JP2004321863A - Original position cleaning apparatus for polluted soil - Google Patents

Original position cleaning apparatus for polluted soil Download PDF

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Publication number
JP2004321863A
JP2004321863A JP2003116546A JP2003116546A JP2004321863A JP 2004321863 A JP2004321863 A JP 2004321863A JP 2003116546 A JP2003116546 A JP 2003116546A JP 2003116546 A JP2003116546 A JP 2003116546A JP 2004321863 A JP2004321863 A JP 2004321863A
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JP
Japan
Prior art keywords
water
injection
contaminated
well
pumping
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JP2003116546A
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Japanese (ja)
Inventor
Yasushi Terao
康 寺尾
Keiichi Kusakabe
啓一 日下部
Shigeyuki Mori
茂之 森
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Kubota Corp
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Kubota Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To shorten a cleaning period by accelerating the elution of the pollutant to injection water by mixing air into injection water to change the injection water into a turbulent flow to accelerate the removal of a pollutant. <P>SOLUTION: In this original position cleaning apparatus for polluted soil constituted so that water is injected in a polluted area 4 polluted with the pollutant from a water injection well 6 provided in the vicinity of the polluted area 4 through a screen 6B to pump up the injected water in a water pump-up well 7 through a screen 7B so as to allow the same to flow through the polluted area 4 and cleaning the ground water pumped up from the water pump-up well 7 in a water treatment system 8, a sterilizing agent mixer for mixing a sterilizing agent with the injected water is provided to prevent the propagation of microorganisms on the respective screens. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

【0001】
【発明の属する技術分野】
本発明は汚染土壌の原位置浄化装置に関し、より詳細には、浄化期間を短縮することを可能にした汚染土壌の原位置浄化装置に関する。
【0002】
【従来の技術】
廃棄物の不法投棄現場、埋立処分場、または廃棄物によって汚染された土壌や地下水汚染現場の浄化方法には、汚染土壌を掘削撤去して良質土により埋め戻す置換法と、例えば、汚染土壌の周囲に所要数の井戸を掘削して汚染された地下水をポンプで汲み上げ浄化する原位置浄化方法がある。置換法は、汚染域の深度が浅い場合には有効な手段となるが、汚染域の深度が深くなる(例えば深度が10m程度)と、掘削量が膨大になりコスト高となる。従って、汚染域の深度が深く、汚染域が帯水層にある場合には、上記のような原位置浄化方法が特に有効となるが、もちろん深度が浅い場合にも原位置浄化方法は適用できる。
【0003】
米国特許第4,435,292号(特許文献1)に示された原位置浄化方法は、注水井から高圧で注水し、揚水井から高い真空で汚染水を排出して、水処理システムで汚染物質を除去するようにしたものである。この従来技術は、処理水を循環使用することにより、注入する清浄水の使用量を削減するとともに、注入媒体として、溶媒、または窒素等の不活性ガス、または汚染物質を浄化する反応性ガスを使用することによって、浄化することができるようにしたものである。
【0004】
また、特公平6−96143号(特許文献2)に示された原位置浄化方法は、注水井及び揚水井からの注水と汲み上げを、間欠的に行う。これにより、注水及び汲み上げの停止期間中に地下水を静止させて、土壌粒子の小間隙中に滞留する汚染物質を、汚染物質の自重により移動させて、地下水流内に誘出させることにより、汚染物質の浄化を促進するようにしたものである。
【0005】
このような汚染土壌の原位置浄化方法または装置において、特許文献ではないが、図2に示すような原位置浄化装置がある。透水層1の地下水位2の下部に有る帯水層3には、廃棄物または汚染土壌からなる汚染域4が含まれている。透水層1の下部に有る難透水層(不透水層とも云う)5の標高を測定し、難透水層5の標高の高い側に所要数の注水井6を掘削して水を注入する。この注入水は標高の低い側に流れ、汚染域4を通過する際に、汚染域4から汚染物質を溶出する。難透水層5の標高の低い側に所要数の揚水井7を掘削し、汚染物質が溶出した汚染水をポンプ7Aで地上に汲み上げ、水処理システム8で汚染物質を除去し、汚染物質が除去された処理水を、再び注水井6に注入し循環している。注水井6および揚水井7には、汚染域4の深度に対応する深さ位置に、編目状のスクリーン6B、7Bが設けられている。スクリーン6Bは、注入水を汚染域4近傍の土壌中に吐出するとともに、土壌が注水井6に侵入しないようにしている。また、スクリーン7Bは、汚染水を揚水井7に吸入するとともに、土壌が揚水井7に侵入しないようにしている。汚染域4、注水井6および揚水井7を囲む汚染土壌の外周を、難透水層5に達する深度の止水壁9、9で包囲し、地表面を表面遮水工10で覆い、汚染物質の周囲への漏出、及び雨水等の土壌中への浸透を防止している。
【0006】
【特許文献1】
米国特許第4,435,292号明細書
【特許文献2】
特公平6−96143号明細書
【0007】
【発明が解決しようとする課題】
しかしながら、上記特許文献1、2及び図2に示す従来技術は、微生物が注水井及び揚水井のスクリーンに付着して繁殖し、スクリ−ンが目詰まりを起こすため、数ヶ月で注水ができなくなることがあった。そのため、注水井及び揚水井の増設工事が必要となって、増設工事期間中は浄化作業が行えず、結果として浄化期間が長くなる不具合があった。
【0008】
また、上記特許文献2に示す従来技術は、地下水の静止中に、土壌粒子の小間隙中に滞留する汚染物質を、汚染物質の自重により移動させるものであるため、地下水流内への汚染物質の誘出に時間がかかり、注水及び汲み上げの停止期間が長くなって、結果として浄化期間が長くなる不具合があった。また、汚染物質の自重による移動を利用するため、汚染物質の浄化にも限度があった。
【0009】
本発明は上記問題に鑑みてなされたもので、その目的は、注入水に滅菌剤を混入、またはスクリーンを滅菌性の部材にして、スクリ−ンに微生物が繁殖しないようにすることによって、スクリーンの目詰まりを防止し、浄化運転の停止期間を無くして、浄化期間を短縮することである。さらに、本発明の目的は、注入水に気体を混入して注入水を乱流にすることにより、汚染物質の上記注入水への溶出を促進させて、汚染物質の浄化を促進し、浄化期間を短縮することである。
【0010】
【課題を解決するための手段】
請求項1の発明は、汚染物質によって汚染された汚染域近傍にスクリーンを介して注水する注水井を設けるとともに、上記注水井からの注入水が汚染域を経由するようにスクリーンを介して揚水する揚水井を設け、上記揚水井から汲み上げた地下水を、水処理システムによって浄化する汚染土壌の原位置浄化装置において、上記注入水に滅菌剤を混入する滅菌剤混入装置を設け、上記各スクリ−ンに微生物が繁殖しないようにしたことを特徴とする汚染土壌の原位置浄化装置である。
【0011】
請求項2の発明は、汚染物質によって汚染された汚染域近傍にスクリーンを介して注水する注水井を設けるとともに、上記注水井からの注入水が汚染域を経由するようにスクリーンを介して揚水する揚水井を設け、上記揚水井から汲み上げた地下水を、水処理システムによって浄化する汚染土壌の原位置浄化装置において、上記各スクリーンを滅菌性の部材にして、上記スクリ−ンに微生物が繁殖しないようにしたことを特徴とする汚染土壌の原位置浄化装置である。
【0012】
請求項3の発明は、請求項1に記載した汚染土壌の原位置浄化装置において、上記滅菌剤として、次亜塩素酸ソーダ、塩素ガス、臭素ガスまたはオゾンガスのいずれかを用いることを特徴とする汚染土壌の原位置浄化装置である。
【0013】
請求項4の発明は、請求項2に記載した汚染土壌の原位置浄化装置において、上記滅菌性の部材として、銅または水不溶性の滅菌剤のコーティングを用いることを特徴とする汚染土壌の原位置浄化装置である。
【0014】
請求項5の発明は、汚染物質によって汚染された汚染域近傍に注水する注水井を設けるとともに、上記注水井からの注入水が汚染域を経由するように揚水井を設け、上記揚水井から汲み上げた地下水を、水処理システムによって浄化する汚染土壌の原位置浄化装置において、上記注入水に気体を混入して注入水を乱流にする気体混入装置を設け、上記汚染物質の上記注入水への溶出を促進させるようにしたことを特徴とする汚染土壌の原位置浄化装置である。
【0015】
請求項6の発明は、請求項1から4、及び5のいずれかに記載した汚染土壌の原位置浄化装置において、上記注入水の注入を間欠的に行う間欠注入装置及び地下水の汲み上げを間欠的に行う間欠汲上装置を設けたことを特徴とする汚染土壌の原位置浄化装置である。
【0016】
【発明の実施の形態】
以下、本発明の実施形態について、前記従来装置と同等部分については同一符号を付けて説明する。図1は、本発明の汚染土壌の原位置浄化装置の施工例を示す土壌の鉛直断面図である。
【0017】
透水層1の地下水位2の下部に有る帯水層3には、廃棄物または汚染土壌からなる汚染域4が含まれている。汚染域4は、地表から10m程度の深度に形成されている。透水層1は、透水係数が10 〜10 cm/秒程度の、比較的地下水の流速が早い砂質土からなる層である。透水層1の下部に有る難透水層
(不透水層とも云う)5の標高を測定し、難透水層5の標高の高い側に所要数の注水井6を掘削し、この注水井6に水を注入する。難透水層5は、透水係数が10− 6 〜10− 7cm/秒程度の、沖積粘土層又は洪積粘土層からなる層であ
る。難透水層5の標高の低い側に所要数の揚水井7を掘削し、汚染物質が溶出した汚染水を揚水井7を通してポンプで地上に汲み上げ、地上に設置した水処理システム8で、汚染水から汚染物質を除去する。
【0018】
注水井6、揚水井7には汚染域4の深度に対応する深さ位置に、編目状のスクリーン6B、7Bが設けられている。スクリーン6Bは、注入水を土壌中に吐出するとともに、土壌が注水井6に侵入しないようにしている。また、スクリーン7Bは、汚染水を揚水井7に吸入するとともに、土壌が揚水井7に侵入しないようにしている。汚染域4、注水井6、揚水井7を囲む汚染土壌の外周を、難透水層5に達する深度の止水壁9、9で包囲し、地表面を表面遮水工10で覆えば、汚染物質の周囲への漏出、及び雨水等の土壌中への浸透を防止できるので好ましい。
【0019】
スクリーン6B、7Bに微生物が付着して繁殖し、スクリーン6B、7Bが目詰まりするのを防止するために、注水井6では注入水に、次亜塩素酸ソーダ、塩素ガス、臭素ガスまたはオゾンガス等の滅菌剤を混入して注入する。注入水に滅菌剤を混入する方法は、従来の安価なスクリーンを使用できる上、微生物の種類に応じて滅菌剤を選択して使用でき、また微生物の繁殖の程度に応じて滅菌剤の混入量を調整できるので好ましい。また、スクリーン6B、7Bを滅菌性の部材にして、スクリーン6B、7Bに微生物が付着して繁殖するのを防止することができる。滅菌性の部材としては、スクリーン6B、7Bの材質を銅にする方法と、スクリーン6B、7Bを水不溶性の滅菌剤でコーティングする方法がある。スクリーン6B、7Bを滅菌性の部材にする方法は、ランニングコストがかからないので好ましい。このようにして、スクリーン6B、7Bに微生物が繁殖せず、スクリーンの目詰まりが無くなるので、注入井6または揚水井7の増設工事に伴う浄化運転の停止期間が無くなり、増設工事費を削減し、浄化期間を短縮することができる。スクリーンの目詰まりを防止する上記手法と、注水および汲み上げを間欠的に行う手法を併用することができる。その場合、注水および汲み上げに使用する電力等のエネルギーが削減できるので、ランニングコストを節約できる。
【0020】
注水井6への注入水の流量が小さいうちは、注入水の流量と浄化効率は比例関係になる。しかし、土壌粒子間の間隙水への汚染物質の溶出速度が律速となって、注入水の流量をある限度以上に大きくしても、浄化効率が頭打ちとなる。従って、注入水に空気等の気体を混入して注入水を乱流にする。高圧の気体を使用すれ
ば、注入水を乱流にする効果が大きくなるので好ましい。これにより、土壌粒子の間隙にあらゆる方向から注入水が流入し、汚染物質の注入水への溶出を促進させて、汚染物質の浄化を促進し、浄化期間を短縮することができる。注入水を乱流にする上記手法と、注水および汲み上げを間欠的に行う手法を併用することができる。その場合、注水および汲み上げに使用する電力等のエネルギーが削減できるので、ランニングコストを節約できる。
【0021】
注入時間、注入停止時間、および汲上時間、汲上停止時間は、実験的手法あるいはリアルタイム手法で決定することができる。実験的手法は、予め、揚水井7から汲み上げられる汚染水中の汚染物の濃度を測定し、最も汚染物の濃度が高くなる注入時間、注入停止時間、および汲上時間、汲上停止時間を求めることにより行う。リアルタイム手法は、揚水井7から汲み上げられる汚染水中の汚染物の濃度を常時測定し、汚染物の濃度が所定の基準値以下になったら、注水井6および揚水井7の運転を所定時間停止し、その後注水井6および揚水井7の運転を再開する。運転再開時の汚染水中の汚染物の濃度が所定の基準値以上であれば、そのまま運転を継続し、所定の基準値以下であれば注水井6および揚水井7の運転を所定時間停止する。
【0022】
なお、以上の実施態様では、注水井6および揚水井7の停止と再開は、同時に行っているが、注入水が汚染域4を経由して揚水井7に到達するまでのタイムラグを考慮して、揚水井7の停止と再開を注水井6の停止と再開よりも遅らせることにより、より効率的な運転を行うことができる。また、注水井6および揚水井7の両方を間欠的に運転することがエネルギー効率の点で好ましいが、平均的な注入流量と揚水流量がバランスすれば、注水井6または揚水井7の一方のみを間欠的に運転しても良い。
【0023】
注水井6から注水すると、この注入水は標高の低い側に流れ、汚染域4を通過する際に、汚染域4の廃棄物または土壌粒子に吸着した汚染物質が注入水に溶出し、この汚染物質が溶出した汚染水が、揚水井7から地上に汲み上げられる。水処理システム8で汚染物質が除去された処理水は、再び注水井6に注入し循環して使用する。この循環を継続することにより、汚染域4の浄化が進行する。処理水は放流し、注水井6から清浄水を注水しても良い。
【0024】
なお、以上の実施態様では、難透水層5の標高の高い側に注水井6を設置し、標高の低い側に揚水井7を設置することにより、地下水流による洗浄効果を併用しているため好ましいが、この実施態様に限定されるものでは無く、注水井6と揚水井7との間の水頭差(位置エネルギー差)により生じる注入水の循環だけで、汚染域4を通る水流を生じさせても良い。さらに、汚染域4が元々の地下水位2よりも下の帯水層3に有る場合について説明したが、元々の地下水位2よりも上に汚染域4があっても、水を注入することで汚染域4が地下水位よりも下になれば良い。
【0025】
【発明の効果】
請求項1から4の発明によれば、スクリーンに微生物が繁殖せず、スクリーンの目詰まりが無くなるので、注水井または揚水井の増設工事に伴う浄化運転の停止期間が無くなり、注水井または揚水井の増設工事費を削減し、汚染土壌の浄化期間を短縮することができる。
請求項5の発明によれば、汚染物質の注入水への溶出を促進させて、汚染物質の浄化を促進し、浄化期間を短縮することができる。
請求項6の発明によれば、請求項1から4及び請求項5に対応する効果に加え、注水および汲み上げに要するランニングコストを節約できる。
【図面の簡単な説明】
【図1】本発明の汚染土壌の原位置浄化装置の施工例を示す土壌の鉛直断面図である。
【図2】従来の汚染土壌の原位置浄化装置の施工例を示す土壌の鉛直断面図である。
【符号の説明】
1…透水層、2…地下水位、3…帯水層、4…汚染域、5…難透水層、6…注水井、7…揚水井、8…水処理システム、9…止水壁、10…表面遮水工。
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to an in-situ purification apparatus for contaminated soil, and more particularly, to an in-situ purification apparatus for contaminated soil that can shorten a purification period.
[0002]
[Prior art]
Remediation methods for illegal dumping sites, landfill sites, or soil and groundwater contamination sites for waste include replacement methods of excavating contaminated soil and refilling it with good quality soil, for example, replacement of contaminated soil. There is an in-situ purification method in which a required number of wells are drilled around and contaminated groundwater is pumped up and purified. The replacement method is an effective means when the depth of the contaminated area is shallow. However, when the depth of the contaminated area is deep (for example, about 10 m), the excavation amount becomes enormous and the cost increases. Therefore, when the depth of the contaminated area is deep and the contaminated area is in the aquifer, the above-described in-situ purification method is particularly effective, but of course, the in-situ purification method can be applied even when the depth is shallow. .
[0003]
The in-situ purification method disclosed in U.S. Pat. No. 4,435,292 (Patent Literature 1) injects high-pressure water from an injection well, discharges contaminated water from a pumping well with high vacuum, and contaminates the water treatment system. It is designed to remove substances. According to this conventional technology, the amount of clean water to be injected is reduced by circulating and using treated water, and a solvent, an inert gas such as nitrogen, or a reactive gas for purifying contaminants is used as an injection medium. By using it, it can be purified.
[0004]
The in-situ purification method disclosed in Japanese Patent Publication No. 6-96143 (Patent Document 2) intermittently injects and pumps water from an injection well and a pumping well. As a result, the groundwater is stopped during the suspension period of water injection and pumping, and contaminants remaining in the small gaps of the soil particles are moved by the weight of the contaminants to be introduced into the groundwater flow, thereby contaminating the groundwater. It promotes the purification of substances.
[0005]
Such an in-situ purification method or apparatus for contaminated soil, which is not a patent document, includes an in-situ purification apparatus as shown in FIG. The aquifer 3 below the permeable layer 1 below the groundwater level 2 contains a contaminated zone 4 of waste or contaminated soil. The elevation of a poorly permeable layer (also referred to as an impermeable layer) 5 below the permeable layer 1 is measured, and a required number of wells 6 are excavated on the higher elevation side of the poorly permeable layer 5 to inject water. The injected water flows to the lower side of the altitude, and elutes the contaminants from the contaminated area 4 when passing through the contaminated area 4. The required number of pumping wells 7 are excavated on the low elevation side of the impervious layer 5, the contaminated water from which the contaminants elute is pumped to the ground by the pump 7 A, the contaminants are removed by the water treatment system 8, and the contaminants are removed. The treated water thus injected is again injected into the injection well 6 and circulated. The injection well 6 and the pumping well 7 are provided with stitch-shaped screens 6B and 7B at a depth position corresponding to the depth of the contaminated area 4. The screen 6B discharges the injected water into the soil near the contaminated area 4 and prevents the soil from entering the water injection well 6. The screen 7 </ b> B draws contaminated water into the pumping well 7 and prevents soil from entering the pumping well 7. The outer perimeter of the contaminated soil surrounding the contaminated area 4, the injection well 6, and the pumping well 7 is surrounded by water blocking walls 9, 9 having a depth reaching the poorly permeable layer 5, and the ground surface is covered with a surface impervious work 10, and the To prevent leakage into the surroundings and penetration of rainwater into the soil.
[0006]
[Patent Document 1]
US Patent No. 4,435,292 [Patent Document 2]
Japanese Patent Publication No. Hei 6-96143 [0007]
[Problems to be solved by the invention]
However, in the prior arts shown in Patent Documents 1 and 2 and FIG. 2, water cannot be injected in several months because microorganisms adhere to and propagate on the screens of the injection well and the pumping well, causing clogging of the screen. There was something. For this reason, additional work of the injection well and the pumping well is required, and the purification work cannot be performed during the extension work, resulting in a problem that the purification period is lengthened.
[0008]
Further, the prior art disclosed in Patent Document 2 described above moves contaminants remaining in the small gaps of the soil particles by the weight of the contaminants while the groundwater is at rest. It takes a long time to derive water, and the period of suspension of water injection and pumping becomes longer, resulting in a problem that the purification period becomes longer. In addition, there is a limit to the purification of pollutants because the transfer of pollutants by their own weight is used.
[0009]
The present invention has been made in view of the above problems, and an object of the present invention is to mix a sterilizing agent into injection water or to make a screen a sterile member so that microorganisms do not propagate on the screen, thereby improving the screen. Is to prevent clogging, eliminate the suspension period of the purification operation, and shorten the purification period. Furthermore, an object of the present invention is to mix the gas into the injection water to make the injection water turbulent, thereby promoting the elution of the pollutant into the injection water, promoting the purification of the pollutant, Is to shorten.
[0010]
[Means for Solving the Problems]
According to the first aspect of the present invention, a water injection well for injecting water through a screen is provided near a contaminated area contaminated by contaminants, and water injected from the water injection well is pumped through the screen so as to pass through the contaminated area. A pumping well is provided, and in-situ purification apparatus for contaminated soil for purifying groundwater pumped from the pumping well by a water treatment system is provided with a sterilizing agent mixing device for mixing a sterilizing agent into the injection water, and each of the screens is provided. An in-situ purification apparatus for contaminated soil, wherein microorganisms are prevented from breeding.
[0011]
According to the invention of claim 2, a water injection well for injecting water through a screen is provided near a contaminated area contaminated by contaminants, and water injected from the water injection well is pumped through the screen so as to pass through the contaminated area. A pumping well is provided, and in the in-situ purification apparatus for contaminated soil for purifying groundwater pumped from the pumping well by a water treatment system, each screen is made a sterile member so that microorganisms do not propagate on the screen. An in-situ purification apparatus for contaminated soil, characterized in that:
[0012]
According to a third aspect of the present invention, in the in-situ purification apparatus for contaminated soil according to the first aspect, any one of sodium hypochlorite, chlorine gas, bromine gas, and ozone gas is used as the sterilizing agent. In-situ purification system for contaminated soil.
[0013]
According to a fourth aspect of the present invention, in the in-situ purification apparatus for a contaminated soil according to the second aspect, a coating of copper or a water-insoluble sterilant is used as the sterilizing member. It is a purification device.
[0014]
The invention according to claim 5 provides a water injection well for injecting water near the contaminated area contaminated by pollutants, and a pumping well for pumping water from the water injection well through the contaminated area, and pumps the water from the well. In the in-situ purification apparatus for contaminated soil that purifies the groundwater that has been purified by the water treatment system, a gas mixing device that mixes gas into the injection water to make the injection water turbulent is provided, An in-situ purification apparatus for contaminated soil characterized by promoting elution.
[0015]
According to a sixth aspect of the present invention, in the in-situ purification apparatus for contaminated soil according to any one of the first to fourth and fifth aspects, the intermittent injection device for intermittently injecting the injection water and the intermittent pumping of groundwater are used. An in-situ purification device for contaminated soil, wherein an intermittent pumping device is provided.
[0016]
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, in the embodiment of the present invention, the same parts as those of the conventional device will be described with the same reference numerals. FIG. 1 is a vertical sectional view of soil showing an example of the in-situ purification apparatus for contaminated soil according to the present invention.
[0017]
The aquifer 3 below the permeable layer 1 below the groundwater level 2 contains a contaminated zone 4 of waste or contaminated soil. The contaminated area 4 is formed at a depth of about 10 m from the surface of the ground. The permeable layer 1 has a permeability coefficient of 10 2 to 10 4 This layer is composed of sandy soil with a relatively high flow rate of groundwater of about cm / sec. The elevation of a poorly permeable layer (also referred to as an impermeable layer) 5 below the permeable layer 1 is measured, and a required number of injection wells 6 are excavated on the higher elevation side of the poorly permeable layer 5, and water is injected into the well 6. Inject. Aquiclude 5, permeability of 10 - 6 It is a layer composed of an alluvial clay layer or a diluvial clay layer of about 10 to 7 cm / sec. A required number of pumping wells 7 are excavated on the low elevation side of the impervious layer 5, and contaminated water from which contaminants have been eluted is pumped to the ground through the pumping well 7 and contaminated water is collected by a water treatment system 8 installed on the ground. Remove contaminants from
[0018]
The injection well 6 and the pumping well 7 are provided with stitch-shaped screens 6B and 7B at a depth position corresponding to the depth of the contaminated area 4. The screen 6B discharges the injected water into the soil and prevents the soil from entering the water injection well 6. The screen 7 </ b> B draws contaminated water into the pumping well 7 and prevents soil from entering the pumping well 7. If the outer perimeter of the contaminated soil surrounding the contaminated area 4, the injection well 6, and the pumping well 7 is surrounded by water blocking walls 9, 9 having a depth reaching the poorly permeable layer 5, if the ground surface is covered with a surface impervious work 10, contamination will occur. It is preferable because leakage of the substance to the surroundings and penetration of rainwater or the like into the soil can be prevented.
[0019]
In order to prevent the microorganisms from adhering and growing on the screens 6B and 7B and clogging the screens 6B and 7B, the injection well 6 contains sodium hypochlorite, chlorine gas, bromine gas or ozone gas in the injection water. Inject with sterilizer. The method of mixing the sterilant into the injection water can use a conventional inexpensive screen, select a sterilant according to the type of microorganism, and use the sterilant according to the degree of propagation of the microorganism. Can be adjusted. In addition, the screens 6B and 7B can be made sterile members to prevent microorganisms from adhering to the screens 6B and 7B and propagating. As a sterilizing member, there are a method of using copper as a material of the screens 6B and 7B, and a method of coating the screens 6B and 7B with a water-insoluble sterilant. The method of using the screens 6B and 7B as sterilizing members is preferable because running costs are not required. In this manner, microorganisms do not propagate on the screens 6B and 7B, and clogging of the screen is eliminated. Therefore, there is no stoppage period of the purification operation associated with the construction of the injection well 6 or the pumping well 7, thereby reducing the construction cost. Thus, the purification period can be shortened. The above-described method for preventing screen clogging and the method for intermittently performing water injection and pumping can be used. In that case, energy such as electric power used for water injection and pumping can be reduced, so that running costs can be saved.
[0020]
While the flow rate of the injection water into the injection well 6 is small, the flow rate of the injection water and the purification efficiency have a proportional relationship. However, the rate of elution of contaminants into the interstitial water between the soil particles is rate-determining, and even if the flow rate of the injected water is increased beyond a certain limit, the purification efficiency reaches a plateau. Therefore, a gas such as air is mixed into the injection water to make the injection water turbulent. It is preferable to use a high-pressure gas because the effect of making the injected water turbulent increases. As a result, the injected water flows into the gaps between the soil particles from all directions, and the elution of the pollutant into the injected water is promoted, the purification of the pollutant is promoted, and the purification period can be shortened. The above-described method of making the injection water turbulent and the method of intermittently injecting and pumping water can be used. In that case, energy such as electric power used for water injection and pumping can be reduced, so that running costs can be saved.
[0021]
The injection time, injection stop time, and pumping time, pumping stop time can be determined by an experimental method or a real-time method. The experimental method measures the concentration of contaminants in the contaminated water pumped from the pumping well 7 in advance, and obtains the injection time, injection stop time, pumping time, and pump stop time at which the concentration of the contaminants is highest. Do. The real-time method constantly measures the concentration of contaminants in the contaminated water pumped from the pumping well 7 and stops the operation of the injection well 6 and the pumping well 7 for a predetermined time when the concentration of the contaminants falls below a predetermined reference value. Then, the operation of the injection well 6 and the pumping well 7 is restarted. If the concentration of the contaminants in the contaminated water at the time of resuming the operation is equal to or higher than the predetermined reference value, the operation is continued, and if the concentration is equal to or lower than the predetermined reference value, the operation of the injection well 6 and the pumping well 7 is stopped for a predetermined time.
[0022]
In the above embodiment, the injection well 6 and the pumping well 7 are stopped and restarted at the same time. However, a time lag until the injected water reaches the pumping well 7 via the contaminated area 4 is considered. By stopping and restarting the pumping well 7 later than stopping and restarting the injection well 6, more efficient operation can be performed. It is preferable to operate both the injection well 6 and the pumping well 7 intermittently from the viewpoint of energy efficiency. However, if the average injection flow rate and the pumping flow rate are balanced, only one of the injection well 6 and the pumping well 7 is used. May be operated intermittently.
[0023]
When water is injected from the injection well 6, the injected water flows to the lower side of the altitude, and when passing through the contaminated area 4, the contaminants adsorbed on the waste or the soil particles in the contaminated area 4 elute into the injected water. The contaminated water from which the substances eluted is pumped from the pumping well 7 to the ground. The treated water from which the contaminants have been removed by the water treatment system 8 is again injected into the injection well 6 and circulated for use. By continuing this circulation, purification of the contaminated area 4 proceeds. The treated water may be discharged and clean water may be injected from the injection well 6.
[0024]
In the above embodiment, the water injection well 6 is installed on the high altitude side of the poorly permeable layer 5 and the pumping well 7 is installed on the low altitude side, so that the cleaning effect by the groundwater flow is also used. Although preferred, but not limited to this embodiment, the circulation of the injected water caused only by the head difference (potential energy difference) between the injection well 6 and the pumping well 7 creates a water flow through the contaminated area 4. May be. Furthermore, the case where the contaminated area 4 is in the aquifer 3 below the original groundwater level 2 has been described. However, even if the contaminated area 4 is present above the original groundwater level 2, water can be injected. What is necessary is that the contaminated area 4 is below the groundwater level.
[0025]
【The invention's effect】
According to the first to fourth aspects of the present invention, microorganisms do not propagate on the screen and clogging of the screen is eliminated, so that there is no suspension period of the purification operation due to the construction of the additional injection well or pumping well, and the injection well or pumping well is eliminated. Construction costs can be reduced, and the period for cleaning up contaminated soil can be shortened.
According to the invention of claim 5, the elution of the contaminant into the injection water is promoted, the purification of the contaminant is promoted, and the purification period can be shortened.
According to the sixth aspect, in addition to the effects corresponding to the first to fourth aspects and the fifth aspect, the running cost required for water injection and pumping can be saved.
[Brief description of the drawings]
FIG. 1 is a vertical sectional view of soil showing an example of installation of an in-situ purification apparatus for contaminated soil according to the present invention.
FIG. 2 is a vertical sectional view of soil showing an example of a conventional in-situ purification apparatus for contaminated soil.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 ... Permeable layer, 2 ... Groundwater level, 3 ... Aquifer, 4 ... Contaminated area, 5 ... Impervious layer, 6 ... Injection well, 7 ... Pumping well, 8 ... Water treatment system, 9 ... Water stop wall, 10 … Surface impermeable construction.

Claims (6)

汚染物質によって汚染された汚染域近傍にスクリーンを介して注水する注水井を設けるとともに、上記注水井からの注入水が汚染域を経由するようにスクリーンを介して揚水する揚水井を設け、上記揚水井から汲み上げた地下水を、水処理システムによって浄化する汚染土壌の原位置浄化装置において、上記注入水に滅菌剤を混入する滅菌剤混入装置を設け、上記各スクリ−ンに微生物が繁殖しないようにしたことを特徴とする汚染土壌の原位置浄化装置。In addition to providing an injection well for injecting water through a screen in the vicinity of a contaminated area contaminated by contaminants, and providing a pumping well for pumping water through the screen so that water injected from the injection well passes through the contaminated area, An in-situ purification device for contaminated soil that purifies groundwater pumped from a well by a water treatment system is provided with a sterilizing agent mixing device that mixes a sterilizing agent into the injection water so that microorganisms do not propagate on the respective screens. In-situ purification device for contaminated soil, characterized in that: 汚染物質によって汚染された汚染域近傍にスクリーンを介して注水する注水井を設けるとともに、上記注水井からの注入水が汚染域を経由するようにスクリーンを介して揚水する揚水井を設け、上記揚水井から汲み上げた地下水を、水処理システムによって浄化する汚染土壌の原位置浄化装置において、上記各スクリーンを滅菌性の部材にして、上記スクリ−ンに微生物が繁殖しないようにしたことを特徴とする汚染土壌の原位置浄化装置。In addition to providing an injection well for injecting water through a screen in the vicinity of a contaminated area contaminated by contaminants, and providing a pumping well for pumping water through the screen so that water injected from the injection well passes through the contaminated area, An in-situ purification apparatus for contaminated soil for purifying groundwater pumped from a well by a water treatment system, wherein each of the screens is made of a sterile member so that microorganisms do not propagate on the screen. In situ purification device for contaminated soil. 請求項1に記載した汚染土壌の原位置浄化装置において、上記滅菌剤として、次亜塩素酸ソーダ、塩素ガス、臭素ガスまたはオゾンガスのいずれかを用いることを特徴とする汚染土壌の原位置浄化装置。The in-situ purification apparatus for contaminated soil according to claim 1, wherein any one of sodium hypochlorite, chlorine gas, bromine gas and ozone gas is used as the sterilizing agent. . 請求項2に記載した汚染土壌の原位置浄化装置において、上記滅菌性の部材として、銅または水不溶性の滅菌剤のコーティングを用いることを特徴とする汚染土壌の原位置浄化装置。3. The in-situ purification apparatus for contaminated soil according to claim 2, wherein a copper or water-insoluble sterilizing agent coating is used as the sterilizing member. 汚染物質によって汚染された汚染域近傍に注水する注水井を設けるとともに、上記注水井からの注入水が汚染域を経由するように揚水井を設け、上記揚水井から汲み上げた地下水を、水処理システムによって浄化する汚染土壌の原位置浄化装置において、上記注入水に気体を混入して注入水を乱流にする気体混入装置を設け、上記汚染物質の上記注入水への溶出を促進させるようにしたことを特徴とする汚染土壌の原位置浄化装置。In addition to providing a water injection well near the contaminated area contaminated by pollutants, a pumping well is provided so that the injection water from the above-mentioned injection well passes through the contaminated area, and groundwater pumped up from the above-mentioned pumping well is subjected to a water treatment system. In the in-situ purification apparatus for contaminated soil to be purified by the method, a gas mixing device that mixes gas into the injection water to make the injection water turbulent is provided to promote elution of the pollutant into the injection water. An in situ purification device for contaminated soil, characterized in that: 請求項1から4、及び5のいずれかに記載した汚染土壌の原位置浄化装置において、上記注入水の注入を間欠的に行う間欠注入装置及び地下水の汲み上げを間欠的に行う間欠汲上装置を設けたことを特徴とする汚染土壌の原位置浄化装置。The in-situ purification apparatus for contaminated soil according to any one of claims 1 to 4, and 5, further comprising an intermittent injection device for intermittently injecting the injection water and an intermittent pumping device for intermittently pumping groundwater. In-situ purification apparatus for contaminated soil.
JP2003116546A 2003-04-22 2003-04-22 Original position cleaning apparatus for polluted soil Withdrawn JP2004321863A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1655916A2 (en) 2004-11-05 2006-05-10 Sony Corporation Asynchronous network system, information processing apparatus, data-transmission managing method, data-reception managing method, and program
JP2018035613A (en) * 2016-09-01 2018-03-08 株式会社竹中工務店 Injection method for injection liquid
CN109013690A (en) * 2018-07-11 2018-12-18 甘灿琼 A kind of linkage pretreatment prosthetic device of contaminated soil
CN109261712A (en) * 2018-10-12 2019-01-25 江苏壹萨生物科技有限公司 A kind of surfactant processing contaminated soil device
CN110255638A (en) * 2019-07-25 2019-09-20 中冶南方都市环保工程技术股份有限公司 A kind of polluted underground water containing nonaqueous phase liquid original position pump-and-treat system system and method

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1655916A2 (en) 2004-11-05 2006-05-10 Sony Corporation Asynchronous network system, information processing apparatus, data-transmission managing method, data-reception managing method, and program
JP2018035613A (en) * 2016-09-01 2018-03-08 株式会社竹中工務店 Injection method for injection liquid
CN109013690A (en) * 2018-07-11 2018-12-18 甘灿琼 A kind of linkage pretreatment prosthetic device of contaminated soil
CN109261712A (en) * 2018-10-12 2019-01-25 江苏壹萨生物科技有限公司 A kind of surfactant processing contaminated soil device
CN110255638A (en) * 2019-07-25 2019-09-20 中冶南方都市环保工程技术股份有限公司 A kind of polluted underground water containing nonaqueous phase liquid original position pump-and-treat system system and method

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