JP2005117915A - Method for producing egg albumen-processed food - Google Patents

Method for producing egg albumen-processed food Download PDF

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JP2005117915A
JP2005117915A JP2003354050A JP2003354050A JP2005117915A JP 2005117915 A JP2005117915 A JP 2005117915A JP 2003354050 A JP2003354050 A JP 2003354050A JP 2003354050 A JP2003354050 A JP 2003354050A JP 2005117915 A JP2005117915 A JP 2005117915A
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egg white
coagulated
fermentation
fermented
decomposition product
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Yusuke Hoshino
勇介 星野
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HOSHINO KAGAKU KK
YUUSAIDO KK
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HOSHINO KAGAKU KK
YUUSAIDO KK
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for producing egg albumen-processed food comprising fermenting egg albumen, by which egg albumen to be used is not particularly limited so that the egg albumen is usable as a main ingredient, the obtained egg albumen-processed food does not smell fishy or sulfurous even when the egg albumen is used as a main ingredient, and usefulness of egg albumen is fully utilized. <P>SOLUTION: The method for producing egg albumen comprises the following processes: a process of heating egg albumen to obtain coagulated egg albumen; a process of adding enzyme to the coagulated egg albumen to obtain enzyme/coagulated egg albumen mixture; a process of holding the enzyme/coagulated egg albumen mixture to obtain a coagulated egg albumen decomposed product; a process of adding a fermentation auxiliary agent to the coagulated egg albumen decomposed product to obtain fermentation auxiliary agent/coagulated egg albumen decomposed product mixture; a process of adding a pH-regulating agent to the fermentation auxiliary agent/coagulated egg albumen decomposed product mixture to regulate pH of the fermentation auxiliary agent/coagulated egg albumen decomposed product mixture; a process of adding fermentative bacteria to the pH-regulated fermentation auxiliary agent/coagulated egg albumen decomposed product mixture to obtain a fermented egg albumen antecedent; and a process of holding the fermented egg albumen antecedent to obtain fermented egg albumen. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、卵白を加工してなる卵白加工食品の製造方法に関する。   The present invention relates to a method for producing an egg white processed food obtained by processing egg white.

たんぱく質は、身体を構成する成分としても、またエネルギー源としても、非常に重要な栄養素の一つであり、動物性食品と植物性食品のいずれからも摂取することができる。しかしながら、動物性食品の代表例である肉等は、一般的に高たんぱく質であるものの、同時に脂肪も多く含むため、近年その摂取が敬遠されている。その一方、かかる動物性食品の一つである卵白は、良質のたんぱく質を多く含んでいながら、低脂肪、低コレステロールであることが知られている。このため、かかる卵白を食品素材として上手く利用すれば、低脂肪、低コレステロールで、かつ高たんぱく質の機能性食品を得ることが可能となる。   Protein is one of the very important nutrients, both as a constituent of the body and as an energy source, and can be ingested from both animal foods and vegetable foods. However, meat and the like, which are typical examples of animal foods, are generally high in protein, but at the same time contain a lot of fat, so their intake has been avoided in recent years. On the other hand, egg white, which is one of such animal foods, is known to have a low fat and a low cholesterol while containing many high-quality proteins. Therefore, if such egg white is successfully used as a food material, it becomes possible to obtain a functional food with low fat, low cholesterol and high protein.

そこで、これまでに、卵白を用いてなる機能性食品が幾つか開発されており、その一つとして、卵白を発酵してなる卵白加工食品の製造方法が開示されている(例えば、特許文献1乃至4参照)。
特開平2−234655号公報(特許請求の範囲) 特開平8−131068号公報(特許請求の範囲) 特開平8−154574号公報(特許請求の範囲) 特開平9−191863号公報(特許請求の範囲)
So far, several functional foods using egg white have been developed, and as one of them, a method for producing an egg white processed food obtained by fermenting egg white is disclosed (for example, Patent Document 1). To 4).
JP-A-2-234655 (Claims) Japanese Patent Laid-Open No. 8-131068 (Claims) JP-A-8-154574 (Claims) JP-A-9-191863 (Claims)

しかしながら、卵白中には、発酵菌が資化し得る栄養素が少量しか含まれていない上に、その成分の一つとして、発酵菌の働きを抑制するリゾチ−ムが含まれているため、割卵して得られる(未加工の)卵白に発酵菌を植菌しても、卵白の発酵を十分に進めることができない。したがって、上記従来の卵白加工食品の製造方法では、卵白に牛乳や糖等の、発酵菌が資化し得る栄養素を大量に添加する工程や、卵白を加熱する等してリゾチ−ムを失活させる工程を含むことを要していた。   However, egg white contains only a small amount of nutrients that can be assimilated by the fermenting bacteria and, as one of its components, contains a lysozyme that suppresses the action of the fermenting bacteria. Even if fermented bacteria are inoculated into (raw) egg white obtained in this way, the fermentation of egg white cannot be sufficiently advanced. Therefore, in the conventional method for producing processed egg white food, the lysozyme is deactivated by adding a large amount of nutrients that can be fermented by fermentation bacteria, such as milk or sugar, to egg white, or heating egg white. It was necessary to include a process.

ここで、卵白を加熱すると、卵白に含まれる含硫アミノ酸が分解して硫化水素が発生するため、加熱後の卵白から硫黄臭がすることとなる。したがって、従来の卵白加工食品の製造方法が、卵白の加熱工程を含む一方、卵白に栄養素を添加する工程を含まずに構成された場合には、卵白中には依然として発酵菌が資化し得る栄養素が少量しか含まれないことから、卵白の発酵が不十分なものとなって、得られる卵白加工食品から硫黄臭がして、食欲を殺ぐおそれがあった。このため、上記従来の卵白加工食品の製造方法では、さらに、卵白を水等で希釈する工程を含むことを要する場合があった。   Here, when the egg white is heated, sulfur-containing amino acids contained in the egg white are decomposed to generate hydrogen sulfide, so that the egg white after the heating has a sulfur smell. Therefore, when the conventional method for producing processed egg white food includes the step of heating egg white but does not include the step of adding nutrients to egg white, nutrients that can still be assimilated by fermentation bacteria in the egg white Is contained in a small amount, the fermentation of egg white becomes insufficient, and the processed egg white processed food has a sulfur odor, which may kill appetite. For this reason, the conventional method for producing processed egg white food may further require a step of diluting the egg white with water or the like.

すなわち、上記従来の卵白加工食品の製造方法においては、得られる卵白加工食品中の卵白の含有量が低く抑えられることとなっていた。その結果、かかる卵白加工食品の製造方法では、卵白を主成分とした卵白加工食品を得ることができず、したがって、低脂肪、低コレステロールで、かつ高たんぱく質の、卵白の有用性を十分に活かした卵白加工食品を作製することができなかった。   That is, in the conventional method for producing processed egg white food, the content of egg white in the obtained processed egg white food is to be kept low. As a result, in such a method for producing processed egg white food, it is not possible to obtain an egg white processed food mainly composed of egg white. Therefore, the usefulness of egg white, which is low in fat, low in cholesterol and high in protein, is fully utilized. An egg white processed food could not be produced.

本発明の目的は、卵白を発酵してなる卵白加工食品の製造方法であって、卵白の使用量が特に制限されることがなく、したがって、卵白を主成分とすることができ、また、卵白を主成分としても、得られる卵白加工食品から卵の生臭さや硫黄臭がしない、卵白の有用性を十分に活かした卵白加工食品の製造方法を提供することにある。   An object of the present invention is a method for producing a processed egg white food obtained by fermenting egg white, and the amount of egg white used is not particularly limited. Therefore, egg white can be the main component. The main object of the present invention is to provide a method for producing a processed egg white food that makes full use of the usefulness of egg white, which does not give the raw egg odor or sulfur odor from the processed egg white processed food.

本発明の卵白加工食品の製造方法の要旨とするところは、卵白を加熱して、凝固卵白とする工程と、前記凝固卵白と酵素とを混合して、酵素・凝固卵白混合体とする工程と、前記酵素・凝固卵白混合体を留置して、凝固卵白分解物とする工程と、前記凝固卵白分解物と発酵補助剤とを混合して、発酵補助剤・凝固卵白分解物混合体とする工程と、前記発酵補助剤・凝固卵白分解物混合体と発酵菌とを混合して、発酵卵白前駆体とする工程と、前記発酵卵白前駆体を留置して、発酵卵白とする工程と、を含んで構成され、前記発酵卵白前駆体のpHが、pH調整剤を用いて4〜6に調整されてなることにある。   The gist of the method for producing a processed egg white food of the present invention is to heat the egg white to obtain a coagulated egg white, and to mix the coagulated egg white and the enzyme to obtain an enzyme / coagulated egg white mixture. , The step of placing the enzyme / coagulated egg white mixture into a coagulated egg white decomposition product, and the step of mixing the coagulated egg white decomposition product and the fermentation auxiliary agent to form a fermentation auxiliary agent / coagulated egg white decomposition product mixture. And a step of mixing the fermentation auxiliary agent / coagulated egg white decomposition product mixture and fermenting bacteria to make a fermented egg white precursor, and a step of placing the fermented egg white precursor to make a fermented egg white. And the pH of the fermented egg white precursor is adjusted to 4 to 6 using a pH adjuster.

かかる構成において、卵白を加熱して凝固させることにより、酵素がたんぱく質に作用し易くなる。また、卵白に含まれる、リゾチ−ムやビタミン結合性タンパクやプロテアーゼ阻害剤等の、酵素や発酵菌の活性を低下させる物質が失活することとなる。   In such a configuration, by heating and coagulating the egg white, the enzyme easily acts on the protein. In addition, substances that reduce the activity of enzymes and fermenting bacteria, such as lysozyme, vitamin-binding proteins, and protease inhibitors, contained in egg white are inactivated.

また、加熱・凝固してなる凝固卵白を酵素で分解して、凝固卵白分解物とすることにより、卵白が発酵菌の資化し易い態様に変わることとなる。   Moreover, by decomposing the coagulated egg white obtained by heating and coagulation with an enzyme to obtain a coagulated egg white decomposition product, the egg white is changed to a mode in which the fermenting bacteria are easily assimilated.

また、凝固卵白分解物に発酵補助剤を混合することにより、発酵菌による卵白の発酵が促進されることとなる。   Moreover, fermentation of egg white by fermenting bacteria will be accelerated | stimulated by mixing a fermentation adjuvant with coagulated egg white decomposition product.

また、発酵卵白前駆体のpHが4〜6に調整されてなることにより、卵白の発酵時における腐敗菌の働きが抑制される一方、発酵菌の働きを活性化し得る。   Moreover, by adjusting the pH of the fermented egg white precursor to 4 to 6, the function of the rot bacteria during the fermentation of the egg white can be suppressed, while the function of the fermented bacteria can be activated.

また、本発明の卵白加工食品の製造方法の要旨とするところは、前記発酵補助剤・凝固卵白分解物混合体とする工程が、前記凝固卵白分解物と発酵補助剤とを混合した後、加熱する工程を含んでなることにある。   Moreover, the place which makes the summary of the manufacturing method of the egg white processed food of this invention is the process made into the said fermentation auxiliary agent and coagulated egg white decomposition product mixture, after mixing the said coagulated egg white decomposition product and a fermentation auxiliary agent, it heats. The process of comprising.

かかる構成により、凝固卵白分解物、及び発酵補助剤中に含まれる腐敗菌が殺菌されることとなる。また、凝固卵白分解物に含まれる酵素が失活されることとなる。   With this configuration, the coagulated egg white decomposition product and the spoilage bacteria contained in the fermentation aid are sterilized. Moreover, the enzyme contained in the coagulated egg white decomposition product will be inactivated.

また、本発明の卵白加工食品の製造方法の要旨とするところは、卵白を加熱して、凝固卵白とする工程と、前記凝固卵白と酵素とを混合して、酵素・凝固卵白混合体とする工程と、前記酵素・凝固卵白混合体を留置して、凝固卵白分解物とする工程と、前記凝固卵白分解物と発酵補助剤とpH調整剤を混合して、pH調整済み発酵補助剤・凝固卵白分解物混合体とする工程と、前記pH調整済み発酵補助剤・凝固卵白分解物混合体と発酵菌とを混合して、発酵卵白前駆体とする工程と、前記発酵卵白前駆体を留置して、発酵卵白とする工程と、を含んで構成され、前記pH調整済み発酵補助剤・凝固卵白分解物混合体のpHが4〜6であることにある。   Moreover, the gist of the method for producing an egg white processed food according to the present invention is that the step of heating egg white to obtain a coagulated egg white and the coagulated egg white and the enzyme are mixed to obtain an enzyme / coagulated egg white mixture. A step, a step of placing the enzyme / coagulated egg white mixture into a coagulated egg white decomposition product, and a mixture of the coagulated egg white decomposition product, fermentation aid and pH adjuster to adjust the pH adjusted fermentation aid / coagulation A step of preparing an egg white decomposition product mixture, a step of mixing the pH-adjusted fermentation aid / coagulated egg white decomposition product mixture and a fermenting fungus to obtain a fermented egg white precursor, and placing the fermented egg white precursor in place. The pH of the fermentation-adjusted fermentation aid / coagulated egg white decomposition product mixture is 4 to 6.

また、本発明の卵白加工食品の製造方法の要旨とするところは、前記酵素・凝固卵白混合体とする工程が、さらにpH調整剤を混合する工程を含んでなり、該工程において、前記酵素・凝固卵白混合体のpHが4〜7に調整されることにある。   Further, the gist of the method for producing an egg white processed food of the present invention is that the step of preparing the enzyme / coagulated egg white mixture further comprises a step of mixing a pH adjuster, The pH of the coagulated egg white mixture is adjusted to 4-7.

かかる構成により、凝固卵白混合体のpHが、卵白が本来示すpHよりも低く抑えられることとなる。このため、後の凝固卵白分解物とする工程において、酵素の活性が促進されることとなる。   With such a configuration, the pH of the coagulated egg white mixture is suppressed to be lower than the pH originally exhibited by the egg white. For this reason, the activity of an enzyme will be accelerated | stimulated in the process used as the coagulated egg white decomposition product later.

また、本発明の卵白加工食品の製造方法の要旨とするところは、前記pH調整済み発酵補助剤・凝固卵白分解物混合体とする工程が、前記凝固卵白分解物と発酵補助剤とpH調整剤とを混合した後、加熱する工程を含んでなることにある。   Further, the gist of the method for producing an egg white processed food of the present invention is that the step of preparing the pH-adjusted fermentation aid / coagulated egg white decomposed product mixture comprises the coagulated egg white decomposed product, the fermentation aid, and the pH adjuster. And a step of heating after mixing.

かかる構成により、凝固卵白分解物、及び発酵補助剤中に含まれる腐敗菌が殺菌されることとなる。また、凝固卵白分解物に含まれる酵素が失活されることとなる。   With this configuration, the coagulated egg white decomposition product and the spoilage bacteria contained in the fermentation aid are sterilized. Moreover, the enzyme contained in the coagulated egg white decomposition product will be inactivated.

また、本発明の卵白加工食品の製造方法の要旨とするところは、前記凝固卵白分解物と前記発酵補助剤との混合比が、99:1〜1:99(重量比)であることにある。   Moreover, the place made into the summary of the manufacturing method of the egg white processed food of this invention exists in the mixing ratio of the said coagulated egg white decomposition product and the said fermentation adjuvant being 99: 1 to 1:99 (weight ratio). .

かかる構成により、卵白を主成分とした卵白加工食品を作製することも可能となる。   With this configuration, it is also possible to produce an egg white processed food containing egg white as a main component.

また、本発明の卵白加工食品の製造方法の要旨とするところは、前記pH調整剤が、クエン酸、酢酸、乳酸、グルコン酸、プロピオン酸から選択されることにある。   Moreover, the place made into the summary of the manufacturing method of the egg white processed food of this invention exists in the said pH adjuster being selected from a citric acid, an acetic acid, lactic acid, gluconic acid, and propionic acid.

かかる構成により、発酵補助剤・凝固卵白分解物混合体のpHを酸性側に調整することが容易となる。また、pH調整剤を摂取した場合の人体への悪影響を危惧することを要しない。   With this configuration, the pH of the fermentation aid / coagulated egg white decomposition product mixture can be easily adjusted to the acidic side. In addition, there is no need to worry about adverse effects on the human body when a pH adjuster is ingested.

また、本発明の卵白加工食品の製造方法の要旨とするところは、前記酵素がプロテイナーゼであることにある。   Moreover, the gist of the method for producing an egg white processed food of the present invention is that the enzyme is a proteinase.

かかる構成により、酵素分解された卵白が、より発酵菌に資化され易い態様となる。   With this configuration, the enzyme-degraded egg white is more easily assimilated by the fermenting bacteria.

また、本発明の卵白加工食品の製造方法の要旨とするところは、前記発酵菌が、プロピオン酸菌、乳酸菌、バチルス属乳酸菌、ビフィズス菌から選択されることにある。   Moreover, the gist of the method for producing an egg white processed food of the present invention is that the fermenting bacteria are selected from propionic acid bacteria, lactic acid bacteria, Bacillus lactic acid bacteria, and bifidobacteria.

かかる構成により、得られる卵白加工食品に種々の風味が付加されることとなる。   With this configuration, various flavors are added to the processed egg white processed food.

また、本発明の卵白加工食品の製造方法の要旨とするところは、前記発酵補助剤が、獣乳、脱脂乳から選択されることにある。   Moreover, the place made into the summary of the manufacturing method of the egg white processed food of this invention exists in the said fermentation adjuvant being selected from animal milk and skim milk.

かかる構成により、得られる卵白加工食品が、チーズ様の風味を呈することとなる。   With this configuration, the processed egg white processed food has a cheese-like flavor.

また、本発明の卵白加工食品の製造方法の要旨とするところは、前記発酵卵白を圧搾して、発酵卵白脱汁物とする工程を含んで構成されることにある。   Moreover, the place made into the summary of the manufacturing method of the egg white processed food of this invention exists in including the process of pressing the said fermented egg white and making it fermented egg white soup.

かかる構成により、発酵卵白に含まれていた水分が取り除かれるため、得られる卵白加工食品の利便性・保存性が上がることとなる。   With such a configuration, moisture contained in the fermented egg white is removed, so that the convenience and preservation of the obtained egg white processed food are improved.

また、本発明の卵白加工食品の製造方法の要旨とするところは、前記発酵卵白脱汁物を熟成する工程を含んで構成されることにある。   Moreover, the place made into the summary of the manufacturing method of the egg white processed food of this invention exists in including the process of aging the said fermented egg white soup.

かかる構成により、得られる卵白加工食品の風味がさらに向上することとなる。   With this configuration, the flavor of the processed egg white processed food is further improved.

本発明の卵白加工食品の製造方法は、先ず卵白を加熱して卵白中のリゾチ−ム等を失活させ、次いでかかる卵白を酵素で発酵菌の資化し易い態様とした後、発酵菌で卵白を発酵させて構成されるため、卵白の発酵時に発酵菌の働きが抑制されることが防がれる。このため、本発明の卵白加工食品の製造方法は、卵白への発酵補助剤の添加量を最小限に抑えても、卵白の発酵を十分に進めることが可能となり、卵白を主成分とした、したがって、低脂肪、低コレステロールで、かつ高たんぱく質の、卵白の有用性を十分に活かした機能性食品を得ることが可能となる。また、卵白を主成分とした卵白加工食品を製造した場合であっても、卵白の発酵が十分に進むことから、得られる卵白加工食品から硫黄臭が発生したり、卵の生臭さが残ることを抑えることができる。   In the method for producing a processed egg white food of the present invention, the egg white is first heated to inactivate lysozyme and the like in the egg white, and then the egg white is made into an embodiment in which the fermentation bacteria are easily assimilated with an enzyme. Therefore, it is possible to prevent the action of the fermenting bacteria from being suppressed during the fermentation of the egg white. For this reason, the method for producing an egg white processed food according to the present invention can sufficiently promote the fermentation of egg white even if the addition amount of the fermentation aid to the egg white is minimized, and the egg white is the main component. Therefore, it becomes possible to obtain a functional food that fully utilizes the usefulness of egg white, which is low in fat, low in cholesterol, and high in protein. In addition, even when an egg white processed food containing egg white as a main component is produced, the fermentation of the egg white proceeds sufficiently, so that the processed egg white processed food generates a sulfur odor or a raw egg odor remains. Can be suppressed.

本発明の卵白加工食品の製造方法は、発酵補助剤、及び凝固卵白分解物に対して、pH調整、及び加熱処理を施す工程を含むことにより、発酵補助剤、及び凝固卵白分解物に含まれる耐酸性の腐敗菌は加熱処理によって、また、耐熱性の腐敗菌にはpH調整によって、それぞれ効果的に殺菌される。このため、発酵卵白前駆体の発酵工程時に、腐敗菌が働いて、得られる卵白加工食品の風味を損ねることを防ぐことができる。   The manufacturing method of the egg white processed food of this invention is contained in a fermentation adjuvant and a coagulated egg white decomposition product by including the process of performing pH adjustment and heat processing with respect to a fermentation auxiliary agent and a coagulated egg white decomposition product. Acid-resistant spoilage bacteria are effectively sterilized by heat treatment, and heat-resistant spoilage bacteria are effectively sterilized by pH adjustment. For this reason, at the time of the fermentation process of a fermented egg white precursor, it can prevent that spoilage bacteria work and impair the flavor of the egg white processed food obtained.

また、本発明の卵白加工食品の製造方法は、発酵補助剤として牛乳等の獣乳を用いることにより、得られる卵白加工食品の風味、食感をチーズ様にすることができ、卵白加工食品に付加価値を付けることができる。   Moreover, the manufacturing method of the egg white processed food of this invention can make the flavor and texture of the obtained egg white processed food into cheese like by using animal milk such as milk as a fermentation aid, Can add value.

また、本発明の卵白加工食品の製造方法は、卵白の使用量を特に制限しないため、マヨネーズの製造等において大量に余った卵白を、廃棄することなく有効に利用する途を提供できる。   Moreover, since the manufacturing method of the egg white processed food of this invention does not restrict | limit the usage-amount of egg white in particular, it can provide the path | route which utilizes the egg white which was left in large quantities in mayonnaise manufacture etc., without discarding.

本発明にかかる卵白加工食品の製造方法について、以下に詳しく説明する。   The manufacturing method of the egg white processed food concerning this invention is demonstrated in detail below.

本発明の卵白加工食品の製造方法は、卵白を加熱して、凝固卵白とする工程と、凝固卵白に酵素を添加して、酵素・凝固卵白混合体とする工程と、酵素・凝固卵白混合体を留置して、凝固卵白分解物とする工程と、凝固卵白分解物に発酵補助剤を添加して発酵補助剤・凝固卵白分解物混合体とする工程と、発酵補助剤・凝固卵白分解物混合体にpH調整剤を添加して、発酵補助剤・凝固卵白分解物混合体のpHを酸性側に調整する工程と、かかるpH調整済み発酵補助剤・凝固卵白分解物混合体に発酵菌を添加して、発酵卵白前駆体とする工程と、発酵卵白前駆体を留置して、発酵卵白とする工程と、を含んで構成される。   The method for producing an egg white processed food of the present invention comprises a step of heating egg white to obtain a coagulated egg white, a step of adding an enzyme to the coagulated egg white to obtain an enzyme / coagulated egg white mixture, and an enzyme / coagulated egg white mixture. A process of adding a fermentation auxiliary to the coagulated egg white decomposition product to make a fermentation auxiliary agent / coagulated egg white decomposition product mixture, and a fermentation auxiliary agent / coagulated egg white decomposition product mixture Adding a pH adjuster to the body to adjust the pH of the fermentation aid / coagulated egg white decomposition product mixture to the acidic side, and adding fermenting bacteria to the pH adjusted fermentation aid / coagulated egg white decomposition product mixture And the process made into a fermented egg white precursor and the process which indwells a fermented egg white precursor and makes it fermented egg white are comprised.

本発明において用いる卵白の態様は、特に限定されるものではなく、割卵して得られる液状卵白の他、凍結卵白、粉末卵白のいずれであってもよく、また、これらを組み合わせて構成してもよい。ここで、卵白として凍結卵白を用いる場合には、卵白を加熱する工程の前に、かかる凍結卵白を解凍しておくことが好ましい。また、卵白として粉末卵白を用いる場合には、卵白を加熱する工程の前に、かかる粉末卵白に水を加えて、液状の卵白とする工程を要する。この際、粉末卵白に加える水の量は、粉末卵白と水の混合比で、10:90〜60:40(重量比)とすることが好ましい。なお、本発明にかかる卵白加工食品の製造コストの観点から、用いる卵白の態様は、液状卵白か凍結卵白であることが好ましい。   The aspect of the egg white used in the present invention is not particularly limited, and may be any of frozen egg white and powdered egg white in addition to liquid egg white obtained by splitting eggs, and may be configured by combining these. Also good. Here, when using frozen egg white as the egg white, it is preferable to thaw the frozen egg white before the step of heating the egg white. Moreover, when using powdered egg white as egg white, the process of adding water to this powdered egg white and making it liquid egg white is required before the process of heating egg white. At this time, the amount of water added to the powdered egg white is preferably 10:90 to 60:40 (weight ratio) in terms of the mixing ratio of the powdered egg white and water. In addition, it is preferable that the aspect of the egg white to be used is a liquid egg white or a frozen egg white from a viewpoint of the manufacturing cost of the egg white processed food concerning this invention.

本発明にかかる卵白を加熱して凝固卵白とする工程は、例えば、未加熱の卵白を蒸し器等を用いて加熱することにより行うことができる。これにより、卵白中のたんぱく質の立体構造が変化して、酵素が作用し易い態様となる。また、卵白中のリゾチ−ムやビタミン結合性タンパクやプロテアーゼ阻害剤等の、酵素や発酵菌の活性を低下させる物質が失活することとなる。このため、後の酵素による卵白の分解が促進できる。また、後の発酵工程において、発酵菌の活性が抑制されることを防止できる。   The step of heating the egg white according to the present invention to obtain a solidified egg white can be performed, for example, by heating the unheated egg white using a steamer or the like. Thereby, the three-dimensional structure of the protein in the egg white is changed, and the enzyme is likely to act. In addition, substances that reduce the activity of enzymes and fermenting bacteria such as lysozyme, vitamin-binding protein and protease inhibitors in egg white will be inactivated. For this reason, decomposition of the egg white by the subsequent enzyme can be promoted. Moreover, it can prevent that the activity of a fermentation microbe is suppressed in a later fermentation process.

本発明において、凝固卵白に添加される酵素としては、例えば、プロテアーゼやリパーゼやアミラーゼ、あるいはセルラーゼ等を挙げることができる。また、かかる酵素の群から選択される2種以上の酵素を組み合わせて用いてもよい。これにより、卵白が発酵菌の資化し易い態様に分解されることとなるため、後の卵白の発酵を十分に進めることが可能となる。なお、卵白をより発酵菌の資化し易い態様に変えるためには、かかる酵素はプロテアーゼを含んで構成されることが好ましく、さらには、かかるプロテアーゼの中でもプロテイナーゼを含んで構成されることがより好ましい。   In the present invention, examples of the enzyme added to the coagulated egg white include protease, lipase, amylase, and cellulase. Moreover, you may use combining 2 or more types of enzymes selected from the group of this enzyme. Thereby, since egg white will be decomposed | disassembled into the aspect which is easy to assimilate fermentation bacteria, it will become possible to fully advance fermentation of egg white after. In addition, in order to change the egg white into a mode that facilitates the assimilation of the fermenting bacteria, such an enzyme is preferably configured to include a protease, and more preferably includes a proteinase among such proteases. .

かかる酵素は、微生物、植物、動物のいずれの由来であってもよいが、食品加工用酵素であることが好ましい。また、かかる酵素の態様は、精製酵素に限られるものではなく、米麹などの菌体を酵素源として用いてもよい。   Such an enzyme may be derived from any microorganism, plant, or animal, but is preferably a food processing enzyme. Moreover, the aspect of this enzyme is not restricted to a refinement | purification enzyme, You may use microbial cells, such as a rice bran, as an enzyme source.

卵白に対する酵素の添加量は、卵白を加熱する工程の前の卵白に対して0.01〜0.1重量%の範囲であることが好ましい。かかる構成によって、酵素による卵白の分解が十分に進むこととなり、発酵菌にとって資化し易い栄養素がより多く卵白中に含まれることとなる。かかる酵素量が0.01%未満の場合には、卵白の分解を進めるのに長い時間を要することとなる。また、0.1%より多い場合には、卵白の分解に要する時間は短くなるものの、本発明の卵白加工食品の製造コストが上がることとなる。   The amount of enzyme added to the egg white is preferably in the range of 0.01 to 0.1% by weight with respect to the egg white before the step of heating the egg white. With this configuration, the decomposition of the egg white by the enzyme proceeds sufficiently, and more nutrients that are easily assimilated by the fermenting bacteria are contained in the egg white. When the amount of the enzyme is less than 0.01%, it takes a long time to proceed with the decomposition of the egg white. On the other hand, when the content is more than 0.1%, the time required for the decomposition of the egg white is shortened, but the production cost of the processed egg white food of the present invention is increased.

本発明において、凝固卵白分解物とする工程は、卵白に添加される酵素の活性が最大となる環境下で、酵素・凝固卵白混合体を一定時間留置して行えばよい。これにより、酵素による卵白の分解がより効率的になされることとなり、結果として、本発明にかかる卵白加工食品の製造期間を短縮することができる。例えば、酵素としてプロテイナーゼを用いる場合には、40〜60℃の範囲で酵素・凝固卵白混合体を留置することが好ましい。   In the present invention, the step of obtaining a coagulated egg white decomposition product may be performed by incubating the enzyme / coagulated egg white mixture for a certain period of time in an environment in which the activity of the enzyme added to the egg white is maximized. Thereby, the decomposition of egg white by an enzyme will be made more efficiently, and as a result, the production period of the processed egg white food according to the present invention can be shortened. For example, when proteinase is used as the enzyme, it is preferable to place the enzyme / coagulated egg white mixture in the range of 40 to 60 ° C.

本発明にかかる卵白は、加熱処理によってリゾチ−ム等が失活され、また、酵素分解によって発酵菌の資化し易い態様となっている。このため、卵白の発酵は、凝固卵白分解物に発酵菌のみを添加することによっても進めることはできる。しかしながら、かかる態様では、卵白の発酵速度が遅くなって、卵白加工食品の製造期間が長くなるおそれがある。このため、本発明にかかる卵白加工食品の製造方法は、凝固卵白分解物に発酵補助剤を添加する工程を含んで、卵白の発酵を速やかに進めることが好ましい。   The egg white according to the present invention has a mode in which lysozyme and the like are deactivated by heat treatment, and fermentation bacteria are easily assimilated by enzymatic degradation. For this reason, the fermentation of egg white can also proceed by adding only fermenting bacteria to the coagulated egg white decomposition product. However, in such an embodiment, there is a possibility that the fermentation rate of egg white becomes slow and the production period of the processed egg white food becomes longer. For this reason, it is preferable that the manufacturing method of the egg white processed food concerning this invention includes the process of adding a fermentation adjuvant to a coagulated egg white decomposition product, and to advance fermentation of egg white rapidly.

本発明において、卵白に添加される発酵補助剤としては、具体的に、牛乳や羊乳や山羊乳等の獣乳や脱脂乳、あるいはカゼイン等の乳類や、砂糖、乳糖、果糖、オリゴ糖等の糖類、果汁や野菜汁等を挙げることができる。また、これらの発酵補助剤の群から選択される2種以上の発酵補助剤を組み合わせて用いてもよい。これにより、卵白の発酵が速やかになされることとなり、卵白加工食品の製造期間を短縮することができる。なお、かかる発酵補助剤は、獣乳を含んで構成されることが好ましい。これにより、得られる卵白加工食品の風味がチーズ様となり、付加価値を付けることができる。また、発酵補助剤として脱脂乳を用いる場合には、かかる発酵補助剤は、脱脂乳にイーストエキスと脂肪とが混合された混合物であることが好ましい。   In the present invention, the fermentation aid added to the egg white specifically includes animal milk such as cow's milk, sheep milk, goat milk, skim milk, or milk such as casein, sugar, lactose, fructose, oligosaccharide. And sugars such as fruit juice and vegetable juice. Moreover, you may use combining 2 or more types of fermentation adjuvants selected from the group of these fermentation adjuvants. Thereby, fermentation of egg white will be made rapidly and the manufacturing period of the egg white processed food can be shortened. In addition, it is preferable that this fermentation adjuvant is comprised including animal milk. Thereby, the flavor of the egg white processed food obtained becomes cheese-like, and can add value. Moreover, when using skim milk as a fermentation adjuvant, it is preferable that this fermentation adjuvant is the mixture with which the yeast extract and fat were mixed with skim milk.

卵白に対する発酵補助剤の添加量は、卵白の発酵を促進できれば特に限定されるものではなく、凝固卵白分解物と発酵補助剤の混合比で、99:1〜1:99(重量比)の範囲であってもよい。ここで、発酵補助剤の添加量が多い程、後の発酵工程が速やかに進むため、卵白加工食品の製造期間を短くすることができ、また、卵白加工食品に発酵補助剤由来の風味を強く付けることができる。なお、かかる態様では、卵白の含有量が低くなるため、低脂肪、低コレステロールの食品を得ることが困難となる。このため、発酵補助剤の添加量は、凝固卵白分解物と発酵補助剤の混合比で、95:5〜80:20(重量比)の範囲内としてもよい。かかる構成により、後の発酵を速やかに進めて、卵白加工食品の製造期間を短くすることができる上に、低脂肪、低コレステロールで、かつ高たんぱく質の、したがって卵白の特質を十分に活かした機能性食品を得ることが可能となる。   The addition amount of the fermentation aid to the egg white is not particularly limited as long as the fermentation of the egg white can be promoted, and the mixture ratio of the coagulated egg white decomposition product and the fermentation aid ranges from 99: 1 to 1:99 (weight ratio). It may be. Here, the greater the amount of fermentation aid added, the faster the subsequent fermentation process will proceed, so the production period of the processed egg white food can be shortened, and the flavor derived from the fermented supplement is strongly enhanced in the processed egg white food. Can be attached. In this embodiment, since the egg white content is low, it is difficult to obtain a low-fat, low-cholesterol food. For this reason, the addition amount of a fermentation auxiliary agent is good also in the range of 95: 5-80: 20 (weight ratio) by the mixing ratio of a coagulated egg white decomposition product and a fermentation auxiliary agent. With this configuration, the subsequent fermentation can be rapidly advanced to shorten the production period of the processed egg white food, and the function of making full use of the characteristics of low fat, low cholesterol, high protein, and thus egg white. It becomes possible to obtain sex food.

本発明において、発酵補助剤・凝固卵白分解物混合体にpH調整剤を添加して、そのpHを酸性側に調整する工程は、かかる発酵補助剤・凝固卵白分解物混合体のpHを4〜6の範囲となるように行うことが好ましく、4〜5.5の範囲となるように行うことがより好ましく、4〜5.0の範囲となるように行うことがさらに好ましい。これにより、後の発酵工程において、発酵補助剤及び凝固卵白分解物中に含まれる、pH6〜10付近に至適pHを有する腐敗菌が作用することが妨げられるため、得られる卵白加工食品から腐敗臭がすることを防ぐことができる。特に、かかるpHを5.0以下とすることにより、発酵工程における上記腐敗菌の活性をほぼ完全に抑制することができる。なお、かかるpHが4未満である場合には、発酵工程における発酵菌の活性も抑制されるおそれがある。また、pHが6より高い場合には、かかる腐敗菌の活性を抑制することができない。   In the present invention, the step of adding a pH adjusting agent to the fermentation auxiliary agent / coagulated egg white decomposition product mixture and adjusting the pH to the acidic side is performed by adjusting the pH of the fermentation auxiliary agent / coagulated egg white decomposition product mixture to 4 to 4. It is preferably carried out so as to be in the range of 6, more preferably carried out so as to be in the range of 4 to 5.5, further preferably carried out so as to be in the range of 4 to 5.0. As a result, in the subsequent fermentation step, it is prevented from the action of spoilage bacteria having an optimum pH in the vicinity of pH 6 to 10 contained in the fermentation aid and the coagulated egg white decomposition product. It can prevent smell. In particular, by setting the pH to 5.0 or less, the activity of the spoilage bacteria in the fermentation process can be almost completely suppressed. In addition, when this pH is less than 4, there exists a possibility that the activity of the fermentation microbe in a fermentation process may also be suppressed. Moreover, when pH is higher than 6, the activity of such spoilage bacteria cannot be suppressed.

本発明において用いるpH調整剤は、有機酸であることが好ましい。かかる有機酸としては、具体的には、クエン酸、酢酸、乳酸、グルコン酸、プロピオン酸等を挙げることができる。また、かかる有機酸の群から選択される2種以上の有機酸を組み合わせて用いてもよい。かかる有機酸は、発酵補助剤・凝固卵白分解物混合体のpHを4〜6の範囲に調整することを容易とし、かつ摂取しても人体に悪影響を与えるおそれがない。   The pH adjuster used in the present invention is preferably an organic acid. Specific examples of such organic acids include citric acid, acetic acid, lactic acid, gluconic acid, and propionic acid. Two or more organic acids selected from the group of organic acids may be used in combination. Such an organic acid makes it easy to adjust the pH of the fermentation auxiliary agent / coagulated egg white decomposition product mixture to a range of 4 to 6, and even when ingested, there is no possibility of adversely affecting the human body.

本発明において、かかるpH調整済み発酵補助剤・凝固卵白分解物混合体に添加される発酵菌としては、例えば、プロピオン酸菌、乳酸菌、バチルス属乳酸菌、ビフィズス菌等を挙げることができる。これらの発酵菌を用いることにより、酵素で分解処理した卵白の発酵を十分に進めることが可能となるだけでなく、得られる卵白加工食品に発酵製品特有の食感、風味が付加されることとなり、その付加価値を上げることができる。なお、本発明で用いる発酵菌は、かかる発酵菌の群から選択される2種以上の発酵菌を組み合わして構成されてもよいが、いずれの態様にあっても、かかる発酵菌(群)は、至適pHを4〜6に有してなる発酵菌(群)であることが好ましい。これにより、発酵卵白前駆体中における発酵菌(群)の活性が最大となって、卵白の発酵を迅速に進めることができる。   In the present invention, examples of fermenting bacteria added to the pH-adjusted fermentation aid / coagulated egg white decomposition product mixture include propionic acid bacteria, lactic acid bacteria, Bacillus lactic acid bacteria, and bifidobacteria. By using these fermenting bacteria, it is possible not only to sufficiently ferment the egg white decomposed with enzymes, but also to add the texture and flavor unique to the fermented product to the processed egg white processed food. , Can increase its added value. In addition, although the fermenting bacteria used by this invention may be comprised combining 2 or more types of fermenting bacteria selected from this group of fermenting bacteria, even if it exists in any aspect, this fermenting bacteria (group) Is preferably a fermenting bacterium (group) having an optimum pH of 4-6. Thereby, the activity of the fermenting bacteria (group) in the fermented egg white precursor is maximized, and the fermentation of the egg white can be rapidly advanced.

本発明において用いる発酵菌の添加量は、pH調整済み発酵補助剤・凝固卵白分解物混合体1gに対して生菌数で10〜10個程度であることが好ましい。かかる態様により、発酵菌に要するコストを低く抑えつつ、短期間で本発明の卵白加工食品を製造することが可能となる。 The amount of fermented bacteria used in the present invention is preferably about 10 5 to 10 8 in terms of the number of viable bacteria per 1 g of the pH-adjusted fermentation aid / coagulated egg white decomposition product mixture. Such an embodiment makes it possible to produce the egg white processed food of the present invention in a short period of time while keeping the cost required for the fermenting bacteria low.

ここで、発酵菌の添加量が10個未満である場合には、発酵卵白前駆体中の凝固卵白分解物を十分に発酵するために長期間を要することとなる。また、発酵卵白前駆体が発酵工程中に腐敗菌で汚染されてしまうおそれがある。また、10個よりも多くした場合には、発酵卵白前駆体中の凝固卵白分解物の発酵は短期間で行うことができるものの、液体培養等によってグラム単位で10個よりも多い菌液を調製しようとする場合に、遠心分離機などの設備や特別な培地が必要となるため、卵白加工食品の製造コストが上がることとなる。 Here, if the addition amount of the fermentation bacteria is 10 less than 5 pieces, it takes a long time to fully fermented coagulated egg white hydrolyzate fermented egg white precursor. In addition, the fermented egg white precursor may be contaminated with spoilage bacteria during the fermentation process. In addition, when the number is more than 10 8 , fermentation of the coagulated egg white decomposition product in the fermented egg white precursor can be performed in a short period of time, but more than 10 8 bacterial solutions in grams by liquid culture or the like. In order to prepare this, since equipment such as a centrifuge and a special medium are required, the production cost of the processed egg white food is increased.

ここで、pH調整済み発酵補助剤・凝固卵白分解物混合体に添加される発酵菌の態様は、生菌体や凍結菌体、凍結乾燥菌体、菌体培養液のいずれであってよいが、生菌であることが好ましい。   Here, the aspect of the fermenting bacteria added to the pH-adjusted fermentation aid / coagulated egg white decomposition product mixture may be any of live cells, frozen cells, freeze-dried cells, and cell culture fluids. Preferably, it is a viable bacterium.

本発明において、発酵卵白を得る工程は、卵白に添加される発酵菌の活性が最大となる環境下で、発酵卵白前駆体を一定時間留置して行えばよい。これにより、卵白の発酵が速やかになされることとなり、本発明にかかる卵白加工食品の製造期間を短縮することができる。例えば、発酵菌としてPropionibacterium freudenreichiiを用いる場合には、30〜40℃の範囲で発酵卵白前駆体を留置することが好ましい。   In the present invention, the step of obtaining fermented egg white may be performed by placing the fermented egg white precursor for a certain period of time in an environment in which the activity of the fermenting bacteria added to the egg white is maximized. Thereby, fermentation of egg white will be made rapidly and the manufacturing period of the egg white processed food concerning this invention can be shortened. For example, when Propionibacterium freudenreichii is used as the fermenting bacterium, it is preferable to place the fermented egg white precursor in the range of 30 to 40 ° C.

以上、本発明の卵白加工食品の一実施例を詳述したが、本発明は上述の実施例に限定されるものではなく、その他の態様でも実施し得るものである。   As mentioned above, although one Example of the processed egg white processed food of this invention was explained in full detail, this invention is not limited to the above-mentioned Example, It can implement also in another aspect.

本発明において、発酵補助剤を添加する工程は、凝固卵白分解物に発酵補助剤を添加して行う態様に限られるものではなく、後の卵白の発酵を促進できればいずれの態様でなされてもよい。したがって、本発明の卵白加工食品の製造方法は、例えば、卵白に発酵補助剤を添加して、発酵補助剤・卵白混合体とする工程と、発酵補助剤・卵白混合体を加熱して、発酵補助剤・凝固卵白混合体とする工程と、発酵補助剤・凝固卵白混合体に酵素を添加して、酵素・発酵補助剤・凝固卵白混合体とする工程と、酵素・発酵補助剤・凝固卵白混合体を留置して、発酵補助剤・凝固卵白分解物混合体とする工程と、発酵補助剤・凝固卵白分解物混合体にpH調整剤を添加して、発酵補助剤・凝固卵白分解物混合体のpHを酸性側に調整する工程と、かかるpH調整済み発酵補助剤・凝固卵白分解物混合体に発酵菌を添加して、発酵卵白前駆体とする工程と、発酵卵白前駆体を留置して、発酵卵白とする工程と、を含んで構成されてもよい。   In the present invention, the step of adding the fermentation aid is not limited to the embodiment performed by adding the fermentation aid to the coagulated egg white decomposition product, and may be performed in any manner as long as the subsequent fermentation of egg white can be promoted. . Therefore, the method for producing an egg white processed food of the present invention includes, for example, a step of adding a fermentation aid to egg white to form a fermentation aid / egg white mixture, and heating the fermentation aid / egg white mixture to ferment A step of making an auxiliary agent / coagulated egg white mixture, a step of adding an enzyme to the fermentation auxiliary agent / coagulated egg white mixture to make an enzyme / fermentation auxiliary agent / coagulated egg white mixture, and an enzyme / fermentation auxiliary agent / coagulated egg white The process of placing the mixture into a fermentation aid / coagulated egg white decomposition product mixture, and adding a pH adjuster to the fermentation aid / coagulated egg white decomposition product mixture, mixing the fermentation aid / coagulated egg white decomposition product The step of adjusting the pH of the body to the acidic side, the step of adding fermentative bacteria to the pH-adjusted fermentation aid / coagulated egg white decomposition product mixture to make a fermented egg white precursor, and the fermented egg white precursor are left in place And a step of producing fermented egg white.

本発明において、発酵卵白前駆体とする工程は、pH調整済み発酵補助剤・凝固卵白分解物混合体とする工程の後、かかる混合体に発酵菌を添加して行う態様に限定されるものではなく、凝固卵白分解物に発酵菌が植菌される態様であればよい。したがって、発酵卵白前駆体とする工程は、例えば、予め発酵菌が発酵補助剤中で培養されてなる発酵菌含有発酵補助剤を調製し、かかる発酵菌含有発酵補助剤と凝固卵白分解物とpH調整剤とを混合することによって行ってもよい。   In the present invention, the step of making a fermented egg white precursor is not limited to an embodiment in which after the step of making a pH-adjusted fermentation aid / coagulated egg white decomposition product mixture, fermenting bacteria are added to the mixture. There is no limitation as long as the fermenting bacteria are inoculated into the coagulated egg white decomposition product. Therefore, the process which makes a fermented egg white precursor, for example, prepares a fermenting fungus-containing fermentation aid in which fermenting bacteria are cultured in advance in a fermentation aid, such fermenting fungus-containing fermentation aid, coagulated egg white decomposition product, and pH You may carry out by mixing with a regulator.

本発明にかかる卵白加工食品の製造方法は、凝固卵白分解物や発酵補助剤に含まれて、発酵工程において上記のpH環境下にあってもその活性を低下させない耐酸性の腐敗菌を殺菌し、また、凝固卵白分解物に含まれる酵素を失活させるために、凝固卵白分解物や発酵補助剤を加熱処理する工程を含んで構成されることが好ましい。これにより、得られる卵白加工食品から腐敗臭がすることを防ぎ、また、発酵菌の働きによってのみ凝固卵白分解物を発酵させることができる。   The method for producing an egg white processed food according to the present invention sterilizes acid-resistant spoilage bacteria that are contained in a coagulated egg white decomposition product and a fermentation aid and do not decrease the activity even in the fermentation process even under the above pH environment. Moreover, in order to inactivate the enzyme contained in the coagulated egg white decomposition product, it is preferable to include a step of heat-treating the coagulated egg white decomposition product and the fermentation aid. Thereby, it is possible to prevent a rotten odor from being obtained from the processed egg white processed food, and to ferment the coagulated egg white decomposition product only by the action of the fermenting bacteria.

ここで、凝固卵白分解物や発酵補助剤を加熱処理する工程は、凝固卵白分解物に発酵菌を植菌する前になされていればよく、また、発酵菌を発酵補助剤中で培養する場合には、発酵補助剤に発酵菌を植菌する前になされていればよい。したがって、本発明の卵白加工食品の製造方法は、pH調整済み発酵補助剤・凝固卵白分解物混合体とする工程において、凝固卵白分解物と発酵補助剤とpH調整剤とを混合した後、加熱する工程を含んで構成されてもよい。また、凝固卵白分解物と発酵補助剤とを混合する工程の前にあって、かつ発酵菌を植菌する前に、予め凝固卵白分解物と発酵補助剤とを別個独立に加熱処理する工程を含んで構成されても構わない。かかる加熱処理工程は、例えば、かかる発酵補助剤や凝固卵白分解物をオートクレーブを用いて加熱することによって行うことができる。   Here, the process of heat-treating the coagulated egg white decomposition product and the fermentation auxiliary may be performed before inoculating the fermented bacteria into the coagulated egg white decomposition product, and when the fermentation bacteria are cultured in the fermentation auxiliary For example, it may be performed before inoculating fermenting bacteria in the fermentation aid. Therefore, the method for producing a processed egg white food according to the present invention comprises a step of mixing a coagulated egg white hydrolyzate, a fermentation auxiliary, and a pH adjuster in the step of preparing a pH-adjusted fermentation auxiliary / coagulated egg white decomposition product mixture, followed by heating. You may comprise including the process to do. In addition, before the step of mixing the coagulated egg white decomposition product and the fermentation aid, and before inoculating the fermenting bacteria, a step of separately heating the coagulated egg white decomposition product and the fermentation auxiliary separately in advance. You may be comprised including. Such a heat treatment step can be performed, for example, by heating the fermentation aid or the coagulated egg white decomposition product using an autoclave.

本発明においては、発酵卵白前駆体の発酵工程中に、pH6〜10付近に至適pHを有する腐敗菌の増殖が抑えられるように、発酵工程前の発酵卵白前駆体のpHが4〜6に調整されて構成されていればよい。すなわち、発酵卵白前駆体のpHを調整する工程は、発酵補助剤・凝固卵白分解物混合体にpH調整剤を添加して行う態様に限られるものではなく、発酵卵白前駆体の発酵工程より前になされていれば、いずれの段階でなされてもよい。   In the present invention, during the fermentation process of the fermented egg white precursor, the pH of the fermented egg white precursor before the fermentation process is adjusted to 4-6 so that the growth of spoilage bacteria having an optimum pH around pH 6-10 is suppressed. What is necessary is just to be adjusted and comprised. That is, the step of adjusting the pH of the fermented egg white precursor is not limited to an embodiment in which a pH adjuster is added to the fermentation auxiliary agent / coagulated egg white decomposition product mixture, but before the fermentation step of the fermented egg white precursor. As long as it is done, it may be done at any stage.

したがって、本発明にかかる発酵卵白前駆体のpH調整は、卵白を凝固卵白とする工程前の(液状の)卵白や、卵白を加熱して得られる凝固卵白や、凝固卵白に酵素を添加して得られる酵素・凝固卵白混合体や、酵素・凝固卵白混合体を留置して得られる凝固卵白分解物や、発酵補助剤・凝固卵白分解物混合体に発酵菌を添加して得られる発酵卵白前駆体の、少なくともいずれか一つにpH調整剤を添加することによって行ってもよい。   Therefore, the pH adjustment of the fermented egg white precursor according to the present invention is performed by adding an enzyme to the (liquid) egg white before the process of converting the egg white into a coagulated egg white, the coagulated egg white obtained by heating the egg white, or the coagulated egg white. The obtained enzyme / coagulated egg white mixture, the coagulated egg white decomposition product obtained by placing the enzyme / coagulated egg white mixture, and the fermented egg white precursor obtained by adding fermentation bacteria to the fermentation auxiliary agent / coagulated egg white decomposition product mixture You may carry out by adding a pH adjuster to at least any one of the body.

なお、かかるpH調整が、凝固卵白とする工程前の(液状の)卵白にpH調整剤を添加して行う場合には、後に、かかるpH調整済みの卵白を加熱して凝固卵白とする工程において、卵白から大量の泡(炭酸ガス)の発生が起こり、卵白を蓄える容器から卵白が噴き出るおそれがある。このため、かかるpH調整済みの卵白を加熱して凝固卵白とする工程は、脱気しながら行うことが好ましい。   In the case where such pH adjustment is performed by adding a pH adjusting agent to the (liquid) egg white before the step of solidifying egg white, in the step of heating the pH adjusted egg white to obtain the solidified egg white later. A large amount of bubbles (carbon dioxide gas) is generated from the egg white, and the egg white may be ejected from a container for storing the egg white. For this reason, it is preferable to carry out the step of heating the pH-adjusted egg white to obtain coagulated egg white while deaeration.

割卵して得られる卵白のpHは一般的に高く(pH8.5〜9.5)、したがって、かかる卵白を加熱して得られる凝固卵白のpHも高い。その一方、かかる凝固卵白に添加される酵素は、至適pHを中性から酸性域に有するものが多い。このため、本発明にかかる卵白加工食品の製造方法において、凝固卵白を酵素分解して、凝固卵白分解物とする工程は、凝固卵白のpHを卵白本来のpHよりも低く抑えて、酵素の活性を促進して行うことが好ましく、かかる構成により、卵白加工食品の製造期間を短くすることができる。   The pH of egg white obtained by dividing eggs is generally high (pH 8.5 to 9.5), and therefore the pH of coagulated egg white obtained by heating such egg white is also high. On the other hand, many enzymes added to the coagulated egg white have an optimum pH in a neutral to acidic range. For this reason, in the method for producing an egg white processed food according to the present invention, the step of enzymatically degrading the coagulated egg white to obtain a coagulated egg white decomposed product suppresses the pH of the coagulated egg white to be lower than the original pH of the egg white, It is preferable to promote this, and such a configuration can shorten the production period of the processed egg white food.

このため、本発明の卵白加工食品の製造方法が、発酵卵白前駆体のpH調整を、上述のように、卵白を凝固卵白とする工程前の(液状の)卵白や、卵白を加熱して得られる凝固卵白や、凝固卵白に酵素を添加して得られる酵素・凝固卵白混合体にpH調整剤を添加して行わない場合には、本発明の卵白加工食品の製造方法は、かかる(液状の)卵白や、凝固卵白、あるいは酵素・凝固卵白混合体の少なくともいずれか一つにpH調整剤を添加する工程を含んで構成されることが好ましい。ここで、凝固卵白混合体のpHは、卵白が本来示すpHよりも低ければ特に限定されるものではないが、凝固卵白に添加される酵素の活性が最大となるように、4〜7に調整されることが好ましく、6〜7に調整されることがより好ましい。   For this reason, the manufacturing method of the processed egg white food of the present invention obtains the pH adjustment of the fermented egg white precursor by heating the egg white before the step of converting the egg white into a solidified egg white or the egg white as described above. When the pH adjuster is not added to the coagulated egg white or the enzyme / coagulated egg white mixture obtained by adding the enzyme to the coagulated egg white, the method for producing an egg white processed food according to the present invention is It is preferable to include a step of adding a pH adjusting agent to at least one of egg white, coagulated egg white, and enzyme / coagulated egg white mixture. Here, the pH of the coagulated egg white mixture is not particularly limited as long as it is lower than the pH originally shown by the egg white, but it is adjusted to 4 to 7 so that the activity of the enzyme added to the coagulated egg white is maximized. It is preferable that it is adjusted, and it is more preferable to adjust to 6-7.

本発明の卵白加工食品の製造方法は、発酵卵白前駆体を留置して、発酵卵白とする工程の後に、得られる発酵卵白を圧搾する工程を含んで構成されても構わない。これにより、発酵卵白から水分が取り除かれることとなるため、得られる卵白加工食品の取り扱いが容易となる。また、卵白加工食品の保存性を上げることができる。さらに、卵白加工食品を濃厚な味わいとすることができる。   The manufacturing method of the processed egg white food of this invention may be comprised including the process of squeezing the obtained fermented egg white after the process of indwelling fermented egg white precursor and making it fermented egg white. Thereby, since water | moisture content will be removed from fermented egg white, handling of the obtained egg white processed food becomes easy. Moreover, the preservability of the egg white processed food can be improved. Furthermore, the egg white processed food can have a rich taste.

また、本発明の卵白加工食品の製造方法は、発酵卵白、あるいは前記圧搾工程後に得られる発酵卵白脱汁物を熟成する工程を含んで構成されても構わない。これにより、得られる卵白加工食品の風味が、より味わい深いものとなるため、その付加価値を上げることができる。なお、かかる熟成工程は、発酵卵白、あるいは発酵卵白脱汁物をフィルムで覆うなどして、低酸素状態で行うことが好ましい。また、熟成する期間は、2週間〜3か月の範囲で行うことが好ましい。かかる構成により、発酵卵白の酸化、及び腐敗が防止されるとともに、発酵卵白の熟成を十分に進めることができる。なお、かかる熟成期間が2週間未満では、発酵卵白の熟成を十分に進めることができない。また、3か月より多くした場合には、発酵卵白の熟成がさらに進むこととなるが、製造期間が長期となって、卵白加工食品の製造コストを上げることとなる。   Moreover, the manufacturing method of the egg white processed food of this invention may be comprised including the process of aging fermented egg white or the fermented egg white soup obtained after the said pressing process. Thereby, since the flavor of the egg white processed food obtained becomes deeper, its added value can be increased. In addition, it is preferable to perform this aging process in a low-oxygen state, such as covering fermented egg white or fermented egg white soup with a film. Moreover, it is preferable to carry out the aging period in the range of 2 weeks to 3 months. With such a configuration, oxidation and decay of the fermented egg white can be prevented, and the ripening of the fermented egg white can be sufficiently advanced. If the aging period is less than 2 weeks, aging of fermented egg white cannot be sufficiently advanced. Moreover, when it increases more than three months, ripening of fermented egg white will advance further, However, A manufacturing period will become long and will raise the manufacturing cost of egg white processed food.

その他、本発明はその趣旨を逸脱しない範囲内で、当業者の知識に基づき種々なる改良、修正、変形を加えた態様で実施しうるものである。   In addition, the present invention can be carried out in a mode in which various improvements, modifications, and variations are added based on the knowledge of those skilled in the art without departing from the spirit of the present invention.

以下に本発明を実施例に基づいて説明するが、本発明はこれらの実施例に限定されるものではない。
(実施例1)
The present invention will be described below based on examples, but the present invention is not limited to these examples.
(Example 1)

殻付きの生卵を割卵した後、卵黄を分離して液状卵白を得、この液状卵白100gを蒸し器で15分間蒸して凝固卵白とした。次に、この凝固卵白を細かく砕き、ここに酵素剤としてウマミザイムG(天野エンザイム株式会社製)0.01gを添加して、酵素・凝固卵白混合体を得た。次に、この混合体を50℃下、15〜20時間留置して凝固卵白を酵素分解し、凝固卵白分解物を得た。次に、この凝固卵白分解物に牛乳11.1g、クエン酸0.76gをそれぞれ添加し、pH調整済み(pH:5.0)発酵補助剤・凝固卵白分解物混合体を得た。次に、この混合体を80℃下、約10分間留置して、発酵補助剤及び凝固卵白分解物の滅菌を行った。次に、加熱処理後の混合体を35℃になるまで冷却した後、発酵菌としてPropionibacterium freudenreichii菌体を、加熱処理後の発酵補助剤・凝固卵白分解物混合体1gに対して最終生菌数10個の濃度で添加して、発酵卵白前駆体を得た。次に、この発酵卵白前駆体を35℃下、1日毎に撹拌を行いながら6日間留置して、発酵卵白を得た。次に、この発酵卵白を濾布で包み、圧搾機で余分な水分を脱汁し、発酵卵白脱汁物を得た。次に、得られた発酵卵白脱汁物に最終濃度2%となるように食塩を添加した。次に、かかる含食塩脱汁物をラップで包み、さらにアルミホイルで包んだ後、5〜15℃の低温で熟成発酵し、本発明の卵白加工食品を作製した。得られた卵白加工食品について、官能テストを行った。その結果を表1に示す。 After breaking the shelled raw egg, the yolk was separated to obtain a liquid egg white, and 100 g of this liquid egg white was steamed for 15 minutes in a steamer to obtain a solidified egg white. Next, this coagulated egg white was finely crushed, and 0.01 g of Umamizyme G (manufactured by Amano Enzyme Co., Ltd.) was added as an enzyme agent to obtain an enzyme / coagulated egg white mixture. Next, this mixture was left at 50 ° C. for 15 to 20 hours to enzymatically decompose the coagulated egg white to obtain a coagulated egg white decomposition product. Next, 11.1 g of milk and 0.76 g of citric acid were added to the coagulated egg white decomposition product, respectively, to obtain a pH adjusted (pH: 5.0) fermentation aid / coagulated egg white decomposition product mixture. Next, this mixture was left at 80 ° C. for about 10 minutes to sterilize the fermentation aid and the coagulated egg white decomposition product. Next, after cooling the mixture after the heat treatment to 35 ° C., Propionibacterium freudenreichii cells as the fermenting bacteria, the final viable cell count with respect to 1 g of the fermentation aid / coagulated egg white decomposition product mixture after the heat treatment 10 6 concentrations were added to obtain a fermented egg white precursor. Next, this fermented egg white precursor was left at 35 ° C. for 6 days with stirring every day to obtain fermented egg white. Next, this fermented egg white was wrapped with a filter cloth, and excess water was squeezed with a press to obtain a fermented egg white lysate. Next, salt was added to the obtained fermented egg white juice so as to have a final concentration of 2%. Next, after wrapping the salt-containing dessert with wrap and further wrapping with aluminum foil, it was aged and fermented at a low temperature of 5 to 15 ° C. to produce the egg white processed food of the present invention. The obtained egg white processed food was subjected to a sensory test. The results are shown in Table 1.

Figure 2005117915
(実施例2)
Figure 2005117915
(Example 2)

実施例1において、凝固卵白を細かく砕き、ここに酵素剤としてウマミザイムG(天野エンザイム株式会社製)0.01gとクエン酸0.38gとを添加して、pH6〜7の酵素・凝固卵白混合体を得、次に、この混合体を50℃下、15〜20時間留置して凝固卵白を酵素分解し、凝固卵白分解物を得、次に、この凝固卵白分解物に牛乳11.1g、クエン酸0.38gをそれぞれ添加し、pH調整済み(pH:5.0)発酵補助剤・凝固卵白分解物混合体を得た以外は実施例1と同様にして、本発明の卵白加工食品を作製した。得られた卵白加工食品について、官能テストを行った。その結果を表1に示す。
(比較例1)
In Example 1, the coagulated egg white was finely crushed, and 0.01 g of Umamizyme G (manufactured by Amano Enzyme Co., Ltd.) and 0.38 g of citric acid were added as enzyme agents, and the enzyme / coagulated egg white mixture at pH 6-7 Next, this mixture is allowed to stand at 50 ° C. for 15 to 20 hours to enzymatically decompose the coagulated egg white to obtain a coagulated egg white decomposed product. The processed egg white processed food of the present invention was prepared in the same manner as in Example 1 except that 0.38 g of acid was added and the pH adjusted (pH: 5.0) fermentation aid / coagulated egg white decomposition product mixture was obtained. did. The obtained egg white processed food was subjected to a sensory test. The results are shown in Table 1.
(Comparative Example 1)

実施例2において、凝固卵白に酵素剤を添加しない以外は実施例2と同様にして、卵白加工食品を作製した。得られた卵白加工食品についての官能テストの結果を表1に示す。
(比較例2)
In Example 2, an egg white processed food was prepared in the same manner as in Example 2 except that the enzyme agent was not added to the coagulated egg white. Table 1 shows the results of the sensory test for the obtained egg white processed food.
(Comparative Example 2)

実施例2において、凝固卵白分解物にクエン酸を添加しない以外は実施例2と同様にして、卵白加工食品を作製した。得られた卵白加工食品についての官能テストの結果を表1に示す。
(比較例3)
In Example 2, an egg white processed food was prepared in the same manner as in Example 2 except that citric acid was not added to the coagulated egg white decomposition product. Table 1 shows the results of the sensory test for the obtained egg white processed food.
(Comparative Example 3)

実施例2において、凝固卵白分解物に牛乳を添加しない以外は実施例2と同様にして、卵白加工食品を作製した。得られた卵白加工食品についての官能テストの結果を表1に示す。   In Example 2, an egg white processed food was prepared in the same manner as in Example 2 except that milk was not added to the coagulated egg white decomposition product. Table 1 shows the results of the sensory test for the obtained egg white processed food.

実施例1の結果から、得られる卵白加工食品は、卵白の含有量を約90重量部としても、硫黄臭がしないことが分かった。このため、本発明にかかる製造方法は、卵白を主成分としていながら、硫黄臭のしない卵白加工食品を作製することが可能であることが分かった。   From the results of Example 1, it was found that the processed egg white processed food did not have a sulfur odor even when the egg white content was about 90 parts by weight. For this reason, it turned out that the manufacturing method concerning this invention can produce the egg white processed food which does not have a sulfur smell, making egg white a main component.

また、得られる卵白加工食品からヨーグルトの様な爽やかな酸味が漂い、またチーズの様な匂いがしており、さらに、風味については、チーズらしいほろ苦い感じがしたことから、本発明にかかる製造方法は、得られる卵白加工食品の付加価値を上げ得ることが分かった。   In addition, the processed egg white processed food has a refreshing sour taste like yogurt, smells like cheese, and the flavor has a bitter taste like cheese, so the production method according to the present invention Was found to increase the added value of the processed egg white processed food.

また、実施例2の結果から、凝固卵白のpHを調整することにより、実施例1と同様の食味、食感が得られる上に、凝固卵白の酵素分解を速やかに進め得ることがわかった。   Moreover, from the results of Example 2, it was found that by adjusting the pH of the coagulated egg white, the same taste and texture as in Example 1 can be obtained, and the enzymatic decomposition of the coagulated egg white can be rapidly advanced.

また、実施例1及び2と比較例1の結果から、凝固卵白を酵素処理しない場合には、得られる卵白加工食品からチーズの様な匂いが殆んどせず、硫黄臭がしており、また、凝固卵白の固さが残って食感も悪かったことから、発酵が十分に進まないことが分かった。   In addition, from the results of Examples 1 and 2 and Comparative Example 1, when the coagulated egg white is not treated with an enzyme, the resulting egg white processed food has little cheese-like odor and has a sulfur odor. In addition, it was found that the fermentation did not proceed sufficiently because the solidified egg whites remained hard and the texture was poor.

また、実施例1及び2と比較例2の結果から、発酵卵白前駆体のpHを調整しない場合には、卵白の発酵は進んでいるものの、得られる卵白加工食品から納豆の様な匂いが漂うことから、発酵工程において、凝固卵白分解物や牛乳を加熱・殺菌してもなお生き残る納豆菌等の耐熱性菌が増殖することが分かった。   Moreover, from the results of Examples 1 and 2 and Comparative Example 2, when the pH of the fermented egg white precursor is not adjusted, the fermentation of the egg white proceeds, but the obtained egg white processed food has a natto-like odor. Therefore, it was found that heat-resistant bacteria such as Bacillus natto that survive the heating and sterilization of the coagulated egg white decomposition product and milk grow in the fermentation process.

また、実施例1及び2と比較例3の結果から、牛乳(発酵補助剤)を添加しない場合には、発酵工程において発酵菌は若干生育するものの、得られる卵白加工食品には、依然として卵の生臭さや硫黄臭がすることから、発酵を十分に進めるためには長時間を要することが分かった。

In addition, from the results of Examples 1 and 2 and Comparative Example 3, when milk (fermentation aid) is not added, the fermented bacteria grow slightly in the fermentation process, but the processed egg white processed food still contains egg. It was found that it takes a long time to fully proceed the fermentation because of the raw smell and sulfur smell.

Claims (12)

卵白を加熱して、凝固卵白とする工程と、
前記凝固卵白と酵素とを混合して、酵素・凝固卵白混合体とする工程と、
前記酵素・凝固卵白混合体を留置して、凝固卵白分解物とする工程と、
前記凝固卵白分解物と発酵補助剤とを混合して、発酵補助剤・凝固卵白分解物混合体とする工程と、
前記発酵補助剤・凝固卵白分解物混合体と発酵菌とを混合して、発酵卵白前駆体とする工程と、
前記発酵卵白前駆体を留置して、発酵卵白とする工程と、
を含んで構成され、前記発酵卵白前駆体のpHが、pH調整剤を用いて4〜6に調整されてなる卵白加工食品の製造方法。
Heating the egg white to obtain a solidified egg white;
Mixing the coagulated egg white and the enzyme to obtain an enzyme / coagulated egg white mixture;
A step of placing the enzyme / coagulated egg white mixture into a coagulated egg white decomposition product;
Mixing the coagulated egg white decomposition product and the fermentation auxiliary agent to obtain a fermentation auxiliary agent / coagulated egg white decomposition product mixture;
Mixing the fermentation auxiliary agent / coagulated egg white decomposition product mixture and the fermenting bacteria to make a fermented egg white precursor;
Placing the fermented egg white precursor into fermented egg white;
And the pH of the fermented egg white precursor is adjusted to 4-6 using a pH adjuster.
前記発酵補助剤・凝固卵白分解物混合体とする工程が、前記凝固卵白分解物と発酵補助剤とを混合した後、加熱する工程を含んでなる請求項1に記載の卵白加工食品の製造方法。 The method for producing an egg white processed food according to claim 1, wherein the step of preparing the fermentation auxiliary agent / coagulated egg white decomposition product mixture comprises the step of heating after mixing the coagulated egg white decomposition product and the fermentation auxiliary agent. . 卵白を加熱して、凝固卵白とする工程と、
前記凝固卵白と酵素とを混合して、酵素・凝固卵白混合体とする工程と、
前記酵素・凝固卵白混合体を留置して、凝固卵白分解物とする工程と、
前記凝固卵白分解物と発酵補助剤とpH調整剤とを混合して、pH調整済み発酵補助剤・凝固卵白分解物混合体とする工程と、
前記pH調整済み発酵補助剤・凝固卵白分解物混合体と発酵菌とを混合して、発酵卵白前駆体とする工程と、
前記発酵卵白前駆体を留置して、発酵卵白とする工程と、
を含んで構成され、前記pH調整済み発酵補助剤・凝固卵白分解物混合体のpHが4〜6である卵白加工食品の製造方法。
Heating the egg white to obtain a solidified egg white;
Mixing the coagulated egg white and the enzyme to obtain an enzyme / coagulated egg white mixture;
A step of placing the enzyme / coagulated egg white mixture into a coagulated egg white decomposition product;
Mixing the coagulated egg white decomposed product, fermentation aid and pH adjuster to obtain a pH-adjusted fermentation aid / coagulated egg white decomposed product mixture;
Mixing the pH-adjusted fermentation auxiliary agent / coagulated egg white decomposition product mixture and fermenting bacteria to make a fermented egg white precursor;
Placing the fermented egg white precursor into fermented egg white;
And the pH adjusted fermentation fermentation agent / coagulated egg white decomposition product mixture has a pH of 4-6.
前記酵素・凝固卵白混合体とする工程が、さらにpH調整剤を混合する工程を含んでなり、該工程において、前記酵素・凝固卵白混合体のpHが4〜7に調整される請求項3に記載の卵白加工食品の製造方法。 The step of preparing the enzyme / coagulated egg white mixture further comprises a step of mixing a pH adjuster, wherein the pH of the enzyme / coagulated egg white mixture is adjusted to 4 to 7. The manufacturing method of the egg white processed food of description. 前記pH調整済み発酵補助剤・凝固卵白分解物混合体とする工程が、前記凝固卵白分解物と発酵補助剤とpH調整剤とを混合した後、加熱する工程を含んでなる請求項3または4に記載の卵白加工食品の製造方法。 5. The step of preparing the pH-adjusted fermentation aid / coagulated egg white decomposition product mixture comprises the step of heating after mixing the coagulated egg white decomposition product, the fermentation aid and the pH adjuster. The manufacturing method of the egg white processed food of description. 前記凝固卵白分解物と前記発酵補助剤との混合比が、99:1〜1:99(重量比)である請求項1から5のいずれかに記載の卵白加工食品の製造方法。 The method for producing an egg white processed food according to any one of claims 1 to 5, wherein a mixing ratio between the coagulated egg white decomposition product and the fermentation aid is 99: 1 to 1:99 (weight ratio). 前記pH調整剤が、クエン酸、酢酸、乳酸、グルコン酸、プロピオン酸から選択される請求項1から6のいずれかに記載の卵白加工食品の製造方法。 The method for producing an egg white processed food according to any one of claims 1 to 6, wherein the pH adjuster is selected from citric acid, acetic acid, lactic acid, gluconic acid, and propionic acid. 前記酵素がプロテイナーゼである請求項1から7のいずれかに記載の卵白加工食品の製造方法。 The method for producing a processed egg white food according to any one of claims 1 to 7, wherein the enzyme is a proteinase. 前記発酵菌が、プロピオン酸菌、乳酸菌、バチルス属乳酸菌、ビフィズス菌から選択される請求項1から8のいずれかに記載の卵白加工食品の製造方法。 The method for producing an egg white processed food according to any one of claims 1 to 8, wherein the fermentative bacteria are selected from propionic acid bacteria, lactic acid bacteria, Bacillus lactic acid bacteria, and bifidobacteria. 前記発酵補助剤が、獣乳、脱脂乳から選択される請求項1から9のいずれかに記載の卵白加工食品の製造方法。 The method for producing an egg white processed food according to any one of claims 1 to 9, wherein the fermentation aid is selected from animal milk and skim milk. 前記発酵卵白を圧搾して、発酵卵白脱汁物とする工程を含んで構成される請求項1から10のいずれかに記載の卵白加工食品の製造方法。 The manufacturing method of the egg white processed food in any one of Claim 1 to 10 comprised including the process of pressing the said fermented egg white and making it fermented egg white soup. 前記発酵卵白脱汁物を熟成する工程を含んで構成される請求項11に記載の卵白加工食品の製造方法。
The manufacturing method of the egg white processed food of Claim 11 comprised including the process of aging the said fermented egg white soup.
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