JP2004285548A - Functional fiber, fiber structural material of the same, and absorbent article - Google Patents

Functional fiber, fiber structural material of the same, and absorbent article Download PDF

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Publication number
JP2004285548A
JP2004285548A JP2003203723A JP2003203723A JP2004285548A JP 2004285548 A JP2004285548 A JP 2004285548A JP 2003203723 A JP2003203723 A JP 2003203723A JP 2003203723 A JP2003203723 A JP 2003203723A JP 2004285548 A JP2004285548 A JP 2004285548A
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Prior art keywords
skin
fiber
absorbent article
functional fiber
nonwoven fabric
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JP2003203723A
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Japanese (ja)
Inventor
Yoshinobu Oya
義信 大家
Tetsuro Furuya
哲朗 古谷
Seiichi Ochi
清一 越智
Shinichiro Inatomi
伸一郎 稲富
Eiki Matoba
栄樹 的場
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Toyobo Co Ltd
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Toyobo Co Ltd
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  • Absorbent Articles And Supports Therefor (AREA)
  • Orthopedics, Nursing, And Contraception (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a functional fiber comfortable when used as a product which is contacted with the human body, scarcely, in detail, irritating the skin, and having properties of caring for the skin, namely, preventing the skin from being roughed or promoting a recovery function by protecting the skin, to provide a fiber structural material of the same, and to provide an absorbent article. <P>SOLUTION: This functional fiber is formed so that a moisture-absorbing agent and a compound having a phospholipid-like structure are combinedly mixed into or adhered to the fiber, wherein a polysaccharide, such as chitosan or arabinogalactan, is preferably used as the moisture-absorbing agent. The fiber structural material contains the functional fiber as at least a part thereof. The absorbent article is given by using the fiber structural material. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

【0001】
【発明の属する技術分野】
本発明は、身体に接触する物品に用いて好適な、更に詳しくは皮膚に対する刺激が少なく、皮膚を保護して肌荒れを防止又は回復機能を促進する機能性繊維及びその繊維構造物に関する。また前記繊維構造物を用いた吸収性物品に関する。
【0002】
【従来の技術】
近年、肌の健康に対する関心が高まっており、化粧品はもとより、繊維に対しても肌にやさしく、健康を保つ機能すなわちスキンケア性が求められている。これらの市場の要望に応えるため、種々の試みがなされている。例えば繊維にスキンケア性を付与するためリン脂質類似構造物を付与することが知られている(例えば、特許文献1、2参照。)。前記文献によれば、リン脂質類似構造物が皮膚表面で水分膜を形成し、肌のバリア機能(水分蒸散の防止)を促進又は補完され、これにより角質中の水分及び天然保湿成分(NMF)流出を防止し、皮膚を正常な状態に回復させていると考えられる。しかしながら、実用上において該ポリマーの効果のみでは有効に肌の機能を回復し得るとは言いがたい。すなわち、健康な皮膚に回復させるためには、皮膚のターンオーバーを正常なサイクルを営み得る状態にする必要があるが、該ポリマーを使用した場合、すなわち通常のバリア機能を付与するのみでは回復まで時間がかかるため、該ポリマーが一旦取り除かれればせっかく回復した水分が蒸散し、元の肌荒れ状態に戻ってしまうという不具合があった。
【0003】
【特許文献1】
特開2002−348778号公報(段落番号(0008〜0016など))
【特許文献2】
特開2002−348779号公報(段落番号(0007〜0019など)
【0004】
【発明が解決しようとする課題】
本発明は、皮膚への刺激性が少なく、肌荒れを回復、防止する等のスキンケア性を有する機能性繊維及びその繊維構造物、該繊維構造物を用いた吸収性物品を提供することを課題とするものである。
【0005】
【課題を解決するための手段】
本発明者等は上記課題を解決すべく鋭意検討した結果、吸湿剤とリン脂質類似構造物とを併用することにより、高いスキンケア性を有する機能性繊維、繊維構造物、及び吸収性物品が得られることを見出し本発明に至った。
【0006】
即ち、本発明は以下の構成よりなる。
1.吸湿剤とリン脂質類似構造物が併用して含有又は付着されていることを特徴とする機能性繊維。
2.吸湿剤が多糖類であることを特徴とする上記第1記載の機能性繊維。
3.多糖類がキトサンであることを特徴とする上記第2記載の機能性繊維。
4.多糖類がアラビノガラクタンであることを特徴とする上記第2記載の機能性繊維。
5.吸湿剤がポリスチレン系、ポリアクリロニトリル系、ポリアクリル酸エステル系、ポリメタクリル酸エステル系のいずれかのビニル系重合体で、スルホン酸基、カルボン酸基、リン酸基あるいは、それらの金属塩の少なくとも1種の親水基を有し、かつジビニルベンゼン、トリアリルイソシアネートまたはヒドラジンのいずれかで架橋された架橋重合体であることを特徴とする上記第1記載の機能性繊維。
6.上記第1〜第5のいずれかに記載の機能性繊維が少なくとも一部に含有されてなることを特徴とする繊維構造物。
7.上記第6に記載の繊維構造物が少なくとも一部に用いられてなることを特徴とする吸収性物品。
8.繊維構造物が不織布であり、該不織布が吸収性物品の肌に接触する面に用いられてなることを特徴とする上記第7に記載の吸収性物品。
【0007】
【発明の実施の形態】
以下、本発明について詳述する。
吸湿剤とリン脂質類似構造物とを併用することにより高いスキンケア性を有する理由について、以下のような理由が考えられる。
第一にリン脂質類似構造物の保湿力が不足していることが考えられる。すなわち、リン脂質類似構造物は高いバリア性を有するが、吸湿性が乏しい乾燥した布帛が肌に接すると肌の水分を回復することができず、その結果正常な肌のターンオーバーを確保できないと考えられる。
第二に皮膚に移行して、皮膜となったリン脂質類似構造物の親水基が、吸湿性が高い布帛の存在により皮膜表面により多く配向し、均一な膜構造を形成していると考えられる。
【0008】
本発明に係る吸湿剤は皮膚の保湿剤として一般的に使用されているアミノ酸やピロリドカンカルボン酸など天然保湿成分であってもよいが、多糖類であってもよく、更にはキトサン又はアラビノガラクタンであることが好ましい。
【0009】
また本発明に係る吸湿剤は、ポリスチレン系、ポリアクリロニトリル系、ポリアクリル酸エステル系、ポリメタクリル酸エステル系のいずれかのビニル系重合体で、スルホン酸基、カルボン酸基、リン酸基あるいは、それらの金属塩の少なくとも1種の親水基を有し、かつジビニルベンゼン、トリアリルイソシアネートまたはヒドラジンのいずれかで架橋された架橋重合体であってもよい。これらの剤は、リン脂質類似構造物と併用することにより、特に優れたスキンケア性を示すからである。この理由としては、これらの剤は吸湿性を有すると同時に、抗菌性をも有し、荒れて外部からの細菌等が進入し易くなった皮膚を保護するのに適していると考えられる。
【0010】
リン脂質類似構造物は下記の構造を含む重合体であることが好ましい。
【0011】
【化1】

Figure 2004285548
【0012】
[上記一般式(1)中、Xは2価の有機残基を示し、Yは炭素数1〜6のアルキレンオキシ基を示し、Zは水素原子もしくはR−O−(C=O)−(但しRは炭素数1〜10のアルキル基または炭素数1〜10のヒドロキシアルキル基を示す。)を示す。また、Rは水素原子もしくはメチル基を示し、R、RおよびRは同一もしくは異なる基であって、水素原子または炭素数1〜6のアルキル基またはヒドロキシアルキル基を示す。mは0〜20の整数を示す。nは1〜4の整数を示す。]
【0013】
係るリン脂質類似構造物は特に高いスキンケア性を有するのみならず、細菌類が付着し難く、かつ血液適合性にも優れ、スキンケア布帛としての高い特性を備えているからである。
【0014】
本発明でいうスキンケア性とは外部からの刺激から皮膚を保護する、又は荒れた皮膚を正常に回復させる機能をいう。
【0015】
本発明におけるリン脂質類似ポリマー及び吸湿剤の付与量は特に限定するものではないが、それぞれ0.01%o.w.f 〜 20%o.w.f (o.w.fはon the weight of fiber)であることが好ましい。この範囲より低ければ、本発明の効果が得られにくくなり、この範囲より高ければ繊維構造物の風合い等に問題が生じ易いからである。
【0016】
本発明に係る繊維の材質は特に限定するものではなく、綿や絹等の天然繊維、ポリエステルやポリアミドの合成繊維であってもよいが、皮膚との摩擦が小さく、風合いが柔らかいものが好ましい。
【0017】
本発明にかかる吸着剤、リン脂質類似構造物は、繊維を構成するポリマーに練り込むことによって含有させてもよい。ポリマーに練り込むことにより、特に洗濯耐久性を要求される用途に用いて長期間効果を発揮するからである。
【0018】
また繊維化後及び繊維構造物にパディング等により付着させてもよい。表面付着させることにより、皮膚に接触する部分に吸着剤、リン脂質類似構造物が分散され、練り込む場合に比して少量で効果を発揮でき、また工程通過性についても練り込む場合より優れているからである。繊維構造物が短繊維不織布の場合には、不織布製造後あるいは吸収性物品などの製品を生産時にスプレー付与などにより付着させてもよい。この場合にも練り込む場合に比して少量で効果を発揮できる点で好ましい。
【0019】
本発明でいう繊維構造物とは、織物、編物、不織布等に代表される、繊維を用いて2次元又は3次元的な構造を有するものを言う。
【0020】
本発明に係る繊維構造物の用途は、特に限定されるものではないが、シーツ類や帽子、手袋、レッグニット等の他、インナーウェア、衛材等の肌に接触するアイテムとして特に効果が発揮される。また、吸収性物品については特に好ましく使用される。吸収性物品の代表例としては、紙おむつ、生理用ナプキン、ライナー、汗わきパッドなどであり、特に紙おむつ、生理用ナプキン、ライナー、汗わきパッドの表面材として本発明の繊維構造物が好ましく使用される。肌に接触する面以外についても、紙おむつのギャザー等の肌に接触して用いられたり、又は長時間あるいは繰り返し使用されるものにも好適である。
【0021】
【実施例】
以下具体的実施例を挙げて説明するが、本発明はこれら実施例に限定されるものではない。また、実施例中の部は重量部を意味する。
【0022】
<スキンケア性評価方法>
(1)試験サンプルを6mmφの大きさに切り抜き、フィンチャンバー (大正製薬製)にセットした。
(2)濃度0.1%、0.3%、0.7%に調整したドデシル硫酸ナトリウム(SDS)水溶液を10μLずつそれぞれ試験布に含浸させた。
(3)成人男性(5名)の背部(脊椎椎部)に閉塞貼付した。
(4)貼付24時間後に試験サンプルを背部より剥離した。
(5)剥離1時間後および24時間後に皮膚の状態を肉眼にて判定した。判定基準は以下の通りである。
【0023】
(皮膚判定基準)
皮膚反応は、試験実施者とは別の判定者が下記表1の基準に従い判定後、反応に評点を与え、その点数を須貝らにより考案された下記式(A)に導入して皮膚刺激指数を算出した。
皮膚刺激指数 = (総評点和/被験者数) × 100……………(A)
上記式Aで示される皮膚刺激指数が低いほど、優れたスキンケア性を有する。
【0024】
【表1】
Figure 2004285548
【0025】
(実施例1)
ポリエチレン(PE)/ ポリエステル(PET)のシース/コア構造を有する2.2dtex×44mmをカードウェッブとし、140℃で5秒熱処理したエアースルー不織布30g/mを得た。得られた不織布に、リン脂質類似構造物としてLipidure(R) MF−3(日本油脂(株)製)を0.25%o.w.f(固形分)、吸湿剤として多糖類であるキトサンを0.5%o.w.f(固形分)をパディングにより塗布した。得られた不織布のスキンケア性評価結果を表2に示す。得られた処理不織布は、リン脂質類似ポリマー及び吸湿剤を塗布していない下記比較例1の不織布と比して明確に優れたスキンケア性を有するものであった。吸収性物品として、前記の処理不織布を肌に直接触れる面であるトップシートに使用し、ポリエチレンフィルムからなる液不透過性のバックシート、吸収性コアを組合せて、パンツ型紙おむつを作製した。優れたスキンケア性を有する紙おむつが得られた。
【0026】
(実施例2)
吸湿剤としてアラビノガラクタンを0.5%o.w.f(固形分)用いる以外は実施例1と同様の方法で処理不織布を得た。得られた処理不織布のスキンケア性評価結果を表2に示す。得られた処理不織布は、実施例1と同様に下記比較例1の不織布と比して明確に優れたスキンケア性を有するものであった。前記の処理不織布を実施例1と同様にトップシートに使用して、紙おむつを作成した。優れたスキンケア性を有する紙おむつが得られた。
【0027】
(実施例3)
まず、次の方法で吸湿性ポリマーを得た。
メタクリル酸/p−スチレンスルホン酸ソーダ=70/30の水溶性重合体350部及び硫酸ナトリウム35部を6500部の水に溶解し、櫂型攪拌機付きの重合槽に仕込んだ。次に、アクリル酸メチル2750部及びジビニルベンゼン330部に2,2’−アゾビス−(2,4−ジメチルバレロニトリル)15部を溶解して重合槽に仕込み、400rpmの攪拌下、60℃で2時間重合し、重合率88%の共重合体を得た。該重合体100部を水900部中に分散し、これに110部の苛性ソーダを添加し、90℃、2.5時間反応を行い、アクリル酸メチルのメチルエステル部を加水分解することによりカルボキシル基4.6ミリ当量/gを有した架橋重合体を得た。得られた架橋重合体を吸湿剤として0.5o.w.f(固形分)使用する以外は実施例1と同様の方法で処理不織布を得た。得られた処理不織布のスキンケア性評価結果を表2に示す。得られた処理不織布は、実施例1と同様に下記比較例1の不織布と比して明確に優れたスキンケア性を有するものであった。前記の処理不織布を実施例1と同様にトップシートに使用して、紙おむつを作成した。優れたスキンケア性を有する紙おむつが得られた。
【0028】
(実施例4)
ポリエステルよりなる目付け50g/mスパンボンド不織布にリン脂質類似構造物としてLipidure MF−3(日本油脂(株)製)を0.25%o.w.f(固形分)、吸湿剤としてアラビノガラクタンを0.5%o.w.f(固形分)をパディングにより塗布した。得られた処理スパンボンド不織布は、実施例2のものと同様に下記比較例1の不織布と比して明確に優れたスキンケア性を有するものであった。前記の処理スパンボンド不織布を実施例1と同様にトップシートに使用して、紙おむつを作成した。優れたスキンケア性を有する紙おむつが得られた。
【0029】
(比較例1)
実施例1と同様にポリエチレン(PE)/ ポリエステル(PET)のシース/コア構造を有する2.2dtex×44mmを原綿として30g/mの不織布を得た。得られた不織布に何らリン脂質類似構造物及び吸湿剤のいずれも付与することなく、スキンケア性評価をおこなった。スキンケア性評価結果を表2に示す。得られた不織布は実施例1〜4の処理不織布と比較して、スキンケア性の劣るものであった。
【0030】
(比較例2)
実施例1と同様にポリエチレン(PE)/ ポリエステル(PET)のシース/コア構造を有する2.2dtex×44mmを原綿として30g/mの不織布を得た。得られた不織布に、リン脂質類似構造物(Lipidure(R) MF−3)のみを0.25%o.w.f(固形分)付与した。得られた処理不織布のスキンケア性評価結果を表2に示す。得られた処理不織布は未処理不織布(比較例1)との明確な差は現れず、十分なスキンケア性は得られなかった。
【0031】
【表2】
Figure 2004285548
【0032】
【発明の効果】
本発明によれば、衣類や医療、健康維持用品、衛材その他身体に接触するアイテムに用いて好適な、更に詳しくは皮膚に対する刺激が少なく、皮膚を保護して肌荒れを防止又は回復機能を促進する機能性繊維及びその繊維構造物を提供することが可能となった。また、前記の繊維構造物を用いて優れたスキンケア性を有する吸収性物品の提供が可能となった。[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a functional fiber suitable for use in an article that comes into contact with the body, and more particularly, to a functional fiber which has little irritation to the skin and protects the skin to prevent rough skin or promote a recovery function, and a fiber structure thereof. In addition, the present invention relates to an absorbent article using the fiber structure.
[0002]
[Prior art]
2. Description of the Related Art In recent years, interest in skin health has been increasing, and not only cosmetics but also fibers have been required to be gentle to the skin and have a function of maintaining health, that is, a skin care property. Various attempts have been made to meet the needs of these markets. For example, it is known to provide a fiber with a phospholipid-like structure for imparting skin care properties (for example, see Patent Documents 1 and 2). According to the literature, the phospholipid-like structure forms a moisture film on the skin surface, and promotes or complements the barrier function of the skin (prevention of water loss), thereby enabling the moisture in the stratum corneum and the natural moisturizing component (NMF) It is thought that the spill was prevented and the skin was restored to a normal state. However, in practical use, it cannot be said that the effect of the polymer alone can effectively restore skin functions. In other words, in order to restore healthy skin, it is necessary to make the skin turnover a state capable of performing a normal cycle.However, when the polymer is used, that is, only by providing a normal barrier function, it is necessary to recover the skin. Since it takes time, once the polymer is removed, the recovered water evaporates and there is a problem that the skin returns to its original roughened state.
[0003]
[Patent Document 1]
JP-A-2002-348778 (paragraph numbers (0008 to 0016, etc.))
[Patent Document 2]
JP-A-2002-348779 (paragraph numbers (0007 to 0019 and the like))
[0004]
[Problems to be solved by the invention]
An object of the present invention is to provide a functional fiber having a skin care property such as having less irritating property to the skin and recovering and preventing rough skin, a fiber structure thereof, and an absorbent article using the fiber structure. Is what you do.
[0005]
[Means for Solving the Problems]
The present inventors have conducted intensive studies to solve the above problems, and as a result, by using a moisture absorbent and a phospholipid-like structure together, a functional fiber, a fiber structure, and an absorbent article having high skin care properties are obtained. This led to the present invention.
[0006]
That is, the present invention has the following configurations.
1. A functional fiber characterized in that a moisture absorbent and a phospholipid-like structure are contained or attached in combination.
2. 2. The functional fiber according to the above item 1, wherein the hygroscopic agent is a polysaccharide.
3. 3. The functional fiber according to the above item 2, wherein the polysaccharide is chitosan.
4. 3. The functional fiber according to the above item 2, wherein the polysaccharide is arabinogalactan.
5. The hygroscopic agent is a polystyrene-based, polyacrylonitrile-based, polyacrylate-based, or polymethacrylate-based vinyl polymer, and includes a sulfonic acid group, a carboxylic acid group, a phosphate group, or at least a metal salt thereof. 2. The functional fiber according to the above item 1, characterized in that it is a crosslinked polymer having one kind of hydrophilic group and crosslinked with any of divinylbenzene, triallyl isocyanate or hydrazine.
6. A fibrous structure comprising at least a part of the functional fiber according to any one of the first to fifth aspects.
7. An absorbent article, wherein the fiber structure according to the sixth aspect is used at least in part.
8. 8. The absorbent article according to the above item 7, wherein the fibrous structure is a nonwoven fabric, and the nonwoven fabric is used on a surface of the absorbent article that comes into contact with the skin.
[0007]
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, the present invention will be described in detail.
The following reasons can be considered as the reason for having high skin care property by using a hygroscopic agent and a phospholipid-like structure together.
First, it is considered that the moisturizing power of the phospholipid-like structure is insufficient. That is, although the phospholipid-like structure has a high barrier property, it is not possible to recover the moisture of the skin when the dried cloth having poor hygroscopicity comes into contact with the skin, and as a result, it is not possible to secure normal skin turnover. Conceivable.
Secondly, it is considered that the hydrophilic group of the phospholipid-like structure that migrates to the skin and forms a film is more oriented on the film surface due to the presence of the highly hygroscopic fabric, forming a uniform film structure. .
[0008]
The moisture absorbent according to the present invention may be a natural moisturizing component such as an amino acid or pyrrolidocan carboxylic acid generally used as a skin moisturizing agent, but may be a polysaccharide, and further may be chitosan or arabino. Preferably it is galactan.
[0009]
Further, the moisture absorbent according to the present invention is a polystyrene-based, polyacrylonitrile-based, polyacrylate-based, polymethacrylate-based vinyl polymer, sulfonic acid group, carboxylic acid group, phosphate group, or It may be a crosslinked polymer having at least one hydrophilic group of those metal salts and crosslinked with any of divinylbenzene, triallyl isocyanate or hydrazine. This is because these agents exhibit particularly excellent skin care properties when used in combination with a phospholipid-like structure. The reason for this is considered to be that these agents have hygroscopicity as well as antibacterial properties, and are suitable for protecting the skin which has become rough and which is easy for bacteria and the like from the outside to enter.
[0010]
The phospholipid-like structure is preferably a polymer having the following structure.
[0011]
Embedded image
Figure 2004285548
[0012]
[In the above general formula (1), X represents a divalent organic residue, Y represents an alkyleneoxy group having 1 to 6 carbon atoms, and Z represents a hydrogen atom or R 5 —O— (C = O) —. (wherein R 5 represents. a hydroxyalkyl group having 1 to 10 carbon alkyl group or a C 1-10 carbon atoms). Further, R 1 represents a hydrogen atom or a methyl group, and R 2 , R 3 and R 4 are the same or different groups and represent a hydrogen atom or an alkyl group having 1 to 6 carbon atoms or a hydroxyalkyl group. m shows the integer of 0-20. n shows the integer of 1-4. ]
[0013]
This is because such a phospholipid-like structure not only has a particularly high skin care property, but also is hard to adhere bacteria, has excellent blood compatibility, and has high properties as a skin care cloth.
[0014]
The skin care property referred to in the present invention means a function of protecting the skin from external irritation or recovering rough skin normally.
[0015]
The application amounts of the phospholipid-like polymer and the hygroscopic agent in the present invention are not particularly limited, but are 0.01% o. w. f-20% o. w. f (owf is on the weight of fiber). If it is lower than this range, it is difficult to obtain the effects of the present invention, and if it is higher than this range, problems tend to occur in the feeling of the fiber structure.
[0016]
The material of the fiber according to the present invention is not particularly limited, and may be a natural fiber such as cotton or silk, or a synthetic fiber of polyester or polyamide. However, a material that has low friction with the skin and has a soft feel is preferable.
[0017]
The adsorbent and the phospholipid-like structure according to the present invention may be contained by kneading the polymer constituting the fiber. By kneading it into the polymer, it is particularly effective for applications requiring washing durability and exerts a long-term effect.
[0018]
Further, it may be attached after fibrillation and to the fibrous structure by padding or the like. By adhering to the surface, the adsorbent, a phospholipid-like structure is dispersed in the part that comes into contact with the skin, and the effect can be exerted in a small amount as compared with kneading, and the process passability is also better than when kneading. Because there is. When the fibrous structure is a short-fiber non-woven fabric, a product such as an absorbent article may be attached after production of the non-woven fabric or during production by spraying or the like. This case is also preferable in that the effect can be exhibited with a small amount as compared with the case of kneading.
[0019]
The fiber structure referred to in the present invention refers to a structure having a two-dimensional or three-dimensional structure using fibers, such as a woven fabric, a knitted fabric, and a nonwoven fabric.
[0020]
The use of the fiber structure according to the present invention is not particularly limited, but is particularly effective as an item that comes into contact with the skin, such as sheets, hats, gloves, and leg knits, as well as innerwear and sanitary materials. Is done. Absorbent articles are particularly preferably used. Representative examples of absorbent articles include disposable diapers, sanitary napkins, liners, sweat pads, and the like. In particular, the fiber structure of the present invention is preferably used as a surface material for disposable diapers, sanitary napkins, liners, and sweat pads. You. The surface other than the surface that comes in contact with the skin is also suitable for use in contact with the skin, such as gathers for disposable diapers, or those that are used for a long time or repeatedly.
[0021]
【Example】
Hereinafter, the present invention will be described with reference to specific examples, but the present invention is not limited to these examples. Parts in the examples mean parts by weight.
[0022]
<Skin care evaluation method>
(1) A test sample was cut out to a size of 6 mmφ and set in a fin chamber (Taisho Pharmaceutical).
(2) Each of the test cloths was impregnated with 10 μL of an aqueous solution of sodium dodecyl sulfate (SDS) adjusted to concentrations of 0.1%, 0.3%, and 0.7%, respectively.
(3) Obstruction was applied to the back (vertebrae) of adult men (5).
(4) The test sample was peeled from the back 24 hours after application.
(5) After 1 hour and 24 hours after peeling, the condition of the skin was visually determined. The criteria are as follows.
[0023]
(Skin criteria)
The skin reaction is evaluated by a judge different from the tester according to the criteria shown in Table 1 below, and the reaction is given a score. The score is introduced into the following formula (A) devised by Sugai et al. Was calculated.
Skin irritation index = (total score total / number of subjects) x 100 ... (A)
The lower the skin irritation index represented by the above formula A, the better the skin care properties.
[0024]
[Table 1]
Figure 2004285548
[0025]
(Example 1)
A 2.2 dtex × 44 mm having a sheath / core structure of polyethylene (PE) / polyester (PET) was used as a card web, and heat-treated at 140 ° C. for 5 seconds to obtain an air-through nonwoven fabric of 30 g / m 2 . Lipidure® MF-3 (manufactured by NOF CORPORATION) as a phospholipid-like structure was 0.25% o. w. f (solid content), 0.5% o.o. of chitosan which is a polysaccharide as a moisture absorbent. w. f (solid content) was applied by padding. Table 2 shows the evaluation results of the skin care properties of the obtained nonwoven fabric. The resulting treated nonwoven fabric had clearly superior skin care properties as compared with the nonwoven fabric of Comparative Example 1 below, to which the phospholipid-like polymer and the hygroscopic agent were not applied. As an absorbent article, the treated nonwoven fabric was used for a top sheet that directly touches the skin, and a liquid-impermeable back sheet made of a polyethylene film and an absorbent core were combined to produce a pants-type paper diaper. A disposable diaper having excellent skin care properties was obtained.
[0026]
(Example 2)
0.5% o. Arabinogalactan as a moisture absorbent. w. A treated nonwoven fabric was obtained in the same manner as in Example 1 except that f (solid content) was used. Table 2 shows the results of evaluating the skin care properties of the obtained nonwoven fabric. The obtained treated nonwoven fabric had a clearly superior skin care property as compared with the nonwoven fabric of Comparative Example 1 described below, as in Example 1. The treated nonwoven fabric was used for a top sheet in the same manner as in Example 1 to prepare a disposable diaper. A disposable diaper having excellent skin care properties was obtained.
[0027]
(Example 3)
First, a hygroscopic polymer was obtained by the following method.
350 parts of a water-soluble polymer of methacrylic acid / sodium p-styrenesulfonate = 70/30 and 35 parts of sodium sulfate were dissolved in 6500 parts of water, and charged in a polymerization tank equipped with a paddle-type stirrer. Next, 15 parts of 2,2′-azobis- (2,4-dimethylvaleronitrile) were dissolved in 2750 parts of methyl acrylate and 330 parts of divinylbenzene, and the mixture was charged into a polymerization tank and stirred at 60 ° C. under stirring at 400 rpm. Polymerization was performed for an hour to obtain a copolymer having a conversion of 88%. 100 parts of the polymer is dispersed in 900 parts of water, 110 parts of caustic soda is added thereto, the reaction is carried out at 90 ° C. for 2.5 hours, and the carboxyl group is obtained by hydrolyzing the methyl ester of methyl acrylate. A crosslinked polymer having 4.6 meq / g was obtained. The obtained crosslinked polymer was used as a moisture absorbent at 0.5 o. w. A treated nonwoven fabric was obtained in the same manner as in Example 1 except that f (solid content) was used. Table 2 shows the results of evaluating the skin care properties of the obtained nonwoven fabric. The treated nonwoven fabric had a clearly superior skin care property as compared with the nonwoven fabric of Comparative Example 1 described below, as in Example 1. The treated nonwoven fabric was used for a top sheet in the same manner as in Example 1 to prepare a disposable diaper. A disposable diaper having excellent skin care properties was obtained.
[0028]
(Example 4)
A 50 g / m 2 spunbond nonwoven fabric made of polyester and 0.25% o.p. of Lipidure MF-3 (manufactured by NOF Corporation) as a phospholipid-like structure. w. f (solid content), arabinogalactan 0.5% o. w. f (solid content) was applied by padding. The resulting treated spunbonded nonwoven fabric had clearly superior skin care properties as compared with the nonwoven fabric of Comparative Example 1 described below, as in the case of Example 2. The treated spunbonded nonwoven fabric was used for a top sheet in the same manner as in Example 1 to prepare a disposable diaper. A disposable diaper having excellent skin care properties was obtained.
[0029]
(Comparative Example 1)
As in Example 1, a nonwoven fabric of 30 g / m 2 was obtained using 2.2 dtex × 44 mm having a sheath / core structure of polyethylene (PE) / polyester (PET) as raw cotton. The skin care properties were evaluated without applying any of the phospholipid-like structure and the hygroscopic agent to the obtained nonwoven fabric. Table 2 shows the results of the skin care evaluation. The obtained nonwoven fabric was inferior in skin care properties as compared with the treated nonwoven fabrics of Examples 1 to 4.
[0030]
(Comparative Example 2)
As in Example 1, a nonwoven fabric of 30 g / m 2 was obtained using 2.2 dtex × 44 mm having a sheath / core structure of polyethylene (PE) / polyester (PET) as raw cotton. To the obtained nonwoven fabric, only a phospholipid-like structure (Lipidure® MF-3) was added at 0.25% o.v. w. f (solid content). Table 2 shows the results of evaluating the skin care properties of the obtained nonwoven fabric. The obtained treated nonwoven fabric did not show a clear difference from the untreated nonwoven fabric (Comparative Example 1), and sufficient skin care properties could not be obtained.
[0031]
[Table 2]
Figure 2004285548
[0032]
【The invention's effect】
ADVANTAGE OF THE INVENTION According to this invention, it is suitable for use for clothing, medical care, health maintenance goods, sanitary materials and other items that come into contact with the body. Functional fiber and a fiber structure thereof. Further, it has become possible to provide an absorbent article having excellent skin care properties using the above-mentioned fiber structure.

Claims (8)

吸湿剤とリン脂質類似構造物が併用して含有又は付着されていることを特徴とする機能性繊維。A functional fiber characterized in that a moisture absorbent and a phospholipid-like structure are contained or attached in combination. 吸湿剤が多糖類であることを特徴とする請求項1記載の機能性繊維。The functional fiber according to claim 1, wherein the hygroscopic agent is a polysaccharide. 多糖類がキトサンであることを特徴とする請求項2記載の機能性繊維。The functional fiber according to claim 2, wherein the polysaccharide is chitosan. 多糖類がアラビノガラクタンであることを特徴とする請求項2記載の機能性繊維。The functional fiber according to claim 2, wherein the polysaccharide is arabinogalactan. 吸湿剤がポリスチレン系、ポリアクリロニトリル系、ポリアクリル酸エステル系、ポリメタクリル酸エステル系のいずれかのビニル系重合体で、スルホン酸基、カルボン酸基、リン酸基あるいは、それらの金属塩の少なくとも1種の親水基を有し、かつジビニルベンゼン、トリアリルイソシアネートまたはヒドラジンのいずれかで架橋された架橋重合体であることを特徴とする請求項1記載の機能性繊維。The moisture absorbent is a polystyrene-based, polyacrylonitrile-based, polyacrylate-based, or polymethacrylate-based vinyl polymer, and includes a sulfonic acid group, a carboxylic acid group, a phosphate group, or at least a metal salt thereof. The functional fiber according to claim 1, which is a crosslinked polymer having one kind of hydrophilic group and crosslinked with any of divinylbenzene, triallyl isocyanate and hydrazine. 請求項1〜5のいずれかに記載の機能性繊維が少なくとも一部に含有されてなることを特徴とする繊維構造物。A fibrous structure comprising the functional fiber according to any one of claims 1 to 5 at least partially. 請求項6に記載の繊維構造物が少なくとも一部に用いられてなることを特徴とする吸収性物品。An absorbent article, wherein the fiber structure according to claim 6 is used at least in part. 繊維構造物が不織布であり、該不織布が吸収性物品の肌に接触する面に用いられてなることを特徴とする請求項7に記載の吸収性物品。The absorbent article according to claim 7, wherein the fibrous structure is a nonwoven fabric, and the nonwoven fabric is used on a surface of the absorbent article that comes into contact with the skin.
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009291283A (en) * 2008-06-03 2009-12-17 Oji Nepia Co Ltd Absorbent article
JPWO2019146660A1 (en) * 2018-01-25 2021-01-28 東レ株式会社 Spun bond non-woven fabric
WO2022119207A1 (en) * 2020-12-02 2022-06-09 주식회사 엘지화학 Method for manufacturing super absorbent polymer
WO2022145242A1 (en) * 2020-12-29 2022-07-07 ユニ・チャーム株式会社 Composite absorbent object and sanitary supply

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009291283A (en) * 2008-06-03 2009-12-17 Oji Nepia Co Ltd Absorbent article
JPWO2019146660A1 (en) * 2018-01-25 2021-01-28 東レ株式会社 Spun bond non-woven fabric
WO2022119207A1 (en) * 2020-12-02 2022-06-09 주식회사 엘지화학 Method for manufacturing super absorbent polymer
WO2022145242A1 (en) * 2020-12-29 2022-07-07 ユニ・チャーム株式会社 Composite absorbent object and sanitary supply

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