JP2005157198A - Guide attached semiconductive belt and method for manufacturing the same - Google Patents

Guide attached semiconductive belt and method for manufacturing the same Download PDF

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Publication number
JP2005157198A
JP2005157198A JP2003398988A JP2003398988A JP2005157198A JP 2005157198 A JP2005157198 A JP 2005157198A JP 2003398988 A JP2003398988 A JP 2003398988A JP 2003398988 A JP2003398988 A JP 2003398988A JP 2005157198 A JP2005157198 A JP 2005157198A
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belt
guide
adhesive
guide material
semiconductive
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Tatsu Yoneda
龍 米田
Keisuke Yoshida
圭介 吉田
Yasuhiro Sako
康浩 迫
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Bando Chemical Industries Ltd
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Bando Chemical Industries Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/71General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined

Abstract

<P>PROBLEM TO BE SOLVED: To provide a guide attached semiconductive belt having an adhesive layer which withstands meandering transverse pressure during belt running, withstands repetitive bending at a small diameter pulley, and ensures a little lowering of adhesive power even to a recent liquid toner. <P>SOLUTION: In the guide attached semiconductive belt, a guide member is formed by extrusion-molding a thermoplastic polyurethane elastomer having a JIS-A hardness of 65-90°, a surface of a belt body to which the guide member is bonded, an adhesive and the guide member each comprise a polyurethane, and the adhesive consists of a base resin comprising a polyurethane solution and a liquid curing agent. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

この発明は、電子写真装置に使用され、蛇行が画像形成に大きく影響する半導電性ベルトに関し、特に、蛇行防止用のガイド材と薄肉円筒体であるベルト本体との接着耐久性に優れ、液状トナーにも適した半導電性ベルトに関する。   The present invention relates to a semiconductive belt used in an electrophotographic apparatus, in which meandering greatly affects image formation, and in particular, has excellent adhesion durability between a meander-preventing guide material and a belt body which is a thin cylindrical body, and is liquid The present invention relates to a semiconductive belt suitable for toner.

本願発明に係るガイド付き半導電性ベルトは、図1に示すように薄肉円筒体であるベルト本体5の内面の幅方向両端部面に断面矩形のガイド材22を接着している。つづけて説明するようにこのガイド付き半導電性ベルト25の外側面に感光体に形成された画像を転写し、更に記録材に転写する。   In the semiconductive belt with guide according to the present invention, as shown in FIG. 1, guide members 22 having a rectangular cross section are bonded to both end faces in the width direction of the inner surface of the belt body 5 which is a thin cylindrical body. As will be described subsequently, the image formed on the photoreceptor is transferred to the outer surface of the guided semiconductive belt 25 and further transferred to a recording material.

電子写真装置には、図2に側面図を示すようにガイド部材を有さない平型のベルト本体5が使用されることが多い。このベルト本体5の働きを図2により簡単に説明すると、感光体1は帯電部2によって帯電された後、露光部3によって潜像が形成され、現像部4によってトナー像が形成されるようになっている。また、中間転写ベルトとして使用されるベルト本体5は、一次転写ローラ6,二次転写ローラ7,駆動ローラ8に張架されており、感光体1と一次転写ローラ6との間に挟まれて矢印xの方向に走行されるようになっている。感光体1に形成された画像は、一次転写口一ラ6の位置において中間転写ベルトであるベルト本体5に転写され、つづいて二次転写ローラ7の位置で記録紙12に転写される。また、一次転写後、感光体1に残留するトナーは、クリーニング部10によって回収され、つづいて感光体1の表面はイレーザーランプ11によって除電される。   As shown in a side view in FIG. 2, a flat belt body 5 having no guide member is often used in an electrophotographic apparatus. The operation of the belt body 5 will be briefly described with reference to FIG. 2. The photosensitive member 1 is charged by the charging unit 2, and then a latent image is formed by the exposure unit 3 and a toner image is formed by the developing unit 4. It has become. A belt body 5 used as an intermediate transfer belt is stretched between a primary transfer roller 6, a secondary transfer roller 7, and a drive roller 8, and is sandwiched between the photoreceptor 1 and the primary transfer roller 6. The vehicle travels in the direction of the arrow x. The image formed on the photoreceptor 1 is transferred to the belt main body 5 that is an intermediate transfer belt at the position of the primary transfer port 1 and then transferred to the recording paper 12 at the position of the secondary transfer roller 7. Further, after the primary transfer, the toner remaining on the photosensitive member 1 is collected by the cleaning unit 10, and then the surface of the photosensitive member 1 is discharged by the eraser lamp 11.

このようにベルト本体5は複数の小径ローラに掛け渡して走行されるので、蛇行が生じやすいという問題点を有している。そこで広幅の中間転写ベルトでは、図1に示すようにベルト本体5の内周面の幅方向両端部に沿って、柔軟材料からなる蛇行防止用のリブ状のガイド材22を設けることが多い。   As described above, the belt body 5 travels over a plurality of small-diameter rollers, and therefore has a problem that meandering is likely to occur. Therefore, in a wide intermediate transfer belt, as shown in FIG. 1, a rib-shaped guide material 22 made of a flexible material for preventing meandering is often provided along both ends in the width direction of the inner peripheral surface of the belt body 5.

このような軟質材料からなるガイド材を設ける方法としては、ベルト本体(半導電性ベルト)を成形する際、ベルト本体と同じ材料で同時に一体に設けることが理想であり、従来、半導電性ベルトの内面の幅方向端部にガイド材に対応した凹溝を形成した型板を押し当て、この凹溝にガイド部材の材料、例えばシリコンゴムや液状ウレタン形成液を注入し、直接にベルト本体にガイド部材を設ける試みがなされている。しかし、これらの注入方法では注入した材料が硬化するまで型板を固定保持することが必要になり、生産性が悪く実用化されている例は少ない。   As a method of providing a guide material made of such a soft material, it is ideal to form a belt main body (semiconductive belt) at the same time using the same material as the belt main body. Press the template that has a groove corresponding to the guide material to the end in the width direction of the inner surface, and inject the material of the guide member, such as silicon rubber or liquid urethane forming liquid, into the groove, and directly into the belt body Attempts have been made to provide guide members. However, in these injection methods, it is necessary to fix and hold the template until the injected material is cured, and there are few examples in which productivity is poor and practical use.

予めガイド材を形成しておき、接着剤を用いてベルト本体に接着する試みも種々なされており、例えば、JIS−A硬度が30〜95度でテーパー摩耗に優れるシートに補強基材を接着し、スリッター等で細幅の基材付きガイド材を形成し、エンドレスベルト(ベルト本体)に接着する技術が開示されている(例えば、特許文献1参照)。また、JIS−A硬度60度以下、好ましくは50度以下の柔軟なガイド材の接着面に凹部を設けて凹凸を形成し、凸部及び凹部に反応型接着剤を塗布・充填し、凸部の薄い塗布膜で初期接着力を確保し、凹部に充填した反応型接着剤を徐々に硬化させて接着力を確保する技術が公開されている(例えば、特許文献2参照)。   Various attempts have been made to form a guide material in advance and bond it to the belt body using an adhesive. For example, a reinforcing base material is bonded to a sheet having a JIS-A hardness of 30 to 95 degrees and excellent taper wear. A technique of forming a narrow guide material with a base material using a slitter or the like and bonding it to an endless belt (belt body) is disclosed (for example, see Patent Document 1). Further, a concave portion is formed on the adhesive surface of a flexible guide material having a JIS-A hardness of 60 degrees or less, preferably 50 degrees or less, and irregularities are formed, and a reactive adhesive is applied and filled into the convex portions and concave portions. A technique for securing an initial adhesive force with a thin coating film and ensuring the adhesive force by gradually curing a reactive adhesive filled in a recess has been disclosed (for example, see Patent Document 2).

また、軟質フイルムからなるベルト本体に、予め弾性体で形成されたガイド材を、芯材入り両面感圧粘着テープと接着剤とを併用して接合する技術が開示されている(例えば、特許文献3、特許文献4参照)。
特開平8−99706号公報 特開平11−338175号公報 特許公開2000−75728号公報 特許公開2000−131999号公報
Further, a technique is disclosed in which a guide material previously formed of an elastic body is joined to a belt body made of a soft film by using a double-sided pressure-sensitive adhesive tape containing a core material and an adhesive in combination (for example, a patent document). 3, see Patent Document 4).
JP-A-8-99706 Japanese Patent Laid-Open No. 11-338175 Japanese Patent Publication No. 2000-75728 Japanese Patent Publication No. 2000-131999

しかし、特許文献1に記載のガイド部材はその構成が複雑でコストが高く実用性に乏しく、接着部に補強基材が介在するために、繰り返し屈曲により亀裂を生じやすいという問題がある。特許文献2では、接着面の凹凸への接着剤の充填むらや、硬化反応のむらを生じやすく、また、硬化完了まで時間が掛かり過ぎ、しかもガイド材が柔軟なため蛇行横圧に耐えられないという問題がある。特許文献3および特許文献4のものは、感圧粘着テープの粘着力のみでは複数の小径ローラに掛け渡して使用する場合の繰り返し屈曲に耐えられず剥離を生じやすく、また、感圧粘着テープと接着剤を併用するものも、ベルト本体との剛性や熱収縮の差によりガイド材の無い側のベルト表面に波打を生じたり、前述の繰り返し屈曲により粘着テープと接着剤の境目より亀裂が入りやすいという問題を有している。   However, the guide member described in Patent Document 1 has a problem that its configuration is complicated, costly, and impractical, and a reinforcing base material is interposed in the bonded portion, so that cracks are likely to occur due to repeated bending. According to Patent Document 2, unevenness of the adhesive on the unevenness of the adhesive surface and unevenness of the curing reaction are likely to occur, it takes too long to complete the curing, and the guide material is flexible and cannot withstand meandering lateral pressure. There's a problem. In Patent Document 3 and Patent Document 4, the pressure-sensitive adhesive tape alone does not withstand repeated bending when used over a plurality of small-diameter rollers, and easily peels. Even those that use an adhesive also cause undulations on the belt surface on the side without the guide material due to differences in rigidity and thermal shrinkage from the belt body, or cracks occur at the boundary between the adhesive tape and adhesive due to the above-mentioned repeated bending. It has the problem of being easy.

一方、近年、電子写真の高解像度化の要求から、液体トナーを用いることが検討されており、前記の特許文献等に記載のガイド材の接着方法では、トナーを分散する溶媒に対する接着低下が問題になっている。   On the other hand, in recent years, the use of liquid toner has been studied due to the demand for higher resolution in electrophotography. In the guide material adhering method described in the above-mentioned patent documents and the like, there is a problem of lower adhesion to the solvent in which the toner is dispersed. It has become.

これらの問題点を解消するために本発明は、ベルト走行時の蛇行横圧に耐え、かつ小径プーリでの繰り返し屈曲にも耐えられ、しかも液体トナーに対しても接着力の低下が少ない接着層を備えたガイド付き半導電性ベルトおよびその製造方法を提供することを目的とする。   In order to solve these problems, the present invention provides an adhesive layer that can withstand meandering lateral pressure during belt running, can withstand repeated bending with a small-diameter pulley, and has little decrease in adhesion to liquid toner. It is an object of the present invention to provide a semiconductive belt with guide and a method for manufacturing the same.

上記した課題を解決するために請求項1に記載のガイド付き半導電性ベルトは、薄肉円筒体であるベルト本体の内面にガイド材を設けて電子写真装置に使用され、前記ガイド材がJIS−A硬度65〜90度である熱可塑性ポリウレタンエラストマーを押出成形したものであり、このガイド材を前記ベルト本体の内面に2液性ポリウレタン接着剤によって接着していることを特徴とする。   In order to solve the above problems, the semiconductive belt with guide according to claim 1 is used in an electrophotographic apparatus by providing a guide material on the inner surface of a belt main body which is a thin cylindrical body, and the guide material is JIS- A thermoplastic polyurethane elastomer having an A hardness of 65 to 90 degrees is extruded, and this guide material is bonded to the inner surface of the belt body with a two-component polyurethane adhesive.

ガイド材は、転写画像に乱れを生じる原因となるベルト走行時の蛇行を防止することを目的とする。半導電性ベルトとは、ベルト本体の内面と外側面との間の体積抵抗値が
104〜1011Ω・cmであるベルトをいう。
The purpose of the guide material is to prevent meandering during belt running, which causes disturbance in the transferred image. The semiconductive belt refers to a belt having a volume resistance value of 10 4 to 10 11 Ω · cm between the inner surface and the outer surface of the belt body.

ベルト本体の厚みとガイド材との寸法関係は、ベルト本体の厚みが0.1〜1.0mmである場合に、ガイド材高さh(mm)は、0.3≦h≦ベルト本体厚み×3であり、特にベルト本体厚みが0.3〜0.5mmでは、ガイド高さ(mm)=(ベルト本体厚み)×1.5〜2.0であることが好ましい。ベルト走行時、駆動ローラおよび従動ローラの部分においてガイド材がベルト本体に追従して、即ち、ベルト本体の外側面の形状に変化(歪み)を与えずスムーズに屈曲走行させるためである。   Regarding the dimensional relationship between the thickness of the belt body and the guide material, when the thickness of the belt body is 0.1 to 1.0 mm, the guide material height h (mm) is 0.3 ≦ h ≦ belt body thickness × In particular, when the belt body thickness is 0.3 to 0.5 mm, it is preferable that the guide height (mm) = (belt body thickness) × 1.5 to 2.0. This is because when the belt is running, the guide material follows the belt body at the driving roller and the driven roller, that is, smoothly changes the shape of the outer surface of the belt body without causing any change (distortion).

ガイド材の断面形状は、ベルトの蛇行が防止できればよく特に限定されず、例えば、矩形、台形、半丸形などが用いられる。このガイド材硬度はJIS−A65度より低くなるにつれてベルトの蛇行横圧に負けて変形や乗り上げを生じ易くなり、安定した転写画像が得にくくなる。また、ガイド材硬度がJIS−A90度を超えると小径の駆動ローラまたは従動ローラ等に追従しにくく走行が不安定になり、やはり安定した画像が得られにくくなる。   The cross-sectional shape of the guide material is not particularly limited as long as the belt can be prevented from meandering. For example, a rectangular shape, a trapezoidal shape, a semicircular shape, or the like is used. As the guide material hardness is lower than JIS-A 65 degrees, the belt is subject to the meandering lateral pressure of the belt, and is likely to be deformed and climbed, making it difficult to obtain a stable transfer image. Further, if the guide material hardness exceeds JIS-A 90 degrees, it is difficult to follow the small-diameter driving roller or the driven roller, and the traveling becomes unstable, so that it is difficult to obtain a stable image.

ガイド材として、熱可塑性ポリウレタンの押出成形品を用いるのは、前記の硬度で引張強度が大きく、耐屈曲性、耐摩耗性に富み、寸法精度が良好で量産性に優れたガイド材が得られ易いからである。   As the guide material, an extruded product of thermoplastic polyurethane is used to obtain a guide material that has the above-mentioned hardness, high tensile strength, excellent bending resistance and wear resistance, good dimensional accuracy, and excellent mass productivity. It is easy.

このガイド材をベルト本体に接着する接着剤として、2液性ポリウレタン系接着剤を用いることにより、種々のベルト材料(ゴム、樹脂)に接着しやすく、接着力および接着層の物性に優れ、かつ柔軟で繰返し屈曲に強い接着が得られる。   By using a two-component polyurethane adhesive as an adhesive for adhering this guide material to the belt body, it is easy to adhere to various belt materials (rubber, resin), has excellent adhesive strength and physical properties of the adhesive layer, and Adhesive that is flexible and resistant to repeated bending can be obtained.

請求項2に記載の電子写真装置用半導電性ベルトは、前記ベルト本体の少なくとも前記ガイド材接着面が熱硬化ポリウレタンからなることを特徴とする。ベルト本体、接着剤およびガイドがともにウレタン結合を有するため、これらの間の接着力が大きく、線膨張係数の差が小さいので、雰囲気温度(室温)が低温から高温まで変化しても、収縮差を生じにくく、ベルト本体表面に歪み、波打ちなどの外観異常が生じなく、接着力が安定する。   The electroconductive belt for an electrophotographic apparatus according to claim 2 is characterized in that at least the guide material bonding surface of the belt body is made of thermosetting polyurethane. Since the belt body, adhesive and guide all have urethane bonds, the adhesive strength between them is large and the difference in coefficient of linear expansion is small, so even if the ambient temperature (room temperature) changes from low to high, there is a difference in shrinkage. The appearance of the belt main body surface is not distorted and undulated, and the adhesive force is stabilized.

請求項3に記載のガイド付き半導電性ベルトは、前記2液性ポリウレタン系接着剤が、ジフェニルメタンジイソシアネート、アジピン酸エステルおよび1,4ブタンジオールからなるポリウレタンを、酢酸エチル、メチルエチルケトン、トルエンの混合溶媒に溶解した主剤と、トリスー(バライソシアネート−フェニル)−チオフオスフエートを酢酸エチルに溶解した硬化剤とからなることを特徴とする。   The guide semiconductive belt according to claim 3, wherein the two-component polyurethane adhesive is a polyurethane composed of diphenylmethane diisocyanate, adipic acid ester and 1,4 butanediol, and a mixed solvent of ethyl acetate, methyl ethyl ketone, and toluene. And a curing agent obtained by dissolving tris- (rose isocyanate-phenyl) -thiophosphite in ethyl acetate.

この接着剤を用いることにより、ベルト本体とガイド材との接着するとき短時間で十分な初期接着力が得られ、熟成後の接着剤層そのものの耐引裂き性、抗張力などの物性が良好で、かつ柔軟性に富むものとなり、外径が15〜25mmという小径の駆動ローラ、従動ローラなどにも追従し屈曲して接着剥離を生じ難い。   By using this adhesive, sufficient initial adhesive force can be obtained in a short time when the belt body and the guide material are bonded, and the adhesive layer itself after aging has good physical properties such as tear resistance and tensile strength, Moreover, it becomes rich in flexibility, and hardly follows the bending of a driving roller or a driven roller having a small outer diameter of 15 to 25 mm, and hardly causes adhesive peeling.

この接着剤は、主剤と硬化剤とを使用直前に混合し、ベルト本体またはガイド材の接着部に塗布し、指を触れて粘着しない程度(指触不粘着という)である半乾燥状態まで乾燥させることにより、これらを圧接して所定期間保管しても「ずれ」を生じない初期接着力が得られる。これを室温や40〜70℃の雰囲気中で熟成することにより強い接着力が得られる。   This adhesive is mixed with the main agent and curing agent just before use, applied to the belt body or the adhesive part of the guide material, and dried to a semi-dry state where it does not stick to the fingers (referred to as non-stick to the touch). By doing so, it is possible to obtain an initial adhesive force that does not cause “displacement” even if they are pressed and stored for a predetermined period. A strong adhesive force can be obtained by aging this in an atmosphere of room temperature or 40 to 70 ° C.

請求項4に記載のガイド付き半導電性ベルトは、前記電子写真装置が液状トナーを使用する方式でその中間転写ベルトとして使用されることを特徴とする。ベルト本体、接着剤、ガイド材がともに、液状トナーの溶媒として使用されるn−ドデカンに侵され難い材料であり、液状トナーの直接接触する中間転写ベルトとして特に好ましく用いられる。   The semiconductive belt with guide according to claim 4 is characterized in that the electrophotographic apparatus is used as an intermediate transfer belt in a system using liquid toner. The belt body, the adhesive, and the guide material are all materials that are difficult to be affected by n-dodecane used as a solvent for the liquid toner, and are particularly preferably used as an intermediate transfer belt in direct contact with the liquid toner.

請求項5に記載のガイド付き半導電性ベルトの製造方法は、薄肉円筒体であるベルト本体の内面にガイド材を設けた電子写真装置に使用されるガイド付き半導電性ベルトの製造方法であって、予め、JIS−A硬度65〜90度の熱可塑性ポリウレタンエラストマーを押出し成形してガイド材を成形した後、前記ベルト本体を、その一部に下面がスライド板で支持する水平移動部を形成するように複数のガイドローラに掛渡して走行させながら、前記水平移動部において前記ベルト本体の内面の幅方向端部に沿って、主剤と硬化剤とを混合してなる2液性ポリウレタン接着剤を塗布し、温風を吹き付けて半乾燥し、この半乾燥した接着剤面に前記ガイド材を圧着ローラを介して走行させながら圧着することを特徴とする。   The method for producing a semiconductive belt with guide according to claim 5 is a method for producing a semiconductive belt with guide used in an electrophotographic apparatus in which a guide material is provided on the inner surface of a belt main body which is a thin cylindrical body. In advance, a guide material is formed by extruding a thermoplastic polyurethane elastomer with a JIS-A hardness of 65 to 90 degrees, and then the belt main body is formed with a horizontal moving part whose lower surface is supported by a slide plate. The two-component polyurethane adhesive formed by mixing the main agent and the curing agent along the widthwise end portion of the inner surface of the belt main body in the horizontal moving portion while running over a plurality of guide rollers. Is applied, and hot air is blown and semi-dried, and the guide material is bonded to the semi-dried adhesive surface while running through a pressure roller.

この製造方法によると、ガイド材をベルト本体に接着するとき、ガイド材に70℃以上の熱を掛けることは無く、殆ど常温で接着でき、加圧も瞬間的に終了するので、接着によりベルト本体が波打ちしたり、熱劣化することが無く、しかも加熱・冷却時間も不用なため、効率よくガイド材をベルト本体に接着することができる。   According to this manufacturing method, when the guide material is bonded to the belt body, the guide material is not heated at 70 ° C. or more, can be bonded almost at normal temperature, and pressurization is instantaneously terminated. Since there is no undulation or heat deterioration, and the heating / cooling time is unnecessary, the guide material can be efficiently bonded to the belt body.

請求項6に記載のガイド付き半導電性ベルトの製造方法は、前記圧着ローラにより前記ガイド材をベルト本体に押しつける線圧が10〜20N/cmで、温風の温度を25〜75℃とし指触不粘着に半乾燥することを特徴とする。ガイド材をベルト本体に押しつける力、即ち、圧着ローラとスライド板との間の線圧が10N/cm未満になると、移動中にガイド材がずれたり密着不足になったりすることがあり、20N/cmを超えるとガイド材が変形することがある。また、温風温度が25℃未満では半乾燥するために長時間を要し、75℃を超えるとベルト本体の波打ちが発生する恐れがある。   The method for manufacturing a semiconductive belt with guide according to claim 6 is characterized in that a linear pressure for pressing the guide material against the belt body by the pressure roller is 10 to 20 N / cm, and the temperature of the hot air is 25 to 75 ° C. It is characterized by being semi-dry to the touch-free adhesive. If the force for pressing the guide material against the belt body, that is, the linear pressure between the pressure roller and the slide plate is less than 10 N / cm, the guide material may be displaced during the movement or the contact may be insufficient. If it exceeds cm, the guide material may be deformed. Further, when the hot air temperature is less than 25 ° C., it takes a long time to be semi-dried, and when it exceeds 75 ° C., the belt body may be wavy.

以上説明したことから明らかなように、本発明の電子写真装置用半導電性ベルトは、ガイド材の硬度を高くすることにより、ベルト走行時の横方向の力に対して変形が少なく、蛇行を防止できる。ベルト本体のガイド材取り付け面、ガイド材、接着層の材質をウレタン系材料に統一することにより接着力が高く、走行による繰り返し屈曲に対する耐久性に優れ、また、液体トナーを使用する電子写真装置の中間転写ベルトとして使用されても、その分散溶媒に侵されることがない。   As is apparent from the above description, the semiconductive belt for an electrophotographic apparatus of the present invention is less deformed with respect to the lateral force when the belt travels by increasing the hardness of the guide material, and is meandering. Can be prevented. The adhesive material of the belt body, the guide material, and the adhesive layer are unified with urethane material, so that the adhesive strength is high, the durability against repeated bending by running is excellent, and the electrophotographic apparatus using liquid toner Even when used as an intermediate transfer belt, it is not affected by the dispersion solvent.

さらに、請求項5に記載のガイド付き半導電性ベルトの製造方法では、75℃以下の温度で接着することができるので、ベルト本体に波打ちを生じたり、ガイド材を熱劣化させることなく、効率よくガイド材をベルト本体に接着することができる。   Furthermore, in the method for manufacturing a semiconductive belt with a guide according to claim 5, since it can be bonded at a temperature of 75 ° C. or less, the belt main body is not corrugated or the guide material is not thermally deteriorated. The guide material can be well adhered to the belt body.

本発明の電子写真装置用半導電性ベルトは、遠心成型法によりJIS−A硬度が65度〜90度である熱硬化性ポリウレタンであるベルト本体を形成し、JIS−A硬度が65度から90度である熱可塑性ポリウレタンエラストマーを断面矩形に押出成形したガイド材を、前記ベルト本体の内面に2液性ポリウレタン系接着剤によって接着している。この2液性ポリウレタン系接着剤は、ジフェニルメタンジイソシアネート、アジピン酸エステルおよび1,4ブタンジオールからなるポリウレタンを、酢酸エチル、メチルエチルケトンおよびトルエンの混合溶媒に溶解した主剤と、トリス−(バライソシアネート−フェニル)−チオフオスフエートを酢酸エチルに溶解した硬化剤とからなる。ベルト本体のガイド材取り付け面、ガイド材、接着層が同一系統の材料からなることにより、繰り返し屈曲耐久性に優れ、特に、液状トナーを用いた電子写真装置の中間転写ベルトとして好適に使用される。   The semiconductive belt for an electrophotographic apparatus of the present invention forms a belt body which is a thermosetting polyurethane having a JIS-A hardness of 65 to 90 degrees by centrifugal molding, and the JIS-A hardness is 65 to 90 degrees. A guide material obtained by extruding a thermoplastic polyurethane elastomer having a rectangular cross section is bonded to the inner surface of the belt body with a two-component polyurethane adhesive. This two-component polyurethane adhesive is composed of a main agent obtained by dissolving polyurethane composed of diphenylmethane diisocyanate, adipic acid ester and 1,4 butanediol in a mixed solvent of ethyl acetate, methyl ethyl ketone and toluene, and tris- (baraisocyanate-phenyl). -Consisting of a curing agent in which thiosophate was dissolved in ethyl acetate. Because the guide material mounting surface, guide material, and adhesive layer of the belt body are made of the same material, it is excellent in repeated bending durability, and is particularly suitable as an intermediate transfer belt for electrophotographic apparatuses using liquid toner. .

なお、ガイド付き半導電性ベルトの製造方法は、ガイド材の接着面またはベルト本体の接着面に前記2液性ポリウレタン系接着剤を塗布し、温風を吹き付けて半乾燥状態として初期接着力を生じさせ、ガイド材を圧着ローラを介して加圧送りして仮接着した後、熟成して完全接着させる。   In addition, the method for producing a semiconductive belt with a guide is such that the two-component polyurethane adhesive is applied to the adhesive surface of the guide material or the adhesive surface of the belt body, and warm air is blown to obtain a semi-dried state to obtain the initial adhesive strength. The guide material is pressure-fed through a pressure roller and temporarily bonded, and then aged and completely bonded.

以下、本発明に係る電子写真装置用半導電性ベルトの実施例、比較例について説明する。   Examples of the semiconductive belt for an electrophotographic apparatus according to the present invention and comparative examples will be described below.

まず、ベルト本体を次のように作成した。ポリエステルポリオール(日本ポリウレタン工業社製、商品名:ニッポラン141、水酸基価=108KOHmg/g)70重量部と導電性フィラーとして導電性カーボンブラック(三菱化成社製、商品名:3030B)3重量部とを混合・分散した後、鎖延長剤として低分子量芳香族ジアミン化合物(住化バイエルウレタン社製、商品名:バイテック1604、アミン当量=120)30重量部を混合して100℃で加熱・溶解した後、100℃で12時間、真空脱水した。   First, the belt body was made as follows. 70 parts by weight of polyester polyol (manufactured by Nippon Polyurethane Industry Co., Ltd., trade name: NIPPOLAN 141, hydroxyl value = 108 KOHmg / g) and 3 parts by weight of conductive carbon black (trade name: 3030B, manufactured by Mitsubishi Kasei Co., Ltd.) as a conductive filler After mixing and dispersing, 30 parts by weight of a low molecular weight aromatic diamine compound (manufactured by Sumika Bayer Urethane Co., Ltd., trade name: Vitec 1604, amine equivalent = 120) as a chain extender is mixed and heated and dissolved at 100 ° C. And vacuum dehydration at 100 ° C. for 12 hours.

これに硬化剤として脂肪酸イソシアネートのブレンド物(三井武田ウレタン社製、商品名:NBDIと、住化バイエルウレタン社製、商品名:スミジュール・N3300とを、重量比でNBDI/スミジュール・N3300=65/35にブレンドしたもの)を40℃に加熱・混合し、120℃に加熱され1000rpmで回転する遠心成形機の円筒金型(内径=170mm、幅=400mm)に注入した。10分後に回転数を500rpmに落とし、20分間回転を続けた後、脱型して、120℃で約12時間熟成し、幅270mmにカットして、弾性体からなる厚み0.5mm、外周長780mmの薄肉円筒体であるベルト本体を得た。   As a curing agent, a blend of fatty acid isocyanate (made by Mitsui Takeda Urethane Co., Ltd., trade name: NBDI and Sumika Bayer Urethane Co., Ltd., trade name: Sumijoule N3300), NBDI / Sumijoule N3300 by weight ratio = 65/35 blended) was heated and mixed at 40 ° C. and injected into a cylindrical mold (inner diameter = 170 mm, width = 400 mm) of a centrifugal molding machine heated to 120 ° C. and rotated at 1000 rpm. After 10 minutes, the rotation speed was reduced to 500 rpm, and the rotation was continued for 20 minutes. After that, the mold was removed, aged at 120 ° C. for about 12 hours, cut into a width of 270 mm, an elastic body having a thickness of 0.5 mm, an outer peripheral length. A belt main body having a thin cylindrical body of 780 mm was obtained.

別途、ガイド材として、熱可塑性ポリウレタンエラストマー(日本ミラクトラン社製、商品名:エラストラン・ET680)を断面矩形(厚み:1mm、幅:5mm)に押出成形してJIS−A硬度=80度であるガイド材を得た。   Separately, as a guide material, a thermoplastic polyurethane elastomer (manufactured by Nippon Milactran Co., Ltd., trade name: Elastollan / ET680) is extruded into a rectangular cross section (thickness: 1 mm, width: 5 mm), and JIS-A hardness = 80 degrees. A guide material was obtained.

さらに、接着剤として、ジフェニルメタンジイソシアネート、アジピン酸エステル及び1,4ブタンジオールからなるウレタンを酢酸エチル、メチルエチルケトンおよびトルエンの混合溶液に溶解した主剤と、トリス−(パライソシアネートフェニル)チオフォスフェートの酢酸エチル溶液である硬化剤とからなる2液性ポリウレタン系接着剤(バンドー化学社製、商品名:サンパット・C#1000セット)を用い、この主剤と硬化剤を重量比1:1で混合している。   Further, as an adhesive, a main agent obtained by dissolving urethane composed of diphenylmethane diisocyanate, adipic acid ester and 1,4 butanediol in a mixed solution of ethyl acetate, methyl ethyl ketone and toluene, and an ethyl acetate solution of tris- (paraisocyanate phenyl) thiophosphate The main component and the curing agent are mixed at a weight ratio of 1: 1 using a two-component polyurethane adhesive (trade name: Sunpat C # 1000 set, manufactured by Bando Chemical Co., Ltd.).

前記ベルト本体の内面側端部に前記接着剤を介して前記ガイド材を接着するガイド付き半導電性ベルトの製造方法を、図3に示す接着冶具の側面図を参考にして説明する。   A method of manufacturing a guided semiconductive belt in which the guide material is bonded to the inner surface side end portion of the belt body via the adhesive will be described with reference to a side view of the bonding jig shown in FIG.

スライド板30を上面がほぼ水平となるように設け、この上方に軸心が平行である3本のガイドローラ35,36,37(外径=30mm)を、下方の2本のガイドローラ35,37はスライド板30に当接、離間可能であって、他の1本のガイドローラ36はガイドローラ35,37の上方に、これらの軸心が側面から見て三角形をなす位置に配置している。さらに、これらの3本のガイドローラの内側に圧着ローラ31と、接着剤を塗布する塗布機32と接着剤を乾燥させるドライヤー33を備えている。なお、圧着ローラ31は、外径=30mm、幅=5mmであって、ガイド材22を圧着する位置に幅=5mmで深さ=0.9mmの溝部を有し、矢印yの方向に昇降できる。   The slide plate 30 is provided so that the upper surface is substantially horizontal, and above this, three guide rollers 35, 36, 37 (outer diameter = 30 mm) whose axis is parallel are disposed, and the two lower guide rollers 35, 37 can contact and be separated from the slide plate 30, and the other guide roller 36 is arranged above the guide rollers 35, 37 at a position where these shaft centers form a triangle when viewed from the side. Yes. Furthermore, a pressure roller 31, a coating machine 32 for applying an adhesive, and a dryer 33 for drying the adhesive are provided inside these three guide rollers. The pressure roller 31 has an outer diameter = 30 mm and a width = 5 mm, and has a groove portion with a width = 5 mm and a depth = 0.9 mm at a position where the guide material 22 is pressure-bonded, and can move up and down in the direction of the arrow y. .

これらを用いた接着手順は、まず、ベルト本体5を3本のガイドローラに懸回して下方のガイドローラ35,37をスライド板30に接近させることにより、ベルト本体5の一部をスライド板30に接触させ(この部分を水平移動部38という、長さ約180cm)、上方のガイドローラ36の位置を調整してベルトを緊張させて回転・走行させる。   The adhering procedure using them is as follows. First, the belt main body 5 is suspended around three guide rollers and the lower guide rollers 35 and 37 are brought close to the slide plate 30, so that a part of the belt main body 5 is moved to the slide plate 30. (This portion is called a horizontal moving portion 38, about 180 cm in length), the position of the upper guide roller 36 is adjusted, and the belt is tensioned to rotate and run.

圧着ローラ31を前記水平移動部38のベルト走行方向(矢印x)下流部分に設けて、ベルト本体5の内面をスライド板30に対して線圧15N/cmで押圧可能で、ベルト本体5を走行させながらスライド板30に圧接する。前記接着剤を充填した塗布機32は、水平移動部の圧着ローラ31のベルト走行方向上流側にあって、ベルト本体5の内面、幅方向一端部(ガイド材22の接着位置、図1参照)に沿って、幅約5.5mmに接着剤を塗布する。塗布された接着剤38は、ドライヤー33より噴出される温風(温度:約50℃)により指触不粘着に半乾燥される。この半乾燥された接着剤層39の上にガイド材22を供給して圧着ローラ31によりベルト本体5に接着する。ガイド材22をベルト本体5の内面に一周接着してガイド材22の残分をカットし、続けて、ベルト本体5の他端部に上記と同様にガイド材22を接着する。このガイド材22が接着されたベルト本体5を接着冶具から外し、約60℃で約12時間熟成してガイド付き半導電性ベルト(幅=270mm、内周長=700mm、厚み=0.5mm、両端部ガイド付き)を得た。   A pressure roller 31 is provided downstream of the horizontal movement portion 38 in the belt traveling direction (arrow x), and the inner surface of the belt body 5 can be pressed against the slide plate 30 with a linear pressure of 15 N / cm. And press-contacting the slide plate 30. The applicator 32 filled with the adhesive is on the upstream side in the belt running direction of the pressure roller 31 of the horizontal moving part, and is on the inner surface of the belt body 5 and one end in the width direction (bonding position of the guide material 22, see FIG. 1). Along the line, an adhesive is applied to a width of about 5.5 mm. The applied adhesive 38 is semi-dried so as not to touch with the hot air (temperature: about 50 ° C.) ejected from the dryer 33. The guide material 22 is supplied onto the semi-dried adhesive layer 39 and bonded to the belt body 5 by the pressure roller 31. The guide material 22 is bonded to the inner surface of the belt main body 5 once to cut the remainder of the guide material 22, and then the guide material 22 is bonded to the other end of the belt main body 5 in the same manner as described above. The belt body 5 to which the guide material 22 is bonded is removed from the bonding jig, and is aged at about 60 ° C. for about 12 hours to be a semiconductive belt with a guide (width = 270 mm, inner peripheral length = 700 mm, thickness = 0.5 mm, With both end guides).

このガイド材を接着した半導電性ベルト5の評価方法は次のとおりである。   The evaluation method of the semiconductive belt 5 to which the guide material is bonded is as follows.

1)接着力は、得られたガイド付き半導電性ベルトの幅方向端部(ガイド材を接着した部分)より、幅=5mm、長さ=150mmの試験片を切り出し、接着長さ50mm分を、ナイフで剥離させて接着試験片とし、引張試験機に180度剥離状態で取り付け、引張速度100mm/分で引張り、応力チャートより最高ピークを読みとった。結果を表1に示す。また、上記試験片を、液体トナーの代表的な分散溶媒であるn−ドデカンに浸漬し、浸漬1日後、1週間後の接着強度を測定した。結果を表1に示す。   1) Adhesive strength was obtained by cutting out a test piece having a width = 5 mm and a length = 150 mm from the width direction end portion (portion where the guide material was bonded) of the obtained semiconductive belt with guide, and reducing the adhesive length by 50 mm. Then, it was peeled off with a knife to form an adhesive test piece, attached to a tensile tester in a 180 degree peeled state, pulled at a pulling speed of 100 mm / min, and the highest peak was read from the stress chart. The results are shown in Table 1. The test piece was immersed in n-dodecane, which is a typical dispersion solvent for liquid toner, and the adhesive strength was measured after 1 day and 1 week after immersion. The results are shown in Table 1.

2)屈曲耐久性は、得られたガイド付き半導電性ベルトを、外径=25mmで長さ=260mmであって、両端の外径を23mmにされた2本のローラ(駆動ローラ、従動ローラ)からなる2軸試験機に、約5%伸張して取り付け、液体トナーをベルト本体に散布しながら、ベルト速度5m/分で走行し、接着部の状況を1時間ごとに100時間までチェックし、剥離発生までの時間を測定した。結果を表1に示す。なお、100時間経過しても剥離しない場合を100<と表示した。   2) Bending durability was obtained by using the obtained semiconductive belt with guide, two rollers (driving roller, driven roller) having an outer diameter = 25 mm, a length = 260 mm, and outer diameters at both ends of 23 mm. ), Stretched by about 5%, run at a belt speed of 5 m / min while spraying liquid toner on the belt body, and check the condition of the bonded part every hour for up to 100 hours. The time until peeling occurred was measured. The results are shown in Table 1. In addition, the case where it did not peel even if 100 hours passed was displayed as 100 <.

3)巻付時ベルト表面の評価は、屈曲耐久性評価用の2軸試験機にベルトを取り付けた時の、外径25mm、両端外径23mmのローラ部のベルト表面を目視観察し、凹凸、波打ちなどの無いものをOK、有るものを×と評価した。   3) The belt surface at the time of winding was evaluated by visually observing the belt surface of the roller portion having an outer diameter of 25 mm and both outer diameters of 23 mm when the belt was attached to a biaxial testing machine for bending durability evaluation. Those without undulation were evaluated as OK, and those with undulation were evaluated as x.

4)蛇行防止性としては、上記2軸試験機の幅方向中心を2mmずらせて走行させた時のローラの外径25mm部へのガイド材の乗り上げ有無を観察し、有りを×、無しをOKと評価した。   4) With respect to the meandering prevention, the presence or absence of the guide material on the outer diameter 25 mm of the roller when the biaxial testing machine is moved by shifting the center in the width direction by 2 mm is observed. It was evaluated.

ガイド材として、JIS−A硬度=90度の熱可塑性ポリウレタンエラストマーを用いた以外は実施例1と同様にしてガイド付き半導電性ベルトを製造し、実施例1と同様に評価した結果を表1に示す。   As a guide material, a semiconductive belt with a guide was produced in the same manner as in Example 1 except that a thermoplastic polyurethane elastomer having a JIS-A hardness of 90 degrees was used. The results of evaluation in the same manner as in Example 1 are shown in Table 1. Shown in

ガイド材として、JIS−A硬度=90度の熱可塑性ポリウレタンエラストマーを用いた以外は実施例1と同様にしてガイド付き半導電性ベルトを製造し、実施例1と同様に評価して結果を表1に示す。   A semiconductive belt with a guide was produced in the same manner as in Example 1 except that a thermoplastic polyurethane elastomer having a JIS-A hardness = 90 degrees was used as a guide material. It is shown in 1.

ベルト本体として、NBR(日本ゼオン社製、商品名:Nipol「DN401LL]=100重量部に導電性カーボン=10重量部、炭酸カルシウム=50重量部、亜鉛華=5重量部と、ステアリン酸、オイルサルファー、促進剤TET各1重量部とを混練りしたNBRゴム組成物を、内金型、外金型からなる円筒状金型に、トランスファー成形し加硫して、幅=270mmにカットしたものを用いた以外は、実施例1と同様ににしてガイド付き半導電性ベルトを製造し、実施例1と同様に評価して結果を表1に示す。   As a belt body, NBR (made by Nippon Zeon Co., Ltd., trade name: Nipol “DN401LL” = 100 parts by weight, conductive carbon = 10 parts by weight, calcium carbonate = 50 parts by weight, zinc white = 5 parts by weight, stearic acid, oil NBR rubber composition kneaded with 1 part by weight of sulfur and accelerator TET, transfer molded into a cylindrical mold consisting of an inner mold and an outer mold, vulcanized, and cut to a width of 270 mm A semiconductive belt with a guide was produced in the same manner as in Example 1 except that was used, and evaluated in the same manner as in Example 1 and the results are shown in Table 1.

(比較例1)
ガイド材として、JIS−A硬度60度の熱可塑性ポリウレタンエラストマーを押出成形したものを用いた以外は実施例1と同様にしてガイド付き半導電性ベルトを製造し、実施例1と同様に評価して結果を表2に示す。
(Comparative Example 1)
A semiconductive belt with a guide was produced in the same manner as in Example 1 except that a thermoplastic polyurethane elastomer having a JIS-A hardness of 60 degrees was used as the guide material, and an evaluation was conducted in the same manner as in Example 1. The results are shown in Table 2.

(比較例2)
ガイド材として、JIS−A硬度95度の熱可塑性ポリウレタンエラストマーを押出成形したものを用いた以外は実施例1と同様にしてガイド付き半導電性ベルトを製造し、実施例1と同様に評価して結果を表2に示す。
(Comparative Example 2)
A semiconductive belt with a guide was produced in the same manner as in Example 1 except that a thermoplastic polyurethane elastomer with a JIS-A hardness of 95 degrees was used as the guide material, and the same was evaluated as in Example 1. The results are shown in Table 2.

(比較例3)
ガイド材として、JIS−A硬度80度の熱可塑性ポリウレタンシートに厚さ0.2mmのPETフィルムを貼り付けた総厚1.0mmのシートを幅5mmにカットしたもの(栄和社製、商品名:HJ−0240)を用いた以外は、実施例と同様にしてガイド付き半導電性ベルトを製造し、実施例1と同様に評価して結果を表1に示す。
(Comparative Example 3)
As a guide material, a sheet having a total thickness of 1.0 mm obtained by bonding a PET film having a thickness of 0.2 mm to a thermoplastic polyurethane sheet having a JIS-A hardness of 80 degrees and cut to a width of 5 mm (trade name: manufactured by Eiwa Co., Ltd.) Except for using HJ-0240), a semiconductive belt with a guide was manufactured in the same manner as in the example, and evaluated in the same manner as in Example 1 and the results are shown in Table 1.

(比較例4)
ベルト本体とガイド材との接着剤として、アクリル系粘着テープ(住友3M社製、商品名:Y−4950)を用いた他は実施例1と同様にしてガイド付き半導電性ベルトを製造し、実施例1と同様に評価して結果を表2に示す。
(Comparative Example 4)
A semiconductive belt with a guide was produced in the same manner as in Example 1 except that an acrylic pressure-sensitive adhesive tape (manufactured by Sumitomo 3M, trade name: Y-4950) was used as an adhesive between the belt body and the guide material. Evaluation was conducted in the same manner as in Example 1, and the results are shown in Table 2.

(比較例5)
ベルト本体として、弾性体でなくポリカーボネートをチューブ状に押出成形したものを用いた他は、実施例1と同様にしてガイド付き半導電性ベルトを製造し、実施例1と同様に評価して結果を表2に示す。
(Comparative Example 5)
A semiconductive belt with a guide was manufactured in the same manner as in Example 1 except that polycarbonate was extruded into a tube shape instead of an elastic body as the belt body, and the results were evaluated and evaluated in the same manner as in Example 1. Is shown in Table 2.

Figure 2005157198
Figure 2005157198

Figure 2005157198
Figure 2005157198

本発明の実施例にかかるガイド付き半導電性ベルトの斜視図を示す。The perspective view of the semiconductive belt with a guide concerning the Example of this invention is shown. 本発明の実施例にかかるガイド付き半導電性ベルト(中間転写ベルト5)が組み込まれた電子写真装置の側面図である。FIG. 3 is a side view of an electrophotographic apparatus in which a guided semiconductive belt (intermediate transfer belt 5) according to an embodiment of the present invention is incorporated. 本発明の実施例にかかるガイド付き半導電性ベルトの製造方法に使用する接着冶具の概要を説明する側面図である。It is a side view explaining the outline | summary of the adhesion jig used for the manufacturing method of the semiconductive belt with a guide concerning the Example of this invention.

符号の説明Explanation of symbols

1:感光体
5:ベルト本体
6,6’:ガイドロール
12:記録材
22:ガイド材
25:ガイド付き半導電性ベルト
30:スライド板
31:圧着ローラ
32:接着剤塗布機
33:ドライヤー
35,36,37:ガイドローラ
38:水平移動部
39:接着剤
1: Photosensitive member 5: Belt body 6, 6 ': Guide roll 12: Recording material 22: Guide material 25: Semiconductive belt with guide 30: Slide plate 31: Pressure roller 32: Adhesive applicator 33: Dryer 35 36, 37: Guide roller 38: Horizontal moving part 39: Adhesive

Claims (6)

薄肉円筒体であるベルト本体の内面にガイド材を設けた電子写真装置に使用されるガイド付き半導電性ベルトであって、
前記ガイド材がJIS−A硬度65〜90度である熱可塑性ポリウレタンエラストマーを押出成形したものであり、このガイド材を前記ベルト本体の内面に2液性ポリウレタン接着剤によって接着していることを特徴とするガイド付き半導電性ベルト。
A semiconductive belt with a guide used in an electrophotographic apparatus in which a guide material is provided on the inner surface of a belt body which is a thin cylindrical body,
The guide material is formed by extruding a thermoplastic polyurethane elastomer having a JIS-A hardness of 65 to 90 degrees, and the guide material is bonded to the inner surface of the belt body with a two-component polyurethane adhesive. Guided semi-conductive belt.
前記ベルト本体の少なくとも前記ガイド材接着面が熱硬化性ポリウレタンからなる請求項1に記載のガイド付き半導電性ベルト。   The semiconductive belt with guide according to claim 1, wherein at least the guide material adhesion surface of the belt body is made of thermosetting polyurethane. 前記2液性ポリウレタン系接着剤が、ジフェニルメタンジイソシアネート、アジピン酸エステルおよび1,4ブタンジオールからなるポリウレタンを、酢酸エチル、メチルエチルケトン、トルエンの混合溶媒に溶解した主剤と、トリス−(バライソシアネート−フェニル)−チオフオスフエートを酢酸エチルに溶解した硬化剤とからなる請求項1または2に記載のガイド付き半導電性ベルト。   The two-component polyurethane adhesive comprises a main agent obtained by dissolving polyurethane composed of diphenylmethane diisocyanate, adipic acid ester and 1,4 butanediol in a mixed solvent of ethyl acetate, methyl ethyl ketone, and toluene; and tris- (baraisocyanate-phenyl). The semiconductive belt with guide according to claim 1 or 2, comprising: a curing agent obtained by dissolving thiosophate in ethyl acetate. 前記電子写真装置が液状トナーを使用する方式でその中間転写ベルトとして使用される請求項1〜3のいずれかに記載のガイド付き半導電性ベルト。   4. The semiconductive belt with guide according to claim 1, wherein the electrophotographic apparatus is used as an intermediate transfer belt in a system using liquid toner. 薄肉円筒体であるベルト本体の内面にガイド材を設けた電子写真装置に使用されるガイド付き半導電性ベルトの製造方法であって、
予め、JIS−A硬度65〜90度の熱可塑性ポリウレタンエラストマーを押出し成形してガイド材を成形した後、前記ベルト本体を、その一部に下面をスライド板で支持する水平移動部を形成するように複数のガイドローラに掛渡して走行させながら、前記水平移動部において前記ベルト本体の内面の幅方向端部に沿って主剤と硬化剤とを混合してなる2液性ポリウレタン接着剤を塗布し、つづいて温風を吹き付けて半乾燥し、この半乾燥した接着剤面に前記ガイド材を圧着ローラを介して走行させながら圧着することを特徴とするガイド付き半導電性ベルトの製造方法。
A method for producing a semiconductive belt with a guide used in an electrophotographic apparatus provided with a guide material on the inner surface of a belt body which is a thin cylindrical body,
A guide material is formed by extruding a thermoplastic polyurethane elastomer having a JIS-A hardness of 65 to 90 degrees in advance, and then the belt main body is formed with a horizontal moving portion in which a lower surface is supported by a slide plate. The two-component polyurethane adhesive formed by mixing the main agent and the curing agent is applied along the widthwise end portion of the inner surface of the belt main body in the horizontal moving portion while running over a plurality of guide rollers. A method for producing a semiconductive belt with guide, characterized in that hot air is blown and semi-dried, and the guide material is pressure-bonded to the semi-dried adhesive surface while running through a pressure roller.
前記圧着ローラにより前記ガイド材をベルト本体に押しつける線圧が10〜20N/cmで、前記温風の温度を25〜75℃とし指触により付着しない程度に半乾燥する請求項5に記載のガイド付き半導電性ベルトの製造方法。
The guide according to claim 5, wherein a linear pressure for pressing the guide material against the belt main body by the pressure roller is 10 to 20 N / cm, the temperature of the hot air is 25 to 75 ° C, and it is semi-dried to the extent that it does not adhere to the finger. Method for manufacturing a semiconductive belt with a tape.
JP2003398988A 2003-11-28 2003-11-28 Guide attached semiconductive belt and method for manufacturing the same Pending JP2005157198A (en)

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* Cited by examiner, † Cited by third party
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JP2015096930A (en) * 2013-11-17 2015-05-21 槌屋ティスコ株式会社 Meandering prevention member and manufacturing method of the same
CN109196245A (en) * 2016-06-06 2019-01-11 三之星机带株式会社 Toothed belt and its manufacturing method
US11300177B2 (en) 2016-06-06 2022-04-12 Mitsuboshi Belting Ltd. Toothed belt and manufacturing method therefor
JP2022105094A (en) * 2016-07-11 2022-07-12 ダウ グローバル テクノロジーズ エルエルシー Two-component adhesive compositions and methods of making the same

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015096930A (en) * 2013-11-17 2015-05-21 槌屋ティスコ株式会社 Meandering prevention member and manufacturing method of the same
CN109196245A (en) * 2016-06-06 2019-01-11 三之星机带株式会社 Toothed belt and its manufacturing method
CN109196245B (en) * 2016-06-06 2020-10-16 三之星机带株式会社 Toothed belt and method for manufacturing same
US11300177B2 (en) 2016-06-06 2022-04-12 Mitsuboshi Belting Ltd. Toothed belt and manufacturing method therefor
JP2022105094A (en) * 2016-07-11 2022-07-12 ダウ グローバル テクノロジーズ エルエルシー Two-component adhesive compositions and methods of making the same

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