剤の原料に加工する。
またこのモミガラ炭素化繊維にパルプガラス繊維、炭素繊維にパルプカーボン、黒鉛粉、ヘドロ繊維を混合して、これを抄紙機で抄造して薄葉紙を作り、これを導電紙に加工し薄葉紙と一般紙クラフト紙、再生紙を加熱凹凸紙を作り、この片面に野菜種子や稲種子を栄養剤と共に紙の突出面の先端に付着せしめたものを、アスペルギリウス菌を吸着したカーボン炭素化繊維パルプ紙を積合したものを圧着せしめた薄葉紙を巻取り、これを必要に応じて田圃や畑の上面に敷き詰めて水液をその上面より散布すると数日後には発芽してその植物は成長する。また炭素化繊維紙に尿素を含浸せしめておくとより成長が助長する。
またモミガラ炭素化繊維は発酵して有機肥料としてその成長を20〜30%向上せしめる。またモミガラ炭素化繊維は電気発熱体として利用され、これに電力を付与すると発熱体として温室栽培に於ける保温加熱体としても利用される。
Therefore, first, the rice bran was heated in a rotary kiln or microwave oven and the toxic pesticide was volatilized, and the one heated with high-pressure steam at 165 ° C at 20 atmospheres was separated, and the liquid smoke was processed into an anticancer agent. Absorbed in pesticide-free rice bran and soybean okara and dried, processed as a raw material for health foods, the solid rice bran carbonized fiber is mixed with Aspergillus bacteria and fermented to be processed into organic fertilizer It is then processed into a home gardening home and then processed into a deodorant raw material.
In addition, pulp glass fiber is mixed with this carbonized fiber, and pulp carbon, graphite powder, sludge fiber is mixed with carbon fiber, and this is made with a paper machine to make a thin paper, which is then processed into a conductive paper. A carbon carbonized fiber pulp paper adsorbed with Aspergillus fungus made from kraft paper and recycled paper with heated uneven paper, with vegetable seeds and rice seeds attached to the tip of the protruding surface of the paper together with nutrients on one side The thin paper on which the product is stacked is rolled up, spread on the upper surface of rice fields or fields as needed, and sprayed with water from the upper surface, germinates and grows a few days later. Further, if carbonized fiber paper is impregnated with urea, growth is further promoted.
Also, rice bran carbonized fiber is fermented to improve its growth as an organic fertilizer by 20-30%. The carbonized carbon fiber is used as an electric heating element, and when electric power is applied thereto, it is also used as a heat-retaining heating element in greenhouse cultivation as a heating element.

またこのモミガラの炭素化繊維をプラスチック袋に密封し、これを電極を一定間隔に取り付けると断熱性発熱袋として暖房用に利用され、また水分を与えると水蒸気を発生し温度を高めビニールハウス内を暖房する。
これを道路や屋根に架設すると解雪に利用され雪害の予防となる。
また炭素化繊維に芝種子を栄養剤とアスペルギリウス菌と共に混合したものを吹き付けによる芝生の殖生が可能となる。またこの炭素化繊維をリグニンやフルフラールやフリフラールアルコールとを加え、高圧プレスで加熱圧縮すると圧縮板タイルが出来、建材や加熱体に利用される。
またこの炭素化繊維を焼成ロータリーキルンで450℃で焼成した炭素化繊維は活性炭粉として吸着剤として汚水処理やし尿処理に脱臭浄化に利用され、これをバインダーで混合成型圧縮したものを焼成すれば活性炭錠剤ができ脱臭剤に利用される。
In addition, when the carbonized fiber of this rice bran is sealed in a plastic bag and this electrode is attached at regular intervals, it is used for heating as a heat insulating heat generating bag. Heat up.
If this is installed on a road or roof, it will be used for snow removal to prevent snow damage.
Also, lawn breeding can be achieved by spraying carbonized fiber mixed with turf seeds with nutrients and Aspergillus. Moreover, when this carbonized fiber is added with lignin, furfural or furfural alcohol and heated and compressed with a high-pressure press, a compressed plate tile can be formed and used as a building material or a heating element.
Carbonized fibers obtained by firing this carbonized fiber at 450 ° C. in a firing rotary kiln are used as activated carbon powder as an adsorbent for sewage treatment and human urine treatment for deodorization purification. Tablets can be made and used as deodorants.

モミガラは稲作の副生物として多量にできるが、モミガラをそのまま土壌と混合して農業用土を作る時は、硅酸植物である稲に於いて特に硅酸分が多く撥水性であるからなかなか発酵分解がおこらず土壌の通気生がよく土壌中に発生するエチレンガス過剰に対して酸化性となるから水分の吸収や養分の吸収や成長が悪く、窒素肥料も加水分解すれには多量に必要となるから、このモミガラをイックスツルダー圧縮して特殊ノズルから押し出して微粉末した粉末を土壌に混合したり飼料の添加剤として利用しているが、未処理のモミガラも多く焼成してモミガラ灰として土壌改良に利用しているが、ほかはほとんど産業廃棄物として棄却されている。
そこで、このモミガラを有効利用するために高圧水蒸気20気圧165℃に加熱した炭素化繊維の45〜50%のものに加工すると、ほとんどの雑菌は死滅し無菌状態の炭素化繊維ができ、その表面には硅酸網のできた炭素化繊維が得られ、バチルス菌を加えて発酵せしめると菌の増殖巣として作用し、連作障害や根ぐされ病を改善し植物の成長率も客土ににすると20〜30%に増大する性質がある。
Rice bran can be produced in large quantities as a by-product of rice cultivation. It does not occur and the aeration of the soil is good, and it is oxidizable with the excess ethylene gas generated in the soil, so it absorbs moisture and absorbs nutrients poorly, and nitrogen fertilizer is also required in large quantities for hydrolysis Therefore, this powder is compressed into a struder, extruded from a special nozzle, and finely divided powder is mixed with the soil or used as an additive for feed. It is used for improvement, but most others are discarded as industrial waste.
Therefore, when this fiber is processed into 45-50% of carbonized fiber heated to 20 atm 165 ° C. with high-pressure steam in order to make effective use of the rice bran, most germs are killed and aseptic carbonized fiber is formed. In this case, carbonized fiber with succinic acid net is obtained, and when fermented with Bacillus bacteria, it acts as a growth follicle of the fungus, improving continuous cropping damage and rooting disease, and making the plant growth rate 20%. It has the property of increasing to ˜30%.

ところが、現実に農家が使う土壌改良の有機質の多くは需要が制限され、価格が低廉であり需要と供給のバランスがとれないのが現実である。
そこでこの高圧水蒸気処理のモミガラ炭素化繊維の需要開拓を余儀なくされた。
このモミガラの炭素化繊維が比較的高い電導性である事を利用し発熱体として利用するには、その炭素化繊維の特徴を利用し発熱に伴う良好な含水性と撥水性と電気電導生を利用して発熱体としての利用、特に北国地方の雪害対策に利用し、また土壌凍結防止と他の積雪害防止に室温調整と温度調整に利用する。また水耕栽培へ利用するほか、家屋の屋根の積雪防止用の加熱体に利用する。また発酵炭素化繊維の脱臭性を利用し糞尿汚泥の発酵による加水分解と悪臭吸着により乾式分解に利用し、従来使用の貯溜式トイレの脱臭や畜産水産化物の脱臭と発酵肥料を作る事により需要バランスを確立する事にした。
However, the reality is that many of the organic materials for soil improvement used by farmers are limited in demand, and the prices are low, making it impossible to balance supply and demand.
Therefore, we were forced to cultivate demand for this high-pressure steam-treated rice bran carbonized fiber.
In order to utilize the carbonized fiber of the rice bran as a heating element utilizing the relatively high electrical conductivity, good water content, water repellency and electrical conductivity associated with heat generation are utilized by utilizing the characteristics of the carbonized fiber. It is used as a heating element, especially for snow damage countermeasures in the northern region, and for room temperature adjustment and temperature adjustment to prevent soil freeze and other snow damage damage. In addition to hydroponics, it is also used as a heating element for preventing snow accumulation on the roof of houses. In addition, the deodorizing property of fermented carbonized fiber is utilized for hydrolysis by fermentation of manure sludge and bad odor adsorption for dry decomposition, demand for deodorization of conventional storage toilets, deodorization of livestock and marine products and production of fertilizer. I decided to establish a balance.

モミガラを地球釜に入れて水蒸気で加圧して165℃で20気圧で蒸解して瀘別し、瀘液は濃縮して制癌剤や忌避剤に加工し、固形物の炭素化繊維を脱水して含水率を調整して熱伝導体として通電材料に加工して各用途に分別利用する。  Put rice bran into the earth kettle, pressurize with water vapor, digest at 165 ° C and 20 atmospheres, separate, and concentrate the liquid smoke into anticancer agent and repellent, dehydrate solid carbonized fiber and contain water The rate is adjusted and processed into a current-carrying material as a heat conductor and used separately for each application.

モミガラやカラ松樹皮及びカラ松廃材をチップ化したものを高圧処理する時100〜120℃では真菌その他の細菌、ウィルスは一部生存する事があるので、165℃〜170℃の高圧水蒸気で加熱殺菌したモミガラ炭素化繊維を導電媒体や発酵有機肥料とした。そのためには地球釜を使用するが、地球釜の回転が毎時4〜7回とする時は回転軸から高圧水蒸気が瀘失することがあるので、鉛パッキングを使用してアスベストパッキングや硫化ゴムパッキングで抑えてグリスボックスホイルベアリングを螺合し、ダブルギヤーを取付け、その回転軸の内部空間に水蒸気パイプを取り付けて、そのパイプを通じて水蒸気を地球釜内に圧入して加熱するので、そのパイプの継手の接続点から水蒸気が漏れるのを焼鈍した銅鉛パッキングパイプとパイプを接合する。そしてベアリングに水蒸気が入らない様にグリスペーストとワイヤホイルを通じて遮断する。When high-pressure processing is applied to chippings of rice crackers, pine bark, and pine waste wood, the fungi and other bacteria and viruses may partially survive at 100-120 ° C, so heat with high-pressure steam at 165 ° C-170 ° C. Sterilized paddy carbonized fiber was used as a conductive medium and fermented organic fertilizer. For this purpose, the earth pot is used, but when the earth pot is rotated 4-7 times per hour, high pressure steam may be lost from the rotating shaft. The grease box wheel bearing is screwed together, a double gear is attached, a steam pipe is attached to the inner space of the rotating shaft, and steam is press-fitted into the earth kettle through the pipe and heated. The copper lead packing pipe annealed to leak water vapor from the connection point is joined to the pipe. Then, the bearing is blocked through a glyspaste and a wire foil so that water vapor does not enter the bearing.

この地球釜で165℃20気圧の水蒸気でモミガラを蒸解せしめる事により、モミガラ炭素化繊維を瀘別し同時に殺菌する。
出来たモミガラの炭素化繊維を導電性として電気抵抗を10〜150Ω/cm/℃に作る。そして更に電気抵抗値をたかめるに、オイルカーボンや黒鉛粉を混合しまた合成樹脂や糖澱粉を接着剤としてモミガラ、カラ松の炭素化繊維に含浸乾燥させたものや、パルプ繊維にこの炭素化繊維と黒鉛やオイルカーボン粉を混合して抄紙した紙質を作り導電性を高める。またこれを発熱体として農業、野菜、園芸その他の栽培時の温度調節に使用する。
次にモミガラの炭素化繊維にアスペルギリウス菌を混合して発酵せしめて有機肥料を作ると共に、この有機肥料を脱臭剤に再加工して汚水の脱臭浄化材として利用する。
また凍結防止の保温パイプの熱源や屋根の積雪融解除去や温室栽培の湿度調節や温度調節についてテストする。
In this earth kettle, the rice bran is digested with steam at 165 ° C. and 20 atm, so that the carbonized fiber is separated and sterilized at the same time.
The resulting carbonized fiber of rice bran is made conductive to make an electric resistance of 10 to 150 Ω / cm / ° C. In order to further increase the electrical resistance value, oil carbon and graphite powder are mixed and synthetic resin or sugar starch is used as an adhesive to impregnate and dry carbonized fibers of peach and pine, and this carbonized fiber is added to pulp fibers. The paper is made by mixing with graphite and oil carbon powder to improve conductivity. It is also used as a heating element for temperature control during cultivation in agriculture, vegetables, horticulture, and others.
Next, aspergillus is mixed with fermented carbon fiber and fermented to make an organic fertilizer. This organic fertilizer is reprocessed into a deodorizer and used as a deodorizing and purifying material for sewage.
It also tests heat sources for freeze-preserving heat insulation pipes, snow removal from roofs, humidity control and temperature control in greenhouses.

課題を解決しようとする課題The challenge to solve the problem

モミガラの高圧水蒸気で20気圧165℃の温度で蒸解したモミガラは炭素化繊維に変化する。これを瀘別し瀘液は制癌剤原料に使用する。カラ松チップも同様に処理し制癌剤の原料に使用する。瀘別した固形物のモミガラ炭素化繊維は雑菌のほとんどが死滅し、無菌化した硅酸膜のついた炭素化繊維となり導電性となる。従ってこの導電性と脱臭性とができる炭素化繊維を発熱体として利用し、これを更に発熱温度をたかめる為に黒鉛やオイルカーボンを混合すると導電性が高められ、パルプや合成樹脂やゼラチンを入れてシート状やフィルム状に加工すると電熱体として利用されるが、モミガラの炭素化繊維自体粉体を道路や屋根に散布したものに電気を与えると含水繊維の水分を発熱によって蒸発し、水分を連続的に補給すれば持続的水蒸気の発生が行われ、温室内の温度を高め温度を調節するから冬期野菜や幼稲の育成に利用される。また積雪には袋にモミガラを入れて充填して通電すると発熱し、水蒸気を発生するから融雪装置として雪害を予防する溶解材として利用し、その溶解した雪水を発熱体に補給を調整して与えるといつまでも水蒸気が発生し、解雪が速やかに行われるのでそのテストを行う。  The rice cracker cooked at 20 atm 165 ° C. with the high-pressure steam of the rice bran changes to carbonized fiber. This is separated and the liquid smoke is used as a raw material for anticancer drugs. Karamatsu chips are processed in the same way and used as a raw material for anticancer drugs. The solid rice bran carbonized fibers that have been sorted out are almost completely killed, and become carbonized fibers with a sterilized oxalic acid film and become conductive. Therefore, using carbonized fiber that can conduct and deodorize as a heating element, and adding graphite or oil carbon to further increase the heating temperature, conductivity is increased, and pulp, synthetic resin, and gelatin are added. If it is processed into a sheet or film, it will be used as an electric heating element. If it is continuously replenished, continuous water vapor is generated, and the temperature inside the greenhouse is raised and the temperature is adjusted, so it is used to grow winter vegetables and young rice. Also, when piling in a bag and filling it with electricity, it will generate heat when it is energized, and since it generates water vapor, it is used as a melting material to prevent snow damage as a snow melting device, and the dissolved snow water is adjusted to replenish the heating element If given, water vapor will be generated forever, and snow melting will be done quickly, so test it.

またパルプと炭素化繊維と黒鉛、オイルカーボンを混合した紙質は電池や電磁場吸収やガス吸着紙や発熱紙や室内空気の浄化吸着紙に利用される。
またこのモミガラ炭素化繊維はプラスチック袋に入れて密封し電極を差し込み、発熱布団として屋根や発酵木屑(鋸屑)乾式風呂に利用すると屋根の積雪を解雪し、道路の解雪に役立ち氷結道路にタイル状の張りに通電すると氷結体を解氷し自動車のスリップ事故を防止し、自動車や列車の窓ガラスの氷結防止に電気発熱体として利用される。
Also, the paper quality that is a mixture of pulp, carbonized fiber, graphite, and oil carbon is used for batteries, electromagnetic field absorption, gas adsorption paper, heat generation paper, and indoor air purification adsorption paper.
In addition, this carbonized fiber is put in a plastic bag and sealed, and an electrode is inserted. When it is used as a heating bed for a roof or fermented wood waste (sawdust) dry bath, it will melt snow on the roof, helping to dissolve snow on the road, and to freeze road When electricity is applied to the tile-like tension, the ice is melted to prevent the car from slipping, and it is used as an electric heating element to prevent the car and train window glass from freezing.

発明の効果The invention's effect

モミガラや竹皮の高圧水蒸気加熱した炭素化繊維は電導体を保持するから、通電によって家屋や農業温室の暖房と湿度調整ができ、更にこれに黒鉛、カーボン繊維オイルカーボンを混合す更に電導性が高くなる事によって電気抵抗体として利用される。
そして、この炭素化繊維を黒鉛、オイルカーボン、カーボン繊維を混合したものを袋に充填し、電気を印加する事によって断熱性のある水蒸気発生発熱体ができるので屋根や道路の除雪用融解加熱材として利用される。
Carbonized fiber heated by high-pressure steam such as rice crackers and bamboo bark retains electrical conductors, so heating and humidity adjustment of houses and agricultural greenhouses can be performed by energization, and furthermore, conductivity can be improved by mixing graphite, carbon fiber oil and carbon. It is used as an electrical resistor by becoming high.
This carbonized fiber is a mixture of graphite, oil carbon, and carbon fiber filled into a bag, and by applying electricity, a heat-generating steam-generating heating element can be formed, so that a melting heating material for removing snow from roofs and roads Used as

またこの炭素化繊維を450℃のロータリーキルン内で焼成すると活性炭ができ、従来の公知の活性炭より歩留が倍増し焼却加熱費が半減し安価であるので、汚水や産業廃棄物の脱臭や大気ガス汚染吸着材として有用である。  In addition, when this carbonized fiber is baked in a rotary kiln at 450 ° C., activated carbon is produced, and the yield is doubled compared to the conventional known activated carbon, and the incineration heating cost is halved and inexpensive. Therefore, deodorization of sewage and industrial waste and atmospheric gas Useful as a contaminant adsorbent.

またモミガラ炭素化繊維は抄造紙に抄紙して、これに栄養剤を吸収させ稲の種子を凹凸紙の突起面に樹脂で塗着せしめて積合紙として巻取り、これを水田に浮上せしめて敷き詰めると簡便な田植えが行われ雑草の駆除にも利用されるので、耕運機の必要はない。  Also, the carbonized fiber is made on paper and absorbed with nutrients, and rice seeds are coated with resin on the protruding surface of the concavo-convex paper, wound up as a laminated paper, and floated on the paddy field. When laid down, simple rice planting is performed and weeds are used to control weeds, so there is no need for a cultivator.

また道路の側面の堤の芝生の植物として、芝生の種子とモミガラ炭素化繊維とを混合し、尿素、硅皮酸、コラーゲンを混合したものを水に分散して吹き付けると、崖面の芝生の植え付けが容易となり連作障害がないばかりでなく電気通電によって加温ができるので豪雪地方の芝生植え付けに便利であり根ぐされを生じない。  Also, as a lawn plant on the side of the road, when grass seeds and rice bran carbonized fiber are mixed, and a mixture of urea, cinnamate, and collagen is dispersed in water and sprayed, Not only is planting easy and there are no continuous cropping failures, but it can be heated by electric current, so it is convenient for planting lawns in heavy snow areas and does not cause rooting.

また竹皮は細長く切断加工して高圧水蒸気処理をした瀘液は濃縮して制癌剤として利用し、瀘別脱水した固形炭素化繊維は水溶性松脂で処理して代用藁として馬の厩舎の敷物に利用すると、藁の様に有害農薬の含有量がほとんどないので安全性が高く、松脂の忌避剤によって馬が食べる心配もなく安全性が高い。  Bamboo skin is cut into thin strips and treated with high-pressure steam. The concentrated liquid is used as an anti-cancer agent. When used, it has a high level of safety because it contains almost no harmful pesticides like salmon, and it is safe without worrying about horses eating with a repellent of pine resin.

モミガラや竹皮や笹葉を高圧水蒸気20気圧165℃の温度で加熱して炭素化繊維と瀘液を濃縮して制癌剤の原料とする。またこの炭素化繊維を電気抵抗発熱材として紙状や繊維マット状に加工して袋に入れて電極を取付けて解雪材や温室の保温材に加工する。
またこの炭素化繊維にパルプスラヂと黒鉛、オイルカーボン、炭素繊維を混合して抄紙した薄葉紙に凹凸面加工したパルプ紙に稲の種子を突起部に張付けた積合紙の巻取紙を水田に敷き詰めると紙は崩壊し水田の田植えをする。
またモミガラ炭素化繊維に芝種子を混合して吹き付けると芝生の植え付けをする。
また炭素化繊維を焼成して活性炭繊維を作る。
Rice bran, bamboo skin, and bamboo leaf are heated at a high-pressure steam of 20 atm. The carbonized fiber is processed into a paper or fiber mat as an electric resistance heating material, put in a bag, attached with an electrode, and processed into a snow melting material or a greenhouse heat insulating material.
In addition, when this padded paddy paper is laid on a paddy field, the paper is made by mixing pulp sludge, graphite, oil carbon, and carbon fiber with this carbonized fiber, and then making the paper into a rough paper. Collapsed and planted rice fields.
If grass seeds are mixed with blown carbonized fibers and sprayed, the grass will be planted.
Carbonized fibers are fired to make activated carbon fibers.

図1は道路の積雪層と除雪融解加熱器の側面図を示す。
モミガラ炭素化繊維粉(A)(A’)(A”)を成型樹脂筐又はポリプロピレンフィルム袋(1)(1’)(1”)に黒鉛粉と混合して含水率85%として調整したものを充填し、両端を密封する。次に予め篏挿した電極(2)(3)と(2)(3’)と(2”)(3”)を密封し、導線(4)(5)と(4’)(5’)と(4”)(5”)とを電極(K)(K’)(K”)に連結して炭素化繊維粉(A)(A’)(A”)に電力を印加し、発熱せしめると内部水分は水蒸気となり袋の上面に予め穿孔した孔(6)(7)(6’)(7’)(6”)(7”)を通じて袋外に水蒸気を発生し、上部の積雪層(8)に拡散して融雪する。そして、成型樹脂筐又はポリプロピレンフィルム袋(1)(1’)(1”)の片方端には細管(9)(9’)(9”)の上部開口(9a)(9’a)(9”a)はジョーゴ即ち回転軸の末広管とする。
電源(K)(K’)(K”)により電力を電極(2)(3)(2’)(3’)(2”)(3”)に印加すると炭素化繊維は発熱し、5〜10ボルトで100〜200アンペアーの電力を与え30〜50℃となると盛んに炭素化繊維含水液は加熱されて蒸気を発生して細孔(6)(7)(6’)(7’)(6”)(7”)から水蒸気を噴出せしめ、その上面の積雪の接触面を融解して水となり流下して道路面に沿って高位から低位に流れ出る。
またポリプロピレンフィルム袋(1)(1’)(1”)を台車(1a)(1’a)(1”a)に積載して移動式とすると、その各車の下を流れる事になる。
しかるに、融雪を速やかに行うには、細管(9)(9’)(9”)のジョーゴ(9a)(9’a)(9”a)から熱水か水を送り込み、炭素化繊維に十分な水液を与えると水蒸気を更に多量に発散してポリプロピレンフィルム袋(1)(1’)(1”)上面の穿孔(6)(7)(6’)(7’)(6”)(7”)から水蒸気を押し出して上面の積雪を融解する。そして、ポリプロピレンフィルム袋又は同成型体の表面の加温度が30〜50℃に達すると、その接触面の雪も接触した面から融雪する。融雪した水液の一部は各穿孔を通じて袋内に入り、炭素化繊維を湿潤せしめる。またジョーゴ(9a)(9’a)(9”a)から時々熱湯を導入すれば連続的融雪を続け、積雪を全部融解する。
一般に積雪層は断熱性であり接触加熱だけでは積雪は消失しない。特に豪雪地方では水蒸気による拡散方式を採用する事によって初めて多量の融雪を試みる事が出来る。
また融雪が終われば台車(1a)(1’a)(1”a)を紐で牽引きすればどこでも移動が出来る。
FIG. 1 shows a side view of a snow layer on a road and a snow removal melting heater.
A powdered carbon fiber fiber powder (A) (A ') (A ") mixed with graphite powder in a molded resin casing or polypropylene film bag (1) (1') (1") and adjusted to a moisture content of 85% And seal both ends. Next, the electrodes (2), (3), (2), (3 ′), (2 ″), and (3 ″) previously inserted are sealed, and the conductors (4), (5), (4 ′), and (5 ′) are sealed. And (4 ″) and (5 ″) are connected to the electrodes (K), (K ′) and (K ″), and electric power is applied to the carbonized fiber powder (A) (A ′) (A ″) to generate heat. The internal moisture becomes water vapor, and water vapor is generated outside the bag through holes (6) (7) (6 ') (7') (6 ") (7") pre-drilled on the upper surface of the bag, and the upper snow layer ( 8) Diffuse to melt snow. Then, at one end of the molded resin casing or the polypropylene film bag (1) (1 ′) (1 ″), upper openings (9a) (9′a) (9 “A) is a jogo, that is, a divergent tube of a rotating shaft.
When power is applied to the electrodes (2) (3) (2 ') (3') (2 ") (3") by the power source (K) (K ') (K "), the carbonized fiber generates heat, When the electric power of 100 to 200 amperes is applied at 10 volts and the temperature reaches 30 to 50 ° C., the carbonized fiber hydrated liquid is actively heated to generate steam and generate pores (6) (7) (6 ′) (7 ′) ( Water vapor is ejected from 6 ″) (7 ″), and the contact surface of the snow cover on the upper surface is melted to flow down into water, and flows from high to low along the road surface.
Further, when the polypropylene film bags (1) (1 ') (1 ") are loaded on the carts (1a) (1'a) (1" a) and moved, they will flow under the respective cars.
However, in order to quickly melt snow, hot water or water is fed from the jogo (9a) (9'a) (9 "a) of the narrow tube (9) (9 ') (9"), and the carbonized fiber is sufficient. If a water solution is applied, a larger amount of water vapor is emitted to perforate the upper surface of the polypropylene film bag (1) (1 ') (1 ") (6) (7) (6') (7 ') (6") ( 7 ”) to extrude water vapor to melt the snow on the upper surface. And when the heating temperature of the surface of the polypropylene film bag or the molded body reaches 30 to 50 ° C., the snow on the contact surface also melts from the contact surface. A part of the melted snow liquid enters the bag through each perforation and wets the carbonized fiber.In addition, if hot water is occasionally introduced from the jogo (9a) (9'a) (9 "a), continuous snow melting is achieved. Continue to melt all the snow.
In general, the snow layer is heat-insulating, and snow is not lost only by contact heating. Especially in the heavy snow region, a large amount of snow melting can be attempted for the first time by adopting a diffusion method using water vapor.
When the snowmelt is over, the truck (1a) (1'a) (1 "a) can be moved anywhere by pulling it with a string.

図2は冬期ビニールハウスの温室の斜正面図を示し、ビニールハウス(1b)の下部の土壌(2b)にビニールハウス(1b)をコンクリート台(3b)上に架設する。
客土(4b)(4’b)(4”b)(4’”b)に敷き詰め凸出せしめ水はけをよくする。そして凹土面に含水炭素化繊維(A)(A’)(A”)の入ったポリプロピレン袋(5b)(5’b)(5”b)を一定間隔をおいて延長して設置し、電極と導線を取り付けて電力を印加すると客土(4b)(4’b)(4”b)(4’”b)に植え付けた苗(6b)(6’b)(6”b)(6’”b)は加温されて水蒸気を発生するので、ビニールハウス(1b)内の空気は湿潤し且つ室温が上昇するので、この調節用にファン(7b)を架設してハウス内の温度や湿度を電子回路で自動的に調整を行う。
FIG. 2 shows an oblique front view of a greenhouse in a winter greenhouse, in which a greenhouse (1b) is installed on a concrete platform (3b) in the soil (2b) below the greenhouse (1b).
Spread on the soil (4b) (4'b) (4 "b) (4 '" b) and improve drainage. Then, the polypropylene bags (5b) (5'b) (5 "b) containing the hydrous carbonized fibers (A) (A ') (A") on the concave soil surface are extended and installed at regular intervals, When power is applied with electrodes and conductors attached, seedlings (6b) (6'b) (6 "b) (6) planted in the soil (4b) (4'b) (4" b) (4 '"b) Since “” b) is heated to generate water vapor, the air in the greenhouse (1b) is moistened and the room temperature rises. For this adjustment, a fan (7b) is installed to adjust the temperature in the house. The humidity is automatically adjusted by an electronic circuit.

図3は多数電極加熱炭素化繊維発熱器の拡大側面図を示し、電極(2c)(3c)(4c)(5c)を一定間隔に架設し、炭素化繊維(6c)をポリビニール成型袋(7c)に充填して電極を接触せしめる。そして、成型袋(7c)の上面に水蒸気噴出孔(8c)(9c)(8’c)(9’c)(8”c)(9”c)を穿設し、室内(A’)を加温し、湿潤せしめる。またこの穿孔は差込み電極の位置に変更に利用し各電極の電流密度を調整せしめると部分的温度調整が可能となる。  FIG. 3 shows an enlarged side view of a multi-electrode heated carbonized fiber heater, in which the electrodes (2c), (3c), (4c), and (5c) are installed at regular intervals, and the carbonized fiber (6c) is placed in a polyvinyl molded bag ( 7c) is filled and the electrodes are brought into contact. Then, water vapor ejection holes (8c) (9c) (8'c) (9'c) (8 "c) (9" c) are formed in the upper surface of the molded bag (7c), and the room (A ') is opened. Warm and moisten. In addition, if this perforation is used to change the position of the insertion electrode and the current density of each electrode is adjusted, partial temperature adjustment becomes possible.

図4は保電用加熱体を具備する一般家屋(1d)の斜正面図を示し、屋根(1’d)上の瓦(2d)上面に炭素化繊維紙積合板穿孔袋(3d)を敷き詰め、電極(K)に導線(4d)(4’d)を接続して炭素化繊維積合紙(4d)は徐々に発熱板穿孔袋(3d)によって発熱し水蒸気を発生し、融雪して水液となって下部のトユ(5d)に流れ込み排出される。(6d)は沸化樹脂フィルムを示し、初期降雪時にはファン(7d)によって屋根上面を吹き付けると雪は積雪とならず屋根から落下する様にすれば電力消費が30%節減となる。  FIG. 4 shows a diagonal front view of a general house (1d) equipped with a heating element for storing electricity, and a carbonized fiber paper plywood perforated bag (3d) is spread on the top surface of the roof tile (2 ') on the roof (1'd). The lead wire (4d) (4'd) is connected to the electrode (K), and the carbonized fiber laminated paper (4d) gradually generates heat by the heat generating plate perforated bag (3d) to generate water vapor, melts snow, It becomes liquid and flows into the lower tou (5d) and is discharged. (6d) shows a fluorinated resin film. When the roof surface is blown by a fan (7d) during initial snowfall, if the snow falls from the roof instead of snow, the power consumption is reduced by 30%.

図5は乾式発熱性風呂の斜正面図を示し、モミガラ炭素化繊維発熱袋(1E)(1’E)を風呂の浴槽(2E)内に酵素入り鋸屑または竹皮細片(3E)と共に篏挿し、モミガラ炭素化繊維袋(1E)(1’E)には電極を架設し、電源(K”)に導線で接続し電力をモミガラ炭素化繊維発熱袋(1E)(1E’)(1”E)(1’”E)に印加して発熱せしめると水蒸気を発生しながら酵素入り鋸屑や竹皮細片(3E)を加熱湿潤する。
この鋸屑や竹皮細片が40℃に達するとモミガラ炭素化繊維袋(1”E)(1’”E)をそのままに電力を印加し、上面の発熱袋(1E)(1’E)を断電する時は、酵素の発酵熱によって40℃の温度を保持する。この鋸屑等の中に身体全体を沈めると40℃の保温を持続し果実皮屑やヒバ(ヒノキ)油香料を散布すると、香料により気分が壮快になる。しかし、ドライ風呂であるから次後温水シャワーで洗浄すれば入浴効果をいつまでも発揮する。この発酵熱を保持するには新しい鋸屑を入れ替えればいつまでも連続して使用される。この電圧が5ボルト200アンペアー以上の電力を印加する時は、絶縁袋を必要とせず発熱が行われるが、安全性のためにポリプロピレン袋に入れて発熱せしめた。
Fig. 5 shows a diagonal front view of a dry exothermic bath, in which a rice bran carbonized fiber heating bag (1E) (1'E) is placed in a bath tub (2E) together with sawdust or bamboo skin strip (3E) containing enzymes. Insert the electrode on the carbonized carbon fiber bag (1E) (1'E), connect it to the power supply (K ") with a lead wire, and supply power to the carbonized fiber heating bag (1E) (1E ') (1" E) When applied to (1 '"E) to generate heat, the sawdust containing an enzyme and bamboo strips (3E) are heated and wetted while generating water vapor.
When the sawdust and bamboo skin pieces reach 40 ° C, power is applied to the carbonized fiber bag (1 "E) (1 '" E) as it is, and the heating bag (1E) (1'E) on the upper surface is applied. When electricity is cut off, the temperature of 40 ° C. is maintained by the fermentation heat of the enzyme. When the whole body is submerged in the sawdust, etc., the heat is maintained at 40 ° C., and when the fruit peel scraps and cypress oil fragrance are sprayed, the fragrance will make the mood more refreshing. However, since it is a dry bath, if you wash it with a warm water shower afterwards, you can enjoy the bathing effect forever. In order to keep this heat of fermentation, new sawdust can be replaced and used continuously. When a voltage of 5 volts and 200 amperes or more is applied, heat is generated without the need for an insulating bag, but for safety, it was put in a polypropylene bag to generate heat.

このモミガラ炭素化繊維の製造は概述の如くで、脱農薬を電子レンジで加熱して気散せしめたものを20気圧165℃の温度で加熱したものを瀘別し、瀘液は濃縮して制癌原料とし、瀘別した固形物の炭素化繊維を発熱体としてまた炭素化繊維をアスペルギリウス菌と栄養剤と尿素と燐酸、塩化カルシウム、マグネシウム、糖分とを加えて70℃で発酵せしめた発酵炭素化繊維は炭素化率を更に高め有機肥料として併用され、土壌と混合して客土としてビニールハウス栽培に併用する時は、発酵時間が90日以上かかっていたものが30日くらいに短縮出来る利点があり、モミガラを土壌と混合した客土の様にモミガラまでもが撥水性となり肥効性を発揮しない欠点を改善する。
この炭素化繊維を含水量85%の状態で測定する電気抵抗値は160Ω/cmであり、黒鉛やオイルカーボン炭素化繊維を入れると0.1Ω/cmまで低下するが、融雪や風呂やビニールハウス栽培には水蒸気を発生するものがよりベターである。
The production of this carbonized carbon fiber is as outlined. The heat-treated desiccated pesticide was heated in a microwave oven at 20 atmospheres and 165 ° C, and the filtrate was concentrated and controlled. As a raw material for cancer, the solidified carbonized fiber was used as a heating element, and the carbonized fiber was fermented at 70 ° C. with Aspergillus bacteria, nutrients, urea, phosphoric acid, calcium chloride, magnesium, and sugar. Fermented carbonized fiber is used as an organic fertilizer with a higher carbonization rate. When it is mixed with soil and used as greenhouse for greenhouse cultivation, the fermentation time of 90 days or more is reduced to about 30 days. There is an advantage that can be done, and even the paddy like the soil where the rice bran was mixed with the soil is water-repellent and improves the defect that it does not exhibit fertilizer.
The electric resistance value of this carbonized fiber measured at a moisture content of 85% is 160 Ω / cm, and when graphite or oil carbon carbonized fiber is added, it decreases to 0.1 Ω / cm. It is better for cultivation to generate water vapor.

このモミガラ炭素化繊維を有機肥料とする場合の配合例は次の如くである。
例1 有機肥料
モミガラ炭素化繊維 100部
尿素 5部
燐酸カリ 0.5部
酵素 1部
硅皮酸コラーゲン縮合粉 0.5部
2億株/gアスペルギリウス菌石粉 10部
例1の有機肥料はモミガラ炭素化繊維を地球釜に入れて先ず20気圧165℃の高圧水蒸気で約1時間加熱して冷却し水槽に放出する。次にこれを瀘別機で瀘別し、瀘液は濃縮して制癌剤粗原料として回収し、米糠や乾燥オカラに吸収せしめてこれを乾燥して電子レンヂで2分間加熱して殺菌して包装する。固形物の瀘別物は炭素化繊維として電気抵抗発熱体や土壌改良材客土として利用し、更に芝の植え付け塗料や稲の種子を紙に凹凸状に成型した突起面に接着剤で塗着して乾燥し、これに他の薄葉紙を積合して長尺に巻取り、これを水田に広げて敷き詰め水に溶出せしめて種子米を自動的に落下植苗する。また電気抵抗発熱体紙や繊維マット盤を作り、ポリプロピレン成型袋に充填して電極を架設してこれに電力を印加して発熱袋とする。またこれを温室、風呂、家屋内の暖房や屋根や道路の解雪用加熱体に使用する。
例2 客土
モミガラ炭素化繊維 30部
砿滓粉又は殺菌土粉 60部
アスペルギリウス菌石粉 10部
例2の客土はマルチング法で田畑の表面に散布し土壌と混合する。
例3 電気抵抗発熱体
モミガラ炭素化繊維 100部
オイルカーボン粉 50部
パルプ 10部
例3は電気抵抗発熱体の配合例である。
例4 芝生噴霧塗料
炭素化繊維 100部
芝種子 5部
尿素又は硫安 3部
燐酸カリ 0.5部
炭酸石灰 10部
顔料 5部
ポパール樹脂又は桂皮酸コラーゲン縮合粉 5.5部
水 3000部
例4は芝生用塗料の配合例であるが、これは粉末炭素化繊維粉混合物を水に分散撹拌しながら吹き付けを行う。
例5 連作障害土壌改良材
炭素化繊維 100部
ロックウール繊維アスペルギリウス菌
(2億株/g当り)石粉 10部
例5は土壌改良材で、特に連作障害の高原野菜に利用する。
例6 積合繊維紙
電気抵抗発熱体モミガラ炭素化繊維 100部
黒鉛粉又はオイルカーボン粉 30部
導電性樹脂 10部
パルプ 10部
例6は電気発熱体(屋根用繊維盤)である。一般抄紙機で抄造して繊維紙に加工して積合して作る。
例7 加熱体や吸着材
含水80%の炭素化繊維 100部
和紙(コウゾ三叉繊維パルプ) 10部
例7は風呂の発熱体や水素ガスの吸着材として利用する。
この水素ガス吸着材は自動車の水素ガス燃料の吸着材としてガス吸着し、これを加温する事によって水素ガス吸着物を放出せしめるに利用する。この加熱体は低電圧5〜10ボルト,電流値100〜200アンペアーを印加すると発熱し、通電した状態でも漏電した状態でも安全であり、終始通電した上面に発酵鋸屑を敷き詰めてその上面に身体を埋め込む様にすれば砂風呂の様に年中保温性の乾式風呂が形成される。
また発酵鋸屑にニームチップの葉粉を入れるとアトピー性皮膚炎に効果があるが、ノンクロレラ、カテキンを入れるとより効果的である。
The compounding example in the case of using this rice bran carbonized fiber as an organic fertilizer is as follows.
Example 1 Organic fertilizer
100 parts of carbonized fiber
Urea 5 parts
Potassium phosphate 0.5 parts
Enzyme 1 part
0.5 parts of cinnamate collagen condensation powder
200 million strains / g Aspergillus fungus stone powder 10 parts The organic fertilizer of Example 1 is first put in the earth kettle, first heated with high-pressure steam at 165 ° C. at 20 atm for about 1 hour, cooled and released to the water tank. Next, this is separated by a separating machine, and the liquid concentrate is concentrated and recovered as a raw material for the anticancer drug, absorbed in rice bran and dried okara, dried, heated in an electronic range for 2 minutes, sterilized and packaged. To do. The solid material is used as carbonized fiber as an electric resistance heating element and soil improvement material, and is further applied with an adhesive to the projection surface of turf planting paint and rice seeds formed into irregularities on paper. It is then dried, stacked with other thin paper, rolled up in a long length, spread on paddy fields, leached into paddy water, and seed rice is automatically dropped and planted. Also, an electric resistance heating element paper or fiber mat board is made, filled in a polypropylene molded bag, an electrode is installed, and electric power is applied to this to form a heating bag. It is also used for heating elements for greenhouses, baths, indoor heating, and roofs and roads.
Example 2
30 parts of carbonized fiber
60 parts of rice cake or sterilized soil powder
Aspergillus fungus stone powder 10 parts of the soil in Example 2 is spread on the surface of the field by the mulching method and mixed with the soil.
Example 3 Electric resistance heating element
100 parts of carbonized fiber
50 parts of oil carbon powder
Pulp 10 parts Example 3 is a blending example of an electric resistance heating element.
Example 4 Lawn spray paint
100 parts of carbonized fiber
Lawn seed 5 parts
Urea or ammonium sulfate 3 parts
Potassium phosphate 0.5 parts
10 parts of lime carbonate
5 parts of pigment
5.5 parts of popal resin or collagen cinnamate condensed powder
3000 parts of water Example 4 is an example of blending a lawn paint, which is sprayed while dispersing and stirring a powdered carbonized fiber powder mixture in water.
Example 5 Continuous crop failure soil improvement material
100 parts of carbonized fiber
Rock wool fiber Aspergillus
(Per 200 million shares / g) Stone powder 10 parts Example 5 is a soil amendment, especially for highland vegetables with continuous cropping problems.
Example 6 Stacked fiber paper
Electric resistance heating element Momiga carbonized fiber 100 parts
Graphite powder or oil carbon powder 30 parts
10 parts of conductive resin
Pulp 10 parts example 6 is an electrical heating element (fibreboard for roofing). Paper is made with a general paper machine, processed into fiber paper, and stacked.
Example 7 Heating body and adsorbent
100 parts carbonized fiber containing 80% water
Japanese paper (Kozo trigeminal fiber pulp) 10 parts Example 7 is used as a heating element of a bath or an adsorbent of hydrogen gas.
This hydrogen gas adsorbent is used as an adsorbent for hydrogen gas fuel in automobiles, and is used to release the hydrogen gas adsorbate by heating it. This heating body generates heat when a low voltage of 5 to 10 volts and a current value of 100 to 200 amperes are applied, and it is safe in both an energized state and a leaked state. If it is embedded, a dry bath that is warm throughout the year is formed like a sand bath.
Adding neem chip leaf powder to fermented sawdust is effective against atopic dermatitis, but adding nonchlorella and catechin is more effective.

図6は炭素化繊維の稲植付け種子付着凹凸加工紙の工程図を示し、一般クラフト紙(S)の巻紙を(1F)のロールで移送せしめ、挾着ロール(2F)(2’F)(3F)(3’F)で挾着してギロチンカッター(4F)(4’F)切断したものをプレス(5F)(5’F)により加熱圧縮して凹凸紙を成型し、巻取機で一定の長さに巻取り、巻取紙(6F)をコンベアー(7F)上にロール(8F)で抑えて回転し、樹脂塗布ロール(9F)(9’F)で樹脂を巻紙の凸面の先端(10F)のみに樹脂又は糊で塗着し、これを誘導してコンベアー(7F)上の米種子(Z)をホッパー(11F)から下部に流下せしめたものに、凸面の先端の糊に種子(Z)を圧着せしめた紙をコンベアー(7F)により搬送して乾燥器(12F)に誘導して乾燥室(12’F)で乾燥して巻取り、穿孔紙と積合して巻取り組合せ紙とする。  FIG. 6 shows a process diagram of the carbonized fiber-planted seed adhesion unevenness processed paper, in which the wrapping paper of general kraft paper (S) is transported by the roll (1F), and the sticking roll (2F) (2′F) ( 3F) (3'F) and guillotine cutter (4F) (4'F) cut and heat-compressed by press (5F) (5'F) to form uneven paper, with a winder Wind the paper to a certain length, rotate the web (6F) on the conveyor (7F) with the roll (8F), and rotate the resin with the resin coating roll (9F) (9'F). ) Only with resin or glue, and the rice seed (Z) on the conveyor (7F) is allowed to flow down from the hopper (11F) to the lower part, and the seed (Z ) Is crimped on the conveyor (7F) and guided to the dryer (12F). Winding and dried in a drying chamber (12'F), the perforated sheet and the product combined and winding combination paper.

図7は図6の積合紙の斜正面図を示し、種子付凹凸紙(P)と穿孔紙(P’)を積合する。凹凸紙(P)の凸面(10F)紙の先端に種子(Z)を付着させ、その下面に穿孔紙を積合する。  FIG. 7 shows an oblique front view of the stacking paper of FIG. 6, in which the uneven paper with seeds (P) and the perforated paper (P ′) are stacked. The seed (Z) is attached to the tip of the convex surface (10F) paper of the concavo-convex paper (P), and the perforated paper is stacked on the lower surface thereof.

は水田の拡大部分的側面図を示し、積合紙(1G)の付着種子(Z)を下部方向に向けて位置せしめ、穿孔紙(2G)の穿孔(2’G)を下部面に向けて敷き詰める。しかる時は稲の種子は水田液(3G)に浸積して沈下し、泥土(4G)上に沈着するとその種子は泥土(4G)中に沈下して発芽する。また種子付着積合紙が崩壊するまでには一定の時間を要するので雑草が混入する余地がなく稲作の手間は省略され、モミガラ炭素化繊維の凹凸紙は肥効性があり肥料の散布の必要もなく、水田液を吸着して浄化し太陽光の吸収による水温の上昇を得る。
またこの積合紙(1G)は予めニーム樹皮、ニーム葉粉、ニームアルコール抽出液を桂皮酸ポパールやワニリン、コラーゲンの忌避剤を塗着しているので、害虫を忌避し抗菌性により根ぐされ病を防ぐ効果を発揮し、有害農薬の使用を行わないですむ様にする。
この炭素化繊維にアスペルギリウス菌を混合し、炭酸カルシウム、多糖類と炭素化繊維ガラスウール、尿素を入れたものを水田に浸積すると連作障害を防止し、1年間の連作に耐える土壌が出来る。
Shows an enlarged partial side view of the paddy field, with the seeds (Z) of the stacking paper (1G) facing down and the perforations (2'G) of the perforated paper (2G) facing down Lay down. At this time, the seeds of rice are immersed in paddy liquid (3G) and submerged, and when they are deposited on mud (4G), the seeds settle in mud (4G) and germinate. In addition, it takes a certain amount of time for the seed adhesion paper to collapse, so there is no room for weeds and rice cultivation is omitted, and the uneven paper of rice bran carbonized fiber is fertile and requires fertilizer application. The paddy liquor is adsorbed and purified to increase the water temperature by absorbing sunlight.
This laminated paper (1G) is pre-coated with neem bark, neem leaf powder, neem alcohol extract, and poplar, crocodile, and collagen repellents. To prevent the use of harmful pesticides.
Mixing this carbonized fiber with Aspergillus bacteria, and immersing calcium carbonate, polysaccharides, carbonized fiber glass wool, and urea in paddy fields will prevent continuous cropping failure, and the soil will withstand one year of continuous cropping. I can do it.

図9は電磁波吸収蓄積筐の正面図を示し,炭素化繊維紙にチタン酸アルコールキレート液を含浸せしめて乾燥したものを碁盤状に紙枠を入れて格子を作り、これを多数個積合した函内に電磁波(M)を照射すると、電磁波を吸収し蓄積する。これは炭素化繊維表面の酸化硅素SicTioによって電磁波エネルギーを蓄積し一定後に放出するが、電磁波が吸収されると共鳴し相互に周波数を変化し消失するので断続的電磁波を送ると負荷価値があがり利用度が増大する。
この炭素化繊維は含水80%の炭素化繊維を通電して発熱せしめて脱水したものに、チタン酸アルコールキレート液を吹き付けて乾燥したものを300℃で焼成したものを使用すると良い電磁波吸収体が得られる。また炭素化繊維に金属アルミニウム粉を混合して抄紙したものは、電磁波の吸収がより高くなり変換電気エネルギーを蓄積するので使用目的によって変更して選別利用する。この炭素化繊維紙は厚み0.1〜0.8ミリのものが一般的に利用される。これは携帯電話の電磁波吸収カバーに利用され、チタン酸は光合成作用がSioと共に保有し極めて有効に作用する。このチタン酸の代用として同じ目的にジルコニウム酸や錫酸も使用される。
図10は電磁波吸収蓄積筐のA−B切断縦断面図を示す。
図9と図10に於いて、図9と図10の(4m)は炭素化繊維紙でその表面に穿孔(4’am)を穿設し、その下部に碁盤の紙枠(2m)があり、その下に同紙面(3m)を敷き詰め紙枠(2’m)が下部にあり、これが複数の紙枠と平面紙でサンドイッチされた構造となる。その背面に(4’m)の穿孔紙面が接合されたもので、電磁波(M)がこの紙枠(2m)(2’m)によって直角方向に来る時に電磁波(M)の吸収が行われる。
そして、紙枠(2’m)(2”m)と平面紙(3m)(3’m)(3”m)が積合して紙枠によって格子状の空間を作る。またこの電磁波吸収筐(1m)は5〜20個が縦横各1cmの間隔で紙枠が作られたもので、電磁波は表面(M)として背面(M’)に貫通して吸収される。
FIG. 9 shows a front view of an electromagnetic wave absorption storage housing. Carbon paper is impregnated with a titanate alcohol chelate solution and dried, and a lattice is formed by putting a paper frame in a grid pattern, and a large number of them are stacked. When the electromagnetic wave (M) is irradiated into the box, the electromagnetic wave is absorbed and accumulated. It accumulates electromagnetic wave energy by silicon oxide Sic 2 Tio 4 on the surface of carbonized fiber and releases it after a certain time. However, when electromagnetic wave is absorbed, it resonates and changes its frequency and disappears. Increases usage.
As this carbonized fiber, it is preferable to use a carbonized fiber having a water content of 80% which is dehydrated by energizing and dehydrated, and a product obtained by spraying a titanic acid alcohol chelate solution and baking it at 300 ° C. can get. Also, paper made by mixing metallic aluminum powder with carbonized fiber has a higher absorption of electromagnetic waves and accumulates converted electric energy. This carbonized fiber paper generally has a thickness of 0.1 to 0.8 mm. This is used for an electromagnetic wave absorption cover of a cellular phone, and titanic acid possesses a photosynthetic action together with Sio 2 and works extremely effectively. Zirconic acid and stannic acid are also used for the same purpose as a substitute for this titanic acid.
FIG. 10 is a vertical cross-sectional view of the electromagnetic wave absorption storage housing taken along the line AB.
In FIGS. 9 and 10, (4m) in FIGS. 9 and 10 is carbonized fiber paper and has a perforation (4'am) formed on the surface thereof, and there is a paper frame (2m) of a grid on the bottom. Underneath, the paper surface (3 m) is laid and a paper frame (2′m) is placed at the lower part, which has a structure sandwiched between a plurality of paper frames and flat paper. The (4'm) perforated paper surface is joined to the back surface, and the electromagnetic wave (M) is absorbed when the electromagnetic wave (M) comes in a perpendicular direction by the paper frame (2m) (2'm).
Then, the paper frame (2′m) (2 ″ m) and the flat paper (3m) (3′m) (3 ″ m) are stacked to form a lattice-like space by the paper frame. In addition, 5 to 20 electromagnetic wave absorbing casings (1 m) are formed with a paper frame at intervals of 1 cm in length and width, and electromagnetic waves penetrate through the back surface (M ′) as the surface (M) and are absorbed.

図11は心電器を架設した患者の胸部に張付ける電磁波吸収盤(1P)の正面図を示し、同炭素化繊維フィルム紙(2P)が重畳されていて、紐(3P)(3’P)を左右の端に突起して接合され、ベルクロ接合剤によって圧着し衣類に固定すると携帯電話の電磁波を吸収せしめる。勿論携帯電話の外装袋として利用される事は言うまでもない。  FIG. 11 is a front view of an electromagnetic wave absorber (1P) that is attached to the chest of a patient on which an electrocardiograph is installed. The carbonized fiber film paper (2P) is superimposed on the cord (3P) (3′P). Are protruded from the left and right edges and bonded to each other with a Velcro bonding agent and fixed to clothing to absorb electromagnetic waves from the mobile phone. Of course, it is needless to say that it is used as an exterior bag of a mobile phone.

図12は建材の正面図を示し、モミガラ、カラ松を高圧水蒸気20気圧165℃の温度で加熱し、瀘別した炭素化繊維板である。この炭素化繊維板(1s)はリグニン粉10部に炭素化繊維を混合して200〜350℃で加熱したものを300〜1000kg/cm圧のプレスで圧縮すると、リグニンが融着して合板が出来る。
カラ松の炭素化繊維は繊維が長いので屈曲強度は高く、圧縮強度は250kg/cmである。建材のほか自動車、列車、船舶に成型して使用される。
(2s)(3s)は表面スチールペーパーである。
FIG. 12 is a front view of a building material, which is a carbonized fiber board obtained by heating rice bran and pine at a high pressure water vapor of 20 atm. This carbonized fiber board (1 s) is a mixture of carbonized fibers mixed with 10 parts of lignin powder and heated at 200 to 350 ° C. When compressed with a 300 to 1000 kg / cm pressure press, the lignin is fused to form a plywood. I can do it.
Since the carbonized fiber of Karamatsu has a long fiber, the bending strength is high and the compressive strength is 250 kg / cm 2 . In addition to building materials, it is molded into automobiles, trains and ships.
(2s) (3s) is surface steel paper.

またこのモミガラの代わりにカラ松のチップや他の木材チップも高圧水蒸気で20気圧、165〜200℃で加熱する時も同様の炭素化繊維と制癌性のリグニン、ポリフェノール、カテキン、多糖類が得られる事は言うまでない。
また竹皮を同様に細長状にカットしてこれを高圧水蒸気20気圧、200℃に加熱する時にも炭素化繊維と制癌性ポリフェノール液カテキン液と多糖類と共に得られ、制癌性粗材として回収し利用されるが、竹皮の炭素化繊維は藁の代用として馬床の藁敷き物の代用として使用される。また笹葉を20気圧165℃で加熱すると炭素化繊維と濃縮液の抽出液は制癌剤として利用されるので、今後高圧水蒸気処理法は広い利用価値がある。
Also, instead of this rice bran, the chip of pine and other wood chips are heated with high-pressure steam at 20 atm and 165-200 ° C., and the same carbonized fiber and anti-cancer lignin, polyphenol, catechin and polysaccharide are also present. It goes without saying that you can get it.
Similarly, when bamboo skin is cut into an elongated shape and heated to 20 atm with high-pressure steam and 200 ° C, it is obtained together with carbonized fiber, anti-cancer polyphenol solution catechin solution and polysaccharide, and as anti-cancer crude material. Although it is recovered and used, the carbonized fiber of bamboo bark is used as a substitute for a saddlecloth on a horse bed as a substitute for a saddle. In addition, when the bamboo leaves are heated at 20 atm 165 ° C., the carbonized fiber and concentrated liquid extract are used as anticancer agents, so that the high-pressure steam treatment method has wide utility value in the future.

モミガラを土壌改良材や有機肥料として利用するには、撥水性の高い硅酸植物であるから3カ月間土壌に混合して発酵しても分解性は少なく脱窒素現象をおこしやすいから、これを一旦脱農薬したものを高圧水蒸気加熱で20気圧165℃の温度で加熱処理すると撥水性はなく、発酵しやすい炭素化繊維ができ、その炭素化繊維には硅酸分子膜状で積合されているので安定した電気抵抗体を形成し繊維状の発熱体を作る。
含水液はその発熱時には断熱性と水蒸気発生に伴うので除雪に適し、また保温材に利用される。またこのモミガラの炭素化繊維の電気抵抗発熱体は風呂の保温用として使用され、10〜20キロワットの電力を電極間電圧5〜10ボルト、電流100〜200アンペアーにより印加し発熱し、水蒸気を同時に発生せしめるから鋸屑や米糠、モミガラ、ニーム葉、ニーム樹皮、ニームチップに酵素とアスペルギリウス菌を加えて発酵し、その発酵熱を予熱とし炭素化繊維電気発熱袋を使用すると、発酵菌による発酵熱のコントロールが短時間で出来るので四季の温度変化に対して便利であり、低電圧を使用するので漏電しても危険性はなく、電気刺激を皮膚に与えて皮膚細胞の賦活に寄与しアトピー性皮膚炎に効果がある。またこの炭素化繊維パルプ、黒鉛、オイルカーボンを混合して電気抵抗体となり、またこれを抄造して製紙すると稲の種子用の紙として田植え時に水田に敷き詰めるだけで田植えの必要性もなく、自動的に移植ができ作業コストが低廉化する。
またモミガラ以外に竹皮を高圧水蒸気処理をすると制癌剤粗材として利用され、炭素化繊維は競争馬の厩舎の藁草の代用品として竹皮の細片が代用される。また有機肥料としても有用である。
In order to use rice straw as a soil conditioner or organic fertilizer, it is a highly water-repellent oxalic acid plant, so even if it is mixed with soil for 3 months and fermented, it is less degradable and easily denitrifies. Once de-pesticidal, heat treatment is performed with high-pressure steam heating at a temperature of 20 atmospheres and 165 ° C., and there is no water repellency, and a fermentable carbonized fiber is formed. As a result, a stable electric resistor is formed to produce a fibrous heating element.
The water-containing liquid is suitable for snow removal because it generates heat and generates water vapor when it generates heat, and is also used as a heat insulating material. The electric resistance heating element of the carbonized fiber of the rice bran is used for heat insulation of the bath, and heat is generated by applying 10 to 20 kilowatts of electric power with an interelectrode voltage of 5 to 10 volts and an electric current of 100 to 200 amperes, and water vapor is simultaneously generated. If it is fermented by adding enzymes and Aspergillus bacteria to sawdust, rice bran, rice bran, neem leaves, neem bark, and neem chips, and preheating the fermentation heat and using a carbonized fiber electric heating bag, fermentation by fermentation bacteria Since heat can be controlled in a short time, it is convenient for temperature changes in the four seasons, and since a low voltage is used, there is no danger even if there is a leak, giving electrical stimulation to the skin and contributing to the activation of skin cells. Effective for dermatitis. In addition, this carbonized fiber pulp, graphite, and oil carbon are mixed to form an electrical resistor, and when this paper is made and made into paper, it is automatically spread without padding at the time of rice planting as rice seed paper. Can be transplanted and the work cost is reduced.
In addition to rice bran, bamboo bark treated with high-pressure steam is used as a raw material for anticancer drugs, and carbonized fiber is replaced with a piece of bamboo bark as a substitute for competitive horse stables. It is also useful as an organic fertilizer.

道路の積雪層と除雪融解加熱器の側面図  Side view of road snow layer and snow removal melting heater ビニールハウスの斜正面図  Oblique front view of greenhouse 多数電極加熱炭素化繊維発熱器の拡大側面図  Expanded side view of multi-electrode heated carbonized fiber heater 保電用加熱体を具備する家屋の斜正面図  Diagonal front view of a house with a heating element for electricity storage 乾式発熱性風呂の斜正面図  Oblique front view of dry exothermic bath 炭素化繊維凹凸加工紙の工程図  Process chart of carbonized fiber uneven processed paper 炭素化繊維凹凸加工紙の積合紙の斜正面図  Oblique front view of carbonized fiber uneven processed paper 水田の拡大部分的側面図  Expanded partial side view of paddy field 電磁波吸収蓄積筐の正面図  Front view of electromagnetic wave storage housing 電磁波吸収蓄積筐のA−B切断縦断面図  AB cut vertical cross-sectional view of electromagnetic wave storage housing 電磁波吸収盤の正面図  Front view of electromagnetic wave absorber 建材の正面図  Front view of building materials

Claims (1)

モミガラや竹皮やカラ松の鋸屑チップ粉を地球釜で20気圧ないしはそれ以上にして、温度165〜200℃に加熱処理したものを瀘別して炭素化繊維と制癌濃縮液とを回収して、この炭素化繊維の電導性を利用して融雪器の発熱体や風呂場や室内の暖房用に利用し、また有機肥料や土壌の客土に利用する。また電磁波吸収体として携帯電話や電気器材に利用する事を特徴としたモミガラ、竹皮やカラ松などの高圧水蒸気加熱による利用法。  Recover the carbonized fiber and the anticancer concentrate by separating the heat-treated rice cake powder of rice bran, bamboo bark, and pine pine sawdust to 20 atm. Utilizing the conductivity of this carbonized fiber, it is used for heating elements for snowmelters, bathrooms and indoor heating, and for organic fertilizer and soil soil. In addition, it is used as an electromagnetic wave absorber for cellular phones and electrical equipment.
JP2004048737A 2004-01-26 2004-01-26 Application of rice hull carbonized fiber Pending JP2005209599A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010113255A1 (en) * 2009-03-31 2010-10-07 株式会社コア・タムタム Method of producing fermented neem
CN107500903A (en) * 2017-09-22 2017-12-22 芜湖新达园林绿化集团有限公司 A kind of indoor pot fairy bamboo dedicated fertilizer

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010113255A1 (en) * 2009-03-31 2010-10-07 株式会社コア・タムタム Method of producing fermented neem
CN107500903A (en) * 2017-09-22 2017-12-22 芜湖新达园林绿化集团有限公司 A kind of indoor pot fairy bamboo dedicated fertilizer

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