JP2005061130A - Liquid medicine discharge vessel - Google Patents

Liquid medicine discharge vessel Download PDF

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JP2005061130A
JP2005061130A JP2003294764A JP2003294764A JP2005061130A JP 2005061130 A JP2005061130 A JP 2005061130A JP 2003294764 A JP2003294764 A JP 2003294764A JP 2003294764 A JP2003294764 A JP 2003294764A JP 2005061130 A JP2005061130 A JP 2005061130A
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chemical
chemical solution
tank
chemical liquid
liquid medicine
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JP4614042B2 (en
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Katsumi Saegusa
克己 三枝
Hozumi Hirahara
穂積 平原
Yosuke Komatsu
洋介 小松
Toshihisa Hayakawa
敏久 早川
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Kao Corp
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Kao Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a liquid medicine discharge vessel mounted on a hand washing part with a low tank of a flush toilet and capable of mixing the liquid medicine in the liquid medicine tank into the low tank by a simple mechanism and preventing dilution of the liquid medicine in the liquid medicine tank in accordance with discharge of the liquid medicine. <P>SOLUTION: This liquid medicine discharge vessel 100A is composed of the liquid medicine tank 1 storing the liquid medicine A and a liquid medicine discharge hole 9 provided below the liquid medicine tank 1. Specific gravity of the liquid medicine is set to less than 1.00 and 0.75 or more, and area of the narrowest flow passage of the liquid medicine discharge hole is set to 0.2 to 80 mm<SP>2</SP>. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、水洗トイレの手洗い付きロータンクの手洗い部に載置し、手洗い部の上方のカランから給水により、ロータンク内に薬液(芳香剤、洗浄剤、殺菌剤等)を吐出する薬液吐出容器に関する。   The present invention relates to a chemical liquid discharge container that is placed in a hand washing part of a hand-washed low tank of a flush toilet and discharges chemical liquid (fragrance, cleaning agent, disinfectant, etc.) into the raw tank by supplying water from a currant above the hand washing part. .

水洗トイレの手洗い付きロータンクの手洗い部に載置し、手洗い部の上方のカランから供給される水に薬液(芳香剤、洗浄剤、殺菌剤等)を混合するために用いる薬液吐出容器として、特許文献1に記載されているオンタンク型薬液剤供給装置が知られている。この薬液剤供給装置は、薬液を収容する容器と、容器の連通口に挿入された液体供給栓と、液体供給栓から漏洩した薬液を保持する貯留槽を備えた台座からなり、液体供給栓が微細輸送路構造と換気用連通路を有し、薬液を保持した貯留槽が、カランから手洗い部に供給された水の流れに晒され、そこから薬液が洗い出され、ロータンク内に流下するようにしたものである。
特開2002−146879号公報
Patented as a chemical solution discharge container that is placed in the hand washing part of a low tank with hand washing in a flush toilet and used to mix chemicals (fragrances, cleaning agents, disinfectants, etc.) into the water supplied from the currant above the hand washing part An on-tank chemical solution supply apparatus described in Document 1 is known. The chemical solution supply apparatus includes a container that stores a chemical solution, a liquid supply plug that is inserted into a communication port of the container, and a pedestal that includes a storage tank that holds a chemical solution that has leaked from the liquid supply plug. A storage tank that has a fine transport path structure and ventilation communication path and holds the chemical solution is exposed to the flow of water supplied from the currant to the hand-washing section, so that the chemical solution is washed out and flows down into the low tank. It is a thing.
JP 2002-146879 A

上述の薬液剤供給装置は、微細輸送路構造を有する液体供給栓の構造が複雑であり、製造コストが高くつく。これに対し、より単純な機構のものとしては、図7(a)に示すように、薬液Aを収容する薬液タンク1と薬液タンク1の底部開口部2に取り付けたキャップ3からなり、キャップ3に薬液吐出ノズル4と足6を設けた薬液吐出容器100xが考えられる。薬液吐出ノズル4の先端開口部5には、薬液Aが表面張力と薬液タンク1内が弱い負圧状態になることにより保持される。   The above-described chemical solution supply apparatus has a complicated structure of the liquid supply plug having a fine transport path structure, and the manufacturing cost is high. On the other hand, as shown in FIG. 7A, a simpler mechanism is composed of a chemical liquid tank 1 for storing the chemical liquid A and a cap 3 attached to the bottom opening 2 of the chemical liquid tank 1. A chemical solution discharge container 100x provided with a chemical solution discharge nozzle 4 and a foot 6 can be considered. The chemical solution A is held in the tip opening 5 of the chemical solution discharge nozzle 4 by the surface tension and the inside of the chemical solution tank 1 being in a weak negative pressure state.

図7(b)に示すように、この薬液吐出容器100xを、ロータンクの手洗い部20の吸水口21上に載置し、水洗トイレの水をフラッシュさせることによりカランから手洗い部20に矢印のように水Wが供給されると、その水Wは薬液Aを保持した薬液吐出ノズル4を洗うようにしてロータンク内に流下するので、これにより薬液Aがロータンク内に混入する。また、カランからの給水が止まった後においても、給水時に比して薬液タンク内の温度が上がり、ヘッドスペースが膨張することによって薬液Aが吐出され、ロータンク内に混入する場合もある。したがって、この薬液吐出容器100xによれば、単純な機構で薬液Aをロータンク内に混入させることが可能となる。   As shown in FIG. 7 (b), this chemical solution discharge container 100x is placed on the water suction port 21 of the hand-washing part 20 of the low tank, and the water in the flush toilet is flushed to make the hand-washing part 20 as indicated by an arrow. When the water W is supplied to the water tank, the water W flows down into the low tank so as to wash the chemical liquid discharge nozzle 4 holding the chemical liquid A, so that the chemical liquid A is mixed into the low tank. Further, even after the water supply from the currant is stopped, the temperature in the chemical liquid tank rises as compared with the time of the water supply, and the chemical liquid A may be discharged and mixed into the raw tank when the head space expands. Therefore, according to the chemical solution discharge container 100x, the chemical solution A can be mixed into the raw tank by a simple mechanism.

しかしながら、この薬液吐出容器100xによれば、薬液Aが吐出されることにより、薬液タンク1内に空気が混入して薬液Aの量が減少する場合と、水が混入して薬液Aが希釈される場合とがあるため、薬液タンク1内の薬液Aの全てが吐出された時期を、薬液吐出容器100xの使用を終了すべき時期とすると、水が混入する場合には、薬液が希釈され、十分な薬効のない薬液が吐出される時期にまで使用が継続されてしまうという問題がある。   However, according to the chemical solution discharge container 100x, when the chemical solution A is discharged, air is mixed into the chemical solution tank 1 to reduce the amount of the chemical solution A, and water is mixed to dilute the chemical solution A. Therefore, if the time when all of the chemical liquid A in the chemical liquid tank 1 is discharged is the time when the use of the chemical liquid discharge container 100x is to be terminated, the chemical liquid is diluted when water is mixed, There is a problem that the use is continued until the time when a chemical solution having insufficient medicinal effect is discharged.

これに対し、本発明は、薬液の物性と薬液吐出容器の構造の適切な組合せにより、薬液タンクから薬液が確実に吐出されるとともに、カランから給水された水が薬液タンク内に混入して薬液タンク内の薬液が希釈されることを防止し、これにより、薬効のない薬液を使い続けるという問題を生じさせることなく、薬液タンク内の薬液を最後まで使い切れるようにすることを目的とする。   On the other hand, according to the present invention, the chemical liquid is surely discharged from the chemical liquid tank by the appropriate combination of the physical properties of the chemical liquid and the structure of the chemical liquid discharge container, and the water supplied from the currant is mixed into the chemical liquid tank. An object of the present invention is to prevent the chemical solution in the tank from being diluted, and thereby to completely use the chemical solution in the chemical solution tank without causing the problem of continuing to use the chemical solution having no medicinal effect.

本発明者らは、水洗トイレのロータンク付き手洗い部に載置する簡便な機構の薬液吐出容器において、薬液タンクに充填する比重を1.00未満とすると、薬液タンク内の薬液がカランから給水された水と置換し難くなり、薬液タンクから薬液が吐出される度に確実に薬液タンク内の液量が減り、最後に薬液タンクは空になることを見出した。   In the chemical solution discharge container having a simple mechanism that is placed in the hand-washing portion with a low tank of the flush toilet, the present inventors supply the chemical solution in the chemical solution tank from the currant when the specific gravity charged in the chemical solution tank is less than 1.00. It was found that the amount of liquid in the chemical liquid tank surely decreased each time the chemical liquid was discharged from the chemical liquid tank, and finally the chemical liquid tank was emptied.

即ち、本発明は、薬液を収容する薬液タンク、及び薬液タンクの下方に設けられた薬液吐出孔からなり、
薬液の比重が1.00未満0.75以上、
薬液吐出孔の最狭流路面積が0.2〜80mm2
である薬液吐出容器を提供する。
That is, the present invention comprises a chemical solution tank for storing a chemical solution, and a chemical solution discharge hole provided below the chemical solution tank,
The specific gravity of the chemical solution is less than 1.00 and 0.75 or more,
The narrowest channel area of the chemical solution discharge hole is 0.2 to 80 mm 2
A chemical solution discharge container is provided.

また、本発明は、上述の薬液吐出容器の薬液タンクに、トイレ洗浄液が充填されてなるトイレ洗浄用品を提供する。   The present invention also provides a toilet cleaning product in which the chemical liquid tank of the above-described chemical liquid discharge container is filled with a toilet cleaning liquid.

本発明によれば、水洗トイレのロータンクの手洗い部に載置することにより、薬液タンク内の薬液をロータンク内に簡便な機構で混入させることができる薬液吐出容器において、カランからの給水やトイレの室温の変化等による薬液タンク内のヘッドスペースの膨張により確実に薬液を吐出させることができ、さらに、カランからの給水時に薬液タンク内の薬液が水と置換し、薬液タンク内の薬液が希釈されることを防止できる。したがって、薬効のない薬液を使い続けるという問題を生じさせることなく、薬液タンク内の薬液を最後まで使い切ることが可能となる。   According to the present invention, in the chemical solution discharge container that can be mixed with the chemical solution in the chemical tank into the raw tank by a simple mechanism by being placed in the hand washing part of the low tank of the flush toilet, Due to the expansion of the head space in the chemical tank due to changes in room temperature, etc., the chemical liquid can be discharged reliably, and the chemical liquid in the chemical tank is replaced with water when water is supplied from the currant, and the chemical liquid in the chemical tank is diluted. Can be prevented. Therefore, the chemical solution in the chemical solution tank can be used up to the end without causing the problem of continuing to use the chemical solution having no medicinal effect.

以下、図面を参照しつつ、本発明を詳細に説明する。なお、各図中、同一符号は同一又は同等の構成要素を表している。   Hereinafter, the present invention will be described in detail with reference to the drawings. In each figure, the same numerals indicate the same or equivalent components.

図1は、本発明の一態様の薬液吐出容器100Aに薬液Aを充填したトイレ洗浄用品200Aを正面から見た部分断面図とその部分拡大断面図(a)、側面図(b)、上面図(c)及び底面図(d)である。   FIG. 1 is a partial sectional view of a toilet cleaning product 200A filled with a chemical solution A in a chemical solution discharge container 100A according to an embodiment of the present invention, a partially enlarged sectional view (a), a side view (b), and a top view. (C) and bottom view (d).

この薬液吐出容器100Aは、薬液タンク1と、薬液タンク1の底部開口部2に取り付けられたキャップ3からなる。   The chemical solution discharge container 100 </ b> A includes a chemical solution tank 1 and a cap 3 attached to the bottom opening 2 of the chemical solution tank 1.

薬液タンク1には、トイレ用芳香剤、洗浄剤、殺菌剤等の薬液Aが充填されている。   The chemical liquid tank 1 is filled with a chemical liquid A such as a toilet fragrance, a cleaning agent, and a disinfectant.

薬液Aの比重が、カランから給水された水の比重以上の場合には、カランから給水された水が薬液吐出ノズル4の先端開口部5に触れていると、薬液タンク1内の薬液Aと置換するが、薬液Aの比重が水の比重よりも小さい場合には、カランから給水された水が薬液吐出ノズル4の先端開口部5を洗っている間の短時間に、その水が薬液タンク1内の薬液Aと置換することはない。したがって、薬液タンク1から薬液Aが吐出される毎に、薬液タンク1内には空気が入り、薬液タンク1内の液量は確実に減少し、ついには空になる。また、薬液の吐出に伴って薬液タンク1内の薬液が薬効のない程度にまで希釈されることもない。よって、一般消費者は、薬液Aが十分な薬効を有する状態で、トイレ洗浄用品200Aを薬液Aが空になるまで使いきることができる。   When the specific gravity of the chemical liquid A is equal to or higher than the specific gravity of the water supplied from the currant, if the water supplied from the currant touches the tip opening 5 of the chemical discharge nozzle 4, the chemical liquid A in the chemical tank 1 In the case where the specific gravity of the chemical solution A is smaller than the specific gravity of water, the water supplied from the currant is stored in the chemical solution tank in a short time while the tip opening 5 of the chemical solution discharge nozzle 4 is washed. The chemical solution A in 1 is not replaced. Therefore, every time the chemical liquid A is discharged from the chemical liquid tank 1, air enters the chemical liquid tank 1, the amount of liquid in the chemical liquid tank 1 is surely reduced, and finally becomes empty. Further, the chemical solution in the chemical solution tank 1 is not diluted to the extent that it is not effective as the chemical solution is discharged. Therefore, the general consumer can use the toilet cleaning product 200A in a state where the chemical liquid A has a sufficient medicinal effect until the chemical liquid A becomes empty.

薬液Aの比重を、カランから給水された水の比重よりも小さくするため、通常の使用条件では、20℃の薬液Aの比重を1.00未満とし、好ましくは温度による水の比重の変動の点から0.99以下とする。また、薬液Aの比重は、薬液配合の点から0.75以上とし、好ましくは0.80以上、さらに好ましくは0.90以上とする。
薬液Aの比重を1未満とするためには、例えば、表1に示す比重1未満の溶媒を薬液Aに適宜使用する。
In order to make the specific gravity of the chemical solution A smaller than the specific gravity of the water supplied from the currant, the specific gravity of the chemical solution A at 20 ° C. should be less than 1.00 under normal use conditions. 0.99 or less from the point. In addition, the specific gravity of the chemical solution A is set to 0.75 or more, preferably 0.80 or more, and more preferably 0.90 or more from the viewpoint of chemical solution blending.
In order to set the specific gravity of the chemical solution A to less than 1, for example, a solvent having a specific gravity of less than 1 shown in Table 1 is appropriately used for the chemical solution A.

[表1]

Figure 2005061130
(溶剤ハンドブック、講談社、1976年)
[Table 1]
Figure 2005061130
(Solvent Handbook, Kodansha, 1976)

薬液Aの粘度(20℃)は、比重を上述の範囲に調整することにより、通常、1〜3000mPa・sとなる。この粘度は、20℃でB型粘度計(60rpm)により測定される値である。   The viscosity (20 ° C.) of the chemical liquid A is usually 1 to 3000 mPa · s by adjusting the specific gravity within the above range. This viscosity is a value measured with a B-type viscometer (60 rpm) at 20 ° C.

薬液吐出容器100Aにおける薬液Aの充填量は、使用開始時の薬液タンク1内のヘッドスペースが、薬液タンク1の満容量の15%以上となるようにすることが好ましい。これにより、カランからの給水やトイレの室温の変化等による薬液タンク1内のヘッドスペースの膨張により、薬液Aを確実に吐出させることができる。   The filling amount of the chemical solution A in the chemical solution discharge container 100A is preferably set so that the head space in the chemical solution tank 1 at the start of use is 15% or more of the full capacity of the chemical solution tank 1. Thereby, the chemical | medical solution A can be reliably discharged by expansion | swelling of the head space in the chemical | medical solution tank 1 by the water supply from a currant, the change of the room temperature of a toilet, etc.

キャップ3の底部には薬液吐出ノズル4が該キャップ3と一体に形成されている。この薬液吐出ノズル4は先端部4aが細径になっており、また、その内部の薬液吐出孔9には、フィルター14が充填されている。   A chemical solution discharge nozzle 4 is formed integrally with the cap 3 at the bottom of the cap 3. The tip 4a of the chemical solution discharge nozzle 4 has a small diameter, and the chemical solution discharge hole 9 inside is filled with a filter 14.

本発明においては、薬液吐出ノズル4に形成されている薬液吐出孔9の最狭流路面積を0.2〜80mm2とする。ここで、薬液吐出孔9の最狭流路面積とは、薬液吐出孔9内の薬液Aの流下方向と垂直な断面における正味の流路面積のうち最小のもの、略すれば、薬液吐出孔9内の正味の流路のうち最も狭い部分の面積をいう。したがって、この薬液吐出容器100Aにおいて、薬液吐出孔9内にフィルター14が充填されていない場合には、流路横断面の面積が最小となる部位は先端開口部5となるので、先端開口部5の開口面積を上述の範囲とするが、図1(a)のように薬液吐出孔9内にフィルター14が充填されている場合に、フィルター14が充填されている部位の薬液吐出孔9の最狭流路面積(薬液吐出ノズル4自体の流路面積からフィルター14が占める面積を差し引いた正味の流路面積の最小値)が先端開口部5の開口面積より小さいときには、フィルター14が充填されている部位の薬液吐出孔9の最狭流路面積を上述の範囲とする。また、薬液吐出ノズルの中間部の薬液吐出孔が先端開口部よりも細径になっている場合には、その細径部分の流路面積を上述の範囲とする。 In the present invention, the narrowest channel area of the chemical liquid discharge hole 9 formed in the chemical liquid discharge nozzle 4 is set to 0.2 to 80 mm 2 . Here, the narrowest flow path area of the chemical liquid discharge hole 9 is the smallest of the net flow path areas in a cross section perpendicular to the flow-down direction of the chemical liquid A in the chemical liquid discharge hole 9. 9 is the area of the narrowest portion of the net flow path within the area 9. Therefore, in this chemical solution discharge container 100A, when the chemical solution discharge hole 9 is not filled with the filter 14, the portion having the smallest channel cross-sectional area is the tip opening portion 5. However, when the chemical solution discharge hole 9 is filled with the filter 14 as shown in FIG. 1A, the opening area of the chemical solution discharge hole 9 at the portion where the filter 14 is filled is as shown in FIG. When the narrow channel area (the minimum value of the net channel area obtained by subtracting the area occupied by the filter 14 from the channel area of the chemical solution discharge nozzle 4 itself) is smaller than the opening area of the tip opening 5, the filter 14 is filled. The narrowest flow path area of the chemical solution discharge hole 9 at the site is set to the above range. Moreover, when the chemical solution discharge hole in the middle portion of the chemical solution discharge nozzle has a smaller diameter than the tip opening, the flow path area of the small diameter portion is set to the above range.

薬液Aの吐出量は、薬液吐出孔9内の流路の最も狭い部分の面積に依存し、その値が小さすぎると薬液Aが吐出されにくく、大きすぎるとカランからの給水が停止している間に薬液吐出ノズル4を通して薬液と空気の置換が連続的に起こり、トイレの使用の有無に関わらず、薬液Aが速やかに無くなっていくが、薬液吐出孔9の最狭流路面積を上述の範囲とすることにより、薬液Aの適量を吐出させることができる。   The discharge amount of the chemical liquid A depends on the area of the narrowest portion of the flow path in the chemical liquid discharge hole 9, and if the value is too small, the chemical liquid A is difficult to be discharged, and if it is too large, the water supply from the currant is stopped. In the meantime, the replacement of the chemical liquid with the air continuously occurs through the chemical liquid discharge nozzle 4, and the chemical liquid A disappears rapidly regardless of whether the toilet is used or not. By setting the range, an appropriate amount of the chemical liquid A can be discharged.

薬液吐出孔の最狭流路面積は、薬液吐出ノズル4の先端開口部あるいは薬液吐出孔9の横断面の口径の他、薬液吐出孔9に充填するフィルターの種類によって調整することができる。また、薬液吐出孔9を単孔構造(図5(a)〜(e)参照)とするか、多孔構造(図5(f)〜(h)参照)とするかによっても調整することができる。したがって、本発明によれば、薬液吐出ノズル4の設計の自由度が高まり、その成型作業が容易となる。特に、最狭流路面積が小さい薬液吐出ノズル4を作製する場合に、薬液吐出ノズル4の先端開口部5の口径は必ずしも小さくしなくてもよいので、薬液吐出ノズル4の成型が容易となる。   The narrowest channel area of the chemical solution discharge hole can be adjusted by the type of the filter filled in the chemical solution discharge hole 9 in addition to the diameter of the tip opening of the chemical solution discharge nozzle 4 or the cross section of the chemical solution discharge hole 9. It can also be adjusted depending on whether the chemical solution discharge hole 9 has a single hole structure (see FIGS. 5A to 5E) or a porous structure (see FIGS. 5F to 5H). . Therefore, according to this invention, the freedom degree of design of the chemical | medical solution discharge nozzle 4 increases, and the shaping | molding operation | work becomes easy. In particular, when the chemical liquid discharge nozzle 4 having the smallest narrow channel area is manufactured, the diameter of the tip opening 5 of the chemical liquid discharge nozzle 4 does not necessarily have to be small, so that the chemical liquid discharge nozzle 4 can be easily molded. .

本発明において、薬液吐出ノズル4の形状は、図3に示したように、内径bがそのまま先端開口部5の口径aとなっている筒状としてもよいが、図1(a)に示したように、内径bに対して先端開口部5の口径aが細い絞りノズルとすることが好ましい。これにより、薬液タンク1内の負圧によって先端開口部5から空気が吸い込まれた場合に、それによって薬液吐出ノズル4が閉塞状態となり、薬液Aの吐出不良が生じることを防止できる。   In the present invention, as shown in FIG. 3, the chemical solution discharge nozzle 4 may have a cylindrical shape in which the inner diameter b is the same as the diameter a of the tip opening 5, as shown in FIG. Thus, it is preferable that the aperture nozzle 5 has a narrow aperture nozzle a having a smaller diameter a than the inner diameter b. Thereby, when air is sucked in from the tip opening 5 due to the negative pressure in the chemical liquid tank 1, it is possible to prevent the chemical liquid discharge nozzle 4 from being closed and thereby causing a discharge failure of the chemical liquid A.

また、薬液吐出ノズル4の形状としては、図1(a)に示したように、先端部4aを鋭角とすることが好ましい。これにより、先端開口部5に薬液Aを保持する表面張力が弱まり、先端開口部5に保持されていた薬液Aが確実にカランから給水された水で洗われ、ロータンク内に吐出されるようになる。先端部4aを鋭角にする態様としては、図4に示したように薬液吐出ノズル4の外径と内径を先端部に向かって狭めてもよい。   Further, as the shape of the chemical solution discharge nozzle 4, it is preferable that the tip portion 4a has an acute angle as shown in FIG. As a result, the surface tension for holding the chemical liquid A in the tip opening 5 is weakened, so that the chemical liquid A held in the tip opening 5 is reliably washed with water supplied from the currant and discharged into the low tank. Become. As an aspect which makes the front-end | tip part 4a an acute angle, as shown in FIG. 4, you may narrow the outer diameter and internal diameter of the chemical | medical solution discharge nozzle 4 toward a front-end | tip part.

薬液吐出ノズル4の横断面形状については、特に制限はない。例えば、薬液吐出孔9を単孔構造とする場合、図5(a)のように円とする他、楕円(同図(b))、矩形(同図(c))、星形(同図(d))、三角形(同図(e))等とすることができる。また、多孔構造とする場合、図5(f)、(g)のようにノズル基材に複数の孔を形成してもよく、同図(h)のように単孔構造のノズル4’内に、断面が格子状の流路仕切り材15を嵌め込んでもよい。   There is no restriction | limiting in particular about the cross-sectional shape of the chemical | medical solution discharge nozzle 4. FIG. For example, when the chemical solution discharge hole 9 has a single-hole structure, it is a circle as shown in FIG. 5A, an ellipse (FIG. 5B), a rectangle (FIG. 5C), a star (FIG. 5). (D)), a triangle ((e) in the figure), and the like. In the case of a porous structure, a plurality of holes may be formed in the nozzle substrate as shown in FIGS. 5 (f) and 5 (g), and inside the single-hole structure nozzle 4 ′ as shown in FIG. 5 (h). Alternatively, the flow path partition member 15 having a lattice-like cross section may be fitted.

フィルター14は、薬液吐出孔9の最狭流路面積を調整するため、必要に応じて薬液吐出ノズル4内に充填される。このフィルター14としては、水透過性のよい材料を使用することが好ましく、例えば、ポリウレタン、ポリエチレン、ナイロン、メラミン等の合成樹脂の連続気泡フォーム、ハニカム状、メッシュ状、網状等の層からなる3次元骨格組織を有する織布、不織布、金属繊維集合体等を使用することができる。中でもセル数5〜50個/25mmの連続気泡フォームが好ましく、特に連続気泡ウレタンフォームが好ましい。なお、連続気泡フォームを充填する場合、そのセル数が多い程、薬液Aの吐出量が少なくなるので、使用する連続気泡ウレタンフォームのセル数を適宜選択することにより、薬液Aの吐出量を調整することができる。   The filter 14 is filled in the chemical liquid discharge nozzle 4 as necessary in order to adjust the narrowest flow path area of the chemical liquid discharge hole 9. The filter 14 is preferably made of a material having good water permeability. For example, the filter 14 is composed of an open-cell foam of a synthetic resin such as polyurethane, polyethylene, nylon, and melamine, a honeycomb-like, mesh-like, or net-like layer 3. A woven fabric, a nonwoven fabric, a metal fiber aggregate, or the like having a dimensional skeleton structure can be used. Among them, an open cell foam having 5 to 50 cells / 25 mm is preferable, and an open cell urethane foam is particularly preferable. In addition, when filling open-cell foam, the larger the number of cells, the smaller the discharge amount of chemical solution A. Therefore, the discharge amount of chemical solution A can be adjusted by appropriately selecting the number of open-cell urethane foam cells to be used. can do.

水洗トイレのフラッシュ1回あたりの薬液Aの吐出量は、薬液の効果が十分に発揮され、かつ過剰な薬液の吐出を抑制してトイレでの使用持続回数が多くなるように、薬液の種類、濃度等に応じて適切な量、例えば、フラッシュ1回当たりの薬液吐出量0.05〜0.5gとすることが好ましく、さらに、約1ヶ月の使用を考慮すると、0.1〜0.2gとすることが好ましい。そのために本発明の範囲内で薬液Aの比重及び薬液吐出孔9の最狭流路面積を適宜組み合わせることが好ましい。   The amount of chemical A discharged per flush in the flush toilet is such that the effect of the chemical is fully exerted, and that the number of sustained use in the toilet is increased by suppressing the excessive discharge of the chemical, It is preferable to use an appropriate amount according to the concentration, for example, 0.05 to 0.5 g of a chemical discharge amount per flash, and 0.1 to 0.2 g in consideration of use for about one month. It is preferable that Therefore, it is preferable to appropriately combine the specific gravity of the chemical liquid A and the narrowest channel area of the chemical liquid discharge hole 9 within the scope of the present invention.

薬液Aとしては、水道水に含まれる塩素に対して耐性があるものが好ましい。また、薬液Aには、必要に応じて人体に安全な青色、緑色等の着色剤を含有させることができる。   As chemical | medical solution A, what has tolerance with respect to the chlorine contained in tap water is preferable. Further, the chemical liquid A can contain a colorant such as blue or green that is safe for the human body, if necessary.

薬液タンク1は、そこに充填された薬液Aの残量を薬液タンク1外から観察できるように、透明又は半透明材料から形成されているものが好ましい。   The chemical tank 1 is preferably made of a transparent or translucent material so that the remaining amount of the chemical liquid A filled therein can be observed from outside the chemical tank 1.

キャップ3の底部には、カランから供給された水を薬液吐出ノズル4の方に流し、薬液吐出ノズル4に沿って流下させる水誘導構造を設けることが好ましい。図1の薬液吐出容器100Aには、水誘導構造の一態様として、薬液吐出ノズル4を中心として放射状に起立した8枚の板状部7がこのキャップ3と一体に設けられている。また、キャップ3には足6が一体的に設けられている。   It is preferable that a water guiding structure is provided at the bottom of the cap 3 so that the water supplied from the currant flows toward the chemical liquid discharge nozzle 4 and flows down along the chemical liquid discharge nozzle 4. In the chemical solution discharge container 100A of FIG. 1, eight plate-like portions 7 erected radially around the chemical solution discharge nozzle 4 are provided integrally with the cap 3 as one aspect of the water guiding structure. The cap 3 is integrally provided with a foot 6.

この水誘導構造をなす板状部7は、本発明において必要に応じて設けられる。薬液吐出ノズル4を中心として放射状に板状部7を設けることにより、ロータンクの手洗い部20の形状、手洗水の水量、水圧、手洗い部20における薬液吐出容器100Aの載置位置等によらず、カランから供給された水を、板状部7に沿わせて薬液吐出ノズル4の方に流し、次いで、薬液吐出ノズル4に沿わせてロータンク内に流下させることができる。したがって、先端開口部5から滴下しかかった薬液を、カランから供給された水の流れにより、確実にロータンク内に混入させることが可能となる。また、キャップ3の底面が吸水口21を塞ぐことが防止されるので、手洗い部20に水が溢れることを防止できる。   The plate-like portion 7 forming this water guiding structure is provided as necessary in the present invention. By providing the plate-like portion 7 radially with the chemical solution discharge nozzle 4 as the center, regardless of the shape of the hand-washing portion 20 of the low tank, the amount of water in the hand-washing water, the water pressure, the placement position of the chemical-solution discharge container 100A in the hand-washing portion 20, etc. The water supplied from the currant can flow along the plate-like portion 7 toward the chemical liquid discharge nozzle 4, and then flow down along the chemical liquid discharge nozzle 4 into the raw tank. Therefore, it is possible to reliably mix the chemical solution dripped from the tip opening 5 into the low tank by the flow of water supplied from the currant. Further, since the bottom surface of the cap 3 is prevented from blocking the water inlet 21, it is possible to prevent water from overflowing into the hand-washing portion 20.

なお、水誘導構造の態様は、上述の例に限らない。例えば、水誘導構造をなす板状部7は、薬液吐出ノズル4を中心として放射状に起立したものである限り、その形状は平板でも曲板でもよい。   In addition, the aspect of a water guidance structure is not restricted to the above-mentioned example. For example, as long as the plate-like portion 7 forming the water guiding structure rises radially around the chemical solution discharge nozzle 4, the shape thereof may be a flat plate or a curved plate.

このトイレ洗浄用品200Aの使用方法としては、まず、薬液Aが薬液タンク1に収容されている状態において、トイレ洗浄用品200Aを水洗トイレの手洗い付きロータンクの手洗い部20の吸水口21上に載置し、薬液吐出ノズル4を吸水口21に挿入する。この状態で、薬液吐出ノズル4の先端開口部5には、表面張力と薬液タンク1内の弱い負圧により薬液Aが保持されている。   As a method of using the toilet cleaning product 200A, first, in the state where the chemical solution A is stored in the chemical solution tank 1, the toilet cleaning product 200A is placed on the water suction port 21 of the hand-washing portion 20 of the low tank with hand-washing of the flush toilet. Then, the chemical solution discharge nozzle 4 is inserted into the water inlet 21. In this state, the chemical liquid A is held in the tip opening 5 of the chemical liquid discharge nozzle 4 by the surface tension and the weak negative pressure in the chemical liquid tank 1.

なお、ロータンクの吸水口21上にカランが設けられ、薬液タンク1の上方から水が供給される場合について、以下に説明するが、ロータンクの吸水口21上にはカランがなく、したがって、ロータンクの吸水口21に薬液吐出ノズル4を挿入した場合に、薬液タンク1の側方のカランから水が供給される場合でも、このトイレ洗浄用品200Aは使用することができる。   A case where a currant is provided on the water inlet 21 of the low tank and water is supplied from above the chemical tank 1 will be described below. However, there is no curan on the water inlet 21 of the low tank, and accordingly, When the chemical liquid discharge nozzle 4 is inserted into the water suction port 21, the toilet cleaning product 200 </ b> A can be used even when water is supplied from the side of the chemical liquid tank 1.

図2に示すように、トイレ洗浄用品200Aを手洗い部20に載置後、水洗トイレの水がフラッシュされ、カランから水が供給されると、水Wは、薬液タンク1に沿って手洗い部20に流れ込む。手洗い部20に流れ込んだ水Wは、板状部7に沿って薬液吐出ノズル4の方に流れ、薬液吐出ノズル4の先端開口部5を洗うようにしてロータンク内に入る。   As shown in FIG. 2, after the toilet cleaning product 200 </ b> A is placed on the hand-washing unit 20, when the water in the flush toilet is flushed and water is supplied from the currant, the water W flows along the chemical tank 1 to the hand-washing unit 20. Flow into. The water W that has flowed into the hand-washing portion 20 flows along the plate-like portion 7 toward the chemical solution discharge nozzle 4 and enters the low tank so as to wash the tip opening 5 of the chemical solution discharge nozzle 4.

したがって、先端開口部5に保持されていた薬液Aが水Wで洗い流され、確実にロータンク内に混入する。また、カランから給水された水の温度がトイレの室温よりも高い場合には、ヘッドスペースが温められ、その膨張により薬液が吐出される。   Therefore, the chemical solution A held in the tip opening 5 is washed away with the water W and reliably mixed into the low tank. Moreover, when the temperature of the water supplied from the currant is higher than the room temperature of the toilet, the head space is warmed and the chemical liquid is discharged by the expansion.

薬液タンク1からロータンク内に混入した薬液の量に応じて、先端開口部5から直ちに空気が薬液タンク1内に入り、薬液吐出ノズル4の先端開口部5には薬液Aが保持される。ここで、薬液Aの比重は1.00未満であるため、洗い流された薬液Aの量に応じて水が薬液タンク1内に入り、薬液タンク1内の薬液が希釈されていくことはない。   Depending on the amount of the chemical liquid mixed from the chemical liquid tank 1 into the raw tank, air immediately enters the chemical liquid tank 1 from the front end opening 5, and the chemical liquid A is held in the front end opening 5 of the chemical liquid discharge nozzle 4. Here, since the specific gravity of the chemical solution A is less than 1.00, water does not enter the chemical solution tank 1 according to the amount of the washed chemical solution A, and the chemical solution in the chemical solution tank 1 is not diluted.

カランからの給水が止まると薬液吐出ノズル4の先端開口部5に保持されている薬液Aをさらう水の流れがなくなる。   When the water supply from the currant stops, there is no flow of water exposing the chemical liquid A held in the tip opening 5 of the chemical liquid discharge nozzle 4.

また、カランからの給水により薬液タンク1内のヘッドスペースが温められた場合には、カランからの給水が止まるとヘッドスペースが冷えて収縮し、薬液タンク1内に空気が吸い込まれる。   Further, when the head space in the chemical tank 1 is warmed by the water supply from the currant, the head space is cooled and contracted when the water supply from the currant stops, and air is sucked into the chemical tank 1.

一方、カランから給水された水の温度がトイレの室温よりも低い場合、カランからの給水時には薬液タンク1内のヘッドスペースが冷えて収縮し、薬液タンク1内に空気が吸い込まれる。そしてカランからの給水が止まると、ヘッドスペースの温度が室温に戻り、膨張して薬液Aが吐出される。   On the other hand, when the temperature of the water supplied from the currant is lower than the room temperature of the toilet, the head space in the chemical tank 1 is cooled and contracted during the supply of water from the currant, and air is sucked into the chemical tank 1. When the water supply from the currant stops, the temperature of the head space returns to room temperature, expands, and the chemical liquid A is discharged.

また、カランからの給水とは別に、トイレの室温の一日の変動によってもヘッドスペースの膨張により薬液Aが吐出される。   In addition to the water supply from the currant, the chemical solution A is discharged due to the expansion of the head space even when the toilet room temperature changes daily.

このように、このトイレ洗浄用品200Aでは、カランからの給水やトイレの室温の変化等によって薬液タンク1から薬液が吐出されるが、薬液タンク1内の薬液Aは比重が1.00未満であるためにカランから供給された水と置換し難いので、薬液Aの吐出は、水との置換よりも、主として、カランからの給水やトイレの室温の変化等によるヘッドスペースの膨張によりなされる。したがって、ヘッドスペースを薬液タンクの容積の15%以上とすることにより、ヘッドスペースの膨張によって確実に薬液Aが吐出され、また、薬液Aの吐出ごとに薬液タンク1内に空気が入り、薬液タンク1内の液量が減少していく。
よって、この薬液吐出容器100Aによれば、十分な薬効のない薬液Aを使い続けるという事態が防止され、十分な薬効を有する状態で最後まで薬液Aを使いきることができる。
As described above, in the toilet cleaning product 200A, the chemical liquid is discharged from the chemical liquid tank 1 due to water supply from the currant, a change in the room temperature of the toilet, etc., but the specific gravity of the chemical liquid A in the chemical liquid tank 1 is less than 1.00. Therefore, since it is difficult to replace the water supplied from the currant, the discharge of the chemical solution A is performed mainly by the expansion of the head space due to the water supply from the currant, the change in the room temperature of the toilet, and the like, rather than the replacement with the water. Therefore, by setting the head space to 15% or more of the volume of the chemical liquid tank, the chemical liquid A is reliably discharged by the expansion of the head space, and air enters the chemical liquid tank 1 every time the chemical liquid A is discharged, and the chemical liquid tank The amount of liquid in 1 decreases.
Therefore, according to this chemical solution discharge container 100A, the situation of continuing to use the chemical solution A having no sufficient medicinal effect can be prevented, and the chemical solution A can be used up to the end with a sufficient medicinal effect.

本発明の薬液吐出容器は、この他種々の態様をとることができる。例えば、図6に示すトイレ洗浄用品200Bの薬液吐出容器100Bのように、薬液吐出ノズルを設けることなく、キャップ3に直接的に薬液吐出孔9を開口してもよく、また、板状部7からなる水誘導構造を省略してもよい。本発明の薬液吐出容器によれば、薬液タンク1内のヘッドスペースの膨張により確実に薬液が吐出されるので、このように簡単な構造とすることができる。   The chemical solution discharge container of the present invention can take various other forms. For example, like the chemical liquid discharge container 100B of the toilet cleaning product 200B shown in FIG. 6, the chemical liquid discharge hole 9 may be directly opened in the cap 3 without providing the chemical liquid discharge nozzle. The water guiding structure consisting of may be omitted. According to the chemical solution discharge container of the present invention, the chemical solution is reliably discharged by the expansion of the head space in the chemical solution tank 1, and thus a simple structure can be obtained.

また、図7の薬液吐出容器100xについても、その薬液吐出ノズルの薬液吐出孔の最狭流路面積を0.2〜80mm2とし、比重1.00未満の薬液を充填することにより、本発明のトイレ洗浄用品とすることができる。 Further, the chemical solution discharge container 100x in FIG. 7 is also filled with a chemical solution having a specific gravity less than 1.00 with the narrowest flow area of the chemical solution discharge hole of the chemical solution discharge nozzle being 0.2 to 80 mm 2. It can be a toilet cleaning product.

(1)薬液の充填量と吐出性能との関係
図1の薬液吐出容器100Aにおいて、薬液吐出ノズル4へのフィルター14の充填を省略したものを作製した(薬液タンクの満容量100mL、薬液吐出ノズル4の先端開口部の口径2mm、薬液吐出孔9の最狭流路面積3mm2)。
(1) Relationship Between Chemical Liquid Filling Volume and Discharge Performance In the chemical liquid discharge container 100A of FIG. 1, a chemical liquid discharge nozzle 4 filled with the filter 14 was prepared (chemical liquid tank full capacity 100 mL, chemical liquid discharge nozzle 4 at the tip opening of 2 mm, the narrowest channel area of the chemical solution discharge hole 9 3 mm 2 ).

一方、表2に示すように、比重(20℃)が0.92、1.05、1.24の3種の薬液A1、A2、A3を調製し、上述の容器に、これら3種の薬液を、それぞれ100mL(満容量)、80mL、又は60mL充填し、これをモデルトイレ(トイレ室温23〜26℃、水温22〜24℃)に設置して1時間間隔でフラッシュを500回繰り返し、その後に薬液タンク内の液残量を測定した。結果を表3に示す。

On the other hand, as shown in Table 2, three types of chemical solutions A1, A2, and A3 having specific gravity (20 ° C.) of 0.92, 1.05, and 1.24 were prepared, and these three types of chemical solutions were placed in the container described above. Are filled in 100 mL (full capacity), 80 mL, or 60 mL, respectively, installed in a model toilet (toilet room temperature 23-26 ° C., water temperature 22-24 ° C.), and flushed 500 times at 1-hour intervals, The remaining amount of liquid in the chemical tank was measured. The results are shown in Table 3.

[表2]

Figure 2005061130
(*1)エコーガムT、大日本製薬社
(*2)アルキルグルコシド、直鎖アルキル基の炭素数が12と14の混合物。糖平均縮合度1.2(縮合度1と2の混合物)
(*3)プロキセルBD、アビシア社
[Table 2]
Figure 2005061130
(* 1) Echo Gum T, Dainippon Pharmaceutical Co., Ltd.
(* 2) Alkyl glucoside, a mixture of straight chain alkyl groups having 12 and 14 carbon atoms. Sugar average condensation degree 1.2 (mixture of condensation degree 1 and 2)
(* 3) Proxel BD, Avicia

[表3]

Figure 2005061130
[Table 3]
Figure 2005061130

表3の結果から、比重1.00未満の薬液を充填し、薬液タンク内にヘッドスペースを設けることにより、薬液の吐出に伴って薬液タンク内の薬液が希釈されることなく、薬液タンク内の液残量が確実に減少することがわかる。
From the results of Table 3, by filling a chemical solution having a specific gravity of less than 1.00 and providing a head space in the chemical solution tank, the chemical solution in the chemical solution tank is not diluted with the discharge of the chemical solution. It can be seen that the remaining amount of liquid is surely reduced.

(2)薬液吐出孔の最狭流路面積と吐出性能との関係
(1)の容器と同様にして、薬液吐出ノズル4の先端開口部の口径が0.34mm(最狭流路面積0.1mm2)、1.12mm(最狭流路面積1.0mm2)、2.6mm(最狭流路面積5mm2)、3.6mm(最狭流路面積10mm2)、11.2mm(最狭流路面積100mm2)の5種の容器を作製し、それぞれに、上述の3種の薬液A1、A2、A3を70mL充填し、これをモデルトイレ(トイレ室温23〜26℃、水温22〜24℃)に設置して1時間間隔でフラッシュを500回繰り返し、その後に薬液タンク内の液残量を測定した。結果を表4に示す。


(2) Relationship between the narrowest flow path area of the chemical liquid discharge hole and the discharge performance In the same manner as in the container of (1), the diameter of the tip opening of the chemical liquid discharge nozzle 4 is 0.34 mm (the narrowest flow path area is. 1 mm 2 ), 1.12 mm (narrowest channel area 1.0 mm 2 ), 2.6 mm (narrowest channel area 5 mm 2 ), 3.6 mm (narrowest channel area 10 mm 2 ), 11.2 mm (maximum 5 types of containers having a narrow flow area of 100 mm 2 ) are prepared, and each of them is filled with 70 mL of the above-mentioned three types of chemical solutions A1, A2, and A3. This is a model toilet (toilet room temperature 23 to 26 ° C., water temperature 22 to At 24 ° C.) and flashing was repeated 500 times at 1 hour intervals, and then the remaining amount of liquid in the chemical tank was measured. The results are shown in Table 4.


[表4]

Figure 2005061130
[Table 4]
Figure 2005061130

表4の結果から、薬液吐出孔の最狭流路面積が1mm2、5mm2、10mm2の容器に、比重1.00未満の薬液を充填した場合には、薬液の吐出に伴って薬液タンク内の薬液が希釈されることなく、薬液タンク内の液残量が確実に減少することがわかる。 The results in Table 4, when the narrowest flow area of the solution discharge hole in the container of 1mm 2, 5mm 2, 10mm 2 , was filled with drug solution specific gravity of less than 1.00, the chemical tank along with the discharge of the chemical It can be seen that the remaining amount of liquid in the chemical liquid tank is surely reduced without dilution of the internal chemical liquid.

本発明の薬液吐出容器は、水洗トイレの手洗い付きロータンクである限り、手洗い部におけるカランや吸水口の位置等に関わらず、使用することができる。   The chemical solution discharge container of the present invention can be used regardless of the position of the currant, the water inlet or the like in the hand-washing part, as long as it is a low tank with hand-washing in a flush toilet.

本発明のトイレ洗浄用品を正面から見た部分断面図とその部分拡大断面図(a)、側面図(b)、上面図(c)及び底面図(d)である。It is the fragmentary sectional view which looked at the toilet cleaning goods of this invention from the front, its partial expanded sectional view (a), side view (b), top view (c), and bottom view (d). 本発明のトイレ洗浄用品をロータンクの手洗い部に載置した状態の断面図である。It is sectional drawing of the state which mounted the toilet cleaning goods of this invention in the hand-washing part of a low tank. 薬液吐出ノズルの断面図である。It is sectional drawing of a chemical | medical solution discharge nozzle. 薬液吐出ノズルの断面図である。It is sectional drawing of a chemical | medical solution discharge nozzle. 薬液吐出ノズルの横断面図である。It is a cross-sectional view of a chemical solution discharge nozzle. 本発明の異なる態様のトイレ洗浄用品をロータンクの手洗い部に載置した状態の断面図である。It is sectional drawing of the state which mounted the toilet cleaning goods of the different aspect of this invention in the hand-washing part of a low tank. 薬液吐出容器の斜視図(a)、及びロータンクの手洗い部に載置した薬液吐出容器の断面図(b)である。It is the perspective view (a) of a chemical | medical solution discharge container, and sectional drawing (b) of the chemical | medical solution discharge container mounted in the hand-washing part of a low tank.

符号の説明Explanation of symbols

1 薬液タンク
2 薬液タンクの底部開口部
3 キャップ
4 薬液吐出ノズル
4a 薬液吐出ノズルの先端部
5 先端開口部
9 薬液吐出孔
14 フィルター
20 手洗い部
21 吸水口
100A、100B 薬液吐出容器
200A、200B トイレ洗浄用品
A 薬液
W 水
DESCRIPTION OF SYMBOLS 1 Chemical liquid tank 2 Opening part of chemical liquid tank 3 Cap 4 Chemical liquid discharge nozzle 4a Tip part of chemical liquid discharge nozzle 5 Tip opening part 9 Chemical liquid discharge hole 14 Filter 20 Hand washing part 21 Water inlet 100A, 100B Chemical liquid discharge container 200A, 200B Toilet cleaning Article A Chemical liquid W Water

Claims (5)

薬液を収容する薬液タンク、及び薬液タンクの下方に設けられた薬液吐出孔からなり、
薬液の比重が1.00未満0.75以上、
薬液吐出孔の最狭流路面積が0.2〜80mm2
である薬液吐出容器。
It consists of a chemical solution tank that contains the chemical solution, and a chemical solution discharge hole provided below the chemical solution tank,
The specific gravity of the chemical solution is less than 1.00 and 0.75 or more,
The narrowest channel area of the chemical solution discharge hole is 0.2 to 80 mm 2
A chemical discharge container.
薬液タンク内のヘッドスペースが、薬液タンクの満容量の15%以上である請求項1記載の薬液吐出容器。 The chemical solution discharge container according to claim 1, wherein a head space in the chemical solution tank is 15% or more of a full capacity of the chemical solution tank. 薬液吐出孔が、薬液タンクの下方に設けられた薬液吐出ノズルに形成されている請求項1又は請求項2記載の薬液吐出容器。 The chemical solution discharge container according to claim 1 or 2, wherein the chemical solution discharge hole is formed in a chemical solution discharge nozzle provided below the chemical solution tank. 薬液吐出ノズル内にフィルターが充填されている請求項3記載の薬液吐出容器。 The chemical solution discharge container according to claim 3, wherein a filter is filled in the chemical solution discharge nozzle. 請求項1〜4のいずれかに記載の薬液吐出容器の薬液タンクに、トイレ洗浄液が充填されてなるトイレ洗浄用品。

A toilet cleaning product in which the chemical liquid tank of the chemical liquid discharge container according to any one of claims 1 to 4 is filled with a toilet cleaning liquid.

JP2003294764A 2003-08-18 2003-08-18 Chemical discharge container Expired - Lifetime JP4614042B2 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006106987A1 (en) * 2005-03-31 2006-10-12 Kobayashi Pharmaceutical Co., Ltd. Chemical supply unit

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02229333A (en) * 1989-03-01 1990-09-12 Kao Corp Liquid fragrant cleaner device for on-tank type flush toilet
JP2001140311A (en) * 1999-11-15 2001-05-22 Takayasu Okubo Chlorine remover fitted to faucet
JP2002242260A (en) * 2001-02-15 2002-08-28 Kao Corp Chemical discharge vessel

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02229333A (en) * 1989-03-01 1990-09-12 Kao Corp Liquid fragrant cleaner device for on-tank type flush toilet
JP2001140311A (en) * 1999-11-15 2001-05-22 Takayasu Okubo Chlorine remover fitted to faucet
JP2002242260A (en) * 2001-02-15 2002-08-28 Kao Corp Chemical discharge vessel

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006106987A1 (en) * 2005-03-31 2006-10-12 Kobayashi Pharmaceutical Co., Ltd. Chemical supply unit
JP2006283539A (en) * 2005-03-31 2006-10-19 Kobayashi Pharmaceut Co Ltd Chemical-solution feeder

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