JP2005111392A - Coating film structure - Google Patents

Coating film structure Download PDF

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Publication number
JP2005111392A
JP2005111392A JP2003350254A JP2003350254A JP2005111392A JP 2005111392 A JP2005111392 A JP 2005111392A JP 2003350254 A JP2003350254 A JP 2003350254A JP 2003350254 A JP2003350254 A JP 2003350254A JP 2005111392 A JP2005111392 A JP 2005111392A
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coating
coating film
layer
film structure
resin
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Yoshikazu Matsuoka
義和 松岡
Kazuo Kataoka
和郎 片岡
Masahiro Chida
正宏 地田
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Aica Kogyo Co Ltd
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Aica Kogyo Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To obtain a composition of a coating material for obtaining a coating film structure characterized by forming a bead layer in which a fine glass bead and a color mica are arranged in parallel on a colored or a white coating material, and an application method therefor. <P>SOLUTION: This coating film structure is constituted of a coating film laminated with a primer coating layer formed from the surface side of a coated substance which is formed from the surface side of the colored or the white coating material, an intermediate coating layer, and a top-coating layer. The application method of each layer is to finish so as to become smooth by using a metal trowel. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、白色あるいは有色塗材の上に施工することで、塗材の色が表面に透過する点描調透光性の塗膜構造に関する。 The present invention relates to a pointillistic translucent coating structure in which the color of a coating material is transmitted to the surface by being applied on a white or colored coating material.

無機質板などの被塗布物上に対する塗装の上塗り層に、反射屈折材としてのガラスビーズを混入させ、このガラスビーズによる光の屈曲反射作用を利用することにより、陶磁器に極めて近い外観を呈する塗装面を構成し、これにより、意匠性を向上させて商品価値を高めるようになっているものがある(特開平5−50030)。
また、建物の表面などの被塗布物上に、御影石調や大理石調などの石材調の塗膜を形成する方法として、例えば被塗布物上に、微細に粉砕した自然石や着色骨材を含んだ骨材含有塗料を塗布する方法が知られている(特開2001-293435)。
しかしながら、変化に富んだ外観を呈する塗膜構造を構成したいと言う要求があり、この要求をいかに実現するかが課題とされていた。
Painted surface that looks very similar to ceramics by mixing glass beads as a catadioptric material into the topcoat layer of the coating on an object to be coated, such as an inorganic plate, and utilizing the bending and reflecting action of light by the glass beads. Thus, the design value is improved to increase the commercial value (Japanese Patent Laid-Open No. 5-50030).
In addition, as a method of forming a stone-like paint film such as granite or marble like on the object to be coated such as the surface of a building, for example, finely ground natural stone or colored aggregate is included on the object to be coated. A method of applying an aggregate-containing paint is known (Japanese Patent Laid-Open No. 2001-293435).
However, there has been a demand to construct a coating film structure that exhibits a varied appearance, and how to realize this demand has been a problem.

本発明は上記問題点に鑑みて提案されたものであり、意匠性に富んだ外観を呈する塗膜構造を提供することを目的とする。
特開平5−50030 特開2001-293435
This invention is proposed in view of the said problem, and it aims at providing the coating-film structure which exhibits the external appearance rich in the designability.
JP 5-50030 A JP 2001-293435 A

まず、本願の請求項1に係る発明は、塗膜の表面に形成された微細なガラスビーズとカラーマイカを並列配置させるビーズ層を特徴とする。
また、本願の請求項2に係る発明は、上記第1発明において、ビーズ層が透光性であることを特徴とする。
更に、本願の請求項3に係る発明は、前記塗膜の下塗り塗料層あるいは中塗り塗料層が乾燥した有色又は白色塗材としたことを特徴とする。
First, the invention according to claim 1 of the present application is characterized by a bead layer in which fine glass beads formed on the surface of a coating film and color mica are arranged in parallel.
The invention according to claim 2 of the present application is characterized in that, in the first invention, the bead layer is translucent.
Furthermore, the invention according to claim 3 of the present application is characterized in that the undercoat paint layer or the intermediate coat paint layer of the coating film is a colored or white coating material dried.

前記目的を達成するため、本発明における塗膜構造は、被塗物の表面側から形成される下塗り塗料層と、中塗り塗料層と、上塗り塗料層を積層した塗膜により構成される。各層の施工方法は、金ゴテを用いて平滑になるように仕上げる。 In order to achieve the above object, the coating film structure in the present invention is constituted by a coating film in which an undercoat coating layer, an intermediate coating layer, and a top coating layer are formed from the surface side of an object to be coated. The construction method of each layer is finished using a gold trowel so as to be smooth.

下塗り塗料層、中塗り塗料層でそれぞれ使用する塗材は、合成樹脂エマルションを塗膜形成の主要素とするものであれば特に限定されるものではないが、さらに、無機の紛体を含有するものが好ましい。 The coating material used for each of the undercoat paint layer and the intermediate coat layer is not particularly limited as long as it has a synthetic resin emulsion as a main component for forming a coating film, but further contains an inorganic powder. Is preferred.

このような合成樹脂エマルションとしては、アクリル酸エステル共重合樹脂系、酢酸ビニル樹脂系、エチレン-酢酸ビニル共重合樹脂系、スチレン−アクリル酸エステル共重合樹脂系、酢酸ビニル−アクリル酸エステル共重合樹脂系、エチレン−塩化ビニル共重合樹脂系、酢酸ビニル−ベオバ共重合樹脂系、エチレン−塩化ビニル共重合樹脂系、エポキシ樹脂系、ウレタン樹脂系、シリコン変性アクリル系、フッ素系の各エマルションが使用でき、適宜混合して使用することも可能である。このような合成樹脂エマルションは、エマルション粒子内部またはエマルション粒子間で架橋するタイプや、架橋剤を加えて架橋反応をさせる二液硬化タイプでもよい。さらに粉末型のエマルションも使用可能である。 Examples of such synthetic resin emulsions include acrylate copolymer resins, vinyl acetate resins, ethylene-vinyl acetate copolymer resins, styrene-acrylate copolymer resins, vinyl acetate-acrylate copolymer resins. , Ethylene-vinyl chloride copolymer resin, vinyl acetate-veova copolymer resin, ethylene-vinyl chloride copolymer resin, epoxy resin, urethane resin, silicon-modified acrylic, and fluorine emulsions can be used. It is also possible to use a mixture as appropriate. Such a synthetic resin emulsion may be of a type that crosslinks within emulsion particles or between emulsion particles, or a two-component curing type that adds a crosslinking agent to cause a crosslinking reaction. Furthermore, a powder type emulsion can also be used.

無機の粉体としては、通常塗材の充填材や顔料として使用するものであれば特に限定はされないが、例えば、無機としては、重質炭酸カルシウム、カオリン、クレー、陶土、珪藻土、ホワイトカーボン、タルク、バライト粉、沈降性硫酸バリウム、炭酸バリウム、酸化チタン、酸化第二鉄、カーボンブラック、黄鉛、オーカー等があげられる。 The inorganic powder is not particularly limited as long as it is usually used as a filler or pigment for coating materials. For example, as inorganic, heavy calcium carbonate, kaolin, clay, porcelain clay, diatomaceous earth, white carbon, Examples include talc, barite powder, precipitated barium sulfate, barium carbonate, titanium oxide, ferric oxide, carbon black, yellow lead, ocher and the like.

さらに、通常塗材に配合する増粘剤、分散剤、消泡剤、湿潤調整剤、防腐剤、防カビ剤、防藻剤等の添加剤やパルプ繊維、ガラス繊維、カーボン繊維等の繊維状物も適宜配合することができる。 In addition, additives such as thickeners, dispersants, antifoaming agents, wetting regulators, antiseptics, fungicides, algaeproofing agents, and other fibrous materials such as pulp fibers, glass fibers, carbon fibers, etc. Products can also be blended as appropriate.

下塗り塗材は、塗布にあたって金ゴテを用いて平滑になるように仕上げ、0.5〜1.8kg/m2の塗布量となるようにすることが好ましい。 The undercoating material is preferably finished so as to be smooth using a gold trowel for application so that the application amount is 0.5 to 1.8 kg / m <2>.

中塗り塗料層で使用する塗材は、下塗り塗料層で使用した塗料組成物が使用できる。仕上がり面を凹凸にして、上塗りの施工をしやすくするために、骨材を含有するものが好ましい。 As the coating material used in the intermediate coating layer, the coating composition used in the undercoat coating layer can be used. In order to make the finished surface uneven and to facilitate the overcoating, those containing aggregates are preferred.

骨材の種類としては、通常塗材に用いられるものであれば特に限定はされないが、例えば、珪砂、寒水石、山砂、川砂、天然石粉砕物、陶磁器・セラミック粉砕物、ガラス粉砕物等があげられる。 The type of aggregate is not particularly limited as long as it is usually used for coating materials. For example, silica sand, cold water stone, mountain sand, river sand, natural stone pulverized material, ceramic / ceramic pulverized material, glass pulverized material, etc. can give.

中塗り塗材は、塗布にあたって金ゴテを用いて平滑になるように仕上げ、1.0〜2.0kg/m2の塗布量となるようにすることが好ましい。 The intermediate coating material is preferably finished using a gold trowel so as to be smooth so that the coating amount is 1.0 to 2.0 kg / m <2>.

上塗り塗料層で使用し、透明性を有する樹脂として、アクリル樹脂、アクリル・スチレン共重合樹脂、酢酸ビニル樹脂、エチレン・酢酸ビニル樹脂等のエマルジョン系樹脂をベース塗料として、必要に応じて、界面活性剤、分散剤、消泡剤、増粘剤、造膜助剤、防腐剤、凍結防止剤、有機溶剤などの塗料用添加剤を加えることができる。 As the base paint, emulsion resin such as acrylic resin, acrylic / styrene copolymer resin, vinyl acetate resin, ethylene / vinyl acetate resin can be used as the base paint for surface coating. Additives for paints such as an agent, a dispersant, an antifoaming agent, a thickener, a film-forming aid, an antiseptic, an antifreezing agent, and an organic solvent can be added.

上塗り材にはベース塗料と、微細なガラスビーズ及び、カラーマイカを加えたものが使用される。上塗り塗料層は金ゴテで塗工される。 As the top coating material, a base paint, fine glass beads and color mica are added. The top coat layer is applied with a gold trowel.

ガラスビーズには平均粒子径0.3 〜 2.0mmのタイプを使用するが、塗工後意匠性に支障が無い限り限定されない。微細なビーズの使用によりビーズ表面のコテ滑がよくなり、簡便な塗工作業性が得られる。なお、ビーズは塗工作業性に問題のない範囲で平均粒子径の異なる数種類を混ぜ合わせて使用しても良い。 A glass bead having an average particle size of 0.3 to 2.0 mm is used, but it is not limited as long as there is no hindrance in design after coating. By using fine beads, the surface of the beads is improved and a simple coating workability is obtained. In addition, the beads may be used by mixing several kinds having different average particle diameters within a range where there is no problem in coating workability.

カラーマイカとは、マイカ紛にアクリル樹脂やエポキシ樹脂等の塗料がコーティングされたものである。 Color mica is obtained by coating mica powder with a paint such as an acrylic resin or an epoxy resin.

カラーマイカには平均粒子径1.0 〜 5.0mmのタイプを使用するが、塗工後意匠性に支障が無い限り限定されない。なお、カラーマイカは塗工作業性に問題のない範囲で平均粒子径の異なる数種類を混ぜ合わせて使用しても良い。 A type having an average particle diameter of 1.0 to 5.0 mm is used for the color mica, but it is not limited as long as there is no hindrance in design properties after coating. In addition, color mica may be used by mixing several types having different average particle diameters within the range where there is no problem in coating workability.

上塗り材で塗布する、ベース塗料とガラスビーズ及びカラーマイカの調合割合は、エマルジョン系樹脂として樹脂分50%相当の品種を50部使用し、消泡剤、成膜助剤、増粘剤等の適量と水50部としたベース塗料100部に対してガラスビーズ300〜500部、カラーマイカが0.1〜5.0部が適合する。この範囲の配合割合であると塗工の作業性が良好であるのに対して、配合量が少ないと乾燥性、意匠性等の問題があり、逆に多いと塗工作業性が劣り、付着性が低下する等の問題があり適合しない。 The blending ratio of base paint, glass beads and color mica to be applied with the top coating material is 50 parts of a resin component equivalent to 50% as an emulsion resin, and used as an antifoaming agent, film-forming aid, thickener, etc. 300 to 500 parts of glass beads and 0.1 to 5.0 parts of color mica are suitable for 100 parts of base paint with an appropriate amount and 50 parts of water. When the blending ratio is within this range, the workability of coating is good, whereas when the blending amount is small, there are problems such as drying properties and design properties. There is a problem such as a decrease in performance, it does not fit.

ベース塗料中の樹脂分の調整は樹脂エマルジョンの品種選定、配合水の配合調整により行うことができ、塗装作業性、仕上がり外観等を参酌して決定されればよい。 Adjustment of the resin content in the base paint can be performed by selecting the type of resin emulsion and adjusting the formulation of the blended water, and may be determined in consideration of coating workability, finished appearance, and the like.

ベース塗料中に配合する消泡剤にはシリコン系化合物、エーテル系化合物、脂肪酸エステル系化合物等が使用され、塗膜中の泡を効果的に解消することができる。成膜助剤にはテキサノール、ベンジルアルコール、ブチルセロソルブ等が使用され塗膜の形成を容易にすることが可能となる。塗装に適合した粘度とするためにはメチルセルロース、ヒドロキシエチル/メチルセルロース、ヒドロキシプロピルメチルセルロース等を適量使用して調整することができる。また配合材料の分散確保のためノニオン系界面活性剤、ポリリン酸塩等の分散剤を使用すれば良好にな分散効果が得られる。 A silicon compound, an ether compound, a fatty acid ester compound, or the like is used as an antifoaming agent to be blended in the base paint, and bubbles in the coating film can be effectively eliminated. Texanol, benzyl alcohol, butyl cellosolve, or the like is used as the film forming auxiliary agent, which facilitates the formation of the coating film. In order to obtain a viscosity suitable for coating, it can be adjusted by using an appropriate amount of methylcellulose, hydroxyethyl / methylcellulose, hydroxypropylmethylcellulose and the like. Further, if a dispersing agent such as a nonionic surfactant or polyphosphate is used for ensuring dispersion of the compounding material, a good dispersion effect can be obtained.

上塗り材は、塗布にあたって金ゴテを用いて平滑になるように仕上げ、3.0〜4.0kg/m2の塗布量となるようにすることが好ましい。さらに、仕上がりが平滑になるようにステンレス製の仕上げゴテで表面をならすことが好ましい。 The top coat material is preferably finished so as to be smooth using a gold trowel when applied, so that the coating amount is 3.0 to 4.0 kg / m <2>. Furthermore, it is preferable to smooth the surface with a stainless steel finish trowel so that the finish is smooth.

また、本発明の塗装方法による、透光性機能を有する塗膜構造を形成するに際して、被塗物表面に不陸や亀裂があり、下塗り層により被覆できない程度に著しい場合は、予め被塗物表面の不陸や亀裂をサンドペーパーやブラスト等で荒らし、樹脂パテ等を埋め込むなど平滑面を形成することが必要である。また、本発明の塗膜の付着性をより向上させるために、下塗り材としてシーラー、プライマーを塗布しておくことも可能である。 In addition, when forming a coating film structure having a translucent function by the coating method of the present invention, if the surface of the object to be coated is uneven or cracked and is so severe that it cannot be covered by the undercoat layer, the object to be coated is previously formed. It is necessary to form a smooth surface such as roughening the surface unevenness or cracks with sandpaper or blasting, and embedding resin putty or the like. In order to further improve the adhesion of the coating film of the present invention, it is possible to apply a sealer or primer as an undercoat.

さらに、中塗りと上塗りの施工間で、塗工作業性の向上と塗膜の付着性をより向上させるために、上塗り材と同様なバインダー成分を塗布しておくことも可能である。 Furthermore, in order to improve the coating workability and the adhesion of the coating film between the intermediate coating and the top coating, it is possible to apply the same binder component as that of the top coating material.

仕上げられた塗装表面はガラスビーズの一部表面が露出して中塗り塗材が透視でき、光を内部で反射する表面外観を呈するとともに、カラーマイカの点描調の色彩がある意匠性に優れた塗膜構造を得ることが出来る。 The finished coating surface is partially exposed to glass beads, allowing the intermediate coating material to be seen through, showing a surface appearance that reflects light internally, and has an excellent design with color mica stippling tone. A coating film structure can be obtained.

実施例1
下地としてプラスターボードを使用し、シーラーとして、アクリル樹脂系エマルジョン{アイカ工業(株)製、JS−500}を塗布して乾燥したのち、下塗り材として汎用仕上げ材{アイカ工業(株)製、JP−100、白色}を0.9Kg/m塗布して乾燥させた。さらに、中塗り材としてこのベース塗料100部に寒水石50部、水5部を添加したものを使用して、1.5Kg/m中塗り層を形成し、乾燥後に、アクリル・スチレン系樹脂エマルジョン50部、消泡剤(エーテル系化合物)0.1部、成膜助剤(テキサノール)3.1部、分散剤(ポリリン酸塩)0.2部、増粘剤(メチルセルロース)1.5部、水50部を加えてベース塗料{アイカ工業(株)製、JPX−7}100部に平均粒子径0.3〜0.5mmのガラスビーズ400部、平均粒子径1.0〜5.0mmの青色カラーマイカ2部を配合して調整した上塗り塗料を3.5Kg/mコテ塗り仕上げをして、実施例の塗装仕上げとした。
Example 1
A plaster board is used as the base, and an acrylic resin emulsion {manufactured by Aika Kogyo Co., Ltd., JS-500} is applied and dried as a sealer. 100, white} was applied at 0.9 kg / m 2 and dried. Furthermore, an intermediate coating layer is formed by using 100 parts of this base paint plus 50 parts of cold water stone and 5 parts of water to form a 1.5 Kg / m 2 intermediate coating layer. After drying, an acrylic / styrene resin emulsion 50 parts, 0.1 part of antifoaming agent (ether compound), 3.1 parts of film forming aid (texanol), 0.2 part of dispersing agent (polyphosphate), 1.5 parts of thickener (methylcellulose) , 50 parts of water, base paint {JPA-7, JPX-7}, 100 parts of glass beads, 400 parts of glass beads with an average particle diameter of 0.3 to 0.5 mm, blue color with an average particle diameter of 1.0 to 5.0 mm The top coating prepared by blending 2 parts of mica was applied with a 3.5 kg / m 2 iron coating finish to obtain the coating finish of the example.

比較例1
実施例1のガラスビーズの配合量を250部にした以外は実施例1と同一にして、コテ塗り仕上げをして比較例1の塗装仕上げとした。
比較例2
実施例1のカラーマイカの配合量を10部にした以外は実施例1と同一にして、コテ塗り仕上げをして比較例2の塗装仕上げとした。
Comparative Example 1
The coating finish of Comparative Example 1 was obtained by applying a trowel coating in the same manner as in Example 1 except that the blending amount of the glass beads of Example 1 was 250 parts.
Comparative Example 2
A coating finish of Comparative Example 2 was made by applying a trowel coating in the same manner as in Example 1 except that the amount of color mica of Example 1 was changed to 10 parts.

実施例1の塗装仕上げにおいて、コテはガラスビーズの表面間を滑らかに且つ同一レベルを容易に移動できるため、塗工作業が極めて容易であり、しかも均一な厚みの塗工が可能であった。また、ガラスビーズの一部表面が露出して白色の中塗り塗材が透視され、カラーマイカの点描調の色彩がある意匠仕上げが得られた。 In the coating finish of Example 1, the iron was able to move smoothly between the surfaces of the glass beads and at the same level, so that the coating operation was extremely easy, and coating with a uniform thickness was possible. In addition, a part of the surface of the glass beads was exposed to allow the white intermediate coating material to be seen through, and a design finish having a color mica stippling tone color was obtained.

比較例1の塗装仕上げにおいてはカラスビース゛の配合量が少ないため塗材が垂れやすい、コテの同一レベルでの移動がしにくく均一な塗膜の確保が困難であった。また歩減りも目立ち仕上がり外観が良くなかった。比較例2の塗装仕上げにおいてはカラーマイカの配合量が多くコテ作業がしにくく、透過性が悪くなり点描調の外観が得られなかった。 In the coating finish of Comparative Example 1, since the amount of the glass beads was small, the coating material was liable to drip, and it was difficult to move the iron at the same level, and it was difficult to ensure a uniform coating film. In addition, the number of steps was conspicuous and the finished appearance was not good. In the coating finish of Comparative Example 2, the amount of color mica was large and the ironing work was difficult, and the permeability was deteriorated, so that a pointed-tone appearance was not obtained.

Claims (3)

塗膜の表面に形成された微細なガラスビーズとカラーマイカが並列配置されてなるビーズ層を有することを特徴とする塗膜構造。 A coating film structure comprising a bead layer in which fine glass beads and color mica formed on the surface of a coating film are arranged in parallel. 前記、ビーズ層が透光性機能を持つことを特徴とする請求項1記載の塗膜構造。 2. The coating film structure according to claim 1, wherein the bead layer has a translucent function. 被前記塗膜の下塗り塗料層あるいは中塗り塗料層が有色又は白色塗材であることを特徴とする請求項1及び2記載の塗膜構造。 3. The coating film structure according to claim 1, wherein the undercoating layer or intermediate coating layer of the coating film is a colored or white coating material.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010058488A (en) * 2008-09-04 2010-03-18 Takatsuki Seikei Kk Decorative coated panel

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010058488A (en) * 2008-09-04 2010-03-18 Takatsuki Seikei Kk Decorative coated panel

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