JP2005034835A5 - - Google Patents

Download PDF

Info

Publication number
JP2005034835A5
JP2005034835A5 JP2004147105A JP2004147105A JP2005034835A5 JP 2005034835 A5 JP2005034835 A5 JP 2005034835A5 JP 2004147105 A JP2004147105 A JP 2004147105A JP 2004147105 A JP2004147105 A JP 2004147105A JP 2005034835 A5 JP2005034835 A5 JP 2005034835A5
Authority
JP
Japan
Prior art keywords
catalyst
conductive film
lattice constant
exhaust gas
particles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2004147105A
Other languages
Japanese (ja)
Other versions
JP2005034835A (en
JP4466191B2 (en
Filing date
Publication date
Application filed filed Critical
Priority to JP2004147105A priority Critical patent/JP4466191B2/en
Priority claimed from JP2004147105A external-priority patent/JP4466191B2/en
Publication of JP2005034835A publication Critical patent/JP2005034835A/en
Publication of JP2005034835A5 publication Critical patent/JP2005034835A5/ja
Application granted granted Critical
Publication of JP4466191B2 publication Critical patent/JP4466191B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Claims (13)

導電性膜と、前記導電性膜の上に形成された触媒粒子とを備え、前記導電性膜を構成する材料の格子定数と前記触媒粒子を構成する材料の格子定数の差が16%以下であることを特徴とする触媒構造体。   A conductive film; and catalyst particles formed on the conductive film, wherein a difference between a lattice constant of a material forming the conductive film and a lattice constant of a material forming the catalyst particle is 16% or less. A catalyst structure characterized by being. 導電性膜と、前記導電性膜に隣接して形成された触媒粒子と、前記触媒粒子に接触して形成されたコーティング材料とを備え、前記導電性膜を構成する材料の格子定数と前記触媒粒子を構成する材料の格子定数の差が16%以下であることを特徴とする触媒構造体。   A conductive film, a catalyst particle formed adjacent to the conductive film, and a coating material formed in contact with the catalyst particle, and a lattice constant of the material constituting the conductive film and the catalyst A catalyst structure characterized in that a difference in lattice constant between materials constituting particles is 16% or less. 前記触媒粒子の主構成材料が白金族合金である請求項1に記載の触媒構造体。   The catalyst structure according to claim 1, wherein a main constituent material of the catalyst particles is a platinum group alloy. 導電性膜と、前記導電性膜の上に形成された触媒粒子とを備え、前記導電性膜を構成する材料の格子定数と前記触媒粒子を構成する材料の格子定数の差が16%以下であり、前記触媒粒子の主構成材料がPtRuまたはPtMoである触媒構造体。 A conductive film; and catalyst particles formed on the conductive film, wherein a difference between a lattice constant of a material forming the conductive film and a lattice constant of a material forming the catalyst particle is 16% or less. There, the main constituent material is PtRu or PtMo der Ru catalysts structure of the catalyst particles. 前記導電性膜の主構成元素がNi、Co、Fe、Cu、Au、Ag、Al、Tiの群から選ばれる一つを有する請求項1に記載の触媒構造体。   The catalyst structure according to claim 1, wherein the main constituent element of the conductive film has one selected from the group consisting of Ni, Co, Fe, Cu, Au, Ag, Al, and Ti. 導電性膜と、前記導電性膜に隣接して形成された触媒粒子と、前記触媒粒子に接触して形成されたコーティング材料とを備え、前記導電性膜を構成する材料の格子定数と前記触媒粒子を構成する材料の格子定数の差が16%以下であり、前記触媒粒子の主構成材料がPtRuまたはPtMoを有し、前記触媒粒子の大きさが2.6 nm以上4.2 nm以下であり、前記導電性膜の主構成元素がNi、Co、Fe、Cu、Au、Ag、Al、Tiの群から選ばれる一つを有し、前記コーティング材料の主構成材料がDNA分子である触媒構造体。 A conductive film, a catalyst particle formed adjacent to the conductive film, and a coating material formed in contact with the catalyst particle, and a lattice constant of the material constituting the conductive film and the catalyst The difference in lattice constant between the materials constituting the particles is 16% or less, the main constituent material of the catalyst particles is PtRu or PtMo, the size of the catalyst particles is 2.6 nm or more and 4.2 nm or less, and the conductive the main constituent element Ni sex film, Co, Fe, Cu, Au , Ag, Al, has one selected from the group consisting of Ti, touch the main constituent material of the coating material Ru Ah in the DNA molecule media structure . 導電性膜と、前記導電性膜に隣接して形成された触媒粒子と、前記触媒粒子に接触して形成されたコーティング材料とを備え、前記導電性膜を構成する材料の格子定数と前記触媒粒子を構成する材料の格子定数の差が16%以下であり、前記触媒粒子の主構成材料が白金族合金であり、前記導電性膜の主構成元素がNi、Co、Fe、Cu、Au、Ag、Al、Tiの群から選ばれる一つであり、前記コーティング材料の主構成材料がカーボンナノホーンである触媒構造体。 A conductive film, a catalyst particle formed adjacent to the conductive film, and a coating material formed in contact with the catalyst particle, and a lattice constant of the material constituting the conductive film and the catalyst The difference in lattice constant between the materials constituting the particles is 16% or less, the main constituent material of the catalyst particles is a platinum group alloy, and the main constituent elements of the conductive film are Ni, Co, Fe, Cu, Au, Ag, Al, is one selected from the group consisting of Ti, catalytic structure main component material is Ru carbon nanohorn der of the coating material. 導電性膜と、前記導電性膜に隣接して形成された触媒粒子と、前記触媒粒子に接触して形成されたコーティング材料とを備え、前記導電性膜を構成する材料の格子定数と前記触媒粒子を構成する材料の格子定数の差が16%以下であり、前記触媒粒子の主構成材料がPtRuまたはPtMoを有し、前記導電性膜の主構成元素がNi、Co、Fe、Cu、Au、Ag、Al、Tiの群から選ばれる一つを有し、前記コーティング材料の主構成材料がカーボンナノホーンである触媒構造体。 A conductive film, a catalyst particle formed adjacent to the conductive film, and a coating material formed in contact with the catalyst particle, and a lattice constant of the material constituting the conductive film and the catalyst The difference in lattice constant between the materials constituting the particles is 16% or less, the main constituent material of the catalyst particles has PtRu or PtMo, and the main constituent elements of the conductive film are Ni, Co, Fe, Cu, Au , Ag, Al, has one selected from the group consisting of Ti, catalytic structure main component material is Ru carbon nanohorn der of the coating material. 燃料極と、酸素極と、前記燃料極と前記酸素極との間に配置される電解質膜とを備え、前記酸素極が触媒を備え、前記触媒は、導電性膜と、前記導電性膜の上に形成された触媒粒子とを備え、前記導電性膜を構成する材料の格子定数と前記触媒粒子を構成する材料の格子定数の差が16%以下である燃料電池。 A fuel electrode; an oxygen electrode; and an electrolyte membrane disposed between the fuel electrode and the oxygen electrode, wherein the oxygen electrode comprises a catalyst, the catalyst comprising: a conductive film; and A fuel cell comprising: catalyst particles formed thereon, wherein a difference between a lattice constant of a material constituting the conductive film and a lattice constant of a material constituting the catalyst particle is 16% or less . 電解質膜と、前記電解質膜の一方側面に隣接して形成された燃料極と、前記燃料極が配置された面の反対側面に隣接して形成された電解質膜とを備え、前記燃料極にはアルコールを原料とする燃料が用いられ、前記酸素極が、触媒構造を備え、前記触媒構造は、導電性膜と、前記導電性膜に隣接して形成された触媒粒子と、前記触媒粒子に接触して形成されたコーティング材料とを備え、前記導電性膜を構成する材料の格子定数と前記触媒粒子を構成する材料の格子定数の差が16%以下である燃料電池。 An electrolyte membrane; a fuel electrode formed adjacent to one side surface of the electrolyte membrane; and an electrolyte membrane formed adjacent to a side surface opposite to the surface on which the fuel electrode is disposed. A fuel using alcohol as a raw material is used, and the oxygen electrode has a catalyst structure, and the catalyst structure is in contact with a conductive film, catalyst particles formed adjacent to the conductive film, and the catalyst particles. A fuel cell , wherein a difference between a lattice constant of a material constituting the conductive film and a lattice constant of a material constituting the catalyst particles is 16% or less . 内燃機関からの排ガス供給部と、前記排ガス供給部から供給された前記排ガスが導入される触媒コンバータとを備えた内燃機関の排ガス浄化システムであって、前記触媒コンバータは、請求項1から請求項8の何れかに記載の触媒構造体を備えていることを特徴とする排ガス浄化システム。   An exhaust gas purification system for an internal combustion engine comprising an exhaust gas supply unit from an internal combustion engine and a catalytic converter into which the exhaust gas supplied from the exhaust gas supply unit is introduced, wherein the catalytic converter is from claim 1 to claim 2. An exhaust gas purification system comprising the catalyst structure according to any one of 8. 排ガスの供給部と、前記供給された排ガス中の煤塵を除去する第一バグフィルタ装置と、前記第一バグフィルタ装置を経た排ガスに含まれる有機ハロゲン化合物を除去する吸着剤充填層装置と、前記吸着剤充填層装置を経た排ガス中の酸性成分を除去する第二バグフィルタ装置を備えた排ガス処理システムであって、前記吸着剤充填層装置が請求項1から請求項8の何れかに記載の触媒構造体を備えていることを特徴とする排ガス処理システム。   An exhaust gas supply unit, a first bag filter device that removes dust in the supplied exhaust gas, an adsorbent packed bed device that removes organic halogen compounds contained in the exhaust gas that has passed through the first bag filter device, and It is an exhaust gas treatment system provided with the 2nd bag filter apparatus which removes the acidic component in the exhaust gas which passed through the adsorbent packed bed apparatus, Comprising: The said adsorbent packed bed apparatus is in any one of Claims 1-8. An exhaust gas treatment system comprising a catalyst structure. 格子定数の差が3%以上である請求項1から請求項8の何れかに記載の触媒構造体。
The catalyst structure according to any one of claims 1 to 8, wherein a difference in lattice constant is 3% or more.
JP2004147105A 2003-06-23 2004-05-18 Catalyst structure and fuel cell with catalyst Expired - Fee Related JP4466191B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2004147105A JP4466191B2 (en) 2003-06-23 2004-05-18 Catalyst structure and fuel cell with catalyst

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2003177439 2003-06-23
JP2004147105A JP4466191B2 (en) 2003-06-23 2004-05-18 Catalyst structure and fuel cell with catalyst

Publications (3)

Publication Number Publication Date
JP2005034835A JP2005034835A (en) 2005-02-10
JP2005034835A5 true JP2005034835A5 (en) 2006-11-16
JP4466191B2 JP4466191B2 (en) 2010-05-26

Family

ID=34220103

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2004147105A Expired - Fee Related JP4466191B2 (en) 2003-06-23 2004-05-18 Catalyst structure and fuel cell with catalyst

Country Status (1)

Country Link
JP (1) JP4466191B2 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006223915A (en) * 2005-02-15 2006-08-31 Hitachi Ltd Catalytic structure and exhaust gas treatment system having the same
JP5151146B2 (en) * 2006-03-06 2013-02-27 トヨタ自動車株式会社 Polymer electrolyte fuel cell and method for producing MEA for polymer electrolyte fuel cell used therefor
JP2007301451A (en) * 2006-05-09 2007-11-22 Osaka Univ Catalyst which keeps absorbability of carbon monooxide controlled and method for manufacturing catalyst, and application of the same
DE102007020561A1 (en) * 2007-05-02 2008-11-06 Enerday Gmbh Exhaust system and fuel cell system
CN101890368B (en) * 2010-06-18 2012-01-11 昆明理工大学 Method for preparing carbon-supported high-activity gold or gold-platinum alloy or gold-core platinum-shell structural nano catalyst
KR101365716B1 (en) 2012-09-24 2014-02-21 한국에너지기술연구원 Method of preparing metal-carbon composite supported catalyst using co-vaporization for hydrogen production process and metal-carbon composite supported catalyst for hydrogen production process prepared thereby
JP6852883B2 (en) * 2017-03-16 2021-03-31 国立大学法人九州大学 An electrode structure, an electrode catalyst layer / gas diffusion layer integrated sheet, and a membrane electrode assembly containing these.

Similar Documents

Publication Publication Date Title
Soliman Factors affecting CO oxidation reaction over nanosized materials: A review
Wei et al. Boosting the removal of diesel soot particles by the optimal exposed crystal facet of CeO2 in Au/CeO2 catalysts
Wei et al. SO2-tolerant catalytic removal of soot particles over 3D ordered macroporous Al2O3-supported binary Pt–co oxide catalysts
JP2009082915A5 (en)
JP5664918B2 (en) Exhaust gas purification catalyst
Yu et al. Alkali metals and cerium-modified La–Co-based perovskite catalysts: facile synthesis, excellent catalytic performance, and reaction mechanisms for soot combustion
RU2016106291A (en) PROCESSING PROCESSING CATALYST AMMONIA
JP2013542053A5 (en)
Serinçay et al. Acetaldehyde adsorption and detection: A density functional theory study on Al-doped graphene
KR101521744B1 (en) Exhaust gas purification catalyst
Fu et al. Constructing Pd/CeO2/C to achieve high leaching resistance and activity for catalytic wet air oxidation of aqueous amide
Russo et al. Promotion effect of Au on perovskite catalysts for the regeneration of diesel particulate filters
Lu et al. Synergistic catalysis of methane combustion using Cu–Ce–O hybrid nanoparticles with high activity and operation stability
JP2013208578A5 (en) Exhaust gas purification apparatus for straddle type vehicle and palladium single layer catalyst used therefor
Peng et al. Ammonia abatement via selective oxidation over electron-deficient copper catalysts
Rau et al. Evaluation of SO2 oxidation and fly ash filtration by an activated carbon fluidized-bed reactor: The effects of acid modification, copper addition and operating condition
JP2005034835A5 (en)
CN107597105A (en) A kind of waste gas purification catalysis material and preparation method thereof
Wahid et al. Catalytic material with enhanced contacting efficiency for volatile organic compound removal at ultrashort contact time
Cauda et al. PM0. 1 emissions during diesel trap regeneration
JP6487114B2 (en) Method and apparatus for chemical process enhancement
Castoldi et al. Simultaneous removal of soot and NO x over silver and ruthenium-based catalysts
JP6296412B2 (en) Exhaust gas purification system and exhaust gas purification method
JP4466191B2 (en) Catalyst structure and fuel cell with catalyst
JP2004503375A (en) Ceramic filter element and method of manufacturing the same