JP2005023449A - Arm cover-attached glove and method for making the same - Google Patents

Arm cover-attached glove and method for making the same Download PDF

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JP2005023449A
JP2005023449A JP2003187604A JP2003187604A JP2005023449A JP 2005023449 A JP2005023449 A JP 2005023449A JP 2003187604 A JP2003187604 A JP 2003187604A JP 2003187604 A JP2003187604 A JP 2003187604A JP 2005023449 A JP2005023449 A JP 2005023449A
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Japan
Prior art keywords
arm cover
glove
adhesive
layer
rubber layer
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JP2003187604A
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JP4334928B2 (en
Inventor
Soichiro Taira
総一郎 平
Kojiro Kuwabara
孝二郎 桑原
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Atom Corp
Atom Medical Corp
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Atom Corp
Atom Medical Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide an arm cover-attached glove obtained by firmly bonding a glove body having a rubber layer to a synthetic resin arm cover part. <P>SOLUTION: The arm cover-attached glove is obtained by the following process: applying an adhesive on a rubber layer 5 of a hem opening part 3 prior to vulcanizing the rubber layer 5 of the glove body 2 to form an adhesive layer 11, wherein the adhesive comprises rubber latex containing no vulcanizing agent, or a mixture of the rubber latex with synthetic resin emulsion; vulcanizing the rubber layer 5 of the glove main body after applying the adhesive thereto; superposing a tip opening part 10 of a synthetic resin arm cover part 6 on the hem opening part 3 of the glove body 2 via the adhesive layer 11; and heating the superposed part so as to heating-weld the arm cover part 6 to the hem opening part 3 via the adhesive layer 11. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

【0001】
【発明の属する技術分野】
本発明は、作業用や家庭用に用いられる腕カバー付き手袋に関し、さらに詳しくは、ゴム層を有する手袋本体と合成樹脂製腕カバー部とを強力に接合した腕カバー付き手袋とその製造方法に関する。
【0002】
【発明の背景】
一般に、腕カバー付き手袋には、指先から手首までを被覆する手袋本体と、この手袋本体の裾口部に接続した腕カバー部とを備えるものがあり、この腕カバー付き手袋を着用することにより、手や腕を汚れや薬剤汚染、擦傷などの危険性から保護するとともに、防寒や防水効果が得られるようにして多種多様の業種に適用できるようにしてある。ここで、上記の手袋本体は、耐油性や耐摩耗性、機械的強度などが要求される等の理由から、少なくとも外面がアクリロニトリルブタジエンゴム(以下、NBRという。)などのゴム材料で形成され、一方、腕カバー部は柔軟性が要求される等の理由から、塩化ビニル樹脂などの合成樹脂材料で薄肉の筒状に形成されたものがある。
【0003】
【従来の技術】
従来、ゴム製手袋本体と合成樹脂製腕カバー部とを接合した腕カバー付き手袋としては、ホットメルトや未加硫ゴムを接合材として用い、この接合材を介して手袋本体の裾口部と腕カバー部の先端開口部とを重合させ、この重合部を溶着することにより接合したものがある(例えば、特許文献1参照。)。
【0004】
【特許文献1】
特開2002−285410号公報
【0005】
【発明が解決しようとする課題】
上記の従来技術にあっては、腕カバー部が重合され溶着される前に、手袋本体のゴム成分が十分に加硫されているため、手袋本体と腕カバー部との間に接合材を配置しても、十分に高い接着強度を得ることができない。このため、使用経過とともにこの接合部が早期に剥離しやすく、剥離部分から水や油などが手袋内に浸入する惧れがあった。
本発明はこれらの問題点を解消し、ゴム層を有する手袋本体と合成樹脂製腕カバー部とを強力に接合した腕カバー付き手袋とその製造方法を提供することを技術的課題とする。
【0006】
【課題を解決するための手段】
本発明は上記の課題を解決するため、例えば本発明の実施の形態を示す図1から図4に基づいて説明すると、次のように構成したものである。
即ち、本発明1は腕カバー付き手袋の製造方法に関し、ゴム層(5)を有する手袋本体(2)を製造する過程で、このゴム層(5)が十分に加硫される前に、この手袋本体(2)の裾口部(3)のゴム層(5)の表面へ接着剤を塗布して接着剤層(11)を形成し、上記の接着剤は加硫剤を含まないゴムラテックスを含有しており、上記のゴム層(5)を加硫したのち、上記の接着剤層(11)を介して上記の裾口部(3)に合成樹脂製腕カバー部(6)の先端開口部(10)を重ね合せ、この腕カバー部(6)を裾口部(3)に加熱溶着することを特徴とする。
【0007】
本発明2は腕カバー付き手袋に関し、ゴム層(5)を有する手袋本体(2)と、この手袋本体(2)の裾口部(3)に接着剤層(11)を介して接続される合成樹脂製腕カバー部(6)とを備え、上記の接着剤層(11)は、加硫剤を含まないゴムラテックスを使用してあり、上記の腕カバー部(6)は、この接着剤層(11)を介して上記の裾口部(3)のゴム層(3)に加熱溶着されていることを特徴とする。
【0008】
【作用】
加硫剤を含まないゴムラテックスを含有する接着剤は、手袋本体が十分に加硫する前にゴム層の表面に塗布されることから、このゴムラテックスを含有する接着剤は手袋本体のゴム層と十分に相溶すると考えられ、手袋本体が加硫されたのちも接着剤層はこの手袋本体に強力に接着している。一方、上記の接着剤層は加硫剤を含まないゴムラテックスを使用したので、手袋本体を加硫したのちも合成樹脂製腕カバーに強力に接着される。この結果、腕カバー部はこの接着剤層を介して手袋本体のゴム層に強力に接合される。
【0009】
上記の接着剤は、加硫剤を含まないゴムラテックスのみで構成してもよく、或いは、合成樹脂エマルジョンとの混合物で構成してもよい。この合成樹脂エマルジョンとの混合物の場合、その混合比率は、手袋本体や腕カバー部との接着力に基づき適宜設定されるが、50%以上含有させると好ましい。
【0010】
上記の接着剤層に混合される合成樹脂成分は、腕カバー部に熱溶着可能な材質であればよく、腕カバー部を構成する合成樹脂材料と種類が異なる合成樹脂材料であってもよい。しかしこれらを同種の合成樹脂材料にすると、一般に各種の物性が近似するうえ高い接着力を得ることができるので、より好ましい。また、接着剤に使用されるゴムラテックスも、同様の理由から手袋本体のゴム層と同種のものが好ましい。
【0011】
上記の手袋本体のゴム層は周知の方法で形成することができる。例えば上記の手袋本体が内面側に編物などからなる繊維層を備える場合、この繊維層をラテックスに浸漬して形成したり、あるいは繊維層にラテックスを塗布することで形成してもよい。例えば上記の手袋本体全体をゴム層で形成する場合は、立体手型の表面に凝固剤を塗布したのちラテックスに浸漬することで形成してもよい。
【0012】
上記の接着剤は、手袋本体のゴム層が未加硫の状態にある間に塗布されるが、このゴム層が流動状態にあると上記の接着剤層の形成が容易でない。そこで、この接着剤は、手袋本体の表面のゴム層の流動が止まり、その形状を保持できる程度の状態、即ち、保形可能な状態で塗布するのが好ましい。
【0013】
【発明の実施の形態】
以下、本発明の実施の形態を図面に基づき説明する。
図1と図2は本発明の第1実施形態を示し、図1(a)は腕カバー付き手袋の一部破断斜視図、図1(b)は図1(a)のB部の拡大断面図、図2は腕カバー付き手袋の製造過程の説明図である。
【0014】
図1(a)に示すように、この腕カバー付き手袋(1)は手袋本体(2)とこの手袋本体(2)の裾口部(3)に接続した腕カバー部(6)とからなる。
上記の手袋本体(2)はメリヤス編からなる繊維層(4)の外面にNBRのゴム層(5)を形成してある。一方、上記の腕カバー部(6)は、塩化ビニル樹脂製の薄いシートの側端縁を溶着や縫製するなどして円筒状に形成してある。この腕カバー部(6)の後端開口部(7)の周縁には、ずれ落ちを防止するための締付け部(8)が形成してあり、この締付け部(8)の近傍に空気抜き孔(9)が形成してある。
【0015】
図1(a)と図1(b)に示すように、上記の腕カバー部(6)は、先端開口部(10)が上記のゴム層(5)の表面に、接着剤層(11)を介して接合してある。
上記の接着剤層(11)は、加硫剤を含まない生のNBRラテックス単独の接着剤、又はこれと塩化ビニル樹脂エマルジョンとの混合物からなる接着剤を使用してあり、この接着剤層(11)を介して、上記の腕カバー部(6)が裾口部(3)のゴム層(5)の表面に加熱溶着してある。
【0016】
次に、上記の腕カバー付き手袋の製造手順について説明する。
最初に、上記の手袋本体(2)が通常の方法で製造される。即ち、図2に示すように、予め調製されたメリヤス手袋(12)が立体手型(13)に装着され、液状のNBRラテックス(14)に浸漬されて引き上げられたのち乾燥される。この浸漬と乾燥は必要に応じて繰り返され、これによりメリヤス手袋(12)の外面に所定厚さのゴム層(5)が形成される。
【0017】
上記のゴム層(5)が所定厚さに達すると、このゴム層(5)の加硫が完了する前に、図2に示すように手袋本体(2)の裾口部(3)の外周面に接着剤が塗布されて接着剤層(11)が形成される。この接着剤の塗布は、上記の乾燥によりゴム層(5)の表面の流動性がなくなった時点、即ち、乾燥等によりゴム層(5)がその形状を保持できる程度になった状態で速やかに行われる。
なお、手袋本体(2)の裾口部(3)のうち、接着剤層(11)よりも端部側部分は必要に応じて切断され除去される。
【0018】
上記の接着剤は、加硫剤を含まない生のNBRラテックス単独、或いは、この生のNBRラテックスと塩化ビニル樹脂エマルジョンとの混合物からなる。このNBRラテックスと塩化ビニル樹脂エマルジョンとの配合比率は、接着剤層(11)とゴム層(5)との接着強度や、接着剤層(11)と腕カバー部(6)との接着強度等に基づいて適宜設定されるが、一般に、NBRラテックスの含有量は多いほど接着力が高いので好ましく、通常、50%以上に設定される。
【0019】
上記の接着剤が塗布されたのち、上記の手袋本体(2)のゴム層(5)は十分に加硫され、手袋本体(2)が上記の立体手型(13)から取り外される。
次いで、この手袋本体(2)の裾口部(3)外面に、上記の腕カバー部の先端開口部が上記の接着剤層(11)を介して重ね合わされる。そして、この状態で上記の手袋本体(2)と腕カバー部とが、例えば高周波などにより加熱され、これにより、接着剤層(11)を介して腕カバー部が上記の裾口部(3)のゴム層(5)に確りと加熱溶着される。
【0020】
次に、上記の接着剤において、加硫剤を含まないNBRラテックスと塩化ビニル樹脂エマルジョンとの混合比率を変えたときの、手袋本体と腕カバー部との接着強度を測定した。即ち、加硫剤を含まないNBRラテックスを単独で用いた場合を実施例1とし、これと塩化ビニル樹脂エマルジョンとを2:1の比率で混合した場合を実施例2とし、1:1の比率で混合した場合を実施例3とした。なお、比較例1として、塩化ビニル樹脂エマルジョン単独の接着剤を用いた場合の接着強度を測定し、比較例2として、加硫済みの手袋本体に未加硫ゴムからなる接着剤を使用して腕カバー部を接着した場合の接着強度を測定した。これらの測定結果を表1に示す。
【0021】
【表1】

Figure 2005023449
【0022】
一般に、上記の接着強度は10N/cm以上が好ましいが、上記の測定結果から明らかなように、実施例1、2、3ではいずれも十分な接着強度が得られた。また、加硫剤を含まないゴムラテックスを多く含むほど接着力が高くなる傾向があり、50%以上含有させると、塩化ビニル樹脂エマルジョン単独の接着剤を使用した比較例1の場合はもとより、加硫後の手袋本体に未加硫ゴムを用いて接着する比較例2の場合よりも強力に、手袋本体のゴム層と腕カバー部とを接着することができた。
【0023】
図3と図4は本発明の第2実施形態を示し、図3(a)は腕カバー付き手袋の一部破断斜視図、図3(b)は図3(a)のC部の拡大断面図、図4は腕カバー付き手袋の製造過程の説明図である。
【0024】
図3(a)に示すように、この第2実施形態では腕カバー付き手袋(1)の手袋本体(2)全体がゴム層(5)で形成されており、この手袋本体(2)の裾口部(3)の内周面に腕カバー部(6)が接続してある。即ち、図3(b)に示すように、上記の裾口部(3)の内周面には、加硫剤を含まない生のNBRラテックスを単独で使用した、又はこれと塩化ビニル樹脂エマルジョンとの混合物を使用した接着剤層(11)が形成してあり、この接着剤層(11)を介して腕カバー部(6)の先端開口部(10)が上記の裾口部(3)内面のゴム層(5)に接合してある。
その他の構成は上記の第1実施形態と同様であるので、説明を省略する。
【0025】
次に、上記の腕カバー付き手袋の製造手順について説明する。
図4に示すように、表面に凝固剤を塗布した立体手型(13)が、液状のNBRラテックス(14)に浸漬されて引き上げられ、乾燥されて立体手型(13)の表面に手袋本体(2)を構成するゴム層(5)が形成される。そして上記の乾燥によりこのゴム層(5)の表面の流動性がなくなると、十分に加硫される前に、速やかに接着剤が裾口部(3)に塗布され、接着剤層(11)が形成される。上記の接着剤は、上記の第1実施形態と同様、加硫剤を含まない生のNBRラテックス単独、又はこれと塩化ビニル樹脂エマルジョンの混合液からなる。
【0026】
次に、上記の接着剤が塗布されたのち、加熱により手袋本体(2)のゴム層(5)が加硫され、立体手型(13)から手袋本体(2)の内外を反転するようにして取り外される。その後、上記の接着剤層(11)を介して腕カバー部の先端開口部が上記の手袋本体(2)の裾口部(3)に重合され、この重合部を加熱することで、接着剤層(11)を介して、腕カバー部の先端開口部が上記の裾口部(3)に加熱溶着される。
【0027】
上記の実施形態では、上記の腕カバー部として予め筒状に形成したものを用いたが、手袋本体との接合時はシート状のものを丸めておき、接合したのち端縁を溶着や縫製などで筒状に形成してもよい。
【0028】
上記の実施形態ではゴム層や接着剤のゴム成分として、耐油性に優れたNBRを用いたが、本発明では他のゴム材料を用いてもよい。また、上記の腕カバー部や接着剤の合成樹脂成分として塩化ビニル樹脂を用いたが、他の合成樹脂材料であってもよい。さらに、上記の腕カバー部は補強用繊維などを組み合わせたものであってもよい。
【0029】
【効果】
本発明は上記のように構成され作用することから、次の効果を奏する。
加硫剤を含まないゴムラテックスを含有する接着剤は、手袋本体の未加硫状態のゴム層に塗布されるので、手袋本体が加硫されたのちも接着剤層をこの手袋本体に強力に接着でき、また、この接着剤層は加硫剤を含まないゴムラテックスを使用したので、合成樹脂製腕カバーにも強力に接着できる。この結果、この接着剤層を介して腕カバー部を手袋本体のゴム層に強力に接合することができ、接合部が容易に剥離しない優れた耐久性を有する腕カバー付き手袋にすることができる。
しかも、上記の接着剤層は、手袋本体を製造する過程で、この手袋本体のゴム層が十分に加硫される前に、この手袋本体の裾口部のゴム層の表面へ、加硫剤を含まないゴムラテックスまたはこれと合成樹脂エマルジョンとの混合物からなる接着剤を塗布するだけでよく、簡単かつ安価に実施することができる。
【図面の簡単な説明】
【図1】本発明の第1実施形態を示し、図1(a)は腕カバー付き手袋の一部破断斜視図、図1(b)は図1(a)のB部の拡大断面図である。
【図2】本発明の第1実施形態の、腕カバー付き手袋の製造過程の説明図である。
【図3】本発明の第2実施形態を示し、図3(a)は腕カバー付き手袋の一部破断斜視図、図3(b)は図3(a)のC部の拡大断面図である。
【図4】本発明の第2実施形態の、腕カバー付き手袋の製造過程の説明図である。
【符号の説明】
1…腕カバー付き手袋
2…手袋本体
3…手袋本体(2)の裾口部
4…繊維層
5…ゴム層
6…腕カバー部
10…腕カバー部(6)の先端開口部
11…接着剤層[0001]
BACKGROUND OF THE INVENTION
More particularly, the present invention relates to a glove with an arm cover in which a glove body having a rubber layer and a synthetic resin arm cover part are strongly bonded to each other and a manufacturing method thereof. .
[0002]
BACKGROUND OF THE INVENTION
In general, some gloves with arm covers include a glove body that covers from the fingertips to the wrist and an arm cover part that is connected to the hem opening of the glove body. In addition to protecting hands and arms from dangers such as dirt, chemical contamination, and scratches, it can be applied to a wide variety of industries by providing cold protection and waterproofing effects. Here, the glove body is formed of a rubber material such as acrylonitrile butadiene rubber (hereinafter referred to as NBR) at least on the outer surface because oil resistance, wear resistance, mechanical strength, and the like are required. On the other hand, there are some arm cover portions formed of a synthetic resin material such as vinyl chloride resin in the shape of a thin tube because flexibility is required.
[0003]
[Prior art]
Conventionally, as a glove with an arm cover in which a rubber glove body and a synthetic resin arm cover are joined, hot melt or unvulcanized rubber is used as a joining material. There exists what joined by superposing | polymerizing with the front-end | tip opening part of an arm cover part, and welding this superposition | polymerization part (for example, refer patent document 1).
[0004]
[Patent Document 1]
Japanese Patent Laid-Open No. 2002-285410
[Problems to be solved by the invention]
In the above prior art, the rubber component of the glove body is sufficiently vulcanized before the arm cover part is polymerized and welded, so a bonding material is placed between the glove body and the arm cover part. Even so, a sufficiently high adhesive strength cannot be obtained. For this reason, this joining part is easy to peel off early with use progress, and there was a possibility that water, oil, etc. may infiltrate into a glove from a peeling part.
An object of the present invention is to solve these problems and to provide a glove with an arm cover in which a glove body having a rubber layer and a synthetic resin arm cover part are strongly joined and a method for manufacturing the glove.
[0006]
[Means for Solving the Problems]
In order to solve the above problems, the present invention is configured as follows, for example, based on FIGS. 1 to 4 showing an embodiment of the present invention.
That is, the present invention 1 relates to a method of manufacturing a glove with an arm cover, and in the process of manufacturing a glove body (2) having a rubber layer (5), before the rubber layer (5) is sufficiently vulcanized, An adhesive is applied to the surface of the rubber layer (5) of the hem portion (3) of the glove body (2) to form an adhesive layer (11), and the adhesive does not contain a vulcanizing agent. After the rubber layer (5) is vulcanized, the tip of the synthetic resin arm cover (6) is inserted into the hem (3) through the adhesive layer (11). The opening (10) is overlapped, and the arm cover (6) is heat-welded to the skirt (3).
[0007]
The present invention 2 relates to a glove with an arm cover, and is connected to a glove body (2) having a rubber layer (5) and a hem opening (3) of the glove body (2) through an adhesive layer (11). A synthetic resin arm cover (6), and the adhesive layer (11) is made of rubber latex containing no vulcanizing agent. The arm cover (6) is made of this adhesive. It is characterized by being heat-welded to the rubber layer (3) of the hem portion (3) through the layer (11).
[0008]
[Action]
Since the adhesive containing a rubber latex that does not contain a vulcanizing agent is applied to the surface of the rubber layer before the glove body is sufficiently vulcanized, the adhesive containing the rubber latex is applied to the rubber layer of the glove body. The adhesive layer is strongly bonded to the glove body after the glove body is vulcanized. On the other hand, since the above-mentioned adhesive layer uses a rubber latex containing no vulcanizing agent, it is strongly bonded to the synthetic resin arm cover after the glove body is vulcanized. As a result, the arm cover portion is strongly bonded to the rubber layer of the glove body through this adhesive layer.
[0009]
The above adhesive may be composed only of rubber latex containing no vulcanizing agent, or may be composed of a mixture with a synthetic resin emulsion. In the case of a mixture with this synthetic resin emulsion, the mixing ratio is appropriately set based on the adhesive strength with the glove body or arm cover part, but it is preferable to contain 50% or more.
[0010]
The synthetic resin component mixed in the adhesive layer may be any material that can be thermally welded to the arm cover portion, and may be a synthetic resin material that is different in type from the synthetic resin material constituting the arm cover portion. However, it is more preferable that these are made of the same kind of synthetic resin material because various physical properties are generally approximated and high adhesive strength can be obtained. Also, the rubber latex used for the adhesive is preferably the same type as the rubber layer of the glove body for the same reason.
[0011]
The rubber layer of the glove body can be formed by a known method. For example, when the glove body includes a fiber layer made of knitted fabric or the like on the inner surface side, the fiber layer may be formed by dipping in latex, or by applying latex to the fiber layer. For example, when the entire glove body is formed of a rubber layer, it may be formed by applying a coagulant to the surface of a three-dimensional hand mold and then immersing it in latex.
[0012]
The adhesive is applied while the rubber layer of the glove body is in an unvulcanized state. However, when the rubber layer is in a fluidized state, the formation of the adhesive layer is not easy. Therefore, this adhesive is preferably applied in such a state that the flow of the rubber layer on the surface of the glove body stops and the shape can be maintained, that is, the shape can be retained.
[0013]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, embodiments of the present invention will be described with reference to the drawings.
1 and 2 show a first embodiment of the present invention, FIG. 1 (a) is a partially broken perspective view of a glove with an arm cover, and FIG. 1 (b) is an enlarged cross-section of a portion B in FIG. 1 (a). FIG. 2 and FIG. 2 are explanatory diagrams of the manufacturing process of gloves with arm covers.
[0014]
As shown to Fig.1 (a), this glove (1) with an arm cover consists of a glove main body (2) and an arm cover part (6) connected to the hem opening part (3) of this glove main body (2). .
The glove body (2) has an NBR rubber layer (5) formed on the outer surface of a fiber layer (4) made of knitted fabric. On the other hand, the arm cover portion (6) is formed in a cylindrical shape by welding or sewing the side edge of a thin sheet made of vinyl chloride resin. On the periphery of the rear end opening (7) of the arm cover portion (6), a tightening portion (8) for preventing slippage is formed, and an air vent hole (in the vicinity of the tightening portion (8) ( 9) is formed.
[0015]
As shown in FIGS. 1 (a) and 1 (b), the arm cover (6) has a tip opening (10) on the surface of the rubber layer (5) and an adhesive layer (11). It is joined via.
The above-mentioned adhesive layer (11) uses an adhesive composed of a raw NBR latex alone containing no vulcanizing agent or a mixture of this and a vinyl chloride resin emulsion. 11) The arm cover portion (6) is heat-welded to the surface of the rubber layer (5) of the hem opening portion (3).
[0016]
Next, the manufacturing procedure of the glove with an arm cover will be described.
First, the glove body (2) is manufactured in the usual way. That is, as shown in FIG. 2, a knitted glove (12) prepared in advance is attached to a three-dimensional hand mold (13), dipped in a liquid NBR latex (14), pulled up, and then dried. This dipping and drying are repeated as necessary, whereby a rubber layer (5) having a predetermined thickness is formed on the outer surface of the knitted glove (12).
[0017]
When the rubber layer (5) reaches a predetermined thickness, before the vulcanization of the rubber layer (5) is completed, the outer periphery of the hem (3) of the glove body (2) as shown in FIG. An adhesive is applied to the surface to form an adhesive layer (11). The adhesive is applied immediately when the surface of the rubber layer (5) loses its fluidity due to the drying, that is, when the rubber layer (5) can maintain its shape by drying or the like. Done.
In addition, the edge part side part rather than an adhesive bond layer (11) is cut | disconnected and removed as needed among the hem opening | mouth parts (3) of a glove main body (2).
[0018]
The adhesive is made of raw NBR latex alone containing no vulcanizing agent or a mixture of this raw NBR latex and a vinyl chloride resin emulsion. The blending ratio of the NBR latex and the vinyl chloride resin emulsion includes the adhesive strength between the adhesive layer (11) and the rubber layer (5), the adhesive strength between the adhesive layer (11) and the arm cover portion (6), etc. In general, the larger the NBR latex content is, the higher the adhesive strength is, and it is generally preferable to set the NBR latex to 50% or more.
[0019]
After the adhesive is applied, the rubber layer (5) of the glove body (2) is sufficiently vulcanized, and the glove body (2) is removed from the three-dimensional hand mold (13).
Next, the tip opening of the arm cover part is overlapped with the outer surface of the hem part (3) of the glove body (2) via the adhesive layer (11). Then, in this state, the glove body (2) and the arm cover part are heated by, for example, high frequency, and the arm cover part is heated by the adhesive layer (11) so that the hem opening part (3). The rubber layer (5) is securely heat-welded.
[0020]
Next, the adhesive strength between the glove body and the arm cover part was measured when the mixing ratio of the NBR latex not containing a vulcanizing agent and the vinyl chloride resin emulsion was changed. That is, when NBR latex containing no vulcanizing agent is used alone, Example 1 is used, and when this is mixed with a vinyl chloride resin emulsion at a ratio of 2: 1, Example 2 is used. The case of mixing in Example 3 was designated as Example 3. In addition, as Comparative Example 1, the adhesive strength in the case of using an adhesive of a vinyl chloride resin emulsion alone was measured, and as Comparative Example 2, an adhesive made of unvulcanized rubber was used on a vulcanized glove body. The adhesion strength when the arm cover part was adhered was measured. These measurement results are shown in Table 1.
[0021]
[Table 1]
Figure 2005023449
[0022]
In general, the above adhesive strength is preferably 10 N / cm or more. However, as is apparent from the above measurement results, in Examples 1, 2, and 3, sufficient adhesive strength was obtained. Also, the more rubber latex that does not contain a vulcanizing agent, the more the adhesive strength tends to increase. When 50% or more is contained, not only in the case of Comparative Example 1 using an adhesive of vinyl chloride resin emulsion alone, The rubber layer of the glove body and the arm cover part could be bonded more strongly than in the case of Comparative Example 2 in which the glove body after vulcanization was bonded using unvulcanized rubber.
[0023]
3 and 4 show a second embodiment of the present invention, FIG. 3 (a) is a partially broken perspective view of a glove with an arm cover, and FIG. 3 (b) is an enlarged cross-section of a portion C in FIG. 3 (a). FIG. 4 and FIG. 4 are explanatory diagrams of the manufacturing process of the glove with arm cover.
[0024]
As shown to Fig.3 (a), in this 2nd Embodiment, the glove main body (2) whole of the glove (1) with an arm cover is formed with the rubber layer (5), and the skirt of this glove main body (2) The arm cover part (6) is connected to the inner peripheral surface of the mouth part (3). That is, as shown in FIG. 3 (b), raw NBR latex that does not contain a vulcanizing agent is used alone on the inner peripheral surface of the hem (3), or this and a vinyl chloride resin emulsion. The adhesive layer (11) using the mixture is formed, and the tip opening (10) of the arm cover part (6) is formed through the adhesive layer (11) through the hem opening (3). Bonded to the rubber layer (5) on the inner surface.
Since other configurations are the same as those of the first embodiment, description thereof is omitted.
[0025]
Next, the manufacturing procedure of the glove with an arm cover will be described.
As shown in FIG. 4, the three-dimensional hand mold (13) having a surface coated with a coagulant is dipped in a liquid NBR latex (14), pulled up, dried, and dried on the surface of the three-dimensional hand mold (13). A rubber layer (5) constituting (2) is formed. Then, when the fluidity of the surface of the rubber layer (5) is lost due to the drying described above, the adhesive is quickly applied to the skirt (3) before being sufficiently vulcanized, and the adhesive layer (11). Is formed. The adhesive is made of raw NBR latex containing no vulcanizing agent alone or a mixture of this and a vinyl chloride resin emulsion, as in the first embodiment.
[0026]
Next, after the adhesive is applied, the rubber layer (5) of the glove body (2) is vulcanized by heating, and the inside and outside of the glove body (2) are reversed from the three-dimensional hand mold (13). Removed. Thereafter, the tip opening of the arm cover part is polymerized on the hem opening part (3) of the glove body (2) through the adhesive layer (11), and the adhesive part is heated by heating the superposed part. Through the layer (11), the tip opening of the arm cover is heat-welded to the hem opening (3).
[0027]
In the above embodiment, the above-mentioned arm cover portion is formed in a cylindrical shape in advance. However, when joining with the glove body, a sheet-like one is rounded, and after joining, the edge is welded or sewn, etc. It may be formed in a cylindrical shape.
[0028]
In the above embodiment, NBR having excellent oil resistance is used as the rubber component of the rubber layer and the adhesive, but other rubber materials may be used in the present invention. Moreover, although the vinyl chloride resin was used as the synthetic resin component of the arm cover part and the adhesive, other synthetic resin materials may be used. Further, the arm cover portion may be a combination of reinforcing fibers and the like.
[0029]
【effect】
Since the present invention is configured and operates as described above, the following effects can be obtained.
Since the adhesive containing rubber latex without vulcanizing agent is applied to the unvulcanized rubber layer of the glove body, the adhesive layer is strongly applied to the glove body after the glove body is vulcanized. It can be bonded, and this adhesive layer uses a rubber latex that does not contain a vulcanizing agent, so it can be strongly bonded to a synthetic resin arm cover. As a result, the arm cover portion can be strongly bonded to the rubber layer of the glove body through this adhesive layer, and the glove with an arm cover having excellent durability that the bonded portion does not easily peel can be obtained. .
Moreover, the adhesive layer is formed on the surface of the rubber layer at the bottom of the glove body before the rubber layer of the glove body is sufficiently vulcanized in the process of manufacturing the glove body. It is only necessary to apply an adhesive made of a rubber latex not containing bismuth or a mixture of this and a synthetic resin emulsion, which can be carried out easily and inexpensively.
[Brief description of the drawings]
FIG. 1 shows a first embodiment of the present invention, FIG. 1 (a) is a partially broken perspective view of a glove with an arm cover, and FIG. 1 (b) is an enlarged cross-sectional view of part B of FIG. 1 (a). is there.
FIG. 2 is an explanatory diagram of a manufacturing process of the glove with an arm cover according to the first embodiment of the present invention.
3A and 3B show a second embodiment of the present invention, in which FIG. 3A is a partially broken perspective view of a glove with an arm cover, and FIG. 3B is an enlarged cross-sectional view of a portion C in FIG. is there.
FIG. 4 is an explanatory diagram of a manufacturing process of a glove with an arm cover according to a second embodiment of the present invention.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 ... Glove with an arm cover 2 ... Glove main body 3 ... The hem opening part 4 of a glove main body (2) ... Fiber layer 5 ... Rubber layer 6 ... Arm cover part 10 ... End opening part 11 of an arm cover part (6) ... Adhesive layer

Claims (7)

ゴム層(5)を有する手袋本体(2)を製造する過程で、このゴム層(5)が未加硫状態の時に、この手袋本体(2)の裾口部(3)のゴム層(5)の表面へ接着剤を塗布して接着剤層(11)を形成し、
上記の接着剤は、加硫剤を含まないゴムラテックスを含有しており、
上記のゴム層(5)を加硫したのち、上記の接着剤層(11)を介して上記の裾口部(3)に合成樹脂製腕カバー部(6)の先端開口部(10)を重ね合せ、この腕カバー部(6)を裾口部(3)に加熱溶着することを特徴とする、腕カバー付き手袋の製造方法。
In the process of manufacturing the glove body (2) having the rubber layer (5), when the rubber layer (5) is in an unvulcanized state, the rubber layer (5) of the hem (3) of the glove body (2) ) To form the adhesive layer (11)
The above adhesive contains a rubber latex that does not contain a vulcanizing agent,
After the rubber layer (5) is vulcanized, the tip opening (10) of the synthetic resin arm cover (6) is inserted into the hem opening (3) through the adhesive layer (11). A method for manufacturing a glove with an arm cover, wherein the arm cover part (6) is heat-welded to the hem opening part (3).
上記の接着剤が、加硫剤を含まないゴムラテックスと合成樹脂エマルジョンとの混合物からなる、請求項1に記載の腕カバー付き手袋の製造方法。The method for producing a glove with an arm cover according to claim 1, wherein the adhesive is made of a mixture of a rubber latex not containing a vulcanizing agent and a synthetic resin emulsion. 上記の接着剤を、上記のゴム層(5)が保形可能な状態にまで乾燥したのち塗布する、請求項1または2に記載の、腕カバー付き手袋の製造方法。The method for producing a glove with an arm cover according to claim 1 or 2, wherein the adhesive is applied after the rubber layer (5) is dried to a shape-retaining state. ゴム層(5)を有する手袋本体(2)と、この手袋本体(2)の裾口部(3)に接着剤層(11)を介して接続される合成樹脂製腕カバー部(6)とを備え、
上記の接着剤層(11)は、加硫剤を含まないゴムラテックスを使用してあり、
上記の腕カバー部(6)は、この接着剤層(11)を介して上記の裾口部(3)のゴム層(3)に加熱溶着されていることを特徴とする、腕カバー付き手袋。
A glove body (2) having a rubber layer (5), and a synthetic resin arm cover (6) connected to the hem opening (3) of the glove body (2) via an adhesive layer (11); With
The adhesive layer (11) uses a rubber latex that does not contain a vulcanizing agent,
The arm cover part (6) is heated and welded to the rubber layer (3) of the hem part (3) through the adhesive layer (11), and the glove with an arm cover is provided. .
上記の接着剤層(11)は、加硫剤を含まないゴムラテックスと合成樹脂エマルジョンとの混合物を使用してある、請求項4に記載の腕カバー付き手袋。The glove with an arm cover according to claim 4, wherein the adhesive layer (11) uses a mixture of a rubber latex not containing a vulcanizing agent and a synthetic resin emulsion. 上記の手袋本体(2)は内面側に繊維層(4)を備え、上記のゴム層(5)はこの繊維層(4)の外面側に形成され、上記の腕カバー部(6)は上記の裾口部(3)の外周面に接続してある、請求項4又は5に記載の腕カバー付き手袋。The glove body (2) includes a fiber layer (4) on the inner surface side, the rubber layer (5) is formed on the outer surface side of the fiber layer (4), and the arm cover portion (6) The glove with an arm cover of Claim 4 or 5 connected to the outer peripheral surface of the hem opening | mouth part (3). 上記の手袋本体(2)は全体がゴム層(5)で形成され、上記の腕カバー部(6)は、上記の裾口部(3)の内周面に接続してある、請求項4又は5に記載の腕カバー付き手袋。The glove body (2) is entirely formed of a rubber layer (5), and the arm cover portion (6) is connected to the inner peripheral surface of the hem port portion (3). Or the glove with an arm cover of 5.
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008534794A (en) * 2005-03-22 2008-08-28 リージェント・メディカル・リミテッド Gloves with cuffs for slip-off prevention
JP3185316U (en) * 2013-05-31 2013-08-08 三重化学工業株式会社 Work gloves
JP2014134350A (en) * 2013-01-11 2014-07-24 Edwards Kk Inlet nozzle and detoxification device
JP2014185415A (en) * 2013-03-25 2014-10-02 Tetsuo Nishimura Work glove connected with special arm cover
KR101782846B1 (en) 2016-03-24 2017-09-28 노현일 The improved durability of rubber gloves
JP2021070896A (en) * 2019-11-01 2021-05-06 ショーワグローブ株式会社 Glove

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008534794A (en) * 2005-03-22 2008-08-28 リージェント・メディカル・リミテッド Gloves with cuffs for slip-off prevention
JP2014134350A (en) * 2013-01-11 2014-07-24 Edwards Kk Inlet nozzle and detoxification device
JP2014185415A (en) * 2013-03-25 2014-10-02 Tetsuo Nishimura Work glove connected with special arm cover
JP3185316U (en) * 2013-05-31 2013-08-08 三重化学工業株式会社 Work gloves
KR101782846B1 (en) 2016-03-24 2017-09-28 노현일 The improved durability of rubber gloves
JP2021070896A (en) * 2019-11-01 2021-05-06 ショーワグローブ株式会社 Glove
US11406146B2 (en) 2019-11-01 2022-08-09 Showa Glove Co. Glove
US11849787B2 (en) 2019-11-01 2023-12-26 Showa Glove Co. Glove

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