JP2005185429A - Nonwoven fabric for cleaning - Google Patents

Nonwoven fabric for cleaning Download PDF

Info

Publication number
JP2005185429A
JP2005185429A JP2003429326A JP2003429326A JP2005185429A JP 2005185429 A JP2005185429 A JP 2005185429A JP 2003429326 A JP2003429326 A JP 2003429326A JP 2003429326 A JP2003429326 A JP 2003429326A JP 2005185429 A JP2005185429 A JP 2005185429A
Authority
JP
Japan
Prior art keywords
cleaning
nonwoven fabric
fiber
fibers
dtex
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2003429326A
Other languages
Japanese (ja)
Inventor
Minoru Wada
稔 和田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kao Corp
Original Assignee
Kao Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kao Corp filed Critical Kao Corp
Priority to JP2003429326A priority Critical patent/JP2005185429A/en
Publication of JP2005185429A publication Critical patent/JP2005185429A/en
Pending legal-status Critical Current

Links

Landscapes

  • Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
  • Nonwoven Fabrics (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide nonwoven fabric for cleaning capable of removing fur and black stains around water in a kitchen, or the like, and burnt stains stuck to a pot or a frying pan while hardly scratching a cleaning surface. <P>SOLUTION: This nonwoven fabric for cleaning is obtained by dispersing synthetic fibers (A) of fineness 20 to 100 dtex and synthetic fibers (B) of fineness 1 to 11 dtex in air and adhering the intersections of the deposited fibers. It is preferable that the adhesion is thermal adhesion by hot melting fibers or hot melting powder. It is further preferable that the synthetic fibers (B) are contained by 10 to 50 pts. wt. to 100 pts. wt. of the synthetic fibers (A). <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、清掃用不織布に関し、特にキッチン周り、浴室や洗面台等の水周りの汚れの清掃に好適に用いられる清掃用不織布に関する。   The present invention relates to a cleaning nonwoven fabric, and more particularly to a cleaning nonwoven fabric suitably used for cleaning dirt around water such as around kitchens, bathrooms and washstands.

従来、キッチン等の水周りの清掃シートには、水垢や黒ずみなどのこびり付いた汚れを落とす為に、研磨粒子入りのスポンジや繊維状の金属たわしなどが知られているが、これらは上記こびりつき汚れを掻き落とす性能があるもののステンレスのシンクや人工大理石などの表面を傷つけてしまい、望ましいものではなかった。   Conventionally, sponges with abrasive particles and fibrous metal scrubbing have been known for cleaning sheets around water in kitchens, etc., to remove dirt and dark dirt. Although it has the ability to scrape off, the surface of stainless steel sinks and artificial marble is damaged, which is not desirable.

一方、特許文献1には、太くて(10〜150dtex)短い繊維(2〜15mm)の先端部を表層に多数存在させたエアレイド不織布中にセルロース系繊維を混合して、洗浄液を保持した清掃シートが記載されている。かかるシートは、表面の太い繊維先端の掻きとりと洗浄液の相互作用により、研磨剤を使わずとも清掃対称面を傷つけずに汚れをとる清掃シートが開示されている。しかし、研磨剤を用いたシートよりは清掃面を傷つけないものの、鍋等に付いた焦付き汚れ落としは満足行くものではなかった。   On the other hand, Patent Document 1 discloses a cleaning sheet in which a cellulosic fiber is mixed in an airlaid nonwoven fabric having a large number (10 to 150 dtex) of short fibers (2 to 15 mm) on the surface layer, and a washing liquid is retained. Is described. Such a sheet is disclosed as a cleaning sheet that removes dirt without damaging the cleaning symmetry plane without using an abrasive by the interaction between the cleaning of the thick fiber tip and the cleaning liquid. However, although the cleaning surface was not damaged more than the sheet using the abrasive, the scorching dirt removal on the pan etc. was not satisfactory.

特開2000−61885号公報JP 2000-61885 A

従って、本発明の解決課題は、キッチン等の水周りの水垢や黒ずみ汚れ、鍋やフライパンについた焦付き汚れを、清掃面を傷つけにくく汚れを落とすことのできる清掃用不織布を提供することにある。   Therefore, the problem to be solved by the present invention is to provide a nonwoven fabric for cleaning that can remove stains that are hard to damage the cleaning surface due to dirt and dark stains around the water in kitchens, etc., and burnt stains on pans and pans. .

本発明は、繊度20〜100dtexの太い合成繊維(A)と繊度1〜11dtexの細い合成繊維(B)を空気中に分散して堆積させた繊維の交点を接着させて得られた清掃用不織布を提供することにより、前記課題を解決したものである。   The present invention relates to a nonwoven fabric for cleaning obtained by adhering intersections of fibers obtained by dispersing and depositing a thick synthetic fiber (A) having a fineness of 20 to 100 dtex and a thin synthetic fiber (B) having a fineness of 1 to 11 dtex in the air. By providing the above, the above-mentioned problems are solved.

また本発明は、水又は水性洗浄液を清掃面に吹き付け、前記の清掃用不織布を用いて清掃を行う清掃方法を提供するものである。   The present invention also provides a cleaning method in which water or an aqueous cleaning liquid is sprayed onto a cleaning surface and cleaning is performed using the above-described nonwoven fabric for cleaning.

本発明の清掃用不織布は、水周りの水垢や黒ずみ等の汚れ、鍋やフライパンに付いた焦付き汚れを、清掃面を傷つけにくく落とすことができる。さらに、本発明の清掃用不織布は、液保持性が良く、洗浄液や水を不織布に含ませたり、清掃面をウエット状態で清掃することでいっそうの汚れ落ち作用が持続し、特に頑固な焦付き汚れ等を、清掃面を傷つけにくくし清掃性能を向上させることができる。また、市販されている研磨剤入りの清掃シートは、一回の使用でも浴槽やプラスチック製品を傷つけてしまい、清掃面の光沢が失われてしまうのに対し、本発明品は傷つけにくく汚れを簡単に落とす事ができる。   The non-woven fabric for cleaning of the present invention can remove dirt such as water stains and darkening around water, and scorched dirt attached to a pan or a frying pan, with less damage to the cleaning surface. Furthermore, the non-woven fabric for cleaning of the present invention has good liquid retention, so that the non-woven fabric can contain cleaning liquid or water, or the cleaning surface can be cleaned in a wet state to maintain a more clean-up action, and particularly stubborn scoring. It is possible to improve the cleaning performance by making dirt and the like difficult to damage the cleaning surface. In addition, a commercially available cleaning sheet containing abrasives will damage the bathtub and plastic products even after single use, and the gloss of the cleaning surface will be lost. Can be dropped.

以下本発明の清掃用不織布をその好ましい実施形態に基づき説明する。本発明の実施形態の清掃用不織布は、合成繊維(A)と合成繊維(B)とからなる構成繊維が空気中で分散されて基体上に堆積させて構成繊維同士の交点を接着させて形成された不織布からなる。構成繊維が空気中で分散されて堆積させると繊維がランダムで、嵩高く空隙が多い不織布が得られる。   Hereinafter, the nonwoven fabric for cleaning of the present invention will be described based on its preferred embodiments. The nonwoven fabric for cleaning according to the embodiment of the present invention is formed by dispersing constituent fibers composed of the synthetic fibers (A) and the synthetic fibers (B) in the air and depositing them on the substrate to bond the intersections of the constituent fibers. Made of nonwoven fabric. When the constituent fibers are dispersed and deposited in the air, a nonwoven fabric in which the fibers are random, bulky and have many voids is obtained.

構成繊維としては、繊度が1〜11dtexの合成繊維(A)と繊度20〜100dtexの合成繊維(B)とから構成される。   The constituent fiber is composed of a synthetic fiber (A) having a fineness of 1 to 11 dtex and a synthetic fiber (B) having a fineness of 20 to 100 dtex.

合成繊維(A)は、太い繊維の交点が、好ましくは熱により接着されているので、繊維の表面や先端部が清掃対象面に強く作用し、清掃面に存する汚れに対する掻き取り性能が得られる。20dtex未満であると、こびりついた汚れ(変性油、焦付き、水垢等)の掻きとり性が良好でなく、100dtex超であると、やはり掻きとり性能がおち、製造面では、均一な不織布が得られにくくなる。特に、合成繊維(A)の繊度は好ましくは20〜75dtex、更に好ましくは20〜50dtexであると、鍋等にこびりついた汚れの掻きとり性能が一層優れたものとなる。詳細には、合成繊維(A)の繊維長は1〜10mmが好ましい。特に、繊維長1〜10mmの短い繊維に繊維長20〜75mmの長い繊維を重量比で9:1〜7:3の割合で合成繊維(A)として使用すると、太くて短い繊維の先端部、太くて長い繊維の胴部とが清掃面の汚れに対して掻きとりと擦り作用が相俟って、汚れ取り性能が向上し、一層好ましい。さらに合成繊維(A)のロックウエル硬さは、清掃面の汚れを傷つける事なく掻きとる最適な硬さとするためにR40〜R150の樹脂を用いることが好ましい。前記硬さを有する樹脂として、ポリエチレン樹脂、ポリプロピレン樹脂、ポリエステル樹脂、アクリロニトリルブタジエンスチレン(ABS)樹脂、6ナイロン樹脂、ポリカーボネート樹脂、ポリ塩化ビニル樹脂、66ナイロン樹脂、アクリル樹脂等用いる事ができる。特にポリエステル樹脂が好ましい。   In the synthetic fiber (A), since the intersection of thick fibers is preferably bonded by heat, the surface and tip of the fiber strongly act on the surface to be cleaned, and the scraping performance against dirt existing on the cleaning surface can be obtained. . If it is less than 20 dtex, the scraping property of sticking dirt (modified oil, scorching, scale, etc.) is not good, and if it exceeds 100 dtex, the scraping performance is also reduced, and a uniform nonwoven fabric is obtained in terms of manufacturing. It becomes difficult to be. In particular, when the fineness of the synthetic fiber (A) is preferably 20 to 75 dtex, more preferably 20 to 50 dtex, the scraping performance of dirt stuck to a pan or the like is further improved. Specifically, the fiber length of the synthetic fiber (A) is preferably 1 to 10 mm. In particular, when a long fiber having a fiber length of 20 to 75 mm is used as a synthetic fiber (A) in a ratio of 9: 1 to 7: 3 by weight to a short fiber having a fiber length of 1 to 10 mm, the tip of a thick and short fiber, A thick and long fiber body is more preferable because of the combination of scraping and rubbing action against dirt on the cleaning surface, improving dirt removing performance. Furthermore, it is preferable to use a resin of R40 to R150 so that the Rockwell hardness of the synthetic fiber (A) is an optimum hardness that can be scraped without damaging the cleaning surface. As the resin having the hardness, polyethylene resin, polypropylene resin, polyester resin, acrylonitrile butadiene styrene (ABS) resin, 6 nylon resin, polycarbonate resin, polyvinyl chloride resin, 66 nylon resin, acrylic resin and the like can be used. A polyester resin is particularly preferable.

合成繊維(B)は、繊度が1〜11dtexであり、合成繊維(A)に対し5〜50重量部含有させることが好ましい。該適量含有させる事で、使用時に、水や洗浄液を清掃面に吹き付けて汚れを拭取ったり、不織布に含ませて使用する場合、水や洗浄液が前記不織布に良く保持され、合成繊維(A)による掻きとり性能と合成繊維(B)による洗浄液保持性能が相俟って、頑固な焦付き汚れ等を清掃面を傷つけないよう掻き落とす事ができると考えられる。特に合成繊維(B)の繊度は2〜8dtexが好ましい。繊維長は、1〜50mmが好ましい。繊度が1dtex未満では、汚れの掻きとり性が低下し、繊度が11dtexを超えると液保持性や泡立ち性が低下する。さらに、第3の構成繊維として、繊度12〜19dtexの繊維を混ぜる事もできる。   The synthetic fiber (B) has a fineness of 1 to 11 dtex, and is preferably contained in an amount of 5 to 50 parts by weight with respect to the synthetic fiber (A). By containing the appropriate amount, when using it by spraying water or a cleaning liquid onto the cleaning surface to wipe off dirt or using it in a nonwoven fabric, the water or the cleaning liquid is well retained in the nonwoven fabric, and the synthetic fiber (A) It is considered that the scraping performance by the combination with the cleaning liquid holding performance by the synthetic fiber (B) can scrape stubborn dirt and the like so as not to damage the cleaning surface. In particular, the fineness of the synthetic fiber (B) is preferably 2 to 8 dtex. The fiber length is preferably 1 to 50 mm. When the fineness is less than 1 dtex, the scraping property of dirt is lowered, and when the fineness is more than 11 dtex, the liquid holding property and foaming property are lowered. Furthermore, a fiber having a fineness of 12 to 19 dtex can be mixed as the third constituent fiber.

合成繊維(A)及び合成繊維(B)としては、例えばポリエチレンやポリプロピレン等のポリオレフィン樹脂、ポリエチレンテレフタレート等のポリエステル系樹脂、ポリアクリル酸やポリメタクリル酸等のアクリル系樹脂、ポリ塩化ビニル等のビニル系樹脂、ナイロンなどのポリアミド系樹脂などを原料とする繊維が用いられる。前記の各種原料のうち、2種の樹脂の組合わせからなる複合繊維(芯鞘型複合繊維やサイドハ゛イサイド型複合繊維)を用いる事もできる。特に合成繊維(A)として、清掃対象面(ステンレス、タイル、琺瑯、人工大理石等)への傷つきがなく、且つ汚れの掻きとり性に優れる観点からアクリル系繊維、ポリエステル系繊維、塩化ビニル系繊維、ポリアミド繊維及びポリオレフィン系繊維が好ましい。更に、繊維の脱落を防止する面からは、融点の異なる低融点樹脂と高融点樹脂とからなり且つ該低融点樹脂が繊維表面の少なくとも一部を形成している熱融着性複合繊維を用いるのが好適である。低融点樹脂/高融点樹脂の組合わせとしては、高密度ポリエチレン/ポリプロピレン、低密度ポリエチレン/ポリプロピレン、高密度ポリエチレン/ポリエチレンテレフタレート、ナイロン−6/ナイロン−66、低融点ポリエステル/ポリエチレンテレフタレート、ポリプロピレン/ポリエチレンテレフタレート等が使われる。   Synthetic fibers (A) and synthetic fibers (B) include, for example, polyolefin resins such as polyethylene and polypropylene, polyester resins such as polyethylene terephthalate, acrylic resins such as polyacrylic acid and polymethacrylic acid, and vinyls such as polyvinyl chloride. Fibers made from polyamide resins such as nylon resins and nylon are used. Of the various raw materials, a composite fiber (core-sheath composite fiber or side-by-side composite fiber) made of a combination of two kinds of resins can be used. In particular, synthetic fibers (A) are acrylic fibers, polyester fibers, and vinyl chloride fibers from the standpoint that there is no damage to the surface to be cleaned (stainless steel, tiles, wrinkles, artificial marble, etc.) and excellent scraping properties. Polyamide fibers and polyolefin fibers are preferred. Furthermore, in terms of preventing the fibers from falling off, a heat-fusible composite fiber made of a low-melting resin and a high-melting resin having different melting points, and the low-melting resin forming at least a part of the fiber surface is used. Is preferred. The combination of low melting point resin / high melting point resin includes high density polyethylene / polypropylene, low density polyethylene / polypropylene, high density polyethylene / polyethylene terephthalate, nylon-6 / nylon-66, low melting point polyester / polyethylene terephthalate, polypropylene / polyethylene. Terephthalate is used.

前記熱融着性複合繊維の形態は、並列型、鞘芯型、偏心鞘芯型、三層以上の多層型、中空並列型、中鞘芯型、異形鞘芯型、海島型等で且つ低融点樹脂が繊維表面の少なくとも一部を形成した構造であれば良い。前記熱融着性複合繊維のうち好ましいものは、高密度ポリエチレン、線状低密度ポリエチレン、エチレン・ブチレンー1結晶性共重合体、ポリエチレンテレフタレートとポリエチレンイソフタレートとの共重合ポリエステル低融点ポリエステルから選ばれる何れか一種のの熱可塑性樹脂を低融点樹脂とし、ポリプロピレン又はポリエチレンテレフタレートを高融点樹脂とする並列型、鞘芯型、偏芯鞘芯型の複合繊維である。特に、汚れの掻きとり性が良好になる点から、低融点ポリエステルとポリエチレンテレフタレートとの複合繊維を用いる事が好ましい。   The form of the heat-fusible conjugate fiber is a parallel type, a sheath core type, an eccentric sheath core type, a multilayer type of three or more layers, a hollow parallel type, a middle sheath core type, a deformed sheath core type, a sea island type, etc. Any structure may be used as long as the melting point resin forms at least a part of the fiber surface. Preferred among the heat-fusible conjugate fibers are selected from high-density polyethylene, linear low-density polyethylene, ethylene-butylene-1 crystalline copolymer, copolymerized polyester of polyethylene terephthalate and polyethylene isophthalate, and low-melting polyester. This is a parallel type, sheath core type, or eccentric sheath core type composite fiber in which any one type of thermoplastic resin is a low melting point resin and polypropylene or polyethylene terephthalate is a high melting point resin. In particular, it is preferable to use a composite fiber of low-melting point polyester and polyethylene terephthalate from the viewpoint of good dirt scraping properties.

合成繊維(A)として、捲縮性を有しているものを用いる事もできる。これによって、清掃シートの厚み感を向上させることができ、良好な拭き心地が得られる。   A synthetic fiber (A) having crimpability can also be used. Thereby, the feeling of thickness of the cleaning sheet can be improved, and good wiping comfort can be obtained.

合成繊維(A)及び合成繊維(B)はそれぞれ1種又は2種以上を用いる事ができる。繊維の交点が接着されることから、合成繊維(B)は合成繊維(A)と同じ樹脂の繊維を用いる事が好ましい。合成繊維の他にセルロース系繊維を含有させてもかわまない。   The synthetic fiber (A) and the synthetic fiber (B) can each be used alone or in combination of two or more. Since the intersections of the fibers are bonded, it is preferable to use the same resin fibers as the synthetic fibers (A) for the synthetic fibers (B). Cellulosic fibers may be contained in addition to synthetic fibers.

清掃用不織布は、合成繊維(A)及び合成繊維(B)を混合した繊維ウエブもしくは、単独ウエブを空気中で分散して基体上に堆積させてウエブを形成し、形成されたウエブにおける構成繊維同士の交点を接着させて不織布形成される。構成繊維の結合手段としては、融着やバインダーによる接着が好適に用いられる。バインダーとしては、アクリル二トリル−ブタジエンゴム、スチレン−ブタジエンゴム、ポリ酢酸ビニル、ポリエチレン酢酸ビニル、ポリアクリレート等が用いられる。好ましくは、エアレイ法でウエブ形成し、繊維の交点を接着して製造することが好ましい。本発明で得られた清掃用不織布においては、構成繊維がランダムに3次元配向し、繊維間の空隙が比較的大きく、嵩高なものが得られる。   The nonwoven fabric for cleaning is a fiber web in which a synthetic fiber (A) and a synthetic fiber (B) are mixed, or a single web is dispersed in air and deposited on a substrate to form a web, and the constituent fibers in the formed web A non-woven fabric is formed by bonding the intersections of each other. As a means for bonding the constituent fibers, fusion bonding or adhesion using a binder is preferably used. As the binder, acrylic nitrile-butadiene rubber, styrene-butadiene rubber, polyvinyl acetate, polyethylene vinyl acetate, polyacrylate, or the like is used. Preferably, the web is formed by the air lay method, and the fiber intersections are bonded and manufactured. In the nonwoven fabric for cleaning obtained in the present invention, the constituent fibers are randomly three-dimensionally oriented, and the gaps between the fibers are relatively large and bulky.

本発明の清掃用不織布は、操作性の観点から、エンボス加工により凹凸構造が形成されていることが好ましい。更に、清掃用不織布の構成繊維として熱融着性の繊維が使用されている場合は、不織布の強度を向上させる点も含めて、ヒートエンボス加工や超音波エンボス加工により凹凸構造が形成されていることが好ましい。また、本発明の清掃用不織布の片面にスポンジ、他の不織布又はフィルムを積層して多層構造としてもかまわない。この場合は、清掃面に直接接するよう表層に本発明の不織布を形成すればよい。   From the viewpoint of operability, the nonwoven fabric for cleaning of the present invention preferably has an uneven structure formed by embossing. Furthermore, when heat-fusible fibers are used as the constituent fibers of the nonwoven fabric for cleaning, the uneven structure is formed by heat embossing or ultrasonic embossing, including the point of improving the strength of the nonwoven fabric. It is preferable. Further, a sponge, another nonwoven fabric or a film may be laminated on one side of the cleaning nonwoven fabric of the present invention to form a multilayer structure. In this case, what is necessary is just to form the nonwoven fabric of this invention in a surface layer so that a cleaning surface may be contact | connected directly.

本実施形態の清掃用不織布は、キッチン、鍋、フライパンにこびりついた変性油、焦付き及び水垢等の汚れの除去、並びに洗面所、トイレ及び浴室周りにこびりついた皮脂、水垢、ホコリ及び石鹸かす汚れの除去等に使用する事ができる。特に、鍋、フライパン、電子レンジ内の焦付き汚れの除去に最適である。   The non-woven fabric for cleaning of this embodiment is a modified oil stuck to kitchens, pans and frying pans, removes dirt such as scorching and scales, and sebum, scales, dust and soap dusts stuck around the bathroom, toilet and bathroom. It can be used for removal of water. In particular, it is most suitable for removing stubborn dirt in pots, pans, and microwave ovens.

本発明の清掃用不織布は、使用時に水又は洗浄液を、清掃対象面又は前記不織布(「清掃面」と言う)に吹き付けて、用いる事が好ましい。そして、清掃用不織布は、細い径の合成繊維(B)を含んでいるので、洗浄液の保持性が良好であり、清掃対象面の汚れを機械的に研磨ないし掻きとり除去することに加えて、洗浄剤によって汚れが膨潤したり、一部溶解するため、機械的な研磨ないし掻きとりの作用と相俟って、特に焦付き汚れの除去等が一層向上し、清掃面に傷つけにくくなる。   The nonwoven fabric for cleaning of the present invention is preferably used by spraying water or a cleaning liquid on the surface to be cleaned or the nonwoven fabric (referred to as “cleaning surface”) at the time of use. And since the nonwoven fabric for cleaning contains the synthetic fiber (B) with a thin diameter, the retention of the cleaning liquid is good, and in addition to mechanically polishing or scraping off the dirt on the surface to be cleaned, Since the dirt swells or partially dissolves by the cleaning agent, in combination with the action of mechanical polishing or scraping, the removal of the dark dirt, etc., is further improved and the cleaning surface is hardly damaged.

本実施形態の清掃用不織布における汚れの除去機構について、該清掃用不織布に洗浄液を拭きつけるか、清掃面に洗浄液を吹き付けて清掃する場合を例に取り説明すると、清掃用不織布の何れか一方の面を清掃対象面に押し当てて、こすり付ける。清掃用不織布に含有する細径合成繊維に、洗浄液が保持されて、こすり付ける際に、洗浄液が表面に染み出して、清掃面には絶えず洗浄液で満たされる。洗浄液が清掃対象面に存する汚れを膨潤、溶解ないし浮き上がらせる。これと共に、清掃用不織布の太い径の合成繊維(A)は、その交点が接着されているので、合成繊維(A)の胴部や先端部の汚れに対する掻きとり性能がさらに向上し、対象面に存する汚れを良く掻きとる。これら機械的、化学的相互作用によって、汚れが清掃対象面から効果的に除去される。特に焦付き汚れに対しては、交点が接着された太径合成繊維(A)による研磨作用と、細径合成繊維(B)に保持された洗浄液が繰返し焦付き面を擦りおとすともに、洗浄作用と相俟って、効果的に落とす事ができ、且つ太い径の合成繊維の胴部や先端部が焦付き汚れに対し擦ったり掻き取ったり作用することで効果的に剥がれ落とす事ができる。従来の金属繊維等の清掃シートのように、鋭利で硬い先端部等で削り落とし、焦付きがおちると同時に清掃面にも傷を付けてしまうといった事はない。また、太い合成繊維のみでエアレイ法で形成した不織布は、表面に太い繊維の先端部が多数存在し、汚れの掻きとり性能を有するものの、焦付き汚れ等を無理に掻き取ろうとすると、先端部で、清掃対象面を傷つけてしまい、特にアルミニウムやプラスチックといった比較的柔らかい素材に対し傷つけ易い。さらに、太い繊維のみで形成した不織布を手で持つと、ちくちくした不快感がある。本発明品は、繊維先端部を表面に多数立たせなくとも傷つき性と汚れ落し性能を両立させたものである。手で持った際にちくちく感があまりない。   The removal mechanism of the dirt in the nonwoven fabric for cleaning according to this embodiment will be described by taking as an example the case of cleaning the nonwoven fabric for cleaning by wiping the cleaning liquid or spraying the cleaning liquid on the cleaning surface. Press the surface against the surface to be cleaned and rub it. When the cleaning liquid is held in the fine synthetic fiber contained in the nonwoven fabric for cleaning and rubbed, the cleaning liquid oozes out to the surface, and the cleaning surface is constantly filled with the cleaning liquid. The cleaning liquid swells, dissolves or floats up dirt on the surface to be cleaned. At the same time, the synthetic fiber (A) having a large diameter of the nonwoven fabric for cleaning is bonded at its intersection, so that the scraping performance of the synthetic fiber (A) with respect to dirt on the body and tip is further improved. Scrape off the dirt that exists in the well. By these mechanical and chemical interactions, dirt is effectively removed from the surface to be cleaned. Especially for scumming stains, the polishing action by the large-diameter synthetic fiber (A) to which the intersection points are bonded, and the cleaning liquid retained on the small-diameter synthetic fiber (B) repeatedly rubs the scooted surface, and the cleaning action. In combination, it can be effectively removed, and the body and tip of the synthetic fiber having a large diameter can be effectively peeled off by rubbing or scraping against the stained dirt. Like a conventional cleaning sheet made of metal fibers or the like, it is not scraped off by a sharp and hard tip, and the scoring is not lost and the cleaning surface is not damaged. In addition, the nonwoven fabric formed only by thick synthetic fibers by air-laying method has many thick fiber tip parts on the surface and has the ability to scrape dirt. Therefore, the surface to be cleaned is damaged, and it is easy to damage particularly soft materials such as aluminum and plastic. Furthermore, when a non-woven fabric formed only of thick fibers is held by hand, there is a tingling discomfort. The product of the present invention achieves both scratching ability and dirt removal performance without having a large number of fiber tips on the surface. There is not much tingling sensation when held by hand.

本発明の清掃用不織布の清掃する側又は清掃対象面(清掃面)に吹き付けたり、あらかじめ不織布に含浸させる洗浄液は、水性洗浄液が好ましく、水を媒体とし、界面活性剤、アルカリ剤、電解質及び水溶性溶剤を含有することが好ましい。更に、除菌剤を含有する事が好ましい。水性洗浄剤中に含有される不揮発残留成分については、10重量%以下であることが清掃後の仕上がり性の面で好ましく、特に5重量%以下であることが好ましい。水性洗浄剤に含有させる界面活性剤、アルカリ剤、電解質、水溶性溶剤、その他成分として、特開2003−61835号公報〔0034〕〜〔0039〕記載のとおり用いる事ができる。水性洗浄剤の媒体である水は、水性洗浄剤中に、50〜99.9重量%、特に80〜99重量%含有されることが、被清掃面の洗浄性及び仕上がり性の点から好ましい。   The cleaning liquid sprayed on the cleaning side of the cleaning nonwoven fabric of the present invention or the surface to be cleaned (cleaning surface) or impregnated into the nonwoven fabric in advance is preferably an aqueous cleaning liquid, using water as a medium, a surfactant, an alkaline agent, an electrolyte, and a water-soluble liquid. It is preferable to contain a reactive solvent. Furthermore, it is preferable to contain a disinfectant. The non-volatile residual component contained in the aqueous cleaning agent is preferably 10% by weight or less from the viewpoint of finish after cleaning, and particularly preferably 5% by weight or less. As a surfactant, an alkali agent, an electrolyte, a water-soluble solvent, and other components to be contained in the aqueous detergent, it can be used as described in JP-A-2003-61835 [0034] to [0039]. Water, which is a medium for the aqueous cleaning agent, is preferably contained in the aqueous cleaning agent in an amount of 50 to 99.9% by weight, particularly 80 to 99% by weight, from the viewpoint of the cleanability and finish of the surface to be cleaned.

洗浄液を吹き付けて使用する場合、清掃用不織布重量に対して、50〜300重量%清掃面もしくは清掃用不織布に吹き付けるて使用するのが簡便でコストも安く好ましい。   When used by spraying the cleaning liquid, it is preferable that the cleaning liquid is used by spraying on the cleaning surface or the nonwoven fabric for cleaning with respect to the weight of the nonwoven fabric for cleaning.

本発明の清掃用不織布の片面にセルロース系繊維を含む液保持シートを積層してもよい。液保持シートは、水性洗浄液の保持担体として作用する。この場合、清掃面又は清掃用不織布に洗浄液を吹き付けなくとも使用できる。   You may laminate | stack the liquid holding sheet | seat containing a cellulosic fiber on the single side | surface of the nonwoven fabric for cleaning of this invention. The liquid holding sheet acts as a holding carrier for the aqueous cleaning liquid. In this case, the cleaning liquid or the cleaning nonwoven fabric can be used without spraying the cleaning liquid.

さらに、本発明の清掃用不織布は、洗浄液を吹き付けたり、あらかじめ含浸させなくとも、キッチンの水周りを清掃する場合は、濡れている水を利用して清掃することが可能であり、簡便である。   Furthermore, the cleaning nonwoven fabric of the present invention can be easily cleaned by using wet water when cleaning around the water in the kitchen without spraying or pre-impregnating the cleaning liquid. .

次に、本実施形態の清掃用不織布の製造方法の一例を説明する。   Next, an example of the manufacturing method of the nonwoven fabric for cleaning of this embodiment is demonstrated.

熱融着性の合成繊維(A)と合成繊維(B)とを混綿した繊維ウエブを解繊し、ほぐされた繊維を振動し、繊維を篩目から分散落下させながら降り積らせ、ネットコンベアー等ウエブ捕集装置上に捕集し繊維ウエブを得る。更に熱処理機で熱融着温度以上の温度で熱処理し繊維の交点を融着することにより目的とする不織布が得られる。前記ウエブの熱処理機は、エアスルー型熱処理機を用いることができる。熱融着性繊維を用いない場合は、繊維を降り積らせた後、熱融着性パウダー又は接着剤を吹き付けて得られた繊維ウエブを熱処理して交点を接着して目的の不織布が得られる。さらに、前記工程の製造条件を適宜コントロールすることで、不織布厚み方向における合成繊維(A)の存在量に勾配を持たせる事ができる。例えば、合成繊維(B)の分散落下工程の次に合成繊維(A)の分散落下工程を通す事で、不織布の表層に合成繊維(A)を多く存在させる事ができて、汚れの掻きとり性能を向上させることができる。さらに、合成繊維(A)を分散落下させる際、下方からの吸引を可変する事で、合成繊維(A)の傾斜が異なり、厚みに対し垂直に立たせたり、寝かせたりすることも可能である。本発明の清掃用不織布は、太い径の合成繊維(A)の胴部と先端部両方が、汚れに作用することから、太径繊維を極端に立たせたり、極端に寝かせないことが好ましい。また、細い径の合成繊維(B)は、太い径の合成繊維(A)に対し偏在することなく、均一である事が好ましいが、厚み方向では、清掃表面には分布せず、清掃面に対し遠い下層又は両面清掃使用する場合は、中層に存在する事が好ましい。なお、本発明の製法は、エアレイ方式を用いる事が好ましが、繊維を空気中で分散堆積した繊維ウエブであれば、適宜他の方式を用いることもできる。また、繊維の接合方式は、サーマルボンド方式、ケミカルボンド方式がもちいられるが、繊維交点が強固であれば、前記方式に限定されない。   The fiber web made by blending the heat-fusible synthetic fiber (A) and synthetic fiber (B) is disentangled, the loosened fibers are vibrated, and the fibers are piled down while being dispersed and dropped from the sieve mesh. A fiber web is obtained by collecting on a web collection device such as a conveyor. Furthermore, the target nonwoven fabric is obtained by heat-treating at a temperature equal to or higher than the heat-fusion temperature with a heat treatment machine and fusing the intersections of the fibers. As the heat treatment machine for the web, an air-through heat treatment machine can be used. When heat-sealable fibers are not used, the target nonwoven fabric is obtained by laminating the fibers and then heat-treating the fiber web obtained by spraying heat-sealable powder or adhesive to bond the intersections. It is done. Further, by appropriately controlling the manufacturing conditions in the above process, the abundance of the synthetic fiber (A) in the nonwoven fabric thickness direction can be given a gradient. For example, by passing the synthetic fiber (A) dispersion and dropping process next to the synthetic fiber (B) dispersion and dropping process, a large amount of the synthetic fiber (A) can be present on the surface layer of the nonwoven fabric. Performance can be improved. Furthermore, when the synthetic fiber (A) is dispersed and dropped, by varying the suction from below, the synthetic fiber (A) can be tilted differently and can stand upright or be laid down. In the nonwoven fabric for cleaning of the present invention, since both the trunk and the tip of the synthetic fiber (A) having a large diameter act on dirt, it is preferable that the large-diameter fiber is extremely raised or not extremely laid down. Further, the synthetic fiber (B) having a small diameter is preferably not uniform with respect to the synthetic fiber (A) having a large diameter, but is uniform on the cleaning surface in the thickness direction. On the other hand, when using a far lower layer or double-sided cleaning, it is preferably present in the middle layer. In the production method of the present invention, it is preferable to use the air array method, but any other method can be used as long as it is a fiber web in which fibers are dispersed and deposited in air. The fiber bonding method may be a thermal bond method or a chemical bond method, but is not limited to the above method as long as the fiber intersection is strong.

本発明の清掃用不織布は、エンボス加工で凹凸を施すことで、手で擦って清掃する時に、操作性をよくする事ができる。熱融着性繊維が使用されている場合には、ヒートエンボス加工、超音波エンボス加工で形成する事ができる。さらに、本発明の清掃用不織布を複数枚重ねて熱処理することで、ブロック状の清掃用不織布ができる。ブロックから元の薄い不織布を数枚剥がして使用する事で、適当な厚手で使用する事ができる。   The non-woven fabric for cleaning of the present invention can improve operability when it is rubbed by hand and cleaned by embossing it. When heat-fusible fiber is used, it can be formed by heat embossing or ultrasonic embossing. Furthermore, a plurality of cleaning nonwoven fabrics according to the present invention are stacked and heat-treated to form a block-shaped cleaning nonwoven fabric. By peeling off several original thin nonwoven fabrics from the block, it can be used with appropriate thickness.

次に、下記実施例に基づいて本発明を具体的に説明する。   Next, the present invention will be specifically described based on the following examples.

〔実施例1〕
繊度56dtex、繊維長5mmのポリエチレンテレフタレート熱融着性繊維と繊度2.2dtex、繊維長5mmのポリエチレンテレフタレート熱融着性繊維とを重量比75:25(太径:細径)に混綿した繊維ウエブを解繊、分散して繊維を基体上に降り積らせて繊維ウエブを得た。得られた繊維ウエブを140℃にて熱処理して繊維の交点を融着させて、厚み1.5mm、坪量80g/m2の清掃用不織布を得た。
[Example 1]
A fiber web in which a polyethylene terephthalate heat-fusible fiber having a fineness of 56 dtex and a fiber length of 5 mm and a polyethylene terephthalate heat-fusible fiber having a fineness of 2.2 dtex and a fiber length of 5 mm are mixed in a weight ratio of 75:25 (large diameter: small diameter). The fiber was defibrated and dispersed, and the fiber was deposited on the substrate to obtain a fiber web. The obtained fiber web was heat-treated at 140 ° C. to fuse the intersections of the fibers to obtain a cleaning nonwoven fabric having a thickness of 1.5 mm and a basis weight of 80 g / m 2 .

〔実施例2〕
繊度22dtex、繊維長5mmのポリエチレンテレフタレート熱融着性繊維と繊度2.2dtex、繊維長5mmのポリエチレンテレフタレート熱融着性繊維とを重量比90:10(太径:細径)に混綿した繊維ウエブを解繊、分散して繊維を基体上に降り積らせて繊維ウエブを得た。得られた繊維ウエブを140℃にて熱処理して繊維の交点を融着させて、厚み1.8mm、坪量80g/m2の清掃用不織布を得た。
[Example 2]
A fiber web in which a polyethylene terephthalate heat-fusible fiber having a fineness of 22 dtex and a fiber length of 5 mm and a polyethylene terephthalate heat-fusible fiber having a fineness of 2.2 dtex and a fiber length of 5 mm are mixed in a weight ratio of 90:10 (large diameter: small diameter). Was defibrated and dispersed, and the fiber was deposited on a substrate to obtain a fiber web. The obtained fiber web was heat-treated at 140 ° C. to fuse the intersections of the fibers to obtain a cleaning nonwoven fabric having a thickness of 1.8 mm and a basis weight of 80 g / m 2 .

〔実施例3〕
繊度35dtex、繊維長5mmのポリプロピレン(芯)/ポリエチレン(鞘)構造の熱融着性繊維と繊度11dtex、繊維長5mmのポリプロピレン(芯)/ポリエチレン(鞘)構造の熱融着性繊維とを重量比50:50(太径:細径)に混綿した繊維ウエブを解繊、分散して繊維を基体上に降り積らせて繊維ウエブを得た。得られた繊維ウエブを145℃にて熱処理して繊維の交点を融着させて、厚み2.3mm、坪量80g/m2の清掃用不織布を得た。
Example 3
Weight of heat-sealable fiber of polypropylene (core) / polyethylene (sheath) structure with a fineness of 35 dtex and fiber length of 5 mm and heat-sealable fiber of polypropylene (core) / polyethylene (sheath) structure with a fineness of 11 dtex and fiber length of 5 mm A fiber web blended in a ratio of 50:50 (thick diameter: thin diameter) was defibrated and dispersed, and the fiber was lowered onto the substrate to obtain a fiber web. The obtained fiber web was heat-treated at 145 ° C. to fuse the intersections of the fibers to obtain a cleaning nonwoven fabric having a thickness of 2.3 mm and a basis weight of 80 g / m 2 .

〔比較例1〕
繊度3.3dtex、繊維長5mmのポリプロピレン(芯)/ポリエチレン(鞘)構造の熱融着性繊維からなる繊維ウエブを解繊、分散して、繊維を基体上に降り積らせて繊維ウエブを得た。得られた繊維ウエブを145℃で熱処理して繊維の交点を融着させて、厚み1.8mm、坪量80g/m2の清掃用不織布を得た。
[Comparative Example 1]
A fiber web made of heat-fusible fibers with a polypropylene (core) / polyethylene (sheath) structure with a fineness of 3.3 dtex and a fiber length of 5 mm is disentangled and dispersed, and the fibers are lowered onto the substrate to form the fiber web. Obtained. The obtained fiber web was heat-treated at 145 ° C. to fuse the intersections of the fibers to obtain a cleaning nonwoven fabric having a thickness of 1.8 mm and a basis weight of 80 g / m 2 .

〔比較例2〕
繊度2.2dtex、繊維長5mmのポリエチレンテレフタレートの熱融着性繊維と繊度1.7dtex、繊維長5mmのポリプロピレン(芯)/ポリエチレン(鞘)構造の熱融着性繊維とを重量比90:10に混綿した繊維ウエブを解繊、分散して基体上に降り積らせて繊維ウエブを得た。得られた繊維ウエブを145℃にて熱処理して繊維の交点を融着させて、厚み1.7mm、坪量80g/m2の清掃用不織布を得た。
[Comparative Example 2]
Weight ratio of heat-fusible fiber of polyethylene terephthalate having a fineness of 2.2 dtex and fiber length of 5 mm to heat-fusible fiber having a fineness of 1.7 dtex and fiber length of 5 mm of polypropylene (core) / polyethylene (sheath) structure The fiber web blended with the fiber was defibrated, dispersed, and deposited on the substrate to obtain a fiber web. The obtained fiber web was heat-treated at 145 ° C. to fuse the intersections of the fibers to obtain a cleaning nonwoven fabric having a thickness of 1.7 mm and a basis weight of 80 g / m 2 .

〔比較例3〕
繊度22dtex、繊維長5mmのポリエチレンテレフタレート熱融着繊維を解繊、分散して基体上に降り積らせて繊維ウエブを得た。得られた繊維ウエブを145℃にて熱処理して繊維の交点を融着させて、厚み1.9mm、坪量80g/m2の清掃用不織布を得た。
[Comparative Example 3]
Polyethylene terephthalate heat-bonded fibers having a fineness of 22 dtex and a fiber length of 5 mm were disentangled, dispersed and loaded onto the substrate to obtain a fiber web. The obtained fiber web was heat-treated at 145 ° C. to fuse the intersections of the fibers to obtain a cleaning nonwoven fabric having a thickness of 1.9 mm and a basis weight of 80 g / m 2 .

〔性能評価〕
実施例及び比較例で得られた清掃用不織布について、以下の方法で汚れ掻きとり性能、傷つき防止性能、洗浄液保持の目安となる洗浄液落下量について評価した。それらの結果を表1に示す。
[Performance evaluation]
About the nonwoven fabric for cleaning obtained by the Example and the comparative example, the cleaning | polishing amount of washing | cleaning liquid used as the standard of dirt scraping performance, damage prevention performance, and washing | cleaning liquid holding | maintenance was evaluated with the following method. The results are shown in Table 1.

〔弱変性汚れの作成方法〕
サンドペーパーで表面を擦った鉄製のテストピース(30mm×80mm)に油(林市次商店社製、商品名菜種油)を0.06g均一に塗布し、160℃30分間焼き付けを行い弱変性油汚れを作った。この弱変性油汚れの鉛筆硬度は5B以下であった。
[How to make weakly denatured dirt]
0.06g of oil (trade name rapeseed oil, manufactured by Hayashi City Next Shoten Co., Ltd.) is uniformly applied to an iron test piece (30mm x 80mm) whose surface is rubbed with sandpaper, and baked at 160 ° C for 30 minutes to weakly denature oil stains made. The pencil hardness of this weakly modified oil stain was 5B or less.

〔中変性油汚れの作成方法〕
サンドペーパーで表面を擦った鉄製のテストピース(30mm×80mm)に油(林市次商店社製、商品名菜種油)を0.06g均一に塗布し、150℃で130分間焼き付けて中変性油汚れを作った。この中変性油汚れの鉛筆硬度は3Bであった。
[How to make moderately modified oil stains]
0.06 g of oil (trade name: rapeseed oil, manufactured by Hayashi City Next Shoten Co., Ltd.) is uniformly applied to an iron test piece (30 mm × 80 mm) whose surface is rubbed with sandpaper, and baked at 150 ° C. for 130 minutes to moderately denatured oil stains made. The pencil hardness of this medium-modified oil stain was 3B.

〔焦付き汚れの作成方法〕
SUS304製のテストピース(30mm×80mm)に、砂糖:醤油:みりん=40:44:16(重量比)で混合した液を0.06g均一に塗布し、180℃120分間焼き付けて焦げ付き汚れを作った。この焦げ付き汚れの鉛筆硬度は9Hであった。
[How to create stubborn dirt]
Apply 0.06g of a mixture of sugar: soy sauce: mirin = 40:44:16 (weight ratio) uniformly to a test piece (30mm x 80mm) made of SUS304, and bake it at 180 ° C for 120 minutes to make a burnt stain. It was. The pencil hardness of this burnt stain was 9H.

〔掻きとり性能評価方法〕
清掃用不織布を軽く水で濡らし界面活性剤を水で41%調整した洗浄液(または花王ファミリーコンパクト)を2ml吹き付けて、軽く揉んだあと、モデル汚れのついたテストピースを手(5000g荷重程度)で擦り、目視にてモデル汚れが取り去られた回数を清拭回数とした。
[Scraping performance evaluation method]
Wet the cleaning nonwoven with light water and spray 2ml of detergent (or Kao Family Compact) with 41% of surfactant in water. After gently squeezing, hand the model-stained test piece with a load of about 5000g. The number of times the model dirt was removed by rubbing and visual observation was defined as the number of times of wiping.

〔傷つき防止性〕
前記洗浄液を吹き付けた清掃用シートでステンレス(SUS304)、人工大理石(アクリル系)、アルミ二ウム、ポリカーボネート、フッ素樹脂加工されたテストピース(30mm×80mm)の上を、400g/cm2の荷重下で、それぞれ20往復擦った。その後以下の基準によって傷つき防止性を評価した。
○:目視で傷つきが全く無い
△:目視で光にかざすと傷が見える
×:目視で傷が多数ついているのが見える(光にはかざさない)
[Injury prevention]
Under the load of 400 g / cm 2 on the test piece (30 mm x 80 mm) processed with stainless steel (SUS304), artificial marble (acrylic), aluminum, polycarbonate, fluororesin with the cleaning sheet sprayed with the cleaning liquid And rubbed 20 times each. Thereafter, scratch resistance was evaluated according to the following criteria.
○: No scratches are visually observed Δ: Scratches are visible when held over light visually X: Many scratches are visible (not held over light)

〔洗浄液保持量の測定方法〕
前記得られた清掃用不織布を300ccビーカーの開口上に置き、界面活性剤を水で41%に調整した洗浄液(または花王ファミリーコンパクト)をガラスピペットにて2mlを不織布中央部に垂らす。1分間静置後、不織布を通過してビーカー内に落下した洗浄液の重量(g)を測定した。
[Measurement method of the amount of washing liquid retained]
The obtained non-woven fabric for cleaning is placed on the opening of a 300 cc beaker, and 2 ml of a cleaning liquid (or Kao Family Compact) in which the surfactant is adjusted to 41% with water is dropped with a glass pipette on the center of the non-woven fabric. After standing for 1 minute, the weight (g) of the cleaning liquid that passed through the nonwoven fabric and dropped into the beaker was measured.

Figure 2005185429
Figure 2005185429

表1に示す結果から明らかなように、各実施例の清掃用不織布(本発明品)は、汚れに対する清掃性能に優れることがわかる。   As is clear from the results shown in Table 1, it can be seen that the nonwoven fabric for cleaning (product of the present invention) of each Example is excellent in cleaning performance against dirt.

Claims (8)

繊度20〜100dtexの合成繊維(A)と繊度1〜11dtexの合成繊維(B)を、空気中に分散して、堆積させた繊維の交点を接着させて、得られた清掃用不織布。   A nonwoven fabric for cleaning obtained by dispersing a synthetic fiber (A) having a fineness of 20 to 100 dtex and a synthetic fiber (B) having a fineness of 1 to 11 dtex in the air and bonding the intersections of the deposited fibers. 前記接着が、熱融着性繊維又は熱融着性パウダーによる熱接着である請求項1記載の不織布。   The nonwoven fabric according to claim 1, wherein the bonding is heat bonding using heat-fusible fibers or heat-fusible powder. 前記合成繊維(B)は、合成繊維(A)100重量部に対して10〜50重量部含有したことを特徴とする請求項1又は2記載の清掃用不織布。   The said synthetic fiber (B) contained 10-50 weight part with respect to 100 weight part of synthetic fibers (A), The nonwoven fabric for cleaning of Claim 1 or 2 characterized by the above-mentioned. 前記合成繊維(A)は、ロックウエル硬さR40〜R150の樹脂を用いたことを特徴とする請求項1ないし3の何れかに記載の清掃用不織布。   The nonwoven fabric for cleaning according to any one of claims 1 to 3, wherein the synthetic fiber (A) uses a resin having a Rockwell hardness of R40 to R150. 前記合成繊維(A)は、繊維長1〜10mmの短い繊維と繊維長20〜75mmの長い繊維を重量比で9:1〜7:3の割合で含有した事を特徴とする請求項1ないし3の何れかに記載の清掃用不織布。   The synthetic fiber (A) contains a short fiber having a fiber length of 1 to 10 mm and a long fiber having a fiber length of 20 to 75 mm in a weight ratio of 9: 1 to 7: 3. The nonwoven fabric for cleaning according to any one of 3. 前記合成繊維(A)は、ポリエチレンテレフタレートからなることを特徴とする請求項3記載の清掃用不織布。   The said synthetic fiber (A) consists of a polyethylene terephthalate, The nonwoven fabric for cleaning of Claim 3 characterized by the above-mentioned. 前記清掃用不織布の洗浄液落下量が、1.5g/1分以下であることを特徴とする請求項1ないし4の何れかに記載の清掃用不織布。   The cleaning nonwoven fabric according to any one of claims 1 to 4, wherein a cleaning liquid dropping amount of the cleaning nonwoven fabric is 1.5 g / 1 min or less. 水又は水性洗浄液を清掃面に吹き付け、請求項1ないし7の何れかに記載の清掃用不織布を用いて清掃を行う清掃方法。
A cleaning method in which water or an aqueous cleaning liquid is sprayed on a cleaning surface, and cleaning is performed using the cleaning nonwoven fabric according to any one of claims 1 to 7.
JP2003429326A 2003-12-25 2003-12-25 Nonwoven fabric for cleaning Pending JP2005185429A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2003429326A JP2005185429A (en) 2003-12-25 2003-12-25 Nonwoven fabric for cleaning

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2003429326A JP2005185429A (en) 2003-12-25 2003-12-25 Nonwoven fabric for cleaning

Publications (1)

Publication Number Publication Date
JP2005185429A true JP2005185429A (en) 2005-07-14

Family

ID=34788028

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2003429326A Pending JP2005185429A (en) 2003-12-25 2003-12-25 Nonwoven fabric for cleaning

Country Status (1)

Country Link
JP (1) JP2005185429A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015229041A (en) * 2014-06-06 2015-12-21 花王株式会社 Cleaning sheet

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5615721A (en) * 1979-07-18 1981-02-16 Kanai Hiroyuki Nonwoven fabric for polishing floor
JPH0614860A (en) * 1992-06-30 1994-01-25 Japan Vilene Co Ltd Non-woven fabric wiper and its production
JP2003061885A (en) * 2000-12-01 2003-03-04 Kao Corp Cleaning sheet
JP2003284659A (en) * 2002-03-27 2003-10-07 Kao Corp Hot cleaning utensil
JP2003325411A (en) * 2002-03-06 2003-11-18 Kao Corp Sheet for scrape-off cleaning

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5615721A (en) * 1979-07-18 1981-02-16 Kanai Hiroyuki Nonwoven fabric for polishing floor
JPH0614860A (en) * 1992-06-30 1994-01-25 Japan Vilene Co Ltd Non-woven fabric wiper and its production
JP2003061885A (en) * 2000-12-01 2003-03-04 Kao Corp Cleaning sheet
JP2003325411A (en) * 2002-03-06 2003-11-18 Kao Corp Sheet for scrape-off cleaning
JP2003284659A (en) * 2002-03-27 2003-10-07 Kao Corp Hot cleaning utensil

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015229041A (en) * 2014-06-06 2015-12-21 花王株式会社 Cleaning sheet

Similar Documents

Publication Publication Date Title
JP4169508B2 (en) Cleaning sheet
EP1211342B1 (en) Cleaning sheet
JP4014214B2 (en) Disposable tableware care and hard surface cleaning wipes
US20070107156A1 (en) Cleaning sheets comprising a polymeric additive to improve particulate pick-up and minimize residue left on surfaces and cleaning implements for use with cleaning sheets
JP2006526463A (en) Cleaning pad
JP2003325411A (en) Sheet for scrape-off cleaning
WO2006014202A1 (en) Kits of foam based cleaning elements
WO2008055015A2 (en) Hand-held cleaning tool assembly
US20060123573A1 (en) Flocked substrates for use as scouring materials
JP4523412B2 (en) Cleaning goods
JP2022008129A (en) Cleaning sheet
JP6118290B2 (en) Manufacturing method of cleaning sheet
JP2011092333A (en) Wiping member
US20030192141A1 (en) Scrub Sponge
JP2005185429A (en) Nonwoven fabric for cleaning
JP3972023B2 (en) Cleaning sheet
JP2005312711A (en) Cleaning article for artificial marble
JP4439359B2 (en) Cleaning sheet
JP4688442B2 (en) Cleaning sheet
JP2017131676A (en) Cleaning sheet
JP4023888B2 (en) Nonwoven fabric for cleaning
JP3157621U (en) Laminated cleaner
JP2006055300A (en) Cleaning implement
JP2009153553A (en) Cleaning implement and cleaning method
JP2011115317A (en) Method of manufacturing laminated cleaner

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20051220

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20080902

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20090113