JP2005028360A - Light irradiation device, touch-up painting method and application for the same - Google Patents

Light irradiation device, touch-up painting method and application for the same Download PDF

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JP2005028360A
JP2005028360A JP2004179295A JP2004179295A JP2005028360A JP 2005028360 A JP2005028360 A JP 2005028360A JP 2004179295 A JP2004179295 A JP 2004179295A JP 2004179295 A JP2004179295 A JP 2004179295A JP 2005028360 A JP2005028360 A JP 2005028360A
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light
light irradiation
coating
irradiation device
lamp
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JP4578866B2 (en
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Shinji Tomita
真司 冨田
Atsushi Makita
厚 真貴田
Toshikazu Okada
斗士一 岡田
Toshiyuki Ogawa
敏之 小川
Tomomi Matsuoka
智巳 松岡
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Kansai Paint Co Ltd
Ushio Denki KK
Ushio Inc
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Kansai Paint Co Ltd
Ushio Denki KK
Ushio Inc
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a light irradiation device used for both of coating film light setting/coating film color evaluation. <P>SOLUTION: The light irradiation device is equipped with an irradiation instrument provided with a lamp for emitting light having ≤5000K correlated color temperature and a filter arranged in front of the irradiation instrument in the light irradiation direction and attached detachably. The light intensity of the light emitted from the lamp is 1-5 mW/cm<SP>2</SP>in 365 nm wavelength and 20 cm irradiation distance and the light intensity in 800 nm wave length and 10 cm irradiation distance is 80-250 mW/cm<SP>2</SP>. The light irradiation device is used for both methods of the setting of a photosetting composition and the detecting of a coating film color determination. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、光硬化型組成物を硬化することができ、且つ塗膜の色調判定に使用することが可能な、光硬化/塗膜色調判定兼用の光照射装置及び該光照射装置を用いた補修塗装方法に関する。   INDUSTRIAL APPLICABILITY The present invention uses a light irradiating device that can cure a photocurable composition and can be used for determining the color tone of a coating film, and also for photocuring / coating color determination, and the light irradiation device. The repair coating method.

近年、自動車補修塗装の業界では、自動車の損傷部に光硬化型の塗料を塗布、あるいは充填せしめ、光照射装置を用いて補修部に光照射し、該塗料を硬化することが広く実施されている。従来、かかる光照射装置には、メタルハライドランプや高圧水銀ランプなどを光源とした紫外線照射装置が使用されてきたが、人体に有害な紫外線やオゾンが発生する問題があった。そこで紫外線やオゾンの発生がほとんどない300nm以上の波長に発光スペクトルを有する光(可視光〜赤外光)の波長域の光で硬化する光硬化型組成物による補修塗装方法が種々提案されてきている。   In recent years, in the automotive repair coating industry, it has been widely practiced to apply or fill a photo-curable paint to a damaged part of an automobile and to irradiate the repair part with a light irradiation device to cure the paint. Yes. Conventionally, an ultraviolet irradiation device using a metal halide lamp, a high-pressure mercury lamp, or the like as a light source has been used as such a light irradiation device, but there is a problem that ultraviolet rays and ozone harmful to the human body are generated. Therefore, various repair coating methods using a photocurable composition that is cured by light in the wavelength range of light (visible light to infrared light) having an emission spectrum at a wavelength of 300 nm or more with almost no generation of ultraviolet rays or ozone have been proposed. Yes.

例えば特許文献1には、特定の補助具を具備していることを特徴とする光照射装置が記載されている。該装置によれば、目的とする範囲に一定に光照射をすることができ、補修塗装に有用である。また、特許文献2には、ランプの照射方向に熱線カットフィルターを装着してなる照射装置を用いた光照射方法が記載されている。該方法によれば、被塗物に変形や変色などを生じさせることなく、被塗物に塗布された光硬化型組成物を硬化できるものである。特許文献3には、ランプを支持する支持支柱が昇降可能であることを特徴とする光照射装置が記載されている。該光照射装置によれば複雑な形状を有する被塗布物面に塗布された光硬化型組成物を、効率よく光硬化させることができるものである。   For example, Patent Document 1 describes a light irradiation apparatus including a specific auxiliary tool. According to this apparatus, it is possible to irradiate light constantly within a target range, which is useful for repair coating. Patent Document 2 describes a light irradiation method using an irradiation apparatus in which a heat ray cut filter is mounted in the irradiation direction of a lamp. According to this method, the photocurable composition applied to the object to be coated can be cured without causing deformation or discoloration of the object to be coated. Patent Document 3 describes a light irradiation device in which a support column supporting a lamp can be raised and lowered. According to this light irradiation apparatus, the photocurable composition applied to the surface of the object having a complicated shape can be efficiently photocured.

ところで、自動車補修塗装の分野においては、補修塗装後の塗膜の色調を評価するために特定の光照射装置を用いている。かかる塗膜色調評価用の光照射装置としては、相関色温度が6500K〜6800Kの光線を放射する光源を有する人工太陽灯、或いは太陽光と同等のスペクトル分布を示すランプが照射光として使用されており、それが塗料業界の常識とされている。   By the way, in the field of automobile repair coating, a specific light irradiation device is used to evaluate the color tone of the coating film after the repair coating. As such a light irradiation apparatus for coating color tone evaluation, an artificial solar lamp having a light source that emits a light beam having a correlated color temperature of 6500K to 6800K or a lamp having a spectral distribution equivalent to that of sunlight is used as irradiation light. It is common sense in the paint industry.

実際、光硬化型組成物の硬化に使用するための光照射装置を、補修後の仕上がり外観評価すなわち塗膜色調の判定、例えば補修塗膜部と色見本とを比較する比色作業等に使用すると、光の量が強すぎる等の理由で、正確な評価ができず、他方、塗膜色調評価用の光照射装置の光線を光硬化型組成物に照射しても、光量が不足し、充分に硬化反応が進行しないことが一般に知られている。従って、光硬化用の光照射装置と塗膜色調判定用の光照射装置の2品種を作業現場に常備するか、塗膜色調判定を屋外の直射日光で行う等の方法が用いられているのが現状である。
特開平10−40703号 特開2001−259511号公報 実用新案登録第3085776号公報
Actually, the light irradiation device for use in curing the photocurable composition is used for the finished appearance evaluation after repair, that is, the judgment of the coating color tone, for example, the colorimetric work for comparing the repair coating and the color sample. Then, for reasons such as the amount of light is too strong, accurate evaluation can not be performed, on the other hand, even if the photocurable composition is irradiated with the light beam of the light irradiation device for coating color tone evaluation, the light amount is insufficient, It is generally known that the curing reaction does not proceed sufficiently. Therefore, there are methods in which two types of light curing device for photo-curing and light irradiation device for coating film color determination are always provided at the work site, or coating film color determination is performed in outdoor direct sunlight. Is the current situation.
Japanese Patent Laid-Open No. 10-40703 JP 2001-259511 A Utility Model Registration No. 3085776

本発明の目的は、塗膜を光硬化することができ、且つ形成された塗膜の色調判定をすることが可能な、光硬化/色調判定兼用の光照射装置及びこれを用いた補修塗装方法及びその使用を提供することにある。   An object of the present invention is to provide a light curing device for photocuring / color tone determination, and a repair coating method using the same, capable of photocuring the coating film and determining the color tone of the formed coating film. And providing its use.

本発明者らは上記した問題点を解決するにあたって鋭意研究を行った結果、特定の範囲の相関色温度と光強度を有する光線を照射するランプを具備する光照射装置が、フィルター装着の有無により、光硬化用と塗膜色調評価用への切り替えが可能なことを見出し、本発明の完成に至った。
即ち本発明は
1.相関色温度が5000K以下である光線を放射するランプを具備する照射器と、該照射器の光照射方向前面に配置される装脱着可能なフィルターとを具備し、ランプから放射される光線が、365nmの波長において照射距離20cmにおける光強度が1〜5mW/cm2の範囲内であって、且つ800nmの波長において照射距離10cmにおける
光強度が、80〜250mW/cm2の範囲内であることを特徴とする光照射装置、
2.ランプが、発光物質が内部に封入されたセラミック製の発光管と、当該発光管を覆う外管とからなる2重管型ランプであって、該外管は、180nmの光線において50%以上の透過率、220nmの光において80%以上の透過率、300nmの光において90%以上の透過率を有する熔融石英ガラスからなることを特徴とする1項に記載の光照射装置、
3.損傷部に、光硬化型組成物を塗布し、該塗膜面に1項または2項に記載の光照射装置を用いて光線を照射することにより該光硬化型組成物を硬化せしめることを特徴とする補修塗装方法、
4.損傷部に、光硬化型組成物を塗布し、該塗膜面に1項または2項に記載の光照射装置を用いて光線を照射することにより該光硬化型組成物を硬化せしめた後、次いで、該塗面上に上塗り塗料を塗布・乾燥して上塗り塗膜を形成し、該上塗り塗膜面に、1項または2項に記載の光照射装置を用い、フィルターを介して光線を照射することにより該上塗り塗膜の色調を判定することを特徴とする補修塗装方法、
5.上塗り塗膜が、その成分の一部として光輝性を有する顔料を含有する4項に記載の補修塗装方法、および
6.1項または2項に記載の光照射装置を、光硬化型組成物の硬化と、塗膜色調判定の両方法に兼用する該光照射装置の使用、
に関する。
As a result of diligent research to solve the above-described problems, the present inventors have determined that a light irradiation apparatus including a lamp that emits a light beam having a specific range of correlated color temperature and light intensity depends on whether or not a filter is mounted. The present inventors have found that switching between photocuring and coating color tone evaluation is possible, and the present invention has been completed.
That is, the present invention provides: An irradiator including a lamp that emits a light beam having a correlated color temperature of 5000 K or less, and a detachable filter disposed in front of the irradiator in a light irradiation direction, and the light beam emitted from the lamp is The light intensity at an irradiation distance of 20 cm at a wavelength of 365 nm is in the range of 1 to 5 mW / cm 2 , and the light intensity at an irradiation distance of 10 cm at a wavelength of 800 nm is in the range of 80 to 250 mW / cm 2. Light irradiation device,
2. The lamp is a double-tube type lamp composed of a ceramic arc tube in which a luminescent material is enclosed and an outer tube covering the arc tube, and the outer tube is 50% or more in a light beam of 180 nm. 2. The light irradiation device according to item 1, comprising a fused silica glass having a transmittance of 80% or more for light at 220 nm and a transmittance of 90% or more for light at 300 nm.
3. The photocurable composition is applied to the damaged part, and the photocurable composition is cured by irradiating the coating film surface with light using the light irradiation device described in Item 1 or 2. Repair painting method,
4). After applying the photocurable composition to the damaged part and irradiating the coating film surface with light using the light irradiation device according to item 1 or 2, the photocurable composition is cured. Next, a top coat is applied and dried on the coated surface to form a top coated film, and the surface of the top coated film is irradiated with light through a filter using the light irradiation device described in item 1 or 2. A repair coating method characterized by determining the color tone of the top coat film by
5. The repair coating method according to item 4, wherein the top coat film contains a pigment having glitter as a part of the component, and the light irradiation device according to item 6.1 or 2, the photocurable composition Use of the light irradiation device for both curing and coating color tone determination,
About.

本発明の光照射装置は、短時間の光照射により光硬化型組成物を十分硬化することでき、しかもフィルター装着により単なる色味の判定だけでなく、従来から判定が困難であった光輝性顔料を含む光輝性顔料の配向性や緻密感、フリップフロップ性等も容易に視認することができる。本発明の光照射装置を例えば自動車等の補修塗装用途に適用すると、補修塗装部と見本カードとを対比する比色作業をより正確に行うことができるので、最終的に得られる補修塗膜を、正常部と同等の色調とすることが容易となる。このように光硬化と塗膜色調判定の双方に適用することができるので、作業現場にはこの光照射装置を備えることによって、塗膜の硬化と色調判定の両方を行うことができるという利点を有する。   The light irradiation apparatus of the present invention is capable of sufficiently curing a photocurable composition by light irradiation for a short time, and is not only a simple color determination but also a bright pigment that has been difficult to determine conventionally by mounting a filter. The orientation, denseness, flip-flop properties, etc. of the glitter pigment containing can be easily visually confirmed. When the light irradiation device of the present invention is applied to a repair coating application such as an automobile, the colorimetric work for comparing the repair coating portion and the sample card can be performed more accurately. It becomes easy to obtain a color tone equivalent to that of the normal part. Since it can be applied to both photocuring and coating color tone determination in this way, by providing this light irradiation device at the work site, it is possible to perform both curing of the coating film and color tone determination. Have.

本発明の光照射装置は、光硬化/塗膜色調判定兼用であり、放射光の相関色温度が5000K以下、好ましくは3000〜4900Kであるランプを具備する照射器と、該照射器の光照射方向に装脱着可能なフィルターを具備しており、該照射器には反射板及びレンズを備えていることが望ましい。ここで「装脱着」とは、「装着及び脱着」を意味している。   The light irradiation apparatus of the present invention is used for both photocuring / coating color tone determination, and an irradiator including a lamp having a correlated color temperature of radiated light of 5000 K or less, preferably 3000 to 4900 K, and light irradiation of the irradiator It is desirable to provide a filter that can be attached and detached in the direction, and the irradiator preferably includes a reflector and a lens. Here, “mounting / removing” means “mounting and demounting”.

本発明において、塗膜の色調とは、塗料やインク、化粧品などによって形成される塗膜外観の仕上がり性全般を意味しており、色味の他に、ツヤ感、透明度、顔料の配向性、顔料の緻密感、フリップフロップ性(キラキラ感)、真珠光沢感、漆黒性等を含む、主に目視で確認することのできるものである。
色温度とは、一般に放射される光線の色度を表す一種の指標であり、一般に色温度が高い光線ほど青く、色温度が低い光線ほど赤くなる傾向がある。色温度は、黒体とよばれる理想体の温度(K)で表される。光線の色が色度図上において、色温度と色の軌跡である黒体軌跡上にない場合、該光線の色温度は相関色温度として近似的に表すことができる。すなわち相関色温度とは、光線の色が黒体軌跡上にない場合、完全に一致しないが最も近似の黒体の温度である。本発明においては、相関色温度が5000Kを超える光線では、塗膜色調評価において、例えば光輝性顔料を含有する塗膜のメタリック感や、パール感(真珠光沢感)といった特有の発色をとらえることができない場合があるので好ましくない。
In the present invention, the color tone of the coating film means the overall finish of the appearance of the coating film formed by paints, inks, cosmetics, etc., in addition to the color, gloss, transparency, orientation of the pigment, It can be confirmed mainly by visual observation, including the denseness of the pigment, flip-flop properties (glittering), pearly luster, jetness and the like.
The color temperature is a kind of index that generally represents the chromaticity of the emitted light. Generally, the light having a higher color temperature tends to be blue, and the light having a lower color temperature tends to be red. The color temperature is expressed by the temperature (K) of an ideal body called a black body. When the color of the light beam is not on the black body locus which is the color locus and the color locus on the chromaticity diagram, the color temperature of the light beam can be approximately expressed as a correlated color temperature. That is, the correlated color temperature is the temperature of the closest black body that does not match completely when the color of the light ray is not on the black body locus. In the present invention, when the correlated color temperature exceeds 5000K, in the coating color tone evaluation, for example, a unique color development such as a metallic feeling or a pearly feeling (pearly luster feeling) of the coating film containing the glitter pigment can be captured. Since it may not be possible, it is not preferable.

尚、本発明における相関色温度は、光照射装置の電源を投入してから例えば3分程度経過して、放射される光線の色温度が実質的に一定になったときに色温度測定器で測定した値としている。
また、放射される光線としては、光硬化型組成物を硬化せしめるために、該組成物に含有される光重合開始剤の光吸収波長領域にある程度の光量があることが望ましく、例えば365nmの波長において照射距離20cmにおける光強度が、1〜5mW/cm2、好
ましくは2〜4mW/cm2の範囲内であって、且つ800nmの波長において、照射距
離10cmにおける光強度が80〜250mW/cm2、好ましくは100〜200mW
/cm2の範囲内であることが望ましい。
The correlated color temperature in the present invention is determined by the color temperature measuring device when the color temperature of the emitted light becomes substantially constant after, for example, about 3 minutes since the light irradiation device is turned on. The measured value.
Further, the emitted light beam preferably has a certain amount of light in the light absorption wavelength region of the photopolymerization initiator contained in the composition in order to cure the photocurable composition, for example, a wavelength of 365 nm The light intensity at an irradiation distance of 20 cm is 1 to 5 mW / cm 2 , preferably 2 to 4 mW / cm 2 , and at a wavelength of 800 nm, the light intensity at an irradiation distance of 10 cm is 80 to 250 mW / cm 2. , Preferably 100-200mW
/ Cm 2 is desirable.

また、放射される光線の照度が、2000〜5000lx、好ましくは2500〜4500lxの範囲内であることが望ましい。
上記光強度は、放射される光線の中心を上記所定距離にて光量計で測定したものである。波長365nmの光強度の測定に使用した光量計としては、例えば「UNIMETER
UIT−150 TYPE UIT−150A」(商品名、ウシオ電機社製)が挙げられ、波長800nmの光強度の測定に使用した光量計としては、例えば「MODEL I400A」(商品名、INTERNATIONAL LIGHT INC.社製)を挙げることができる。また、照度とは、放射される光線の中心を照射距離が1mにて「MINOLTA T−10」(商品名、ミノルタ社製、照度計)で測定した値である。
Further, the illuminance of the emitted light is desirably in the range of 2000 to 5000 lx, preferably 2500 to 4500 lx.
The light intensity is obtained by measuring the center of the emitted light with a light meter at the predetermined distance. As a light meter used for measuring the light intensity with a wavelength of 365 nm, for example, “UNIMETER”
UIT-150 TYPE UIT-150A "(trade name, manufactured by Ushio Denki Co., Ltd.), and as a light meter used for measuring the light intensity at a wavelength of 800 nm, for example," MODEL I400A "(trade name, INTERNATIONAL LIGHT INC. Manufactured). The illuminance is a value obtained by measuring the center of the emitted light with “MINOLTA T-10” (trade name, manufactured by Minolta, Inc., illuminometer) at an irradiation distance of 1 m.

上記色温度及び光強度の光線を照射するための照射器に具備されるランプとしては、従来公知のものが制限なく使用でき、例えばメタルハライドランプ、セラミックメタルハライドランプ、ハロゲンランプ、キセノンランプ、クリプトンランプ、蛍光灯、半導体レ−ザ−、発光ダイオ−ドなどが挙げられ、このうち発光管の材質がセラミックであるセラミックメタルハライドランプが好適である。   As a lamp provided in an irradiator for irradiating a light beam having the above color temperature and light intensity, a conventionally known lamp can be used without limitation, such as a metal halide lamp, a ceramic metal halide lamp, a halogen lamp, a xenon lamp, a krypton lamp, Examples include fluorescent lamps, semiconductor lasers, and light emitting diodes. Among these, ceramic metal halide lamps in which the arc tube is made of ceramic are suitable.

本発明の光照射装置に好適なセラミックメタルハライドランプとしては、例えば、発光物質が封入された発光管を覆うように外管が被さった2重管構造を有する構造であることが望ましく、発光管と外管との間の空間には、窒素ガスが封入され密封されているランプが好適である。
このようにセラミックメタルハライドランプが2重管構造であり、発光管としてセラミックを用いることにより、発光管内の発光物質が外部に抜け出ることを防止でき、長時間点灯してもランプから放射される光線の相関色温度の変化が起こらないようにすることができるからであり、さらに発光管に外管を被せることにより、発光管の保温性を向上させ、点灯中、発光管内の発光ガスの温度を一定に保持出来、点灯中にランプから放射される光線の相関色温度の変化が起こらないようにすることができるので好適である。
As a ceramic metal halide lamp suitable for the light irradiation apparatus of the present invention, for example, it is desirable to have a structure having a double tube structure in which an outer tube is covered so as to cover a luminous tube in which a luminescent material is sealed. A lamp in which nitrogen gas is sealed and sealed is suitable for the space between the outer tube and the outer tube.
In this way, the ceramic metal halide lamp has a double tube structure, and by using ceramic as the arc tube, the luminescent material in the arc tube can be prevented from escaping to the outside. This is because the correlated color temperature can be prevented from changing, and the arc tube is covered with an outer tube, thereby improving the heat retention of the arc tube and keeping the temperature of the luminescent gas in the arc tube constant during lighting. It is preferable that the correlated color temperature of the light emitted from the lamp does not change during lighting.

この結果、光硬化用及び塗膜色調判定に適した、相関色温度、365nmの紫外線の光強度、800nmの赤外線の光強度の3つの条件を満足する発光物質を決定することができるという効果がある。
上記セラミックメタルハライドランプにおいて、発光管から放射された紫外線を良好に透過するための外管の材質としては、熔融石英ガラスを挙げることができる。該熔融石英ガラスとしては、365nm以下の紫外線を良好に透過する材質であることが望ましい。具体的には、180nmの光線において、50%〜70%、好ましくは50〜60%の透過率、220nmの光において80〜90%、好ましくは80〜85%の透過率、300nmの光線において90%以上、好ましくは90〜95%の透過率を有する特性の熔融石英ガラスであることが望ましい。このような特性の熔融石英ガラス製の外管を用いることにより、光硬化型組成物を硬化させることができ、光輝性塗膜の比色作業であっても色調判定を容易に行うことが可能となる。
As a result, it is possible to determine a luminescent material that satisfies the three conditions of correlated color temperature, 365 nm ultraviolet light intensity, and 800 nm infrared light intensity, which are suitable for photocuring and coating color tone determination. is there.
In the ceramic metal halide lamp, a fused quartz glass can be used as a material for the outer tube for satisfactorily transmitting the ultraviolet rays emitted from the arc tube. The fused silica glass is preferably made of a material that transmits ultraviolet light having a wavelength of 365 nm or less. Specifically, it has a transmittance of 50% to 70%, preferably 50 to 60% for 180 nm light, 80 to 90% for 220 nm light, preferably 80 to 85%, and 90% for 300 nm light. % Or more, preferably 90 to 95% of the characteristic fused silica glass. By using an outer tube made of fused silica glass with such characteristics, the photocurable composition can be cured, and color tone judgment can be easily performed even in the colorimetric work of a glittering coating film. It becomes.

本明細書において、熔融石英ガラスに対する光線の透過率は、分光測定方法を用いて算出する。あらかじめ分光分布がわかっている標準光源を使い、その光源から放射された光を熔融石英ガラスに照射して、該ガラスを透過した光線の分光分布を測定する。次いでガラスを透過した光線の分光分布を、標準光源の分光分布と比較することにより光線の透過率として算出する。   In this specification, the light transmittance with respect to fused silica glass is calculated using a spectroscopic measurement method. Using a standard light source whose spectral distribution is known in advance, the fused silica glass is irradiated with light emitted from the light source, and the spectral distribution of the light transmitted through the glass is measured. Next, the spectral distribution of the light transmitted through the glass is calculated as the light transmittance by comparing with the spectral distribution of the standard light source.

発光物質としては具体的には、例えば、紫外線を主に放射する発光物質である水銀と、赤外線を主に放射する発光物質であるナトリウムを選択することができる。また、発光物質にディスプロシウム、セリウムを加えてもよい。これにより演色性のよい光を放射することができ、塗膜の色調を正確に判定することができる。
本発明の光照射装置において照射器の光照射方向レンズ前面等に装脱着するフィルターとしては、例えば通常のガラス原料に微量の鉄、ニッケル、コバルト、セレン等の金属を加え着色した熱線吸収板ガラス、フロート板ガラスの表面に反射率の高い金属酸化物の膜をコーティングした熱線反射板ガラス、表面に研磨剤である砂を圧縮エアーによってガラス表面に吹きつけたフロスト加工ガラス等が使用できる。
Specifically, for example, mercury, which is a luminescent substance that mainly emits ultraviolet rays, and sodium, which is a luminescent substance that mainly emits infrared rays, can be selected as the luminescent substance. Further, dysprosium and cerium may be added to the light-emitting substance. Thereby, light with good color rendering properties can be emitted, and the color tone of the coating film can be accurately determined.
In the light irradiation device of the present invention, as a filter that is attached to and detached from the front surface of the light irradiation direction lens of the irradiator, for example, a heat-absorbing plate glass colored by adding a trace amount of metal such as iron, nickel, cobalt, selenium, etc. A heat ray reflecting plate glass in which a metal oxide film having a high reflectance is coated on the surface of the float plate glass, frosted glass in which sand as an abrasive is blown onto the glass surface with compressed air, and the like can be used.

本発明においては、上記フィルターを具備した光照射装置により照射される光線の散乱を抑制し、被照射物に対する照度を均一化することができ、塗膜の色調をより正確に評価することが可能である。
本発明においては、フィルターを介した状態における光線の照度が100〜3000lx、好ましくは1500〜2500lxの範囲内であることが望ましい。
In the present invention, it is possible to suppress the scattering of the light irradiated by the light irradiation device equipped with the filter, to make the illuminance to the irradiated object uniform, and to more accurately evaluate the color tone of the coating film. It is.
In the present invention, it is desirable that the illuminance of the light ray through the filter is in the range of 100 to 3000 lx, preferably 1500 to 2500 lx.

上記照射器は、単独で使用してもよいし複数個適宜配置せしめて使用してもよい。また、支持支柱に装着されたものであってもよいし、手で持って操作するものであってもよい。支持支柱は伸縮自在であることが望ましく、また底部に移動用のホイールを取り付けたものであってもよい。
本発明方法は、被塗面に、光硬化型組成物を塗布し、該塗膜面に上記光照射装置を用いて光線を照射することにより該光硬化型組成物を硬化せしめる補修塗装方法である。
The above irradiators may be used alone, or a plurality of the irradiators may be appropriately arranged and used. Further, it may be one that is mounted on a support column or one that is held and operated by hand. It is desirable that the support column is telescopic, and a support wheel may be attached to the bottom.
The method of the present invention is a repair coating method in which a photocurable composition is applied to a surface to be coated, and the photocurable composition is cured by irradiating the coating film surface with light using the light irradiation device. is there.

光硬化型組成物としては、光線の照射により活性化される光重合開始剤及び光重合性樹脂組成物を含有するものであれば、従来公知の光硬化型パテ組成物や光硬化型プライマー組成物等が制限なく使用できる。
被塗面としては、特に制限はなく、例えば金属面、プラスチック面、無機基材面等の基材及び該基材上に形成された塗膜面が挙げられる。
As the photocurable composition, any conventional photocurable putty composition or photocurable primer composition may be used as long as it contains a photopolymerization initiator activated by irradiation of light and a photopolymerizable resin composition. Things can be used without restriction.
There is no restriction | limiting in particular as a to-be-coated surface, For example, the coating-film surface formed on base materials, such as a metal surface, a plastic surface, an inorganic base material surface, and this base material is mentioned.

本発明においては、上記光照射装置を光硬化に使用する際においては、上記フィルターを脱着した状態であることが望ましいが、必要に応じてフィルターを装着してもよい。また、上記照射条件は、光硬化型組成物の種類や、膜厚等に応じて適宜調整できるが、例えば、ランプから塗膜までの照射距離としては、一般に50cm以下、好ましくは10〜30cmの範囲内であり、照射時間としては、60〜180秒、好ましくは100〜150
秒の範囲が好適である。
In the present invention, when the light irradiation device is used for photocuring, it is desirable that the filter is in a detached state, but a filter may be attached if necessary. Moreover, although the said irradiation conditions can be suitably adjusted according to the kind of photocurable composition, a film thickness, etc., as an irradiation distance from a lamp | ramp to a coating film, for example, generally 50 cm or less, Preferably it is 10-30 cm. The irradiation time is in the range of 60 to 180 seconds, preferably 100 to 150.
A range of seconds is preferred.

また、本発明方法は、損傷部に、光硬化型組成物を塗布し、該塗膜面に上記光照射装置を用いて光線を照射することにより該光硬化型組成物を硬化せしめた後、次いで、該塗面上に上塗り塗料を塗布し、該上塗り塗膜面に、上記光照射装置を用いてフィルターを介して相関色温度が5000K以下の光線を照射することにより該上塗り塗膜の色調を判定する補修塗装方法である。   In addition, the method of the present invention is to apply a photocurable composition to the damaged part and to cure the photocurable composition by irradiating the coating film surface with light using the light irradiation device. Next, a top coating is applied on the coated surface, and the color of the top coated film is irradiated on the surface of the top coated film by irradiating light having a correlated color temperature of 5000 K or less through a filter using the light irradiation device. This is a repair coating method for judging

上記光照射装置による光線の存在下で、上塗り塗膜面の色調を判定する方法としては、目視による方法、色見本と塗膜面とを比色する方法、測定器等を使用する方法等が挙げられる。ランプから上塗り塗膜面までの照射距離は、10cm以上、好ましくは30〜200cm程度であることが望ましく、塗膜の種類等に応じて適宜調整できる。
本発明方法が適用される上塗り塗膜面としては、特に制限はないが、上塗り塗装に通常用いられるメタリック塗料、パール塗料、ソリッドカラー塗料等のエナメル塗料;クリヤー塗料等による塗膜面を挙げることができる。また、これら上塗り塗料から選ばれる2種以上の塗料による複層塗膜も包含することができる。上塗り塗料の塗布及び乾燥方法は、従来公知の方法が使用でき、特に制限はない。
As a method for judging the color tone of the top coat film surface in the presence of light rays by the light irradiation device, there are a method by visual observation, a method for color-coordinating the color sample and the paint film surface, a method using a measuring instrument, etc. Can be mentioned. The irradiation distance from the lamp to the top coat film surface is desirably 10 cm or more, and preferably about 30 to 200 cm, and can be appropriately adjusted according to the type of the film.
The top coat film surface to which the method of the present invention is applied is not particularly limited, but enamel paints such as metallic paints, pearl paints and solid color paints usually used for top coat painting; Can do. Moreover, the multilayer coating film by 2 or more types of coating materials chosen from these top coating materials can also be included. Conventionally known methods can be used for applying and drying the top coat, and there is no particular limitation.

本発明方法においては、上記上塗り塗膜面がその成分の一部として光輝性顔料を含有する場合においても、その効果を十分に発揮することができる。光輝性顔料としては、アルミニウム顔料、酸化チタンや酸化鉄等の金属酸化物をマイカ粉の表面に薄くコーティングしてなる光輝性マイカ顔料、銅粉、金粉、真鍮粉等を挙げることができる。
本発明の光照射装置は、光硬化型組成物を硬化することができ、且つ上記した上塗り塗膜等の色調判定にも使用できるので各用途に使用できるが、特に光硬化型組成物と上塗り塗料を用いた補修用途、例えば自動車車体に設けられた塗膜等の補修用途に好適に適用される。
In the method of the present invention, even when the top coat surface contains a glitter pigment as a part of the component, the effect can be sufficiently exhibited. Examples of the glitter pigment include aluminum pigment, glitter mica pigment obtained by thinly coating the surface of mica powder with metal oxide such as titanium oxide and iron oxide, copper powder, gold powder, brass powder and the like.
The light irradiation device of the present invention can be used for each application because it can cure the photocurable composition and can also be used for color tone determination of the above-mentioned top coat film, etc. The present invention is suitably applied to repair applications using paint, for example, repair applications such as a coating film provided on an automobile body.

以下、実施例を挙げて本発明を詳細に説明する。
実施例1
図1は本発明の光照射装置側面を示す概略図である。
図2は本発明の光照射装置に具備されるランプを示す概略図である。
図1において光照射装置1は、ランプ2、ミラー3及びレンズ4を備えた照射器5が、可動式の支持支柱6に昇降自在に装着された構造をしている。ランプ2は、相関色温度が4300Kであり、365nmの波長において照射距離20cmにおける光強度が3mW/cm2程度であり、さらに800nmの波長において、照射距離10cmにおける光強
度が、150mW/cm2程度である光線を放射するセラミックメタルハライドランプで
ある。両面フロスト加工されたガラス製のフィルター7はレンズ4前面に取り付けられ、着脱可能となっており、照射器5からの発光面をカバーするように設置可能である。
Hereinafter, the present invention will be described in detail with reference to examples.
Example 1
FIG. 1 is a schematic view showing a side surface of the light irradiation apparatus of the present invention.
FIG. 2 is a schematic view showing a lamp provided in the light irradiation apparatus of the present invention.
1, the light irradiation device 1 has a structure in which an irradiator 5 having a lamp 2, a mirror 3 and a lens 4 is mounted on a movable support column 6 so as to be movable up and down. Lamp 2 is a correlated color temperature 4300K, the light intensity in the irradiation distance 20cm in 365nm wavelength is about 3 mW / cm 2, still at a wavelength of 800 nm, the light intensity in the irradiation distance 10cm is, 150 mW / cm 2 of about This is a ceramic metal halide lamp that emits a light beam. The glass filter 7 subjected to double-side frosting is attached to the front surface of the lens 4 and is detachable, and can be installed so as to cover the light emitting surface from the irradiator 5.

図2においてランプ2は、発光管21を覆うように外管22が被さった2重管構造をしている。発光管21はセラミック製であり、この発光管21内に、所定の発光物質である水銀やナトリウム等が封入され、当該発光管21に続く両端には封止管が形成されている。
外管22は、180nmの光線において55%の透過率、220nmの光において83%の透過率、300nmの光において93%の透過率である熔融石英ガラス製であり、発光管21を覆うように形成され、外管22の一端部においてシール部23が形成されて、外管22内に発光管21が密閉状態で配置されている。また、外管22と発光管21の間の空間は窒素が充填されている。
In FIG. 2, the lamp 2 has a double tube structure in which an outer tube 22 is covered so as to cover the arc tube 21. The arc tube 21 is made of ceramic, and a predetermined luminescent substance such as mercury or sodium is enclosed in the arc tube 21, and sealing tubes are formed at both ends following the arc tube 21.
The outer tube 22 is made of fused silica glass having 55% transmittance for 180 nm light, 83% transmittance for 220 nm light, and 93% transmittance for 300 nm light, and covers the arc tube 21. The sealing portion 23 is formed at one end of the outer tube 22, and the arc tube 21 is disposed in a sealed state in the outer tube 22. Further, the space between the outer tube 22 and the arc tube 21 is filled with nitrogen.

発光管22に続く封止管からは、外部に突出する外部リード棒が外管22内の内部リード24に接続されている。
さらに、外管22のシール部23には、接着剤によって、セラミック製のベース25が固着され、当該ベース25には内部リード24に電気的に接続された給電ピン26が設けられている。
From the sealing tube that follows the arc tube 22, an external lead rod that protrudes to the outside is connected to the internal lead 24 in the outer tube 22.
Further, a ceramic base 25 is fixed to the seal portion 23 of the outer tube 22 by an adhesive, and a power supply pin 26 electrically connected to the internal lead 24 is provided on the base 25.

塗装及び色調判定評価
実施例2
実施例1に記載の光照射装置1を用いて「オプトラック」(関西ペイント社製、光硬化型パテ)が1mm厚となるように塗布された鋼板に光照射を行い、光照射装置1による硬化性を評価した。
Example 2 of coating and color tone evaluation
The light irradiation apparatus 1 described in Example 1 was used to irradiate the steel sheet coated with “OPTRAC” (manufactured by Kansai Paint Co., Ltd., photocurable putty) to a thickness of 1 mm. The curability was evaluated.

次いで光照射装置1を用いて光硬化せしめた塗板を3枚準備し、シルバーメタリック(注1)、3コートパール(注2)青ソリッド(注3)の各上塗り塗膜を夫々形成せしめ、塗膜色調判定用の試験塗板を夫々作成した。次いで各試験塗板について、各塗色に対応する色見本を各試験塗板近傍に配置させ、照射距離100cmにて各試験塗板及びそれに対応する各色見本を同時にフィルターを装着した状態の光照射装置1で光照射せしめ、該塗膜の色調について評価した。   Next, three sheets of light-cured coating plates were prepared using the light irradiation device 1, and each of the top coating films of silver metallic (Note 1), 3 coat pearl (Note 2) and blue solid (Note 3) was formed. Test coating plates for color tone judgment were prepared. Next, for each test coating plate, a color sample corresponding to each coating color is arranged in the vicinity of each test coating plate, and each test coating plate and each color sample corresponding to the test coating plate are simultaneously mounted with a filter at an irradiation distance of 100 cm. The film was irradiated with light, and the color tone of the coating film was evaluated.

実施例3〜4及び比較例1〜2
実施例2において、光硬化及び塗膜色調判定における光照射条件を表1に記載の通りとする以外は実施例2と同様にして、各試験塗板を作成し、硬化性並びに該試験塗板の色調を判定した。結果を表1に併せて示す。表1中の光強度は、フィルター装なしの条件で測定した値である。
Examples 3-4 and Comparative Examples 1-2
In Example 2, each test coating plate was prepared in the same manner as in Example 2 except that the light irradiation conditions in the photocuring and coating color tone determination were as shown in Table 1, and the curability and the color tone of the test coating plate were prepared. Was judged. The results are also shown in Table 1. The light intensity in Table 1 is a value measured under the condition of no filter.

Figure 2005028360
Figure 2005028360

(注1)シルバーメタリック:シルバーメタリック塗膜(「レタンPGハイブリッドIII メタリックホワイト」、関西ペイント社製、商品名、アルミニウム顔料含有塗料によ
る塗膜)とクリヤー塗膜(「レタンPGマルチクリヤーHx(Q)ベース」(商品名、関西ペイント社製)100重量部、「レタンPGマルチクリヤーHxスタンダード硬化剤」(商品名、関西ペイント社製)50重量部及び「PGハイブリッドシンナー20」(商品名、関西ペイント社製)20重量部を使用直前に混合したクリヤー塗料による塗膜)を順
次形成してなる複層塗膜。
(注2)3コートパール:着色ベース塗膜(「レタンPGハイブリッド ホワイト」、商品名、関西ペイント社製、白系顔料含有塗料による塗膜)、パール塗膜(「レタンPG217Lパールリキッドホワイト」、商品名、関西ペイント社製、マイカ顔料含有塗料による塗膜)、クリヤー塗膜(「レタンPGマルチクリヤーHx(Q)ベース」(商品名、関西ペイント社製)100重量部、「レタンPGマルチクリヤーHxスタンダード硬化剤」(商品名、関西ペイント社製)50重量部及び「PGハイブリッドシンナー20」(商品名、関西ペイント社製)20重量部を使用直前に混合したクリヤー塗料による塗膜)を順次形成してなる複層塗膜。
(Note 1) Silver metallic: Silver metallic coating ("Letane PG Hybrid III metallic white", manufactured by Kansai Paint Co., Ltd., trade name, coating with paint containing aluminum pigment) and clear coating ("Letane PG Multi Clear Hx (Q) base) "(Trade name, manufactured by Kansai Paint Co., Ltd.) 100 parts by weight," Letane PG Multiclear Hx Standard Curing Agent "(trade name, manufactured by Kansai Paint Co., Ltd.) 50 parts by weight and" PG Hybrid Thinner 20 "(trade name, Kansai Paint Co., Ltd.) (Manufactured) A multilayer coating film in which 20 parts by weight of a clear coating film mixed immediately before use is sequentially formed.
(Note 2) 3-Coated Pearl: Colored base coating (“Letane PG Hybrid White”, trade name, manufactured by Kansai Paint Co., Ltd., coating with white pigment-containing paint), Pearl coating (“Letane PG217L Pearl Liquid White”, product Name, manufactured by Kansai Paint Co., Ltd., paint film with mica pigment-containing paint), clear coating film ("Letan PG Multi Clear Hx (Q) Base" (trade name, manufactured by Kansai Paint Co., Ltd.) 100 parts by weight, "Letan PG Multi Clear Hx""Standard curing agent" (trade name, manufactured by Kansai Paint Co., Ltd.) 50 parts by weight and "PG Hybrid Thinner 20" (trade name, manufactured by Kansai Paint Co., Ltd.) 20 parts by weight are sequentially formed. A multilayer coating film.

(注3)青ソリッド:青系着色ベース塗膜(「レタンPGハイブリッドG38ディープブルー」、商品名、関西ペイント社製、青系顔料含有塗料による塗膜)、クリヤー塗膜(「レタンPGマルチクリヤーHx(Q)ベース」(商品名、関西ペイント社製)100重量部、「レタンPGマルチクリヤーHxスタンダード硬化剤」(商品名、関西ペイント社製)50重量部及び「PGハイブリッドシンナー20」(商品名、関西ペイント社製)20重量部を使用直前に混合したクリヤー塗料による塗膜)を順次形成してなる複層塗膜。
評価項目
(*1)硬化性:光硬化性組成物の硬化性を指触で調べた。
(Note 3) Blue solid: Blue-based colored base coating (“Letane PG Hybrid G38 Deep Blue”, trade name, manufactured by Kansai Paint Co., Ltd., coating with blue pigment-containing paint), Clear coating (“Letane PG Multi-Clear” 100 parts by weight of “Hx (Q) base” (trade name, manufactured by Kansai Paint), 50 parts by weight of “Letane PG Multiclear Hx Standard Curing Agent” (trade name, manufactured by Kansai Paint) and “PG Hybrid Thinner 20” (product) (Name, manufactured by Kansai Paint Co., Ltd.) A multilayer coating film formed by sequentially forming a coating film (clear coating mixed with 20 parts by weight immediately before use).
Evaluation item (* 1) Curability: The curability of the photocurable composition was examined by touch.

◎:非常に良好、○:良好、×:硬化不良
(*2)アルミ配向性:シルバーメタリックの色見本として「ABI II」(商品名、色見本、関西ペイント社製)の塗色番号トヨタ199を使用し、アルミ顔料の大きさや向きについて上記シルバーメタリックの試験塗板と該色見本とを目視で対比した。
◎:アルミ顔料の大きさや向きについて、試験塗板と色見本とで違いが非常にわかりやすく、目視評価が非常にしやすい、○:アルミ顔料の大きさや向きについて、試験塗板と色見本とで違いがわかりやすく目視評価がしやすい、○△:アルミ顔料の大きさや向きについて、試験塗板と色見本とで違いを確認することができ、目視評価可能である、△:アルミ顔料の大きさや向きについて、塗板と色見本とで違いがわかりにくく、目視評価が若干しづらい。×:アルミ顔料の大きさや向きについて、塗板と色見本とで違いが目視評価によりできない。
◎: Very good, ○: Good, ×: Poor curing (* 2) Aluminum orientation: “ABI II” (trade name, color sample, manufactured by Kansai Paint Co., Ltd.) The above-mentioned silver metallic test coating plate and the color sample were visually compared with respect to the size and direction of the aluminum pigment.
◎: About the size and orientation of the aluminum pigment, the difference between the test coating plate and the color sample is very easy to understand, and visual evaluation is very easy. ○: About the size and direction of the aluminum pigment, there is a difference between the test coating plate and the color sample. Easy to understand and easy to visually evaluate. ○ △: The size and orientation of the aluminum pigment can be confirmed by the difference between the test coating plate and the color sample, and visual evaluation is possible. △: About the size and orientation of the aluminum pigment. The difference between the coated plate and the color sample is difficult to understand, and the visual evaluation is slightly difficult. X: Regarding the size and orientation of the aluminum pigment, a difference between the coated plate and the color sample cannot be visually evaluated.

(*3)パール感:3コートパールの見本として「ABI II」(商品名、色見本、関西ペイント社製)の塗色番号トヨタ051を使用し、パール顔料の大きさや光照射方向の変化による色味の変化について、3コートパールの試験塗板と該色見本とを目視で対比した。
◎:パール顔料の大きさや光照射方向の変化による色味の変化について、試験塗板と色見本とで違いが非常にわかりやすく、目視評価が非常にしやすい、○:パール顔料の大きさや光照射方向の変化による色味の変化について、試験塗板と色見本とで違いがわかりやすく、目視評価がしやすい、○△:パール顔料の大きさや光照射方向の変化による色味の変化について、試験塗板と色見本とで違いが確認でき、目視評価が可能である、△:パール顔料の大きさや光照射方向の変化による色味の変化について、試験塗板と色見本とで違いがわかりづらく、目視評価が若干しにくい、×:パール顔料の大きさや光照射方向の変化による色味の変化について、試験塗板と色見本とで違いが目視評価によりできない。
(* 3) Pearl feeling: Using paint color number Toyota051 of “ABI II” (trade name, color sample, manufactured by Kansai Paint Co., Ltd.) as a sample of 3-coat pearl, depending on the size of pearl pigment and changes in light irradiation direction Regarding the change in color, the test coat plate of 3 coat pearl and the color sample were compared visually.
A: The change in color due to the change in the size of the pearl pigment and the direction of light irradiation is very easy to see the difference between the test coating plate and the color sample, and the visual evaluation is very easy. ○: The size of the pearl pigment and the direction of light irradiation Regarding the change in color due to the change in color, the difference between the test coating plate and the color sample is easy to understand and easy to visually evaluate. ○ △: About the change in color due to the change in the size of the pearl pigment and the direction of light irradiation Differences can be confirmed with the color swatches, and visual evaluation is possible. △: Regarding the change in color due to changes in the size of the pearl pigment and the direction of light irradiation, it is difficult to see the difference between the test coating plate and the color swatches. Slightly difficult, x: Regarding the change in color due to the change in the size of the pearl pigment and the light irradiation direction, the difference between the test coating plate and the color sample cannot be determined by visual evaluation.

(*4)透明性:青ソリッド色の見本として「ABI II」(商品名、色見本、関西ペイント社製)の塗色番号トヨタ082を使用し、透明性について、青ソリッド色の試験塗板と該色見本とを目視で対比した。
◎:透明性について、試験塗板と色見本とで違いが非常にわかりやすく、目視評価が非常にしやすい。○:透明性について、試験塗板と色見本とで違いがわかりやすく、目視評価がしやすい、△:透明性について、試験塗板と色見本とで違いが若干わかりにくく、目
視評価がしづらい、×:透明性について、試験塗板と色見本とで違いが目視評価によりできない。
(* 4) Transparency: Blue solid color sample “ABI II” (trade name, color sample, manufactured by Kansai Paint Co., Ltd.) is used as paint color number Toyota 082. The color sample was visually compared.
A: Regarding transparency, the difference between the test coated plate and the color sample is very easy to understand, and visual evaluation is very easy. ○: Regarding transparency, the difference between the test coating plate and the color sample is easy to understand, and visual evaluation is easy. Δ: Regarding transparency, the difference between the test coating plate and the color sample is slightly difficult to understand, and visual evaluation is difficult. × : Regarding the transparency, a difference between the test coating plate and the color sample cannot be made by visual evaluation.

例えば自動車補修塗装など、光硬化型組成物と上塗り塗料を共に使用するような補修塗装用途に適用できる。   For example, the present invention can be applied to repair coating applications that use both a photocurable composition and a top coating, such as automotive repair coating.

図1は、本発明の光照射装置の構成を説明する概略図である。FIG. 1 is a schematic diagram illustrating the configuration of the light irradiation apparatus of the present invention. 図2は、本発明の光照射装置のランプの構成を説明する概略図である。FIG. 2 is a schematic diagram illustrating the configuration of the lamp of the light irradiation apparatus of the present invention.

符号の説明Explanation of symbols

1 光照射装置
2 ランプ
21 発光管
22 外管
23 シール部
24 リード
25 ベース
26 給電ピン
3 ミラー
4 レンズ
5 照射器
6 支持支柱
7 フィルター
DESCRIPTION OF SYMBOLS 1 Light irradiation apparatus 2 Lamp 21 Light emission tube 22 Outer tube 23 Seal part 24 Lead 25 Base 26 Feeding pin 3 Mirror 4 Lens 5 Irradiator 6 Supporting support 7 Filter

Claims (6)

相関色温度が5000K以下である光線を放射するランプを具備する照射器と、該照射器の光照射方向前面に配置される装脱着可能なフィルターとを具備し、ランプから放射される光線が、365nmの波長において照射距離20cmにおける光強度が1〜5mW/cm2の範囲内であって、且つ800nmの波長において照射距離10cmにおける光強
度が、80〜250mW/cm2の範囲内であることを特徴とする光照射装置。
An irradiator including a lamp that emits a light beam having a correlated color temperature of 5000 K or less, and a detachable filter disposed in front of the irradiator in a light irradiation direction, and the light beam emitted from the lamp is The light intensity at an irradiation distance of 20 cm at a wavelength of 365 nm is in the range of 1 to 5 mW / cm 2 , and the light intensity at an irradiation distance of 10 cm at a wavelength of 800 nm is in the range of 80 to 250 mW / cm 2. A light irradiation device characterized.
ランプが、発光物質が内部に封入されたセラミック製の発光管と、当該発光管を覆う外管とからなる2重管型ランプであって、該外管は、180nmの光線において50%以上の透過率、220nmの光において80%以上の透過率、300nmの光において90%以上の透過率を有する熔融石英ガラスからなることを特徴とする請求項1に記載の光照射装置。   The lamp is a double-tube type lamp composed of a ceramic arc tube in which a luminescent material is enclosed and an outer tube covering the arc tube, and the outer tube is 50% or more in a light beam of 180 nm. The light irradiation device according to claim 1, wherein the light irradiation device is made of fused silica glass having a transmittance of 80% or more for light of 220 nm and a transmittance of 90% or more for light of 300 nm. 損傷部に、光硬化型組成物を塗布し、該塗膜面に請求項1または2に記載の光照射装置を用いて光線を照射することにより該光硬化型組成物を硬化せしめることを特徴とする補修塗装方法。   A photocurable composition is applied to the damaged part, and the photocurable composition is cured by irradiating the coating film surface with light using the light irradiation device according to claim 1. Repair painting method. 損傷部に、光硬化型組成物を塗布し、該塗膜面に請求項1または2に記載の光照射装置を用いて光線を照射することにより該光硬化型組成物を硬化せしめた後、次いで、該塗面上に上塗り塗料を塗布・乾燥して上塗り塗膜を形成し、該上塗り塗膜面に、請求項1または2に記載の光照射装置を用い、フィルターを介して光線を照射することにより該上塗り塗膜の色調を判定することを特徴とする補修塗装方法。   After applying the photocurable composition to the damaged part and irradiating the coating film surface with light using the light irradiation device according to claim 1 or 2, the photocurable composition is cured. Next, a top coat is applied to the coated surface and dried to form a top coated film, and the surface of the top coated film is irradiated with light using a light irradiation device according to claim 1 or 2. A repair coating method characterized by determining the color tone of the top coat film. 上塗り塗膜が、その成分の一部として光輝性を有する顔料を含有する請求項4に記載の補修塗装方法。   The repair coating method according to claim 4, wherein the top coat film contains a pigment having glitter as part of its components. 請求項1または2に記載の光照射装置を、光硬化型組成物の硬化と、塗膜色調判定の両方法に兼用する該光照射装置の使用。   Use of this light irradiation apparatus which uses the light irradiation apparatus of Claim 1 or 2 for both methods of hardening of a photocurable composition, and a coating-film color tone determination.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010501984A (en) * 2006-08-24 2010-01-21 ゼネラル・エレクトリック・カンパニイ High color large pearlite with improved efficiency and longevity
JP2016043343A (en) * 2014-08-26 2016-04-04 株式会社アペックス Automobile coating method and coating dedicated construction booth

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51126134A (en) * 1975-04-25 1976-11-04 Kometsuto Kk Illumination device for photography
JPS61156237A (en) * 1984-12-28 1986-07-15 Fuji Photo Film Co Ltd Lighting device for photographing
JPH0680212U (en) * 1993-04-23 1994-11-08 株式会社モルテン Lighting equipment

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51126134A (en) * 1975-04-25 1976-11-04 Kometsuto Kk Illumination device for photography
JPS61156237A (en) * 1984-12-28 1986-07-15 Fuji Photo Film Co Ltd Lighting device for photographing
JPH0680212U (en) * 1993-04-23 1994-11-08 株式会社モルテン Lighting equipment

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010501984A (en) * 2006-08-24 2010-01-21 ゼネラル・エレクトリック・カンパニイ High color large pearlite with improved efficiency and longevity
JP2016043343A (en) * 2014-08-26 2016-04-04 株式会社アペックス Automobile coating method and coating dedicated construction booth

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