JP2005145516A - Biaxially drawn blow molded bottle - Google Patents

Biaxially drawn blow molded bottle Download PDF

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JP2005145516A
JP2005145516A JP2003386388A JP2003386388A JP2005145516A JP 2005145516 A JP2005145516 A JP 2005145516A JP 2003386388 A JP2003386388 A JP 2003386388A JP 2003386388 A JP2003386388 A JP 2003386388A JP 2005145516 A JP2005145516 A JP 2005145516A
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peripheral wall
wall
molded
bottle
ridge
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JP4570019B2 (en
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Yoshinori Sato
嘉則 佐藤
Tatsuya Nozaki
達也 野崎
Mie Ota
美恵 太田
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Dai Nippon Printing Co Ltd
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Dai Nippon Printing Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a biaxially drawn blow molded bottle, whose bottom is not deformed to sag and keep unstable under gravity and heat from a content when the bottle as a plastic container is filled with a drink, heated with a hot warmer or the like, and is served to a consumer. <P>SOLUTION: The biaxially drawn blow molded bottle has a cave-in part, which caves in toward the bottle interior at the center of the bottom of the bottle, and consists of a tapered peripheral wall sloping toward the bottle interior and a top wall continuous with the upper end of the peripheral wall. The tapered peripheral wall consists of a plurality of peripheral wall portions, which are continuous with each other and slope against the ground surface of the bottle at respective different angles to give the peripheral wall a shape similar to that of the side wall of a wine glass. In the cave-in part, the distance between the ground surface of the bottle and the top wall is 25 to 40% of the trunk diameter of the bottle, and the diameter of a ground ring formed at the lower end of the cave-in part is 50 to 75% of the trunk diameter. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、ポリエチレンテレフタレート樹脂などを用いた2軸延伸吹込成形壜に関し、更に詳しくはホットウォーマー等による加温に耐え得る底部構造を有する2軸延伸吹込成形壜に関する。   The present invention relates to a biaxially-stretched blow-molded cage using a polyethylene terephthalate resin or the like, and more particularly to a biaxially-stretched blow-molded kit having a bottom structure that can withstand warming by a hot warmer or the like.

一般に、飲料をプラスチック容器に充填し、ホットウォーマー機器等によって加温して、消費者に提供することが広く行われている。   In general, a beverage is filled in a plastic container, heated by a hot warmer device or the like, and provided to consumers.

また、ポリエチレンテレフタレート等からなる2軸延伸吹込成形壜では、図13に従来品の断面図を示し、図14にその底面図を示すように、底部21の中央部分を周壁22を介して壜内部23に陥没させて、壜に自立性を付与している。しかし、2軸延伸吹込成形壜21は、壜の側壁24に比べて延伸が不足がちであるため、液体内容物が高温に加熱されると、内容物からの重力と熱の影響を受けて陥没部25が壜の接地面に到達するほど下方に垂れ下がり壜の座りが悪くなりやすい(特許文献1参照)。
特開平第8−104313号公報
In addition, in a biaxially stretched blow molded cage made of polyethylene terephthalate or the like, FIG. 13 shows a cross-sectional view of a conventional product, and FIG. 14 shows a bottom view thereof. 23 is depressed, and the independence is given to the bag. However, since the biaxially stretched blow-molded bowl 21 tends to be insufficiently stretched compared to the side wall 24 of the bowl, when the liquid content is heated to a high temperature, it is affected by gravity and heat from the contents. As the portion 25 reaches the ground contact surface of the heel, it hangs down and the heel sits more easily (see Patent Document 1).
JP-A-8-104313

ホットウォーマー機器内には、一般に、約65℃に加温する飲料入り金属罐と約55℃に加温する飲料入りプラスチック製壜が一緒に収容され、加温される場合がある。また、ホットウォーマー機器は加熱プレートの温度を100〜120℃に設定し、雰囲気温度が所定の温度になったとき加熱プレートはOFFにするように操作される。更に商品が売れて追加の商品をホットウォーマー機器内に投入すると、加熱プレートがONとなり、内容物の温度が70〜75℃位に上昇する。そのためポリエチレンテレフタレート樹脂のガラス転移点Tg=67℃を越える75℃にプラスチック製壜が加温される場合がおこる。   In a hot warmer device, a metal bowl containing a beverage heated to about 65 ° C. and a plastic bowl containing a beverage heated to about 55 ° C. are generally housed together and heated. The hot warmer device is operated so that the temperature of the heating plate is set to 100 to 120 ° C. and the heating plate is turned off when the ambient temperature reaches a predetermined temperature. When the product is sold and an additional product is put into the hot warmer device, the heating plate is turned on, and the temperature of the contents rises to about 70 to 75 ° C. For this reason, the plastic soot may be heated to 75 ° C. exceeding the glass transition point Tg = 67 ° C. of the polyethylene terephthalate resin.

本発明の目的は、飲料をプラスチック容器に充填し、ホットウォーマー機器等によって加温して、消費者に提供する場合において底部が加温された内容物からの重力と熱の影響を受けて垂れ下がり座りが悪くなることのない2軸延伸吹込成形壜を提供することである。   It is an object of the present invention to fill a beverage in a plastic container, heat it by a hot warmer device, etc., and provide it to a consumer, and the bottom part hangs down under the influence of gravity and heat from the heated contents. It is to provide a biaxially-stretched blow-molded cage that does not deteriorate sitting.

請求項1に記載の発明は、上記の課題を解決するもので、2軸延伸吹込成形壜において、その底部は、中央部に壜内部に向けて傾斜したテーパー状周壁とその上端に連接する天壁とからなる壜内部に向けて陥没する陥没部を備え、テーパー状周壁は互いに連接した壜の接地面に対して互いに異なる角度で傾斜した複数の周壁部分からなり、ワイングラスの側壁形状の様に形成されており、該陥没部の2軸延伸吹込成形壜の接地面から天壁までの距離は胴径の25〜40%であり、陥没部の下端の環状の接地径は胴径の50〜75%であることを特徴とする2軸延伸吹込成形壜を要旨とする。   The invention according to claim 1 solves the above-mentioned problem, and in the biaxially stretched blow-molded ridge, the bottom thereof is a tapered peripheral wall inclined toward the inside of the ridge at the center and a ceiling connected to the upper end thereof. The tapered peripheral wall is composed of a plurality of peripheral wall portions that are inclined at different angles with respect to the ground contact surface of the ridge that is connected to each other. The distance from the ground contact surface of the biaxially-stretched blow-molded cage to the top wall of the depression is 25 to 40% of the trunk diameter, and the annular ground contact diameter at the lower end of the depression is 50 of the trunk diameter. The gist is a biaxially-stretched blow-molded wrinkle characterized by being -75%.

本発明に係る2軸延伸吹込成形壜は、胴径55〜70mmを有する加温用容器として形成することができる。   The biaxially-stretched blow molding ridge according to the present invention can be formed as a heating container having a body diameter of 55 to 70 mm.

また、本発明の2軸延伸吹込成形壜は、胴部はその下方に側壁強度アップのための横リブを備え、上記陥没部の天壁は上記横リブより上方に位置するように形成することができる。このように構成することにより、天壁から底部までの延伸率が上がり、このことが壜の耐熱性アップにつながったものと考えられる。   Further, the biaxially stretched blow molding rod of the present invention is formed so that the body portion is provided with a lateral rib for increasing the side wall strength below, and the top wall of the depressed portion is positioned above the lateral rib. Can do. By comprising in this way, the extending | stretching rate from a ceiling wall to a bottom part goes up, and it is thought that this led to the heat resistance improvement of a ridge.

本発明に係る2軸延伸吹込成形壜では、底部中央部に壜内部に向けて傾斜したテーパー状周壁とその上端に連接する天壁とからなる壜内部に向けて陥没する陥没部を備え、テーパー状周壁は互いに連接した壜の接地面に対して互いに異なる角度で傾斜した複数の周壁部分からなり、ワイングラスの側壁形状の様に形成されており、該陥没部の2軸延伸吹込成形壜の接地面から天壁までの距離は、従来品の場合、胴径の23%以下(例えば胴径66mmに対して15mm)に形成されているのに対して、胴径の25〜40%と高く形成され、且つ陥没部の下端の環状の接地径を、胴径の50〜75%にして、陥没部の山形状を急にすることにより、液体内容物が高温に加熱され、内容物からの重力と熱の影響を受けて陥没部が下方に垂れ下がり、壜の座りが悪くなることは防止され、且つ75℃乃至80℃の温度の下の長時間保温に耐え、ホットウォーマー機器による保温保存中に底部の陥没部が下方に垂れ下がり、壜の座りが悪くなることはなく、胴径55〜70mmの加温用容器として活用することができる。   The biaxially-stretched blow molding ridge according to the present invention includes a tapered portion that is recessed toward the inside of the ridge that includes a tapered peripheral wall that is inclined toward the inside of the ridge and a top wall that is connected to an upper end of the tapered peripheral wall. The peripheral wall is composed of a plurality of peripheral wall portions inclined at different angles with respect to the ground contact surfaces of the ridges connected to each other, and is formed like a side wall shape of a wine glass. In the case of the conventional product, the distance from the contact surface to the ceiling wall is 23% or less of the trunk diameter (for example, 15 mm with respect to the trunk diameter of 66 mm), but is as high as 25 to 40% of the trunk diameter. By forming the ring-shaped ground contact diameter at the lower end of the depression part to be 50 to 75% of the trunk diameter and making the mountain shape of the depression part abrupt, the liquid content is heated to a high temperature, Under the influence of gravity and heat, the depression sags downward It is prevented that the saddle sits down and withstands long-term insulation at a temperature of 75 ° C. to 80 ° C., and the depressed portion of the bottom hangs down during the warm preservation by the hot warmer device, and the saddle sits badly. It can be utilized as a heating container having a trunk diameter of 55 to 70 mm.

本発明の2軸延伸吹込成形壜において、底部の環状のテーパー底壁とその外側の湾曲底壁の間に変曲点を設けることが望ましい。このような変曲点が存在することにより、内容物の充填後に底部の陥没部を押し上げてキャッピングし、その後底押し力を除くことにより減圧状態で内容物を密封包装することができる。これによってホットウォーマー機器による加熱により内圧の上昇が起こっても内圧上昇は減圧状態から出発するので底部中央のゲート部が出っ張る程度が少なくなり、本発明の底部の陥没部の垂れ下がりを防止する効果を更に高めることができる。   In the biaxially stretched blow-molded mold of the present invention, it is desirable to provide an inflection point between the annular tapered bottom wall at the bottom and the curved bottom wall on the outside. Due to the existence of such an inflection point, after filling the contents, the depressed portion at the bottom can be pushed up and capped, and then the contents can be sealed and packaged under reduced pressure by removing the bottom pushing force. As a result, even if the internal pressure rises due to heating by the hot warmer device, the internal pressure rise starts from the reduced pressure state, so that the gate portion at the center of the bottom portion is less protruded, and the effect of preventing the sagging of the depressed portion of the bottom portion of the present invention is prevented. It can be further increased.

また、本発明の2軸延伸吹込成形壜は、ホットウォーマー機器等による加温用の壜として利用されるものであるので、口栓部(壜の天面からサポートリング下までの領域)を結晶化(白化)した壜であることが望ましい。それというのも、ホットウォーマー機器等による加温用の壜は、加温の過程で壜にガラス転移点以上の温度が加わるため、壜の口栓部が変形してキャップとの密栓部がなくなり、内容物の腐敗・液漏れ等の不具合を起こす可能性があり、これを解消するために、口栓部を結晶化するのが望ましいからである。   Moreover, since the biaxially-stretched blow molding cage of the present invention is used as a heating rod by a hot warmer device or the like, the plug portion (the region from the top surface of the basket to the bottom of the support ring) is crystallized. It is desirable that the cocoon is whitened. This is because, with a warming device such as a hot-warmer device, since the temperature above the glass transition point is applied to the product during the heating process, the mouthpiece of the product is deformed and the sealed part with the cap disappears. This is because it is desirable to crystallize the plug portion in order to eliminate the possibility of problems such as decay of the contents and liquid leakage.

本発明の2軸延伸吹込成形壜は、底部の中央部に壜内部に向けて傾斜したテーパー状周壁とその上端に連接する天壁とからなる壜内部に向けて陥没する陥没部を備え、テーパー状周壁は互いに連接した壜の接地面に対して互いに異なる角度で傾斜した複数の周壁部分からなり、ワイングラスの側壁形状の様に形成されており、該陥没部の2軸延伸吹込成形壜の接地面から天壁までの距離は胴径の25〜40%であり、陥没部の下端の環状の接地径は胴径の50〜75%であることを特徴とし、ホットウォーマー機器内に長時間おいても加温された内容物からの重力と熱の影響を受けて陥没部が下方に垂れ下がり壜の座りが悪くなることのない利点を有するものである。   The biaxially-stretched blow molding ridge of the present invention includes a tapered portion that is recessed toward the inside of the ridge formed by a tapered peripheral wall that is inclined toward the inside of the ridge and a top wall that is connected to an upper end of the tapered peripheral wall. The peripheral wall is composed of a plurality of peripheral wall portions inclined at different angles with respect to the ground contact surfaces of the ridges connected to each other, and is formed like a side wall shape of a wine glass. The distance from the ground surface to the ceiling wall is 25 to 40% of the trunk diameter, and the annular ground diameter at the lower end of the depression is 50 to 75% of the trunk diameter. However, there is an advantage that the depression does not hang down under the influence of gravity and heat from the heated contents, and the sitting of the heel does not deteriorate.

図1は本発明の実施の形態の2軸延伸吹込成形壜の側面図を示す。図2は前記2軸延伸延伸吹込成形壜の底面図である。図3は前記2軸延伸吹込成形壜の底部の断面図である。図4は前記2軸延伸吹込成形壜の斜視図である。   FIG. 1 shows a side view of a biaxially stretched blow-molded cage according to an embodiment of the present invention. FIG. 2 is a bottom view of the biaxially stretched blow-molded mold. FIG. 3 is a cross-sectional view of the bottom of the biaxially stretched blow-molded bowl. FIG. 4 is a perspective view of the biaxially stretched blow-molded cage.

図1乃至4に示す本発明の2軸延伸吹込成形壜1は、ポリエチレンテレフタレート等からなり、胴径が55乃至70mm、好ましくは60乃至70mmの小型壜(容量240ml乃至360ml)である。この2軸延伸吹込成形壜は、底部3の中央部に、壜内部に向けて傾斜したテーパー状周壁4とその上端に連接する天壁5とからなる壜内部に向けて陥没するワイングラス状の形状の陥没部6を備える。天部5の中央にはゲート部(図示せず)が存在する。尚、2は壜の胴部を示す。また、3aは陥没部9を包囲している環状のテーパー底壁であり、このテーパー底壁の内側に環状の接地部が形成されている。また、陥没部6の2軸延伸吹込成形壜の接地面から天壁5までの距離Hは胴径の25〜40%、好ましくは25〜35%であり、陥没部6の下端の環状の接地径Rは胴径の50〜75%、好ましくは55〜70%である。また、壜の胴部にはその下方に側壁強度アップのための横リブ11が設けられている。   The biaxially stretched blow-molded kite 1 of the present invention shown in FIGS. 1 to 4 is a small kite (capacity 240 ml to 360 ml) made of polyethylene terephthalate or the like and having a body diameter of 55 to 70 mm, preferably 60 to 70 mm. This biaxially stretched blow-molded bowl has a wineglass-like shape that sinks toward the inside of the bowl comprising a tapered peripheral wall 4 inclined toward the inside of the bowl and a top wall 5 connected to the upper end thereof at the center of the bottom 3. A recessed portion 6 having a shape is provided. A gate portion (not shown) exists in the center of the top portion 5. Reference numeral 2 denotes the body of the heel. Reference numeral 3a denotes an annular tapered bottom wall surrounding the depressed portion 9, and an annular grounding portion is formed inside the tapered bottom wall. Further, the distance H from the ground contact surface of the biaxially stretched blow-molded bowl of the depressed portion 6 to the top wall 5 is 25 to 40%, preferably 25 to 35% of the trunk diameter, and the annular grounding at the lower end of the depressed portion 6 The diameter R is 50 to 75% of the body diameter, preferably 55 to 70%. Further, a lateral rib 11 for increasing the side wall strength is provided below the trunk of the heel.

距離Hが胴径の25%よりも小さいと加温された内容物からの重力と熱の影響を受けて陥没部が接地面に達するまで下方に垂れ下がり壜の座りが悪くなる。一方距離Hが胴径の40%を越えると成形性の安定が悪くなり、底部3の形状が出にくいので好ましくない。   If the distance H is less than 25% of the body diameter, the depression will hang down under the influence of gravity and heat from the heated contents until the depression reaches the ground contact surface, and the saddle will not sit well. On the other hand, if the distance H exceeds 40% of the body diameter, the stability of the moldability is deteriorated and the shape of the bottom 3 is difficult to be obtained, which is not preferable.

テーパー状周壁4は、壜の接地面から移行領域3bを介して接地面から約3mmのところから起立した壜の接地面に対して傾斜した第1の周壁部分4aと該周部分に連接した、第1の周壁部分4aとは異なる角度で壜の接地面に対して傾斜した第2の周壁部分4bからなり、ワイングラスの側壁形状の様に形成されている。各周壁部分の傾斜角度は45°乃至70°が適当である。尚、7は周壁部分4aと周壁部分間の移行領域、8は周壁部分4bと天壁5間の移行領域を示す。   The tapered peripheral wall 4 is connected to the peripheral portion with a first peripheral wall portion 4a that is inclined with respect to the ground contact surface of the reed standing up from about 3 mm from the ground contact surface via the transition region 3b from the reed ground surface. The first peripheral wall portion 4a includes a second peripheral wall portion 4b that is inclined with respect to the ground contact surface of the bag at a different angle, and is formed like a side wall shape of a wine glass. The inclination angle of each peripheral wall portion is suitably 45 ° to 70 °. 7 represents a transition region between the peripheral wall portion 4a and the peripheral wall portion, and 8 represents a transition region between the peripheral wall portion 4b and the top wall 5.

また、接地径Rが胴径の50%よりも小さいと壜がホットウォーマー等の傾斜のついた加熱プレート上で倒れやすくなるので好ましくない。一方接地径Rが胴径の75%よりも大きくなると加温された内容物からの重力と熱の影響を受けて陥没部が接地面に達するまで下方に垂れ下がりやすくなる。   Moreover, it is not preferable that the ground contact diameter R is smaller than 50% of the trunk diameter because the heel tends to fall on a heating plate with an inclination such as a hot warmer. On the other hand, when the ground contact diameter R is larger than 75% of the body diameter, it is easy to hang down until the depressed portion reaches the ground contact surface due to the influence of gravity and heat from the heated contents.

本発明の2軸延伸吹込成形壜の特徴として、小さな径の天壁5をテーパー状周壁4で支え、天壁5は胴部側壁の下方に設けた強度アップのための横リブよりも上に位置しているることが挙げられる。それに対して、従来の容器においては天壁5に相当する部分が横リブ11と同等又はそれ以下の高さのところに位置している。また、このように底部の陥没部6を高くシンプルな形状にしたために天壁5から底部3までの部分の延伸率を高めることができ、このことが壜の耐熱性アップにつながったものと考えられる。   As a feature of the biaxially stretched blow molded cage of the present invention, a ceiling wall 5 having a small diameter is supported by a tapered peripheral wall 4, and the ceiling wall 5 is located above a lateral rib for increasing strength provided below the body side wall. It is mentioned that it is located. On the other hand, in the conventional container, the portion corresponding to the top wall 5 is located at a height equal to or lower than the lateral ribs 11. Further, since the bottom depression 6 has a high and simple shape, the stretch ratio of the portion from the top wall 5 to the bottom 3 can be increased, which is thought to have led to an increase in the heat resistance of the kite. It is done.

本発明の2軸延伸吹込成形壜は、底部3の中央部に、壜内部に向けて傾斜した周壁部分4a、4bからなるテーパー状周壁4とその上端に連接する天壁5とからなる壜内部に向けて陥没するワイングラスの様な形状の陥没部6を備え、陥没部6の2軸延伸吹込成形壜の接地面から天壁までの距離Hは胴径の25〜40%、好ましくは25〜35%であり、陥没部6の下端の環状の接地径Rは胴径の50〜75%、好ましくは55〜70%であるので、テーパー状壁によって底部の機械的強度は確保されているのみならず、陥没部6の2軸延伸吹込成形壜の接地面から天壁までの距離Hは従来の胴径の23%よりも高いので、液体内容物が高温に加熱され、内容物からの重力と熱の影響を受けて陥没部が下方に垂れ下がり、壜の座りが悪くなることは防止され、且つ75℃乃至80℃の温度の下の長時間保温に耐え、底部の陥没部が下方に垂れ下がり、壜の座りが悪くなることはなく、ホットウォーマー加温用容器として活用することができる。   The biaxially stretched blow-molded kite according to the present invention includes a taper-shaped peripheral wall 4 made up of peripheral wall portions 4a and 4b inclined toward the inside of the coffin at the center of the bottom portion 3, and a ceiling wall 5 connected to the upper end thereof. And the distance H from the ground contact surface of the biaxially stretched blow-molded bowl to the ceiling wall is 25 to 40% of the body diameter, preferably 25. Since the annular contact diameter R at the lower end of the depression 6 is 50 to 75%, preferably 55 to 70% of the trunk diameter, the mechanical strength of the bottom is ensured by the tapered wall. Not only that, the distance H from the ground contact surface of the biaxially stretched blow-molded bowl of the depressed portion 6 to the top wall is higher than 23% of the conventional trunk diameter, so that the liquid content is heated to a high temperature, Under the influence of gravity and heat, the depressed part hangs down, and the sitting of the eagle worsens Can withstand long-term heat retention at temperatures of 75 ° C. to 80 ° C., and the bottom depressions hang down, so that the sitting of the heel does not worsen, and it is used as a hot warmer heating container. be able to.

また、本発明の2軸延伸吹込成形壜において、図5に示すように、底部3の環状のテーパー底壁3aとその外側の湾曲底壁3cの間に変曲点3dを設けることが望ましい。このような変曲点が存在することにより、内容物の充填後に、底部3に底部3を接地面17のほうに押す力を付与して、押し一点鎖線18で示す形状に変形させ、底部の陥没部6を押し上げた状態で、キャッピングし、その後底部3を押す力を除くことにより減圧状態で内容物を密封包装することができる。これによってホットウォーマー機器による加熱により内圧の上昇が起こっても内圧上昇は減圧状態から出発するので底部中央のゲート部が出っ張る程度が少なくなり、本発明の底部の陥没部の垂れ下がりを防止する効果を更に高めることができる。   Further, in the biaxially stretched blow-molded punch of the present invention, as shown in FIG. 5, it is desirable to provide an inflection point 3d between the annular tapered bottom wall 3a of the bottom portion 3 and the curved bottom wall 3c outside thereof. Due to the presence of such an inflection point, after filling the contents, a force is applied to the bottom 3 to push the bottom 3 toward the grounding surface 17, and the shape is changed to the shape indicated by the dashed-dotted line 18. The contents can be sealed and packaged in a reduced pressure state by removing the force that pushes the bottom portion 3 after capping with the depressed portion 6 pushed up. As a result, even if the internal pressure rises due to heating by the hot warmer device, the internal pressure rise starts from the reduced pressure state, so that the gate portion at the center of the bottom portion is less protruded, and the effect of preventing the sagging of the depressed portion of the bottom portion of the present invention is prevented. It can be further increased.

図6は2軸延伸吹込成形壜の製造方法において、吹込成形型内にパリソンを挿入した状態を示す略断面図である。   FIG. 6 is a schematic cross-sectional view showing a state in which a parison is inserted into a blow mold in a method for producing a biaxially stretched blow mold.

図6に示すように、ポリエチレンテレフタレート等からなる射出成形したパリソン9を成形型10内に挿入し、吹込成形することにより本発明の2軸延伸吹込成形壜を製造することができる。その場合、成形型10の底部の形状が比較的シンプルであるので容易に壜体を成形することができる。尚、本発明の2軸延伸吹込成形壜は、角壜(四角筒形の壜)でも成形出来るが、丸系の壜(六面以上の面からなる多面筒形胴部を有する壜又は円筒胴部を有する壜)のほうが成形性がよい。   As shown in FIG. 6, the biaxially-stretched blow molded bag of the present invention can be manufactured by inserting an injection-molded parison 9 made of polyethylene terephthalate or the like into a mold 10 and blow-molding it. In that case, since the shape of the bottom part of the shaping | molding die 10 is comparatively simple, a housing can be shape | molded easily. The biaxially-stretched blow molding ridge of the present invention can be formed by a square ridge (square cylinder ridge), but a round ridge (a ridge or cylindrical cylinder having a multi-sided cylindrical body having six or more faces) The mold having a part has better formability.

また、ホットウォーマー機器等による加温用の壜としては、口栓部(壜の天面からサポートリング下までの領域)を結晶化(白化)した壜が望ましい。それというのも、ホットウォーマー機器等による加温用の壜は、加温の過程で壜にガラス転移点以上の温度が加わるため、壜の口栓部が変形してキャップとの密栓部がなくなり、内容物の腐敗・液漏れ等の不具合を起こす可能性があり、これを解消するために、口栓部を結晶化するのが望ましいからである。   In addition, as a warming kite with a hot warmer device or the like, it is desirable to crystallize (whiten) the plug part (region from the top of the kite to the bottom of the support ring). This is because, with a warming device such as a hot-warmer device, since the temperature above the glass transition point is applied to the product during the heating process, the mouthpiece of the product is deformed and the sealed part with the cap disappears. This is because it is desirable to crystallize the plug portion in order to eliminate the possibility of problems such as decay of the contents and liquid leakage.

口栓部の結晶化は従来法のように口栓部全体を結晶化する方法によってもよいが、望ましくは、サポートリング以外の口部及び後部に続く移行部を結晶化させるのが良い。サポートリングを非結晶のままに残して口栓部を結晶化したものは、サポートリングが非結晶のままに残されているので、良好な耐衝撃性を保持し、衝撃を受けた際にも破損することはないという利点を有する。   The plug portion may be crystallized by a method of crystallizing the entire plug portion as in the conventional method. Preferably, the transition portion that follows the mouth portion and the rear portion other than the support ring is preferably crystallized. The support ring remains crystallized and the mouthpiece is crystallized, so the support ring remains amorphous. It has the advantage that it does not break.

サポートリング以外の口部及び後部に続く移行部を結晶化させた口栓部を作る方法として、(1)パリソンの段階で口栓部に加熱結晶化処理を施す方法、(2)吹込成形後に口栓部に加熱結晶化処理を施す方法及び、(3)パリソンの段階で口栓部の内側だけ加熱処理し、次いで吹込成形後にサポートリング以外の口部の外側を加熱処理する方法がある。以下、各方法について説明する。   As a method of making the plug part crystallizing the mouth part other than the support ring and the rear part, (1) a method of subjecting the plug part to heat crystallization at the stage of parison, (2) after blow molding There are a method of subjecting the plug portion to heat crystallization treatment, and (3) a method of heat-treating only the inside of the plug portion at the parison stage, and then heat-treating the outside of the mouth portion other than the support ring after blow molding. Hereinafter, each method will be described.

(1)パリソンの段階で口栓部に加熱結晶化処理を施す方法
先ず、図7に示すように口部型121と、インジェクションキャビティ型122と、インジェクションコア型123とからなる射出成形型12を用いて、通常の射出成形法によりパリソン9を成形する。
(1) Method of Heating and Crystallizing the Mouth Portion at the Parison Stage First, as shown in FIG. 7, an injection mold 12 comprising a mouth mold 121, an injection cavity mold 122, and an injection core mold 123 is formed. Then, the parison 9 is formed by a normal injection molding method.

成形したパリソン9がガラス転移温度より低い温度まで冷却したら、インジェクションコア型123及びインジェクションキャビティ型122を離型する。このとき、図8に示すように、口部型121はパリソン9の口部91を把持したままとする。   When the molded parison 9 is cooled to a temperature lower than the glass transition temperature, the injection core mold 123 and the injection cavity mold 122 are released. At this time, as shown in FIG. 8, the mouth part mold 121 keeps holding the mouth part 91 of the parison 9.

次に図9に示すように、口部型121で把持したパリソン9を冷却型13内に入れるのが好ましい。そのとき、口部型121のみならず、パリソン9の胴部及び底部も冷却するのが好ましい。冷却温度は、樹脂の結晶化温度より低ければ良く、具体的に10〜50℃程度が好ましい。   Next, as shown in FIG. 9, the parison 9 gripped by the mouth mold 121 is preferably placed in the cooling mold 13. At that time, it is preferable to cool not only the mouth mold 121 but also the body and bottom of the parison 9. The cooling temperature should just be lower than the crystallization temperature of resin, and specifically about 10-50 degreeC is preferable.

上記のようにパリソンを外側から冷却した状態で、図9に示すようにパリソン9の口部91からロッドヒータ14を挿入し、口部91及びサポートリング92下の胴部への移行部93を内側から加熱し、口部91及びサポートリング92下の胴部への移行部93の内側部分だけを結晶化し、結晶化部19aを形成する。このとき、パリソンの表面温度が100〜190℃となるように加熱するのが好ましい。100〜190℃で加熱処理することにより行うことができる。その場合において、100℃未満では、口栓部の樹脂は結晶化せず、一方、190℃を超えると結晶化が遅くなると共にパリソンが軟化、変形し易くなる。また、加熱時間は、樹脂が部分的結晶化を起こすように設定するが、具体的には0.5〜3分程度が好ましい。   With the parison cooled from the outside as described above, the rod heater 14 is inserted from the mouth portion 91 of the parison 9 as shown in FIG. By heating from the inside, only the inner part of the transition part 93 to the body part below the mouth part 91 and the support ring 92 is crystallized to form the crystallized part 19a. At this time, it is preferable to heat the parison so that the surface temperature becomes 100 to 190 ° C. It can carry out by heat-processing at 100-190 degreeC. In that case, when the temperature is lower than 100 ° C., the resin in the plug portion does not crystallize. Further, the heating time is set so that the resin causes partial crystallization, and specifically, about 0.5 to 3 minutes is preferable.

次に、口部型121をパリソン9から取りはずし、図10に示すように、サポートリング92をサポートリング型16a、16bで把持する。この状態で口部91を外側からリングヒータ15で加熱する。その場合、口部外側からの加熱は、リングヒータに代えて熱風ヒータ、赤外線ヒータ等を用いて行ってもよい。加熱温度は、上記と同様に100〜190℃程度で良い。また、口部外層中の未結晶の樹脂が結晶化するのに十分な時間であればよいが、具体的には0.5〜3分程度が好ましい。また、このとき、サポートリング型16a、16bは樹脂の結晶化温度より低い温度に冷却するのが好ましい。具体的にはサポートリング91の冷却温度は、10〜40℃程度が好ましい。   Next, the mouth mold 121 is removed from the parison 9, and the support ring 92 is held by the support ring molds 16a and 16b as shown in FIG. In this state, the mouth portion 91 is heated from the outside by the ring heater 15. In that case, heating from the outside of the mouth may be performed using a hot air heater, an infrared heater or the like instead of the ring heater. The heating temperature may be about 100 to 190 ° C. as described above. Further, the time may be sufficient for the amorphous resin in the outer layer of the mouth to be crystallized, but specifically about 0.5 to 3 minutes is preferable. At this time, the support ring molds 16a and 16b are preferably cooled to a temperature lower than the crystallization temperature of the resin. Specifically, the cooling temperature of the support ring 91 is preferably about 10 to 40 ° C.

このような方法で口部91を加熱することにより、図11に示すように、サポートリング92中の樹脂は非結晶のままで、それ以外の口部91が結晶化する。19bは非結晶化部を示す。   By heating the mouth portion 91 by such a method, as shown in FIG. 11, the resin in the support ring 92 remains amorphous, and the other mouth portions 91 are crystallized. 19b shows a non-crystallized part.

サポートリング92は、加熱すると自重で変形し易くなるが、図10に示すように、サポートリング92は、加熱処理過程でサポートリング型16a、16bで把持されているので、変形は防止される。   The support ring 92 is easily deformed by its own weight when heated, but as shown in FIG. 10, the support ring 92 is held by the support ring molds 16a and 16b in the course of the heat treatment, so that deformation is prevented.

次いで、このようにして得られたパリソン9を通常の方法で吹込成形するが、その際、移行部93からその下の肩部に掛けて急峻な肉厚差が生じない。   Subsequently, the parison 9 obtained in this way is blow-molded by a normal method, but at this time, a steep thickness difference does not occur from the transition portion 93 to the lower shoulder portion.

(2)吹込成形後に口栓部に加熱結晶化処理を施す方法
壜の吹込成形後、壜を口部型で把持したまたま金型から取り出し、次の加熱結晶化処理を行う。加熱結晶化処理では、口部型で保持した壜を冷却型内に入れ、上記した(1)の方法と同様にして壜の口部からヒータを挿入して口部及び移行部を内側から加熱し、その部分の樹脂を結晶化する。加熱結晶化条件は(1)の方法で良い。
(2) Method of applying heat crystallization treatment to mouthpiece part after blow molding After blow molding of cocoons, the heel is taken out from the mold held by the mouth mold and subjected to the following heat crystallization treatment. In the heat crystallization treatment, the cocoon held in the mouth mold is placed in the cooling mold, and the heater and the transition part are heated from the inside by inserting a heater from the mouth of the jar in the same manner as in the method (1) described above. Then, the resin in that portion is crystallized. The heating crystallization condition may be the method (1).

次に、口部型を壜から離型した後、壜のサポートリングをサポートリング型で把持する。この状態で口部を外側から加熱し、口部外層中の未結晶の樹脂を結晶化する。加熱結晶化条件は(1)の方法と同様で良い。   Next, after releasing the mouth mold from the heel, the support ring of the heel is gripped by the support ring mold. In this state, the mouth is heated from the outside to crystallize the amorphous resin in the outer layer of the mouth. The heat crystallization conditions may be the same as in the method (1).

(3)パリソンの段階で口栓部の内側だけ結晶化し、次いで吹込成形後にサポートリング以外の口部の外側を結晶化する方法
パリソン製造後、口部型でパリソンを把持した状態でインジェクションコア型及びインジェクションキャビティ型を取り外し、口部及び移行部を内側から加熱し、その部分の樹脂を結晶化する。加熱結晶化条件は(1)の方法と同様で良い。
(3) Method of crystallizing only the inside of the mouthpiece at the parison stage and then crystallizing the outside of the mouth other than the support ring after blow molding After injection of the parison, the injection core type with the parison held by the mouth mold Then, the injection cavity mold is removed, and the mouth portion and the transition portion are heated from the inside to crystallize the resin at that portion. The heat crystallization conditions may be the same as in the method (1).

上記パリソンを用いて吹込成形を行った後、壜のサポートリングをサポートリング型で把持する。この状態でサポートリング以外の口部を外側から加熱し、口部外層中の未結晶の樹脂を結晶化する。加熱結晶化条件は(1)の方法で良い。   After blow molding using the parison, the support ring of the heel is gripped with a support ring mold. In this state, the mouth other than the support ring is heated from the outside to crystallize the amorphous resin in the outer layer of the mouth. The heating crystallization condition may be the method (1).

本発明の2軸延伸吹込成形壜の成形用樹脂としては、飽和ジカルボン酸と飽和二価アルコールとからなるポリエステル樹脂を適用することができる。飽和ジカルボン酸としては、テレフタル酸、イソフタル酸、フタル酸、ナフタレン−1,4−又は2,6ジカルボン酸、ジフェニルエーテル−4,4’−ジカルボン酸、ジフェニルジカルボン酸類、ジフェノキシエタンジエタンジカルボン酸類等の芳香族ジカルボン酸類、アジピン酸、セバチン酸、アゼライン酸、デカン−1,10−ジカルボン酸等の脂肪族ジカルボン酸等を使用することができる。また、飽和二価アルコールとしては、エチレングリコール、プロピレングリコール、トリメチレングリコール、テトラメチレングリコール、ジエチレングリコール、ポリエチレングリコール、ポリプロピレングリコール、ポリテトラメチレングリコール、ヘキサメチレングリコール、ドデカメチレングリコール、ネオペンチルグリコール等の脂肪族グリコール、2,2−ビス(4’−β−ヒドロキシエトキシフェニル)プロパン、その他の芳香族ジオール類等を使用することができる。このような飽和ジカルボン酸と飽和二価アルコールとからなるポリエステル樹脂としては、テレフタル酸とエチレングリコールとからなるポリエチレンテレフタレートを用いるのが好ましい。   As the molding resin for the biaxially stretched blow molded mold of the present invention, a polyester resin composed of a saturated dicarboxylic acid and a saturated dihydric alcohol can be applied. Examples of saturated dicarboxylic acids include terephthalic acid, isophthalic acid, phthalic acid, naphthalene-1,4- or 2,6 dicarboxylic acid, diphenyl ether-4,4′-dicarboxylic acid, diphenyldicarboxylic acids, diphenoxyethanediethanedicarboxylic acids, etc. Aromatic dicarboxylic acids, aliphatic dicarboxylic acids such as adipic acid, sebacic acid, azelaic acid, decane-1,10-dicarboxylic acid, and the like can be used. In addition, saturated dihydric alcohols include fats such as ethylene glycol, propylene glycol, trimethylene glycol, tetramethylene glycol, diethylene glycol, polyethylene glycol, polypropylene glycol, polytetramethylene glycol, hexamethylene glycol, dodecamethylene glycol, and neopentyl glycol. Group glycol, 2,2-bis (4′-β-hydroxyethoxyphenyl) propane, other aromatic diols, and the like can be used. As such a polyester resin comprising a saturated dicarboxylic acid and a saturated dihydric alcohol, it is preferable to use polyethylene terephthalate comprising terephthalic acid and ethylene glycol.

また、本発明の2軸延伸吹込成形壜は、2層、3層の多層成形壜として形成することもできる。即ち2色押し出し成形または2色射出成形により、例えば、ポリエチレンテレフタレート/MXD6、MXD6+コバルト塩、PGA(ポリグリコール酸)、EVOH(エチレンビニルアルコール共重合体)又はPEN(ポリエチレンナフタレート)等の酸素バリア性及び紫外線バリア性を有する樹脂/ポリエチレンテレフタレートの三層からなるパリソンを押出成形後、吹込成形することにより酸素バリア性及び紫外線バリア性を有する多層壜を形成しても良い。   In addition, the biaxially stretched blow molded cage of the present invention can also be formed as a two-layer or three-layer multilayer molded cage. That is, oxygen barrier such as polyethylene terephthalate / MXD6, MXD6 + cobalt salt, PGA (polyglycolic acid), EVOH (ethylene vinyl alcohol copolymer) or PEN (polyethylene naphthalate) is obtained by two-color extrusion molding or two-color injection molding. A multilayer bag having oxygen barrier properties and ultraviolet barrier properties may be formed by extrusion molding a three-layer parison of resin / polyethylene terephthalate having heat resistance and ultraviolet barrier properties, followed by blow molding.

また、吹込成形型にインモールドラベル成形用ラベルを取付けインモールドラベル二軸延伸吹込成形を行いバリア性を有するホットウォーマー用容器を形成することもできる。   Alternatively, a hot-warmer container having a barrier property can be formed by attaching an in-mold label forming label to a blow mold and performing in-mold label biaxial stretching blow molding.

インモールドラベル成形用ラベルとして基材層と接着層からなり、接着層は130℃以下で軟化して延伸吹込成形品の表面に接着する熱接着性材料からなるものである。   The in-mold label forming label comprises a base material layer and an adhesive layer, and the adhesive layer is made of a heat-adhesive material that is softened at 130 ° C. or lower and adheres to the surface of the stretch blow molded article.

ここにおいて、熱接着性材料として、(a)低密度ポリエチレン、中密度ポリエチレン、高密度ポリエチレン、線状低密度ポリエチレン、メタロセン触媒を使用して重合したエチレン−αオレフィン共重合体、ポリプロピレン、エチレン−酢酸ビニル共重合体、アイオノマー樹脂、エチレン−アクリル酸エチル共重合体、エチレン−メチルメタクリル酸共重合体、エチレン−アクリル酸共重合体、エチレン−メタクリル酸共重合体、エチレン−プロピレン共重合体、メチルペンテンポリマー、ポリエチレンまたはポリプロピレン等のポリオレフィン系樹脂をアクリル酸、メタクリル酸、無水マレイン酸、フマール酸その他の不飽和カルボン酸で変性した酸変性ポリオレフィン系樹脂、ポリ(メタ)アクリル系樹脂、熱可塑性ポリエステル系樹脂、熱可塑性ポリアミド系樹脂の1種乃至複数種からなるもの、(b)ヒートシール層を有する、ポリエチレン、ポリプロピレン、ポリエチレンテレフタレート等の未延伸又は延伸プラスチックフィルム、(c)エチレン−酢酸ビニル共重合体を含むホットメルト接着剤層、或いは(d)エチレン−酢酸ビニル共重合体を含むヒートシール剤層などを適用することができる。   Here, as a heat-adhesive material, (a) low density polyethylene, medium density polyethylene, high density polyethylene, linear low density polyethylene, ethylene-α olefin copolymer polymerized using a metallocene catalyst, polypropylene, ethylene- Vinyl acetate copolymer, ionomer resin, ethylene-ethyl acrylate copolymer, ethylene-methyl methacrylic acid copolymer, ethylene-acrylic acid copolymer, ethylene-methacrylic acid copolymer, ethylene-propylene copolymer, Polyolefin resins such as methylpentene polymer, polyethylene or polypropylene modified with acrylic acid, methacrylic acid, maleic anhydride, fumaric acid or other unsaturated carboxylic acid, poly (meth) acrylic resin, thermoplastic Polyester tree One or a plurality of thermoplastic polyamide-based resins, (b) an unstretched or stretched plastic film such as polyethylene, polypropylene or polyethylene terephthalate having a heat seal layer, (c) an ethylene-vinyl acetate copolymer A hot-melt adhesive layer containing (d) a heat sealant layer containing ethylene-vinyl acetate copolymer or the like can be applied.

基材層はバリア層、紫外線防止層、遮光層、印刷基材層などを含むものである。   The base material layer includes a barrier layer, an ultraviolet ray prevention layer, a light shielding layer, a printing base material layer, and the like.

次に実施例及び比較例をあげて本発明につき説明する。   Next, the present invention will be described with reference to examples and comparative examples.

ポリエチレンテレフタレート樹脂を用い、2軸延伸吹込成形により、図1に示すように、胴径66mmを有し、底部3の中央部に、壜内部に向けて傾斜したテーパー状周壁4とその上端に連接する天壁5とからなる壜内部に向けて陥没するワイングラス状の形状の陥没部6を備え、陥没部6の2軸延伸吹込成形壜の接地面から天壁までの距離Hは20mm(胴径の30.3%)であり、陥没部6の下端の環状の接地径Rは40mm(胴径の60.6%)である、内容量350ml(高さ163mm)の壜及び内容量280ml(高さ136mm)の壜を成形した。内容量350mlの壜には350mlの水を入れ、また、内容量280mlの壜には280mlの水を入れ、温度80℃の恒温槽内にいれて10時間放置した。しかし、加温された内容物からの重力と熱の影響を受けて底部が垂れ下がり座りが悪くなることはおこらなかった。   As shown in FIG. 1, using a polyethylene terephthalate resin, a tapered peripheral wall 4 having a body diameter of 66 mm and inclined toward the inside of the ridge is connected to the upper end thereof, as shown in FIG. A recessed portion 6 of a wineglass shape that is recessed toward the inside of the ridge formed by the ceiling wall 5 that is formed, and the distance H from the ground contact surface of the biaxially stretched blow molded ridge of the depressed portion 6 to the ceiling wall is 20 mm (body The ring-shaped ground contact diameter R at the lower end of the depressed portion 6 is 40 mm (60.6% of the body diameter), the inner capacity 350 ml (height 163 mm), and the inner capacity 280 ml ( A wrinkle with a height of 136 mm was formed. 350 ml of water was put into a tub with an internal volume of 350 ml, and 280 ml of water was put into a tub with an internal volume of 280 ml, and placed in a thermostatic bath at a temperature of 80 ° C. and left for 10 hours. However, under the influence of gravity and heat from the heated contents, the bottom part hangs down and the sitting does not worsen.

ポリエチレンテレフタレート樹脂を用い、2軸延伸吹込成形により、図1に示すように、胴径66mmを有し、底部3の中央部に、壜内部に向けて傾斜したテーパー状周壁4とその上端に連接する天壁5とからなる壜内部に向けて陥没するワイングラス状の形状の陥没部6を備え、陥没部6の2軸延伸吹込成形壜の接地面から天壁までの距離Hは17.5mm(胴径の26.5%)であり、陥没部6の下端の環状の接地径Rは40mm(胴径の60.6%)である、内容量350ml(高さ163mm)の壜及び内容量280ml(高さ136mm)の壜を成形した。内容量350mlの壜には350mlの水を入れ、また、内容量280mlの壜には280mlの水を入れ、78℃の恒温槽内にいれて10時間放置した。しかし、加温された内容物からの重力と熱の影響を受けて底部が垂れ下がり座りが悪くなることはおこらなかった。   As shown in FIG. 1, using a polyethylene terephthalate resin, a tapered peripheral wall 4 having a body diameter of 66 mm and inclined toward the inside of the ridge is connected to the upper end thereof, as shown in FIG. A recessed portion 6 having a wineglass-like shape that is recessed toward the interior of the ridge formed by the ceiling wall 5, and the distance H from the ground contact surface of the biaxially stretched blow molded ridge of the recessed portion 6 to the ceiling wall is 17.5 mm (26.5% of the trunk diameter), the ring-shaped grounding diameter R at the lower end of the depression 6 is 40 mm (60.6% of the trunk diameter), the inner capacity 350 ml (height 163 mm), and the inner capacity A 280 ml (136 mm height) bag was formed. 350 ml of water was put into a tub with an inner volume of 350 ml, and 280 ml of water was put into a tub with an inner volume of 280 ml, placed in a thermostat at 78 ° C. and left for 10 hours. However, under the influence of gravity and heat from the heated contents, the bottom part hangs down and the sitting does not worsen.

ポリエチレンテレフタレート樹脂を用い、2軸延伸吹込成形により、図1に示すように、胴径66mmを有し、底部3の中央部に、壜内部に向けて傾斜したテーパー状周壁4とその上端に連接する天壁5とからなる壜内部に向けて陥没するワイングラス状の形状の陥没部6を備え、陥没部6の2軸延伸吹込成形壜の接地面から天壁までの距離Hは17.5mm(胴径の26.5%)であり、陥没部6の下端の環状の接地径Rは45mm(胴径の68.1%)である、内容量350ml(高さ163mm)の壜及び内容量280ml(高さ136mm)の壜を成形した。内容量350mlの壜には350mlの水を入れ、また、内容量280mlの壜には280mlの水を入れ、75℃の恒温槽内にいれて10時間放置した。しかし、加温された内容物からの重力と熱の影響を受けて底部が垂れ下がり座りが悪くなることはおこらなかった。   As shown in FIG. 1, using a polyethylene terephthalate resin, a tapered peripheral wall 4 having a body diameter of 66 mm and inclined toward the inside of the ridge is connected to the upper end thereof, as shown in FIG. A recessed portion 6 having a wineglass-like shape that is recessed toward the interior of the ridge formed by the ceiling wall 5, and the distance H from the ground contact surface of the biaxially stretched blow molded ridge of the recessed portion 6 to the ceiling wall is 17.5 mm (26.5% of the trunk diameter), the ring-shaped ground contact diameter R at the lower end of the depression 6 is 45 mm (68.1% of the trunk diameter), the inner capacity 350 ml (height 163 mm), and the inner capacity A 280 ml (136 mm height) bag was formed. 350 ml of water was put into a tub with an inner volume of 350 ml, and 280 ml of water was put into a tub with an inner volume of 280 ml, placed in a thermostat at 75 ° C. and left for 10 hours. However, under the influence of gravity and heat from the heated contents, the bottom part hangs down and the sitting does not worsen.

ポリエチレンテレフタレート樹脂を用い、2軸延伸吹込成形により、図1に示すように、胴径66mmを有し、底部3の中央部に、壜内部に向けて傾斜したテーパー状周壁4とその上端に連接する天壁5とからなる壜内部に向けて陥没するワイングラス状の形状の陥没部6を備え、陥没部6の2軸延伸吹込成形壜の接地面から天壁までの距離Hは16.5mm(胴径の25%)であり、陥没部6の下端の環状の接地径Rは50mm(胴径の75.8%)である、内容量350ml(高さ163mm)の壜及び内容量280ml(高さ136mm)の壜を成形した。内容量350mlの壜には350mlの水を入れ、また、内容量280mlの壜には280mlの水を入れ、75℃の恒温槽内にいれて10時間放置した。しかし、加温された内容物からの重力と熱の影響を受けて底部が垂れ下がり座りが悪くなることはおこらなかった。   As shown in FIG. 1, using a polyethylene terephthalate resin, a tapered peripheral wall 4 having a body diameter of 66 mm and inclined toward the inside of the ridge is connected to the upper end thereof, as shown in FIG. The wine glass-like depression 6 is recessed toward the inside of the ridge, which is formed from the ceiling wall 5, and the distance H from the ground contact surface of the biaxially stretched blow molded ridge of the depression 6 to the ceiling wall is 16.5 mm. The ring-shaped ground contact diameter R at the lower end of the depressed portion 6 is 50 mm (75.8% of the trunk diameter), the inner capacity 350 ml (height 163 mm) and the inner capacity 280 ml ( A wrinkle with a height of 136 mm was formed. 350 ml of water was put into a tub with an inner volume of 350 ml, and 280 ml of water was put into a tub with an inner volume of 280 ml, placed in a thermostat at 75 ° C. and left for 10 hours. However, under the influence of gravity and heat from the heated contents, the bottom part hangs down and the sitting does not worsen.

〔比較例1〕
ポリエチレンテレフタレート樹脂を用い、2軸延伸吹込成形により、図1に示すように、胴径66mmを有し、底部3の中央部に、壜内部に向けて傾斜したテーパー状周壁4とその上端に連接する天壁5とからなる壜内部に向けて陥没するワイングラス状の形状の陥没部6を備え、陥没部6の2軸延伸吹込成形壜の接地面から天壁までの距離Hは15mm(胴径の22.7%)であり、陥没部6の下端の環状の接地径Rは50mm(胴径の75.7%)である、内容量350mlの壜を成形した。この壜内に水350mlを入れ、75℃の恒温槽内にいれて10時間放置した。その結果、加温された内容物からの重力と熱の影響を受けて底部が接地面に至るまで垂れ下がり座りが悪くなることが生じた。
[Comparative Example 1]
As shown in FIG. 1, using a polyethylene terephthalate resin, a tapered peripheral wall 4 having a body diameter of 66 mm and inclined toward the inside of the ridge is connected to the upper end thereof, as shown in FIG. A recessed portion 6 having a wineglass shape that is recessed toward the interior of the ridge formed by the ceiling wall 5, and the distance H from the ground contact surface of the biaxially stretched blow molded ridge of the depressed portion 6 to the ceiling wall is 15 mm (body A ring having an inner volume of 350 ml was formed, with an annular grounding diameter R of 50 mm (75.7% of the body diameter) at the lower end of the depressed portion 6. 350 ml of water was placed in this basket, placed in a constant temperature bath at 75 ° C. and left for 10 hours. As a result, under the influence of the gravitational force and heat from the heated contents, the bottom part hangs down until it reaches the ground contact surface, and the seating becomes worse.

〔比較例2〕
ポリエチレンテレフタレート樹脂を用い、2軸延伸吹込成形により、図1に示すように、胴径66mmを有し、底部3の中央部に、壜内部に向けて傾斜したテーパー状周壁4とその上端に連接する天壁5とからなる壜内部に向けて陥没するワイングラス状の形状の陥没部6を備え、陥没部6の2軸延伸吹込成形壜の接地面から天壁までの距離Hは16.5mm(胴径の25%)であり、陥没部6の下端の環状の接地径Rは53mm(胴径の80%)である、内容量350mlの壜を成形した。この壜内に水350mlを入れ、75℃の恒温槽内にいれて10時間放置した。その結果、加温された内容物からの重力と熱の影響を受けて底部が接地面に至るまで垂れ下がり座りが悪くなることが生じた。
[Comparative Example 2]
As shown in FIG. 1, using a polyethylene terephthalate resin, a tapered peripheral wall 4 having a body diameter of 66 mm and inclined toward the inside of the ridge is connected to the upper end thereof, as shown in FIG. The wine glass-like depression 6 is recessed toward the inside of the ridge, which is formed from the ceiling wall 5, and the distance H from the ground contact surface of the biaxially stretched blow molded ridge of the depression 6 to the ceiling wall is 16.5 mm. A collar having an inner capacity of 350 ml was formed, which was (25% of the trunk diameter) and the annular ground contact diameter R at the lower end of the depression 6 was 53 mm (80% of the trunk diameter). 350 ml of water was placed in this basket, placed in a constant temperature bath at 75 ° C. and left for 10 hours. As a result, under the influence of the gravitational force and heat from the heated contents, the bottom part hangs down until it reaches the ground contact surface, and the seating becomes worse.

図12は75℃に温度を維持した恒温層(ヤマト科学(株)製DN43)内で内容物入り壜を加温した時の(加温)経過時間対ゲート部深さ変化率((壜の接地部から壜中央部にあるゲート部までの距離(以下ゲート部深さと称する)の初期値−加温後の壜のゲート部深さの測定値)/ゲート部深さの初期値×100(%))のグラフを示す。尚、ゲート部深さは、(株)ミツトヨ製デプスケージを使用して測定した。図12において、−●−は比較例1、−○−は比較例2、−▲−は実施例1、−×−は実施例2、−◆−は実施例3、−■−は実施例4を示す。この図から明らかなように、実施例1乃至4の場合、10時間加温後のゲート変化率は70%以下であり、底部の陥没部がが接地面に至るまで垂れ下がり座りが悪くなることはない。これに対し比較例1,2の場合、10時間加温を続けるとゲート変化率は100%に達し底部の陥没部が接地面に至るまで垂れ下がり壜の座りが悪くなる。   FIG. 12 shows the time when the contents of the soot are heated in a constant temperature layer (DN43 manufactured by Yamato Kagaku Co., Ltd.) maintained at 75 ° C. (warming) with respect to the gate portion depth change rate ((ground of the soot) Initial value of distance from gate part to gate part in the central part of the ridge (hereinafter referred to as gate part depth) −measured value of gate part depth of heel after heating) / initial value of gate part depth × 100 (% )) Graph. The gate depth was measured using a depth cage manufactured by Mitutoyo Corporation. In FIG. 12,-●-is Comparative Example 1, -O- is Comparative Example 2,-▲-is Example 1, -X- is Example 2,-◆-is Example 3,-■-is an Example. 4 is shown. As is clear from this figure, in Examples 1 to 4, the gate change rate after heating for 10 hours is 70% or less, and the bottom depression hangs down until it reaches the grounding surface, and the seating becomes worse. Absent. On the other hand, in the case of Comparative Examples 1 and 2, if the heating is continued for 10 hours, the gate change rate reaches 100% and the bottom depression hangs down until it reaches the ground contact surface, and the sitting of the heel becomes worse.

本発明に係る2軸延伸吹込成形壜は、飲料をホットウォーマー機器等によって加温して販売する販売容器として有効に活用し得る。   The biaxially stretched blow-molded bowl according to the present invention can be effectively used as a sales container for heating and selling a beverage by a hot warmer device or the like.

本発明の実施の形態の2軸延伸吹込成形壜の側面図である。It is a side view of the biaxial stretching blow-molding cage of an embodiment of the invention. 本発明の実施の形態の2軸延伸延伸吹込成形壜の底面図である。It is a bottom view of the biaxially-stretched stretch blow molding punch of embodiment of this invention. 本発明の実施の形態の2軸延伸吹込成形壜の底部の断面図である。It is sectional drawing of the bottom part of the biaxially-stretched blow molding cage | basket of embodiment of this invention. 本発明の実施の形態の2軸延伸吹込成形壜の斜視図である。1 is a perspective view of a biaxially stretched blow-molded cage of an embodiment of the present invention. 本発明の2軸延伸吹込成形壜の変曲点を有する底部の形状を示す略図である。It is the schematic which shows the shape of the bottom part which has an inflection point of the biaxially-stretched blow molding cage | basket of this invention. 前記2軸延伸吹込成形壜の成形過程において、吹込成形型内にパリソンを挿入した状態を示す略断面図である。FIG. 6 is a schematic cross-sectional view showing a state in which a parison is inserted into a blow molding die in the molding process of the biaxially stretched blow molded punch. 本発明の2軸延伸吹込成形壜のパリソンの製造過程を示す略図である。It is the schematic which shows the manufacturing process of the parison of the biaxially-stretched blow molding cage | basket of this invention. 成形したパリソンの口部型で把持した状態を示す略図である。It is the schematic which shows the state hold | gripped with the mouth part type | mold of the shape | molded parison. パリソンのの口部の内側を結晶化する過程を示す略図である。1 is a schematic diagram showing the process of crystallizing the inside of the mouth of a parison. パリソンの口部の外側を結晶化する過程を示す略図である。1 is a schematic diagram illustrating a process of crystallizing the outside of a parison mouth. 口部を結晶化した後吹込成形した壜の口部の拡大図である。It is an enlarged view of the mouth part of the bag which was blow-molded after crystallizing the mouth part. 2軸延伸吹込成形壜の加温の経過時間対ゲート部深さElapsed time of heating of biaxially stretched blow molded mold vs. gate depth 従来の2軸延伸吹込壜の底部の断面図である。It is sectional drawing of the bottom part of the conventional biaxial stretching blower. 図12に示す2軸延伸吹込成形壜の底部の底面図である。It is a bottom view of the bottom part of the biaxially stretched blow-molded bowl shown in FIG.

符号の説明Explanation of symbols

1 2軸延伸吹込成形壜
2 壜の胴部
3 底部
3a 環状のテーパー底壁
3b 移行領域
3c 湾曲底壁
3d 変曲点
4 テーパー状周壁
4a 周壁部分
4b 周壁部分
5 天壁
6 陥没部
7 移行領域
8 移行領域
9 パリソン
91 口部
92 サポートリング
93 サポートリング92下の胴部への移行部
10 吹込成形型
11 横リブ
12 射出成形型
121 口部型
122 インジェクションキャビティ型
123 インジェクションコア型
13 冷却型
14 ロッドヒータ
15 リングヒータ
16a サポートリング型
16b サポートリング型
17 接地面
18 接地面のほうへ押圧され変形した底部の輪郭を示す線
19a 結晶化領域
19b 非結晶化領域
21 底部
22 周壁
23 壜内部
24 壜の側壁
25 陥没部
DESCRIPTION OF SYMBOLS 1 Biaxial stretch blow molding cage | basket 2 Trunk body 3 Bottom 3a Annular taper bottom wall 3b Transition area 3c Curved bottom wall 3d Inflection point 4 Tapered peripheral wall 4a Perimeter wall part 4b Perimeter wall part 5 Top wall 6 Depression part 7 Transition area DESCRIPTION OF SYMBOLS 8 Transition area | region 9 Parison 91 Mouth part 92 Support ring 93 Transition part to the trunk | drum under support ring 92 10 Blow-molding die 11 Horizontal rib 12 Injection molding die 121 Mouth type 122 Injection cavity type 123 Injection core type 13 Cooling type 14 Rod heater 15 Ring heater 16a Support ring type 16b Support ring type 17 Ground surface 18 Line indicating the outline of the bottom portion that is pressed and deformed toward the ground surface 19a Crystallized region 19b Non-crystallized region 21 Bottom 22 Peripheral wall 23 壜 Inside 24 壜Side wall of 25

Claims (5)

2軸延伸吹込成形壜において、その底部は、中央部に壜内部に向けて傾斜したテーパー状周壁とその上端に連接する天壁とからなる壜内部に向けて陥没する陥没部を備え、テーパー状周壁は互いに連接した壜の接地面に対して互いに異なる角度で傾斜した複数の周壁部分からなり、ワイングラスの側壁形状の様に形成されており、該陥没部の2軸延伸吹込成形壜の接地面から天壁までの距離は胴径の25〜40%であり、陥没部の下端の環状の接地径は胴径の50〜75%であることを特徴とする2軸延伸吹込成形壜。   In the biaxially stretched blow-molded ridge, the bottom portion is provided with a recessed portion that is recessed toward the interior of the ridge comprising a tapered peripheral wall that is inclined toward the interior of the ridge and a top wall that is connected to the upper end thereof, and is tapered. The peripheral wall is composed of a plurality of peripheral wall portions inclined at different angles with respect to the ground contact surfaces of the ridges connected to each other, and is formed like a side wall shape of a wine glass. A biaxially-stretched blow molded ridge, characterized in that the distance from the ground to the ceiling wall is 25 to 40% of the trunk diameter, and the annular ground contact diameter at the lower end of the depression is 50 to 75% of the trunk diameter. 胴径55〜70mmを有する加温用容器であることを特徴とする請求項1に記載の2軸延伸吹込成形壜。   The biaxially stretched blow-molded bowl according to claim 1, which is a heating container having a body diameter of 55 to 70 mm. 胴部はその下方に側壁強度アップのための横リブを備え、上記陥没部の天壁は上記横リブより上方に位置することを特徴とする請求項1又は2に記載の2軸延伸吹込成形壜。   The biaxially-stretched blow molding according to claim 1 or 2, wherein the body portion is provided with a lateral rib for lowering the side wall strength, and the top wall of the depressed portion is located above the lateral rib.壜. テーパー状周壁とその外側の湾曲底壁の間に変曲点が存在することを特徴とする請求項1乃至3の何れか一項に記載の2軸延伸吹込成形壜。   4. The biaxially stretched blow-molded bowl according to claim 1, wherein an inflection point exists between the tapered peripheral wall and the curved bottom wall on the outside thereof. 5. 壜の口栓部が白化されていることを特徴とする請求項1乃至4の何れか一項に記載の2軸延伸吹込成形壜。
The biaxially stretched blow-molded bowl according to any one of claims 1 to 4, wherein the mouthpiece portion of the bowl is whitened.
JP2003386388A 2003-11-17 2003-11-17 Biaxial stretch blow molding mold Expired - Fee Related JP4570019B2 (en)

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JP2007030893A (en) * 2005-07-22 2007-02-08 Yoshino Kogyosho Co Ltd Synthetic resin bottle
JP2011251756A (en) * 2010-06-04 2011-12-15 Toyo Seikan Kaisha Ltd Olefin-based resin bottle for non-oily content
JP2016135692A (en) * 2016-05-06 2016-07-28 株式会社吉野工業所 Bottle production method
JP6143213B1 (en) * 2016-03-04 2017-06-07 三菱ケミカル株式会社 Plastic bottle
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