JP2005178020A - Coating forming method for coated metal pipe and coating forming apparatus therefor - Google Patents
Coating forming method for coated metal pipe and coating forming apparatus therefor Download PDFInfo
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Abstract
Description
本発明は、特に自動車等のブレーキ管、燃料管あるいはその他の配管として車体の下部等に配設される管径20mm程度以下の比較的細径からなる金属管における走行中での飛石(チッピング)あるいは/および雨水、泥水(スプラッシュ)等に対する防錆対策として、その外周面に樹脂層からなる樹脂層を形成した被覆金属管の被覆形成方法およびその形成装置に関するものである。 In particular, the present invention provides a stepping stone (chipping) during traveling in a metal pipe having a relatively small diameter of about 20 mm or less, which is disposed as a brake pipe, a fuel pipe or other piping of an automobile or the like in a lower portion of a vehicle body. Alternatively, as a rust prevention measure against rainwater, muddy water (splash), etc., the present invention relates to a method for forming a coating of a coated metal tube in which a resin layer made of a resin layer is formed on its outer peripheral surface and a forming apparatus therefor.
従来、この種の被覆形成方法およびその形成装置としては、一般に亜鉛等によるめっき膜を有する金属管の外周面上に、予めナイロン樹脂、塩化ビニール樹脂あるいはポリオレフィン樹脂等からなる長尺の熱収縮性材料の円筒状部材を被着せしめ、この状態で該金属管を還元ガスの雰囲気下の加熱炉中を通過させることにより前記熱収縮性樹脂を熱収縮せしめ、しかる後に放冷固化して被覆層を形成する方法によるか、あるいは複層による重合被覆のものにあっては、材質を異にする所望の樹脂層を、それぞれ別体として前後に位置して併設したダイ本体に連設したそれぞれの押出供給ユニットにより金属管の外周面に押出成形して重合被覆せしめ、しかる後に放冷固化して被覆形成する方法によるかしてなるものであった。 Conventionally, as this type of coating forming method and apparatus for forming such a coating, a long heat shrinkability made of a nylon resin, a vinyl chloride resin, a polyolefin resin or the like in advance on the outer peripheral surface of a metal tube generally having a plating film made of zinc or the like. A cylindrical member of material is deposited, and in this state, the heat-shrinkable resin is thermally contracted by passing the metal tube through a heating furnace under a reducing gas atmosphere, and then is cooled and solidified. In the case of a polymer coating by a method of forming a plurality of layers, a desired resin layer made of a different material is provided separately on the front and back of the die body that is provided separately from each other. The extrusion was carried out by a method in which the outer peripheral surface of the metal tube was extruded and polymerized by an extrusion supply unit, and then cooled and solidified to form a coating.
しかしながら、前記従来の技術においては、前者にあっては高価な熱収縮性材料からなる円筒状部材の使用、金属管への長尺に亘る被着作業、さらに加熱装置としての還元ガスの雰囲気による加熱炉の必要と、その還元加熱炉中を低速通過することによる処理効率の低下とによって、製造効率が悪く、製品コストの高価を余儀なくされる結果となった。また後者にあっては、押出被覆装置としてそれぞれ別体の前後して備えたダイ本体およびこれらダイ本体に連設する、押出された溶融樹脂を管に密着させるための高価な吸引機構および押出供給ユニットの構造とによって、溶融樹脂の押出成形速度に全て依存するため管の送り速度5〜10m/minで製造効率を上げることができず、また被着形成装置全体を概して複雑となし、かつ単層あるいは複層を問わずその被覆後に単に放冷固化するために、特に金属管表面での被覆層の密合および接着性を十分となし得ず、しばしばその後の製品としての曲げ加工部分に剥離を生ぜしめる問題を有するものであった。 However, in the conventional technique, the former is based on the use of a cylindrical member made of an expensive heat-shrinkable material, a long-time deposition work on a metal tube, and a reducing gas atmosphere as a heating device. Due to the necessity of the heating furnace and the reduction in processing efficiency due to low-speed passage through the reduction heating furnace, the production efficiency is poor and the product cost is inevitably increased. In the latter case, the die body provided separately before and after the extrusion coating apparatus, and an expensive suction mechanism and extrusion supply for connecting the extruded molten resin to the tube, which are connected to the die body. Depending on the structure of the unit, it depends entirely on the extrusion speed of the molten resin, so that the production efficiency cannot be increased at a pipe feed speed of 5 to 10 m / min, and the entire deposition apparatus is generally complicated and simple. In order to simply cool and solidify after coating, regardless of whether it is a layer or multiple layers, it is not possible to achieve sufficient adhesion and adhesion of the coating layer, especially on the surface of the metal tube. It had a problem that gave rise to.
本発明は、従来技術の有する前記問題に鑑みてなされたものであり、従来技術のような前記円筒状部材とその被着作業とを不要となし、また押出被覆装置を概して簡素となすとともに、製造速度を高めることができ、また被覆形成装置全体での被覆加工を容易に行うことができるために総じて製品コストを比較的安価となすことができ、さらに金属管表面での被覆層のなす密合およびその接着を強固となして剥離の生ずる憂いをなくすことができる被覆金属管の被覆形成方法およびその形成装置を提供することを目的とするものである。 The present invention has been made in view of the above-mentioned problems of the prior art, makes the cylindrical member and its application work as in the prior art unnecessary, makes the extrusion coating apparatus generally simple, The manufacturing speed can be increased, and the coating process can be easily performed on the entire coating forming apparatus, so that the product cost can be relatively low as a whole, and the density of the coating layer on the surface of the metal tube can be reduced. It is an object of the present invention to provide a method for forming a coating of a coated metal tube and an apparatus for forming the same, which can strengthen the adhesion and the adhesion thereof and can eliminate the fear of peeling.
上記目的を達成するため本発明の第1の実施態様は、予め外周面にめっき処理を施した金属管を一方向に移動しながら該外周面に押出成形により少なくとも単層からなる樹脂層を被覆せし、さらに前記一方向の移動に連動して高周波誘導加熱により該樹脂層の有する溶融温度以上に金属管を加熱せしめ、次いで可及的速かに押えロールにより樹脂層を外方より押圧して密合状に接着せしめ、その後冷却装置の通過によって該樹脂層を冷却固化せしめる被覆金属管の被覆形成方法を特徴とするものである。 In order to achieve the above object, the first embodiment of the present invention covers at least a single resin layer by extrusion molding on the outer peripheral surface while moving a metal tube whose outer peripheral surface is previously plated in one direction. In addition, in conjunction with the movement in the one direction, the metal tube is heated to a temperature higher than the melting temperature of the resin layer by high frequency induction heating, and then the resin layer is pressed from the outside by a press roll as quickly as possible. It is characterized by a method for forming a coating of a coated metal tube, which is bonded in a dense manner, and then the resin layer is cooled and solidified by passing through a cooling device.
また本発明の第2の実施態様は、予め外周面にめっき処理を施した金属管の移動方向に、順次送りロール装置、押出被覆装置をなすダイ本体に連設した少なくとも1つの押出供給ユニット、高周波誘導加熱装置、押えロール装置、および冷却装置からなる一連の装置を配列せしめて備えてなる被覆金属管の形成装置を特徴とするものである。 In addition, the second embodiment of the present invention is characterized in that at least one extrusion supply unit connected to a die body that sequentially forms a feed roll device and an extrusion coating device in a moving direction of a metal tube whose outer peripheral surface has been plated in advance. The present invention is characterized by a coated metal tube forming apparatus comprising a series of devices including a high-frequency induction heating device, a press roll device, and a cooling device.
本発明の被覆金属管の被覆形成方法およびその形成装置は、特に前記押出被覆装置をなすダイ本体(2)に連設した押出供給ユニット(21)あるいは/および(22)と、高周波誘導加熱装置(3)およびその後の押えロール装置(4)とによる一連の装置での被覆形成方法によるため、ダイ本体(2)における高価な吸引機構を不要となし、単層の被覆にあっては従来技術のような袋部材とその被着作業とを不要となし、同時に前記高周波誘導加熱装置の高速加熱により押出成形の速度を高速化でき、また単層あるいは複層による重合被覆を問わず押出被覆装置を概して簡素となし、さらに被覆形成装置全体での被覆加工を容易に行うことができて製品コストを比較的安価となすことができるとともに、金属管(P)表面での被覆層の密合およびその接着を強固となして製品としての曲げ加工部分の剥離の生ずる憂いをなくし、飛石あるいは/および雨水、泥水等の防錆対策として十分に対処することができる等の多くの効果を奏する。 The coated metal tube coating forming method and apparatus therefor according to the present invention include an extrusion supply unit (2 1 ) or / and (2 2 ) connected to a die body (2) constituting the extrusion coating apparatus, and a high-frequency induction. Due to the coating forming method in a series of devices with the heating device (3) and the subsequent press roll device (4), an expensive suction mechanism in the die body (2) is not required, and in the case of a single layer coating Eliminates the need for the bag member and its deposition work as in the prior art, and at the same time, the high-speed heating of the high-frequency induction heating device can increase the speed of extrusion molding, and can be extruded regardless of whether it is a single layer or multiple layers of polymer coating. The coating apparatus is generally simplified, and the coating process of the entire coating forming apparatus can be easily performed, so that the product cost can be relatively low, and the coating layer on the surface of the metal pipe (P) can be reduced. Many effects such as tightness and adhesion can be strengthened to eliminate the fear of peeling of the bent part of the product, and it can be adequately dealt with as anti-corrosion measures such as stepping stones and / or rainwater, muddy water, etc. Play.
以下、本発明の実施例を図面に基づいて説明すれば、図1は本発明における被覆金属管の被覆形成装置に係る単層被覆時の全体を線図に示す説明図であり、図2は他の実施例の被覆形成装置の複層による重合被覆時の同上図1相当の説明図であって、(P)は管径20mm程度以下の比較的細径からなる金属管であり、所望に応じその外周面にクロメート処理を施した、例えば亜鉛、ニッケル、アルミニウムまたはこれら基合金等による耐食性めっき処理を施してなるものである。 DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Embodiments of the present invention will be described below with reference to the drawings. FIG. 1 is an explanatory diagram showing a diagram of the whole of a single-layer coating according to a coating forming apparatus for a coated metal tube according to the present invention, and FIG. It is explanatory drawing equivalent to FIG. 1 at the time of the superposition | polymerization coating by the multilayer of the coating formation apparatus of another Example, (P) is a metal pipe which consists of a comparatively small diameter below about 20 mm in pipe diameter, Accordingly, the outer peripheral surface is subjected to a chromate treatment, for example, a corrosion-resistant plating treatment with zinc, nickel, aluminum, or a base alloy thereof.
そしてかかる状態をもって金属管(P)を一方向へ移動するとともに、この方向に順次配列した送りロール装置(1)、該金属管(P)の外周面に樹脂を押出成形するため押出被覆装置をなす吸引機構を要しないダイ本体(2)に連設した単数の押出供給ユニット(21)(図1参照)もしくは複数の押出供給ユニット(21)、(22)(図2参照)を備えるものであるが、該ダイ本体からの樹脂の押出速度は、従来のものに比べて後記するように加熱装置の加熱速度が極めて高速であるためにこれに応じて高速化し得るものである。 In this state, the metal pipe (P) is moved in one direction, and a feed roll device (1) sequentially arranged in this direction, and an extrusion coating device for extruding resin on the outer peripheral surface of the metal pipe (P). A single extrusion supply unit (2 1 ) (see FIG. 1) or a plurality of extrusion supply units (2 1 ), (2 2 ) (see FIG. 2) connected to the die body (2) that does not require a suction mechanism. Although it is provided, the extrusion speed of the resin from the die main body can be increased according to this because the heating speed of the heating device is extremely high compared to the conventional one, as will be described later.
そして本発明ではさらに以下の一連の装置を該金属管(P)の移動方向に併設したものである。
すなわち樹脂層の被覆後に該樹脂層の有する溶融温度以上に金属管を加熱せしめるために設けた高周波誘導加熱装置(3)は金属管(P)を瞬時加熱して前記樹脂層の少なくとも最内層を溶融させるものである。
In the present invention, the following series of devices is further provided in the moving direction of the metal pipe (P).
That is, the high-frequency induction heating device (3) provided for heating the metal tube to a temperature higher than the melting temperature of the resin layer after coating the resin layer instantaneously heats the metal tube (P) to form at least the innermost layer of the resin layer. It is to be melted.
次に設けた押圧ロール装置(4)は、該金属管(P)への加熱によって少なくともその最内層が溶融した樹脂層を可及的速かに外方よりほぼ全周に亘って押圧する複数、例えば4つの溝付きロールからなるものであって、該金属管の外周面に対して樹脂層を強固に密合かつ接着するものである。 Next, the press roll device (4) provided is a plurality of members that press the resin tube, at least the innermost layer of which is melted by heating the metal tube (P), over the entire circumference from the outside as quickly as possible. For example, it is composed of four grooved rolls, and the resin layer is firmly intimately bonded to the outer peripheral surface of the metal tube.
さらに被覆層を効果的に冷却固化する冷却装置(5)を設けて強制的な冷却を行い、その後にあって金属管(P)を定尺に切断する切断装置(6)が設けられている。以上の一連の装置によって、それぞれ金属管(P)を送り、かつ樹脂層を被覆、加熱、押圧、冷却して定尺に切断して被覆層を有する金属管を形成するものである。 Further, a cooling device (5) for effectively cooling and solidifying the coating layer is provided to perform forced cooling, and then a cutting device (6) for cutting the metal tube (P) to a regular size is provided. . With the series of devices described above, the metal tube (P) is fed, and the resin layer is coated, heated, pressed, cooled, and cut into a regular size to form a metal tube having a coating layer.
なお、前記ダイ本体(2)は、押出供給ユニット(21)、(22)にあってそれぞれ連通する区劃された流通間隙路に通ずる同芯状に重なるそれぞれのノズル口を有してなるものであり、また(7)は必要に応じて前記冷却装置(5)の下流側に介在して設けた測定ロールであり、後続する切断装置(6)と同期して樹脂被覆金属管を自動的に定尺切断するために設けられたものである。 Note that the die body (2) has respective nozzle openings that are concentrically overlapped with each other in the extrusion supply units (2 1 ) and (2 2 ) and communicate with the defined flow gaps. In addition, (7) is a measurement roll provided on the downstream side of the cooling device (5) as necessary, and the resin-coated metal tube is placed in synchronization with the subsequent cutting device (6). It is provided for automatic regular cutting.
次に本発明の被覆形成方法に関連してその実施例を説明する。
実施例1
Next, the example is described in relation to the coating forming method of the present invention.
Example 1
予め外周面にクロメート処理してなる電解浴温度55℃、電流密度60A/dm2、通電時間2分による膜厚25μmの亜鉛のめっき処理を施した材質SPCCによる管径8mm、肉厚0.7mmの二重巻金属管をもって、該金属管を送りロール装置により送り速度20〜40m/minで一定移動しながら、その外周面に、押圧被覆装置をなす押出供給ユニットの連設したダイ本体からの押出により溶融温度190℃のポリアミド系樹脂(PA12)を層厚約0.9mmに押出成形して樹脂層を被覆せしめた。次いで前記移動に連動して高周波誘導加熱装置によって温度約240℃に金属管を瞬時に加熱して前記ポリアミド系樹脂の内層を溶融し、しかる後に可及的速かに4つのロールからなる押えロール装置により樹脂層の外周面をほぼ全周に亘って外方より押圧して金属管の外周面に密合状に接着せしめ、層厚約0.7mmの被覆層を得た。そして引続き循環水による冷却装置を通過せしめることにより、強制的に冷却固化し、次いで製品長5mに切断して金属管表面で強固に接着した被覆層を有する被覆金属管を得ることができた。
実施例2
Electrolytic bath temperature of 55 ° C, current density 60A / dm2 with a chromate treatment on the outer peripheral surface in advance, tube diameter of 8mm and wall thickness of 0.7mm by material SPCC plated with zinc of 25μm thickness with energization time of 2 minutes Extrusion from a die body with a continuous supply of extrusion supply units on the outer peripheral surface of a double-rolled metal tube, while the metal tube is moved at a feed rate of 20 to 40 m / min by a feed roll device. Thus, a polyamide resin (PA12) having a melting temperature of 190 ° C. was extruded to a layer thickness of about 0.9 mm to cover the resin layer. Next, in conjunction with the movement, the metal tube is instantaneously heated to a temperature of about 240 ° C. by a high-frequency induction heating device to melt the inner layer of the polyamide-based resin, and thereafter, a press roll comprising four rolls as quickly as possible. The outer peripheral surface of the resin layer was pressed from the outside over the entire circumference by means of an apparatus and adhered in an intimate manner to the outer peripheral surface of the metal tube to obtain a coating layer having a layer thickness of about 0.7 mm. Then, by continuously passing through a cooling device using circulating water, it was possible to obtain a coated metal tube having a coating layer that was forcibly cooled and solidified, then cut into a product length of 5 m and firmly adhered to the surface of the metal tube.
Example 2
実施例1と同様の二重巻金属管の外周面に実施例1と同様の条件で処理した膜厚23μmの亜鉛のめっき膜を有する金属管をもって、該金属管を送りロール装置により送り速度20〜40m/minで前方に移動しながらその外周面に、押圧被覆装置をなすダイ本体に連設した後部に位置する押出供給ユニットにより供給した該ダイ本体からの押出により、溶融温度180℃のポリアミド系樹脂(PA11)を押出成形して層厚約0.2mmの樹脂層を被覆せしめるとともに、ほぼこれに同期して別体のなす前部側に位置した押出供給ユニットに連通するダイ本体の区劃されたノズル口からの押出による溶融温度170℃のポリプロピレン樹脂(PP)を押出成形して層厚約0.8mmの重合被覆を行った。次いで前記移動に連続して高周波誘導加熱装置による温度約220℃の瞬時加熱を行い、しかる後に可及的速かに実施例1と同様の押えロール装置により押圧して密合状に接着せしめた層厚約1.0mmの重合被覆層を得た。そして引続き実施例1と同様の冷却装置の通過により冷却固化し、次いで製品長4mに切断して金属管表面に強固に接着した重合被覆層を有する被覆金属管を得ることができた。 A metal tube having a 23 μm-thickness zinc plating film treated under the same conditions as in Example 1 on the outer peripheral surface of a double-rolled metal tube similar to Example 1, and the metal tube is fed at a feed rate of 20 by a feed roll device. Polyamide having a melting temperature of 180 ° C. by extrusion from the die main body supplied by an extrusion supply unit located at the rear of the die main body that is connected to the die main body forming the press coating device on the outer peripheral surface while moving forward at ˜40 m / min. The resin body (PA11) is extruded to coat a resin layer having a layer thickness of about 0.2 mm, and the die main body section communicating with the extrusion supply unit located on the front side formed in a separate body is almost synchronized with this. Polypropylene resin (PP) having a melting temperature of 170 ° C. by extrusion from a trapped nozzle port was extruded to form a polymer coating having a layer thickness of about 0.8 mm. Subsequently, instantaneous heating at a temperature of about 220 ° C. by a high-frequency induction heating device was performed continuously after the movement, and after that, pressing was carried out as quickly as possible by a press roll device similar to that of Example 1 to bond them in a dense form. A polymer coating layer having a layer thickness of about 1.0 mm was obtained. Then, it was cooled and solidified by passing through the same cooling device as in Example 1, and then a coated metal tube having a polymer coating layer firmly cut to a product length of 4 m and firmly adhered to the surface of the metal tube could be obtained.
本発明は、押出被覆装置を概して簡素となし、押出成形の速度を高速化でき、また被覆形成装置全体での被覆加工を容易に行うことができて、総じて製品コストを比較的安価となすことができ、さらに被覆後の高周波誘導加熱装置による金属管への瞬時の加熱とその後の可及的速かな押えロール装置による押圧とによって、金属管表面での被覆層の密合およびその接着を強固となすことができるので、製品としての曲げ加工部分等での剥離の生ずる憂いをなくし、飛石あるいは/および雨水、泥水等の防錆対策として十分に対処することができ、外周面に樹脂層からなる樹脂層を形成した各種被覆金属管の被覆形成に極めて有効である。 In the present invention, the extrusion coating apparatus is generally simplified, the speed of extrusion molding can be increased, and the coating processing in the entire coating forming apparatus can be easily performed, so that the product cost is relatively low as a whole. Furthermore, the coating of the coating layer on the surface of the metal tube and its adhesion are strengthened by instantaneous heating of the metal tube by the high frequency induction heating device after coating and subsequent pressing by the press roll device as quickly as possible. Therefore, it can be used as a rust prevention measure for flying stones and / or rainwater, muddy water, etc. This is extremely effective for forming coatings on various coated metal tubes having a resin layer formed thereon.
P 金属管
1 送りロール装置
2 ダイ本体
21 押出供給ユニット
22 押出供給ユニット
3 高周波誘導加熱装置
4 押えロール装置
5 冷却装置
6 切断装置
P Metal tube 1
Claims (2)
At least one extrusion supply unit (2 1 ) connected in series to the die body (2) forming the feed roll device (1) and the extrusion coating device in the moving direction of the metal pipe (P) whose outer peripheral surface has been plated in advance. ), A high-frequency induction heating device (3), a press roll device (4), and a cooling device (5) are arranged to provide a series of devices.
Priority Applications (1)
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JP2003417983A JP4315792B2 (en) | 2003-12-16 | 2003-12-16 | COATING METHOD FOR COATING METAL TUBE AND FORMING DEVICE THEREOF |
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JP2003417983A JP4315792B2 (en) | 2003-12-16 | 2003-12-16 | COATING METHOD FOR COATING METAL TUBE AND FORMING DEVICE THEREOF |
Publications (3)
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JP2005178020A true JP2005178020A (en) | 2005-07-07 |
JP2005178020A5 JP2005178020A5 (en) | 2007-02-08 |
JP4315792B2 JP4315792B2 (en) | 2009-08-19 |
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JP2003417983A Expired - Fee Related JP4315792B2 (en) | 2003-12-16 | 2003-12-16 | COATING METHOD FOR COATING METAL TUBE AND FORMING DEVICE THEREOF |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103489534A (en) * | 2013-09-25 | 2014-01-01 | 苏州贯龙电磁线股份有限公司 | Thin film sintering electromagnetic wire induction heating bonding system and method for manufacturing electromagnetic wire |
CN107052080A (en) * | 2017-03-09 | 2017-08-18 | 江苏兴洋管业股份有限公司 | A kind of hot-pressed three-way pipe fitting pipe partition heating temperature controlling instruments and its heated for controlling temperature method |
CN107696519A (en) * | 2017-09-29 | 2018-02-16 | 镇江春环密封件集团有限公司 | A kind of production method of polyfluortetraethylecomposite composite pipe |
-
2003
- 2003-12-16 JP JP2003417983A patent/JP4315792B2/en not_active Expired - Fee Related
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103489534A (en) * | 2013-09-25 | 2014-01-01 | 苏州贯龙电磁线股份有限公司 | Thin film sintering electromagnetic wire induction heating bonding system and method for manufacturing electromagnetic wire |
CN107052080A (en) * | 2017-03-09 | 2017-08-18 | 江苏兴洋管业股份有限公司 | A kind of hot-pressed three-way pipe fitting pipe partition heating temperature controlling instruments and its heated for controlling temperature method |
CN107696519A (en) * | 2017-09-29 | 2018-02-16 | 镇江春环密封件集团有限公司 | A kind of production method of polyfluortetraethylecomposite composite pipe |
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JP4315792B2 (en) | 2009-08-19 |
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